pacpyro slow-pyrolysis technology: waste to energy and biochar

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PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar Adriana Downie WasteMINZ Rotorua 2011

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Page 1: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

PacPyro Slow-Pyrolysis Technology:

Waste to Energy and Biochar

Adriana Downie

WasteMINZ – Rotorua 2011

Page 2: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar
Page 3: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Technology Design Objectives • Quality controlled product – biochar (energy)

• Energy Efficiency

• Emissions control (air

quality, greenhouse gases)

• Workplace Health and Safety

• Economic viability Traditional utilisation of residual rice

hulls as charred soil amendment.

Page 4: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar
Page 5: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Product Optimisation

Page 6: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Technology Overview

• Creates clean electrical and thermal energy

• Solves organic waste problems

• Reduces landfill & waste hauling

• Increases sustainability and productivity of

agriculture

• Mitigates greenhouse gases

• Sequesters atmospheric carbon long-term

Page 7: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

PacPyro Project Value Areas

Waste $

Disposal or tipping fee

Biochar

Soil Amendment $

Carbon Storage $

Energy $

Excess energy

integrated into

waste facility,

embedded

customer and/or

grid

Page 8: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

• Multiple Revenue Streams

• Volume reduction –

concentration of carbon and

nutrients. Dry product. Access

to broader markets.

• Improved Greenhouse Gas

outcomes

• Feedstock Blends (plastics

contamination, oversize)

Advantages for Organics Management

Page 9: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

The ‘Waste’ Challenge

• Contamination • Consistency

Target ‘waste’ that is of a quality that will make a

quality biochar product of environmental benefit

OR

Reduce the volume of waste, achieve energy

recovery, stabilise carbon and send char residue to

landfill

Page 10: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Quality ‘Waste’ Organics for

Biochar Production

Page 11: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

PacPyro Commercialisation

Approach

• Technology Development and Demonstration

• Product Marketability – Biochar and Bioenergy

• Lifecycle Sustainability and Risk Management

• Strategically Supported Commercial Readiness

Project Delivery

Page 12: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Technology Development

El Torro ~ 40kg/hr dry biomass Daisy ~ 10kg batch dry biomass

Page 13: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Pilot Scale Production

Page 14: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Commercial Greenwaste Project

PacPyro has been offered $4.5 million dollars by the Victorian

State Government to assist in building a project for the

conversion of waste organics to renewable energy and biochar.

Page 15: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Viable Project Requirements

• Site

• Sustainable Feedstock

• Energy off-take

• Biochar off-take

• Stakeholders

– project structure

Return hurdles that reflect first-of-kind project risk

Page 16: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

PacPyro Commercialisation

Approach

• Technology Development and Demonstration

• Product Marketability – Biochar and Bioenergy

• Lifecycle Sustainability and Risk Management

• Strategically Supported Commercial Readiness

Project Delivery

Page 17: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

• Carbon Offsets – Biochar

production can result in a

net sequestration of

carbon.

• Soil Health – some

biochars have been

scientifically demonstrated

to improve soil health and

improve crop yields.

Key Attributes of Biochar

Page 18: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Greenhouse Assessment

Page 19: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

• Carbon Offsets – Biochar

production can result in a

net sequestration of

carbon.

• Soil Health – some

biochars have been

scientifically demonstrated

to improve soil health and

improve crop yields.

Key Attributes of Biochar

Page 20: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Independent Third Party Trials PacPyro has worked closely with research institution of

high reputation since 2006 on AgricharTM biochar

research.

- MOU with Industry and Investment NSW

- ARC industry linkage program with UNSW

- Collaborative research partners on the DAFF National

Biochar Research program headed by CSIRO

- Member of the committee of the Australian and NZ

Biochar Researchers Network

- Founding members of the International Biochar

Initiative

- Key supplier of research grade biochar internationally

Page 21: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Peer-Reviewed Scientific Literature

Page 22: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Meta-Analysis of Biochar and

Crop Productivity

Statistically significant, benefit of biochar application to soils

on crop productivity, with a grand mean increase of 10%.

Page 23: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

PacPyro acquisition - ASX

• PacPyro acquired the global rights to the

technology from Best Energies Inc.

• ASX listed company WAG has exercised their

option to acquire Pacific Pyrolysis Pty Ltd.

