perth basin well intervention activities environment plan

DOCUMENT NO

HSE-E-075-SUM

REVISION

4

DATE OF REVISION

14 OCTOBER 2019

Perth Basin

Well Intervention Activities

Environment Plan Summary

Perth Basin Well Intervention Activities Environment Plan Summary

HSE-E-075-SUM Rev 4 Page 3 of 40

TABLE OF CONTENTS

1.0 INTRODUCTION ............................................................................................................................... 7

1.1 Contact Details ............................................................................................................................... 7

1.2 Purpose .......................................................................................................................................... 9

1.3 Environment Plan Implementation ................................................................................................ 9

2.0 DESCRIPTION OF THE ACTIVITY ...................................................................................................... 10

2.1 Scope ............................................................................................................................................ 10

2.2 Location ........................................................................................................................................ 10

2.3 WIA related activities ................................................................................................................... 15

2.4 Well Intervention Activities ......................................................................................................... 15

2.4.1 Timeframes ................................................................................................................... 15

2.4.2 Chemical Disclosure for Products, Additives, Chemicals and Other Substances ......... 15

2.4.3 Decommissioning (Plug and Abandonment) Activities ................................................ 16

2.5 Demobilisation ............................................................................................................................. 16

2.6 Rehabilitation ............................................................................................................................... 16

2.7 Utilities and Services .................................................................................................................... 16

2.7.1 Water ............................................................................................................................ 16

2.7.2 Refuelling ...................................................................................................................... 16

2.7.3 Electricity ...................................................................................................................... 17

2.7.4 Offices and Storage Areas ............................................................................................ 17

2.7.5 Chemical Storage .......................................................................................................... 17

2.7.6 Waste Disposal ............................................................................................................. 18

3.0 DESCRIPTION OF THE ENVIRONMENT ............................................................................................ 20

3.1 Physical Environment ................................................................................................................... 20

3.1.1 Climate .......................................................................................................................... 20

3.1.2 Soil ................................................................................................................................ 20

3.1.3 Surface and Groundwater Systems .............................................................................. 20

3.2 Biological Environment ................................................................................................................ 20

3.2.1 WA Biodiversity Search ................................................................................................ 21

3.2.2 Australian Protected Matters Search ........................................................................... 21

3.2.3 Conservation Area ........................................................................................................ 22

3.2.4 Environmentally Sensitive Areas .................................................................................. 24

3.2.5 Groundwater Dependent Ecosystems .......................................................................... 24

3.2.6 Vegetation Communities and Flora .............................................................................. 24

3.2.7 Weeds ........................................................................................................................... 25

3.2.8 Dieback ......................................................................................................................... 26

3.2.9 Fauna ............................................................................................................................ 26

3.3 Heritage ........................................................................................................................................ 28

3.3.1 Aboriginal Heritage ....................................................................................................... 28



3.3.2 European Heritage ........................................................................................................ 30

3.4 Socio-economic Environment ...................................................................................................... 30

4.0 ENVIRONMENTAL RISK ASSESSMENT AND MANAGEMENT ............................................................ 31

4.1 Risk Management and Justification of ALARP ............................................................................. 31

4.2 Risk Classification and Reporting Requirements ......................................................................... 31

5.0 IMPLEMENTATION STRATEGY ........................................................................................................ 35

5.1 Systems, Practices and Procedures.............................................................................................. 36

5.2 Record Keeping ............................................................................................................................ 38

6.0 CONSULTATION ............................................................................................................................. 39

7.0 REFERENCES .................................................................................................................................. 40

LIST OF FIGURES

Figure 1: Map of MEPAU Perth Basin Permits and Producing Fields ............................................................ 8

Figure 2: Map of Potential Wells to be intervened in the L1 (Hovea Area) ................................................ 11

Figure 3: Map of Potential Wells to be intervened in the L1 (Dongara) and L2 ......................................... 12

Figure 4: Map of Potential Wells to be intervened in L4 and L5 (Woodada) ............................................. 13

Figure 5: Map of Potential Wells to be intervened in L1 (Waitsia) ............................................................. 14

Figure 6: Nature Reserves, ESAs and Water Supply Areas within MEPAU Permit Areas ........................... 23

Figure 7: Registered Aboriginal Heritage Sites Perth Basin Permit Areas .................................................. 29

LIST OF TABLES

Table 1 Acronyms ....................................................................................................................................... 6

Table 2: WIA Waste Disposal ..................................................................................................................... 18

Table 3: NatureMap Species Search Summary .......................................................................................... 21

Table 4: EPBC Act Protected matters report search summary .................................................................. 21

Table 5: Conservation Significant Fauna Desktop Search (incorporating Field Survey Results) ............... 27

Table 6: WIA Risk Assessment ................................................................................................................... 32

Table 7: Systems, Practices and Procedures.............................................................................................. 36

Table 8a: System Details .............................................................................................................................. 43

Table 8b: Product List .................................................................................................................................. 43

Table 8c: Chemical List ................................................................................................................................ 51

Table 9: Products, additives, chemicals and other substances (Cementing) ............................................ 54

Table 9a: System Details .............................................................................................................................. 54

Table 9b: Product List .................................................................................................................................. 54

Table 9c: Chemical List ................................................................................................................................ 59



LIST OF APPENDICES

APPENDIX 1 WIA FLUIDS CHEMICAL DISCLOSURE TABLES ........................................................................ 42

APPENDIX 2 SAFETY DATA SHEETS – FLUIDS ............................................................................................ 52

APPENDIX 3 WIA CEMENTING CHEMICAL DISCLOSURE TABLES ................................................................ 53

APPENDIX 4 SAFETY DATA SHEETS - CEMENTING ..................................................................................... 61



The following acronyms have been used throughout this Plan and are defined in Table 1.

Table 1 Acronyms

Acronym Definition

ALARP As Low As Reasonably Practicable

ASRIS Australian Soil Resource Information System

BAM Act 2007 Biosecurity and Agricultural Management Act 2007

BoM Bureau of Meteorology

DBCA Department of Biodiversity, Conservation and Attractions (previously Department of Parks and Wildlife (DPaW))

DFES Department of Fire and Emergency Services (formerly Fire and Emergency Services Authority (FESA))

DG Dangerous Goods

DMIRS Department of Minerals, Industry Regulation and Safety (previously Department of Mines and Petroleum (DMP))

DPF Dongara Production Facility

DWER Department of Water and Environmental Regulation (formerly Department of Water (DoW) and Department of Environment Regulation (DER) / Department of Environment Conservation (DEC))

E&Ds Emissions and Discharges

EARS DMIRS Environmental Assessment and Regulatory System

EP Environment Plan

EPBC Act Environment Biodiversity Conservation Act 1999

ERP Emergency Response Plan

ESA Environmentally Sensitive Area

EWSWA Environmental Weed Strategy West Australia

GDE Groundwater Dependent Ecosystem

HSEQ Health, Safety, Environment and Quality

JHA Job Hazard Analysis

Lead Contractor The main contractor involved with the WIA or WIA related activity.

MNES Matters of National Environmental Significance

MyOSH Upstream PS/AWE HSEQ Database

NGER National Greenhouse and Energy Reporting Act 2007

OSCP Oil Spill Contingency Plan

PTW Permit to Work

WoNS Weeds of National Significance

WIA Well Intervention Activities



1.0 INTRODUCTION

AWE Perth Pty Ltd is a wholly owned subsidiary of AWE Limited. Mitsui E&P Australia Pty Ltd

and AWE Ltd (including subsidiaries) are wholly owned subsidiaries of Mitsui & Co. Ltd.

Combined they form the unified brand Mitsui E&P Australia (MEPAU).

MEPAU has a Perth based operations office and one active gas production facility in the Mid-

West region, the Xyris Production Facility (XPF), with the Dongara Production Facility (DPF)

and Hovea Production Facility (HPF) active in part and with Central Control at DPF. The

Woodada Gas Production Facility is in care and maintenance (Figure 1). MEPAU also has an

operator presence in New Zealand.

In addition to these operations, MEPAU is a non-operating joint venture partner with

petroleum activities in Australia’s onshore (Queensland) and offshore regions (Western

Australia and Victoria) and Indonesia.

1.1 Contact Details

External Affairs Manager

MEPAU

(08) 9480 1300

PO Box 574

WEST PERTH 6782



Figure 1: Map of MEPAU Perth Basin Permits and Producing Fields



1.2 Purpose

The purpose of this document is to provide a summary of the Perth Basin Well Intervention

Activities (WIA) Environment Plan [HSE-E-075].

This summary document has been prepared to in accordance with requirements of

subregulation (7) of the Petroleum and Geothermal Energy Resources (Environment)

Regulations 2012.

1.3 Environment Plan Implementation

MEPAU is the custodian of this EP and has overall responsibility for its implementation,

compliance and revision.



2.0 DESCRIPTION OF THE ACTIVITY

2.1 Scope

The scope of this document includes the environmental aspects of all Perth Basin WIAs

within AWE Perth Pty Ltd permit areas (Figure 1).

The activities listed in Sections 2.3 to 2.7 of this document could potentially be conducted on

all wells in the Perth Basin.

2.2 Location

There are potentially fifty-five (55) wells (plus any new drilled wells) that could be worked

over in the Perth Basin. Forty-four (44) of these wells are located on cleared farmland; and

eleven (11) are located within Nature Reserve (Figure 2 to Figure 5).



Figure 2: Map of Potential Wells to be intervened in the L1 (Hovea Area)



Figure 3: Map of Potential Wells to be intervened in the L1 (Dongara) and L2



Figure 4: Map of Potential Wells to be intervened in L4 and L5 (Woodada)



Figure 5: Map of Potential Wells to be intervened in L1 (Waitsia)



2.3 WIA related activities

The WIA related activities include:

• Possible modifications to the existing well site pad area to ensure the ground can support the

WIA, and ancillary equipment;

• Mobilisation of WIA Equipment, personnel and supplies to and from the site;

• Conducting the WIA;

• Demobilisation of WIA Equipment, personnel and supplies; and

• Restoration of the site following the completion of activities.

2.4 Well Intervention Activities

WIA are remedial operations undertaken by MEPAU to maintain maximum oil or gas

producing rates and well integrity. WIA are any operation carried out on an oil or gas well

during, or at the end of its productive life, that alters the state of the well and or well

geometry, provides well diagnostics or manages the production of the well. The types of WIA

conducted on the Perth Basin Production facilities can be summarised as follows:

• General WIA (covered under this EP):

• Wellhead Maintenance;

• Pumping;

• Wireline/Slickline operations;

• Well diagnostics; and

• Acid wash treatments.

• WIA requiring an Environmental Bridging Document:

• Pulling and Replacing a Completion;

• Snubbing;

• Coiled tubing;

• Well workover;

• Well testing;

• Remedial Cement Squeezing; and

• Plug and Abandonment.

2.4.1 Timeframes

WIA generally run for approximately 14 days or less (including both

mobilisation/demobilisation time). Noise and light disturbance to surrounding landowners is

not generally a concern due to the remote location of the wells and due to WIA being

typically conducted during daylight hours.

2.4.2 Chemical Disclosure for Products, Additives, Chemicals and Other Substances

DMIRS set out the requirements for chemical disclosure within the Chemical Disclosure

Guideline released August 2013. The guideline details the chemical disclosure requirements

for products, additives, chemicals and other substances used ‘down-hole’ in petroleum or



geothermal related activities regulated under regulation 15(9) of the Petroleum and

Geothermal Energy Resources (Environment) Regulations 2012.

For General WIA requiring down-hole chemical use (refer to Section 2.4), the proposed

chemicals are outlined within the disclosure tables within Appendix 1 and the corresponding

Safety Data Sheets are listed within Appendix 2.

2.4.3 Decommissioning (Plug and Abandonment) Activities

When a well has reached the end of its life due to economic, integrity or reservoir reasons,

the well will be decommissioned. The objective of decommissioning operations is to isolate

the reservoir communication via the wellbore to surface as well as any other zones that may

be in communication with the well. Well decommissioning is undertaken in accordance with

the applicable Well Management Plan approved under the Petroleum and Geothermal

Energy Resources (Resource Management and Administration) Regulations 2015.

2.5 Demobilisation

Upon completion of the WIA work scope, all WIA equipment, personnel and supplies will be

demobilised. Equipment will be transferred to the next WIA location or stacked awaiting

further work.

2.6 Rehabilitation

A rehabilitation EP will be submitted to the DMIRS for approval within 12 months of well

decommissioning. Rehabilitation will commence as soon as practicable, usually within two

years of the well decommissioning.

2.7 Utilities and Services

The utilities and services for WIA are described below.

2.7.1 Water

Water cartage equipment for WIA includes a mobile tanker (38 kL) and two to four

(depending on well volume) cylindrical and / or open-topped water tanks (16 to 60 kL sized)

for the storage of water at a well site. The water is supplied by licensed onsite water bores

or to the site via mobile truck mounted water tankers either collected from the HPF or

Dongara townsite.

Bottled drinking water is supplied and available to personnel at the site office.

2.7.2 Refuelling

Diesel fuel is delivered by mobile diesel tank (mounted on a 4WD vehicle) to equipment

diesel tanks on site. Refuelling will occur at the WIA site. Storage of flammable or

combustible liquids will be designed to contain not less than 110% of the volume of the

largest storage vessel, and at least 25% of the total volume of substances stored.



For small WIA, if refuelling is required, it will be via a vehicle-mounted mobile diesel tank or

portable cans. For larger WIA, a dual skinned diesel tank is set up for refuelling the mobile

tank with bulk fuel being delivered by an off-site contractor.

2.7.3 Electricity

Portable on-site diesel generation provides power during WIA.

2.7.4 Offices and Storage Areas

Temporary offices, workshops and storage areas for typical WIA are as follows:

• 37 m3 (2.4 mW x 6 mL x 2.6 mH) break room

• 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) Rig Manager/HSE office

• 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) Company Man office

• 20 m3 (2.4 mW x 3.2 mL x 2.6 mH) workshop

• 50 m3 (2.4 mW x 7.9 mL x 2.6 mH) workshop

Additional ancillary offices or work areas may be supplied by the Lead Contractor or MEPAU

depending on the nature and scale of the WIA.

2.7.5 Chemical Storage

The chemicals required for WIA will be stored and handled as follows:

Onsite storage:

• A Lease Liner (polypropylene composite) (maximum infiltration rate: 10-9 m/s) will be

in place for each well and used as a means of secondary containment for the returned

fluids expected as part of the well-decommissioning activity. The polypropylene

composite Lease Liner is four times more puncture resistant than commonly used

HDPE liners, and its nonslip surface helps prevent slips and falls. The liner is a three-

layer polypropylene composite consisting of three barrier films sandwiched by double

layers of needle punched geotextile with heat fused surfaces.

• The WIA fluids will be mixed onsite within a water cart, a mud mixing tank or storage

vessel(s) with secondary containment (Lease Liner and/or drip trays) to capture any

spillage should it occur. The chemicals will be stored in the portable bunding as

described above. The process of mixing chemicals on location will be supervised by site

personnel. Secondary containment for freshwater storage is not required.

• Chemical storage (environmentally hazardous) will be within a 20 ft internally bunded

Dangerous Goods container. Storage of flammable or combustible liquids will be

designed to contain not less than 110% of the volume of the largest storage vessel, and

at least 25% of the total volume of substances stored.

• Liquid hydrocarbon products such as lubricants will be stored within bunded pallets or

the 20 ft internally bunded Dangerous Goods container designed to contain not less

than 110% of the volume of the largest storage vessel.

Offsite storage:



• WIA chemicals stored offsite will be stored at the Hovea Production Facility Chemical

Shed (this is a permanent bunded storage shed) or within a lease liner. Dangerous

Goods are stored in compliance with the Dangerous Goods Site Licence (DGS016892).

2.7.6 Waste Disposal

WIA waste will be disposed of in accordance with the Landfill Waste Classification and Waste

Definitions 1996 (as amended 2018) and the Perth Basin Waste Management Plan [PB-HSE-

PLN-001] as summarised in Table 2.

Table 2: WIA Waste Disposal

Waste Stream Minimisation Strategy Onsite storage Disposal location

General waste Purchase items in bulk

to minimise packaging Covered skip Class I Landfill

Asbestos containing

assets, (i.e.

Asbestos Gaskets)

Historic asbestos

containing assets, are

no longer procured

<10m3 bagged and

handled according to

Asbestos Management

Plan1

Class I Landfill

Solid oily waste

Significant

maintenance activities

conducted off-site

Covered oil waste skip Class III Landfill

Liquid oily waste

Significant

maintenance activities

conducted off-site

Drum, IBC or tank

DPF condensate

storage for export /

hydrocarbon recycling

facility / Class III

Landfill

Oily water

Separation of liquid

oily waste and water

where possible

Drum, IBC or tank

DPF waste water

system / hydrocarbon

recycling facility / Class

III Landfill

Wood Recycle pallets Open top skip/back

freighted

Class I Landfill or

returned to the

supplier

Scrap steel Recycle Open top skip Scrap steel recycling

facility

Empty drums and

IBCs Use reusable IBCs

Stored in a bunded

area

Class I Landfill or

returned to the

supplier

1 Disposal of >10m3 of bonded (non-friable) asbestos requires a Restricted Asbestos Removal Licence



Waste Stream Minimisation Strategy Onsite storage Disposal location

Septic liquid waste

from ablutions Prevent spills Approved Class III Landfill Facility

Returned

fluids/WIA fluids

Evaporate on site, plan

fit for purpose volume

for WIA

Returned fluids tank/

WIA open top tank

Waste management

contractor/Approved

evaporation pond/

disposal well (i.e.

Eremia-04, DPF WDW).



3.0 DESCRIPTION OF THE ENVIRONMENT

3.1 Physical Environment

3.1.1 Climate

The WIA are located across the permit areas in the Perth Basin region, situated

approximately 300 km north of Perth (Figure 1). The region has a Mediterranean-type

climate characterised by seasonal patterns of hot, dry summers and mild, wet winters. The

area is subject to high wind speeds, dust storms, lightning storms, high summer

temperatures and low winter night temperatures.

3.1.2 Soil

Generally, soils within the Perth Basin are light and sandy and well drained. Beard (1976)

described the soils as “calcareous sand soils of minimal development”. The soils consist of

calcareous and siliceous sand underlain by aeolianite, which is often exposed.

The Perth Basin is situated entirely within the Geraldton Sandplains Biogeographical Region.

Within this region, three broad physiographical units are recognised; the Swan Coastal Plain,

the Arrowsmith Region and the Dandaragan Plateau. The areas in which WIA will be

undertaken will generally be located entirely within the Swan Coastal Plain unit, which forms

an elongated strip approximately 40 km wide running along the coast.

3.1.3 Surface and Groundwater Systems

The hydrology of the region is dominated by the landform units described in Section 3.1.2.

Drainage is westward but the Irwin River valley to the north of the region is the only major

coordinated drainage indentation. A number of swamps surrounded by dense scrub,

frequent limestone outcrops and the occasional laterite outcrop are the other major

features in the region. The sub-surface geology of the area consists of the Late Jurassic

Yarragadee Formation, which is overlain by Tertiary Sediments. Groundwater is present in

the Tertiary Sediments and the Yarragadee Formation, and the groundwater level is near, or

at surface in the aforementioned swamps and low-lying areas, following the surface

topography, but with lower relief. The porous and permeable coastal limestone and dune

systems tend to allow rainwater to percolate vertically to the water table rather than

running laterally off the surface.

3.2 Biological Environment

Information on the fauna assemblage of the Perth Basin Permit WIA areas was drawn from a

wide range of sources. These included State and Federal government databases. Databases

accessed were the DPaW Naturemap (incorporating the Western Australian Museum’s

Fauna Base and the DPaW Threatened and Priority Fauna Database), BirdLife Australia’s

Atlas Database (BA), the EPBC Protected Matters Search Tool and the BCE database as

described in Sections 3.2.1 to 3.2.9.



3.2.1 WA Biodiversity Search

A WA Biodiversity search (Naturemap) – Department of Parks and Wildlife (DPaW) was

conducted (12/11/2018), a summary of the conservation significant species identified within

the permit areas is provided (Table 3).

Table 3: NatureMap Species Search Summary

Conservation Status Species Records

Non-conservation taxon 2436 22061

Other specially protected fauna 1 2

Priority 1 24 132

Priority 2 59 509

Priority 3 94 888

Priority 4 45 821

Protected under international agreement 12 37

Rare or likely to become extinct 41 888

Total 2712 25338

3.2.2 Australian Protected Matters Search

The EPBC Act Protected Matters Report provides general guidance on matters of national

environmental significance (MNES) and other matters protected by the EPBC Act. A

summary of MNES in the permit areas is provided (Table 4).

Table 4: EPBC Act Protected matters report search summary

MNES Presence Status

World Heritage Properties None -

National Heritage Places 1 Lesueur National Park – located west of EP455

Wetlands of International Importance

None -

Great Barrier Reef Marine Park

None -

Commonwealth Marine Area 1 Not located within Permit areas.

Listed Threatened Ecological Communities

3 Refer to Section 3.2.6 for likely occurrence.

Listed Threatened Species 131 Refer to Section 3.2.9 for likely occurrence.

Listed Migratory Species 50 Refer to Section 3.2.9 for likely occurrence.



3.2.3 Conservation Area

The Department of Biodiversity, Conservation and Attractions (DBCA) manages 23 million

hectares of national parks, conservation parks, regional parks, nature reserves, state forest

and timber reserves in WA. DBCA manages these areas for the conservation of biodiversity

in ecosystems within these areas. Major conservation areas across the MEPAU Perth Basin

permit areas (refer to Figure 6). Wells within Nature Reserves are Drakea-02 (Yardanogo

Nature Reserve), East Lake Logue 01 & 02, Woodada-06, 08, 11, 12, 14, 15, 16 and 19, and

Woodada Deep-01 (Lake Logue Nature Reserve) (Figure 4).

3.2.3.1 Red Book

Red Book recommendations, released by the EPA between 1976 and 1984, were made on

areas to be classed as conservation reserves. These EPA tenures are part of a listing of Crown

Land areas identified in 'Conservation Reserves for Western Australia' and identify different

systems which the EPA considered to be of environmental significance and proposed

conservation areas.

The proposed WIA will not be within any Red Book areas.



Figure 6: Nature Reserves, ESAs and Water Supply Areas within MEPAU Permit Areas



3.2.4 Environmentally Sensitive Areas

Environmentally Sensitive Areas (ESAs) are declared under the Environmental Protection

(Clearing of Native Vegetation) Regulations 2004 and cover:

• Declared World Heritage property sites;

• An area that is registered on the Register of the National Estate;

• A defined wetland and the area within 50 m of the wetland;

• The area covered by vegetation within 50 m of rare flora;

• The area covered by a threatened ecological community;

• Bush Forever sites;

• The areas covered by the following policies:

• the Environmental Protection (Gnangara Mound Crown Land) Policy 1992

• the Environmental Protection (Western Swamp Tortoise Habitat) Policy 2002

• The areas covered by the lakes to which the Environmental Protection (Swan Coastal

Plain Lakes) Policy 1992 applies;

• Protected wetlands as defined in the Environmental Protection (South West

Agricultural Zone Wetlands) Policy 1998.

• Areas of fringing native vegetation in the policy area as defined in the Environmental

Protection (Swan and Canning Rivers) Policy 1997

The potential WIA wells are located within the Perth Basin permit areas (Figure 4). Wells

within ESAs are East Lake Logue 01 & 02, Woodada-06, 08, 11, 12, 14, 15, and 16 and

Woodada Deep-01.

3.2.5 Groundwater Dependent Ecosystems

A previous Groundwater Dependent Ecosystem (GDE) study was undertaken by Rutherford

et al (2005) for the Northern Perth Basin. This study considered sites to be potentially reliant

on groundwater only if the depth to groundwater was less than 20 m. Any remnant

vegetation in areas of shallow groundwater could potentially be groundwater dependent.

Most areas across the permits are classified as having low/moderate potential for GDEs

(BoM, 2018).

3.2.6 Vegetation Communities and Flora

The Perth Basin is located within the Irwin Botanical District (Northern Sandplains Region),

within the Southwest Botanical Province as defined by Beard (1976). Under the Interim

Biogeographic Regionalisation for Australia (IBRA) (Environment Australia 2000), the area

lies on the Geraldton Sandplain, which is described as ‘mainly proteaceous scrub-heaths, rich

in endemics, on the sandy earths of an extensive, undulating, lateritic sandplain mantling

Permian to Cretaceous strata’.

Vegetation surveys have been undertaken in the Perth Basin in support of petroleum

activities and include surveys. Vegetation in the region ranges from native vegetation with



little or no disturbance in the Beekeepers, Yardanogo and Lake Logue Nature Reserves to

cleared areas for broad acre cropping and grazing with little remnant native vegetation. A

summary of the Threatened Flora across the region is provided in the following sections.

3.2.6.1 Threatened Ecological Communities (TECs)

The EPBC Act Protected Matters Search identified three Listed TECs likely to occur within the

Permit areas as listed below:

• Banksia Woodlands of the Swan Coastal Plain ecological community (Endangered)

• Eucalypt Woodlands of the Western Australian Wheatbelt (Critically Endangered)

• Subtropical and Temperate Coastal Saltmarsh (Vulnerable)

As WIA are on existing sites, which require minimal clearing, the potential risk of impacting

TECs is low.

3.2.6.2 Declared Rare Flora (DRF)

A desktop search of the Declared Rare Flora List (DBCA, Threatened and Priority Flora List,

2018), identified 122 Threatened Flora2 distributed across the Mid-west region.

WIA are on existing sites, which require minimal clearing. AWE has a clearing permit (CPS

8207) to cover the clearing of native vegetation regrowth in the Woodada Gas Field area. A

targeted flora and vegetation survey will be contracted for clearing of native vegetation

where no clearing permit (or clearing exemption) is in place. The survey will include a search

for the presence of Threatened Flora.

3.2.7 Weeds

Weeds commonly found across the key Perth Basin permit areas are summarised in the

following text.

L1/L2

A total of 38 weed taxa were recorded within a recent weed assessment of Waitsia-03

(Permit L1). Of these taxa, three are rated as High under the EWSWA (CALM 1999) and are

therefore considered to be significant weed species. There were no taxa listed as a Declared

Pests under BAM Act (DAF 2017) or WoNS (AWC 2017) recorded during the survey

(Woodman, 2017).

The L2 permit areas consist mainly of previously cleared agricultural land (excluding the

Dongara /Beekeepers Nature Reserves). The common weed species found across the

Dongara region Golden Crownbeard (Dongara Daisy) Verbesina encelioides, African Boxthorn

2 Threatened Flora - Specially protected under the Wildlife Conservation Act 1950, listed under Schedules 1, 2 and 3 of

the Wildlife Conservation (Rare Flora) Notice (which may also be referred to as Declared Rare Flora).



Lycium ferocissimum Miers, African Love Grass Eragrostis curvula (Schrad.) Nees, Walkaway

Burr Cenchrus echinatus L. (Shire of Irwin, Pest Plant Advice Notes).

L4/L5

Weed foliage cover is low at the majority of sites assessed (total weed covers of 5% or less)

with the exception of Woodada-02 and sumps and drainage gullies associated with a number

of well pads. The majority of the tracks around Woodada had only scattered minor weeds.

However, there were some areas along the tracks which had a high cover of weeds

(Woodman, 2012).

3.2.8 Dieback

The project area lies at the northern limit of the portion of Western Australia where

significant plant disease caused by Phytophthora cinnamomi is known to occur. The

environmental conditions of the area significantly affect the pathogens ability to survive or

flourish and spread over time. All land with an annual average rainfall of more than 400

millimetres and suitable soil composition is considered vulnerable to Phytophthora Dieback

(Department of Parks and Wildlife, 2015).

Dieback is known to occur in permit areas L4 and L5. Phytopthora cinnamomi, the most

destructive species, is known to occur over a large area in Eneabba Creek and Lake Logue

and at several small sites along the Leeman and Erindoon Roads (Glevan Consulting, 2012).

3.2.9 Fauna

Fauna diversity is closely aligned with landform-vegetation characteristics.

The area surrounding the L1/L2 permits is predominantly pasture land. Broad-acre cropping

and sheep and cattle grazing predominate. The Waitsia wells are generally within existing

cleared land (although there was clearing to establish the Waitsia-03 site).

A recent desktop survey identified 251 vertebrate fauna species as potentially occurring in

the survey area and this assemblage included 30 species of conservation significance

(Bamford, 2015). Of those species, only 7 conservation significant are considered likely to

use the broader area on a regular basis (see Table 5).

.



Table 5: Conservation Significant Fauna Desktop Search (incorporating Field Survey Results)

CS Species Status CS

Level3 Expected

presence Waitsia

INVERTEBRATES

Shield-backed Trapdoor Spider

Idiosoma nigrum V S1 CS1 Locally extinct?

millipede Antichiropus Eneabba 1 CS3 Resident

AMPHIBIANS

Slender Tree Frog Litoria adelaidensis CS3 Resident

REPTILES

White-spotted Ground Gecko

Diplodactylus alboguttatus

CS3 Resident

Western Spiny-tailed Skink Egernia stokesii badia En S1 CS1 Locally extinct?

Woma Aspidites ramsayi S4 P1 CS1 Resident or locally extinct?

Carpet Python Morelia spilota subsp. imbricata

S4 CS1 Resident

Tiger Snake Notechis scutatus CS3 Resident

Black-striped Snake Neelaps calonotos P3 CS2 Resident

BIRDS

Malleefowl Leipoa ocellata V S1 CS1 Vagrant (formerly resident)

Blue-billed Duck Oxyura australis P4 CS2 Irregular visitor

Fork-tailed Swift Apus pacificus M S3 CS1 Irregular visitor

Eastern Great Egret Ardea modesta M S3 CS1 Regular visitor

Cattle Egret Ardea ibis M S3 CS1 Vagrant

White-bellied Sea-Eagle Haliaeetus leucogaster M S3 CS1 Vagrant

Peregrine Falcon Falco peregrinus S4 CS1 Irregular visitor

Australian Bustard Ardeotis australis P4 CS2 Regular visitor

Hooded Plover Thinornis rubricollis V CS1 Vagrant

Common Sandpiper Actitis hypoleucos M S3 CS1 Irregular visitor

Curlew Sandpiper Calidris ferruginea M S1 S3

CS1 Irregular visitor

Red-necked Stint Calidris ruficollis M S3 CS1 Irregular visitor

Common Greenshank Tringa nebularia M S3 CS1 Irregular visitor

Western Corella Cacatua pastinator CS3 Irregular visitor

Carnaby's Black-Cockatoo Calyptorhynchus latirostris

E S1 CS1 Regular migrant

Western Ground Parrot Pezoporus flaviventris Cr S1 CS1 Possible resident

Rainbow Bee-eater Merops ornatus M S3 CS1 Regular migrant

Rufous Fieldwren Calamanthus campestris montanellus

P4 CS2 Resident

3 EPBC Act listed species: V = Vulnerable, E = Endangered, Cr = Critically Endangered, M = Migratory.

WC Act listed species: S1 - S4 = Schedule 1 - 4, DEC Priority Species: P1 - P5 = Priority 1 - 5.

(based on desktop review) and the likelihood of their presence in the project area, bold indicates species recorded in

the field survey.



CS Species Status CS

Level3 Expected

presence Waitsia

Shy Heathwren Calamanthus cautus P4 CS2 Resident

Crested Bellbird Oreoica gutturalis P4 CS2 Resident

Southern Scrub-robin Drymodes brunneopygia CS3 Resident

White-breasted Robin Eopsaltria georgiana CS3 Resident

MAMMALS

Brush Wallaby Macropus irma P4 CS2 Resident

Total Number of Species: 32 Recorded: 7

A Level 1 Vertebrate Fauna Assessment within the L4/L5 permit area identified two

mammal, 27 bird and four reptile species of conservation significance potentially occur

within the survey area. However, based on the habitats present, only 10 of these species

have a medium or high likelihood of occurrence within the survey area. The majority of the

remaining species with a low likelihood of occurrence within the survey area consist of

waterbirds and waders that have been recorded in previous surveys and databases based on

the general region (Eastern Great Egret, Cattle Egret, Glossy Ibis, Eastern Osprey,

White‐bellied Sea‐eagle, Hooded Plover, Terek Sandpiper, Common Sandpiper, Common

Greenshank, Wood Sandpiper, Red‐necked Stint, Sharp‐tailed Sandpiper, and Curlew

Sandpiper). These species may occur in the nearby Lake Logue and associated lakes.

(Ecologia, 2011)

There is no significant native fauna habitat which could be impacted by the proposed WIA.

Although protected fauna is known to reside within the broader region, the WIA are within

agricultural or highly disturbed land, only minimal clearing of native vegetation is proposed

and there are limited activities taking place outside of established sites or fenced

compounds therefore impacts to native fauna are anticipated to be negligible.

3.3 Heritage

3.3.1 Aboriginal Heritage

MEPAU will abide by the provisions of the WA Aboriginal Heritage Act 1972. Field and

desktop ethnographic surveys have been carried out to determine if operations are likely to

impact upon areas of cultural heritage significance.

A search of the Aboriginal Heritage Inquiry System – Department of Aboriginal Affairs

(Desktop search), across all permit areas identified the sites depicted within Figure 7. As a

result of the field and desktop surveys it has been established that except for the Irwin River

(Site 18907), the individual well sites where WIA could occur do not overlap any registered

sites or any areas of significance to the Aboriginal people who participated in the process.

There are 15 WIA wells in the Dongara region are <1 km from the Irwin River (Site 18907).



Figure 7: Registered Aboriginal Heritage Sites Perth Basin Permit Areas



3.3.2 European Heritage

A State Heritage Register – Heritage Council – www.stateheritage.wa.gov.au search was

completed (19/11/2018). A total of 16 State Registered Heritage Sites are found within the

Irwin Shire, the majority within the immediate Township of Dongara.

The Australian Protected Matters Search Tool referenced in Section 3.2.2 also provides

information regarding National Heritage Places, Commonwealth Heritage Places, and World

Heritage Properties. No Commonwealth Heritage Places or World Heritage Properties were

within 65 kilometres of the petroleum activity area. One National Heritage Place (Lesueur

National Park) is within proximity to EP455, however there is currently no wells within the

EP455 permit.

3.4 Socio-economic Environment

The Mid West region has a diversified economy that varies with the geography and climate.

Near the coast, annual rainfall of between 400 and 500 millimetres allows intensive

agriculture. Further inland, annual rainfall decreases to less than 250 millimetres and here

the economy is dominated by mining of iron ore, gold, nickel and other mineral resources.

The nearest townships to the Perth Basin Permit Areas are the town of Dongara - Port

Denison (L1/L2) and Eneabba (L4/L5).

http://www.stateheritage.wa.gov.au/



4.0 ENVIRONMENTAL RISK ASSESSMENT AND MANAGEMENT

4.1 Risk Management and Justification of ALARP

The approach undertaken towards risk management for each aspect involves a review of the

residual risk post treatment to determine if the environmental impacts and risks of the

activity will be managed to an acceptable level. Where additional implementation measures

are necessary to reach a level of acceptability they have been considered and adopted

The environmental risks and management identified for the WIA ranked medium or above

are presented in Table 6.

4.2 Risk Classification and Reporting Requirements

Under the definition in the Guideline for the Development of Petroleum and Geothermal

Environment Plans in Western Australia, November 2016 in Western Australia the risk

consequence of Moderate is equivalent to High on the MEPAU matrix.



Table 6: WIA Risk Assessment

Risk identification Risk treatment

(Existing Safeguards / Management Methods)

Residual risk assessment

Aspect Source of Risk Potential Environmental

Impact Consequence Likelihood Risk Ranking

1. Fauna • Stored pipework

• Vehicle interaction

• Fauna entrapment

• Death to conservation significant native fauna

• Pipework capped to prevent fauna entry

• Fencing in place around facilities

• Caging on waste skips

• Wellhead cellar grates in place

• Speed limits adhered to on site.

• All fauna related incidents are recorded and reported

• Vehicles and equipment are mobilised via established access tracks and roads

• Induction covers fauna interaction protocols

3 2 M5

2. Air emissions – venting/flaring

• Venting associated with WIA (cold venting)

• Emergency flaring associated WIA

• GHG + VOC emissions reduced air quality

• Visual disturbance

• Minimise venting/flaring to meet WIA operational requirements

• Venting/flaring is under a controlled release

• Flaring only under emergency situations

• Emissions reporting (NGER, Emissions & Discharges)

1 4 M5

3. Surface water • WIA spill/loss of containment within proximity to a surface water body

• Contamination of surface water (Irwin River or Lake Logue)

• Routine inspection of hydrocarbon and chemical storage areas (HSE-FR-06]

• Limited volume (Minor Storage) of hydrocarbons stored on site dependent on WIA requirements

• Secondary containment will be provided for hydrocarbons and hazardous chemical storage, with capacity >110% of largest container and >25% of total storage (whichever greater); portable bunded containers (spill pallets) will be utilised for minor storage.

• WIA fluids are stored within tanks with secondary containment (i.e. Lease Liner)

• Drip tray utilised during transfer operations

• Spill response equipment available on site as per OSCP [HSE-OP-030]

• Further risk assessment is undertaken where there is a credible risk of loss of containment reaching water body.

• Barrier/surface flow management in place based on risk assessment

3 2 M5

4. Weeds • Transfer and spread of weeds due to WIA

• Land degradation/decreased biodiversity

• WIA Biosecurity Procedure [HSE-E-051]

• Weed control measures (herbicide treatment, slashing) undertaken in accordance with the Weed & Vegetation Management Plan [HSE-E-116]

• Induction covers biosecurity requirements

• Vehicle/ Equipment Inspection Check Sheet [HSE-FR-018] conducted prior to mobilisation into Environmentally Sensitive Areas, equipment and vehicles are clean upon arrival to site

3 2 M5

5. Dieback • Transfer and spread of Dieback due to WIA equipment and vehicles

• Importation of gravel/sheeting material

• Land and vegetation degradation due to spread of Dieback (P.Cinnamomi)

• WIA Biosecurity Procedure [HSE-E-051]

• Vehicle/ Equipment Inspection Check Sheet [HSE-FR-018] conducted prior to mobilisation into Environmentally Sensitive Areas, equipment and vehicles are clean upon arrival to site

• Weed control measures (herbicide treatment, slashing) undertaken in accordance with the Weed & Vegetation Management Plan [HSE-E-116]

3 2 M5








• Induction covers biosecurity requirements for activities in dieback prone areas

• DBCA approved gravel source for WIA activities within dieback prone areas (i.e. Woodada Gas Field) or alternately assessed as low risk by a DBCA accredited dieback interpreter

6. Fire • Site not maintained clear of vegetation

• Ignition sources e.g. vehicle exhaust, smokers

• Hot work

• Flaring of gaseous waste

• Lightning strike

• Ignited gas release

• Vehicle incident

• Arson

• Offsite uncontrolled bushfire

• Release of noxious gases

• Bushfire – loss of vegetation, fauna and/or habitat

• Disruption of operations and site access

• Damage to equipment

• Damage to site offices

• Loss of crops

• Liaison with the Department of Fire & Emergency Services (DFES) prior to activities commencing (during restricted burning periods) and observation of any local fire restrictions

• Provision of a suitable fire break around the worksite

• Induction covers awareness / response to a fire and highlights the need for good housekeeping

• Only diesel fuel vehicles / equipment to be used at the worksite

• Permit to work system used to control hot work activities

• Smoking allowed at designated smoking location only.

