phase change materials - comsol multiphysics...pcm donato rubinetti appendix a - modeling functions...
TRANSCRIPT
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Final Remarks
1
Phase Change MaterialsModeling Approach to Facilitate Thermal Energy Management in Buildings
Donato Rubinetti 1 Daniel A. Weiss 1 Arnab Chaudhuri 2 Dimitrios Kraniotis 2
1Institute of Thermal and Fluid EngineeringUniversity of Applied Sciences and Arts Northwestern Switzerland
2Department of Civil Engineering and Energy TechnologyOslo Metropolitan University, Norway
27.09.2018
PCM
DonatoRubinetti
Introduction
Application
Modeling
PhysicalModel
NumericalModel
ApplicationExample
Final Remarks
2
IntroductionWhat are PCMs and what are their application areas?
• Materials with a characteristically large enthalpy of fusion
• Latent heat energy storage systems
• Decouple energy supply and demand → increase efficiency
• Wide range of applications from -40 to 500◦C, i.e. space to photovoltaics
PCM
DonatoRubinetti
Introduction
Application
Modeling
PhysicalModel
NumericalModel
ApplicationExample
Final Remarks
3
IntroductionThe need for modeling PCM
• Obtain fundamental understanding for freezing and melting cycle
• Predict the complex behavior well enough
• Efficiently choose among the vast selection of suitable PCM
• Design improvements
• Reduce development costs
PCM
DonatoRubinetti
Introduction
PhysicalModel
Couplings
NumericalModel
ApplicationExample
Final Remarks
4
Physical ModelMultiphysical couplings
Heat Transfer Fluid Flow
Geometry
Phase Change
Natural Convection
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
Implementation
Melted fraction
ApplicationExample
Final Remarks
5
Numerical ModelImplementation into COMSOL Multiphysics
Laminar Flow (CFD)
Heat Transfer in Fluids
auxiliary algebraicequations for material
properties
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
Implementation
Melted fraction
ApplicationExample
Final Remarks
6
Numerical ModelMelted fraction θ(T )
θ(T ) =
0, solidT−(Tm−∆T/2)
∆T, mushy
1, liquid
(1)
Temperature T [°C]M
elt F
ract
ion
θ(T
)
0.0
0.5
1.0
35.4 36.4 37.4
Tm
Tm + 1
2 ∆T
Tm − 1
2 ∆T
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
7
Application ExampleObserved week in Oslo, temperature profile
Operation / Day Time [h]
Tem
pera
ture
T [°
C]
0 24 48 72 96 120 144 168
01/0
4/18
02/0
4/18
03/0
4/18
04/0
4/18
05/0
4/18
06/0
4/18
07/0
4/18−10
−5
05
10
Weather Forecast Oslo. 2018. url: https://www.wunderground.com/weather/no/oslo
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
8
Application ExampleWall crossection of a typical Norwegian building
9 15 15 50 50 120 100
x [mm] 21
1 2 3 4 5 6 7
1
2
Thermostat: Keep 19 < T < 26 °C+ internal heat gains
Weather data for T
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
9
Application ExampleResults - energy savings?
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
10
Application ExampleA less instulated wall crosssection
9 50 50 100
x [mm] 2
1
Indo
orro
om(a
ir)
PCM
CLT
woo
d
Am
bien
t(a
ir)
100 C
LT w
ood
1
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
11
Application ExampleResults - substantial energy savings!
Operation Time [h]
Roo
m H
eatin
g
0 24 48 72 96 120 144 168
Off
On
w/o PCM (66%)w/ PCM (13%)
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Temperature
Crossection 1
Results
Crosssection 2
Thermostat
Wall coretemperature
Final Remarks
12
Application ExampleWall core temperature
Operation / Day Time [h]
Wal
l Tem
pera
ture
[°C
]
0 24 48 72 96 120 144 168
1518
.520
2325
Time−averaged Room Temperature without PCM
Time−averaged Room Temperature with PCM
Melting Temperature (Liquefaction / Heat Absorption)
Freezing Temperature (Liquefaction / Heat Release)
With PCMWithout PCMPhase State
0.0
0.2
0.4
0.6
0.8
1.0
Mel
t / L
iqui
d F
ract
ion
θ(t)
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Final Remarks
13
Final Remarks
Discussion• Release heat to reduce heating demand• For well insulated walls → marginal savings!• But: PCM reduces peak temperatures on both extremes• Cold climates → main benefit in summer
Conclusion• Comprehensive and suitable modeling approach for phase change phenomena
developed• Rapid orientation whether a PCM meets thermal, technical and economic
requirements• Model shows the importance of including indoor dynamics to assess the PCM
potential• Numerically stable model, extendable to enhanced PCM
PCM
DonatoRubinetti
Introduction
PhysicalModel
NumericalModel
ApplicationExample
Final Remarks
14
Thank you for your attention!