• WAG is currently undergoing a capital raising

for working capital, finalisation of technology

licensing package and project delivery. Adriana Downie – Kyoto, 2011

Page 24: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

www.pacificpyrolysis.com

www.anzbiochar.org

Page 25: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

1

BIOCHAR AND BIOENERGY FROM WASTE ORGANICS – A NEW Z EALAND PERSPECTIVE

Author: Adriana Downie, Chief Technology Officer, Pacific Pyrolysis Pty Ltd

[email protected]

Introduction

Several local governments groups and corporations in New Zealand are considering

the adoption of slow-pyrolysis technology for the management of waste organics

under their management. Pacific Pyrolysis (PacPyro) have a proprietary technology

solution that has been demonstrated on a pilot scale to convert a large range of

waste organic feedstocks into bioenergy (electricity and thermal) and biochar. The

identified potential for the technology in the New Zealand market is large. The

abundance of low-grade organic residues, and requirements for; increased

renewable energy at a distributed level, greenhouse gas emissions offsets, and

locally produced agricultural soil amendments, provide a framework for the business

case of slow-pyrolysis projects.

PacPyro have been undertaking feasibility studies in New Zealand for clients that

investigate the technical and economic viability of producing bioenergy and biochar

from waste organic resources. The key drivers to such projects, the barriers to

commercialisation, and the progress made to date will be discussed. Project

feasibility parameters will be evaluated to assist waste managers to understand and

assess the opportunity that utilising the technology may bring to their businesses.

Progress has been made on understanding possible outlets for biochar products in

the New Zealand market.

The PacPyro Slow-Pyrolysis Technology

PacPyro is a world leader in the development of waste to energy and biochar

technology. Their award winning slow pyrolysis technology delivers an innovative

Page 26: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

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solution that redefines best practice for waste and low grade feedstock management

by achieving the co-production of bioenergy and carbon products.

The PacPyro technology converts biomass residues, such as kerb-side collected

organics, into renewable energy and a proprietary biochar called Agrichar™, which

has been proven by independent trials to increase food production and sequester

carbon over long periods of time. PacPyro’s slow pyrolysis technology provides

carbon negative (removes CO2 from the atmosphere) renewable energy through

sequestration of carbon, long-term, via stabilisation into biochar.

The PacPyro technology platform is based on slow-pyrolysis, which is the thermo-

chemical decomposition of organic material at elevated temperatures in the absence

of oxygen. The feed material is dried and fed into an externally heated kiln. As the

material passes through the kiln, it reacts to produce an off-gas (syngas), which is

continuously removed from the kiln and utilised for its energy value in much the

same way as natural gas or liquid petroleum gas (LPG). The pyrolysis syngas can

be piped to a local consumer of thermal energy such as steam boilers, dryers and

absorption chillers, or can be converted to electricity using a reciprocating engine

generator. The electricity is then available for local consumption, embedded into

existing operations, or can be distributed to a much broader market through the

power supply network. A portion of the syngas produced is used to sustain the

process. This makes the pyrolysis plant highly efficient. Minimal external utility

inputs are required, even for wet, low energy feed materials.

PacPyro has an operational continuous flow slow pyrolysis pilot demonstration

facility (see Figure 1 below), at the Somersby Advanced Engineering Facility north of

Sydney.

Page 27: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

Figure 1: PacPyro Demonstration Facility

PacPyro has process and mechanical designs for 48 (2 tph) and 96 (4 tph) dry tonne

per day commercial units (PyroChar 2000 and PyroChar 4000 respectively). Three

dimensional modelling of the 48 t

Figure 2: PyroChar 2000 plant, designed for municipal green waste and wood waste

blends

Solution Delivery – Project Drivers

PacPyro has conducted several feasibility studies on the application of their

commercial scale pyrolysis process for local government and industry partners. The

ability to combine process engineering and mechanical design expertise with

commercial business development, economic modelling and project financing

PacPyro Demonstration Facility

PacPyro has process and mechanical designs for 48 (2 tph) and 96 (4 tph) dry tonne

per day commercial units (PyroChar 2000 and PyroChar 4000 respectively). Three

48 tonne per day unit design can be seen below.

PyroChar 2000 plant, designed for municipal green waste and wood waste

Project Drivers

PacPyro has conducted several feasibility studies on the application of their

commercial scale pyrolysis process for local government and industry partners. The

ability to combine process engineering and mechanical design expertise with

s development, economic modelling and project financing

3

PacPyro has process and mechanical designs for 48 (2 tph) and 96 (4 tph) dry tonne

per day commercial units (PyroChar 2000 and PyroChar 4000 respectively). Three

onne per day unit design can be seen below.