• Equipment classified for hazardous areas

• Adequate fire equipment (including extinguisher) located on-site and personnel trained in its use

• Mobile fire-fighting unit available on site

• Emergency Response Plan [HSE-OP-089], including fire emergency response available at Dongara and Geraldton

4 2 M5

7. Surface loss of containment

• Spill or loss of containment resulting in a significant release of liquid hydrocarbons/ returned WIA fluids

• Localised soil or ground and surface water contamination

• Induction covers OSCP requirements

• Keeping chemicals offsite until necessary.

• Equipment and chemicals oriented within bunded areas to ensure no impact on water bodies

• Routine inspection of hydrocarbon and chemical storage areas (HSE-FR-06]

• SDSs located in site office and chemical storage shed.

• Containers checked to ensure that they are in sound order.

• Flammable and corrosive materials are segregated within the wellsite chemical storage area.

• Open top tank for temporary storage of returned WIA fluids, additional capacity available for urgent storage

• Secondary containment will be provided for hydrocarbons and hazardous chemical storage, with capacity >110% of largest container and >25% of total storage (whichever greater); portable bunded containers (spill pallets) will be utilised for minor storage.

• OSCP [HSE-OP-030] and ERP [HSE-OP-089] in place and personnel trained in their implementation.

3 2 M5

8. Gas/liquid release

• Uncontrolled gas/liquid release from well during WIA

• Increased GHG emissions

• Contaminated soil

• Contaminated groundwater

• Operating procedures, PTW system and JHAs for well operations

• Pressure testing

• Hazardous area maintained around wellhead (reducing the potential for ignition)

• Portable gas detectors used when working in vicinity of the well

3 2 M5








• Routine maintenance and inspections

• Induction covers OSCP requirements

• OSCP [HSE-OP-030] and ERP [HSE-OP-089] in place

• Blow Out Preventer or Wireline pressure control equipment as required and regularly tested.



5.0 IMPLEMENTATION STRATEGY

The objective of the implementation strategy is to describe how all aspects of the activity

will be directed, reviewed and managed to ensure that all potential impacts and risks are

continuously reduced to ALARP.

The specific objectives with reference to the relevant section of the EP are listed below:

1. Ensure that the agreed environmental performance objectives and standards are met

(Section 5.0)

2. Identify specific systems, practices and procedures to be used to ensure that

environmental risks and effects are reduced to ALARP (Section 7.0)

3. Establish a commitment to the protection of the environment (Section 7.1)

4. Establish a clear chain of command that sets out the roles and responsibilities of

personnel in relation to the implementation, management and review of the EP

(Section 7.3)

5. Ensure that each employee or contractor working on or in connection with Perth

Basin WIA has the appropriate skills and training (Section 7.4)

6. Monitor, audit and review environmental performance and the Implementation

Strategy (Section 7.5)

7. Maintain quantitative records (Section 5.2)

8. Develop and implement emergency and spill preparedness planning and response

capability (Section 7.1 and 8.0)

9. Report on environmental performance (Section 9.0)

10. Provide for appropriate consultation with relevant government authorities and other

interested persons or organisations (Section 10.0)



5.1 Systems, Practices and Procedures

Details of MEPAU systems, practices and procedures relating to the management of all potential impacts and risks of the activity are detailed in

Table 7. The objective of these are to continually reduce the potential impacts and risks of the activity to ALARP.

Table 7: Systems, Practices and Procedures

Item Objective to achieve ALARP Documentation Location

Code of Practice for MEPAU sites

To outline the main HSE criteria to be observed by MEPAU and its contractors

MEPAU Limited Health Safety & Environment Policy [MEP HSE-POL-001]

MEPAU Authority to Stop An Unsafe practice [MEP-HSE-POL-002]

• MEPAU intranet site

• Displayed on site in the WIA office

HSE Management System Standards

To provide a framework for HSE systems and outline the elements

MEPAU Health, Safety and Environment Management System [MEP-HSE-MAN-002]


Environment Plan or Environmental Bridging Document

To document environmental management for WIA

Perth Basin Well Intervention Activities Environment Plan [HSE-E-075]


• Lead WIA Contractor (via electronic distribution)

Oil Spill Preparedness and Response

To provide guidance on the management of a spill

Oil Spill Contingency Plan [HSE-OP-030] • MEPAU intranet site


Completion Criteria To set the criteria required to be achieved for rehabilitation with sign off by the landowner/stakeholder

Rehabilitation Completion Criteria table and relevant Land Access Agreement (LAA)

• MEPAU intranet site (internal)

• Landowner (via electronic distribution)

Emergency Response Plan To provide guidance on the management of an emergency related to WIA

Emergency Response Plan for MEPAU Onshore Well Intervention Operations [HSE-OP-094]



Hazard and Incident Reporting

To outline the processes and requirements for hazard and incident reporting

Lead WIA Contractor and MEPAU hazard and incident reporting forms [HSE-FR-08]


• MyOSH System for hazard



Item Objective to achieve ALARP Documentation Location

and incident tracking

Hygiene Management To document the completion of hygiene inspections for personnel entrance into environmentally sensitive areas (Woodada Gas Field, Drakea-01, Waitsia-03)

WIA Biosecurity Procedure [HSE-E-051] and Hygiene Inspection Form [HSE-FR-018]


• MyOSH System for hazard and incident tracking

Environmental Compliance Scheduling

Schedule internal compliance audits to verify WIA are being undertaken in compliance to legislation commitments

Perth Basin Audit Schedule [HSE-OP-098] • MEPAU intranet site

Clearing Vegetation Recording

To ensure clearing of native vegetation is undertaken in compliance with the relevant legislative instrument

Clearing Vegetation Record Form [PB-HSE-FRM-001]



Weed and Vegetation Management

Provide management strategies to minimise the introduction of weed species into operational areas to acceptable levels

Perth Basin Weed and Vegetation Management Plan [HSE-E-116]



Waste Management To provide guidance on the management of waste in relation to MEPAU Perth Basin activities.

Perth Basin Waste Management Plan [PB-HSE-PLN-001]


Stakeholder Engagement Assists Company to establish and/or maintain its standing with key stakeholders that Company is a valued and trusted partner of the Mid West community as well as the broader WA community.

Stakeholder Engagement Plan – Perth Basin [CP-PM-039]


Landowner Communications Ensure landowners are aware of the proposed activities on their property before they occur.

Landowner and General Community Communication Procedure [HSE-PR-059]




5.2 Record Keeping

The following records will be kept for a minimum of five years and made available to DMIRS

on request:

• Induction and training records;

• Emissions & Discharges records;

• Waste disposal records;

• Details of incidents and associated investigations undertaken;

• Audit and inspection records (including non-conformances and corrective action

tracking);

• Current and archived controlled documents; and

• Regulatory submissions.



6.0 CONSULTATION

Consultation has been undertaken with stakeholders over the life of WIA in the Perth Basin

with:

• DMIRS;

• DBCA;

• DFES;

• DWER;

• Shire of Irwin;

• Local landowners;

• Local stakeholders;

• Dongara and Port Denison Residents; and

• Traditional Owners.

Ongoing consultation regarding WIA are documented within activity specific Environment

Plan Bridging Documents.



7.0 REFERENCES

Beard, J.S. (1976). The Vegetation of the Dongara Area Western Australia. Map and

explanatory memoir 1:250 000 series. Vegmap Publications, Perth.

Department of Water (2017), Northern Perth Basin: Geology, hydrogeology and groundwater

resources, Hydrogeological bulletin series, report no. HB1, Department of Water,

Government of Western Australia, Perth.

Ecologia Environment (2011) AWE Limited Woodada Deep-01 Level 1 Vertebrate Fauna

Assessment, February 2011

Glevan Consulting (2012). Access tracks to wells and infrastructure at Woodada gas fields –

Phytophthora cinnamomi occurrence and assessment. Unpublished report (Document No.:

V1) for AWE Ltd, March 2012.

Rutherford, J., Roy, V. and Johnson, S.L., (2005), The Hydrogeology of Groundwater

Dependent Ecosystems in the Northern Perth Basin, Department of Environment,

Hydrogeological Record Series, HG11.

Smith M.G. & Jones A. (2018) Threatened and Priority Flora List, 16 January 2018.

Department of Biodiversity, Conservation and Attractions: Kensington, WA.

Woodman Consulting, (2012) Woodada Gas Field Dieback, Weed and Rehabilitation

Assessment, Spring 2012.

Woodman Consulting, (2017) Waitsia-03 Weed Assessment 2017.

Bamford M.J. & A.R Consulting Ecologists (2015), Waitsia Wells, Dongara Fauna Assessment,

2015.


HSE-E-075-SUM Rev 4

APPENDICES


HSE-E-075-SUM Rev 4

Appendix 1

WIA Fluids Chemical Disclosure Tables


HSE-E-075-SUM Rev 4

Table 8: Products, Additives, Chemicals and Other Substances (Fluids)

Table 8a: System Details

Operator AWE Perth Pty Ltd

Project/Well Potentially any well listed in Section 2.2

System WIA Fluids

Total Volume of System (per well) 3000 bbl (477,000 L)

Table 8b: Product List

Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data % Product in System Fluid SDS Attached

Water Town or Bore water Base fluid N/A – Natural product. 77.631% Yes

Idcide 20 Newpark Drilling Fluids Biocide Acute Toxicity:

75% Tetrakis (hydroxymethyl) Phosphonium Sulphate (55566-30-8):

LC50 (Rainbow Trout) = 119 mg/L/96 hr

LC50(Bluegill Sunfish) = 93 mg/L/ 96 hr

EC50 (Daphnia Magna) = 19 mg/L/48 hr

LC50 (Brown Shrimp) = 340 mg/L/96 hr

LC50 (Mysid Shrimp ) = 9.5 mg/L/96 hr

LC50 (Sheepshead Minnow) = 94 mg/L/96 hr

LC50 (Juvenile Plaice) = 86 mg/L/96 hr

Waste Water management EC50 (Activated Sludge) = 24mg/L/3 hr.

Water: 25%

Natural product.

Biodegradation/bioaccumulation:

No specific studies undertaken to date.

0.051% Yes

Sodium sulphite Newpark Drilling Fluids Oxygen

Scavenger

Acute Toxicity:

LD50 (ingestion) 820 mg/kg (mouse)

LD50 (intraperitoneal) 950 mg/kg (mouse)

LD50 (intravenous) 175 mg/kg (mouse)

LDLo (ingestion) 2825 mg/kg (rabbit)

LDLo (intravenous) 400 mg/kg (cat)

LDLo (subcutaneous) 600 mg/kg (rabbit)


This product is completely biodegradable.

0.021% Yes


HSE-E-075-SUM Rev 4


Sodium Sulphite is an oxygen scavenger when introduced to water.

Bioaccumulation of this product has not been determined.

Ancor 1 Newpark Drilling Fluids Corrosion

Inhibitor

Acute Toxicity:

May be harmful if swallowed, in contact with skin, and/or if inhaled.

Toxicity Data available for the ingredient:

TRIETHANOLAMINE (102-71-6):

LD50 (Ingestion): 2200 mg/kg (rabbit)

LD50 (Intraperitoneal): 1450 mg/kg (mouse)

LD50 (Skin): > 20 mL/kg (rabbit)

TDLo (Ingestion): 16 g/kg/64 weeks (mouse – cancer)


In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life

in the order of days to weeks).

0.705% Yes

Xanthan Gum (P) Newpark Drilling Fluids Viscosifier Acute/Chronic toxicity Xanthan Gum as an ingredient: 90%:

LD50 (Oral): >1000 mg/kg (mouse)88.885

LD50 (Intraperitoneal): >50 mg/kg (mouse)

LD50 (Intravenous): 100-250 mg/kg (mouse)

LD50 (Oral): >45,000 mg/kg (rat)

LD50 (Oral): >20,000 mg/kg (dog)

Biodegradation/Bioaccumulation:

This product is not anticipated to cause adverse effects to animal or plant life if released to the

environment in small quantities. Not expected to bioaccumulate.

Water: 10%

Natural product.

0.049% Yes

SAPP Newpark Drilling Fluids Water Wetting

Agent

Toxicity (SAPP)

Oral Toxicity LD50: 5,100 mg/kg (Rat)

Fish Toxicity LC50/48h: >1,500 mg/l (Golden orfe)

Chronic Toxicity (SAPP):

No data available to indicate product or components present at greater than 1% are chronic

health hazards. Not ranked as a Chronic Health Hazard under the Sara 311/312 Tier II Hazard

Ratings.

Biodegradation/bioaccumulation (SAPP):

This product is readily biodegradable. It is an edible product.

0.001% Yes


HSE-E-075-SUM Rev 4


HCL 15% Telford Acid to remove

scale

Acute/Chronic toxicity HCL as an ingredient: 15%

LD50 (Oral): >900mg/Kg (rat)

LC50 (Inhalation): 300 ppm/hr (rat)

Biodegradation/Bioaccumulation:

When released into the soil, this material is not expected to biodegrade. When released into

the soil, this material may leach into groundwater.

Water: 58%

Natural product.

1.302% Yes

Fracseal

Fine/Cellplug/NDFT

377

(LCM – cellulose

fibre)

Newpark Drilling Fluids Prevent lost

circulation

Acute Toxicity:

Cellulose (9004-34-6)

LC50 (inhalation) > 5800 mg/m³/4 hours (rat)

LD50 (ingestion) > 5000 mg/kg (rat)

LD50 (intraperitoneal) > 31600 mg/kg (rat)

LD50 (skin) > 2000 mg/kg (rabbit)


Main ingredient is Cellulose, an organic material which is readily biodegradable.

0.385% Yes

Quickseal F/M/C Newpark Drilling Fluids Lost circulation

material

This product consists of 100% organic fibres (plant material) and is therefore not anticipated to

cause adverse effects to animal or plant life if released to the environment in small quantities

Acute Toxicity:

No LD50 data available for this product.


This product is not expected to bioaccumulate.

0.256% Yes

Rheopac LV Newpark Drilling Fluids Viscosifier Acute Toxicity:

Aquatic toxicity: LC50 (Fresh Water Trout) > 21,000 ppm/96hrs.

LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.


This product is not anticipated to cause adverse effects on animal or plant life if released to the


0.087%

Yes

KCL Newpark Drilling Fluids Weighting

Agent

Acute Toxicity:

LD50 (Ingestion): 1500 mg/kg (mouse)


Chronic Toxicity:

Not listed as a carcinogen. No data available to indicate product or components present at

10.907% Yes


HSE-E-075-SUM Rev 4


greater than 1% are chronic health hazards.


Low bioaccumulation in water/soil. High mobility.

Salt/NaCl Newpark Drilling Fluids Weighting

Agent

Acute Toxicity:

Oral Toxicity LD50: 3000 mg/kg (Rat)

Oral Toxicity LD50: 4,000 mg/kg (Mouse)

Dermal Toxicity LD50: >10,000 mg/kg (Rabbit)

Chronic Toxicity:

Not listed as a carcinogen. No data available to indicate product or components present at

greater than 1% are chronic health hazards.


Low bioaccumulation in water/soil. High mobility.

2.150% Yes

Calcium Chloride Newpark Drilling Fluids Weighting

Agent

Acute Toxicity:

CALCIUM CHLORIDE ANHYDROUS as an ingredient (10043-52-4):

LD50 (Ingestion): 1000 mg/kg (rat)


LD50 (Intravenous): 42 mg/kg (mouse)

LD50 (Subcutaneous): 823 mg/kg (mouse)

LDLo (Ingestion): 1384 mg/kg (rabbit)

LDLo (Intravenous): 150 mg/kg (guinea pig)

LDLo (Subcutaneous): 249 mg/kg (cat)

TDLo (Intravenous): 20 mg/kg/1 hour (woman)

SODIUM CHLORIDE (7647-14-5):

LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)




LD50 (Skin): > 10000 mg/kg (rabbit)




LDLo (Subcutaneous): 2160 mg/kg (guinea pig)

6.180% Yes


HSE-E-075-SUM Rev 4


TDLo (Ingestion): 12357 mg/kg (human)


Biodegradability does not pertain to inorganic substances. This product does not

bioaccumulate.

Contingency Volumes

TEA (Contingent

Chemical)

Newpark Drilling Fluids Corrosion

Inhibitor

Acute Toxicity:



TRIETHANOLAMINE (102-71-6):

LD50 (Ingestion): 2200 mg/kg (rabbit)


LD50 (Skin): > 20 mL/kg (rabbit)

TDLo (Ingestion): 16 g/kg/64 weeks (mouse – cancer)


In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life

in the order of days to weeks). The substance is expected to be readily biodegradable according

to the AS 4351 Part 2 test method.

0.705% Yes

Condensate (Xyris) AWE Perth Pty Ltd Production by-

product

Acute Toxicity:



NATURAL GAS CONDENSATES (PETROLEUM) (64741-47-5):

LC50 (inhalation): 600mg/m3 (rat)

TOLUENE (108-88-3):

LD50 (oral): 5,580 mg/kg (rat)

LD50 (dermal): 5,000 mg/kg (rabbit)

LC50 (inhalation): 25.7-30 mg/L/4hrs (rat)

1,2,4-TRIMETHLYBENZENE (95-63-6):


LD50 (dermal): None

LC50 (inhalation): 18 g/m3/4hrs (rat)

BENZENE (71-43-2):

LD50 (oral): 930 mg/kg (rat)

LD50 (dermal): 48 mg/kg (mouse)

3.333% Yes


HSE-E-075-SUM Rev 4


LC50 (inhalation): 9,980 ppm (mouse)

ETHYLBENZENE (100-41-4):


LD50 (dermal): 17,800 mg/kg (rabbit)

LC50 (inhalation): 50 g/m3/2 hours (mouse)

N-HEXANE (110-54-3):

LD50 (oral): 25 g/kg (rat)

LD50 (dermal): 3.000 mg/kg (rabbit)

LC50 (inhalation): 48,000 ppm/4 hours (rat)

MERCURY (7439-97-6):

LD50 (oral): 10-40 mg/kg (expected)

LD50 (dermal): None

LC50 (inhalation): 0.014 mg/L/4 hours (rat)

Toxicity

Harmful to aquatic life with long lasting effects.


No information provided.

RX-7492 NewPark Drilling

Fluids/Roemex

Cleaning agent

(substitute for

PAO24273)

Acute toxicity:

Acute Toxicity – Fish

LC50 96 hours 0.71 mg/l Pimephales promelas (Fat-head Minnow)

Acute Toxicity – Aquatic Invertebrates

EC50 0.4 mg/l Daphnia magna

Acute Toxicity – Aquatic Plants

IC50 4 mg/l Selenastrum capricornutum


Possibly hazardous short term degradation products are not likely. However, long term

degradation products may arise.

0.267% Yes

Bromine

Trifluoride

Chammas Cutters Oxidizer for

cutting steel

tubing

Acute/Chronic toxicity of Bromine fluoride (BrF3) as an ingredient: 100%

Bromine Trifluoride is irritating and corrosive to all living tissues. Product is supplied inside a

sealed cylinder for transportation

Purpose and handled by trained personnel; seal discs can only be sheared at carefully

controlled temperature and pressure.

0.007% Yes


HSE-E-075-SUM Rev 4


LC50 (Inhalation): >230 ppm/hr (monkey)

LC50 (Inhalation): >299 ppm/hr (rat)


Products of degradation: halogenated compounds.

Guar Gum Newpark Drilling Fluids Viscosifier

(Substitute for

Xanthem Gum)

Acute Toxicity:

GUAR GUM (9000-30-0)

This product is expected to be of low toxicity. Under normal conditions of use, adverse health

effects are not anticipated.

Oral Toxicity (LD50) 6000 mg/kg (Hamster)

TDLo (oral) 228,000 mg/kg/13 weeks continuous (rat)




0.049% Yes

Rheoplug /

Rheoplug Ultra

Newpark Drilling Fluids LCM Acute Toxicity:

This product is expected to be of low toxicity. Under normal conditions of use, adverse health

effects are not anticipated.

Acute Oral Toxicity: LD50 (rat) is > 40 g/kg.




0.052% Yes

Calcium Carbonate Newpark Drilling Fluids LCM Acute Toxicity:

Oral Toxicity LD50: 7,340 mg/kg (Rat) Fish Toxicity TLM96: 100-500 ppm (Oncorhynchus mykiss)

Crustaceans Toxicity TLM96: 478,520 ppm (Mysidopsis bahia) SPP @ 8 ppb.

Chronic Toxicity: No data available to indicate product or components present at greater than

1% are chronic health hazards.


Sparingly soluble in water as hydroxide to form an alkaline solution. Low mobility in most

ground conditions. Not expected to bioaccumulate.

0.098% Yes

Fluorodye UC Newpark Drilling Fluids/Nalco Tracer Acute Toxicity:

Ethylene glycol has moderate toxicity to aquatic life on both a short term and long-term basis.

ACETIC ACID (64-19-7)

LC50 (Inhalation): 5620 ppm/1 hour

LCLo (Inhalation): 16000 ppm/4 hours (rat)


0.0524% Yes


HSE-E-075-SUM Rev 4



LD50 (Skin): 1.06 g/kg (rabbit)


LDLo (Subcutaneous): 600 mg/kg (rabbit)

TCLo (Inhalation): 816 ppm/3 minutes (human)

TDLo (Ingestion): 1470 ug/kg (human)

ETHYLENE GLYCOL (1,2-ETHANEDIOL) (107-21-1)

LC50 (Inhalation): 10876 mg/kg (rat)

LD50 (Ingestion): 1670 mg/kg (cat);> 2000 mg/kg (rat)

LD50 (Skin): 9530 mg/kg (rabbit)

LDLo (Ingestion): 398 mg/kg (human)

TCLo (Inhalation): 10,000 mg/m³ (human - cough)

TDLo (Ingestion): 5,500 mg/kg (child - anaesthesia)

RHODAMINE (81-88-9)

LD50 (Ingestion): 887 mg/kg (mouse)

LD50 (Intraperitoneal): 112 mg/kg (rat)

LD50 (Intravenous): 89 mg/kg (rat)


LDLo (Ingestion): 500 mg/kg (rat)


In water and soil ethylene glycol is expected to degrade in several days to a week. The major

degradation product is hydroxyacetaldehyde. Ethylene glycol is not expected to bioaccumulate.


HSE-E-075-SUM Rev 4

Table 8c: Chemical List

Chemicals Name CAS number Mass fraction (%)

Water 7732-18-5 78.941

Tetrakis (hydroxymethyl) Phosphonium Sulphate 55566-30-8 0.724

Sodium sulphite 7757-83-7 0.021

Triethanolamine 102-71-6 0.705

Xanthan Gum 11138-66-2 0.044

Disodium Pyrophosphate 7758-16-9 0.001

Hydrochloric Acid 7647-01-0 0.195

Cellulose 9004-34-6 0.116

Sodium Carboxymethyl Cellulose 9004-32-4 0.077

Sodium Chloride 7647-14-5 2.337

Sodium Glycolate 2836-32-0 0.001

Potassium Chloride 7447-40-7 10.907

Calcium Chloride Anhydrous 10043-52-4 5.933

Triethanolamine 102-71-6 0.426

Diethanolamine 111-42-2 0.213

Ethanolamine 141-43-5 0.071

Natural Gas Condensate 64741-47-5 0.820

Toluene 108-88-3 0.100

1,2,4-Trimethlybenzene 95-63-6 0.030

Benzene 71-43-2 0.030

Ethylbenzene 100-41-4 0.010

N-hexane 110-54-3 0.010

Mercury 7439-97-6 <0.001

D-Limonene 5989-27-5 0.160

Bromine Trifluoride 7787-71-5 0.007

Water 7732-18-5 0.107

Guar gum 9000-30-0 0.044

Poly(acrylic acid sodium salt) 9003-04-7 0.052

Quartz (Crystalline Silica) 14808-60-7 0.0098

Calcium Carbonate 471-34-1 0.09702

Orange terpenes 8028-48-6 0.1869

Terpene Hydrocarbons 68956-56-9 0.0801

Ethylene Glycol 107-21-1 0.01572

Acetic Acid 64-19-7 0.01572

C.I. Basic Violet 10 (Rhodamine B or D&C Red No 19) 81-88-9 0.01572

Total: 100.00%

(excluding contingency volumes)


HSE-E-075-SUM Rev 4

Appendix 2

Safety Data Sheets – Fluids

THRU TUBING SYSTEMS SAFETY DATA SHEET

Document # Version Prepared by: Issue Date: November 14, 2017 SDS – ACE Mix 1.1 Brad Cook Supersedes: All previous

Cement (Portland/Oilwell) Page 1 of 12

SECTION 1: IDENTIFICATION Product Identifier: Portland Cement (cement) Product Name(s): ACE Mix Cement, ACE Mix-HTE, ACE Mix-LTX, ACE Mix-SSW, ACE Mix-EX Synonyms: Cement, Portland Cement, Hydraulic Cement, Oil Well Cement, OWH,OW Class H HSR Recommended Use: This product is intended to be used as an Oilwell Cement Manufacturer: Thru Tubing Systems, Inc

1806B Highway 90 East New Iberia, LA 70560 +1 337-606-0031

Responsible Party and Emergency Contact:

Thru Tubing Systems, Inc. +1 337-606-0031

SECTION 2: HAZARD(S) IDENTIFICATION

Hazard Classification: Skin Corrosive 1C H314 Eye Damage 1 H318 Skin Sensitivity 1 H317 Carcinogen 1A H350 STOT SE 3 H335 Label Elements: Pictograms

Signal Word: Danger Hazard Statements: H314 – Causes severe skin burns and eye damage H315 – Causes skin irritation H317 – May cause an allergic skin reaction H318 – Causes serious eye damage H335 – May cause respiratory irritation H350 – May cause cancer (inhalation) H372 – Causes damage to organs through prolonged or repeated exposure Precautionary Statements: P201 – Obtain special instructions before use P202 – Do not handle until all safety precautions have been read and understood P260 – Do not breathe dust P264 – Wash hands, forearms, and exposed areas thoroughly after handling P271 – Use only outdoors or in a well-ventilated area P272 – Contaminated work clothing should not be allowed out of the workplace P280 – Wear protective gloves, protective clothing, face protection, eye protection



Cement (Portland/Oilwell) Page 2 of 12 P301+P330+P331 – IF SWALLOWED: rinse mouth. Do NOT induce vomiting P303+P361+P353+P352 – IF ON SKIN (or hair): Remove/Take off Immediately all

Contaminated clothing. Rinse skin with water/shower. Wash with plenty of soap and water

P304+P340 – IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing

P305+P351+P338 – If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing

P310 – Immediately call a POISON CENTER or doctor/physician P321 – Specific treatment (see Section 4) P333+P313 – If skin irritation or rash occurs: Get medical advice/attention P362+364 – Take off contaminated clothing and wash it before reuse P403+P233 – Store in a well-ventilated place. Keep container tightly closed P405 – Store locked up P501 – Dispose of contents/container according to local, regional, state, national,

territorial, provincial, and international regulations Other Hazards: Other Hazards not Contributing to the Classification:

Inhalation can cause serious, potentially irreversible lung/respiratory tract tissue damage due to chemical (caustic) burns, including third degree burns. Individuals with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary disease) or sensitivity to hexavealent chromium can be aggravated by exposure

Unknown Acute Toxicity Not Available

SECTION 3: COMPOSITION/INFORMATION ON INGREDIENTS Mixture

Name Product Identifier %(w/w) Classification (GHS-US)

Cement, Portland, chemicals CAS# 65997-15-1 58-70

Skin Irritant 2, H315 Eye Damage 1, H318 Skin Sensitivity 1, H317 STOT SE 3, H335

Crystalline Silica (quartz) CAS# 14808-60-7 28-35 Carc. 1A, H350 STOT SE 3, H335 STOT RE 1, H372

Gypsum, Calcium Sulfate CAS# 13397-24-5 <5 Not Classified Magnesium Oxide CAS# 1309-48-4 <5 Not Classified

Calcium Oxide CAS# 1305-78-8 <3 Skin Corr. 1C,H314 Eye Dam. 1, H318 STOT SE 3, H335

The specific percentage concentration of the mixture is withheld because it is a proprietary trade secret.

SECTION 4: FIRST AID MEASURES



Cement (Portland/Oilwell) Page 3 of 12 Description of First Aid Measures General: Never give anything by mouth to an unconscious person. If you feel unwell, seek medical

advice (show label if possible). Inhalation: When symptoms occur: go into open air and ventilate suspected area. Keep at rest and in a

position comfortable for breathing. If you feel unwell, see medical advice. Skin Contact: Remove contaminated clothing. Immediately flush skin with plenty of water for at least 60

minutes. Immediately call POISON CENTER or doctor/physician. Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy

to do. Continue rinsing for at least 60 minutes. Immediately call POISON CENTER or doctor/physician.

Ingestion: Rinse mouth. Do not induce vomiting. Immediately call POISON CENTER or doctor/physician.

Most Important Symptoms and Effects Both Acute and Delayed General: Corrosive to eyes, respiratory system and skin. Exposure may produce an allergic reaction. Inhalation: The three types of silicosis include: 1) Simple chronic silicosis – which results from long-

term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis – results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to repairable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis, and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory tract.

Skin Contact: Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure to sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious potentially irreversible damage to skin, eye, respiratory, and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be hazardous even if there is no pain or discomfort. Cement is capable of causing dermatitis by irrigation and allergy. Skin affected by dermatitis may include symptoms such as; redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical properties of cement including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in cement. The reaction can range from a mild rash to severe skin ulcers. Persons already sensitized may react to the




first contact with cement. Others may develop allergic dermatitis after years of repeated contact with cement.

Eye Contact: Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of dry powder or with wet cement can cause moderate eye irritation, chemical burns, and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye.

Ingestion: May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract. Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung

disease. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, get medical advice and attention.

SECTION 5: FIRE-FIGHTING MEASURES Extinguishing Media Suitable Extinguishing Media:

Use extinguishing Media appropriate for surrounding fire.

Unsuitable Extinguishing Media:

Do not use a heavy water stream. Use of heavy stream of water may spread fire.

Special Hazards Arising From the Substance or Mixture Fire Hazard Not flammable. Explosion Hazard: Product is not explosive. Reactivity: Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum

metal. Cement dissolves in hydrofluoric acid, producing corrosive tetraflouride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron triflouride, chlorine triflouride, manganese triflouride, and oxygen diflouride.

Advice for Firefighters Precautionary Measures Fire:

Exercise caution when fighting any chemical fire.

Firefighting Instructions:

Do not get water inside containers. Do not apply water stream directly at source of leak.

Protection During Firefighting:

Do not enter fire area without proper protective equipment, including respiratory protection.

Hazardous Combustion Products:

None.

Reference to Other Sections Refer to Section 9 for flammability properties.




SECTION 6: ACCIDENTAL RELEASE MEASURES Personal Precautions, Protective Equipment and Emergency Procedures General Measures: Do not breathe dust. Do not get in eyes, on skin, or on clothing. For Non-Emergency Personnel Protective Equipment:

Use appropriate personal protection equipment (PPE)

Emergency Procedures:

Evacuate unnecessary personnel.

For Emergency Personnel Protective Equipment:

Equip cleanup crew with proper protection.

Emergency Procedures:

Ventilate area.

Environmental Precautions Prevent entry to sewers and public waters Methods and Material for Containment and Cleaning Up For Containment: Place spilled material into a container. Avoid actions that cause the cement to become

airborne. Avoid inhalation of e and contact with skin. Wear appropriate protective equipment as described in Section 8. Scrape wet cement and place in container. Allow material to dry or solidify before disposal. Do not wash cement down sewage and drainage systems or into bodies of water (e.g. streams).

Methods for Cleaning Up:

Avoid actions that cause dust to become airborne during clean-up such as sweeping or using compressed air. Use HEPA vacuum or thoroughly wet with water to clean up dust. Use PPE described in Section 8.

Reference to Other Sections See Section 8, Exposure Controls and Personal Protection. Concerning disposal elimination after cleaning, see Section 13.

SECTION 7: HANDLING AND STORAGE Precautions for Safe Handling Additional Hazards When Processed:

Keep totes and bagged cement dry until used. Stack totes and/or bagged material in a secure manner to prevent falling. Packaged cement is heavy and poses risks such as sprains to the back, arms, shoulders, and legs during lifting and mixing. Handle with care and use appropriate control measures. Cutting, crushing, or grinding hardened cement will release respirable crystalline silica. Use all appropriate measures of dust control or suppression, and Personal Protective Equipment (PPE) described in Section 8 below.

Hygiene Measures: Handle in accordance with good industrial hygiene and safety procedures. Wash hands and other exposed areas with mild soap and water before eating, drinking, or smoking, and again when leaving work. Wash contaminated clothing before reuse.

Conditions for Safe Storage, Including Any Incompatibilities Storage Conditions: Store in a dry, cool, and well-ventilated place. Keep containers closed when not in use. Incompatible Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum



Cement (Portland/Oilwell) Page 6 of 12 Materials: metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetraflouride gas.

Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron, triflouride, chlorine triflouride, manganese triflouride, and oxygen diflouride.

Storage Temperature:

Unlimited.

Specific End Use(s) This product is intended to be used as an oilwell cement.

SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION EXPOSURE GUIDELINES

Component OSHA PEL ACGIH TLV NIOSH REL Cement, Portland (TWA) 5 mg/m3 (TWA) 1 mg/m3 (TWA) 5 mg/m3 Crystalline Silica, Quartz 10 mg/m3 %SiO2 + 2 TWA (TWA) 0.025 mg/m3 (TWA) 0.05 mg/m3 Gypsum, Calcium Sulfate (TWA) 5 mg/m3 (TWA) 10 mg/m3 (TWA) 5 mg/m3 Calcium Oxide (TWA) 5 mg/m3 (TWA) 2 mg/m3 (TWA) 2 mg/m3 Magnesium Oxide (TWA) 15 mg/m3 (TWA) 10 mg/m3 EXPOSURE CONTROLS Appropriate Engineering Controls. Use adequate general or local exhaust ventilation to maintain concentrations in the workplace below the applicable exposure limits listed above. Emergency eye wash stations should be available in the immediate vicinity or any potential exposure. Personal Protective Equipment. Gloves. Protective goggles. Dust Mask. Materials for Protective Clothing. Chemically resistant materials and fabrics. Hand Protection. Wear gloves impervious to water to prevent skin contact. Eye Protection. Wear ANSI approved glasses or safety goggles when handling dust. Wearing contact lenses is not recommended. Skin and Body Protection. Wear gloves, boot covers, and protective clothing impervious to water to prevent skin contact. Respiratory Protection. Wear a NIOSH approved respirator that is properly fitted and is in good condition when exposed to dust over exposure limits. Other Information. Do not eat, drink, or smoke when using.

SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES

Information on Basic Physical and Chemical Properties Appearance: Gray, White, or Off-white powder Odor: Odorless Odor Threshold: Not Available pH: 12-13 in water Melting Point/Freezing Point: Not Available Initial Boiling Point/Range: >1000o C (>1832o F) Flash Point: Not Available Evaporation Rate: Not Available



Cement (Portland/Oilwell) Page 7 of 12 Flammability (solid/gas): Not Available Upper/Lower Flammability Limits: Not Available Vapor Pressure: Not Available Vapor Density: Not Available Relative Density: 2.97 Solubility: Water: 0.1 -1% (slightly soluble) Partition Coefficient: n-octonal/water: Not Available Auto-Ignition Temperature: Not Determined Decomposition Temperature: Not Determined Viscosity: Not Available

SECTION 10: STABILITY AND REACTIVITY

Reactivity:

Wet cement is alkaline and is incompatible with acids, ammonium salts, and aluminum metal. Cement dissolves in hydrofluoric acid, producing corrosive silicon tetraflouride gas. Cement reacts with water to form silicates and calcium hydroxide. Silicates react with powerful oxidizers such as fluorine, boron trifouride, chlorine triflouride, manganese triflouride, and oxygen diflouride.

Chemical Stability: Stable under recommended handling and storage conditions (see Section 7)

Possibility of Hazardous Reactions: Contact with powerful oxidizing agents, such as fluorine, chlorine triflouride and oxygen diflouride, may cause fires.

Hazardous Decomposition: Silica will dissolve in hydrofluoric acid and produce a corrosive gas, silicon tetraflouride. Adding water results in hydration and produces (caustic) calcium hydroxide.

Hazardous Polymerization: Will not occur

Conditions to Avoid: Extremely high or low temperatures. Incompatible materials. Avoid generation of dust in handling and use.

Incompatible Materials: Acids. Ammonium Salts. Aluminum. Hydrofluoric acid. Water. Oxidizers such as fluorine, chlorine triflouride, oxygen diflouride.

SECTION 11: TOXICOLOGICAL INFORMATION

Acute Effects of Exposure:

Inhalation: Inhalation of dust may cause respiratory tract irritation. Symptoms of exposure may include cough, sore throat, nasal congestion, sneezing, wheezing, and shortness of breath.

Ingestion: Ingestion is an unlikely route of exposure. If dust is swallowed, it may irritate the mouth and throat.

Skin contact: May cause an allergic skin reaction. Eye Contact: Causes serious eye damage.

Chronic Effects of Exposure: Prolonged inhalation of repairable crystalline silica may cause lung disease, silicosis, lung cancer, and other effects.