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
15
A - Modeling FunctionsMelt Fraction θ(T )
θ(T ) =
0, solidT−(Tm−∆T/2)
∆T, mushy
1, liquid
(2)
Temperature T [°C]M
elt F
ract
ion
θ(T
)
0.0
0.5
1.0
35.4 36.4 37.4
Tm
Tm + 1
2 ∆T
Tm − 1
2 ∆T
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
16
A - Modeling FunctionsGaussian Distribution Function D(T )
D(T ) =e−
(T − Tm)2
(∆T/4)2√π(∆T/4)2
(3)
Temperature T [°C]G
auss
ian
Dis
trib
utio
n D
(T)
0.0
0.5
1.0
35.4 36.4 37.4
Tm
34.9 37.9
∆T = 2 K
∆T = 3 K
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
17
A - Modeling FunctionsModified Heat Capacity Cp(T )
Cp(T ) = Cp,s+θ(T )(Cp,l−Cp,s)+D(T )L(4)
Temperature T [°C]H
eat C
apac
ity C
P(T
) [J
/(kg
K)]
1926
2400
35.4 36.4 37.4
Cp,l
Cp,s
∆T
D(T) L
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
18
A - Modeling FunctionsModified Material Density ρ(T )
ρ(T ) = ρs+θ(T )(ρl−ρs)(5)
780
820
860
900
Temperature T [°C]M
odifi
ed D
ensi
ty ρ
(T)
[kg/
(m^3
K)]
35.4 36.4 37.4
ρs
ρl
Tm − 1
2 ∆T
Tm + 1
2 ∆T
Tm
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
19
A - Modeling FunctionsModified Thermal Conductivity k(T )
k(T ) = ks+k(T )(kl−ks)(6)
0.15
0.20
0.25
0.30
0.35
0.40
Temperature T [°C]M
odifi
ed T
herm
al C
ondu
ctiv
ity k
(T)
[W/(
mK
)]
35.4 36.4 37.4
ks
kl
Tm − 1
2 ∆T
Tm + 1
2 ∆T
Tm
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
20
A - Modeling FunctionsCarman-Kozeny Porosity Function S(T )
S(T ) = Am(1− θ(T ))2
θ(T )3 + ε(7)
0e+
004e
+08
8e+
08
Temperature T [°C]
Car
man
−K
ozen
y F
unct
ion
S(T
)
Solid dominatedmushy−zone
Liquid dominatedmushy−zone
35.4 36.4 37.4
Tm
Ali C. Kheirabadi and Dominic Groulx. “Simulating Phase Change Heat Transfer using COMSOL and FLUENT: Effect of the Mushy-ZoneConstant”. In: Computational Thermal Sciences: An International Journal 7.5-6 (2015). doi: 10.1615/ComputThermalScien.2016014279
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
21
A - Modeling FunctionsViscosity of n-eicosane µ(T )
µ(T ) = (9×10−4 T 2−0.6529 T+119.94)×10−3
(8)
40 50 60 70 80 90
0.00
00.
001
0.00
20.