PyroChar 2000 plant, designed for municipal green waste and wood waste

PacPyro has conducted several feasibility studies on the application of their

commercial scale pyrolysis process for local government and industry partners. The

ability to combine process engineering and mechanical design expertise with

s development, economic modelling and project financing

Page 28: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

4

capability is a core competitive strength of PacPyro. Areas where PacPyro aim to

provide solutions by delivering project using their technology are set out in the table

below:

Waste Management

• Provide waste management solutions for a wide range of source separated organic wastes destined for landfill or low value applications. • Improving the efficiency of existing manufacturing and industrial processes through transformation of waste products to usable energy and products. • Decreasing mass and volume and hence haulage cost of bulky and wet organics. • Reducing the carbon liability associated with organics waste management.

Energy Security

• Provide access to cheaper/more competitive energy pricing and reducing the impact of the escalating costs (financial and social) of fossil fuel based energy. • Securing access to a more dependable or redundant energy supply. • Utilising renewable energy from sustainable local project resources, which are not influenced by international political and market pressures.

Minimising and/or avoiding

environmental rents

• Achieve reduction in carbon liability (greenhouse gas emissions mitigation and sequestration). • Meet demand for renewable energy. • Delivers on need for land remediation or rehabilitation. • Reduce run-off and nutrient leaching (from fertiliser usage) into water ways. • Reduce requirement for landfill (avoid levies).

Improving agronomic outcomes through biochar

• Increased productivity with decreased inputs. • Improved soil health for degraded soils. • Water security through improved water holding capacity of soils.

Page 29: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

5

Corporate Commitment to “green” image

• Improved environmental footprint. • Achieve sustainability credentials for products. • Achieve vertical integration of energy from waste.

Land Use

• Extending the life of urban landfills. • Reduced agricultural clearing through increased productivity per hectare. • Decreased requirement to mine fossil fuels and new energy resources.

Atmospheric Greenhouse Gas

• Achieve the complementary blending of emission mitigation with the drawing down of carbon from the atmosphere into long term terrestrial sinks.

The Business Case – What makes a feasible project?

PacPyro have been working with clients to conduct feasibility studies for commercial

projects, utilising their technology, with the aim to establishing one or more

commercial demonstration projects in the coming years. As is the case with

commercialising new technology in any industry, overcoming the return hurdle

required for a first-of-kind project is challenging as it must be high to mitigate the

unknown elements of the project.

Projects implementing the technology can derive revenue stream from one or more

of the following:

• Biochar sales;

• Energy sales such as electricity or thermal energy generated from syngas

products;

• Environmental offsets such as policy driven fiscal incentives for greenhouse

gas emissions abatement, renewable energy generation, waste reduction

(avoided landfill levies), etc;

• Organics waste management charges - perhaps offsetting landfill tipping fees.

Page 30: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

6

PacPyro have found that for the first projects to reach their financial targets it is

necessary for all of the above revenue streams to be achieved. However if one or

more of the revenue streams is performing above market rates, due to some

niche circumstance, then this takes the pressure off the other sources of revenue.

Biochar Markets

It is proposed that biochar be sold into the higher value home gardening and

horticultural markets as an ingredient in growing media or potting mixes or as a

product in its own right. Products that are currently well established in this market

include materials such as; perlite, vermiculite, rockwool, scorcia, peat, hydroton (clay

pebbles), coir, horticultural barks.

PacPyro have been world leaders in fostering the scientific development of biochar

products as soil amendments through the production and provision of biochar to

research groups, actively collaborating in research programs and through publishing

findings in the peer-reviewed scientific literature. The biochar product from the

PacPyro pyrolysis process continues to attract scientific, political and industry

attention due to its demonstrated benefits as a soil amendment that can beneficially

sequester carbon. PacPyro’s technology platform ensures the production of a

highly quality controlled and sustainable, AgricharTM biochar product. PacPyro brings

a wealth of biochar research knowledge, developed as a result of its collaborations

with many research institutions of high regard, to their projects. This enhances the

marketability of biochars produced by the PacPyro technology.

Page 31: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

7

Figure 3: AgricharTM Biochar made from crop residue (wheat straw) and an SEM

micrograph showing the highly developed porous structure of AgricharTM biochar.

Some benefits of biochar products have been set out in the table along with

quantitative estimates of the benefits concerned. It is noted that not all biochars

have the same impacts in all soils and the crop productivity results depend on many

factors including soil, biochar, crop, and climate.