Cement (Portland/Oilwell) Page 8 of 12 Numerical Measures of Toxicity of Ingredients:

Portland Cement: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3

Crystalline Silica (quartz): OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3. LD50 Oral Rat > 5000mg/kg

Calcium Oxide: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 2 mg/m3. IDLH 25 mg/m3

Gypsum: OSHA PEL (TWA) 15 mg/m3 (Total) 5 mg/m3 (Resp). NIOSH REL (TWA) 10 mg/m3 (Total) 5 mg/m3 (Resp).

Magnesium Oxide: OSHA PEL (TWA) 15 mg/m3. IDLH 750 mg/m3

Symptoms/Injuries After Inhalation:

The three types of silicosis include: 1) Simple chronic silicosis – which results from long-term exposure (more than 20 years) to low amounts of respirable crystalline silica. Nodules of chronic inflammation and scarring provoked by the respirable crystalline silica form in the lungs and chest lymph nodes. This disease may feature breathlessness and may resemble chronic obstructive pulmonary disease (COPD); 2) Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline silica over a shorter period of time (5-15 years); 3) Acute silicosis – results from short-term exposure to very large amounts of respirable crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe shortness of breath and low blood oxygen levels. Inflammation, scarring, and symptoms progress faster in accelerated silicosis than in simple silicosis. Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more common in the accelerated form. Progressive massive fibrosis results from severe scarring and leads to the destruction of normal lung structures. Some studies show that exposure to repairable crystalline silica (without silicosis) or that the disease silicosis may be associated with the increased incidence of several autoimmune disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus, rheumatoid arthritis, and diseases affecting the kidneys. Silicosis increases the risk of tuberculosis. Some studies show an increased incidence of chronic kidney disease and end-stage renal disease in workers exposed to respirable crystalline silica. Corrosive to the respiratory tract.

Symptoms/Injuries After Skin Contact:

Cement may cause dry skin, discomfort, irritation, severe burns, and dermatitis. Exposure to sufficient duration to wet cement, or to dry cement on moist areas of the body, can cause serious potentially irreversible damage to skin, eye, respiratory, and digestive tracts due to chemical (caustic) burns, including third degree burns. A skin exposure may be hazardous even if there is no pain or discomfort. Cement is capable of causing dermatitis by irrigation and allergy. Skin affected by dermatitis may include symptoms such as; redness, itching, rash, scaling, and cracking. Irritant dermatitis is caused by the physical properties of cement including alkalinity and abrasion. Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate) present in cement. The reaction can




range from a mild rash to severe skin ulcers. Persons already sensitized may react to the first contact with cement. Others may develop allergic dermatitis after years of repeated contact with cement.

Symptoms/Injuries After Eye Contact:

Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact with large amounts of dry powder or with wet cement can cause moderate eye irritation, chemical burns, and blindness. Eye exposures require immediate first aid and medical attention to prevent significant damage to the eye.

Symptoms/Injuries After Ingestion May cause burns or irritation of the linings of the mouth, throat, and gastrointestinal tract.

Chronic Symptoms: If dust is generated, repeated exposure through inhalation may cause cancer or lung disease.

Information on Carcinogenicity of Ingredients: Portland Cement: TLV-A4 Crystalline Silica: IARC Group 1 Calcium Oxide: Gypsum: Magnesium Oxide: TLV-A4

SECTION 12: ECOLOGICAL INFORMATION Toxicity: Not Classified. No recognized unusual toxicity to plants or animals.

Calcium Oxide (1305-78-8) : LC50 Fish: 1070 mg/l (Exposure time: 96 h – Species: Cyprinus carpio [static]) Persistence and Degradability: Crystalline Silica is not degradable. Bioaccumulation Potential:

Crystalline Silica is not bioaccumulative. Calcium Oxide (1305-78-8) : BCF fish 1 (no bioaccumulation).

Mobility in Soil: Crystalline Silica is not mobile in soil. Other Adverse Effects: No data available.

SECTION 13: DISPOSAL CONSIDERATIONS Waste Disposal Recommendations:

Dispose of waste material in accordance with all local, regional, state, national, provincial, territorial and international regulations.

Additional Information:

If discarded in its purchased form, this product would not be a hazardous waste either by listing or characteristic. However, under RCRA, it is the responsibility of the product user to determine at the time of disposal, whether a material containing or derived from the product should be classified as a hazardous waste.

SECTION 14: TRANSPORT INFORMATION



Cement (Portland/Oilwell) Page 10 of 12 UN Number: None UN Proper Shipping Name: Not regulated Transport Hazard Class(es): None Packing Group, if applicable: None Environmental hazards: None Not regulated for transport by DOT, IMDG,IATA, TDG

SECTION 15: REGULATORY INFORMATION US Federal Regulations USDOL-OSHA Hazard Communication Rule 29CFR 1900.1200

Portland cement is considered a “hazardous chemical” under this regulation, and should be part of any hazard communication program.

CERCLA/Superfund 40 CFR 117 and 302(v) Not classified as a hazardous substance under regulations of this Act.

Hazard Category under SARA (Title III) Section 311 and 312

Portland cement qualifies as a “hazardous substance” with immediate (acute) and delayed (chronic) health effects

Status Under SARA (Title III) Section 313 Not subject to reporting requirements under Section 313.

Status under TSCA Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305-78-8), Magnesium Oxide (1309-48-4) are listed on United States TSCA (Toxic Substances Control Act) inventory

Status under the Federal Hazardous Substances Act

Portland cement is a “hazardous substance” subject to statutes promulgated under the subject act.

US State Regulations

California Prop 65 WARNING: This product contains chemicals known to the State of California to cause cancer.

California Inhalation Reference Exposure Level (REL)

California established a chronic non-cancer effect REL of 3μg for silica (crystalline, respirable). A chronic REL is an airborne level of a substance at or below which no non-cancer health effects are anticipated in individuals indefinitely exposed to the substance at the level.

Massachusetts Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305-78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on Right to Know List

Pennsylvania Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305-78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on RTK (Right to Know) List

New Jersey Portland Cement (65997-15-1), Quartz (14808-60-7), Calcium Oxide (1305-78-8), Magnesium Oxide (1309-48-4) and Gypsum (13397-24-5) are listed on Right to Know Hazardous Substance List

CANADA Regulations CANADA Regulations WHMIS Classification Cement, Portland (65997-15-1) Listed on Canadian DSL Inventory. E – Corrosive Material




Listed on the Canadian Ingredient Disclosure List.

Silica, Quartz (14808-60-7) Listed on Canadian DSL Inventory. D2A – Very toxic material causing other toxic effects.

Calcium Oxide (1305-78-8) Listed on Canadian DSL Inventory. Listed on the Canadian Ingredient Disclosure List.

E – Corrosive Material

Magnesium Oxide (1309-48-4) Listed on Canadian DSL Inventory. Listed on the Canadian Ingredient Disclosure List.

Uncontrolled product according to WHMIS classification criteria.

SECTION 16: OTHER INFORMATION

Date of Preparation: May 10, 2016

Prepared By:

Thru Tubing Systems, Inc. 1806B Highway 90 East New Iberia, LA 70560 +1 (337) 606-0031

GHS Full Text Phrases: Carc. 1A Carcinogenicity Category 1A

Eye Dam. 1 Serious eye damage/eye irritation Category 1 Skin Corr. 1C Skin corrosion/irritation Category 1C

Skin Irrit. 2 Skin corrosion/irritation Category 2 Skin Sens. 1 Skin sensitization Category 1

STOT RE 1 Specific target organ toxicity (repeated exposure) Category 1 STOT SE 3 Specific target organ toxicity (single exposure) Category 3

H314 Causes severe burns and eye damage H315 Causes skin irritation H317 May cause allergic skin reaction H318 Causes serious eye damage H335 May cause respiratory irritation H350 May cause cancer (Inhalation) H372 Causes damage to organs through prolonged or repeated exposure P201 Obtain special instructions before use P202 Do not handle until all safety precautions have been read and understood. P260 Do not breathe dust. P264 Wash hands, forearms, and exposed areas thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P272 Contaminated work clothing should not be allowed out of workplace. P280 Wear protective gloves, protective clothing, face protection, eye protection.

P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting. P303+P361+P353+P352 IF ON SKIN (or hair): Remove/Take off immediately all contaminated




clothing. Rinse skin with water/shower. Wash with plenty of soap and water

P304+P340 IF INHALED: Remove person to fresh air and keep at rest in a position comfortable for breathing.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician. P321 Specific treatment (see Section 4).

P333+P313 If skin irritation or rash occurs: Get medical advice/attention. P362+P364 Take off contaminated clothing and wash it before reuse. P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

P501 Dispose of contents/container according to local, regional, state, national, territorial, provincial, and international regulations.

Other Important Information: Portland cement should only be used by knowledgeable persons. Inexperienced product users must obtain proper training before using this product. A key to using the product safely requires the user to recognize the Portland cement chemically reacts with water, and that some of the intermediate products of this reaction (that is, those present while a Portland cement product is “setting “) pose a far more severe hazard than does Portland cement itself. While the information provided in this Safety Data Sheet is believed to provide a useful summary of the hazards of Portland cement as it is commonly used, the sheet cannot, and does not, anticipate and provide all of the information that might be needed in every situation. In particular, the data furnished in this sheet does not address hazards that may be posed by other materials mixed with Portland cement products. Users therefore, should review other applicable material safety data sheets before working with this Portland cement or working on Portland cement or working Portland cement products, for example, Portland cement concrete.

THRU TUBING SYSTEMS, INC. (TTS) MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS THEREOF FOR ANY PURPOSE OR CONCERNING THE ACCURACY OF ANY INFORMATION PROVIDED BY TTS EXCEPT THAT THE PRODUCT SHALL CONFORM TO CONTRACTED SPECIFICATIONS. THE INFORMATION PROVIDED HEREIN WAS BELIEVED BY TTS TO BE ACCURATE AT THE TIME FO PERPARATION OR PREPARED FROM SOURCES BELIEVED TO BE RELIABLE, BUT IT IS THE RESPONSIBILITY OF THE USER TO INVESTIGATE AND UNDERSTAND OTHER PERTINENT SOURCES OF INFORMATION, TO COMPLY WITH ALL LAWS AND PROCEDURES APPLICABLE TO THE SAFE HANDLING AND USE OF PRODUCT, AND TO DETERMINE THE SUITABILITY OF THE PRODUCT FOR ITS INTENDED USE. BUYER’S EXCLUSIVE REMEDY SHALL BE FOR DAMAGES AND NO CLAIM OF ANY KIND, WHETHER AS TO PRODUCT DELIVERED OR FOR NON-DELIVERY OF PRODUCT, AND WHETHER BASED ON CONTRACT, BREACH OF WARRANTY, NEGLIGENCE, OR OTHERWISE SHALL BE GREATER IN AMOUNT THAN THE PURCHASE PRICE OF THE QUANTITY OF PRODUCT IN RESPECT OF WHICH DAMAGES ARE CLAIMED. IN NO EVENT SHALL TTS BE LIABLE FOR INCIDENTAL OR CONSEQUENTIAL DAMAGES, WHETHER BUYER’S CLAIM IS BASED ON CONTRACT, BREACH OF WARRANTY, NEGLIGENCE, OR OTHERWISE.

1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER

HSE-SDS-006 ● PETROLEUM, HYDROCARBON, STABILISED CONDENSATE ● WAITSIA STAGE 1ACONDENSATE ● XPF CONDENSATE ● XYRIS CONDENSATE ● XYRIS PROCESSING FACILITYCONDENSATE ● XYRIS PRODUCTION FACILITY CONDENSATE

Synonyms

PETROLEUM REFININGUses1.2 Uses and uses advised against

1.3 Details of the supplier of the product

AWE PERTH PTY LTD (WHOLLY OWNED SUBSIDIARY OF MITSUI & CO LTD)Supplier name

Level 3, 1101 Hay Street, West Perth, WA, 6005, AUSTRALIAAddress

(08) 9480 1300Telephone

(08) 9480 1388Fax

[email protected]

1800 882 118Emergency

1.4 Emergency telephone numbers

www.mitsui.com.au/mepauWebsite

1.1 Product identifier

CONDENSATE (XYRIS)Product name

2. HAZARDS IDENTIFICATION

CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

2.2 GHS Label elements

Signal word DANGER

Pictograms

Physical Hazards

Flammable Liquids: Category 2

Health Hazards

Aspiration Hazard: Category 1Skin Corrosion/Irritation: Category 2Germ Cell Mutagenicity: Category 1BCarcinogenicity: Category 1AToxic to Reproduction: Category 1ASpecific Target Organ Toxicity (Repeated Exposure): Category 2

Environmental Hazards

Aquatic Toxicity (Chronic): Category 3

2.1 Classification of the substance or mixture

SDS Date: 23 Jan 2019

Version No: 1ofPage 1 8

mailto:[email protected]

www.mitsui.com.au/mepau

CONDENSATE (XYRIS)PRODUCT NAME

No information provided.2.3 Other hazards

Dispose of contents/container in accordance with relevant regulations.P501Disposal statements

Store in a well-ventilated place. Keep cool.P403 + P235Store locked up.P405

Storage statements

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.P301 + P310IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.P303 + P361 + P353IF exposed or concerned: Get medical advice/ attention.P308 + P313Specific treatment is advised - see first aid instructions.P321Do NOT induce vomiting.P331Take off contaminated clothing and wash before re-use.P362In case of fire: Use appropriate media for extinction.P370 + P378

Response statements

Obtain special instructions before use.P201Do not handle until all safety precautions have been read and understood.P202Keep away from heat/sparks/open flames/hot surfaces. No smoking.P210Keep container tightly closed.P233Ground/bond container and receiving equipment.P240Use explosion-proof electrical/ventilating/lighting equipment.P241Use only non-sparking tools.P242Take precautionary measures against static discharge.P243Do not breathe dust/fume/gas/mist/vapours/spray.P260Wash thoroughly after handling.P264Avoid release to the environment.P273Wear protective gloves/protective clothing/eye protection/face protection.P280

Prevention statements

Highly flammable liquid and vapour.H225May be fatal if swallowed and enters airways.H304Causes skin irritation.H315May cause genetic defects.H340May cause cancer.H350May damage fertility or the unborn child.H360May cause damage to organs through prolonged or repeated exposure.H373Harmful to aquatic life with long lasting effects.H412

Hazard statements

3. COMPOSITION/ INFORMATION ON INGREDIENTS

Ingredient CAS Number EC Number Content

>80%64741-47-5 265-047-3NATURAL GAS CONDENSATES (PETROLEUM)

3 to <10%108-88-3 203-625-9TOLUENE

1 to 3%95-63-6 202-436-91,2,4-TRIMETHYLBENZENE

1 to 3%71-43-2 200-753-7BENZENE

<1%100-41-4 202-849-4ETHYLBENZENE

<1%110-54-3 203-777-6N-HEXANE

<0.001%7439-97-6 231-106-7MERCURY

3.1 Substances / Mixtures

4. FIRST AID MEASURES

If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

4.1 Description of first aid measures

Eye

If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.

Inhalation

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin




Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.

Ingestion

None allocated.First aid facilities

See Section 11 for more detailed information on health effects and symptoms.4.2 Most important symptoms and effects, both acute and delayed

4.3 Immediate medical attention and special treatment neededTreat symptomatically.

5. FIRE FIGHTING MEASURES

Highly flammable. May evolve carbon oxides and hydrocarbons when heated to decomposition. Eliminate all ignition sources includingcigarettes, open flames, spark producing switches/tools, heaters, naked lights, pilot lights, mobile phones, etc when handling. Earthcontainers when dispensing fluids.

5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.

5.3 Advice for firefighters

3YE3 Normal Foam (protein based foam that is not alcohol resistant).Y Risk of violent reaction or explosion. Wear full fire kit and breathing apparatus. Contain spill and run-off.E Evacuation of people in and around the immediate vicinity of the incident should be considered.

5.4 Hazchem code

Dry agent, carbon dioxide or foam. Prevent contamination of drains and waterways.5.1 Extinguishing media

6. ACCIDENTAL RELEASE MEASURES

Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible.

6.1 Personal precautions, protective equipment and emergency procedures

Prevent product from entering drains and waterways.6.2 Environmental precautions

Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.

6.3 Methods of cleaning up

See Sections 8 and 13 for exposure controls and disposal.6.4 Reference to other sections

7. HANDLING AND STORAGE

Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Large storage areas should have appropriate fire protection systems.

7.2 Conditions for safe storage, including any incompatibilities

No information provided.7.3 Specific end uses

7.1 Precautions for safe handling

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminated areas.




8. EXPOSURE CONTROLS / PERSONAL PROTECTION

8.1 Control parameters

Exposure standards

Ingredient ReferenceTWA STEL

ppm mg/m³ ppm mg/m³

1,2,4-Trimethylbenzene (as Trimethyl benzene) SWA [AUS] 25 123 -- --

Benzene SWA [AUS] 1 3.2 -- --

Ethyl benzene SWA [AUS] 100 434 125 543

Mercury, elemental vapour (as Hg) SWA [AUS] 0.003 0.025 -- --

Toluene SWA [AUS] 50 191 150 574

n-Hexane SWA [AUS] 20 72 -- --

Biological limits

Ingredient Determinant BEISampling Time

25 µg/gcreatinine

End of shiftS-Phenylmercapturic acid in urineBENZENE

500 µg/g creatineEnd of shiftt,t-Muconic acid in urine

0.7 g/g creatinineEnd of shift atend of workweek

Sum of mandelic acid and phenylglyoxylicacid in urine

ETHYLBENZENE

-Not criticalEthyl benzene in end-exhaled air

20 µg/gcreatinine

Prior to shiftTotal inorganic mercury in urineMERCURY

0.4 mg/LEnd of shift atend of workweek

2,5-Hexanedione in urine (without hydrolysis)N-HEXANE

0.02 mg/LEnd of shifto-Cresol in urineTOLUENE

0.03 mg/LEnd of shiftToluene in urine

0.02 mg/LPrior to last shiftof workweek

Toluene in blood

Reference: ACGIH Biological Exposure Indices

PPE

Eye / Face Wear splash-proof goggles.

Hands Wear PVC or rubber gloves. With prolonged use, wear viton (R) or nitrile gloves.

Body With prolonged use, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator.

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Flammable/explosive vapours may accumulate in poorly ventilated areas.Vapours are heavier than air and may travel some distance to an ignition source and flash back.

8.2 Exposure controlsEngineering controls

9. PHYSICAL AND CHEMICAL PROPERTIES

9.1 Information on basic physical and chemical propertiesCLEAR YELLOW/BROWN LIQUIDAppearanceHYDROCARBON ODOUROdourHIGHLY FLAMMABLEFlammability> 20°CFlash point63°CBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpH




9.1 Information on basic physical and chemical propertiesNOT AVAILABLEVapour density0.85Specific gravityINSOLUBLESolubility (water)6.2 kPag @ 37.8°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperature1.778 cSt @ 20°CViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information100 %% Volatiles

10. STABILITY AND REACTIVITY

10.2 Chemical stability

Stable under recommended conditions of storage.

10.4 Conditions to avoid

Avoid heat, sparks, open flames and other ignition sources.

10.5 Incompatible materials

Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), alkalis (e.g. sodium hydroxide), heat and ignitionsources.

May evolve carbon oxides and hydrocarbons when heated to decomposition.10.6 Hazardous decomposition products

Polymerization is not expected to occur.

10.3 Possibility of hazardous reactions

10.1 ReactivityCarefully review all information provided in sections 10.2 to 10.6.

11. TOXICOLOGICAL INFORMATION

May be harmful if swallowed, in contact with skin, and/or if inhaled.Acute toxicity

Information available for the ingredients:

IngredientOral LD50 Dermal LD50 Inhalation LC50

-- -- 600 mg/m³ (rat)NATURAL GAS CONDENSATES (PETROLEUM)

5580 mg/kg (rat) 5000 mg/kg (rabbit) 25.7 - 30 mg/L/4hrs (rat)TOLUENE

6000 mg/kg (rat) -- 18 g/m³/4hrs (rat)1,2,4-TRIMETHYLBENZENE

930 mg/kg (rat) 48 mg/kg (mouse) 9980 ppm (mouse)BENZENE

3500 mg/kg (rat) 17800 mg/kg (rabbit) 50 g/m³/2 hours(mouse)

ETHYLBENZENE

25 g/kg (rat) 3000 mg/kg (rabbit) 48000 ppm/4 hours (rat)N-HEXANE

10 - 40 mg/kg(expected)

-- 0.014 mg/L/4 hours (rat)MERCURY

Contact may result in drying and defatting of the skin, rash and dermatitis.Skin

Contact may result in irritation, lacrimation and redness.Eye

Not classified as causing skin or respiratory sensitisation.Sensitisation

May cause genetic defects. Several studies have demonstrated induction of both numerical and structuralchromosomal aberrations, sister chromatid exchanges and micronuclei in experimental animals and humansafter in vivo benzene exposure.

Mutagenicity

11.1 Information on toxicological effects




Over exposure may result in irritation of the nose and throat, coughing, dizziness, drowsiness and headache.STOT - singleexposure

Aspiration or inhalation may cause chemical pneumonitis and pulmonary oedema.Aspiration

Available evidence from animal studies indicate that repeated or prolonged exposure to this material couldresult in adverse skin effects. Effects to lungs and central nervous system have also been reported. Chronicexposure to benzene may result in loss of appetite, tremors, anaemia (bone marrow depression), liver andkidney damage.

STOT - repeatedexposure

Over exposure to toluene may damage fertility or the unborn child.Reproductive

May cause cancer. Benzene is classified as carcinogenic to humans (IARC Group 1). Ethylbenzene isclassified as possibly carcinogenic to humans (IARC Group 2B). Condensates may contain other polycyclicaromatic hydrocarbons (PCAHs), some of which are classified as probably carcinogenic to humans (IARCGroup 2A).

Carcinogenicity

12. ECOLOGICAL INFORMATION

12.1 Toxicity

Harmful to aquatic life with long lasting effects.

12.2 Persistence and degradabilityNo information provided.

12.4 Mobility in soil



12.5 Other adverse effects

12.3 Bioaccumulative potentialNo information provided.

13. DISPOSAL CONSIDERATIONS

For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site.Contact the manufacturer/supplier for additional information if disposing of large quantities (if required).Prevent contamination of drains and waterways as aquatic life may be threatened and environmentaldamage may result.

13.1 Waste treatment methods

Waste disposal

Dispose of in accordance with relevant local legislation.Legislation

14. TRANSPORT INFORMATION

LAND TRANSPORT (ADG) SEA TRANSPORT (IMDG / IMO) AIR TRANSPORT (IATA / ICAO)

II

3 3

II II

314.3 Transporthazard class

14.4 Packing Group

HYDROCARBONS, LIQUID,N.O.S. (natural gas condensate)

3295


3295 3295


14.1 UN Number

14.2 ProperShipping Name

Not a Marine Pollutant

14.5 Environmental hazards

14.6 Special precautions for user

CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE




3YEHazchem code

F-E, S-DEMS

3A1GTEPG

15. REGULATORY INFORMATION

Classified as a Schedule 7 (S7) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule

AUSTRALIA: AICS (Australian Inventory of Chemical Substances)All components are listed on AICS, or are exempt.

Inventory listings

Safework Australia criteria is based on the Globally Harmonised System (GHS) of Classification andLabelling of Chemicals.

Classifications

16. OTHER INFORMATION

MINERAL OILS - NON REFINED: Animal experiments and human experience have shown cancerrisks when handling mineral oils. Such cases are reported to have occurred in conditions where pooroccupational hygiene practices resulted in prolonged skin contact. CLEANING MINERAL OILCONTAMINATED CLOTHING: Cleaners are advised that when cleaning oil contaminated clothing itis essential that freshly distilled solvent is used for each batch, including final rinse, as even filteredsolvent will leave oil residues.

EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established onthe premise of an 8 hour work period of normal intensity, under normal climatic conditions and wherea 16 hour break between shifts exists to enable the body to eliminate absorbed contaminants. In thefollowing circumstances, exposure standards must be reduced: Strenuous work conditions; hot,humid climates; high altitude conditions; extended shifts (which increase the exposure period andshorten the period of recuperation).

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as form of product, method of application, working environment, quantity used,product concentration and the availability of engineering controls should be considered before finalselection of personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: form of product; frequency and duration of use; quantity used; effectiveness of controlmeasures; protective equipment used and method of application. Given that it is impractical toprepare a report which would encompass all possible scenarios, it is anticipated that users willassess the risks and apply control methods where appropriate.

Additional information




ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous

Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average

Abbreviations

This document has been compiled by RMT on behalf of the manufacturer, importer or supplier of theproduct and serves as their Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by themanufacturer, importer or supplier or obtained from third party sources and is believed to representthe current state of knowledge as to the appropriate safety and handling precautions for the productat the time of issue. Further clarification regarding any aspect of the product should be obtaineddirectly from the manufacturer, importer or supplier.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it doesnot provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT acceptsno liability for any loss, injury or damage (including consequential loss) which may be suffered orincurred by any person as a consequence of their reliance on the information contained in this SDS.

Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmtglobal.com

Prepared by

[ End of SDS ]




Synonym(s) CORROSION INHIBITOR

BRINE • CORROSION INHIBITOR • DRILLING FLUID ADDITIVE • OIL AND GAS INDUSTRYUse(s)

1.2 Uses and uses advised against


Supplier name NEWPARK DRILLING FLUIDS (AUSTRALIA) LTD

Address 11 Alacrity Place, Henderson, WA, 6166, AUSTRALIA

Telephone +61 8 9410 8200

Fax +61 8 9410 8299

1800 127 406 (Australia); +64 3 3530199 (International)Emergency

1.4 Emergency telephone number(s)

www.newpark.comWebsite


ANCOR 1Product name


CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS

2.2 Label elements

Signal word WARNING


Disposal statement(s)None allocated.

Storage statement(s)None allocated.

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

If eye irritation persists: Get medical advice/attention.P337 + P313

Response statement(s)

Wash thoroughly after handling.P264Wear protective gloves/protective clothing/eye protection/face protection.P280

Prevention statement(s)

Causes serious eye irritation.H319Hazard statement(s)

Pictogram(s)

Serious Eye Damage / Eye Irritation: Category 2AGHS classification(s)


Page 1 of 6SDS Date: 06 May 2015

Version No: 2.2

www.newpark.com

ANCOR 1PRODUCT NAME



TRIETHANOLAMINE 68 to 72%102-71-6 203-049-8

NON HAZARDOUS INGREDIENTS 28 to 32%Not Available Not Available





Eye

Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.

First aid facilities Eye wash facilities and safety shower should be available.

Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.4.2 Most important symptoms and effects, both acute and delayed



Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Ventilatearea where possible. Contact emergency services where appropriate.



Contain spillage, then cover / absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.





Version No: 2.2

ANCOR 1PRODUCT NAME

Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Store as a Class C1 Combustible Liquid (AS1940).


No information provided.7.3 Specific end use(s)






Triethanolamine SWA (AUS) -- 5 -- --


Exposure standards

Biological limits

No biological limit values have been entered for this product.

PPE


Hands Wear PVC or rubber gloves.

Body Wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.

Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.

8.2 Exposure controls


9.1 Information on basic physical and chemical properties COLOURLESS LIQUIDAppearanceSLIGHT ODOUROdourCLASS C1 COMBUSTIBLEFlammability> 100°CFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.1Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosity


Version No: 2.2

ANCOR 1PRODUCT NAME

9.1 Information on basic physical and chemical properties NOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other informationNOT AVAILABLE% Volatiles







Incompatible with oxidising agents (e.g. hypochlorites), acids (e.g. nitric acid), nitrites, heat and ignition sources.

May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products

Hazardous polymerization is not expected to occur.




Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled.Toxicity Data available for the ingredient:TRIETHANOLAMINE (102-71-6):LD50 (Ingestion): 2200 mg/kg (rabbit)LD50 (Intraperitoneal): 1450 mg/kg (mouse)LD50 (Skin): > 20 mL/kg (rabbit)TDLo (Ingestion): 16 g/kg/64 weeks (mouse - cancer)

Skin Contact may result in mild irritation, redness, pain and rash.

Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact.

Sensitization Triethanolamine has been reported to cause allergic contact dermatitis. It is not known to cause respiratorysensitisation.

Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.

STOT – singleexposure

Aspiration This product is not expected to present an aspiration hazard.

Not classified as causing organ effects from repeated exposure.STOT – repeatedexposure

Reproductive Insufficient data available to classify as a reproductive toxin.

Carcinogenicity Triethanolamine is not classifiable as to its carcinogenicity to humans (IARC Group 3).

Mutagenicity Insufficient data available to classify as a mutagen.



12.1 Toxicity

LC50 (shrimp): > 100 ppm.

12.2 Persistence and degradabilityIn soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks).

12.3 Bioaccumulative potentialNot expected to bioaccumulate.


Version No: 2.2

ANCOR 1PRODUCT NAME


In soil, residual triethanolamine may leach to groundwater.




Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid.Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of toan approved landfill site. Contact the manufacturer/supplier for additional information (if required).


Legislation Dispose of in accordance with relevant local legislation.

LAND TRANSPORT(ADG)

SEA TRANSPORT(IMDG / IMO)

AIR TRANSPORT(IATA / ICAO)

14.4 Packing Group None Allocated

None Allocated None Allocated


None Allocated14.3 Transporthazard class

14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated

No information provided14.5 Environmental hazards

None AllocatedHazchem code


NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE, IMDG OR IATA



Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

R36 Irritating to eyes.Risk phrases


Inventory listing(s)

S36 Wear suitable protective clothing.Safety phrases

Xi IrritantHazard codes


Classifications

The classifications and phrases listed below are based on the Approved Criteria for Classifying HazardousSubstances [NOHSC: 1008(2004)].


RESPIRATORS: In general the use of respirators should be limited and engineering controlsemployed to avoid exposure. If respiratory equipment must be worn ensure correct respiratorselection and training is undertaken. Remember that some respirators may be extremelyuncomfortable when used for long periods. The use of air powered or air supplied respirators shouldbe considered where prolonged or repeated use is necessary.



Version No: 2.2

ANCOR 1PRODUCT NAME

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a ChemAlert reportwhich would encompass all possible scenarios, it is anticipated that users will assess the risks andapply control methods where appropriate.




Abbreviations




Report status

Prepared by Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.

[ End of SDS ]


Version No: 2.2

Material Safety Data Sheet

EMERGENCY PHONE PRODUCT NAME

1-800-255-3924 BROMINE TRIFLUORIDE CAS #7787-71-5TRADE NAME AND SYNONYMS

Pipe Recovery Systems, Inc. Bromine Trifluoride UN - 1746 PACKING GROUP IHouston, Texas, USA CHEMICAL NAME AND SYNONYMS

(713) 461-7770 Bromine Trifluoride

ISSUE DATE 04/78, 02/84 FORMULA CHEMICAL FAMILY

REVISION DATE 5/95, 7/99, 8/02, 2/03, 4/04, BrF3 Halogen Fluoride

6/06, 6/07, 8/07, 05/09, 10/11 HEALTH HAZARD DATATIME WEIGHTED AVERAGE EXPOSURE LIMIT See last pageSYMPTOMS OF EXPOSURE

Corrosive and extremely irritating to the upper and lower respiratory tracts, skin, and eyes. BrF3 hydrolyzes to form hydrofluoric acid, thereforeskin burns and mucous membrane irritation are similar to those caused by the acid. Symptoms include tearing of the eyes, cough, difficultbreathing, abnormal fluids formation in the nose, mouth and throat. Inhalation of BrF3 may cause pneumonitis ( deep lung inflammation) and pulmonary edema (abnormal fluid buildup in the lungs) which can be fatal. Symptons of hydrofluoric acid burns are severe pain, redness,

possible swelling and tissue destruction.

TOXICOLOGICAL PROPERTIES

Bromine Trifluoride is irritating and corrosive to all living tissues. Toxic level exposure to skin tissue causes hydrofluoric acid burns and skin lesions

resulting in tissue destruction and eventual scarring. Burn activity continues while any residual active fluorides remain. Chemical pneumonitis and

pulmonary edema result from exposure to the lower respiratory tract and deep lung. Residual pulmonary malfunction might also occur. Burns

of the eye result in lesions and possible loss of vision. Extended low level systemic absorption of fluorides may cause fluorosis, an abnormal

calcium accumulation in the bone structure.

RECOMMENDED FIRST AID TREATMENTPROMPT MEDICAL ATTENTION IS REQUIRED IN ALL CASES OF OVEREXPOSURE. BROMINE TRIFLUORIDE RESCUE PERSONNEL SHOULD BE EQUIPPED WITH APPROPRIATE PROTECTIVE EQUIPMENT (SELF-CONTAINED BREATHING APPARATUS, ETC.) TO PREVENT UNNECESSARY EXPOSURE.

Inhalation: Move exposed personnel to an uncontaminated area. If not breathing, give artifical respiration, preferably mouth-to-mouth. Ifbreathing is difficult, give oxygen. Keep victim warm and quiet. Assure that mucus or vomited material does not obstruct the airway by use ofpositional drainage. Delayed pulmonary edema may occur. Keep patient under medical observation for at least 24 hours.

Eye Contact: PERSONS WITH POTENTIAL EXPOSURE TO BROMINE TRIFLUORIDE SHOULD NOT WEAR CONTACT LENSES.Flush contaminated eye(s) with large quantites of water. Hold eyelids open with fingers to assure complete flushing. Continue for minimum of30 minutes.

Skin Contact: Flush affected area with large quantities of water. Remove affected clothing as rapidly as possible. Skin burns may be treatedwith a calcium gluconate gel or slurry in water or glycerine. This compound binds the active fluorides in an insoluble form and limits burnextension and relieves pain.

HAZARDOUS MIXTURES OF OTHER LIQUIDS, SOLIDS, OR GASESBromine Trifluoride is a very reactive halogen fluoride. It reacts with virtually all organic and most inorganic substances. Some of the perfluorinated organic substances in their pure form will not be oxidized by Bromine Trifluoride. It reacts violently with water or fuels.

PHYSICAL DATABOILING POINT 258.4°F (125.8°C) LIQUID DENSITY AT BOILING 157.2 lb/ft 3 (2518Kg/m 3 )

VAPOR PRESSURE @70°F (21.1°C) 0.145psia (1.0 kPa) GAS DENSITY AT 79°F 1 atm Liquid

SOLUBILITY IN WATER Reacts violently FREEZING POINT 47.8°F (8.8°C)

APPEARANCE AND ODOR Colorless, fuming liquid with a choking, pungent odor.

FIRE AND EXPLOSION HAZARD DATAFLASH POINT (Method used) AUTO IGNITION TEMPERATURE FLAMMABLE LIMITS % BY VOLUME

N/A N/A LEL UEL N/AEXTINGUISHING MEDIA ELECTRICAL CLASSIFICATION

Nonflammable NonhazardousSPECIAL FIRE FIGHTING PROCEDURES UNUSUAL FIRE AND EXPLOSION HAZARDS

Fires with bromine trifluoride as the oxidizer can only be extinguished Reacts violently or explodes on contact with water or organic mate-

by shutting off the source of bromine trifluoride. Do not use water, rials. Combustion products, including hydrogen fluoride, are toxic

chemicals, carbon dixide or other extinguishing media as these will and reactive.

only add more fuel to the fire.

REACTIVITY DATASTABILITY CONDITIONS TO AVOID

Unstable

Stable X Reacts violently or explodes on contact with water and organic materials.INCOMPATIBILITY (Material to avoid)

Water, plastics, hydrocarbons, other organic materials.HAZARDOUS DECOMPOSITION PRODUCTS

Bromine, fluorine, bromine monofluoride; hydrogen fluoride in reactionsHAZARDOUS POLYMERIZATION CONDITIONS TO AVOID

May Occur

Will Not Occur X

SPILL OR LEAK PROCEDURESSTEPS TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED

Evacuate all personnel from affected area. Use appropriate protective equipment.Call company technical supervisor or Pipe Recovery phone number (713)461-7770.WASTE DISPOSAL METHOD

All Federal, State and Local Regulations regarding health and pollution should be followed in waste disposal. ContactPipe Recovery Systems for specific recommendations. Do not dispose of unused quantities. Contact Tech Manageror Pipe Recovery Systems for instructions.

SPECIAL PROTECTION INFORMATIONRESPIRATORY PROTECTION (Specify type)

Full face respirator, positive pressure airline or self breathing apparatus.VENTILATION

INDOOR: Hood with forced ventilationOUTDOOR: Open area, none requiredPROTECTIVE GLOVES EYE PROTECTION

Neoprene Rubber Full face piece respiratorOTHER PROTECTIVE EQUIPMENT

Safety shoes, eyewash and acid resistant overgarments.

SPECIAL PRECAUTIONS*SPECIAL LABELING INFORMATION D.O.T.Shipping Name:Bromine Trifluoride D.O.T.Shipping Label:Oxidizer, corrosive,poison,

inhalation hazard.

D.O.T.Shipping Class: Oxidizer I.D. No.: UN 1746 Zone BSPECIAL HANDLING RECOMMENDATIONS

Use in only well-ventilated areas. Do not drag, slide or roll cylinder.SPECIAL STORAGE RECOMMENDATIONS

Protect cylinders from physical damage. Store in cool, dry, well-ventilated area away from heavily trafficked areas andemergency exits. Do not allow the temperature where cylinders are stored to exceed 130°F (54°C) Full and empty cylinders should be segregated. Use a "first-in-first-out" inventory system.TIME WEIGHTED AVERAGE EXPOSURE LIMIT

None established (ACGIH 1984-85). Observation of the exposure limits for hydrogen fluoride, which forms when BrF3 ishydrolyzed, is recommended.The TWA for HF is 3 molar ppm; the STEL is 6 molar ppm (ACGIH 1984-85)Note: ACGIH (1984-85) has proposed adoption of a ceiling value of 3 molar for HF.Local Exhaust: To prevent accumulation above the TWA for hydrogen fluoride

*Various Government agencies (I.e., Department of Transportation, Occupational Safety and Health Administration, Food and Drug

Administration and others) may have specific regulations concerning the transportation, handling, storage or use of this product which

will not be reflected in this data sheet. The customer should review these regulations to ensure that he is in full compliance.