003
0.00
4
Temperature T [°C]D
ynam
ic V
isco
sity
µ(T
) [P
a s]
Tm
n − eicosanewater
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
22
A - Modeling FunctionsBasic numerical requirements to govern the physics of PCM
conservation equation solid fraction liquid fraction
continuity Xmomentum Xenergy X X
→ direct approach: two subdomains for liquid and solid fraction with front trackingalgorithm
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
23
A - Modeling FunctionsAlternative approach: introduction of a mushy zone
• Idea: material properties are smeared out over an user-defined meltingtemperature range
• Method: use of porosity formulation, liquid and solid co-exist in the mushyzone• Benefits:
• avoid numerical singularities• use one single mesh• easy to implement
• Setback: highly mesh-dependent solution in terms of physical accuracy
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
24
A - Modeling Functions2D Test-case
Ω 1 x 1 cm2
x
y
n-eicosane
𝑇𝑇1 = 55 °C
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
25
A - Modeling FunctionsBoundary conditions and setup
x
y
❶
❷
❸
❹Ω
Boundary CFD Heat Transfer
❶
No slipwall
𝑻𝑻𝑹𝑹 = 𝟒𝟒𝟒𝟒,𝟓𝟓𝟓𝟓,𝟕𝟕𝟒𝟒 °𝐂𝐂
❷
Thermal insulation❸
❹
𝒈𝒈
Pressure constraint point, 𝒑𝒑 = 𝟒𝟒 𝐏𝐏𝐏𝐏
Transient study, 𝟒𝟒 < 𝒕𝒕 < 𝟏𝟏𝟒𝟒𝟒𝟒𝟒𝟒 𝐬𝐬
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Melt Fraction
Gaussian
Heat Capacity
Density
Th. Conductivity
Carman-Kozeny
Viscosity
Requirements
Mushy zone
2D Test-case
BC
Carman-Kozeny
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
26
A - Modeling FunctionsCarman-Kozeny porosity function S(T )
S(T ) = Am(1− θ(T ))2
θ(T )3 + ε(9)
0e+
004e
+08
8e+
08
Temperature T [°C]
Car
man
−K
ozen
y F
unct
ion
S(T
)
Solid dominatedmushy−zone
Liquid dominatedmushy−zone
35.4 36.4 37.4
Tm
Ali C. Kheirabadi and Dominic Groulx. “Simulating Phase Change Heat Transfer using COMSOL and FLUENT: Effect of the Mushy-ZoneConstant”. In: Computational Thermal Sciences: An International Journal 7.5-6 (2015). doi: 10.1615/ComputThermalScien.2016014279
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
Results
Model Setup
Material properties
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
27
B - Comparison to Experimental DataResults
−30 −20 −10 0 10 20 30
010
2030
4050
60
Radial Distance r [mm]
Axi
al D
ista
nce
z [m
m]
SimulationExperiment
t = 2164 s
−30 −20 −10 0 10 20 30
010
2030
4050
60
Radial Distance r [mm]A
xial
Dis
tanc
e z
[mm
]
SimulationExperiment
t = 6964 s
−30 −20 −10 0 10 20 30
010
2030
4050
60
Radial Distance r [mm]
Axi
al D
ista
nce
z [m
m] Simulation
Experiment
t = 11524 s
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
Results
Model Setup
Material properties
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
28
B - Comparison to Experimental DataModel Setup
z
r
𝑻𝑻𝑹𝑹 = 45 °C
n-eicosane
𝑯𝑯 = 59.8 mm
𝟐𝟐𝑹𝑹 = 63.8 mm
𝑻𝑻𝑩𝑩 = 32 °C
Ω
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
Results
Model Setup
Material properties
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
29
B - Comparison to Experimental DataMaterial properties of n-eicosane, comparison with water
n-eicosane watersolid liquid solid liquid
density ρ [kg m−3] 910 769 916 997thermal conductivity k [W m−1 K−1] 0.423 0.146 1.6 0.6heat capacity Cp [kJ kg−1 K−1] 1.9 2.4 2.1 4.2melting temperature Tm [◦C] 36.4 - 0 -latent heat of fusion L [kJ kg−1] 248 - 334 -
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
30
C - ResultsGrashof Number
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
31
C - ResultsMelt Fraction
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
32
C - ResultsMesh sensitivity - melting front prediction
0.000 0.002 0.004 0.006 0.008 0.010
0.00
00.
002
0.00
40.
006
0.00
80.
