pahs pah - دانشگاه آزاد اسلامی واحد...
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PAHs
PAH
PAHsPAHs
-Polycyclic Aromatic Hydrocarbons(PAHs)
PAHs
PAHs
PAHs
PAH
PAH
PAH
PAH
PAHs
PAHs
-Stirred aqueous batch reactor
-Lysimeter
DIN CEN/TS
L/S
PAHs
Hewlett-Packard
US EPA
PAHs
PAHs
mg/kg
PAHs
PAHs
PAHs
L/S
PAHs
PAHs
PAHs
PAHs
PAHs
PyreneFluoranthene
PAH
PAHs
PAHs
g/molmg/l
logKow
Naphthalene C H
Acenaphthene C H
Benzo(a)anthracene C H
Dibenz(a,z)anthracene C H
Indeno) -c,d(pyrene C H
L/S
Acenaphthene
Dibenz(a,z)anthracene
Indeno) -c,d(pyrene
Dibenz(a,z)anthraceneIndeno) -
c,d(pyrene
PAHs
PAHs
Kow
Kow
Kow
Naphthalene
Acenaphthelen
Kowlog Kow
KowDibenz(a,z)anthracene
Indeno) -c,d(pyrene
PAHs
PAHs
PAH
PAHs
Enell
PAHs
PAHs
PAHs
L/S
0
2000
4000
6000
8000
10000
12000
Nap
2-M
Nap
1-M
Nap Any Ace FlnPhe
Ant Fth PyBaA Chr
Bbf-BkF
BaP
Inden
o
DahA
BghiP
C (
µg/k
g)
PAHs
PAHs
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Nap
0
0.5
1
1.5
2
2.5
3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Nap
Naphtalene
0
10
20
30
40
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Ace
0
200
400
600
800
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Ace
Acenaphtalene
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
BaA
0
1
2
3
4
5
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg
/kg]
BaA
Benzo(a)anthracene
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
DahA
0
0.5
1
1.5
2
2.5
3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
DahA
Dibenz(a,h)anthracene
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Indeno
0
0.5
1
1.5
2
2.5
3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Indeno
Indeno) -c,d(pyrene
0
10
20
30
40
50
60
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
] Sum PAHs
0
200
400
600
800
1000
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Sum PAHs
PAHs
0
0.1
0.2
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Nap
0
0.1
0.2
0.3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Nap
Naphthalene
0
4
8
12
16
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Ace
0
20
40
60
80
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Ace
Acenaphtalene
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
DahA
0
1
2
3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
DahA
Benzo(a)anthracene
0
0.1
0.2
0.3
0.4
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
DahA
0
1
2
3
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
DahA
Dibenz(a,h)anthracene
0
1
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Indeno
0
1
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Indeno
Indeno) -c,d(pyrene
0
5
10
15
20
0 4 8 12 16 20
LS [L/kg]
C [
µg/L
]
Sum PAHs
0
50
100
150
0 4 8 12 16 20
LS [L/kg]
Cum
ulat
ive
Rel
ease
[µg/
kg]
Sum PAHs
PAHs
PAH
Indeno) -c,d(pyreneBenzo(a)anthracene
PAH
Benzo(a)anthracene
PAHs
PAHs
PAHs
PAH
PAHs
L/S
L/S
. Krauss, M., Wilcke, W. and Zech,
W. .Availability of polycyclic
aromatic hydrocarbons (PAHs) and
polychlorinated biphenyls (PCBs) to
earthworms in urban soils.
Environmental Science and
Technology,Vol. ,pp. -
. Grathwohl, P., . Diffusion in
Natural Porous Media: Contaminant
Transport, Sorption /Desorption and
Dissolution Kinetics,
Boston/Dordrecht/London: Kluwer
Academic Publishers.
. Kalbe,U.,Berger,W.,Eckardt ,J. and
Simon ,F., .Evaluation of leaching
and extraction procedures for soil and
waste",Waste
management,Vol. ,pp. -
. Oleszczuk,P. and Baran
,S., .Leaching of Individual PAHs
in Soil Varies with the Amounts of
Sewage Sludge Applied and Total
Organic Carbon Content. Polish
Journal of Environmental
Studies,Vol. ,pp. -
. Baran S., Oleszczuk P. and
Baranowska E., .Degradation of
soil environment in post flooding area.
Content of polycyclic aromatic
hydrocarbons (PAHs) and striating
herbicide. Journal of Environmental
Science and Health Part B-Pesticides
Food Contaminants and Agricultural
Wastes, Vol. , pp. - .
. Zanst, K., .Comparison of
Leaching Tests for PAHs
Contaminated Soils. MSc Thesis,
Center for Applied Geosciences,
University of Tubingen, Germany.
. Grathwohl, P. & Van der Sloot, H.,
. Groundwater risk assessment at
contaminated sites (GRACOS): test
methods and modeling approaches. In
Quevauviller, P. (ed.): Groundwater
Science and Policy, pp. . RSC
Publishing, Cambridge, UK.
. Grathwohl, P. & Susset, B.,
.Comparison of percolation to
batch and sequential leaching tests:
Theory and data. Waste Management,
Vol . , pp. .
. Enell, A., Reichenberg, F., Warfvinge,
P. & Ewald, G., .A column
method for determination of leaching
of polycycling aromatic hydrocarbons
from aged contaminated soil.
Chemosphere, Vol. , pp. .
. Kan, A., Hunter, G., Chen, W., Ward,
C. & Tomson, M. ( ) Irreversible
sorption of neutral hydrocarbons to
sediments: experimental observations
and model predictions. Environmental
Science and Technology, Vol. ,
pp. .
. DIN."CEN/TS , .
Characteristics of waste leaching
behavior tests-Up flow percolation
tests (under specified conditions),
Brussels: European Committee for
Standardization.
. US EPA, .Method
,Polynuclear aromatic
hydrocarbons,United States
Environmental Protection Agency.
. Enell, A., Reichenberg, F., Warfvinge,
p. And Ewald, G., . A column
method for determination of leaching
of polycycling aromatic hydrocarbons
from aged contaminated
soil.Chemosphere, Vol. , pp. -
.
. Grathwhol, P.and Susset, B.,
.Comparison of percolation to
batch and sequential leaching tests:
Theory and data", Waste Management,
Vol. , pp. - .
. Zhang, Y., Zhu, S., Xiao, R., Wang, J.
and Li, F., .Vertical transport of
polycyclic aromatic hydrocarbons in
different particle-size fraction of sandy
soils", Environmental Geology,
Vol. , pp. - .
. Roskam, G.D.and Comans, R.N.,
.Availability and leaching of
polycyclic aromatic hydrocarbons:
controlling processes and comparision
testing methos.Waste Management,
Vol. , pp. - .
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