ABGRIT ● CIRCAL ● LIMESTONE ● MARBLE ● NEWCARB, AG LIMESTONE, UNICAL 20, UNICAL 40 ANDUNICAL C300C ● OMYACAL ● OMYACARB ● RHEOCARB ● STONEDUST

Synonym(s)

DRILLING FLUID ADDITIVE ● WEIGHTING AGENTUse(s)1.2 Uses and uses advised against


NEWPARK DRILLING FLUIDS (AUSTRALIA) LTDSupplier name

11 Alacrity Place, Henderson, WA, 6166, AUSTRALIAAddress

+61 8 9410 8200Telephone

+61 8 9410 8299Fax





CALCIUM CARBONATEProduct name


NOT CLASSIFIED AS HAZARDOUS ACCORDING TO SAFE WORK AUSTRALIA CRITERIA

2.2 Label elementsNo signal word, pictograms, hazard or precautionary statements have been allocated.





>96%1317-65-3 215-279-6LIMESTONE (CALCIUM CARBONATE)

<1%14808-60-7 238-878-4QUARTZ (CRYSTALLINE SILICA)





Eye

If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Inhalation

If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting.

Ingestion

Eye wash facilities and safety shower should be available.First aid facilities

SDS Date: 24 Feb 2017

Version No: 2.3ofPage 1 6

www.newpark.com

CALCIUM CARBONATEPRODUCT NAME

May cause irritation to the eyes, skin and respiratory system.4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve toxic gases if strongly heated.5.2 Special hazards arising from the substance or mixture

No fire or explosion hazard exists.5.3 Advice for firefighters

None allocated.

5.4 Hazchem code

Use an extinguishing agent suitable for the surrounding fire.5.1 Extinguishing media


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS.6.1 Personal precautions, protective equipment and emergency procedures


If spilt, collect and reuse where possible. If reuse is not possible, contain spillage, then collect and place in suitable containers fordisposal. Avoid generating dust.




Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.




Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skin contact and inhalation.Observe good personal hygiene, including washing hands before eating. Prohibit eating, drinking and smoking in contaminatedareas.



Exposure standards



Calcium carbonate (Limestone, Marble, Whiting) SWA (AUS) -- 10 -- --

Quartz (respirable dust) SWA (AUS) -- 0.1 -- --

No Biological Limit Value allocated.Biological limits




PPE

Eye / Face Wear dust-proof goggles.

Hands When using large quantities or where heavy contamination is likely, wear PVC or rubber gloves.

Body When using large quantities or where heavy contamination is likely, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.



9.1 Information on basic physical and chemical propertiesOFF-WHITE POWDERAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point840°C (Decomposes)Boiling point825°CMelting pointNOT AVAILABLEEvaporation rate9pHNOT AVAILABLEVapour density2.7Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with acids (e.g. nitric acid), fluorine, aluminium (hot) and ammonium salts. Incompatible with oxidising agents (e.g.hypochlorites).

May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products

Polymerization will not occur.







This product is expected to be of low toxicity. Based on available data, the classification criteria are not met.LD50 (Ingestion) = 6450 mg/kg (rat).

Acute toxicity

Information available for the ingredient(s):

IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity

(LC50)

> 5000 mg/kg (rat) -- --LIMESTONE (CALCIUM CARBONATE)

Not classified as a skin irritant. Contact may result in mild irritation, redness and rash.Skin

Not classified as an eye irritant. However, direct contact may result in mild irritation, lacrimation, pain andredness. Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.

Eye


Not classified as causing organ damage from single exposure.STOT - singleexposure

This product does not present an aspiration hazard.Aspiration

Not classified as causing organ damage from repeated exposure. Chronic exposure to respirable silica mayresult in pulmonary fibrosis (silicosis). However, given the low levels present, over exposure is notanticipated.


Insufficient data available to classify as a reproductive toxin.Reproductive

Insufficient data available to classify as a carcinogen.Carcinogenicity

Not classified as a mutagen. Insufficient data available to classify as a mutagen.Mutagenicity



12.1 Toxicity

Calcium carbonate occurs naturally in a wide variety of substances including limestone, marble and egg shells. It is not anticipated tocause adverse environmental effects.

12.2 Persistence and degradabilityDissolved calcium carbonate dissociates into calcium and carbonate ions. Calcium ions will be assimilated by living organisms in thewater and the carbonate will become part of the carbon cycle.


Due to its limited solubility, calcium carbonate precipitates and deposits on the sediment.

Avoid contamination of drains and waterways.


12.3 Bioaccumulative potentialThis product does not bioaccumulate.


Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).


Waste disposal








None allocated.

None allocated. None allocated.


None allocated.14.3 Transporthazard class

14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number




None allocated.Hazchem code



A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

Poison schedule

None allocated.Risk phrases



None allocated.Safety phrases

None allocated.Hazard codes



Classifications



EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.










Abbreviations



While RMT has taken all due care to include accurate and up-to-date information in this SDS, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMTaccepts no liability for any loss, injury or damage (including consequential loss) which may besuffered or incurred by any person as a consequence of their reliance on the information containedin this SDS.

Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au

Prepared by

[ End of SDS ]



SAFETY DATA SHEET

Fluorodye UC

1 / 9

Section: 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : Fluorodye UC

Other means of identification : Not applicable.

Recommended use : PROCESS AID

Restrictions on use : Refer to available product literature or ask your local Sales Representative for

restrictions on use and dose limits.

Company : ECOLAB PTY LTD 2 Drake Avenue Macquarie Park NSW 2113 Australia A.B.N. 59 000 449 990 TEL: 1300 654 224 FAX: +61 2 8870 8680

Emergency telephone number

: 1800 205 506 International: +64 7 958 2372

Issuing date : 19.02.2017

Section: 2. HAZARDS IDENTIFICATION

GHS Classification

Skin corrosion/irritation : Category 2 Serious eye damage/eye irritation

: Category 1

Specific target organ toxicity - repeated exposure

: Category 2 (Kidney)

GHS Label element

Hazard pictograms :

Signal Word : Danger

Hazard Statements : Causes skin irritation.

Causes serious eye damage. May cause damage to organs (Kidney) through prolonged or repeated exposure.

Precautionary Statements : Prevention: Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/ eye protection/ face protection. Wash skin thoroughly after handling. Response: IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. Get medical advice/ attention if you feel unwell. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. Disposal: Dispose of contents/ container to an approved waste disposal plant.

SAFETY DATA SHEET

Fluorodye UC

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Other hazards : Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Section: 3. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. Concentration: (%)

Ethylene Glycol 107-21-1 10 - 30 Acetic Acid 64-19-7 10 - 30 C.I. Basic Violet 10 (Rhodamine B or D&C Red No 19) 81-88-9 10 - 30

Section: 4. FIRST AID MEASURES

In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15

minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.

In case of skin contact : Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Get medical attention if irritation develops and persists.

If swallowed : Rinse mouth. Get medical attention if symptoms occur.

Contact the Poison's Information Centre (eg Australia 13 1126; New Zealand 0800 764 766).

If inhaled : Remove to fresh air. Treat symptomatically. Get medical attention if symptoms occur.

Protection of first-aiders : In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required.

Notes to physician : Treat symptomatically.

Most important symptoms and effects, both acute and delayed

: See Section 11 for more detailed information on health effects and symptoms.

Section: 5. FIREFIGHTING MEASURES

Suitable extinguishing media : Use extinguishing measures that are appropriate to local circumstances and the

surrounding environment. Unsuitable extinguishing media

: None known.

Specific hazards during firefighting

: Not flammable or combustible.

Hazardous combustion products

: Decomposition products may include the following materials: Carbon oxides

Special protective equipment for firefighters

: Use personal protective equipment.

Specific extinguishing methods

: Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations.

Section: 6. ACCIDENTAL RELEASE MEASURES

SAFETY DATA SHEET

Fluorodye UC

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Personal precautions, protective equipment and emergency procedures

: Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8.

Environmental precautions : Do not allow contact with soil, surface or ground water. Methods and materials for containment and cleaning up

: Stop leak if safe to do so. Contain spillage, and then collect with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway.

Section: 7. HANDLING AND STORAGE

Advice on safe handling : Avoid contact with skin and eyes. Do not breathe

dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wash hands thoroughly after handling. Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions for safe storage : Keep out of reach of children. Keep container tightly closed. Store in suitable labelled containers.

Suitable material : Keep in properly labelled containers.

Unsuitable material : not determined

Section: 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Components with workplace control parameters

Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.

Components CAS-No. Form of exposure Permissible concentration

Basis

Ethylene Glycol 107-21-1 TWA (Vapour.) 20 ppm 52 mg/m3

AU OEL

VLE (Vapour.) 40 ppm 104 mg/m3

AU OEL

TWA (Particulate.)

10 mg/m3 AU OEL

Ethylene Glycol 107-21-1 WES-Ceiling (Vapour and mist)

50 ppm 127 mg/m3

NZ OEL

Ethylene Glycol 107-21-1 Ceiling (Aerosol only)

100 mg/m3 ACGIH

Acetic Acid 64-19-7 VLE 15 ppm 37 mg/m3

AU OEL

TWA 10 ppm 25 mg/m3

AU OEL

Acetic Acid 64-19-7 WES-TWA 10 ppm 25 mg/m3

NZ OEL

WES-STEL 15 ppm 37 mg/m3

NZ OEL

Acetic Acid 64-19-7 TWA 10 ppm ACGIH

STEL 15 ppm ACGIH

SAFETY DATA SHEET

Fluorodye UC

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STEL 15 ppm 37 mg/m3

NIOSH REL

TWA 10 ppm 25 mg/m3

NIOSH REL

TWA 10 ppm 25 mg/m3

OSHA Z1

Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below

occupational exposure standards. Personal protective equipment Eye protection : Safety goggles

Face-shield

Hand protection : Wear the following personal protective equipment: Standard glove type. Laminate film Nitrile Unsupported neoprene PVC Natural rubber Neoprene/natural rubber blend Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin protection : Wear suitable protective clothing.

Respiratory protection : No personal respiratory protective equipment normally required.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard.

Section: 9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance : liquid

Colour : dark

Odour : stinging

Flash point : Not applicable.

pH : 3.1, 1 - 10 %, (as aqueous solution)

Odour Threshold : no data available

Melting point/freezing point : not determined

Initial boiling point and boiling range

: ca. 100 °C

Evaporation rate : not determined

Flammability (solid, gas) : no data available

Upper explosion limit : not determined

Lower explosion limit : not determined

Vapour pressure : 15.7 hPa, (20 °C),

Relative vapour density : not determined

SAFETY DATA SHEET

Fluorodye UC

5 / 9

Relative density : 1.052 - 1.082, (20 °C),

Density : no data available

Water solubility : soluble

Solubility in other solvents : no data available

Partition coefficient: n-octanol/water

: no data available

Auto-ignition temperature : > 400 °C

Thermal decomposition temperature

: no data available

Viscosity, dynamic : ca. 50 - 100 mPa.s (20 °C)

Viscosity, kinematic : no data available

Molecular weight : no data available

VOC : no data available

Section: 10. STABILITY AND REACTIVITY

Chemical stability : Stable under normal conditions. Possibility of hazardous reactions

: Do not mix with bleach or other chlorinated products – will cause chlorine gas.

Conditions to avoid : None known. Incompatible materials : Strong acids

Strong bases Strong oxidizing agents

Hazardous decomposition products

: Decomposition products may include the following materials: Carbon oxides

Section: 11. TOXICOLOGICAL INFORMATION

Information on likely routes of exposure

: Inhalation, Eye contact, Skin contact

Potential Health Effects Eyes : Causes serious eye damage. Skin : Causes skin irritation. Ingestion : Health injuries are not known or expected under normal use. Inhalation : Health injuries are not known or expected under normal use. Chronic Exposure : May cause damage to organs through prolonged or repeated exposure. Experience with human exposure Eye contact : Redness, Pain, Corrosion Skin contact : Redness, Irritation Ingestion : No symptoms known or expected.

SAFETY DATA SHEET

Fluorodye UC

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Inhalation : No symptoms known or expected. Toxicity Product

Acute oral toxicity : Acute toxicity estimate: > 2,000 mg/kg

Acute inhalation toxicity : no data available

Acute dermal toxicity : Acute toxicity estimate: > 2,000 mg/kg

Skin corrosion/irritation : no data available

Serious eye damage/eye irritation

: no data available

Respiratory or skin sensitization

: no data available

Carcinogenicity : no data available

Reproductive effects : no data available

Germ cell mutagenicity : no data available

Teratogenicity : no data available

STOT - single exposure : no data available

STOT - repeated exposure : no data available

Aspiration toxicity : no data available

Human Hazard Characterization

Based on our hazard characterization, the potential human hazard is: High

Section: 12. ECOLOGICAL INFORMATION

Ecotoxicity Environmental Effects : This product has no known ecotoxicological effects.

Product

Toxicity to fish : no data available

Toxicity to daphnia and other aquatic invertebrates

: no data available

Toxicity to algae : no data available

Components

Toxicity to fish : Ethylene Glycol LC50 : 72,860 mg/l Exposure time: 96 h

Acetic Acid LC50 Oncorhynchus mykiss (rainbow trout): 1,000 mg/l Exposure time: 96 h

Components

Toxicity to daphnia and other aquatic invertebrates

: Ethylene Glycol EC50 : > 100 mg/l

SAFETY DATA SHEET

Fluorodye UC

7 / 9

Exposure time: 48 h

Acetic Acid EC50 Daphnia magna (Water flea): 39.6 mg/l Exposure time: 48 h

Components

Toxicity to algae : Ethylene Glycol EC50 : 6,500 mg/l Exposure time: 96 h

Acetic Acid EC50 Skeletonema costatum (marine diatom): 1,000 mg/l Exposure time: 72 h

Components

Toxicity to bacteria : Ethylene Glycol > 1,995 mg/l

Components

Toxicity to fish (Chronic toxicity)

: Ethylene Glycol NOEC: 15,380 mg/l Exposure time: 7 d

Components

Toxicity to daphnia and other aquatic invertebrates (Chronic toxicity)

: Ethylene Glycol NOEC: 8,590 mg/l Exposure time: 7 d

Persistence and degradability no data available Mobility no data available Bioaccumulative potential no data available Other information no data available ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION Based on our hazard characterization, the potential environmental hazard is: Low

Section: 13. DISPOSAL CONSIDERATIONS

Disposal methods : Where possible recycling is preferred to disposal or

incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility.

Disposal considerations : Dispose of as unused product. Empty containers should be

taken to an approved waste handling site for recycling or

SAFETY DATA SHEET

Fluorodye UC

8 / 9

disposal. Do not re-use empty containers.

Section: 14. TRANSPORT INFORMATION

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport. Land transport Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s): : Acetic Acid UN/ID No. : UN 2801 Transport hazard class(es) : 8 Packing group : III Air transport (IATA) UN/ID No. : UN 2801 Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s) : Acetic Acid Transport hazard class(es) : 8 Packing group : III Sea transport (IMDG/IMO) UN/ID No. : UN 2801 Proper shipping name : Dye, liquid, corrosive, n.o.s. Technical name(s) : Acetic Acid Transport hazard class(es) : 8 Packing group : III

Section: 15. REGULATORY INFORMATION

Standard for the Uniform Scheduling of Medicines and Poisons

: Schedule 6

INTERNATIONAL CHEMICAL CONTROL LAWS : Australia. Industrial Chemical (Notification and Assessment) Act All substances in this product comply with the National Industrial Chemicals Notification & Assessment Scheme (NICNAS).

Section: 16. OTHER INFORMATION

REFERENCES Hazardous Substances Data Bank, National Library of Medicine, Bethesda, Maryland (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO. IARC Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Man, Geneva: World Health Organization, International Agency for Research on Cancer. Integrated Risk Information System, U.S. Environmental Protection Agency, Washington, D.C. (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO. Annual Report on Carcinogens, National Toxicology Program, U.S. Department of Health and Human Services, Public Health Service.

SAFETY DATA SHEET

Fluorodye UC

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Registry of Toxic Effects of Chemical Substances, National Institute for Occupational Safety and Health, Cincinnati, OH, (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO. The Teratogen Information System, University of Washington, Seattle, WA (TOMES CPS™ CD-ROM Version), Micromedex, Inc., Englewood, CO. Revision Date : 19.02.2017 Version Number : 1.0 Prepared By : Regulatory Affairs REVISED INFORMATION: Significant changes to regulatory or health information for this revision is indicated by a bar in the left-hand margin of the SDS. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. For additional copies of an SDS visit www.nalco.com and request access.


Synonym(s) FRACSEAL F • FRACSEAL FINE • FRACSEAL M • FRACSEAL MEDIUM

DRILLING FLUID ADDITIVEUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





FRACSEAL FINE/MEDIUMProduct name








CELLULOSE 100%9004-34-6 232-674-9





Eye

Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.

Skin Exposure is considered unlikely. Skin irritation is not anticipated.

Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Due toproduct form and application, ingestion is considered unlikely.

First aid facilities No information provided.

This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are not anticipated.4.2 Most important symptoms and effects, both acute and delayed

Page 1 of 6

SDS Date: 25 Nov 2014

www.newpark.com

FRACSEAL FINE/MEDIUMPRODUCT NAME



Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition. Finely divided dust may formexplosive mixtures with air.




None allocated.

5.4 Hazchem code





Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for damage tocontainers.








Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --


Exposure standards

Biological limits


Page 2 of 6



PPE

Eye / Face When using large quantities or where heavy contamination is likely, wear dust-proof goggles.




Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.



9.1 Information on basic physical and chemical properties YELLOW TO BROWN SOLIDAppearanceODOURLESSOdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling point500°C to 518°CMelting pointNOT AVAILABLEEvaporation rate6.5 to 7.5pHNOT AVAILABLEVapour density0.9Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








Incompatible with oxidising agents (e.g. hypochlorites).





Page 3 of 6




Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. Oral LD50 (rat) is > 5000 mg/kg.Dermal LD50 (rabbit) is > 2000 mg/kg.LC50 (rat) is 510 mg/m³/2 hours.

Skin Not classified as a skin irritant.

Eye Not classified as an eye irritant. Contact may cause mild discomfort.

Sensitization This product is not known to be a skin or respiratory sensitiser.

Not classified as causing organ effects from single exposure.STOT – singleexposure

Aspiration Not relevant.


Reproductive No evidence of reproductive effects.

Carcinogenicity No evidence of carcinogenic effects.

Mutagenicity No evidence of mutagenic effects.



12.1 Toxicity









Waste disposal Reuse where possible. No special precautions are normally required when handling this product.



LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated





Page 4 of 6





Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).


Risk phrases None allocated.



Safety phrases None allocated.

Hazard codes None allocated.


Classifications


16. OTHER INFORMATIONPERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guideonly. Factors such as method of application, working environment, quantity used, productconcentration and the availability of engineering controls should be considered before final selectionof personal protective equipment is made.


ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly


Abbreviations


Page 5 of 6



DescriptionRevision

Standard SDS Review. 3.2


Converted to GHS. 3.0

Standard SDS Review 2.0

Initial SDS creation 1.0

Revision history




Report status


SDS date:

[ End of SDS ]

Revision:25 November 20143.2

Page 6 of 6



Synonym(s) CYNOPSIS TETRAGONALOBA • GUARGUM • VISCOSIFIER

EMULSIFIER • FOOD ADDITIVE • PAPER COATING • STABILISER • THICKENING AGENTUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





GUAR GUMProduct name


NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS






>90%9000-30-0 232-536-8GUAR GUM





Eye




First aid facilities Eye wash facilities and safety shower are recommended.

Page 1 of 6SDS Date: 02 Jun 2015

Version No: 2.3

www.newpark.com

GUAR GUMPRODUCT NAME

Individuals with pre-existing respiratory impairment (eg asthmatics) may be more susceptible to adverse health effects.4.2 Most important symptoms and effects, both acute and delayed

4.3 Immediate medical attention and special treatment neededTreat symptomatically. Material swells on contact with water.






None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide or water fog. Prevent contamination of drains and waterways.5.1 Extinguishing media


Wear Personal Protective Equipment (PPE) as detailed in section 8 of the SDS. Clear area of all unprotected personnel. Contactemergency services where appropriate.



Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled and tightly closed when not in use.






No exposure standards have been entered for this product.


Exposure standards


Engineering controls Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.



Version No: 2.3


PPE



Body Wear safety boots. When using large quantities or where heavy contamination is likely, wear coveralls.

Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear a ClassP3 (Particulate) respirator.


9.1 Information on basic physical and chemical properties OFF-WHITE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate6.8 - 7.5 (1.0% slurry)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold







Incompatible with oxidising agents (e.g. hypochlorites) and acids (e.g. nitric acid).








Version No: 2.3


Acute toxicity Information available for the product:This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated.


IngredientOral Toxicity

(LD50)Dermal Toxicity

(LD50)Inhalation Toxicity

(LC50)

6000 mg/kg (Hamster) -- --GUAR GUM

Skin Not classified as a skin irritant. Contact may result in mild irritation.

Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.

Sensitization This product is not classified to be a skin or respiratory sensitiser. However, individuals with pre-existingrespiratory impairment (eg asthmatics) may be more susceptible to adverse health effects.

No known effects from this product.STOT – singleexposure

Aspiration This product does not present an aspiration hazard.

No known effects from this product.STOT – repeatedexposure




Additional ingredient toxicity value(s):

GUAR GUM (9000-30-0)TDLo (oral) 228,000 mg/kg/13 weeks continuous (rat)


12.1 Toxicity






This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities. Notexpected to bioaccumulate.



Waste disposal Ensure product is covered with moist soil to prevent dust generation and dispose of to approved Councillandfill. Contact the manufacturer/supplier for additional information (if required).






Version No: 2.3


LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated













Classifications






Version No: 2.3





Abbreviations




Report status


[ End of SDS ]


Version No: 2.3

Issue Date: September 2017 SDS No: 722 Version: V.0.0.2

Page 1 of 12

TelChem Hydrochloric Acid 15%

Telford Industries

Safety Data Sheet according to WHS and ADG requirements

SECTION 1 IDENTIFICATION OF THE SUBSTANCE / MIXTURE AND OF THE COMPANY / UNDERTAKING

Product Identifier

Product name TelChem Hydrochloric Acid 15%

Chemical Name Hydrochloric Acid 15 %

Synonyms Muriatic Acid

Proper shipping name HYDROCHLORIC ACID

Chemical formula HCl

Other means of identification Not Available

Relevant identified uses of the substance or mixture and uses advised against

Relevant Identified Uses Acidising of petroleum wells, Boiler scale removal, Chemical intermediate, Ore reduction, Pickling and metal

cleaning, Alcohol denaturant, pH adjusting of swimming pool water.

Details of the supplier of the safety data sheet

Company Name Telford Industries

Address 7 Valentine Street Kewdale WA 6105 Australia

Telephone +61 8 9353 2053 / 1800 835 115

Fax +61 8 9353 2054

Website https://www.telfordindustries.com.au/

Email [email protected]

Emergency telephone number

Association/Organisation Not Available

Emergency telephone numbers 1800 774 557

Other Emergency telephone numbers 1800 SPILLS

SECTION 2 HAZARDS IDENTIFICATION

Classification of the substance or mixture

HAZARDOUS CHEMICAL. DANGEROUS GOODS. According to the WHS Regulations and the ADG Code.

Poisons Schedule S6

Classification Metal Corrosion Category 1, Acute Toxicity (Inhalation) Category 2, Skin Corrosion/Irritation Category 1A,

Serious Eye Damage Category 1

Label Elements

GHS label elements

SIGNAL WORD DANGER

https://www.telfordindustries.com.au/


Page 2 of 12

Hazard statement(s)

H290 May be corrosive to metals.

H302 Harmful if swallowed.

H314 Causes severe skin burns and eye damage.

H318 Causes serious eye damage.

H330 Fatal if inhaled.

Precautionary statement(s) Prevention

P260 Do not breathe dust/fume/gas/mist/vapours/spray.

P270 Do not eat, drink or smoke when using this product

P271 Use only outdoors or in a well-ventilated area.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P234 Keep only in original container.

P284 Wear respiratory protection.

Precautionary statement(s) Response

P301+P330+P331 IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.

P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower.

P305+P351+P338

IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and

easy to do. Continue rinsing.

P310 Immediately call a POISON CENTER or doctor/physician.

P363 Wash contaminated clothing before reuse.

P390 Absorb spillage to prevent material damage.

P304+P340 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing.

Precautionary statement(s) Storage

P403+P233 Store in a well-ventilated place. Keep container tightly closed.

P405 Store locked up.

Precautionary statement(s) Disposal

P501 Dispose of contents/container in accordance with local regulations.

SECTION 3 COMPOSITION / INFORMATION ON INGREDIENTS

Substances

CAS No % [weight] Name

7647-01-0 15 hydrochloric acid

Not Available <0.1 silica

7440-32-6 <1 titanium

7732-18-5 balance water


Page 3 of 12

SECTION 4 FIRST AID MEASURES

Description of first aid measures

Eye Contact

If this product comes in contact with the eyes:

Immediately hold eyelids apart and flush the eye continuously with running water.

Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the

eyelids by occasionally lifting the upper and lower lids.

Continue flushing until advised to stop by the Poisons Information Centre or a doctor, or for at least 15

minutes.

Transport to hospital or doctor without delay.

Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

Skin Contact

If skin or hair contact occurs:

Immediately flush body and clothes with large amounts of water, using safety shower if available.

Quickly remove all contaminated clothing, including footwear.

Wash skin and hair with running water. Continue flushing with water until advised to stop by the

Poisons Information Centre.

Transport to hospital, or doctor.

Inhalation

If fumes or combustion products are inhaled remove from contaminated area.

Lay patient down. Keep warm and rested.

Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to

initiating first aid procedures.

Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask

device, or pocket mask as trained. Perform CPR if necessary.

Transport to hospital, or doctor, without delay.

Ingestion

For advice, contact a Poisons Information Centre or a doctor at once.

Urgent hospital treatment is likely to be needed.

If swallowed do NOT induce vomiting.

If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to

maintain open airway and prevent aspiration.

Observe the patient carefully.

Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming

unconscious.

Give water to rinse out mouth, then provide liquid slowly and as much as casualty can comfortably

drink.

Transport to hospital or doctor without delay.

Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

For acute or short term repeated exposures to strong acids:

Airway problems may arise from laryngeal edema and inhalation exposure. Treat with 100% oxygen initially.

Respiratory distress may require cricothyroidotomy if endotracheal intubation is contraindicated by excessive swelling Intravenous lines should be

established immediately in all cases where there is evidence of circulatory compromise.

Strong acids produce a coagulation necrosis characterised by formation of a coagulum (eschar) as a result of the dessicating action of the acid on proteins

in specific tissues.

INGESTION:

Immediate dilution (milk or water) within 30 minutes post ingestion is recommended.

DO NOT attempt to neutralise the acid since exothermic reaction may extend the corrosive injury.

Be careful to avoid further vomit since re-exposure of the mucosa to the acid is harmful. Limit fluids to one or two glasses in an adult.

Charcoal has no place in acid management.

Some authors suggest the use of lavage within 1 hour of ingestion.

SKIN:

Skin lesions require copious saline irrigation. Treat chemical burns as thermal burns with non-adherent gauze and wrapping.

Deep second-degree burns may benefit from topical silver sulfadiazine.

EYE:

Eye injuries require retraction of the eyelids to ensure thorough irrigation of the conjuctival cul-de-sacs. Irrigation should last at least 20-30 minutes.

DO NOT use neutralising agents or any other additives. Several litres of saline are required.

Cycloplegic drops, (1% cyclopentolate for short-term use or 5% homatropine for longer term use) antibiotic drops, vasoconstrictive agents or artificial tears

may be indicated dependent on the severity of the injury.

Steroid eye drops should only be administered with the approval of a consulting ophthalmologist).

[Ellenhorn and Barceloux: Medical Toxicology]


Page 4 of 12

SECTION 5 FIREFIGHTING MEASURES

Extinguishing Media

Water spray or fog

Foam

Special hazards arising from the substrate or mixture

Fire Incompatibility None known.

Advice for firefighters

Fire Fighting

Alert Fire Brigade and tell them location and nature of hazard.

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Use fire fighting procedures suitable for surrounding area.

Do not approach containers suspected to be hot.

Cool fire exposed containers with water spray from a protected location.

If safe to do so, remove containers from path of fire.

Equipment should be thoroughly decontaminated after use.

May evolve toxic gases (chlorine) when heated to decomposition.

Fire/Explosion Hazard

Non combustible.

Not considered to be a significant fire risk.

Acids may react with metals to produce hydrogen, a highly flammable and explosive gas.

Heating may cause expansion or decomposition leading to violent rupture of containers.

May emit corrosive, poisonous fumes. May emit acrid smoke.

Decomposition may produce toxic fumes of:

hydrogen chloride

HAZCHEM 2R

SECTION 6 ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

See section 8

Environmental precautions

See section 12

Methods and material for containment and cleaning up

Minor Spills

Drains for storage or use areas should have retention basins for pH adjustments and dilution of spills

before discharge or disposal of material.

Check regularly for spills and leaks.

Clean up all spills immediately.

Avoid breathing vapours and contact with skin and eyes.

Control personal contact with the substance, by using protective equipment.

Contain and absorb spill with sand, earth, inert material or vermiculite.

Wipe up.

Place in a suitable, labelled container for waste disposal.

Major Spills

Chemical Class: acidic compounds, inorganic

For release onto land: recommended sorbents listed in order of priority.

SORBENT TYPE

RANK

APPLICATION

COLLECTION

LIMITATIONS


Page 5 of 12

LAND SPILL – SMALL

foamed glass - pillows 1 throw pitchfork R, P, DGC, RT

expanded mineral - particulate 2 shovel shovel R, I, W, P, DGC

foamed glass - particulate 2 shovel shovel R, W, P, DGC

LAND SPILL – MEDIUM

expanded mineral -particulate 1 blower skiploader R, I, W, P, DGC

foamed glass- particulate 2 blower skiploader R, W, P, DGC

foamed glass - particulate 3 throw skiploader R, W, P, DGC

Legend

DGC: Not effective where ground cover is dense

R; Not reusable

I: Not incinerable

P: Effectiveness reduced when rainy

RT: Not effective where terrain is rugged

SS: Not for use within environmentally sensitive sites W: Effectiveness reduced when windy

Reference: Sorbents for Liquid Hazardous Substance Cleanup and Control;

R.W Melvold et al: Pollution Technology Review No. 150: Noyes Data Corporation 1988

Clear area of personnel and move upwind.

Alert Fire Brigade and tell them location and nature of hazard.

Wear full body protective clothing with breathing apparatus.

Prevent, by any means available, spillage from entering drains or water course.

Stop leak if safe to do so.

Contain spill with sand, earth or vermiculite.

Collect recoverable product into labelled containers for recycling.

Neutralise/decontaminate residue (see Section 13 for specific agent).

Collect solid residues and seal in labelled drums for disposal.

Wash area and prevent runoff into drains.

After clean up operations, decontaminate and launder all protective clothing and equipment before

storing and re-using.

If contamination of drains or waterways occurs, advise emergency services.

Personal Protective Equipment advice is contained in Section 8 of the SDS.

SECTION 7 HANDLING AND STORAGE

Precautions for safe handling

Safe handling

DO NOT allow clothing wet with material to stay in contact with skin

Avoid all personal contact, including inhalation.

Wear protective clothing when risk of exposure occurs.

Use in a well-ventilated area.

WARNING: To avoid violent reaction, ALWAYS add material to water and NEVER water to material.

Avoid smoking, naked lights or ignition sources.

Avoid contact with incompatible materials.

When handling, DO NOT eat, drink or smoke.

Keep containers securely sealed when not in use.

Avoid physical damage to containers.

Always wash hands with soap and water after handling.

Work clothes should be laundered separately. Launder contaminated clothing before re -use.

Use good occupational work practice.

Observe manufacturer's storage and handling recommendations contained within this SDS.

Atmosphere should be regularly checked against established exposure standards to ensure safe

working conditions are maintained.

Other Information

Store in original containers.

Keep containers securely sealed.

Store in a cool, dry, well-ventilated area.

Store away from incompatible materials and foodstuff containers.

Protect containers against physical damage and check regularly for leaks.

Observe manufacturer's storage and handling recommendations contained within this SDS.


Page 6 of 12

Conditions for safe storage, including any incompatibilities

Suitable Container

DO NOT use aluminium or galvanised containers

Check regularly for spills and leaks

Lined metal can, lined metal pail/ can.

Plastic pail.

Polyliner drum.

Packing as recommended by manufacturer.

Check all containers are clearly labelled and free from leaks.

Storage Incompatibility

Inorganic acids neutralise chemical bases (for example: amines and inorganic hydroxides) to form salts

- neutralisation can generate dangerously large amounts of heat in small spaces.

The dissolution of inorganic acids in water or the dilution of their concentrated solutions with additional

water may generate significant heat.

The addition of water to inorganic acids often generates sufficient heat in the small region of mixing to

cause some of the water to boil explosively. The resulting "bumping" can spatter the acid.

Inorganic acids react with active metals, including such structural metals as aluminum and iron, to

release hydrogen, a flammable gas.

Inorganic acids react with cyanide compounds to release gaseous hydrogen cyanide.

Inorganic acids generate flammable and/or toxic gases in contact with dithiocarbamates, isocyanates,

mercaptans, nitrides, nitriles, sulfides, and strong reducing agents. Additional gas-generating reactions

occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and even carbonates.

Reacts vigorously with alkalis.

Reacts with mild steel, galvanised steel / zinc producing hydrogen gas which may form an explosive

mixture with air.

Contact with acids, organics, reducing agents (eg. amines), metallic powders and heat sources

produces toxic fumes of chlorine. May be decomposed by hot water releasing chlorine fumes.

SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION

Control parameters

OCCUPATIONAL EXPOSURE LIMITS (OEL)

INGREDIENT DATA

Source Ingredient Material Name TWA STEL Peak Notes

Australia Exposure

Standards

hydrochloric acid Hydrogen chloride Not

Available

Not Available 7.5 mg/m3 /

5ppm

Not Available

Australia Exposure

Standards

titanium Fume (thermally generated)

(respirable dust)

2 mg/m3 Not Available Not Available Not Available

EMERGENCY LIMITS

Ingredient Material Name TEEL-1 TEEL-2 TEEL-3

hydrochloric acid Hydrogen chloride; (Hydrochloric acid) Not Available Not Available Not Available

hydrochloric acid Deuterochloric acid; (Deuterium chloride) 1.8 ppm 22 ppm 100 ppm

titanium Titanium 30 mg/m3 330 mg/m3 2,000 mg/m3

Ingredient Original IDLH Revised IDLH

hydrochloric acid 100 ppm 50 ppm

silica Not Available Not Available

titanium Not Available Not Available

water Not Available Not Available

MATERIAL DATA

Exposure controls

Appropriate engineering

controls

Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-

designed engineering controls can be highly effective in protecting workers and will typically be independent of

worker interactions to provide this high level of protection.


Page 7 of 12

Personal Protection

Eye and Face protection

Safety glasses with imperforated side shields may be used where continuous eye protection is

desirable, as in laboratories; spectacles are not sufficient where complete eye protection is needed

such as when handling bulk-quantities, where there is a danger of splashing, or if the material may be

under pressure.

Chemical goggles whenever there is a danger of the material coming in contact with the eyes; goggles

must be properly fitted.

Full face shield (20 cm, 8 in minimum) may be required for supplementary but never for pr imary

protection of eyes.

Alternatively a gas mask may replace splash goggles and face shields.

Skin protection See Hand protection below

Hands/feet protection

Elbow length PVC gloves

Wear chemical protective gloves, e.g. PVC.

Wear safety footwear or safety gumboots, e.g. Rubber

When handling corrosive liquids, wear trousers or overalls outside of boots, to avoid spills entering

boots.

Select gloves tested to a relevant standard (e.g. Europe EN 374, US F739, AS/NZS 2161.1 or national

equivalent).

Body protection See Other protection below

Other protection

Overalls.

PVC Apron.

PVC protective suit may be required if exposure severe.

Eyewash unit.

Ensure there is ready access to a safety shower.

Thermal hazards Not Available

Respiratory protection

Type B-P Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance Colourless to slightly yellow corrosive liquid with a pungent acidic odour; miscible with water.

Physical state Liquid Flash point (°C) Not Applicable

Odour Not Available Evaporation rate Not Available

Odour threshold Not Available Flammability Not Applicable

Relative density (water=1) 1.07 – 1.08 Upper Explosive Limit (%) Not Applicable

Colour Colourless - slightly yellow Lower Explosive Limit (%) Not Applicable

pH (as supplied) < 1 Vapour pressure (kPa) Not Available

Melting point/Freezing point

(°C) < 0 Solubility in water (g/L) Miscible

Initial boiling point and

boiling range (°C) > 100 Vapour density (Air = 1) Not Available

SECTION 10 STABILITY AND REACTIVITY

Reactivity See section 7

Chemical stability Contact with alkaline material liberates heat

Possibility of hazardous

reactions

See section 7

Conditions to avoid See section 7

Incompatible materials See section 7


Page 8 of 12

Hazardous decomposition

products

See section 5

SECTION 11 TOXICOLOGICAL INFORMATION

Information on toxicological effects

Inhaled

Acidic corrosives produce respiratory tract irritation with coughing, choking and mucous membrane damage.

Symptoms of exposure may include dizziness, headache, nausea and weakness. Hydrogen chloride (HCl) vapour

or fumes present a hazard from a single acute exposure. Exposures of 1300 to 2000 ppm have been lethal to

humans in a few minutes. Inhalation of aerosols (mists, fumes), generated by the material during the course of

normal handling, may produce toxic effects; these may be fatal.

Inhalation of the vapour is hazardous and may even be fatal.

Ingestion

Ingestion of acidic corrosives may produce circumoral burns with a distinct discolouration of the mucous

membranes of the mouth, throat and oesophagus. Immediate pain and difficulties in swallowing and speaking may

also be evident.

Skin Contact

Skin contact with acidic corrosives may result in pain and burns; these may be deep with distinct edges and may

heal slowly with the formation of scar tissue.

Skin contact with the material may damage the health of the individual; systemic effects may result follow ing

absorption. Open cuts, abraded or irritated skin should not be exposed to this material

Entry into the blood-stream through, for example, cuts, abrasions, puncture wounds or lesions, may produce

systemic injury with harmful effects. Examine the skin prior to the use of the material and ensure that any external

damage is suitably protected.

Eye

When applied to the eye(s) of animals, the material produces severe ocular lesions which are present twenty -four

hours or more after instillation.

Direct eye contact with acid corrosives may produce pain, lachrymation, photophobia and burns. Mild burns of the

epithelia generally recover rapidly and completely. Severe burns produce long-lasting and possible irreversible

damage. The appearance of the burn may not be apparent for several weeks after the initial contact. The cornea

may ultimately become deeply vascularised and opaque resulting in blindness.

Chronic

Repeated or prolonged exposure to acids may result in the erosion of teeth, inflammatory and ulcerative changes

in the mouth and necrosis (rarely) of the jaw. Bronchial irritation, with cough, and frequent attacks of bronchial

pneumonia may ensue.