Table 1: Biochar Advantaged and Benefits

Advantage Example of Potential Benefit

Increase water holding capacity of the

soil

27% in field water capacity (Chan et al.,

2007)

Increase biomass (crop) production Up to 320% (Nehls, 2002)

Increase soil carbon levels Increase proportional to quantity of

biochar introduced (1-2% increases

easily achieved with standard application

rates). Further consequential labile

carbon accumulation has been observed

(Van Zwieten et al., 2010c).

Improve fertiliser use efficiency Nitrogen inputs can be reduced by up to

Page 32: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

8

90% while achieving the same crop

growth response (Van Zwieten et al.,

2010a).

Increase soil pH Increases of up to 2.6 pH units observed

(Van Zwieten et al., 2010b).

Decrease aluminium toxicity Inhibiting levels of aluminium can be

reduced to below detection limits using

biochar for soil remediation (Van Zwieten

et al., 2008).

Decrease tensile strength Tensile strength of hard setting soils

reduced by 70% (Chan et al., 2007).

Change microbiology of the soil Biochar has been demonstrated to

improve mycorrhizal colonisation

(Solaiman et al., 2010).

Decrease emissions from soil of the

greenhouse gases

Up to 86% reduction of applied nitrogen

lost as N2O observed (Van Zwieten et al.,

2009). Complete suppression of CH4

observed (Rondon et al., 2005).

Improve soil conditions for earthworm

populations

Earthworms have shown a preference for

ferrosol soil amended with biochar (Van

Zwieten et al., 2010b).

Increase CEC, especially over the long-

term

Increases in CEC of approximately 300%

have been measured in biochar treated

soils over the long term (Downie et al.,

2011).

Page 33: PacPyro Slow-Pyrolysis Technology: Waste to Energy and Biochar

9

Conclusions

PacPyro are making significant progress in commercialising their slow-pyrolysis

technology for the conversion of waste organics to bioenergy and biochar. There is

significant potential for the New Zealand waste management sector to benefit for the

utilisation of such technology to deliver a number of solutions. Establishing a

commercial-scale demonstration project, along with developing markets for biochar

products will be critical to reducing the technical and commercials risks associated

with the technology so that it can be rolled-out extensively into multiple project

opportunities.

References

Chan, K.Y., Van Zwieten, L., Meszaros, I., Downie, A., Joseph, S., 2007. Agronomic values of greenwaste biochar as a soil amendment. Aust J Soil Res 45, 629-634. Downie, A.E., Van Zwieten, L., Smernik, R.J., Morris, S., Munroe, P.R., 2011. Terra Preta Australis: Reassessing the carbon storage capacity of temperate soils. Agriculture, Ecosystems Environment 140, 137-147. Rondon, M.A., Ramirez, J., Lehmann, J., 2005. Charcoal additions reduce net emissions of greenhouse gases to the atmosphere. Third USDA Symposium on greenhouse gases and carbon sequestration, Baltimore, p. 208. Solaiman, Z.M., Blackwell, P., Abbott, L.K., Storer, P., 2010. Direct and residual effect of biochar application on mycorrhizal root colonisation, growth and nutrition of wheat. Aust J Soil Res 48, 546-554.

Van Zwieten, L., Kimber, S., Downie, A., Morris, S., Petty, S., Rust, J., Chan, K.Y., 2010a. A glasshouse study on the interaction of low mineral ash biochar with nitrogen in a sandy soil. Aust J Soil Res 48, 569-576. Van Zwieten, L., kimber, S., downie, A., Sinclair, K., Chan, K.Y., 2008. Field assessment of Biochar: Agronomic performance and soil fertility. International Biochar Initiative, Newcastle, UK. Van Zwieten, L., Kimber, S., Morris, S., Chan, K.Y., Downie, A., Rust, J., Joseph, S., Cowie, A., 2010b. Effects of biochar from slow pyrolysis of papermill waste on agronomic performance and soil fertility. Plant Soil 327, 235-246. Van Zwieten, L., Sinclair, K., Slavich, P., Morris, S.G., Kimber, S., Downie, A., 2010c. Influence of biochar on soil fertility, carbon storage and biomass production in a subtropical pasture: results from a 3 year field study. International Biochar Conference, Rio De Janeiro, Brazil.

Van Zwieten, L., Singh, B., Joseph, S., Kimber, S., A., C., Chan, K.Y., 2009. Biochar and Emissions of Non-CO2 Greenhouse Gases from Soil. In: Lehmann, J., Joseph, S. (Eds.), Biochar for Environmental Management: Science and Technology. Earthscan, London.