ozone/aop - pilot installation sustainable water use in ... offers/advanced... · cod reduction in...

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DISSEMINATION R&D Application, ITT Water & Wastewater Herford GmbH M. Bromen, Dr. J. Mielcke, J. Vogt* [email protected], Tel. +49 (0) 5221 930 221 | AquaFit4Use | The AquaFit4use project aims at a more sustainable use of water in the main water consuming industries. Through development and implementation of new, reliable and cost-effective technologies, tools and methods, a far-going closure of the water cycle in these industries is foreseen. Consequently, the intake of fresh water and the disposal of wastewater will be reduced significantly as will the burden imposed by this on the environment. | Pilot plant - technical data | » Flow: 0.7 - 5 m³/h » Max. ozone production: 1 kg/h » Max. energy consumption: 40 KW » Oxygen is required as feed gas. » Space required (container): 3 m * 6 m (20’-container) »H 2 O 2 -dosing station up to 90 g H 2 O 2 per m 3 water » Defoamer-dosing station Ozone/AOP - Pilot Installation Sustainable Water Use in the Chemical Industry Ozone/AOP- Pilot installation at Perstorp AB / Sweden: | Case Study - Chemical Industry | Goal: COD reduction in final wastewater effluent for water reuse in cooling tower; COD below 100 mg/l required. 1. Existing effluent from treatment plant at Perstorp AB 2. Effluent of pilot Membrane-Bio-Reactor Treatment: Ozone treatment (O 3 -dosage: 0 - 700 mgO 3 /m 3 ) Ozone-H 2 O 2 (AOP) (same range, surplus of H 2 O 2 ) | COMPETITIVE ADVANTAGES | Even non biodegradable contaminants, that couldn’t be degraded in the WWTP, were reduced. Persistent COD can be reduced below COD = 100 mg/l by combining Ozone and H 2 O 2 . Water quality is now sufficient for being reused as cooling tower water. Flow scheme of the Ozone/AOP pilot system Responsibilities of Wedeco: SP3.1 Evaluation of relevant treatment processes, data mining, lab test of industrial (paper, chemicals) waste water to design a pilot installation. SP5.1 Pilot trials in paper industry SP5.2 Pilot trials in chemicals industry. SP6 Knowledge transfer Ozone/H 2 O 2 tests on WWTP effluent CSB reduction on different O3 dosages 0 50 100 150 200 250 0 100 200 300 400 500 600 700 Dosis O3 in (mg/l) CSB (mg/l) CSB out CSB in Ozonetest on WWTP effluent CSB reduction on different O3 dosages 0 50 100 150 200 250 0 100 200 300 400 500 600 700 Dosis O3 in (mg/l) CSB (mg/l) CSB out CSB in

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DISSEMINATION

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R&D Application, ITT Water & Wastewater Herford GmbHM. Bromen, Dr. J. Mielcke, J. Vogt*[email protected], Tel. +49 (0) 5221 930 221

| AquaFit4Use |

The AquaFit4use project aims at a more sustainable use of water in the main water consuming industries. Through development and implementation of new, reliable and cost-effective technologies, tools and methods, a far-going closure of the water cycle in these industries is foreseen. Consequently, the intake of fresh water and the disposal of wastewater will be reduced significantly as will the burden imposed by this on the environment.

| Pilot plant - technical data |

» Flow: 0.7 - 5 m³/h» Max. ozone production: 1 kg/h» Max. energy consumption: 40 KW» Oxygen is required as feed gas.» Space required (container): 3 m*6 m (20’-container)» H2O2-dosing station up to 90 g H2O2 per m3

water

» Defoamer-dosing station

Ozone/AOP - Pilot Installation Sustainable Water Use in the Chemical Industry

Ozone/AOP- Pilot installation at Perstorp AB/Sweden:

| Case Study - Chemical Industry |

Goal:

COD reduction in final wastewater effluent for water reuse in cooling tower; COD below 100 mg/l required.

1. Existing effluent from treatment plant at Perstorp AB

2. Effluent of pilot Membrane-Bio-Reactor

Treatment:

Ozone treatment (O3-dosage: 0 - 700 mgO3/m3)

Ozone-H2O2 (AOP) (same range, surplus of H2O2)

| COMPETITIVE ADVANTAGES |

� Even non biodegradable contaminants, that couldn’t be degraded inthe WWTP, were reduced.

� Persistent COD can be reduced below COD = 100 mg/l by combiningOzone and H2O2.

� Water quality is now sufficient for being reused as cooling towerwater.

Flow scheme of the Ozone/AOP pilot system

Responsibilities of Wedeco:SP3.1 Evaluation of relevant treatment processes, data mining, lab test of industrial (paper, chemicals) waste water to design a pilot installation.

SP5.1Pilot trials in paper industry

SP5.2Pilot trials in chemicals industry.

SP6 Knowledge transfer

Ozone/H2O2 tests on WWTP effluent

CSB reduction on different O3 dosages

0

50

100

150

200

250

0 100 200 300 400 500 600 700

Dosis O3 in (mg/l)

CSB

(mg/

l)

CSB outCSB in

Ozone test on WWTP effluent

CSB reduction on different O3 dosages

0

50

100

150

200

250

0 100 200 300 400 500 600 700

Dosis O3 in (mg/l)

CSB

(mg/

l)

CSB outCSB in