Limited evidence suggests that repeated or long-term occupational exposure may produce cumulative health

effects involving organs or biochemical systems.

Chronic minor exposure to hydrogen chloride (HCl) vapour or fume may cause discolouration or erosion of the

teeth, bleeding of the nose and gums; and ulceration of the nasal mucous membranes.

Repeated exposures of animals to concentrations of about 34 ppm HCl produced no immediate toxic effects.

Workers exposed to hydrochloric acid suffered from gastritis and a number of cases of chronic bronchitis have

also been reported.

Repeated or prolonged exposure to dilute solutions of HCl may cause dermatitis.

Product Name TOXICITY IRRITATION

TelChem Hydrochloric

Acid 15 %

Not Available Not Available

hydrochloric acid Inhalation (rat) LC50: 3124 ppm/1hr[2]

Oral (rat) LD50: 900 mg/kg[2]

Eye (rabbit): 5mg/30s - mild

titanium Oral (rat) LD50: >2000 mg/kg[1] Not Available

Water Oral (rat) LD50: >90000 mg/kg[2] Not Available

1. Value obtained from Europe ECHA Registered Substances - Acute toxicity 2.* Value obtained from manufacturer's SDS. Unless otherwise specified data extracted from RTECS -

Register of Toxic Effect of chemical Substances

HYDROCHLORIC ACID

Asthma-like symptoms may continue for months or even years after exposure to the material ceases. This may be

due to a non-allergenic condition known as reactive airways dysfunction syndrome (RADS) which can occur

following exposure to high levels of highly irritating compound.

For acid mists, aerosols, vapours;

Data from assays for genotoxic activity in vitro suggest that eukaryotic cells are susceptible to genetic damage

when the pH falls to about 6.5. Cells from the respiratory tract have not been examined in this respect.

The material may be irritating to the eye, with prolonged contact causing inflammation. Repeated or prolonged

exposure to irritants may produce conjunctivitis.

The substance is classified by IARC as Group 3: NOT classifiable as to its carcinogenicity to humans.

Evidence of carcinogenicity may be inadequate or limited in animal testing.

HYDROCHLORIC ACID &

TITANIUM & WATER No significant acute toxicological data identified in literature search.


Page 9 of 12

Acute Toxicity Carcinogenicity

Skin Irritation/Corrosion Reproductivity

Serious Eye

Damage/Irritation

STOT – single exposure

Respiratory or Skin

sensitisation

STOT – repeated exposure

Mutagenicity

Aspiration Hazard

Legend: – Data available but does not fill the criteria for classification

– Data required to make classification available

– Data Not Available to make classification

SECTION 12 ECOLOGICAL INFORMATION

Toxicity

Ingredient Endpoint Test Duration (hr) Species Value Source

hydrochloric acid LC50 96 Fish 70.057mg/L 3

hydrochloric acid EC50 96 Algae or other aquatic plants 344.947mg/L 3

hydrochloric acid EC50 9.33 Fish 0.014000mg/L 4

hydrochloric acid NOEC 0.08 Fish 10mg/L 4

titanium EC50 4.5 Algae or other aquatic plants >100mg/L 2

titanium NOEC 48 Crustacean 1mg/L 2

Legend:

Extracted from 1. IUCLID Toxicity Data 2. Europe ECHA Registered Substances - Ecotoxicological Information - Aquatic Toxicity 3. EPIWIN

Suite V3.12 - Aquatic Toxicity Data (Estimated) 4. US EPA, Ecotox database - Aquatic Toxicity Data 5. ECETOC Aquatic Hazard

Assessment Data 6. NITE (Japan) - Bioconcentration Data 7. METI (Japan) - Bioconcentration Data 8. Vendor Data

Ecotoxicity

Prevent, by any means available, spillage from entering drains or water courses.

DO NOT discharge into sewer or waterways.

Persistence and degradability

Ingredient Persistence: Water/Soil Persistence: Air

hydrochloric acid LOW LOW

water LOW LOW

Bio accumulative potential

Ingredient Bioaccumulation

hydrochloric acid LOW (Log KOW = 0.5392)

water LOW (Log KOW = -1.38)

Mobility in Soil

Ingredient Mobility

hydrochloric acid LOW (KOC = 14.3)

water LOW (KOC = 14.3)


Page 10 of 12

SECTION 13 DISPOSAL CONSIDERATIONS

Waste treatment methods

Product/Packaging disposal

Containers may still present a chemical hazard/ danger when empty.

Return to supplier for reuse/ recycling if possible.

Otherwise:

If container can’t be cleaned sufficiently well to ensure that residuals do not remain or if the container

cannot be used to store the same product, then puncture containers, to prevent re-use, and bury at an

authorised landfill.

Where possible retain label warnings and SDS and observe all notices pertaining to the product.

Recycle wherever possible.

Consult manufacturer for recycling options or consult local or regional waste management authority for

disposal if no suitable treatment or disposal facility can be identified.

Treat and neutralise at an approved treatment plant. Treatment should involve: Neutralisation with soda -ash

or soda-lime followed by: burial in a land-fill specifically licensed to accept chemical and / or pharmaceutical

wastes or incineration in a licensed apparatus (after admixture with suitable combustible material).

Decontaminate empty containers with 5% aqueous sodium hydroxide or soda ash, followed by water.

Observe all label safeguards until containers are cleaned and destroyed.

SECTION 14 TRANSPORT INFORMATION

Labels Required

Marine Pollutant NO

HAZCHEM 2R

Land transport (ADG)

UN Number 1789

UN proper shipping name HYDROCHLORIC ACID

Transport Hazard class(es) Class 8

Sub Risk Not Applicable

Packing group II

Environmental Hazard Not Applicable

Special precautions for user Special provisions Not Applicable

Limited quantity 1 L

Air transport (ICAO-IATA / DGR)

UN Number 1789


Transport Hazard class(es) ICAO/IATA Class 8

ICAO/IATA Sub Risk Not Applicable

Packing group II


Special precautions for user

Special provisions Not Applicable

Cargo Only Packing Instructions Not Available

Cargo Only Maximum Qty/Pack Not Available

Passenger and Cargo Packing Instructions 851

Passenger and Cargo Maximum Qty/Pack 1 L


Page 11 of 12

Passenger and Cargo Limited Quantity Packing Instructions Y840

Passenger and Cargo Limited Maximum Qty / Pack 0.5 L

Sea transport (IMDG-Code / GGVSee)

UN Number 1789


Transport Hazard class(es) IMDG Class 8

IMDG Sub Risk Not Applicable

Packing group II


Special precautions for user EMS, Fire F-A

EMS, Spillage S-B

Transport in bulk according to Annex II of MARPOL and the IBC code

Source Product Name Pollution Category Ship Type

IMO MARPOL (Annex II) – List of Noxious Liquid

Substances Carried in Bulk

Hydrochloric acid

Z

3

SECTION 15 REGULATORY INFORMATION

Safety, health and environmental regulations / legislation specific for the substance or mixture

HYDROCHLORIC ACID (7647-01-0) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Exposure Standards

Australia Inventory of Chemical Substances (AICS)

Australia Hazardous Substances Information System - Consolidated Lists

TITANIUM (7440-32-6) IS FOUND ON THE FOLLOWING REGULATORY LISTS

Australia Exposure Standards

International Air Transport Association (IATA) Dangerous Goods Regulations Prohibited List Passenger and Cargo Aircraft


WATER (7732-18-5) IS FOUND ON THE FOLLOWING REGULATORY LISTS


National Inventory

Status

Australia - AICS Y

Canada - DSL Y

Canada - NDSL N (titanium; hydrochloric acid; water)

China - IECSC Y

Europe - EINEC / ELINCS / NLP Y

Japan - ENCS N (titanium; water)

Korea - KECI Y

New Zealand - NZIoC Y

Philippines - PICCS Y

USA - TSCA Y

Legend:

Y = All ingredients are on the inventory

N = Not determined or one or more ingredients are not on the inventory and are not exempt from listing(see

specific ingredients in brackets)


Page 12 of 12

SECTION 16 OTHER INFORMATION

The SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether th e reported Hazards are risks in

the workplace or other settings. Risks may be determined by reference to Exposures Scenarios. Scale of use, frequency of use and current or available engineering

controls must be considered.

Definitions and abbreviations

Name CAS No

PC－TWA Permissible Concentration-Time Weighted Average PC－STEL Permissible Concentration-Short Term Exposure Limit

IARC International Agency for Research on Cancer ACGIH American Conference of Governmental Industrial Hygienists

STEL Short Term Exposure Limit TEEL Temporary Emergency Exposure Limit

IDLH Immediately Dangerous to Life or Health Concentrations OSF Odour Safety Factor

NOAEL No Observed Adverse Effect Level LOAEL Lowest Observed Adverse Effect Level

TLV Threshold Limit Value LOD Limit Of Detection

OTV Odour Threshold Value BCF BioConcentration Factors

BEI Biological Exposure Index

END OF SDS


Synonym(s) IDCIDE 20

BIOCIDE • DRILLING FLUID ADDITIVE • WATER TREATMENTUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





IDCIDE-20Product name



2.2 Label elements

Signal word WARNING

IF ON SKIN: Wash with plenty of soap and water.P302 + P352IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy todo. Continue rinsing.

P305 + P351 + P338

Specific treatment is advised - see first aid instructions.P321If skin irritation or rash occurs: Get medical advice/attention.P333 + P313Take off contaminated clothing and wash before re-use.P362


Avoid breathing dust/fume/gas/mist/vapours/spray.P261Wash thoroughly after handling.P264Contaminated work clothing should not be allowed out of the workplace.P272Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes skin irritation.H315May cause an allergic skin reaction.H317Causes serious eye irritation.H319

Hazard statement(s)

Pictograms

Skin Sensitization: Category 1Skin Corrosion/Irritation: Category 2Serious Eye Damage / Eye Irritation: Category 2A

GHS classification


Page 1 of 7

SDS Date: 28 Jul 2014

www.newpark.com

IDCIDE-20PRODUCT NAME


Dispose of contents/container in accordance with relevant regulations.P501Disposal statement(s)



Ingredient Identification Classification Content GHS Risk

TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE

CAS: 55566-30-8EC: 259-709-0

18 to 25%Not Available Not Available

WATER CAS: 7732-18-5EC: 231-791-2

RemainderNot Available Not Available





Eye




First aid facilities Eye wash facilities should be available.




Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides, sulphur oxides and phosphates when heated todecomposition.


Treat as per requirements for surrounding fires. Evacuate area and contact emergency services. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire. Usewaterfog to cool intact containers and nearby storage areas.


None allocated.

5.4 Hazchem code



Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area wherepossible.


Page 2 of 7




Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.




Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use.








Exposure standards

Biological limits


PPE

Eye / Face Wear a faceshield and splash-proof goggles.


Body Not required under normal conditions of use.

Respiratory Not required under normal conditions of use.

Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.



9.1 Information on basic physical and chemical properties COLOURLESS TO PALE YELLOW LIQUIDAppearanceSLIGHT ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point> 100°CBoiling point< 0°CMelting pointAS FOR WATEREvaporation rate3.0 to 3.5pHNOT AVAILABLEVapour density1.08Specific gravitySOLUBLESolubility (water)

Page 3 of 7



9.1 Information on basic physical and chemical properties 18 mm Hg @ 20°CVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

9.2 Other information> 60 % (Water)% Volatiles







Incompatible with oxidising agents (eg. hypochlorites) and acids (eg. nitric acid).

May evolve carbon oxides, sulphur oxides and phosphates when heated to decomposition.10.6 Hazardous decomposition products





Eye Irritant. Contact may result in irritation, lacrimation, pain and redness.

Inhalation Low to moderate irritant. Over exposure to vapours may result in irritation of the nose and throat, withcoughing. High level exposure may result in dizziness, nausea and headache. Due to the low vapourpressure, an inhalation hazard is not anticipated with normal use.

Skin Irritant. Contact may result in irritation. May cause sensitisation by skin contact.

Ingestion May be harmful. Ingestion may result in gastrointestinal irritation, nausea, vomiting, abdominal pain anddiarrhoea.

May be harmful - irritant. This product has the potential to cause adverse health effects with over exposure.Upon dilution, the potential for adverse health effects may be reduced.

Health hazardsummary


Toxicity data TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8)LD50 (ingestion) 248 mg/kg (rat)TDLo (ingestion) 650 mg/kg/13 weeks - intermittent (rat)

Page 4 of 7




12.1 Toxicity

75% TETRAKIS(HYDROXYMETHYL)PHOSPHONIUM SULPHATE (55566-30-8):LC50 (Rainbow Trout) = 119 mg/L/96 hrLC50(Bluegill Sunfish) = 93 mg/L/ 96 hrEC50 (Daphnia Magna) = 19 mg/L/48 hrLC50 (Brown Shrimp) = 340 mg/L/96 hrLC50 (Mysid Shrimp ) = 9.5 mg/L/96 hrLC50 (Sheepshead Minnow) = 94 mg/L/96 hrLC50 (Jevenile Plaice) = 86 mg/L/96 hr

Waste Water managementEC50 (Activated Sludge) = 24 mg/L/3 hr

12.2 Persistence and degradabilityThis product is readily biodegradable.







Waste disposal For small amounts, absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Forlarger amounts, contact the manufacturer for additional information. Prevent contamination of drains orwaterways as aquatic life may be threatened and environmental damage may result.



LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated










Classifications


Page 5 of 7



R36/38 Irritating to eyes and skin.R43 May cause sensitisation by skin contact.

Risk phrases



S23 Do not breathe gas/fumes/vapour/spray (where applicable).S24/25 Avoid contact with skin and eyes.S36 Wear suitable protective clothing.

Safety phrases

Xi IrritantHazard codes


EXPOSURE CONTROL: If utilised in a closed system the potential for over exposure is reduced. Ifnot used in a closed system, local exhaust ventilation is recommended to control exposure. Provideeye wash and safety shower in close proximity to points of potential exposure. Where the potentialfor an inhalation risk exists, an approved respirator may be required. Do not eat, store, consumefood, tobacco or drink in areas where product is used.




ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average

Abbreviations


Page 6 of 7



DescriptionRevision



Revision history




Report status


SDS date:

[ End of SDS ]

Revision:28 July 20142

Page 7 of 7



Synonym(s) KCL • MURIATE OF POTASH • POTASH • SYLVITE

DRILLING FLUID ADDITIVE • FERTILISER • INHIBITORUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





POTASSIUM CHLORIDEProduct name


NOT CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS






POTASSIUM CHLORIDE >97%7447-40-7 231-211-8





Eye





Page 1 of 6SDS Date: 16 Apr 2015

Version No: 2.1

www.newpark.com

POTASSIUM CHLORIDEPRODUCT NAME

Adverse effects not expected from this product under normal conditions of use.4.2 Most important symptoms and effects, both acute and delayed



Non flammable. May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code





Contain spillage, then collect and place in suitable containers for disposal. Avoid generating dust.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use.








Exposure standards

Biological limits





Version No: 2.1


PPE

Eye / Face At high dust levels, wear dust-proof goggles.

Hands With prolonged use, wear PVC or rubber or cotton gloves.

Body With prolonged use, wear coveralls.

Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.


9.1 Information on basic physical and chemical properties WHITE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash point1413°CBoiling point773°CMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density2.0Specific gravity340 g/L @ 20°CSolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








Incompatible (potentially explosive) with oxidising agents (e.g. hypochlorites).

May evolve toxic gases (potassium oxides, chlorides) when heated to decomposition.10.6 Hazardous decomposition products

Polymerization will not occur.




Acute toxicity May be harmful if swallowed. Oral Toxicity: An oral LD50 in rats of 2600 mg/kg was reported for potassiumchloride. Additional toxicity data for potassium chloride:LD50 (Intraperitoneal): 620 mg/kg (mouse)LD50 (Intravenous): 117 mg/kg (mouse)LDLo (Ingestion): 20 mg/kg (man)



Version No: 2.1


LDLo (Intraperitoneal): 900 mg/kg (guinea pig)LDLo (Intravenous): 77 mg/kg (guinea pig)LDLo (Subcutaneous): 2120 mg/kg (frog)TDLo (Ingestion): 60 mg/kg/days (woman)

Skin Not classified as a skin irritant. Contact may result in mild irritation and rash.

Eye Not classified as an eye irritant. Contact may cause mild irritation and lacrimation.


Acute potassium poisoning via ingestion is rare as a large single dose usually induces vomiting, andpotassium is rapidly excreted by the body, however this product does have the potential to causecardiovascular disorders.


Aspiration Not relevant.






12.1 Toxicity

In short-term acute toxicity tests with fish, daphnia and algae the following results were found (lowest test result values): Ictaluruspunctulus 48h-LC50 = 720 mg/l; Daphnia magna: 48h-LC50 = 177 mg/l; Nitzschia linearis: 120 h-EC50 = 1337 mg/l. A chronicreproductive test with the invertebrate Daphnia magna gave a LOEC of 101 mg/l. All the studies compiled on the acute and chronicaquatic toxicity were > 100 mg/L. Thus it is concluded that KCl is not hazardous to freshwater organisms. Taking into considerationsthe background concentrations of KCl in seawater (380 mg/l K+ and 19,000 mg/l Cl-), it is concluded that there is no reason for furtherinvestigations of KCl on marine species. The low concern for the environment is supported by the absence of a bioaccumulationpotential for the substance.

12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.


No impact if small amount is released to the soil.



12.3 Bioaccumulative potentialDoes not bioaccumulate.


Waste disposal Collect and place in sealable containers and dispose of to an approved landfill site. Contact themanufacturer/supplier for additional information (if required).



LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated





Version No: 2.1













Classifications








Version No: 2.1





Abbreviations




Report status


[ End of SDS ]


Version No: 2.1


NEWPAC RD ● POLICELL RG ● RHEOPAC LV ● RHEOPAC R ● RHEOPAC R/LV/UL/RD/LVD ● RHEOPACUL

Synonym(s)

DRILLING FLUID ADDITIVEUse(s)1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax





NEWPAC LV/RDProduct name








>88%9004-32-4 618-378-6SODIUM CARBOXYMETHYL CELLULOSE

<1.8%7647-14-5 231-598-3SODIUM CHLORIDE

<10%7732-18-5 231-791-2WATER

<0.7%2836-32-0 212-730-9SODIUM GLYCOLATE





Eye


If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.

Ingestion

SDS Date: 07 Dec 2016


www.newpark.com

NEWPAC LV/RDPRODUCT NAME

None allocated.First aid facilities








None allocated.

5.4 Hazchem code
















Exposure standards


Biological limitsNo biological limit values have been entered for this product.




PPE





Avoid inhalation. Use in well ventilated areas. Maintain dust levels below the recommended exposurestandard.



9.1 Information on basic physical and chemical propertiesWHITE OR YELLOWISH POWDER/GRANULESAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate6.0 to 8.5 (1 % solution)pHNOT AVAILABLEVapour densityNOT AVAILABLESpecific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold
















This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated.Toxicity Data available on the ingredients:SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4)LD50 (Ingestion): 16000 mg/kg (guinea pig)LD50 (Skin): > 2000 mg/kg (rabbit)TDLo (Ingestion): 140 mg/kg (rat)SODIUM CHLORIDE (7647-14-5)LC50 (Inhalation): > 42000 mg/m3/1 hour (rat)LD50 (Ingestion): 3000 mg/kg (rat)LD50 (Intraperitoneal): 2602 mg/kg (mouse)LD50 (Intravenous): 645 mg/kg (mouse)LD50 (Skin): > 10000 mg/kg (rabbit)LD50 (Subcutaneous): 3000 mg/kg (mouse)LDLo (Ingestion): 8000 mg/kg (rabbit)LDLo (Intravenous): 300 mg/kg (guinea pig)LDLo (Subcutaneous): 2160 mg/kg (guinea pig)TDLo (Ingestion): 12357 mg/kg (human)SODIUM GLYCOLATE (2836-32-0)LD50 (Ingestion): 6700 mg/kg (mouse) LDLo (Ingestion): 500 mg/kg (cat)

Acute toxicity


IngredientOral Toxicity (LD50) Dermal Toxicity (LD50) Inhalation Toxicity

(LC50)

16000 mg/kg (guinea > 2000 mg/kg (rabbit) --SODIUM CARBOXYMETHYL CELLULOSE

3000 mg/kg (rat) > 10000 mg/kg (rabbit) > 42000 mg/m³/1 hourSODIUM CHLORIDE

6700 mg/kg (mouse) -- --SODIUM GLYCOLATE

Not classified as a skin irritant. Contact may result in mild irritation.Skin

Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye


Not classified as causing organ damage from single exposure.STOT – singleexposure


Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure

No relevant or reliable studies were identified.Reproductive

No evidence of carcinogenic effects.Carcinogenicity

No evidence of mutagenic effects.Mutagenicity


SODIUM CARBOXYMETHYL CELLULOSE (9004-32-4)TDLo (oral) 140 mg/kg (rat)

SODIUM CHLORIDE (7647-14-5)LD50 (intraperitoneal) 2602 mg/kg (mouse)LD50 (intravenous) 645 mg/kg (mouse)LD50 (subcutaneous) 3000 mg/kg (mouse)LDLo (intravenous) 300 mg/kg (guinea pig)LDLo (oral) 8000 mg/kg (rabbit)LDLo (subcutaneous) 2160 mg/kg (guinea pig)TDLo (oral) 12357 mg/kg (human)

SODIUM GLYCOLATE (2836-32-0)LDLo (oral) 500 mg/kg (cat)






12.1 Toxicity

LC50 (Fresh Water Trout) > 21,000 ppm/96hrs.LC50 (Salt Water Stickel Back) > 56,000 ppm/96hrs.




This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.






Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number










Poison schedule








Classifications







HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a report whichwould encompass all possible scenarios, it is anticipated that users will assess the risks and applycontrol methods where appropriate.




Abbreviations




Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au.

Prepared by





[ End of SDS ]




Synonym(s) QUICKSEAL

DRILLING FLUID ADDITIVEUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





QUICKSEAL (F,M,C)Product name








CELLULOSE 100%9004-34-6 232-674-9





Eye


Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.




Page 1 of 6


www.newpark.com

QUICKSEAL (F,M,C)PRODUCT NAME



Combustible. May evolve carbon oxides and hydrocarbons when heated to decomposition. Dust may form explosive mixtures with air.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.Difficult to extinguish once burning.


None allocated.

5.4 Hazchem code





Moisten with water to prevent a dust hazard and place in sealable containers for disposal.6.3 Methods of cleaning up



Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are labelled, protected from light, freezing or physical damage and tightly sealed when not in use. Keep out of reach ofchildren.








Cellulose (paper fibre) (a) SWA (AUS) -- 10 -- --


Exposure standards


Engineering controls Avoid inhalation. Use in well ventilated areas.8.2 Exposure controls

Page 2 of 6



PPE






9.1 Information on basic physical and chemical properties YELLOW TO BROWN SOLIDAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT AVAILABLEFlash pointNOT RELEVANTBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate7 to 8pHNOT AVAILABLEVapour density0.9 - 1.2Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








Incompatible with calcium oxides, bleaching powder, perchlorates, perchloric acid, sodium chlorate, fluorine, nitric acid, sodium nitrateand sodium nitrite.





Page 3 of 6




Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. Acute Oral Toxicity: LD50 (oral) > 5000 mg/kg (rats).Acute Dermal Toxicity: LD50 (dermal) > 2000 mg/kg (rats).Acute Inhalation Toxicity: LC50 (Inhalation) = 5800 mg/m3/4hrs (rat).

Skin Not classified as a skin irritant. Contact may result in mechanical irritation, redness and rash.

Eye Not classified as an eye irritant. However, this product may cause mechanical eye irritation with redness andlacrimation.


Not classified as causing organ effects from single exposure.STOT – singleexposure








12.1 Toxicity

Low toxicity to aquatic organisms.

12.2 Persistence and degradabilityThis product is readily biodegradable.





12.3 Bioaccumulative potentialThis product is not expected to bioaccumulate.


Waste disposal Reuse where possible. No special precautions are normally required when handling this product.



LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated





Page 4 of 6













Classifications







Abbreviations


Page 5 of 6



DescriptionRevision



Provided Ingredient CAS No. 2.1



Revision history




Report status


SDS date:

[ End of SDS ]

Revision:13 February 20152.3

Page 6 of 6



Synonym(s) SUPER ABSORBENT POLYMER

ABSORBENT • LOSS CIRCULATION MATERIALUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





RHEOPLUG ULTRAProduct name








POLYACRYLIC POLYMER >95%- -





Eye





Page 1 of 6


www.newpark.com

RHEOPLUG ULTRAPRODUCT NAME




Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides and sodium oxides when heated todecomposition.




None allocated.

5.4 Hazchem code

















Exposure standards

Biological limits


Page 2 of 6



PPE




Respiratory At high dust levels, wear a Class P1 (Particulate) respirator.




9.1 Information on basic physical and chemical properties WHITE POWDERAppearanceFAINT CHARACTERISTIC ODOUROdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density0.8Specific gravityINSOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold









May evolve carbon oxides and sodium oxides when heated to decomposition.10.6 Hazardous decomposition products




Page 3 of 6




Acute toxicity This product is expected to be of low toxicity. Under normal conditions of use, adverse health effects are notanticipated. Acute Oral Toxicity: LD50 (rat) is > 40 g/kg.

Skin Not classified as a skin irritant. Contact may result in mild irritation.

Eye Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.


Not classified as causing organ effects from single exposure. Sulphuric acid vapours may be generatedwhen product is overheated, oxidised or damaged.









12.1 Toxicity












LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated






Page 4 of 6












Classifications




ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly


Abbreviations

DescriptionRevision



Revision history


Page 5 of 6






Report status


SDS date:

[ End of SDS ]

Revision:18 November 20142

Page 6 of 6


SAFETY DATA SHEET

RX-7492

Page: 1

Revision date: 02/11/2015

Revision No: 12

Section 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product identifier

Product name: RX-7492

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of substance / mixture: Wax Dissolver PC35: Washing and cleaning products (including solvent based

products).

1.3. Details of the supplier of the safety data sheet

Company name: Roemex Limited

Badentoy Crescent

Badentoy Park

Portlethen

Aberdeen

AB12 4YD

United Kingdom

Tel: 01224 783444

Fax: 01224 783663

Email: [email protected]

1.4. Emergency telephone number

Emergency tel: +44(0)1224 783444 - 24 hour

Section 2: Hazards identification

2.1. Classification of the substance or mixture

Classification under CLP: Aquatic Acute 1: H400; Aquatic Chronic 1: H410; Asp. Tox. 1: H304; Flam. Liq. 3: H226;

Skin Irrit. 2: H315; Skin Sens. 1: H317

Most important adverse effects: Flammable liquid and vapour. May be fatal if swallowed and enters airways. Causes

skin irritation. May cause an allergic skin reaction. Very toxic to aquatic life. Very toxic to

aquatic life with long lasting effects.

2.2. Label elements

Label elements:

Hazard statements: H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

[cont...]


SAFETY DATA SHEET

RX-7492

Page: 2

Hazard pictograms: GHS02: Flame

GHS07: Exclamation mark

GHS08: Health hazard

GHS09: Environmental

Signal words: Danger

Precautionary statements: P210: Keep away from heat, hot surfaces, sparks, open flames and other ignition

sources. No smoking.

P241: Use explosion-proof electrical/ventilating/lighting/.. equipment.

P280: Wear protective gloves/protective clothing/eye protection/face protection.

P301+310: IF SWALLOWED: Immediately call a POISON CENTER/doctor.

P302+352: IF ON SKIN: Wash with plenty of water/soap.

P303+361+353: IF ON SKIN (or hair): Take off immediately all contaminated clothing.

Rinse skin with water/shower.

2.3. Other hazards

Other hazards: In use, may form flammable / explosive vapour-air mixture.

PBT: This product is not identified as a PBT/vPvB substance.

Section 3: Composition/information on ingredients

3.2. Mixtures

Hazardous ingredients:

ORANGE TERPENES - REACH registered number(s): 01-2119493353-35-0000

EINECS CAS PBT / WEL CLP Classification Percent

232-433-8 8028-48-6 - Skin Irrit. 2: H315; Aquatic Chronic 1:

H410; Flam. Liq. 3: H226; Asp. Tox. 1:

H304

70-90%

TERPENE HYDROCARBONS, BY PRODUCT - REACH registered number(s): 01-2119980606-28-0000

273-309-3 68956-56-9 - Flam. Liq. 3: H226; Skin Irrit. 2: H315;

Skin Sens. 1: H317; Asp. Tox. 1: H304;

Aquatic Acute 1: H400; Aquatic Chronic

1: H410

10-30%

Section 4: First aid measures

4.1. Description of first aid measures

Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash

immediately with plenty of soap and water.

Eye contact: Bathe the eye with running water for 15 minutes. Consult a doctor.

Ingestion: Wash out mouth with water. Consult a doctor.

[cont...]

SAFETY DATA SHEET

RX-7492

Page: 3

Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Consult a

doctor.

4.2. Most important symptoms and effects, both acute and delayed

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Inhalation of fumes from

the stomach may cause symptoms similar to direct inhalation. Nausea and stomach

pain may occur. The breathing may become shallow and rapid.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may

cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

4.3. Indication of any immediate medical attention and special treatment needed

Immediate / special treatment: Eye bathing equipment should be available on the premises.

Section 5: Fire-fighting measures

5.1. Extinguishing media

Extinguishing media: Alcohol resistant foam. Water spray. Carbon dioxide. Dry chemical powder. Use water

spray to cool containers.

5.2. Special hazards arising from the substance or mixture

Exposure hazards: Flammable. In combustion emits toxic fumes. Forms explosive air-vapour mixture.

5.3. Advice for fire-fighters

Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact

with skin and eyes.

Section 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Personal precautions: Refer to section 8 of SDS for personal protection details. If outside do not approach from

downwind. If outside keep bystanders upwind and away from danger point. Mark out the

contaminated area with signs and prevent access to unauthorised personnel. Turn

leaking containers leak-side up to prevent the escape of liquid. Eliminate all sources of

ignition.

6.2. Environmental precautions

Environmental precautions: Do not discharge into drains or rivers. Contain the spillage using bunding.

6.3. Methods and material for containment and cleaning up

Clean-up procedures: Absorb into dry earth or sand. Transfer to a closable, labelled salvage container for

disposal by an appropriate method. Do not use equipment in clean-up procedure which

may produce sparks.

[cont...]

SAFETY DATA SHEET

RX-7492

Page: 4

6.4. Reference to other sections

Reference to other sections: Refer to section 8 of SDS.

Section 7: Handling and storage

7.1. Precautions for safe handling

Handling requirements: Avoid direct contact with the substance. Ensure there is sufficient ventilation of the area.

Do not handle in a confined space. Avoid the formation or spread of mists in the air.

Smoking is forbidden. Use non-sparking tools.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions: Store in a cool, well ventilated area. Keep container tightly closed. Keep away from

sources of ignition. Prevent the build up of electrostatic charge in the immediate area.

Ensure lighting and electrical equipment are not a source of ignition.

Suitable packaging: Must only be kept in original packaging.

7.3. Specific end use(s)

Specific end use(s): No data available.

Section 8: Exposure controls/personal protection

8.1. Control parameters

Workplace exposure limits: No data available.

DNEL/PNEC Values

DNEL / PNEC No data available.

8.2. Exposure controls

Engineering measures: Ensure there is sufficient ventilation of the area. Ensure lighting and electrical

equipment are not a source of ignition.

Respiratory protection: Self-contained breathing apparatus must be available in case of emergency.

Hand protection: Nitrile gloves. Minimum protection: EN420 standard- 0.26 mm

Eye protection: Safety glasses. Ensure eye bath is to hand.

Skin protection: Protective clothing.

Environmental: Prevent from entering in public sewers or the immediate environment.

Section 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

State: Liquid

Colour: Colourless to yellow.

Odour: Citrus.

Evaporation rate: Slow

Oxidising: Non-oxidising (by EC criteria)

Solubility in water: Insoluble

[cont...]

SAFETY DATA SHEET

RX-7492

Page: 5

Also soluble in: Most organic solvents.

Viscosity: <10cP

Viscosity test method: Dynamic viscosity

Boiling point/range°C: 176 Melting point/range°C: <0

Flammability limits %: lower: 0.6 upper: 6.1

Flash point°C: 48 Part.coeff. n-octanol/water: >3

Autoflammability°C: 236 Vapour pressure: ~1.4 mmHg

Relative density: 0.84-0.88 pH: Not applicable.

VOC g/l: No data available.

9.2. Other information

Other information: No data available.

Section 10: Stability and reactivity

10.1. Reactivity

Reactivity: Stable under recommended transport or storage conditions.

10.2. Chemical stability

Chemical stability: Stable under normal conditions. Stable at room temperature.

10.3. Possibility of hazardous reactions

Hazardous reactions: Hazardous reactions will not occur under normal transport or storage conditions.

Decomposition may occur on exposure to conditions or materials listed below.

10.4. Conditions to avoid

Conditions to avoid: Heat. Hot surfaces. Sources of ignition. Flames.

10.5. Incompatible materials

Materials to avoid: Strong oxidising agents. Strong acids.

10.6. Hazardous decomposition products

Haz. decomp. products: In combustion emits toxic fumes.

Section 11: Toxicological information

11.1. Information on toxicological effects

Relevant hazards for product:

Hazard Route Basis

Skin corrosion/irritation DRM Hazardous: calculated

Respiratory/skin sensitisation DRM Hazardous: calculated

Aspiration hazard - Hazardous: calculated

[cont...]

SAFETY DATA SHEET

RX-7492

Page: 6

Symptoms / routes of exposure

Skin contact: There may be irritation and redness at the site of contact.

Eye contact: There may be irritation and redness. The eyes may water profusely.

Ingestion: There may be soreness and redness of the mouth and throat. Inhalation of fumes from

the stomach may cause symptoms similar to direct inhalation. Nausea and stomach

pain may occur. The breathing may become shallow and rapid.

Inhalation: There may be irritation of the throat with a feeling of tightness in the chest. Exposure may

cause coughing or wheezing.

Delayed / immediate effects: Immediate effects can be expected after short-term exposure.

Section 12: Ecological information

12.1. Toxicity

Ecotoxicity values: No data available.

12.2. Persistence and degradability

Persistence and degradability: Biodegradable.

12.3. Bioaccumulative potential

Bioaccumulative potential: No bioaccumulation potential.

12.4. Mobility in soil

Mobility: Readily absorbed into soil.

12.5. Results of PBT and vPvB assessment

PBT identification: This product is not identified as a PBT/vPvB substance.

12.6. Other adverse effects

Other adverse effects: Negligible ecotoxicity.

Section 13: Disposal considerations

13.1. Waste treatment methods

Disposal operations: Transfer to a suitable container and arrange for collection by specialised disposal

company.

Recovery operations: Use principally as a fuel or other means to generate energy.

Disposal of packaging: Arrange for collection by specialised disposal company.

NB: The user's attention is drawn to the possible existence of regional or national

regulations regarding disposal.

Section 14: Transport information

14.1. UN number

UN number: UN1169

[cont...]

SAFETY DATA SHEET

RX-7492

Page: 7

14.2. UN proper shipping name

Shipping name: EXTRACTS, AROMATIC, LIQUID

14.3. Transport hazard class(es)

Transport class: 3

14.4. Packing group

Packing group: III

14.5. Environmental hazards

Environmentally hazardous: Yes Marine pollutant: Yes

14.6. Special precautions for user

Special precautions: No special precautions.

Tunnel code: D/E

Transport category: 3

Section 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

Specific regulations: Not applicable.

15.2. Chemical Safety Assessment

Section 16: Other information

Other information

Other information: This safety data sheet is prepared in accordance with Commission Regulation (EU) No

2015/830.

* indicates text in the SDS which has changed since the last revision.

RX-7492: Danish PR No-1934826

RX-7492: Norwegian PR No-86377

Phrases used in s.2 and s.3: H226: Flammable liquid and vapour.

H304: May be fatal if swallowed and enters airways.

H315: Causes skin irritation.

H317: May cause an allergic skin reaction.

H400: Very toxic to aquatic life.

H410: Very toxic to aquatic life with long lasting effects.

Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive

and shall be used only as a guide. This company shall not be held liable for any

damage resulting from handling or from contact with the above product.

[final page]

SAFETY DATA SHEET

SAPP

Revision Date: 27-Jun-2016 Revision Number: 21

1. Product Identifier & Identity for the Chemical

Statement of Hazardous Nature Non-Hazardous according to the criteria of the 3rd Revised Edition of the GloballyHarmonised System of Classification and Labelling of Chemicals (GHS), Non-DangerousGoods according to the criteria of ADG.

1.1. Product Identifier Product Name SAPP

Other means of Identification

Synonyms NoneHazardous Material Number: HM003755

Recommended use of the chemical and restrictions on use Recommended Use ThinnerControl AgentUses advised against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton/Baroid Australia Pty. Ltd.

15 Marriott RoadJandakotWA 6164Australia

ACN Number: 009 000 775Telephone Number: 61 (08) 9455 8300Fax Number: 61 (08) 9455 5300

Product Emergency TelephoneAustralia: + 61 1 800 686 951Papua New Guinea: + 61 1 800 686 951NewZealand: +64 800 451719

Fire, Police & Ambulance - Emergency TelephoneAustralia: 000Papua New Guinea: 000New Zealand: 111

E-mail Address [email protected]

Emergency phone number + 61 1 800 686 951

Australian Poisons Information Centre 24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100

2. Hazard Identification


_____________________________________________________________________________________________

Page 1 / 8

_____________________________________________________________________________________________SAPP Revision Date: 27-Jun-2016

Classification of the hazardous chemical

Acute Oral Toxicity Category 4 - H302

Serious Eye Damage/Irritation Category 2 - H319

Label elements, including precautionary statements

Hazard pictograms

Signal Word Warning

Hazard Statements: H302 - Harmful if swallowedH319 - Causes serious eye irritation

Precautionary Statements

Prevention P264 - Wash face, hands and any exposed skin thoroughly after handlingP270 - Do not eat, drink or smoke when using this productP280 - Wear eye protection/face protection

Response P301+ P312 - IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feelunwellP330 - Rinse mouthP305 + P351 + P338 - IF IN EYES: Rinse cautiously with water for several minutes.Remove contact lenses, if present and easy to do. Continue rinsingP337 + P313 - If eye irritation persists: Get medical advice/attention

Storage None

Disposal P501 - Dispose of contents/container in accordance withlocal/regional/national/international regulations

ContainsSubstances CAS NumberSodium acid pyrophosphate 7758-16-9

Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

For the full text of the H-phrases mentioned in this Section, see Section 16

3. Composition/information on Ingredients

Substances CAS Number PERCENT (w/w) GHS Classification -Australia

Sodium acid pyrophosphate 7758-16-9 60 - 100% Acute Tox. 4 (H302)Eye Irrit. 2A (H319)

4. First aid measures

Description of necessary first aid measures

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratoryirritation develops or if breathing becomes difficult.