010
x−Coordinate [m]
y−C
oord
inat
e [m
]
100 s
300 s
500 s
700 s
900 s
Mesh cells25 x 2550 x 50100 x 100150 x 150
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
33
C - ResultsMelt fraction - curvature of melting front
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
34
C - ResultsLocal Grashof number - influence of natural convection
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
35
C - ResultsValidation case - setup
z
r
𝑻𝑻𝑹𝑹 = 45 °C
n-eicosane
𝑯𝑯 = 59.8 mm
𝟐𝟐𝑹𝑹 = 63.8 mm
𝑻𝑻𝑩𝑩 = 32 °C
Ω
Benjamin J. Jones et al. “Experimental and numerical study of melting in a cylinder”. In: International Journal of Heat and Mass Transfer49.15-16 (2006), pp. 2724–2738
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
Grashof Number
Melt Fraction
Mesh sensisitvity
Melt fraction
Gr
Validation I
Validation II
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
36
C - ResultsValidation case - comparison to experimental data
−30 −20 −10 0 10 20 30
010
2030
4050
60
Radial Distance r [mm]
Axi
al D
ista
nce
z [m
m]
SimulationExperiment
t = 2164 s
−30 −20 −10 0 10 20 30
010
2030
4050
60Radial Distance r [mm]
Axi
al D
ista
nce
z [m
m]
SimulationExperiment
t = 6964 s
−30 −20 −10 0 10 20 30
010
2030
4050
60
Radial Distance r [mm]
Axi
al D
ista
nce
z [m
m] Simulation
Experiment
t = 11524 s
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
37
D - Application ExampleInternal Heat Gains, Hourly
050
010
0015
00
Hour of day [h]
Sen
sibl
e H
eat G
ain
[W]
0:00 03:00 06:00 09:00 12:00 15:00 18:00 21:00 24:00
PeopleLightingEl. equipmentRadiationSum
Komite-SN/K-034. Bygningers energiytelse, Beregning av energibehov of energiforsyning (engl.: Energy performance of buildings, calculationof energy needs and energy supply). URL:https://www.standard.no/no/Nettbutikk/produktkatalogen/Produktpresentasjon/?ProductID=859500. 2016
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
38
D - Application ExampleIndoor Temperature w/o PCM
Operation / Day Time [h]
Tem
pera
ture
T [°
C]
0 24 48 72 96 120 144 168
01/0
4/18
02/0
4/18
03/0
4/18
04/0
4/18
05/0
4/18
06/0
4/18
07/0
4/18
−10
−5
05
1015
2025 Comfort
TemperatureRange
AmbientIndoor
Weather Forecast Oslo. 2018. url: https://www.wunderground.com/weather/no/oslo
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
39
D - Application ExampleIndoor Temperature w/ PCM
Operation / Day Time [h]
Tem
pera
ture
T [°
C]
0 24 48 72 96 120 144 168
01/0
4/18
02/0
4/18
03/0
4/18
04/0
4/18
05/0
4/18
06/0
4/18
07/0
4/18
−10
−5
05
1015
2025 Comfort
TemperatureRange
AmbientIndoor
Weather Forecast Oslo. 2018. url: https://www.wunderground.com/weather/no/oslo
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
40
D - Application ExampleThermostat
Operation Time [h]
Roo
m H
eatin
g
0 24 48 72 96 120 144 168
Off
On
w/o PCM (66%)w/ PCM (13%)
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
41
D - Application ExampleWall Core Temperature
Operation / Day Time [h]
Wal
l Tem
pera
ture
[°C
]
0 24 48 72 96 120 144 168
1518
.520
2325
Time−averaged Room Temperature without PCM
Time−averaged Room Temperature with PCM
Melting Temperature (Liquefaction / Heat Absorption)
Freezing Temperature (Liquefaction / Heat Release)
With PCMWithout PCMPhase State