_____________________________________________________________________________________________

Page 2 / 8


Eyes In case of contact, immediately flush eyes with plenty of water for at least 15minutes and get medical attention if irritation persists.

Skin Wash with soap and water. Get medical attention if irritation persists.

Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medicalattention.

Symptoms caused by exposure

Causes eye irritation Harmful if swallowed.

Medical Attention and Special Treatment Notes to Physician Treat symptomatically

5. Fire Fighting Measures

Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting media

Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireNot applicable

Special protective equipment and precautions for fire fighters Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.

6. Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust. Ensure adequate ventilation. Avoid contact with skin,eyes and clothing.

6.2. Environmental precautions Prevent from entering sewers, waterways, or low areas.

6.3. Methods and material for containment and cleaning up Scoop up and remove.

7. Handling and storage

7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid creating or inhaling dust. Ensure adequate ventilation. Wash hands after use.Launder contaminated clothing before reuse. Use appropriate protective equipment.

Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool, dry location.

Other GuidelinesNo information available

8. Exposure Controls/Personal Protection

_____________________________________________________________________________________________

Page 3 / 8

Control parameters - exposure standards, biological monitoring


Exposure Limits

Substances CAS Number Australia NOHSC ACGIH TLV-TWASodium acid pyrophosphate 7758-16-9 Not applicable Not applicable

Appropriate engineering controls Engineering Controls Use in a well ventilated area.

Personal protective equipment (PPE) Personal Protective Equipment If engineering controls and work practices cannot prevent excessive exposures, the

selection and proper use of personal protective equipment should be determined by anindustrial hygienist or other qualified professional based on the specific application of thisproduct.

Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

Environmental Exposure Controls Do not allow material to contaminate ground water system

9. Physical and Chemical Properties


Property Values Remarks/ - Method

pH: 4-4.6

Freezing Point / Range No data available

Melting Point / Range No data available

Boiling Point / Range No data available

Flash Point No data available

Evaporation rate No data available

Vapor Pressure No data available

Vapor Density No data available

Specific Gravity 1.04

Water Solubility Soluble in water

Solubility in other solvents No data available

Partition coefficient: n-octanol/water No data available

Autoignition Temperature No data available

Decomposition Temperature No data available

Viscosity No data available

Explosive Properties No information available

Oxidizing Properties No information available

9.2. Other information Molecular Weight 223.96

VOC Content (%) No data available

10. Stability and Reactivity

10.1. Reactivity Not expected to be reactive.

10.2. Chemical stability Stable

10.3. Possibility of hazardous reactions

Physical State: Solid Color White

Odor: Odorless Odor Threshold:

_____________________________________________________________________________________________

Page 4 / 8

No information available


Will Not Occur

10.4. Conditions to avoid None anticipated

10.5. Incompatible materials Strong oxidizers.

10.6. Hazardous decomposition products Oxides of phosphorus.

11. Toxicological Information

Information on routes of exposure Principle Route of Exposure Eye or skin contact, inhalation.

Symptoms related to exposure

Most Important Symptoms/EffectsCauses eye irritation Harmful if swallowed.

Numerical measures of toxicity

Toxicology data for the components

Substances CAS Number LD50 Oral LD50 Dermal LC50 Inhalation

Sodium acidpyrophosphate

7758-16-9 1800 mg/kg (Rat)2650 mg/kg (Mouse)

3600 mg/kg (Rat)

> 2000 mg/kg (Rat)> 7940 mg/kg (Rabbit)

0.58 mg/L (Rat) 4h> 0.58 mg/L (Mouse) 4h

Immediate, delayed and chronic health effects from exposure Inhalation None known.

Eye Contact Causes eye irritation.

Skin Contact Not irritating to skin in rabbits.

Ingestion Harmful if swallowed.

Chronic Effects/Carcinogenicity No data available to indicate product or components present at greater than 0.1%are chronic health hazards.

Exposure LevelsNo data available

Interactive effects None known.

Data limitationsNo data available

Substances CAS Number Skin corrosion/irritationSodium acid pyrophosphate 7758-16-9 Non-irritating to the skin (Rabbit)

Substances CAS Number Serious eye damage/irritationSodium acid pyrophosphate 7758-16-9 Irritating to eyes (Rabbit)

Substances CAS Number Skin SensitizationSodium acid pyrophosphate 7758-16-9 Did not cause sensitization on laboratory animals (mouse)

Substances CAS Number Respiratory SensitizationSodium acid pyrophosphate 7758-16-9 No information available

Substances CAS Number Mutagenic EffectsSodium acid pyrophosphate 7758-16-9 In vitro tests did not show mutagenic effects. In vivo tests did not show mutagenic effects.

Substances CAS Number Carcinogenic EffectsSodium acid pyrophosphate 7758-16-9 No data of sufficient quality are available.

_____________________________________________________________________________________________

Page 5 / 8


Substances CAS Number Reproductive toxicitySodium acid pyrophosphate 7758-16-9 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animal

experiments.

Substances CAS Number STOT - single exposureSodium acid pyrophosphate 7758-16-9 No information available

Substances CAS Number STOT - repeated exposureSodium acid pyrophosphate 7758-16-9 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazardSodium acid pyrophosphate 7758-16-9 Not applicable

12. Ecological Information

Ecotoxicity Product Ecotoxicity DataNo data available

Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms

Toxicity to Invertebrates

Sodium acidpyrophosphate

7758-16-9 No information available LC50 (48h) > 1500 mg/L(Goldorfen)

No information available No information available


Substances CAS Number Persistence and Degradability

Sodium acid pyrophosphate 7758-16-9 The methods for determining biodegradability arenot applicable to inorganic substances.


Substances CAS Number Log Pow

Sodium acid pyrophosphate 7758-16-9 No information available


Substances CAS Number Mobility

Sodium acid pyrophosphate 7758-16-9 No information available

12.6. Other adverse effects Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors

13. Disposal Considerations

Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.

Disposal of any contaminated packaging Follow all applicable national or local regulations.

Environmental regulationsNot applicable

14. Transport Information

_____________________________________________________________________________________________

Page 6 / 8

Transportation Information


UN Number Not restricted

UN proper shipping name: Not restricted

Transport Hazard Class(es): Not applicable

Packing Group: Not applicable

Environmental Hazards: Not applicable

Special precautions during transport None

HazChem Code

None Allocated

15. Regulatory Information

Safety, health and environmental regulations specific for the product

International Inventories Australian AICS Inventory All components are listed on the AICS or are subject to a relevant exemption, permit, or

assessment certificate.

New Zealand Inventory ofChemicals

All components are listed on the NZIoC or are subject to a relevant exemption, permit, orassessment certificate.

EINECS (European Inventory ofExisting Chemical Substances)

This product, and all its components, complies with EINECS

US TSCA Inventory All components listed on inventory or are exempt.

Canadian Domestic Substances List(DSL)

All components listed on inventory or are exempt.

Poisons Schedule number None Allocated

International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply

Stolkhom Convention - Persistent Organic Pollutants: Does not apply

Rotterdam Convention - Prior Informed Consent: Does not apply

Basel Convention - Hazardous Waste: Does not apply

16. Other information

Date of preparation or review

Revision Date: 27-Jun-2016

Revision NoteSDS sections updated: 2

Full text of H-Statements referred to under sections 2 and 3H302 - Harmful if swallowedH319 - Causes serious eye irritation

Additional information For additional information on the use of this product, contact your local Halliburtonrepresentative.

For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used

_____________________________________________________________________________________________

Page 7 / 8

bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%


LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/

Disclaimer StatementThis information is furnished without warranty, expressed or implied, as to accuracy or completeness. The information is obtainedfrom various sources including the manufacturer and other third party sources. The information may not be valid under allconditions nor if this material is used in combination with other materials or in any process. Final determination of suitability of anymaterial is the sole responsibility of the user.

End of Safety Data Sheet

_____________________________________________________________________________________________

Page 8 / 8


Synonym(s) SODIUM SULFITE

ANTIOXIDANT • FOOD PRESERVATIVE • LABORATORY REAGENT • PAPER INDUSTRY •PHOTOGRAPHIC DEVELOPER • REDUCING AGENT • WATER TREATMENT

Use(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





SODIUM SULPHITEProduct name


CLASSIFIED AS HAZARDOUS ACCORDING TO AUSTRALIAN WHS REGULATIONS

2.2 Label elements

Signal word DANGER



P305 + P351 + P338

Immediately call a POISON CENTER or doctor/physician.P310Rinse mouth.P330


Wash thoroughly after handling.P264Do not eat, drink or smoke when using this product.P270Wear protective gloves/protective clothing/eye protection/face protection.P280


Harmful if swallowed.H302Causes serious eye damage.H318Contact with acids liberates toxic gasAUH031

Hazard statement(s)

Pictogram(s)

Acute Toxicity: Oral: Category 4Serious Eye Damage / Eye Irritation: Category 1

GHS classification(s)


Page 1 of 7SDS Date: 04 Aug 2016

Version No: 2

www.newpark.com

SODIUM SULPHITEPRODUCT NAME





>97%7757-83-7 231-821-4SODIUM SULPHITE

<2.5%7757-82-6 231-820-9SODIUM SULPHATE

<0.1%497-19-8 207-838-8SODIUM CARBONATE

<0.1%7732-18-5 231-791-2WATER





Eye



Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Urgenthospital treatment is likely to be needed. If swallowed, do not induce vomiting.

First aid facilities Eye wash facilities and safety shower are recommended.




Non flammable. May evolve toxic gases (sulphur oxides) when heated to decomposition.5.2 Special hazards arising from the substance or mixture

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwind and notify thosedownwind of hazard. Wear full protective equipment including Self Contained Breathing Apparatus (SCBA) when combating fire.


None allocated.

5.4 Hazchem code








Version No: 2




Store in a cool, dry, well ventilated area, removed from incompatible substances and foodstuffs. Ensure containers are adequatelylabelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.








Sodium Carbonate (total dust) SWA (AUS) -- 10 -- --


Exposure standards

Biological limits


PPE




Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear aFull-face Class P3 (Particulate) respirator.




9.1 Information on basic physical and chemical properties WHITE CRYSTALLINE SOLIDAppearanceODOURLESSOdourNON FLAMMABLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rate9.0 to 10.5pHNOT AVAILABLEVapour density2.6Specific gravitySOLUBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limit


Version No: 2


9.1 Information on basic physical and chemical properties NOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold





Avoid heat, sparks, open flames and other ignition sources. Sensitive to air and moisture.



May evolve toxic gases (sulphur oxides) when heated to decomposition.10.6 Hazardous decomposition products



10.1 ReactivityContact with acids liberates toxic gas.


Acute toxicity Information available for the product:Harmful if swallowed.


IngredientOral Toxicity

(LD50)Dermal Toxicity

(LD50)Inhalation Toxicity

(LC50)

820 mg/kg (mouse) -- --SODIUM SULPHITE

5989 mg/kg (mouse) -- --SODIUM SULPHATE

4090 mg/kg (rat) > 2000 mg/kg (rabbit) 800 mg/m³/2 hoursSODIUM CARBONATE

Skin Not classified as a skin irritant. Contact may result in mild irritation, redness, rash and dermatitis.

Eye Causes serious eye damage. Contact may result in irritation, lacrimation, pain and redness.


SODIUM SULPHITE (7757-83-7)LD50 (intraperitoneal) 950 mg/kg (mouse)LD50 (intravenous) 175 mg/kg (mouse)LDLo (intravenous) 400 mg/kg (cat)LDLo (oral) 2825 mg/kg (rabbit)LDLo (subcutaneous) 600 mg/kg (rabbit)

SODIUM SULPHATE (7757-82-6)LD50 (intravenous) 1220 mg/kg (rabbit)LDLo (intravenous) 1220 mg/kg (mouse)TDLo (oral) 14 g/kg (mouse - 8-12 days pregnant)TDLo (subcutaneous) 806 mg/kg/26 weeks intermittently (mouse)

SODIUM CARBONATE (497-19-8)LD50 (intraperitoneal) 117 mg/kg (mouse)LD50 (subcutaneous) 2210 mg/kg (mouse)



Version No: 2


Sensitisation Not classified as causing skin or respiratory sensitisation. Some individuals are hypersensitive to sulphites,and may experience asthma like symptoms (wheezing and shortness of breath) immediately followingexposure.

Over exposure may result in mucous membrane irritation of the respiratory tract, with coughing.STOT – singleexposure

Aspiration Not classified as causing aspiration.

Not classified as causing organ damage from repeated exposure.STOT – repeatedexposure

Reproductive Not classified as a reproductive toxin.

Carcinogenicity Not classified as a carcinogen.

Mutagenicity Not classified as a mutagen.


12.1 Toxicity


12.2 Persistence and degradabilityBiodegradability does not pertain to inorganic substances.





12.3 Bioaccumulative potentialThis product does not bioaccumulate.


Waste disposal Cover spill with soda ash or sodium bicarbonate. Mix and spray with water, may be effervescent. Wait untilreaction is complete, scoop into a large beaker and cautiously add equal volume of sodium hypochlorite(reaction may be vigorous). Add more water, stir and allow to stand (~1hr). Dilute and neutralise. Absorb withsand/similar dispose of to an approved landfill site, or alternatively (for small amounts) flush to sewer withlarge excess of water.



LAND TRANSPORT(ADG)






None Allocated14.3 TransportHazard Class

14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated








Version No: 2




R22 Harmful if swallowed.R31 Contact with acids liberates toxic gas.R41 Risk of serious damage to eyes.

Risk phrases



S25 Avoid contact with eyes.S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container

or label.

Safety phrases

T ToxicXi IrritantXn Harmful

Hazard codes


Classifications




WORKPLACE CONTROLS AND PRACTICES: Unless a less toxic chemical can be substituted for ahazardous substance, ENGINEERING CONTROLS are the most effective way of reducing exposure.The best protection is to enclose operations and/or provide local exhaust ventilation at the site ofchemical release. Isolating operations can also reduce exposure. Using respirators or protectiveequipment is less effective than the controls mentioned above, but is sometimes necessary.


HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factorsincluding: frequency and duration of use; quantity used; effectiveness of control measures; protectiveequipment used and method of application. Given that it is impractical to prepare a report whichwould encompass all possible scenarios, it is anticipated that users will assess the risks and applycontrol methods where appropriate.



Version No: 2





Abbreviations




Report status


[ End of SDS ]


Version No: 2

SAFETY DATA SHEET

SODIUM CHLORIDE



1.1. Product Identifier Product Name SODIUM CHLORIDE

Other means of Identification

Synonyms: NoneProduct Code: HM001682

Recommended use of the chemical and restrictions on use Recommended Use AdditiveUses Advised Against No information available

Supplier's name, address and phone number Manufacturer/Supplier Halliburton Australia Pty. Ltd.


ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300

E-Mail address: [email protected]


Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100



Classification of the hazardous chemical

Not classified


Hazard Pictograms

Signal Word Not Hazardous

_____________________________________________________________________________________________

Page 1 / 7

Revision Date: 08-Sep-2015 Revision Number: 23

_____________________________________________________________________________________________

Hazard Statements Not Classified


Prevention None

Response None

Storage None

Disposal None

ContainsSubstances CAS NumberSodium chloride 7647-14-5

Other hazards which do not result in classification This substance is not considered to be persistent, bioaccumulating nor toxic (PBT).This substance is not considered to be very persistent nor very bioaccumulating (vPvB).

Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16

Classification Not Classified

Risk Phrases None



Sodium chloride 7647-14-5 60 - 100%


Description of necessary first aid measures

Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratoryirritation develops or if breathing becomes difficult.

Eyes In case of contact, immediately flush eyes with plenty of water for at least 15minutes and get medical attention if irritation persists.

Skin Wash with soap and water. Get medical attention if irritation persists.

Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure

Causes mild eye irritation.



Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting media

Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical

_____________________________________________________________________________________________

Page 2 / 7

SODIUM CHLORIDE Revision Date: 08-Sep-2015

_____________________________________________________________________________________________

Special Exposure HazardsNone anticipated

Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid creating and breathing dust.


6.3. Methods and material for containment and cleaning up Scoop up and remove.


7.1. Precautions for Safe Handling Handling PrecautionsAvoid creating or inhaling dust.

Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore in a cool, dry location.

Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure Limits

Substances CAS Number Australia NOHSC ACGIH TLV-TWA

Sodium chloride 7647-14-5 Not applicable Not applicable


Personal protective equipment (PPE) Respiratory Protection If engineering controls and work practices cannot keep exposure below occupational

exposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.

Skin Protection Normal work coveralls.

Eye Protection Wear safety glasses or goggles to protect against exposure.

Other Precautions None known.

Environmental Exposure Controls No information available



_____________________________________________________________________________________________

Page 3 / 7


_____________________________________________________________________________________________

Property Values Remarks/ - Method

pH: No data available

Freezing Point/Range No data available

Melting Point/Range 801 °C / 1473.8 °F

Boiling Point/Range No data available

Flash Point No data available

Evaporation rate No data available

Vapor Pressure No data available

Vapor Density No data available

Specific Gravity 2.16

Water Solubility Very soluble

Solubility in other solvents No data available

Partition coefficient: n-octanol/water No data available

Autoignition Temperature No data available

Decomposition Temperature No data available

Viscosity No data available

Explosive Properties No information available

Oxidizing Properties No information available

9.2. Other information VOC Content (%) No data available


10.1. Reactivity Not expected to be reactive.

10.2. Chemical Stability Stable

10.3. Possibility of Hazardous Reactions Will Not Occur

10.4. Conditions to Avoid None anticipated

10.5. Incompatible Materials None known.

10.6. Hazardous Decomposition Products None known.



Sympotoms related to exposure

Most Important Symptoms/EffectsCauses mild eye irritation.




Sodium chloride 7647-14-5 3000 mg/kg (Rat)3550 mg/kg (Rat)

>10000 mg/kg (Rabbit) 42 mg/L (Rat) 1h

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.

Eye Contact Causes mild eye irritation.

Skin Contact May cause mild skin irritation.

_____________________________________________________________________________________________

Page 4 / 7

Odor: Odorless

Revision Date: 08-Sep-2015

Odor Threshold: No information availablePhysical State: Solid Color: White

SODIUM CHLORIDE

_____________________________________________________________________________________________

Ingestion None known.





Substances CAS Number Skin corrosion/irritation

Sodium chloride 7647-14-5 Non-irritating to the skin (Rabbit)

Substances CAS Number Eye damage/irritation

Sodium chloride 7647-14-5 May cause mild eye irritation. (Rabbit)

Substances CAS Number Skin Sensitization

Sodium chloride 7647-14-5 No information available

Substances CAS Number Respiratory Sensitization


Substances CAS Number Mutagenic Effects


Substances CAS Number Carcinogenic Effects

Sodium chloride 7647-14-5 Did not show carcinogenic effects in animal experiments

Substances CAS Number Reproductive toxicity

Sodium chloride 7647-14-5 Animal testing did not show any effects on fertility. Did not show teratogenic effects in animalexperiments.

Substances CAS Number STOT - single exposure


Substances CAS Number STOT - repeated exposure

Sodium chloride 7647-14-5 No significant toxicity observed in animal studies at concentration requiring classification.

Substances CAS Number Aspiration hazard

Sodium chloride 7647-14-5 Not applicable



Substance Ecotoxicity Data

Substances CAS Number Toxicity to Algae Toxicity to Fish Toxicity toMicroorganisms

Toxicity to Invertebrates

Sodium chloride 7647-14-5 EC50 (120h) 2430 mg/L(Nitzschia sp.)

TLM96 > 1000 mg/L(Oncorhynchus mykiss)LC50 (96h) 5840 mg/L(Lepomis macrochirus)NOEC (33d) 252 mg/L(Pimephales promelas)

NOEC 5000 – 8000 mg/L(activated sludge)

NOEC 292-584 mg/L(Escherichia coli)

TLM96 > 1,000,000 ppm(Mysidopsis bahia)

LC50 (48h) 874-4136mg/L (Daphnia magna)NOEC (21d) 314 mg/L

(Daphnia pulex)


_____________________________________________________________________________________________

Page 5 / 7


_____________________________________________________________________________________________

Substances CAS Number Persistence and Degradability






Substances CAS Number Mobility




Safe handling and disposal methods Bury in a licensed landfill according to federal, state, and local regulations.

Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.



Transportation Information UN Number: Not restricted

UN Proper Shipping Name: Not restricted

Transport Hazard Class(es): Not applicable

Packing Group: Not applicable

Environmental Hazards: Not applicable


HazChem Code

None Allocated



International Inventories Australian AICS Inventory All components listed on inventory or are exempt.

New Zealand Inventory ofChemicals


EINECS Inventory This product, and all its components, complies with EINECS

US TSCA Inventory All components listed on inventory or are exempt.

Canadian DSL Inventory All components listed on inventory or are exempt.

Poisons Schedule number

_____________________________________________________________________________________________

Page 6 / 7


_____________________________________________________________________________________________None Allocated



Revision Date: 08-Sep-2015


Full text of R-phrases referred to under Sections 2 and 3None

Full text of H-Statements referred to under sections 2 and 3None



Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCID



_____________________________________________________________________________________________

Page 7 / 7



Synonym(s) RHEOCHEM TRIETHANOLAMINE

CHEMICAL INTERMEDIATE • LABORATORY REAGENT • SOLVENTUse(s)





Telephone +61 8 9410 8200

Fax +61 8 9410 8299





TRIETHANOLAMINEProduct name



2.2 Label elements

Signal word DANGER




P305 + P351 + P338

Immediately call a POISON CENTRE or doctor/physician.P310Get medical advice/attention if you feel unwell.P314


Do not breathe dust/fume/gas/mist/vapours/spray.P260Wear protective gloves/protective clothing/eye protection/face protection.P280


Causes serious eye damage.H318May cause damage to organs through prolonged or repeated exposure.H373

Hazard statement(s)

Pictograms

Serious Eye Damage / Eye Irritation: Category 1Specific Target Organ Systemic Toxicity (Repeated Exposure): Category 2

GHS classification


Page 1 of 7


www.newpark.com

TRIETHANOLAMINEPRODUCT NAME



Ingredient Identification Classification Content GHS Risk

TRIETHANOLAMINE CAS: 102-71-6EC: 203-049-8

>60%Not Available Not Available

DIETHANOLAMINE CAS: 111-42-2EC: 203-868-0

10 to <30%Acute Tox. 4, H302Skin Irrit. 2, H315Eye Dam. 1, H318STOT RE 2, H373

Xn;R22, Xi;R38,Xi;R41, Xn;R48/22

ETHANOLAMINE CAS: 141-43-5EC: 205-483-3

<10%Acute Tox. 4, H302Acute Tox. 4, H312Skin Corr. 1B, H314Acute Tox. 4, H332

Xn;R20/21/22,C;R34





Eye

Inhalation If inhaled, remove from contaminated area. To protect rescuer, use a Type A (Organic vapour) respirator oran Air-line respirator (in poorly ventilated areas). Apply artificial respiration if not breathing.


Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Rinse mouth out with water and give plenty of water to drink.


Over exposure may result in irritation to the eyes, nose and respiratory system. May cause allergic contact dermatitis.4.2 Most important symptoms and effects, both acute and delayed



Combustible. May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.5.2 Special hazards arising from the substance or mixture



None allocated.

5.4 Hazchem code

Dry agent, carbon dioxide, foam or water fog. Prevent contamination of drains or waterways.5.1 Extinguishing media


Wear Personal Protective Equipment (PPE) as detailed in Section 8. Clear area of all unprotected personnel. Ventilate area wherepossible. Contact emergency services where appropriate.


Page 2 of 7




Contain spillage, then cover/absorb spill with non-combustible absorbent material (vermiculite, sand, or similar), collect and place insuitable containers for disposal.




Store in a cool, dry, well ventilated area, removed from incompatible substances, heat or ignition sources and foodstuffs. Ensurecontainers are adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks or spills.Store as a Class C2 Combustible Liquid (AS1940).








Diethanolamine (h) SWA (AUS) 3 13 -- --

Ethanolamine SWA (AUS) 3 7.5 6 15

Triethanolamine SWA (AUS) -- 5 -- --


Exposure standards

Biological limits


PPE



Body Wear coveralls.

Respiratory Where an inhalation risk exists, wear a Type A (Organic vapour) respirator. If spraying, wear a Type A-ClassP1 (Organic gases/vapours and Particulate) respirator.

Engineering controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain vapour levels below the recommended exposure standard.



9.1 Information on basic physical and chemical properties CLEAR LIQUIDAppearanceMILD AMMONIACAL ODOUROdourCLASS C2 COMBUSTIBLEFlammability190°CFlash point

Page 3 of 7



9.1 Information on basic physical and chemical properties 335°CBoiling point12°CMelting point< 0.01 (n-Butyl acetate = 1)Evaporation rate10.5 (1 % Solution)pH4.80 (Air = 1)Vapour density1.12Specific gravitySOLUBLESolubility (water)< 1 kPa @ 20°CVapour pressureNOT AVAILABLEUpper explosion limitNOT AVAILABLELower explosion limitNOT AVAILABLEPartition coefficient375°CAutoignition temperatureNOT AVAILABLEDecomposition temperature450 cP @ 25°CViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold








Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), nitrites, heat and ignition sources. Also incompatible withorganic anhydrides, isocyanates, vinyl acetate, acrylates, substituted allyls, alkylene oxides, epichlorohydrin, aldehydes, copper, brassand aluminium.

May evolve toxic gases (carbon/ nitrogen oxides, amines, ammonia, hydrocarbons) when heated to decomposition.10.6 Hazardous decomposition products

Hazardous polymerization is not expected to occur.




Acute toxicity May be harmful if swallowed, in contact with skin, and/or if inhaled. LD50 (oral) = 2200 mg/kg (rabbit).

Skin Contact may result in mild irritation, redness, pain and rash.

Eye Contact may result in irritation, lacrimation, pain and redness. May result in burns with prolonged contact.

Sensitization Triethanolamine has been reported to cause allergic contact dermatitis in humans. It is not known to causerespiratory sensitisation.

Over exposure may result in irritation of the nose and throat, with coughing. High level exposure may result inbreathing difficulties.


Aspiration This product is not expected to present an aspiration hazard.

Diethanolamine may cause damage to organs (liver) through prolonged and repeated exposure.STOT – repeatedexposure


Carcinogenicity Triethanolamine and diethanolamine are not classifiable as to carcinogenicity to humans (IARC Group 3).



Page 4 of 7




12.1 Toxicity


12.2 Persistence and degradabilityThe substance is expected to be readily biodegradable according to the AS 4351 Part 2 test method.




In soil and water, triethanolamine will biodegrade fairly rapidly following acclamation (half-life in the order of days to weeks). In soil,residual triethanolamine may leach to groundwater. LC50 (shrimp): > 100 ppm.



Waste disposal Reduce with sodium thiosulphate/ bisulphite (not strong reducing agent), acidify with 3M sulphuric acid.Scoop into a container of water and neutralise with soda ash. Absorb with sand or similar and dispose of toapproved landfill site. Contact the manufacturer for additional information.



LAND TRANSPORT(ADG)







14.1 UN Number


None Allocated

None Allocated

None Allocated


None Allocated







Poison schedule Classified as a Schedule 5 (S5) Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP).15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

R41 Risk of serious damage to eyes.R48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.

Risk phrases

S25 Avoid contact with eyes.S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical adviceS39 Wear eye/face protection.

Safety phrases

Xi IrritantXn Harmful

Hazard codes


Classifications


Page 5 of 7









ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberGHS Globally Harmonized SystemIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitPEL Permissible Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly

alkaline).ppm Parts Per MillionREACH Regulation on Registration, Evaluation, Authorisation and Restriction of ChemicalsSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average

Abbreviations

DescriptionRevision



Revision history


Page 6 of 7






Report status


SDS date:

[ End of SDS ]

Revision:25 July 20142

Page 7 of 7



NEWZAN D ● VISCO XC 84 ● XANTHAN GUM (BIOPOLYMER)Synonym(s)

DRILLING FLUID ADDITIVE ● VISCOSITY MODIFIERUse(s)1.2 Uses and uses advised against




+61 8 9410 8200Telephone

+61 8 9410 8299Fax

1800 127 406 (Australia); +64 4 917 9888 (International)Emergency




XANTHAN GUM (P)Product name








>87%11138-66-2 234-394-2XANTHAN GUM

<13%7732-18-5 231-791-2WATER





Eye


If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.

Skin

For advice, contact a Poisons Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). Ifswallowed, do not induce vomiting. Ingestion is considered unlikely due to product form.

Ingestion

Eye wash facilities and safety shower should be available.First aid facilities

SDS Date: 03 May 2017


www.newpark.com

XANTHAN GUM (P)PRODUCT NAME








None allocated.

5.4 Hazchem code
















Exposure standards


Biological limitsNo biological limit values have been entered for this product.

Avoid inhalation. Use in well ventilated areas.8.2 Exposure controlsEngineering controls




PPE




Respiratory Wear a Class P1 (Particulate) respirator. Where an inhalation risk exists, wear a Class P1 (Particulate)respirator.


9.1 Information on basic physical and chemical propertiesLIGHT BEIGE POWDERAppearanceSLIGHT ODOUROdourCOMBUSTIBLEFlammabilityNOT RELEVANTFlash pointNOT AVAILABLEBoiling pointNOT AVAILABLEMelting pointNOT AVAILABLEEvaporation rateNOT AVAILABLEpHNOT AVAILABLEVapour density1.5Specific gravityMISCIBLESolubility (water)NOT AVAILABLEVapour pressureNOT RELEVANTUpper explosion limitNOT RELEVANTLower explosion limitNOT AVAILABLEPartition coefficientNOT AVAILABLEAutoignition temperatureNOT AVAILABLEDecomposition temperatureNOT AVAILABLEViscosityNOT AVAILABLEExplosive propertiesNOT AVAILABLEOxidising propertiesNOT AVAILABLEOdour threshold

















This product is expected to be of low acute toxicity. Under normal conditions of use, adverse health effectsare not anticipated. LD50 (oral) > 1000 mg/kg (mouse)LD50 (oral) > 45,000 mg/kg (rat)LD50 (oral) > 20,000 mg/kg (dog) LD50 (intraperitoneal): > 50 mg/kg (mouse) LD50 (intravenous): 100-250 mg/kg (mouse)

Acute toxicity

Not classified as a skin irritant. Contact may result in mild irritation.Skin

Not classified as an eye irritant. Contact may cause discomfort, lacrimation and redness.Eye


Not classified as causing organ damage from single exposure.STOT - singleexposure


Not classified as causing organ damage from repeated exposure.STOT - repeatedexposure

No relevant or reliable studies were identified.Reproductive

No evidence of carcinogenic effects.Carcinogenicity

No evidence of mutagenic effects.Mutagenicity


12.1 Toxicity

This product is not anticipated to cause adverse effects to animal or plant life if released to the environment in small quantities.










Waste disposal




None allocated.




14.4 Packing Group

None allocated.

None allocated.

None allocated.


None allocated.

14.1 UN Number













Poison schedule








Classifications












Abbreviations




Report status

Risk Management Technologies 5 Ventnor Ave, West Perth Western Australia 6005 Phone: +61 8 9322 1711 Fax: +61 8 9322 1794 Email: [email protected] Web: www.rmt.com.au

Prepared by

[ End of SDS ]



CHEMALERT REPORTFull Report



Product name CALCIUM CHLORIDE POWDER 94-97%

Synonym(s) CALCIUM CHLORIDE ANHYDRATE


Use(s) CONCRETE CONDITIONER • DESICCANT • DUST CONTROL AGENT • FOOD ADDITIVE • INDUSTRIALAPPLICATIONS

1.3 Details of the supplier of the safety data sheet


Address 11 Alacrity Place, Henderson, WA, Australia, 6166Telephone +61 8 9410 8200Fax +61 8 9410 8299Email Not suppliedWebsite http://www.newpark.com


Emergency 1800 127 406 (Australia); +64 3 3530199 (International)



Risk phrases

R36 Irritating to eyes.Safety phrases

S22 Do not breathe dust.S24 Avoid contact with skin.

Other Hazards




Ingredient CAS number EC number Content

CALCIUM CHLORIDE ANHYDROUS 10043-52-4 233-140-8 94 - 97%SODIUM CHLORIDE 7647-14-5 231-598-3 1 - 5%WATER 7732-18-5 231-791-2 1%



Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised tostop by a Poisons Information Centre, a doctor, or for at least 15 minutes.

Inhalation If inhaled, remove from contaminated area. Apply artificial respiration if not breathing.Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water.

Continue flushing with water until advised to stop by a Poisons Information Centre or a doctor.Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If

swallowed, do not induce vomiting.First aid facilities Eye wash facilities and safety shower should be available.

4.2 Most important symptoms and effects, both acute and delayed

4.3 Immediate medical attention and special treatment needed

Irritating to the eyes and skin.


Page 1 of 7Reviewed: 17 Apr 2015

Printed: 29 Jul 2016This report was compiled based on the SDS dated 17 Apr 2015



5. FIREFIGHTING MEASURES

5.1 Extinguishing media

Use an extinguishing agent suitable for the surrounding fire.


Non flammable. May evolve toxic gases (chlorides) when heated to decomposition.



5.4 Hazchem code

None allocated




6.2 Environmental precautions

Prevent product from entering drains and waterways.


Contain spillage, then collect and place in suitable containers for reuse or disposal. Avoid generating dust.

6.4 Reference to other sections

See Sections 8 and 13 for exposure controls and disposal.






7.3 Specific end use(s)


8. EXPOSURE CONTROLS/ PERSONAL PROTECTION


Exposure standards


Biological limits No Biological Limit Value allocated.


Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.

PPE





Eye/Face Wear dust-proof goggles.Hand Wear PVC or rubber gloves.Body When using large quantities or where heavy contamination is likely, wear coveralls.Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.


9.1 Information on basic physical and chemical properties

Appearance WHITE POWDEROdour ODOURLESSOdour Threshold NOT AVAILABLEpH 7.0 to 9.0Melting Point 772°CBoiling Point > 1600°CFlash Point NOT RELEVANTEvaporation Rate NOT RELEVANTFlammability NON FLAMMABLEUpper Explosion Limit NOT RELEVANTLower Explosion Limit NOT RELEVANTVapour Pressure NOT AVAILABLEVapour Density NOT AVAILABLESolubility (water) 590 kg/m³ (Approximately)Partition Coefficient NOT AVAILABLEAutoignition Temperature NOT AVAILABLEDecomposition Temperature NOT AVAILABLEViscosity NOT AVAILABLEExplosive Properties NOT AVAILABLEOxidising Properties NOT AVAILABLESpecific Gravity 2.15

9.2 Other information

% Volatiles NOT AVAILABLE


10.1 Reactivity

Carefully review all information in sections 10.2 to 10.6.






Avoid contact with incompatible substances.


Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calcium oxide.May react exothermically with water (i.e. releasing heat).

10.6 Hazardous decomposition products





May evolve toxic gases (chlorides) when heated to decomposition.



Acute toxicity Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients:CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman)SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)


Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness.


Carcinogenicity Insufficient data available to classify as a carcinogen.


STOT - singleexposure

Not classified as causing organ effects from single exposure.


Not classified as causing organ damage from repeated exposure.


Sensitisation Not classified as causing skin or respiratory sensitisation.






12.1 Toxicity


12.2 Persistence and degradability

Biodegradability does not pertain to inorganic substances.

12.3 Bioaccumulative potential

This product does not bioaccumulate.



12.5 Results of PBT and vPvB assessment




13. DISPOSAL CONSIDERATIONS13.1 Waste treatment methods





Land Transport Sea Transport Air Transport(ADG) (IMDG/IMO) (IATA/ICAO)

14.1 UN number None Allocated None Allocated None Allocated14.2 UN proper shipping name None Allocated None AllocatedNone Allocated14.3 Transport hazard classes

DG Class None Allocated None AllocatedNone AllocatedSubsidiary risk(s) None Allocated None AllocatedNone Allocated

14.4 Packing group None Allocated None AllocatedNone Allocated14.5 Environmental hazards None Allocated14.6 Special precautions for user

Hazchem Code None Allocated



Poison schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for theUniform Scheduling of Medicines and Poisons (SUSMP).Xi - IrritantClassifications

AUSTRALIA: AICS (Australian Inventory of Chemical Substances)

All components are listed on AICS, or are exempt.Inventory listing(s)

15.2 Chemical safety assessment







Additional information RESPIRATORS: In general the use of respirators should be limited and engineering controls employed toavoid exposure. If respiratory equipment must be worn ensure correct respirator selection and training isundertaken. Remember that some respirators may be extremely uncomfortable when used for long periods.The use of air powered or air supplied respirators should be considered where prolonged or repeated use isnecessary.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including:frequency and duration of use; quantity used; effectiveness of control measures; protective equipment usedand method of application. Given that it is impractical to prepare a ChemAlert report which would encompassall possible scenarios, it is anticipated that users will assess the risks and apply control methods whereappropriate.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this report is provided as a guide only.Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protectiveequipment is made.

Abbreviations ACGIH American Conference of Governmental Industrial HygienistsCAS # Chemical Abstract Service number - used to uniquely identify chemical compoundsCNS Central Nervous SystemEC No. EC No - European Community NumberEMS Emergency Schedules (Emergency Procedures for Ships Carrying Dangerous Goods)GHS Globally Harmonized SystemGTEPG Group Text Emergency Procedure GuideIARC International Agency for Research on CancerLC50 Lethal Concentration, 50% / Median Lethal ConcentrationLD50 Lethal Dose, 50% / Median Lethal Dosemg/m³ Milligrams per Cubic MetreOEL Occupational Exposure LimitpH relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm Parts Per MillionSTEL Short-Term Exposure LimitSTOT-RE Specific target organ toxicity (repeated exposure)STOT-SE Specific target organ toxicity (single exposure)SUSMP Standard for the Uniform Scheduling of Medicines and PoisonsSWA Safe Work AustraliaTLV Threshold Limit ValueTWA Time Weighted Average

Report Status This ChemAlert report has been independently compiled by RMT's scientific department utilising the originalSafety Data Sheet ('SDS') for the product provided to RMT by the manufacturer. The information is based onthe latest chemical and toxicological research and is believed to represent the current state of knowledge asto the appropriate safety and handling precautions for the product at the time of issue. It is an independentcollation by RMT of information obtained from the original SDS for this product. Its content has not beenauthorised or verified by the manufacturer / distributor of the chemical to which it relates.

This ChemAlert report does not constitute the manufacturer's original SDS and is not intended to be areplacement for same. It is provided to subscribers of ChemAlert as a reference tool only, is not all-inclusiveand does not represent any guarantee as to the properties of the product. Further clarification regarding anyaspect of the product should be obtained directly from the manufacturer.





While RMT has taken all due care to include accurate and up-to-date information in this ChemAlert report, itdoes not provide any warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts noliability for any loss, injury or damage (including consequential loss) which may be suffered or incurred byany person as a consequence of their reliance on the information contained in this ChemAlert report.

Prepared By Risk Management Technologies5 Ventnor Ave, West PerthWestern Australia 6005Phone: +61 8 9322 1711Fax: +61 8 9322 1794Email: [email protected]: www.rmt.com.au

Last Reviewed:17 Apr 2015Date Printed:29 Jul 2016

17 Apr 2015

End of Report

Based on SDS dated:




HSE-E-075-SUM Rev 4

Appendix 3

WIA Cementing Chemical Disclosure Tables


HSE-E-075-SUM Rev 4

Table 9: Products, additives, chemicals and other substances (Cementing)

Table 9a: System Details

Operator AWE Perth Pty Ltd

Project/Well Potentially any well listed in Error! Reference source not found.

System Cementing

Total Volume of System 300bbl (47,700 L) per well

Table 9b: Product List

Product Name Supplier Purpose Toxicity, Ecotoxicity & Biodegradability data** % Product in System Fluid

SDS Attached

Cement - Class G Halliburton Cement PRODUCT CEFAS LISTED

100% PLONOR

CONSTITUENT 1 (≤100%):

LD50 Oral: >2,000 mg/kg (Rat), LD50 Dermal: >2,000 mg/kg, LC50 Inhalation: >1.0 mg/L (4h) (Rat) After hardening with water or moister, cement presents no ecotoxicity risks. (Source: IUCLID 2000) Static Aquatic Toxicity - Freshwater and Marine Algae: 72 hour EC50: >1,000 mg/L

Static Aquatic Toxicity -Freshwater and Marine Invertebrates: 48 hour LC50: >1,000 mg/L Static Aquatic Toxicity- Freshwater and Marine Fish: 96 hour LC50: >1,500 mg/L

Partition Coefficient, n-Octanol/Water: Not Applicable for inorganics Oxygen Demand, Chemical Oxygen Demand: Not Applicable for inorganics Biodegradability, Seawater – Indigenous microbes: Not Applicable for inorganics CONSTITUENT 2 (≤10%):

LD50 Oral: >15000 mg/kg (human)

Freshwater Crustacean Toxicity 24h LL50: > 10,000 mg/L (Daphnia magna) [Health Canada] (similar substance); Freshwater Fish Toxicity 96h LL0: 10,000 mg/L (Danio rerio) [Health Canada] (similar substance); Bioaccumulation: Substance is inorganic - bioaccumulation is not applicable.

Biodegradation: Substance is inorganic - biodegradation is not applicable.

68.6% Yes

Customer Supplied Mix Water

Customer To Mix Fluids No Hazard 30% No

Halad-413L Halliburton Fluid Loss Additive PRODUCT CEFAS LISTED


Oral LD50: >2,000 mg/kg (Rat)

Marine Water Algae Toxicity 72h EC50: 1102 mg/L (Skeletonema costatum) [OSPAR]; Marine Water Crustacean Toxicity 48h LC50: > 2000 mg/L (Acartia tonsa) [OSPAR]; Marine Water Fish Toxicity 96h LC50: > 1,000 mg/L (Scophthalmus maximus) [OSPAR]; Bioaccumulation Log Kow: < 3.5 [Halliburton Funded Study];

Marine Water Biodegradation 28d: 6 % [Halliburton Funded Study];


Product is naturally occurring and not intrinsically hazardous

No data available to indicate product or components present at greater than 0.1% are chronic health hazards

1.00% Yes

CFR-8L Halliburton Friction Reducer PRODUCT CEFAS LISTED


Oral LD50: >5,000 mg/kg (Rat)

Marine Water Algae Toxicity 72h EC50: 7,631.73 mg/L (Skeletonema costatum); Marine Water Crustacean Toxicity 48h LC50: 2,200 mg/L (Acartia tonsa);

0.246% Yes


HSE-E-075-SUM Rev 4


SDS Attached

Marine Water Fish Toxicity 96h LC50: 1006 mg/L (Scophthalmus maximus); Fresh Water Crustacean Toxicity 48h LC50: >100 mg/L (Daphnia magna); Bioaccumulation Log Pow: < 0;

Inherently biodegradable: Biodegradation 28d: 38%;


Component is naturally occurring and not intrinsically hazardous


NF-6 Halliburton Reduces air entrainment into cement slurry

PRODUCT DATA

Marine Water Algae Toxicity 72h EC50: 1100 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: > 1000 mg/L (Acartia tonsa) [Halliburton Funded Study]; Marine Water Fish Toxicity 96h LC50: > 1,000 mg/L (Scophthalmus maximus) [Halliburton Funded Study]; Marine Water Biodegradation 28d: 70% [Halliburton Funded Study];

CONSTITUENT 1 (≤10%)

Marine Algae Toxicity 72h EC50: 991.02 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 2,500 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >3,200 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 7.45


Oral LD50: >15,900 mg/kg (Mouse), Inhalation LC50: >5 mg/L (4h) (Rat) Marine Algae Toxicity 72h EC50: 41 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10,000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >1,800 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 4.28


Oral LD50: > 5000 mg/kg (Rat), Dermal LD50: >5,000 mg/kg (Guinea Pig) Marine Algae Toxicity 72h EC50: 6,488.87 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: 5,085.71 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5,600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 22.69 (MW>700)


No Hazard Product is naturally occurring


Oral LD50: 90 mg/kg (Mouse) (Similar Substance)

Marine Algae Toxicity 72h EC50: >3,200 mg/L (Skeletonema costatum) Marine Crustacean Toxicity 48h LC50: >10,000 mg/L (Acartia tonsa); Marine Fish Toxicity 96h LC50: >5,600 mg/L (Scophthalmus maximus); Bioaccumulation: Calculated Log Pow: 7.09


0.0772% Yes


HSE-E-075-SUM Rev 4


SDS Attached

HR-6L Halliburton Cement Retarder PRODUCT CEFAS LISTED

100% PLONOR


Component is naturally occurring and is not intrinsically hazardous


Oral LC50: >5,000 mg/L, Inhalation LC50: > 480 mg/m3

Freshwater Fish Toxicity LC50: >1,000 mg/L (Danio rerio)

Marine Water Algae Toxicity 72h EC50: 301 mg/L (Skeletonema costatum) [Halliburton Funded Study]; Marine Water Crustacean Toxicity 48h LC50: 1,261 mg/L (Acartia tonsa) [Halliburton Funded Study]; Bioaccumulation Log Pow: -3.45 (Calculated) [Halliburton Funded Study];

Biodegradation: No data - expected to be inherently biodegradable

No data available to indicate product or components present at greater than 0.1% are chronic health hazards.

0.0754% Yes

Contingency Volumes

Water Town or Bore water

Base fluid N/A - Natural product. 53.749% N/A

Dump Bailed Cement Thru Tubing

Systems

Neo Products

Cement Toxicological Information

Inhalation of dust may cause respiratory tract irritation. Symptoms of exposure may include cough, sore throat, nasal congestion,

sneezing, wheezing, and shortness of breath.

May cause an allergic skin reaction.

Portland Cement: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3

Crystalline Silica (quartz): OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 5 mg/m3. IDLH 5000 mg/m3. LD50 Oral Rat > 5,000 mg/kg

Calcium Oxide: OSHA PEL (TWA) 5 mg/m3. NIOSH REL (TWA) 2 mg/m3. IDLH 25 mg/m3

Gypsum: OSHA PEL (TWA) 15 mg/m3 (Total) 5 mg/m3 (Resp). NIOSH REL (TWA) 10 mg/m3 (Total) 5 mg/m3 (Resp).

Magnesium Oxide: OSHA PEL (TWA) 15 mg/m3. IDLH 750 mg/m3

Chronic Toxicity

Prolonged inhalation of repairable crystalline silica may cause lung disease, silicosis, lung cancer, and other effects.

Ecological Toxicity

Not Classified. No recognized unusual toxicity to plants or animals.

Calcium Oxide (1305-78-8): LC50 Fish: 1,070 mg/l (Exposure time: 96 h – Species: Cyprinus carpio [static])

Biodegradation / Bioaccumulation:

Biodegradation not applicable as cement is intended to remain long term in well and will be inert.

0.666% Yes


HSE-E-075-SUM Rev 4


SDS Attached

Cement (API Class G) D907

Schlumberger Setting plugs to isolate hydrocarbon producing reservoirs from aquifers

Toxicity - Constituent 1 (60-100%)

Fish Toxicity LC50 (96h): 41.2 mg/L (Oreochromis niloticus)

Toxicity - Constituent 2 (30-60%)

96h LL0: 10,000 mg/L (Branchdanio rerio) Crustacean Toxicity 24h EL50: >10,000 mg/L (Daphnia magna) Na‐Al silicates: Fish Toxicity 96h LL0: 10,000 mg/L (Branchdanio rerio); Algae Toxicity 72h NOEL:10,000 mg/L (Scenedesmus subspicatus)

Source: IUCLID 2,000 Addition of large amounts of cement to water may, however, cause a rise in pH and may, therefore be toxic to aquatic life under certain circumstances.

Toxicity - Constituent 3 (5%)

LD50 (Ingestion): > 5,000 mg/kg (rat)


TCLo (Inhalation): 194 g/m³/10 years intermittently (human)

TDLo (Ingestion): 450 mg/kg/3 weeks intermittently (rat)


LD50 (Ingestion): 3,160 mg/kg (rat).

Chronic Toxicity:

Silicosis: Excessive inhalation of respirable crystalline silica dust may cause a progressive, disabling, and sometimes-fatal lung disease called silicosis. Symptoms include a cough, shortness of breath, wheezing, non-specific chest illness, and reduced pulmonary function. Individuals with silicosis are predisposed to develop tuberculosis.


Biodegradation not applicable as cement is intended to remain long term in well and will be inert.

42.12% Yes

A-300L Baker Hughes Suspension agent Toxicity - Constituent 1 (60%)

Silicon dioxide is a naturally occurring substance.

Source: http://www.food.gov.uk/multimedia/pdfs/evm_silicon.pdf.

(NOAEL) no observed adverse effect level = 7,500 mg/kg bw/day silicon dioxide for mice

Toxicity - Constituent 2- (0.6%)

Inhalation, mouse: LC50 = 1,200 mg/m3/2H;

Inhalation, rat: LC50 = 2,300 mg/m3/2H;

Oral, mouse: LD50 = 6,600 mg/kg;

Oral, mouse: LD50 = 6,600 mg/kg;

Oral, rat: LD50 = 4,090 mg/kg.


This product is not anticipated to cause adverse effects on animal or plant life if released to the environment in small quantities. Not expected to bioaccumulate.

Water: (69.4%)

Natural product

0.22% Yes

CD-31L Baker Hughes Dispersant Toxicity - Constituent 1 (20%)

LC50: 135 ppm for Daphnia Magna Straus waterflea

LD50: 2,000 mg/kg(Rat)


Possibly hazardous short-term degradation products are not likely. However, long term degradation products may arise. These products are sulfur oxides (SO2, SO3…), some metallic oxides.

1.12% Yes


HSE-E-075-SUM Rev 4


SDS Attached

Water: (80%)

Natural product

FL-66L Baker Hughes Cement fluid loss Toxicity - Constituent 1 (20%) Acrylic copolymer

LD50 oral rat: 12,950 mg/kg. LD50 oral rabbit: 11,250 mg/kg.


Polyacrylamides are generally water-soluble, high molecular weight synthetic organic polymers that primarily interact with the clay fraction of soils. The degree of interaction depends on both the properties of the polymer and properties of the soil.

For the most part, polyacrylamide is resistant to microbial attack, and its degradation is mainly through a physical breakdown. Polyacrylamide has been shown to be non-toxic to humans, animals, fish, and plants; the only concern has been the toxicity of its residual monomer (acrylamide) content, which is a known neurotoxin to humans. Polyacrylamide can also degrade to acrylamide under environmental conditions. The monomer degradable and does not accumulate in soils.

Water: (80%)

Natural product

2.24% Yes

FP-9LS Baker Hughes Antifoaming agent Toxicity - Constituent 1 (60%) Isononanol

LD50 oral rat: 3950 mg/kg

LC0 Rat(male/female): > 0.21 mg/l / 7 h / vapour

LD50 Rat(male/female): > 4,000 mg/kg dermal


Aerobic, Inoculum: Activated sludge

Exposure time: 28 d

Result: 79 % Readily biodegradable.

Method: (CO2; modif. Sturm test - 92/69/EEC part C.4-C)

Bioconcentration factor (BCF): 15.2

Significant concentrations do not accumulate.

The data are derived from the evaluations or test results achieved with similar products (conclusion by analogy).

logKOC: 2.17 (Soil)

Method: OECD TG 121

Water: (40%)

Natural product

0.34% Yes

R-21L Baker Hughes Cement retardant Toxicity - Constituent 1 (15%)

LD50 oral rat >4,000 mg/Kg

LC50 Rainbow Trout 7,300 ppm/48 h


LD50 oral rat >2,000 mg/Kg


Material is expected to biodegrade only very slowly (in the environment). Fails to pass OECD/EEC tests for ready biodegradability.

Water: (55%)

Natural product

0.11% Yes

Calcium Chloride Newpark Drilling Fluids

Weighting Agent Acute Toxicity:

CALCIUM CHLORIDE ANHYDROUS as an ingredient (10043-52-4):

LD50 (Ingestion): 1,000 mg/kg (rat)

0.09% Yes


HSE-E-075-SUM Rev 4


SDS Attached




LDLo (Ingestion): 1,384 mg/kg (rabbit)


LDLo (Subcutaneous): 249 mg/kg (cat)

TDLo (Intravenous): 20 mg/kg/1 hour (woman)

SODIUM CHLORIDE (7647-14-5):

LC50 (Inhalation): > 42,000 mg/m3/1 hour (rat)

LD50 (Ingestion): 3,000 mg/kg (rat)

LD50 (Intraperitoneal): 2,602 mg/kg (mouse)


LD50 (Skin): > 10,000 mg/kg (rabbit)

LD50 (Subcutaneous): 3,000 mg/kg (mouse)

LDLo (Ingestion): 8,000 mg/kg (rabbit)


LDLo (Subcutaneous): 2,160 mg/kg (guinea pig)

TDLo (Ingestion): 12,357 mg/kg (human)


Biodegradability does not pertain to inorganic substances. This product does not bioaccumulate.

Table 9c: Chemical List


Portland cement 65997-15-1 65.2%

Customer Supplied Mix Water 7732-18-5 30.0%

Crystalline silica, quartz 14808-60-7 3.43%

Water in Products 7732-18-5 0.912%

Humic acids, sodium salts, polymers with N,N-dimethyl-2- propenamide, sodium 2-methyl-2-[(1-oxo-2-propen-1-yl)amino]-1- propanesulfonate (1:1) and 2-propenenitrile, sodium bisulfite-

473268-27-8 0.301%

Sulfonated organic polymer 526203-62-3 0.0861%

Rape Oil 8002-13-9 0.0680%

Sodium Lignosulfonate 8061-51-6 0.0301%

Monopropylene glycol monooleate 1330-80-9 0.00386%

Aluminium stearate 637-12-7 0.000772%

Sorbitan, monopalmitate 26266-57-9 0.000772%

Contingency Volumes (Alternate Baker Hughes)

Water 7732-18-5 56.72658

Portland cement 65997-15-1 31.59


HSE-E-075-SUM Rev 4


Calcium Oxide 1305-78-8 2.106

Calcium Carbonate 1317-65-3 2.106

Gypsum 13397-24-5 4.212

Magnesium Oxide 1309-48-4 2.106

Silicon dioxide (colloidal) 69012-64-2 0.132

Na2O 1313-59-3 0.00132

Sodium Naphthalene Sulphonate 130-14-3 0.224

Acrylic copolymer 9003-06-9 0.448

Isononanol 27458-94-2 0.204

Sodium Lignosulphonate 8061-51-6 0.0165

Gluconic acid 526-95-4 0.0385

Calcium Chloride Anhydrous 10043-52-4 0.0873

Sodium Chloride 7647-14-5 0.0018

Total: 100.00% (excluding contingency)


HSE-E-075-SUM Rev 4

Appendix 4

Safety Data Sheets - Cementing


108 Poole st , Welshpool , WA, AUSTRALIA, 6106

+61 8 9350 3800

1800 988 778

+61 8 9350 5453

http://www.bakerhughes.com

BAKER HUGHES PRESSURE PUMPING

A-300L

CEMENT ADDITIVE

A300L • BAKER HUGHES A-300L

31 May 2011

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name



NOT CLASSIFIED AS A DANGEROUS GOOD BY THE CRITERIA OF THE ADG CODE

None Allocated None Allocated None Allocated


UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)


Ingredient Formula CAS No. Content

NON HAZARDOUS INGREDIENTS Not Available Not Available 100%

Eye If in eyes, hold eyelids apart and flush continuously with running water. Continue flushing until advised to stop by aPoisons Information Centre, a doctor, or for at least 15 minutes.

Skin If skin or hair contact occurs, remove contaminated clothing and flush skin and hair with running water. Continueflushing with water until advised to stop by a Poisons Information Centre or a doctor.


Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once). If swallowed,do not induce vomiting.

Advice to Doctor Treat symptomatically.


Fire andExplosion

No fire or explosion hazard exists.

Extinguishing Prevent contamination of drains or waterways.

Flammability Non flammable. May evolve toxic gases if strongly heated.



Page 1 of 4

Reviewed: 31 May 2011

Printed: 31 May 2011

RMT

A-300LProduct Name

Spillage If spilt (bulk), use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustibleabsorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Prevent spillentering drains or waterways. CAUTION: Spill site may be slippery.

Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs. Ensure containersare adequately labelled, protected from physical damage and sealed when not in use.

Storage

Before use carefully read the product label. Use of safe work practices are recommended to avoid eye or skincontact and inhalation. Observe good personal hygiene, including washing hands before eating. Prohibit eating,drinking and smoking in contaminated areas.


7. STORAGE AND HANDLING

8. EXPOSURE CONTROLS/ PERSONAL PROTECTIONExposure Stds No exposure standard(s) allocated.

No biological limit allocated.Biological Limits

EngineeringControls

Avoid inhalation. Use in well ventilated areas.

Wear splash-proof goggles and PVC or rubber gloves. When using large quantities or where heavy contaminationis likely, wear: coveralls.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance MILKY LIQUID Solubility (water) DISPERSIBLE

Odour MILD ODOUR Specific Gravity 1.2

pH 10.5 % Volatiles NOT AVAILABLE

Vapour Pressure NOT AVAILABLE Flammability NON FLAMMABLE

Vapour Density NOT AVAILABLE Flash Point NOT RELEVANT

Boiling Point 100°C Upper Explosion Limit NOT RELEVANT

Melting Point 0°C Lower Explosion Limit NOT RELEVANT

Evaporation Rate NOT AVAILABLE

Autoignition Temperature NOT AVAILABLE Decomposition Temperature NOT AVAILABLE

Partition Coefficient NOT AVAILABLE Viscosity NOT AVAILABLE

Chemical Stability Stable under recommended conditions of storage.

Conditions to Avoid Avoid heat, sparks, open flames and other ignition sources.


Material to Avoid Incompatible with oxidising agents and acids (eg. nitric acid). Contact with acids may cause product toform a gel.

HazardousDecompositionProducts

May evolve toxic gases if heated to decomposition.

Hazardous Reactions Polymerization is not expected to occur.

Page 2 of 4



RMT

A-300LProduct Name

Health HazardSummary

Low toxicity - low irritant. This product may present a hazard with direct eye contact or prolonged skin contact.Chronic effects are not anticipated.

Eye Low irritant. Contact may result in irritation, lacrimation and redness.

Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing.

Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.

Ingestion Low toxicity. Ingestion of large quantities may result in nausea, vomiting and gastrointestinal irritation.

Toxicity Data No LD50 data available for this product.


Environment This product is not anticipated to cause adverse effects to animal or plant life if released to the environment insmall quantities. Not expected to bioaccumulate.


Waste Disposal For small amounts, absorb with sand or similar and dispose of to an approved landfill site. Contact themanufacturer for additional information. Ensure that appropriate personal protective equipment is used duringdisposal.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated

Poison Schedule A poison schedule number has not been allocated to this product using the criteria in the Standard for the UniformScheduling of Drugs and Poisons (SUSDP).

AICS All chemicals listed on the Australian Inventory of Chemical Substances (AICS).


AdditionalInformation

ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.ADG - Australian Dangerous Goods.BEI - Biological Exposure Indice(s).CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.CNS - Central Nervous System.EC No - European Community Number.HSNO - Hazardous Substances and New Organisms.IARC - International Agency for Research on Cancer.mg/m³ - Milligrams per Cubic Metre.NOS - Not Otherwise Specified.pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm - Parts Per Million.RTECS - Registry of Toxic Effects of Chemical Substances.STEL - Short Term Exposure Limit.SWA - Safe Work Australia.TWA - Time Weighted Average.

HEALTH EFFECTS FROM EXPOSURE:It should be noted that the effects from exposure to this product will depend on several factors including: frequencyand duration of use; quantity used; effectiveness of control measures; protective equipment used and method ofapplication. Given that it is impractical to prepare a ChemAlert report which would encompass all possiblescenarios, it is anticipated that users will assess the risks and apply control methods where appropriate.

PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only.


Page 3 of 4



RMT

A-300LProduct Name

Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.

Report Status This document has been compiled by RMT on behalf of the manufacturer of the product and serves as themanufacturer's Safety Data Sheet ('SDS').

It is based on information concerning the product which has been provided to RMT by the manufacturer orobtained from third party sources and is believed to represent the current state of knowledge as to the appropriatesafety and handling precautions for the product at the time of issue. Further clarification regarding any aspect ofthe product should be obtained directly from the manufacturer.

While RMT has taken all due care to include accurate and up-to-date information in this SDS, it does not provideany warranty as to accuracy or completeness. As far as lawfully possible, RMT accepts no liability for any loss,injury or damage (including consequential loss) which may be suffered or incurred by any person as aconsequence of their reliance on the information contained in this SDS.


31 May 2011

End of ReportSDS Date

Page 4 of 4



RMT



+61 8 9350 3800

1800 988 778

+61 8 9350 5453



CD-31L

CEMENT ADDITIVE • DISPERSANT

100291 - ITEM NUMBER • 31L CD • BJ SERVICES CD-31L • CD 31L

31 May 2011

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name






UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)



DISPERSANT Not Available Not Available Not Available

SODIUM NAPHTHALENE SULPHONATE Not Available Not Available Not Available

WATER H2O 7732-18-5 Not Available




Ingestion For advice, contact a Poison Information Centre on 13 11 26 (Australia Wide) or a doctor (at once).


First Aid Facilities Eye wash facilities should be available.


Page 1 of 4



RMT

CD-31LProduct Name

Fire andExplosion

No fire or explosion hazard exists.





Spillage Contact emergency services where appropriate. Use personal protective equipment. Clear area of all unprotectedpersonnel. Ventilate area where possible. Contain spillage, then cover / absorb spill with non-combustibleabsorbent material (vermiculite, sand, or similar), collect and place in suitable containers for disposal. Eliminate allignition sources.

Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, heat or ignition sources andfoodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not inuse. Check regularly for leaks or spills. Large storage areas should have appropriate ventilation systems. Storebelow 4.4°C.

Storage






EngineeringControls


Wear splash-proof goggles and rubber or PVC gloves. When using large quantities or where heavy contaminationis likely, wear: coveralls. Where an inhalation risk exists, wear: a Type A (Organic vapour) respirator.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance CLEAR DARK BROWN LIQUID Solubility (water) SOLUBLE

Odour SLIGHT MOTH-BALL ODOUR Specific Gravity 1.0 (Approximately)

pH 9.0 to 10.5 % Volatiles NOT AVAILABLE

Vapour Pressure 18 mm Hg @ 20°C Flammability NON FLAMMABLE


Boiling Point 87.8°C to 101.7°C Upper Explosion Limit NOT RELEVANT

Melting Point 0°C (Approximately) Lower Explosion Limit NOT RELEVANT

Evaporation Rate AS FOR WATER



Page 2 of 4



RMT

CD-31LProduct Name




Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), heat and ignition sources.





Low toxicity. This product has the potential to cause adverse health effects with direct eye contact, prolonged skincontact or vapour inhalation in poorly ventilated areas. Use safe work practices to avoid eye or skin contact andvapour generation - inhalation.


Inhalation Low irritant. Over exposure may result in irritation of the nose and throat, with coughing. Due to the low vapourpressure, an inhalation hazard is not anticipated with normal use.

Skin Low irritant. Prolonged or repeated contact may result in mild irritation.




Environment Limited ecotoxicity data was available for this product at the time this report was prepared. Ensure appropriatemeasures are taken to prevent this product from entering the environment.


Waste Disposal Dispose of to an approved landfill site. Contact the manufacturer for additional information.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated





RESPIRATORS: In general the use of respirators should be limited and engineering controls employed to avoidexposure. If respiratory equipment must be worn ensure correct respirator selection and training is undertaken.Remember that some respirators may be extremely uncomfortable when used for long periods. The use of airpowered or air supplied respirators should be considered where prolonged or repeated use is necessary.

ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.ADG - Australian Dangerous Goods.BEI - Biological Exposure Indice(s).CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.CNS - Central Nervous System.EC No - European Community Number.HSNO - Hazardous Substances and New Organisms.IARC - International Agency for Research on Cancer.


Page 3 of 4



RMT

CD-31LProduct Name

mg/m³ - Milligrams per Cubic Metre.NOS - Not Otherwise Specified.pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm - Parts Per Million.RTECS - Registry of Toxic Effects of Chemical Substances.STEL - Short Term Exposure Limit.SWA - Safe Work Australia.TWA - Time Weighted Average.


PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only.Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.





31 May 2011


Page 4 of 4



RMT

SAFETY DATA SHEET

CFR-8LRevision Date: 24-Apr-2018 Revision Number: 21



1.1. Product Identifier Product Name CFR-8L

Other means of Identification Synonyms NoneHazardous Material Number: HM005627

Recommended use of the chemical and restrictions on use Recommended Use Cement DispersantUses advised against No information available


15 Marriott Road, Jandakot, WA 6164AustraliaACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300


Emergency phone number + 61 1 800 686 951Global Incident Response Access Code: 334305Contract Number: 14012




Classification of the hazardous chemical Not classified


Hazard Pictograms


Hazard Statements: Not Classified

_____________________________________________________________________________________________Page 1 / 7

_____________________________________________________________________________________________CFR-8L Revision Date: 24-Apr-2018


Prevention NoneResponse NoneStorage NoneDisposal None

ContainsSubstances CAS NumberContains no hazardous substances in concentrations abovecut-off values according to the competent authority

NA

Other hazards which do not result in classification This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT).This mixture contains no substance considered to be very persistent nor very bioaccumulating (vPvB).




Contains no hazardous substances in concentrationsabove cut-off values according to the competent authority

NA 60 - 100% Not classified


Description of necessary first aid measures Inhalation If inhaled, remove from area to fresh air. Get medical attention if respiratory

irritation develops or if breathing becomes difficult.Eyes In case of contact, immediately flush eyes with plenty of water for at least 15

minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Under normal conditions, first aid procedures are not required.

Symptoms caused by exposure No significant hazards expected.



Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.


_____________________________________________________________________________________________Page 2 / 7



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.


6.3. Methods and material for containment and cleaning up Isolate spill and stop leak where safe. Contain spill with sand or other inert materials. Scoop up and remove.


7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Keep container closed when not in use.Other GuidelinesNo information available


Control parameters - exposure standards, biological monitoring Exposure LimitsSubstances CAS Number Australia NOHSC ACGIH TLV-TWAContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA Not applicable Not applicable




Respiratory Protection Not normally necessary.

Hand Protection Nitrile gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system


9.1. Information on basic physical and chemical properties Physical State: Liquid Color Brown-blackOdor: Characteristic Odor Threshold: No information available

_____________________________________________________________________________________________Page 3 / 7


Property Values Remarks/ - Method pH: 9 - 11.3Freezing Point / Range -7 °CMelting Point / Range No data availableBoiling Point / Range 100 °C / 212 °FFlash Point No data availableEvaporation rate No data availableVapor Pressure < 18 mmHgVapor Density No data availableSpecific Gravity 1.17 - 1.2Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of sulfur.



Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.



Contains no hazardoussubstances inconcentrations abovecut-off values accordingto the competentauthority

NA No data available No data available No data available

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mechanical irritation to eye.Skin Contact None known.

_____________________________________________________________________________________________Page 4 / 7


Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.






Ecotoxicity

Substance Ecotoxicity DataSubstances CAS Number Toxicity to Algae Toxicity to Fish Toxicity to

MicroorganismsToxicity to Invertebrates

Contains nohazardous substancesin concentrationsabove cut-off valuesaccording to thecompetent authority

NA No information available No information available No information available No information available


Substances CAS Number Persistence and DegradabilityContains no hazardous substances inconcentrations above cut-off values according tothe competent authority

NA No information available



Contains no hazardous substances inconcentrations above cut-off values according tothe competent authority



Substances CAS Number MobilityContains no hazardous substances in concentrationsabove cut-off values according to the competent authority


12.6. Other adverse effects No information available

_____________________________________________________________________________________________Page 5 / 7

Endocrine Disruptor InformationThis product does not contain any known or suspected endocrine disruptors



Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.




Transportation Information Australia ADG

UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IMDG/IMO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable

IATA/ICAO UN Number Not restrictedUN proper shipping name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable


HazChem Code None Allocated




assessment certificate.New Zealand Inventory ofChemicals

Product contains one or more components not listed on inventory.



US TSCA Inventory Product contains one or more components not listed on the inventory.Canadian Domestic Substances List(DSL)

Product contains one or more components not listed on the inventory.


_____________________________________________________________________________________________Page 6 / 7


International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.



Revision Date: 24-Apr-2018

Revision NoteSDS sections updated:2




Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/



_____________________________________________________________________________________________Page 7 / 7




Product name CEMENT CLASS G

Synonym(s) 100021 - PRODUCT CODE


Use(s) CEMENT • MORTAR • OILFIELD APPLICATIONS


Supplier name BAKER HUGHES PRESSURE PUMPING

Address 108 Poole st, Welshpool, WA, Australia, 6106Telephone +61 8 9350 3800Fax +61 8 9350 5453Email Not suppliedWebsite http://www.bakerhughes.com


Emergency 1800 988 778



Risk phrases

R37/38 Irritating to respiratory system and skin.R41 Risk of serious damage to eyes.Safety phrases

S22 Do not breathe dust.S24/25 Avoid contact with skin and eyes.S37 Wear suitable gloves.

Other Hazards





PORTLAND CEMENT 65997-15-1 266-043-4 >60%CALCIUM OXIDE 1305-78-8 215-138-9 1 - 5%LIMESTONE (CALCIUM CARBONATE) 1317-65-3 215-279-6 1 - 5%GYPSUM 13397-24-5 603-783-2 5 - 10%MAGNESIUM OXIDE 1309-48-4 215-171-9 1 - 5%


Page 1 of 7Reviewed: 26 Nov 2014

Printed: 03 Aug 2016This report was compiled based on the SDS dated 05 Apr 2014







swallowed, do not induce vomiting.First aid facilities No information provided.



Irritating to the eyes, skin and respiratory system. Some Individuals may exhibit an allergic response upon exposure to this product,possibly due to the trace amounts of chromium present. Hexavalent chromium compounds are classified as carcinogenic to humans(IARC Group 1).






Non flammable. May evolve toxic gases if strongly heated.



5.4 Hazchem code

None allocated














Store in a cool, dry, well ventilated area, removed from moisture, incompatible substances and foodstuffs. Ensure packages areadequately labelled, protected from physical damage and sealed when not in use.









Exposure standards

Substance ReferenceTWA STEL

ppmppm mg/m³mg/m³

Calcium carbonate (Limestone, Marble,Whiting)

SWA (AUS) -- 10 -- --

Calcium oxide SWA (AUS) -- 2 -- --Gypsum (Calcium sulphate) SWA (AUS) -- 10 -- --Magnesium oxide (fume) SWA (AUS) -- 10 -- --Portland Cement SWA (AUS) -- 10 -- --

No biological limit values have been entered for this product.Biological limits


Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended.

PPE

Eye/Face Wear dust-proof goggles.Hand Wear PVC or rubber gloves.Body When using large quantities or where heavy contamination is likely, wear coveralls.Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator. At high dust levels, wear an Air-line

respirator or a Full-face Class P3 (Particulate) respirator.



Appearance GREY POWDEROdour ODOURLESSOdour Threshold NOT AVAILABLEpH NOT AVAILABLEMelting Point NOT RELEVANTBoiling Point NOT RELEVANTFlash Point NOT RELEVANTEvaporation Rate NOT AVAILABLEFlammability NON FLAMMABLEUpper Explosion Limit NOT RELEVANTLower Explosion Limit NOT RELEVANTVapour Pressure NOT AVAILABLEVapour Density NOT AVAILABLESolubility (water) SLIGHTLY SOLUBLEPartition Coefficient NOT AVAILABLEAutoignition Temperature NOT AVAILABLEDecomposition Temperature NOT AVAILABLEViscosity NOT AVAILABLEExplosive Properties NOT AVAILABLE





Oxidising Properties NOT AVAILABLESpecific Gravity 3.15




10.1 Reactivity









Incompatible with oxidising agents (e.g. hypochlorites), ethanol, acids (e.g. hydrofluoric acid) and interhalogens (e.g. chlorinetrifluoride). Water contact may increase product temperature 2°C to 3°C.

May evolve toxic gases if heated to decomposition.10.6 Hazardous decomposition products



Health hazardsummary

Slightly corrosive - irritant. This product has the potential to cause adverse health effects with over exposure.Use safe work practices to avoid eye or skin contact and inhalation. Once water is added, an inhalationhazard is not anticipated. Chronic respiratory effects are not anticipated with over exposure at high levelsdue to the immediate irritant and/or corrosive effects. Hexavalent chromium compounds are classified ascarcinogenic to humans (IARC Group 1).

Eye Corrosive - irritant. Contact may result in irritation, lacrimation, pain, redness, corneal burns and possiblepermanent damage. Severe irritant upon contact with powder/ dust.

Inhalation Slightly corrosive - irritant. Over exposure may result in irritation of the nose and throat, coughing andbronchitis. Hexavalent chromium is reported to cause respiratory sensitisation, however due to the traceamount present, a hazard is not anticipated under normal conditions of use.

Skin Slightly corrosive. Contact with powder or wetted form may result in rash and dermatitis. Some individualsmay exhibit an allergic response upon exposure to cement, possibly due to trace amounts of chromium.

Ingestion Slightly corrosive. Ingestion may result in burns to the mouth and throat, nausea, vomiting and abdominalpain. Ingestion is considered unlikely due to product form.

Toxicity data LIMESTONE (CALCIUM CARBONATE) (1317-65-3) LD50 (Ingestion): > 5000 mg/kg (rat)GYPSUM (13397-24-5) TCLo (Inhalation): 194 g/m³/10 years intermittently (human) TDLo (Ingestion): 450 mg/kg/3 weeks intermittently (rat)






12.1 Toxicity













Waste disposal Reuse or recycle where possible. Alternatively, ensure product is covered with moist soil to prevent dustgeneration and dispose of to an approved landfill site. Contact the manufacturer/supplier for additionalinformation (if required).






















CEMENT CONTACT DERMATITIS - Individuals using wet cement, mortar, grout or concrete could be at riskof developing cement dermatitis. Symptoms of exposure include itchy, tender, swollen, hot, cracked orblistering skin with the potential for sensitisation. The dermatitis is due to the presence of soluble(hexavalent) chromium.












Last Reviewed:26 Nov 2014Date Printed:03 Aug 2016

05 Apr 2014

End of Report

Based on SDS dated:



Safety Data Sheet Portland Cement - Dry Powder Blend

QUICK IDENTIFIER (See Section 1 Product Name)

SECTION 1- IDENTIFICATION OF PRODUCT AND COMPANY

Product: Export NeoSlurry & NeoSuperSlurry Systems, P/Ns: E0105-350-017, E0105-450-017 & E0105-300-017

Application: 5 gallon batch of cement slurry for dump bailers

Manufacturer’s NeoProducts, LLC

name:

Address: 1201 Dealers Ave. Emergency Telephone #: 504-731-1011

City, State, Zip: Harahan, LA 70123 e-mail: [email protected]

Signature of After hours calls will be answered by answering service.

person

responsible for

preparation Date Prepared: May 2019

(Optional):

SECTION 2- HAZARD IDENTIFICATION

Fire: This preparation is not flammable.

Health: Potentially hazardous during normal handling and use as instructed.

Environment: No known hazards.

Other Hazards: CAUTION! – ACUTE HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. May cause eye and respiratory irritation.

DANGER! – CHRONIC HEALTH HAZZARD This dry powder blend contains crystalline silica and quartz. Breathing crystalline silica can cause lung disease including silicosis and lung cancer. Crystalline silica has also been associated with scleroderma and kidney disease.

This product contains quartz, cristobalite, and/or tridymite, which may become airborne without a visible cloud. Use only with adequate ventilation to keep exposures below recommended exposure limits. Wear a NIOSH certified, European Standard EN 149 or equivalent respirator when using this product. Review the Material Safety Data Sheet (MSDS) for this product, which has been provided to your employer.

Pictograms:


SIGNAL WORD:..........................DANGER! GHS HAZARD AND PRECAUTIONARY STATEMENTS: H303 H313 H333: May be harmful if swallowed, in contact with skin or if inhaled

P101+102+103: If medical advice is needed, have product container or label at hand. Keep out of the reach of

children. Read label before use.