0.0
0.2
0.4
0.6
0.8
1.0
Mel
t / L
iqui
d F
ract
ion
θ(t)
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
Internal Heat Gains,Hourly
Indoor Temperaturew/o PCM
Indoor Temperaturew/ PCM
Thermostat
Wall CoreTemperature
Wall Cross-Section
E - 2DTest-Case
F -DimensionlessEstimation
42
D - Application ExampleWall Cross-Section
9 15 15 50 50 120 100
x [mm] 21
Indo
orro
om(a
ir)
Soft
woo
d
PCM
CLT
woo
d
Soft
woo
d
Min
eral
woo
l
Am
bien
t(a
ir)
1 2 3 4 5 6 7
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
2D Test-Case
Couplings
2D Test-case
F -DimensionlessEstimation
43
E - 2D Test-Case2D Test-Case
Ω 0.01 x 0.01 m2
𝑻𝑻𝑹𝑹
x
y
n-eicosane
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
2D Test-Case
Couplings
2D Test-case
F -DimensionlessEstimation
44
E - 2D Test-CaseMultiphysical couplings
Solid
𝑻𝑻𝑹𝑹 ≫ 𝑻𝑻𝒎𝒎
𝑻𝑻𝑹𝑹 > 𝑻𝑻𝒎𝒎
Liquid
𝑻𝑻𝑹𝑹: Boundary Temperature
𝑻𝑻𝒎𝒎: Melting Temperature
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
2D Test-Case
Couplings
2D Test-case
F -DimensionlessEstimation
45
E - 2D Test-Case2D Test-case
Ω 0.01 x 0.01 m2
𝑻𝑻𝑹𝑹= 40, 55, 70 °C
x
y
n-eicosane
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
Mushy ZoneInvestigation
Scaling Variables
DimensionlessEquations
DimensionlessNumbers
Values For LiquidFraction
46
F - Dimensionless EstimationMushy Zone Investigation
Temperature T [°C]
Mel
t Fra
ctio
n θ(
T)
0.0
0.5
1.0
Tm−1/2∆T Tm Tm+1/2∆T
Solid dominated
mushy−zone
Liquid dominated
mushy−zone
0
1
2
3
4
5
6
7
8
9
10
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
Mushy ZoneInvestigation
Scaling Variables
DimensionlessEquations
DimensionlessNumbers
Values For LiquidFraction
47
F - Dimensionless EstimationScaling Variables
x =x
Hy =
y
Hp =
p − prefρu0
2
t =u0t
Huuu =
uuu
u0T =
T − Tref
TR − Tref
Φv =
(H
u0
)2
Φv ∇ = H∇ D
Dt=
(H
u0
)D
Dt
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
Mushy ZoneInvestigation
Scaling Variables
DimensionlessEquations
DimensionlessNumbers
Values For LiquidFraction
48
F - Dimensionless EstimationDimensionless Equations
∇ · uuu = 0 (10)
Duuu
Dt= −∇p +
[µ
u0ρH
]∇2uuu −
[gβ(TR − Tm)H
u02
](ggg
g
)(T − Tm) (11)
DT
Dt=
[k
u0ρHCp
]∇2T +
[µu0
ρHCp(TR − Tm)
]Φv (12)
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
Mushy ZoneInvestigation
Scaling Variables
DimensionlessEquations
DimensionlessNumbers
Values For LiquidFraction
49
F - Dimensionless EstimationDimensionless Numbers
Brinkman Br =µu0
2
k∆Theat production visc. dissipation vs heat transport by cond.
Grashof Gr =gβ∆TH3
ν2buoyant forces vs viscous forces
Prandtl Pr =ν
αmomentum diffusivity vs thermal diffusivity
Rayleigh Ra =gβ∆TH3
αν= GrPr heat transport conv. vs cond.
Reynolds Re =ρu0H
µinertial vs viscous forces
PCM
DonatoRubinetti
Appendix
A - ModelingFunctions
Validation
C - Results
D -ApplicationExample
E - 2DTest-Case
F -DimensionlessEstimation
Mushy ZoneInvestigation
Scaling Variables
DimensionlessEquations
DimensionlessNumbers
Values For LiquidFraction
50
F - Dimensionless EstimationValues For Liquid Fraction
Dimensionless group TR
40 ◦C 55 ◦C 70 ◦C[µ
u0ρH
]=
1
Re1 1 1
[gβ(TR − Tm)H
u02
]=
Gr
Re2=
Ra
PrRe2266 1376 2486
[k
u0ρHCp
]=
1
RePr0.008 0.008 0.008
[µu0
ρHCp(TR − Tm)
]=
Br
RePr1.25 × 10−10 2.42 × 10−11 1.34 × 10−11