P202+270+280+281: Do not handle until all safety precautions have been read and understood. Do not eat, drink or smoke when using this product. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required.

SECTION 3- COMPOSITION/INFORMATION ON INGREDIENTS

Component(s) % OPT. Average Average CAS No. [chemical and common name(s)] (inhalable dust) (respirable

dust)

Portland Cement #2104 60.0 – 65.0 wgt % 10.0 mg/m3 4 mg/m3 65997-15-1

Silica Sand #2162 30.0 – 35.0 wgt % 0.3mg/m3 N/A 14808-60-6

Magnesium Oxide #2151 0 – 6.0 wgt % 10.0mg/m3 4mg/m3 1309-48-4

Suspension Agent #2099 0.50 – 3.0 wgt % N/A N/A 103115-52-2

Friction Reducer #2105 0.25 wgt % N/A N/A 9084-06-4

Cement Slurry Retarder #2117 1.0 – 4.0 wgt % N/A N/A 8061-51-6

Symbol(s): Xi, Xn

Risk Phrases: R36, R37, R38, R40

Safety Phrases: S22, S25, S36/37/39, S38

SECTION 4- FIRST AID MEASURES

Inhalation: Remove from area to fresh air.

Ingestion: First aid procedures are not required.

Skin: Wash with soap and water.

Eyes: Flush with plenty of water for at least 15 minutes.

SECTION 5- FIRE FIGHTING MEASURES

Extinguishing media: Product does not burn.

Special fire fighting precautions: None. Product does not burn.

Unusual fire and explosion hazards: No fire hazards.

SECTION 6- ACCIDENTAL RELEASE MEASURES

Personal precautions: Wear dust/mist respirator, work gloves and dust proof goggles.

Environmental: No environmental hazards reported.

Spillage: Use protective equipment, avoid creating or inhaling dust, sweep up and attempt to reuse product if not contaminated. Prevent entry into drains, sewers and watercourses.

SECTION 7- HANDLING AND STORAGE

Avoid contact with skin and eyes. Wear Approved work gloves, dust proof goggles and dust/mist respirator. Avoid creating

dust. Store in dry location in original container. Use only as instructed.

SECTION 8- EXPOSURE CONTROLS/ PERSONAL PROTECTION

Engineering controls: Use in well ventilated area.

Respiratory protection: Use approved dust/mist respirator.

Hand protection: Use normal work gloves.

Skin protection: Normal work coveralls.

Eye protection: Use dust proof goggles.

SECTION 9- PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Color: Odor: PH: Reactivity in Water:

Solid Gray Odorless Not Determined N/A

Vapor Density Solubility in Water Vapor Pressure Specific Gravity @ Flammable Limits in

(Air=1): (g/100ml): (mm HG): 20C (H2O=1): Air% by Volume:

Not Determined 0.5 Not Determined 3.15 Not Determined

Flash Point: LEL Lower: LEL Upper: Melting Point: Boiling Point:

Not Determined N/A N/A N/A Not Determined

SECTION 10- STABILITY AND REACTIVITY

Stability Data: Hazardous Conditions to avoid: Incompatibility Hazardous

Polymerization: (Materials to avoid): Decomposition or

Byproducts:

Stable Will not occur Avoid contact with water None known None known

SECTION 11- TOXICOLOGICAL INFORMATION

Principle route of exposure: Eye or Skin contact, Inhalation.

Inhalation: This dry powder blend contains crystalline silica and quartz. Inhaled crystalline silica in

the form of quartz or cristobalite from occupational sources is carcinogenic to humans

(IARC, Group 1). There is sufficient evidence in experimental animals for the

carcinogenicity of tridymite (IARC, Group 2A).

This dry powder blend contains crystalline silica and quartz. Breathing silica dust may

cause irritation of the nose, throat and respiratory passages. Breathing silica may cause

noticeable injury or illness even through permanent lung damage may be occurring.

Inhalation of dust may also have serious chronic health effects (See “Chronic Effects /

Carcinogenicity” subsection below).

Skin Contact: Wet cement can dry skin and cause Alkali burns.

Eye Contact: Dust can irritate eyes.

Ingestion: No harmful affects known.

Medical conditions aggravated by exposure: Dermatitis

Chronic effects/ Carcinogenicity:

Silicosis: Excessive inhalation of respirable crystalline silica dust may

cause a progressive, disabling and sometime-fatal lung disease called

silicosis. Symptoms include cough, shortened of breath, wheezing, non-

specific chest illness, and reduced pulmonary function. This disease is

exacerbated by smoking. Individuals will silicosis are predisposed to

develop tuberculosis.

Cancer Status: The International Agency for Research on Cancer (IARC)

has determined that crystalline silica inhaled in the form of quartz or

crystallite from occupational sources can cause lung cancer in humans

(Group 1 – carcinogenic to humans) and has determined that there is

sufficient evidence in experimental animals for the carcinogenicity of

tridymite (Group 2A – possible carcinogen to humans). Refer to IARC

Monograph 68, Silica, Some Silicates and Organic Fibers (June 1997) in

conjunction with the use of these minerals. The National Toxicology

Program classifies respirable crystalline silica as “Known to be a human

carcinogen”. Refer to the 9th Report of Carcinogens (2000). The

American Conference of Governmental Industrial Hygienists (ACGIH)

classifies crystalline silica, quartz, as a suspected human carcinogen

(A2).

There is some evidence that breathing respirable crystalline silica or the

disease silicosis is associated with an increased incidence of significant

endpoints such as acleroderma (an immune system disorder manifested

by scarring of the lungs, skin, and other internal organs) and kidney

disease.

Other Information

This dry powder blend contains quartz, crystalline, silica and quartz. For

further information consult “Adverse Effects of Crystalline Silica

Exposure” published by the American Journal of Respiratory and Critical

Care Medicine, Volume 155, pages 71-768 (1997).

Toxicity Tests/ Carcinogenicity: This dry powder blend contains quartz, crystalline, silica and quartz.

Refer to IARC Monograph 68, Silica, Some Silicates and Organic Fibers

(June 1997).

SECTION 12- ECOLOGICAL INFORMATION

Mobility (water/air/soil): Not Determined

Persistence/ Degradability: Not Applicable

Bio-Accumulation: Not Determined

Aquatic Toxicity: Not Determined

SECTION 13- DISPOSAL CONSIDERATIONS

Disposal Method: Consult Federal, State or Local regulations.

Contaminated Packaging: Follow all applicable national or local regulations.

SECTION 14- TRANSPORT INFORMATION

NO SPECIAL PRECAUTIONS NECESSARY

SECTION 15- REGULATORY INFORMATION

Hazardous Ingredients: None

Symbol(s): Xi , Xn

Risk Phrases:

R36 Irritating to eyes.

R37 Irritating to Respiratory System.

R38 Irritating to Skin.

R40 Limited evidence of a carcinogenic effect. (Lab test results on silica sand have shown limited evidence of a carcinogenic effect.)

Safety Phrases:

S22 Do not breathe dust.

S25 Avoid contact with eyes.

S36/37/39 Wear suitable protective clothing, gloves, and eye/face protection.

S38 In case of insufficient ventilation, wear suitable respiratory equipment.

SECTION 16- ADDITIONAL INFORMATION

Please read the Safety Data Sheet before using this or any NeoProducts items. This product is intended for the stated application only. Do not use this product for any other application without first obtaining guidance from an approved

NeoProducts employee beforehand.

If this product is for resale, make sure the purchaser receives a copy of this safety data sheet upon

acceptance of this preparation. Make sure the employees of your company are aware of the hazards,

both chronic and acute, before allowing them to use this product.

The information contained in this Safety Data Sheet is believed to be correct and reflects our best

professional judgment. Because it is impossible to anticipate every condition under which this

product will be used, this Safety Data Sheet shall only be used as a guide. It is imperative that each

user of this product determines its suitability for his particular application and comply with all

environmental and workplace regulations.

HMIS:

HEALTH 1

FLAMMABILITY 0

REACTIVITY 0

PERSONAL PROTECTION B

*HMIS®HAZARD INDEX: 0=Minimal Hazard, 1=Slight Hazard, 2=Moderate Hazard, 3=Serious Hazard,

4=Severe Hazard. HMIS® rating involves data interpretations that may vary from company to company. They

are intended only for rapid, general identification of the magnitude of the specific hazard. To deal adequately

with the safe handling of this material, all the information contained in this SDS and product label must be

considered.

REVISION STATEMENT: Changes have been made throughout this Safety Data Sheet (SDS). Please read the entire

document. Prepared according to the OSHA Hazard Communication Standard (29 CFR 1910.1200) and The Globally

Harmonized System of Classification and Labeling of Chemicals (GHS) by the Company Health and Risk Assessment

Unit.

DISCLAIMER: Although the information and recommendations set forth herein (hereinafter "Information") are presented in good faith and

believed to be correct as of the date hereof, the Company makes no representations as to the completeness or accuracy

thereof. Information is supplied upon the condition that the persons receiving this Safety Data Sheet (SDS) will make their

own determination as to its suitability for their intended purposes prior to use. Since the product is within the exclusive

control of the user, it is the user's obligation to determine the conditions of safe use of this product. Such conditions should

comply with all Federal and State Regulations concerning the Product. It must be recognized that the physical and

chemical properties of any product may not be fully understood and that new, possibly hazardous products may arise from

reactions between chemicals. The information given in this data sheet is based on our present knowledge and shall not

constitute a guarantee for any specific product features and shall not establish a legally valid contractual relationship. NO

REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY,

FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH

RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION REFERS.

***This is the last page of this SDS***



+61 8 9350 3800

1800 988 778

+61 8 9350 5453



FL-66L

CEMENT FLUID LOSS

488270, 488273 - ITEM NUMBER • BJ SERVICES FL-66L • FL - 66L

31 May 2011

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name






UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)



NON HAZARDOUS INGREDIENTS Not Available Not Available 100%







Fire andExplosion

Treat as per requirements for Surrounding Fires: Evacuate area and contact emergency services. Remain upwindand notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.





Page 1 of 4



RMT

FL-66LProduct Name

Spillage Use personal protective equipment. Contain spillage, then cover / absorb spill with non-combustible absorbentmaterial (vermiculite, sand, or similar), collect and place in suitable containers for disposal. CAUTION: Spill sitemay be slippery.

Handling

Store in a cool, dry, well ventilated area, removed from foodstuffs. Ensure containers are adequately labelled,protected from physical damage and sealed when not in use.

Storage






EngineeringControls


Wear splash-proof goggles and rubber or neoprene or PVC gloves. When using large quantities or where heavycontamination is likely, wear: coveralls.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance BROWN LIQUID Solubility (water) SOLUBLE

Odour SLIGHT ODOUR Specific Gravity 1.06

pH 7 % Volatiles NOT AVAILABLE



Boiling Point NOT AVAILABLE Upper Explosion Limit NOT RELEVANT

Melting Point NOT AVAILABLE Lower Explosion Limit NOT RELEVANT







Material to Avoid Compatible with most commonly used materials.




Page 2 of 4



RMT

FL-66LProduct Name


Low toxicity - low irritant. Use safe work practices to avoid eye or skin contact and inhalation. Due to the lowvapour pressure of this product, an inhalation hazard is not anticipated with normal use.



Skin Low irritant. Prolonged or repeated contact may result in mild irritation, rash and dermatitis.




Environment This product is not anticipated to cause adverse effects to animal or plant life if released to the environment insmall quantities. Not expected to bioaccumulate.


Waste Disposal Solutions: Cover with sodium carbonate (soda ash), lime or similar alkali to ensure pH greater than 8.5. Collectprecipitated solids in sealable containers and label accordingly. Solids: Dampen if necessary and avoid dustgeneration. Collect solids and store in sealable labelled containers. Absorb with soil and contact the manufacturerfor disposal instructions.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated







PERSONAL PROTECTIVE EQUIPMENT GUIDELINES:


Page 3 of 4



RMT

FL-66LProduct Name

The recommendation for protective equipment contained within this ChemAlert report is provided as a guide only.Factors such as method of application, working environment, quantity used, product concentration and theavailability of engineering controls should be considered before final selection of personal protective equipment ismade.





31 May 2011


Page 4 of 4



RMT



+61 8 9350 3800

1800 988 778

+61 8 9350 5453



FP-9L

ANTIFOAMING AGENT

BAKER HUGHES FP-9L • FP 9L

17 May 2011

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name



RISK PHRASESR36/37/38 Irritating to eyes, respiratory system and skin.

SAFETY PHRASESS36/37 Wear suitable protective clothing and gloves.S46 If swallowed, contact a doctor or Poisons Information Centre immediately and show container or label.




UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)



ISONONANOL C9-H20-O 27458-94-2 >60%






First Aid Facilities Eye wash facilities and safety shower should be available.


Page 1 of 4



RMT

FP-9LProduct Name

Fire andExplosion

Evacuate area and contact emergency services. Toxic gases may be evolved in a fire situation. Remain upwindand notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

Extinguishing Dry agent, carbon dioxide or foam. Prevent contamination of drains or waterways.

Flammability Combustible. May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.




Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents, acids, heat or ignition sources andfoodstuffs. Ensure containers are adequately labelled, protected from physical damage and sealed when not inuse. Large storage areas should have appropriate ventilation systems. Store as a Class C1 Combustible Liquid(AS1940).

Storage






EngineeringControls

Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extraction ventilation isrecommended.

Wear splash-proof goggles and rubber or PVC gloves. When using large quantities or where heavy contaminationis likely, wear: coveralls. Where an inhalation risk exists, wear: a Type A (Organic vapour) respirator.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance CLEAR COLOURLESS TO LIGHT

AMBER COLOURED LIQUIDSolubility (water) INSOLUBLE

Odour MILD ODOUR Specific Gravity 0.98 to 1.0

pH NOT AVAILABLE % Volatiles NOT AVAILABLE

Vapour Pressure NOT AVAILABLE Flammability CLASS C1 COMBUSTIBLE

Vapour Density NOT AVAILABLE Flash Point 105°C

Boiling Point > 200°C Upper Explosion Limit 6.0 %

Melting Point NOT AVAILABLE Lower Explosion Limit 0.9 %




Page 2 of 4



RMT

FP-9LProduct Name




Material to Avoid Incompatible with oxidising agents (eg. hypochlorites), acids (eg. nitric acid), heat and ignition sources.


May evolve toxic gases (carbon oxides, hydrocarbons) when heated to decomposition.



Low to moderate toxicity - irritant. This product has the potential to cause adverse health effects with overexposure. Use safe work practices to avoid eye or skin contact and inhalation. Over exposure may result in centralnervous system (CNS) effects.

Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns withprolonged contact.

Inhalation Irritant. Over exposure may result in irritation of the nose and throat, coughing and headache. High level exposuremay result in nausea, dizziness and drowsiness.

Skin Irritant. Contact may result in drying and defatting of the skin, rash and dermatitis. May be absorbed through skinwith harmful effects.

Ingestion Low to moderate toxicity. Ingestion may result in nausea, vomiting, abdominal pain, diarrhoea, dizziness anddrowsiness. Aspiration may result in chemical pneumonitis and pulmonary oedema.





Waste Disposal For small amounts absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact themanufacturer for additional information if larger amounts are involved. Prevent contamination of drains andwaterways as aquatic life may be threatened and environmental damage may result.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated





National Industrial Chemicals Notification and Assessment (NICNAS) Registration number: 2475.


WORK PRACTICES - SOLVENTS: Organic solvents may present both a health and flammability hazard. It isrecommended that engineering controls should be adopted to reduce exposure where practicable (for example, ifusing indoors, ensure explosion proof extraction ventilation is available). Flammable or combustible liquids with


Page 3 of 4



RMT

FP-9LProduct Name

explosive limits have the potential for ignition from static discharge. Refer to AS 1020 (The control of undesirablestatic electricity) and AS 1940 (The storage and handling of flammable and combustible liquids) for controlprocedures.








17 May 2011


Page 4 of 4



RMT

SAFETY DATA SHEET

HALAD® 413L CEMENT ADDITIVERevision Date: 07-May-2018 Revision Number: 26



1.1. Product Identifier Product Name HALAD® 413L CEMENT ADDITIVE


Recommended use of the chemical and restrictions on use Recommended Use Fluid Loss AdditiveUses advised against No information available










Hazard Pictograms



_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________HALAD® 413L CEMENT ADDITIVE Revision Date: 07-May-2018




NA






NA 60 - 100% Not classified








Suitable extinguishing equipment Suitable Extinguishing MediaAll standard fire fighting mediaExtinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireDecomposition in fire may produce harmful gases.


_____________________________________________________________________________________________Page 2 / 8



6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Wash hands after use. Launder contaminated clothing beforereuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.

7.2. Conditions for safe storage, including any incompatibilities Storage InformationStore away from oxidizers. Product has a shelf life of 24 months.Other GuidelinesNo information available







Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Not normally needed. But if significant exposures are possible then the following respiratoris recommended:Dust/mist respirator. (N95, P2/P3)

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system

_____________________________________________________________________________________________Page 3 / 8




Property Values Remarks/ - Method pH: 7.5Freezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range No data availableFlash Point No data availableEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.1Water Solubility Miscible with waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available



10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Oxides of nitrogen. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.





Physical State: Liquid Color Brown-blackOdor: Sweet Odor Threshold: No information available

_____________________________________________________________________________________________Page 4 / 8


Immediate, delayed and chronic health effects from exposure Inhalation None known.Eye Contact None known.Skin Contact None known.Ingestion None known.






Ecotoxicity















_____________________________________________________________________________________________Page 5 / 8




Safe handling and disposal methods Disposal should be made in accordance with federal, state, and local regulations.

















US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)

Product contains one or more components not listed on the inventory.

_____________________________________________________________________________________________Page 6 / 8



International Agreements Montreal Protocol - Ozone Depleting Substances: Does not apply.Stockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not apply.Basel Convention - Hazardous Waste: Does not apply.



Revision Date: 07-May-2018

Revision NoteSDS sections updated:2




Key abreviations or acronyms used bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per millionSTEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day


_____________________________________________________________________________________________Page 7 / 8




_____________________________________________________________________________________________Page 8 / 8

SAFETY DATA SHEET

HR-6L



1.1. Product Identifier Product Name HR-6L

Other means of Identification Synonyms: NoneProduct Code: HM000901

Recommended use of the chemical and restrictions on use Recommended Use Cement RetarderUses Advised Against No information available



ACN Number: 009 000 775Telephone Number: + 61 1 800 686 951Fax Number: 61 (08) 9455 5300

E-Mail address: [email protected]


Australian Poisons Information Centre24 Hour Service: - 13 11 26Police or Fire Brigade: - 000 (exchange): - 1100





Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

Revision Date: 29-Jan-2015 Revision Number: 13

_____________________________________________________________________________________________

Hazard Statements Not Classified


Prevention None

Response None

Storage None

Disposal None


NA

Other hazards which do not result in classification None known

Australia ClassificationFor the full text of the H-phrases mentioned in this Section, see Section 16

Classification Not ClassifiedRisk Phrases None




NA 60 - 100% Not Applicable








Suitable extinguishing equipment Suitable Extinguishing MediaWater fog, carbon dioxide, foam, dry chemical.Extinguishing media which must not be used for safety reasonsNone known.

_____________________________________________________________________________________________Page 2 / 8

HR-6L Revision Date: 24-Feb-2015

_____________________________________________________________________________________________Specific hazards arising from the chemical Special Exposure HazardsDecomposition in fire may produce harmful gases.

Special protective equipment and precautions for fire fighters Special Protective Equipment for Fire-FightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment.




7.1. Precautions for Safe Handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.






Personal protective equipment (PPE) Respiratory Protection Not normally necessary.

Hand Protection Normal work gloves.Skin Protection Normal work coveralls.Eye Protection Wear safety glasses or goggles to protect against exposure.Other Precautions None known.Environmental Exposure Controls No information available



_____________________________________________________________________________________________Page 3 / 8

Revision Date: 24-Feb-2015HR-6L

_____________________________________________________________________________________________

Property Values Remarks/ - Method pH: 9.5Freezing Point/Range No data availableMelting Point/Range No data availableBoiling Point/Range No data availableFlash Point > 98 °C / > 210 °F PMCCEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 1.21Water Solubility Soluble in waterSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature No data availableDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableLiquid Density 10.08 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical Stability Stable10.3. Possibility of Hazardous Reactions Will Not Occur10.4. Conditions to Avoid None anticipated10.5. Incompatible Materials Strong oxidizers.10.6. Hazardous Decomposition Products Oxides of sulfur. Carbon monoxide and carbon dioxide.



Sympotoms related to exposure Most Important Symptoms/EffectsNo significant hazards expected.






_____________________________________________________________________________________________Page 4 / 8

Odor Threshold: No information availablePhysical State: Liquid Color: Dark brown

HR-6L

Odor: Molasses

Revision Date: 24-Feb-2015

_____________________________________________________________________________________________

Immediate, delayed and chronic health effects from exposure Inhalation May cause mild respiratory irritation.Eye Contact May cause mild eye irritation.Skin Contact None known.Ingestion None known.





Substances CAS Number Skin corrosion/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Eye damage/irritationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable.

Substances CAS Number Skin SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Respiratory SensitizationContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Mutagenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Carcinogenic EffectsContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Reproductive toxicityContains no hazardoussubstances inconcentrations above cut-off

NA Not applicable

_____________________________________________________________________________________________Page 5 / 8


_____________________________________________________________________________________________values according to thecompetent authority

Substances CAS Number STOT - single exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number STOT - repeated exposureContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable

Substances CAS Number Aspiration hazardContains no hazardoussubstances inconcentrations above cut-offvalues according to thecompetent authority

NA Not applicable


















_____________________________________________________________________________________________Page 6 / 8


_____________________________________________________________________________________________


Safe handling and disposal methods This product is not regarded as hazardous waste. Dispose in accordance with local regulations.




Transportation Information UN Number: Not restrictedUN Proper Shipping Name: Not restrictedTransport Hazard Class(es): Not applicablePacking Group: Not applicableEnvironmental Hazards: Not applicable





International Inventories Australian AICS Inventory All components listed on inventory or are exempt.New Zealand Inventory ofChemicals


EINECS Inventory This product, and all its components, complies with EINECSUS TSCA Inventory All components listed on inventory or are exempt.Canadian DSL Inventory All components listed on inventory or are exempt.




Revision Date: 29-Jan-2015


Full text of R-phrases referred to under Sections 2 and 3None



_____________________________________________________________________________________________Page 7 / 8


_____________________________________________________________________________________________For questions about the Safety Data Sheet for this or other Halliburton products, contactChemical Stewardship at 1-580-251-4335.

Key abreviations or acronyms used bw – body weight CAS – Chemical Abstracts Service EC50 – Effective Concentration 50% LC50 – Lethal Concentration 50% LD50– Lethal Dose 50% LL50 – Lethal Loading 50% mg/kg – milligram/kilogram mg/L – milligram/liter NOEC – No Observed EffectConcentration OEL – Occupational Exposure Limit PBT – Persistent Bioaccumulative and Toxic ppm – parts per million STEL –Short Term Exposure Limit TWA – Time-Weighted Average vPvB – very Persistent and very Bioaccumulative h - hour mg/m3 -milligram/cubic meter mm - millimeter mmHg - millimeter mercury w/w - weight/weight d - day




_____________________________________________________________________________________________Page 8 / 8


SAFETY DATA SHEET

NF-6Revision Date: 16-Aug-2016 Revision Number: 28



1.1. Product Identifier Product Name NF-6


Recommended use of the chemical and restrictions on use Recommended Use DefoamerUses advised against No information available










Hazard Pictograms


_____________________________________________________________________________________________Page 1 / 8

_____________________________________________________________________________________________NF-6 Revision Date: 16-Aug-2016





NA






NA 60 - 100% Not Applicable




minutes and get medical attention if irritation persists.Skin Wash with soap and water. Get medical attention if irritation persists.Ingestion Do NOT induce vomiting. Give nothing by mouth. Obtain immediate medical

attention.




Suitable extinguishing equipment Suitable Extinguishing MediaCarbon dioxide, dry chemical, foam.Extinguishing media which must not be used for safety reasonsNone known.

Specific hazards arising from the chemical Special exposure hazards in a fireUse water spray to cool fire exposed surfaces. Decomposition in fire may produce harmful gases.

_____________________________________________________________________________________________Page 2 / 8

Special protective equipment and precautions for fire fighters


Special protective equipment for firefightersFull protective clothing and approved self-contained breathing apparatus required for fire fighting personnel.


6.1. Personal precautions, protective equipment and emergency procedures Use appropriate protective equipment. Avoid contact with skin, eyes and clothing. Avoid breathing vapors. Ensure adequateventilation.




7.1. Precautions for safe handling Handling PrecautionsAvoid contact with eyes, skin, or clothing. Avoid breathing vapors. Ensure adequate ventilation. Wash hands after use. Laundercontaminated clothing before reuse. Use appropriate protective equipment.Hygiene MeasuresHandle in accordance with good industrial hygiene and safety practice.





Appropriate engineering controls Engineering Controls A well ventilated area to control dust levels. Local exhaust ventilation should be used in

areas without good cross ventilation.



Respiratory Protection If engineering controls and work practices cannot keep exposure below occupationalexposure limits or if exposure is unknown, wear a NIOSH certified, European Standard EN149, AS/NZS 1715:2009, or equivalent respirator when using this product. Selection of andinstruction on using all personal protective equipment, including respirators, should beperformed by an Industrial Hygienist or other qualified professional.Organic vapor respirator with a dust/mist filter. (A2P2/P3)

Hand Protection Chemical-resistant protective gloves (EN 374) Suitable materials for longer, direct contact(recommended: protection index 6, corresponding to > 480 minutes permeation time as perEN 374): Polyvinylchloride gloves. (>= 0.7 mm thickness)This information is based on literature references and on information provided by glovemanufacturers, or is derived by analogy with similar substances. Please note that inpractice the working life of chemical-resistant protective gloves may be considerably shorter

_____________________________________________________________________________________________Page 3 / 8


than the permeation time determined in accordance with EN 374 as a result of the manyinfluencing factors (e.g. temperature). If signs of wear and tear are noticed then the glovesshould be replaced. Manufacturer's directions for use should be observed because of greatdiversity of types.

Skin Protection Normal work coveralls.Eye Protection Chemical goggles; also wear a face shield if splashing hazard exists.Other Precautions None known.Environmental Exposure Controls Do not allow material to contaminate ground water system



Property Values Remarks/ - Method pH: No data availableFreezing Point / Range No data availableMelting Point / Range No data availableBoiling Point / Range 182 °C / 360 °FFlash Point > 170 °C / > 340 °FEvaporation rate No data availableVapor Pressure No data availableVapor Density No data availableSpecific Gravity 0.93Water Solubility DispersibleSolubility in other solvents No data availablePartition coefficient: n-octanol/water No data availableAutoignition Temperature 385 °C / 725 °FDecomposition Temperature No data availableViscosity No data availableExplosive Properties No information availableOxidizing Properties No information available

9.2. Other information VOC Content (%) No data availableLiquid Density 7.70 lbs/gal


10.1. Reactivity Not expected to be reactive.10.2. Chemical stability Stable10.3. Possibility of hazardous reactions Will Not Occur10.4. Conditions to avoid None anticipated10.5. Incompatible materials Strong oxidizers.10.6. Hazardous decomposition products Hydrocarbons. Carbon monoxide and carbon dioxide.



Symptoms related to exposure Most Important Symptoms/Effects

Physical State: Liquid Color YellowOdor: Mild Odor Threshold:

_____________________________________________________________________________________________Page 4 / 8

No information available


No significant hazards expected.






Immediate, delayed and chronic health effects from exposure Product Information Under certain conditions of use, some of the product ingredients may cause the following:Inhalation May cause mild respiratory irritation.Eye Contact None known.Skin Contact None known.Ingestion May cause abdominal pain, vomiting, nausea, and diarrhea.






Ecotoxicity Product Ecotoxicity Data






_____________________________________________________________________________________________Page 5 / 8













Safe handling and disposal methods Incineration recommended in approved incinerator according to federal, state, and local regulations. Substance should NOT bedeposited into a sewage facility.

Disposal of any contaminated packaging Follow all applicable national or local regulations. Contaminated packaging may be disposed of by: rendering packaging incapableof containing any substance, or treating packaging to remove residual contents, or treating packaging to make sure the residualcontents are no longer hazardous, or by disposing of packaging into commercial waste collection.







_____________________________________________________________________________________________Page 6 / 8

Special precautions during transport


None









US TSCA Inventory All components listed on inventory or are exempt.Canadian Domestic Substances List(DSL)



International Agreements Montreal Protocol - Ozone Depleting Substances: Does not applyStockholm Convention - Persistent Organic Pollutants: Does not applyRotterdam Convention - Prior Informed Consent: Does not applyBasel Convention - Hazardous Waste: Does not apply



Revision Date: 16-Aug-2016





Key abreviations or acronyms used

_____________________________________________________________________________________________Page 7 / 8

bw – body weightCAS – Chemical Abstracts ServiceEC50 – Effective Concentration 50%LC50 – Lethal Concentration 50%LD50 – Lethal Dose 50%LL50 – Lethal Loading 50%mg/kg – milligram/kilogrammg/L – milligram/literNOEC – No Observed Effect ConcentrationOEL – Occupational Exposure LimitPBT – Persistent Bioaccumulative and Toxicppm – parts per million


STEL – Short Term Exposure LimitTWA – Time-Weighted AveragevPvB – very Persistent and very Bioaccumulativeh - hourmg/m3 - milligram/cubic metermm - millimetermmHg - millimeter mercuryw/w - weight/weightd - day

Key literature references and sources for datawww.ChemADVISOR.com/NZ CCIDCosmetic Ingredient Review



_____________________________________________________________________________________________Page 8 / 8



+61 8 9350 3800

1800 988 778

+61 8 9350 5453



R-21L

RETARDANT

21L R • 488066 - ITEM NUMBER • BJ SERVICES R-21L • R 21L

31 May 2011

Fax

Supplier Name

Address

Telephone

Emergency

Web Site

Synonym(s)

Use(s)

SDS Date

Product Name






UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)



WATER H2O 7732-18-5 >60%

SODIUM LIGNOSULPHONATE Not Available Not Available Not Available






First Aid Facilities Eye wash facilities should be available.


Fire andExplosion

Treat as per requirements for Surrounding Fires: Evacuate area and contact emergency services. Remain upwindand notify those downwind of hazard. Wear full protective equipment including Self Contained BreathingApparatus (SCBA) when combating fire. Use waterfog to cool intact containers and nearby storage areas.

Flammability Non flammable. May evolve toxic gases if strongly heated. May evolve carbon oxides and sulphur oxides whenheated to decomposition.


Page 1 of 4



RMT

R-21LProduct Name




Handling

Store in a cool, dry, well ventilated area, removed from oxidising agents, acids and foodstuffs. Ensure containersare adequately labelled, protected from physical damage and sealed when not in use. Check regularly for leaks orspills.

Storage






EngineeringControls


Wear splash-proof goggles and PVC or rubber gloves. When using large quantities or where heavy contaminationis likely, wear: coveralls.

PPE

9. PHYSICAL AND CHEMICAL PROPERTIESAppearance BROWN LIQUID Solubility (water) SOLUBLE

Odour SLIGHT ODOUR Specific Gravity 1.296

pH 9.5 to 10.5 (3% solution) % Volatiles NOT AVAILABLE


Vapour Density 1.21 (Air = 1) Flash Point NOT RELEVANT

Boiling Point 101.7°C Upper Explosion Limit NOT RELEVANT

Melting Point -1.1°C Lower Explosion Limit NOT RELEVANT

Evaporation Rate AS FOR WATER






Material to Avoid Incompatible with oxidising agents and acids (eg. nitric acid).


May evolve carbon oxides and sulphur oxides when heated to decomposition.


Page 2 of 4



RMT

R-21LProduct Name


Low toxicity - irritant. Use safe work practices to avoid eye or skin contact and inhalation. Over exposure mayresult in irritation.

Eye Irritant. Contact may result in irritation, lacrimation, pain, redness and conjunctivitis. May result in burns withprolonged contact.


Skin Irritant. Contact may result in irritation, redness, rash and dermatitis. Prolonged or repeated contact may result inburns.






Waste Disposal For small amounts absorb with sand, vermiculite or similar and dispose of to an approved landfill site. Contact themanufacturer for additional information if larger amounts are involved. Prevent contamination of drains andwaterways as aquatic life may be threatened and environmental damage may result.







Shipping Name

UN No.

Packing Group

DG Class

Hazchem Code

Subsidiary Risk(s)

None Allocated






EXPOSURE STANDARDS - TIME WEIGHTED AVERAGES: Exposure standards are established on the premiseof an 8 hour work period of normal intensity, under normal climatic conditions and where a 16 hour break betweenshifts exists to enable the body to eliminate absorbed contaminants. In the following circumstances, exposurestandards must be reduced: strenuous work conditions; hot, humid climates; high altitude conditions; extendedshifts (which increase the exposure period and shorten the period of recuperation).

ABBREVIATIONS:ACGIH - American Conference of Industrial Hygienists.ADG - Australian Dangerous Goods.BEI - Biological Exposure Indice(s).CAS# - Chemical Abstract Service number - used to uniquely identify chemical compounds.CNS - Central Nervous System.EC No - European Community Number.HSNO - Hazardous Substances and New Organisms.IARC - International Agency for Research on Cancer.mg/m³ - Milligrams per Cubic Metre.NOS - Not Otherwise Specified.pH - relates to hydrogen ion concentration using a scale of 0 (high acidic) to 14 (highly alkaline).ppm - Parts Per Million.


Page 3 of 4



RMT

R-21LProduct Name

RTECS - Registry of Toxic Effects of Chemical Substances.STEL - Short Term Exposure Limit.SWA - Safe Work Australia.TWA - Time Weighted Average.







31 May 2011


Page 4 of 4



RMT





Synonym(s) CALCIUM CHLORIDE ANHYDRATE


Use(s) CONCRETE CONDITIONER • DESICCANT • DUST CONTROL AGENT • FOOD ADDITIVE • INDUSTRIALAPPLICATIONS



Address 11 Alacrity Place, Henderson, WA, Australia, 6166Telephone +61 8 9410 8200Fax +61 8 9410 8299Email Not suppliedWebsite http://www.newpark.com


Emergency 1800 127 406 (Australia); +64 3 3530199 (International)



Risk phrases

R36 Irritating to eyes.Safety phrases

S22 Do not breathe dust.S24 Avoid contact with skin.

Other Hazards





CALCIUM CHLORIDE ANHYDROUS 10043-52-4 233-140-8 94 - 97%SODIUM CHLORIDE 7647-14-5 231-598-3 1 - 5%WATER 7732-18-5 231-791-2 1%






swallowed, do not induce vomiting.First aid facilities Eye wash facilities and safety shower should be available.



Irritating to the eyes and skin.










Non flammable. May evolve toxic gases (chlorides) when heated to decomposition.



5.4 Hazchem code

None allocated



















Exposure standards


Biological limits No Biological Limit Value allocated.


Engineering Controls Avoid inhalation. Use in well ventilated areas. Where an inhalation risk exists, mechanical extractionventilation is recommended. Maintain dust levels below the recommended exposure standard.

PPE





Eye/Face Wear dust-proof goggles.Hand Wear PVC or rubber gloves.Body When using large quantities or where heavy contamination is likely, wear coveralls.Respiratory Where an inhalation risk exists, wear a Class P1 (Particulate) respirator.



Appearance WHITE POWDEROdour ODOURLESSOdour Threshold NOT AVAILABLEpH 7.0 to 9.0Melting Point 772°CBoiling Point > 1600°CFlash Point NOT RELEVANTEvaporation Rate NOT RELEVANTFlammability NON FLAMMABLEUpper Explosion Limit NOT RELEVANTLower Explosion Limit NOT RELEVANTVapour Pressure NOT AVAILABLEVapour Density NOT AVAILABLESolubility (water) 590 kg/m³ (Approximately)Partition Coefficient NOT AVAILABLEAutoignition Temperature NOT AVAILABLEDecomposition Temperature NOT AVAILABLEViscosity NOT AVAILABLEExplosive Properties NOT AVAILABLEOxidising Properties NOT AVAILABLESpecific Gravity 2.15




10.1 Reactivity







Avoid contact with incompatible substances.


Incompatible with acids (e.g. nitric acid), methyl vinyl ether, zinc/ galvanised metals, bromine trifluoride, boron oxide and calcium oxide.May react exothermically with water (i.e. releasing heat).

10.6 Hazardous decomposition products





May evolve toxic gases (chlorides) when heated to decomposition.



Acute toxicity Based on available data, the classification criteria are not met. Toxicity Data available for the ingredients:CALCIUM CHLORIDE ANHYDROUS (10043-52-4): LD50 (Ingestion): 1000 mg/kg (rat) LD50 (Intraperitoneal): 210 mg/kg (mouse) LD50 (Intravenous): 42 mg/kg (mouse) LD50 (Subcutaneous): 823 mg/kg (mouse) LDLo (Ingestion): 1384 mg/kg (rabbit) LDLo (Intravenous): 150 mg/kg (guinea pig) LDLo (Subcutaneous): 249 mg/kg (cat) TDLo (Intravenous): 20 mg/kg/1 hour (woman)SODIUM CHLORIDE (7647-14-5): LC50 (Inhalation): > 42000 mg/m3/1 hour (rat) LD50 (Ingestion): 3000 mg/kg (rat) LD50 (Intraperitoneal): 2602 mg/kg (mouse) LD50 (Intravenous): 645 mg/kg (mouse) LD50 (Skin): > 10000 mg/kg (rabbit) LD50 (Subcutaneous): 3000 mg/kg (mouse) LDLo (Ingestion): 8000 mg/kg (rabbit) LDLo (Intravenous): 300 mg/kg (guinea pig) LDLo (Subcutaneous): 2160 mg/kg (guinea pig) TDLo (Ingestion): 12357 mg/kg (human)


Eye Irritating to the eyes. Contact may result in irritation, lacrimation, pain and redness.


Carcinogenicity Insufficient data available to classify as a carcinogen.


STOT - singleexposure

Not classified as causing organ effects from single exposure.


Not classified as causing organ damage from repeated exposure.


Sensitisation Not classified as causing skin or respiratory sensitisation.






12.1 Toxicity



Biodegradability does not pertain to inorganic substances.


This product does not bioaccumulate.






























Last Reviewed:17 Apr 2015Date Printed:29 Jul 2016

17 Apr 2015

End of Report

Based on SDS dated:

