new mexico state university department of chemistry and ... 092413 item 18 uraniumabatement.pdf ·...

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New Mexico St a Department o d i h and Bioch Antonio Jamie Jamie Nick B Emilio Jared Do Seal Ortega Erika V Beau B a te University of Chemistry h i hemistry o Lara Dr. Robert Marquez e Vela e Vela Beltran Rivera omenico aRodriguez V elasco adonie

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Page 1: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

New Mexico StaDepartment o

d i hand BiochAntonioJamieJamieNick BEmilio 

Jared DoSeal Ortega

Erika VBeau B

ate Universityof Chemistry h ihemistryo Lara Dr. Robert Marqueze Velae VelaBeltranRiveraomenicoa‐RodriguezVelascoadonie

Page 2: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Sh h t kShare what we kno

Abatement  ‐

Meet partners inMeet partners in pr

Share what we nShare what we n

b t U iow about Uranium 

Potable Water

this endeavor tothis endeavor to roduce Potable water

need to succeedneed to succeed

Page 3: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Uranium Abatemeare beyond proof‐of‐conc

ppropriate Solution – Motommunity involvement/shommunity involvement/sh

Partnership     ‐ Conesources to include dispoesources, to include dispoSoil Samples, Uranium Stdudentshat We Need to Succeedontacts/consultants  ‐ Sup

ent  ‐ Potable Watercept, so ……

ther Earth Heals hare ‐ Collaborate/hare     Collaborate/ ntacts/consultantosal (cradle to grave)osal (cradle‐to‐grave)tandards, Water samples

pport the continuation

Page 4: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Appropriat

^  Water purification, safe p

Abate pathogens, toxicAbate pathogens, toxic^  Simple, inexpensive hous^ Provide^  Provide

Household systemW k h h lthWorkshops – health, mSharing quality control

^  Clay Pellets (Mother Earth

te Solution

potable waterfrom ANY water sourc

c heavy metals, uraniumc heavy metals, uraniumsehold systems

th d li l imethod, sampling, analysis , self‐sustainingh provides)

Page 5: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

y Pellets (Mother Earth):

What’s NOT Appropriate:  RWhole 

(N(NHistorical origins ‐ Dr. Robe

M iMexico

BUT in water, clay makes a 

Clay Pellets (

RO and Distillation and House Kinetic Degradation 

Next 4 slides)Next 4 slides)rt Marquez’s work in √o  √

mud suspension

(Mother Earth)

Page 6: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

DistillationPrice $549 95Price $549.95

Price $129To To

Where?

Page 7: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Reverse Osmosis

Now what???

Page 8: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Whole House Kinetic(KD(

How does KDF Work? I h t th KDF d kIn short, the KDF redox process workcontaminants. This "give and take" ofcontaminants into harmless componeare transferred between molecules aare transferred between molecules, aharmful contaminants are changed inare electrochemically bound to the K

Degradation Fluxion DF))

BUY NOW IN USA!

US $359.95+ $19.95 shipping

k b h i l t ith ks by exchanging electrons with f electrons converts many ents. During this reaction, electrons

and new elements are created Some and new elements are created. Some nto harmless components. Others

KDF media.

Page 9: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Whole House Kinetic (KDF)( )

Metn+ • x(H O) y(OH-)Metn+ • x(H2O) y(OH-)

OnlOnl

0n = 0 or n = y

Solubility is very pH

Degradation Fluxion

; (x + y typically = 6); (x + y typically = 6)

ly ifly if

I l bl Insoluble

H and pE dependent

Page 10: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

ICP/MS ReB i S ilBerino Soil

Uranium Abatement Concentration

n ppb

Con

cent

ration in 

100 200 300 400 500

C

Time in Minutes

esultsG ll S ilGallup Soil

500

Uranium Abatement Concentration

400

200

300

100

0

0 100 200 300 400 500

Time in Minutes

Page 11: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

MKMK--3 Resu3 Resu

10/15/2013

ultsults

Page 12: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

MKMK--4: Com4: Commparemparepp

10/15/2013

Page 13: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal
Page 14: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

WHY SWHY S

ManageableManageableManageableManageable

Will not leaWill not leaInexpensiveInexpensive

Robust (Temperature, Robust (Temperature, Redox, pH)Redox, pH)

SOILS?SOILS?

Safe to transportSafe to transport

achach

Safe to transportSafe to transport

Ease of final disposalEase of final disposal

Vitrification for added safetyVitrification for added safety

Page 15: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Researrch Lab

Page 16: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal
Page 17: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Arroyo water beefore & after

Page 18: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

oyo water at start of fil

Arr

lter process

royo water after 10 h

Page 19: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Arroyo water aftter 10 hours

Page 20: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Potable water, pouring for p gimmediate consumptionp

SimpleSimpleInexpensiveLong life-timeNo energyNo energyNo moving partsElegant

Page 21: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Appropriatepp pCla

Universally avay$$$$

simsource

 Technologygyaysyilable materials$$ ↓$$ ↓ple, easyp , ye of income

Page 22: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Sustainable, long-term

S li ( l t d)

, g

Sampling  (unregulated)

Materials

Student funding

ICP/MS,instrumentationICP/MS,instrumentation

m Quality Assurance

)

Q y

)

n vs outsourcingn vs outsourcing

Page 23: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

ReseLS 55 L iLS 55 Luminescen

Allows measurment 

Uranium Nitrate or Uranyl NitrateUranyl Nitrate

UO2(NO3)2 • 6H2O

When exposed to ultraviolet light, U is visible as a faint green glow

earchSnce Spectrometer

of phosphorescence

U l Nit t      Uranyl Nitrate 100 ppm phosphorescing

Page 24: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

ICPICP--(Inductively Coupled Pla(Inductively Coupled Pla

--MS MS asma asma –– Mass SpectrometerMass Spectrometer

Page 25: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

LC‐MSGasGas chromatogra– mass spectromete

Page 26: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Surface /Surface / AnaAna

Pore SizePore Sizelyzerlyzer

Page 27: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

HandheldHandheld

X Ray FluorimeterX‐Ray Fluorimeter

Page 28: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Problem

What we kno

Quality assuranceQ y

Time TableTime Table

Friends Friends

C l iConclusion

ow / Methods

Page 29: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Time TableP f f t (B h M d l)Proof-of-concept (Bench Model)

L b /P ll f b i iLab prototype/Pellet fabrication

Prototype in- Situ, Tsaile, or Ch

Full system, to include their owdistribution, dissemination, qua

e))

bli i i n-publication in process

hapter Site chosen

wn pellet fabrication, pellet ality assurance

Page 30: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

Assistanc•Info for proposals

Illnesses/Deaths/Comp•Strong Letters of RecoStrong Letters of Reco•Funding Sources1. ICPMS/Materials/A2 Stipends2. Stipends3. Continue with the T

e Needed

pensation- Statisticsmmendationmmendation

Analysis

ime Table

Page 31: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal

ay pellets will abate uraniumIn a nu

ay pellets will abate uranium

When optimized, pellets can be any other contaminants world

ocial Entrepreneurship . $$$ for pellet makerPellet fabrication and dissem. Pellet fabrication and dissem

. Pellet Fate

Healthier Society

utshell

used for other heavy metals adwide

minationmination 

Page 32: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal
Page 33: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal
Page 34: New Mexico State University Department of Chemistry and ... 092413 Item 18 UraniumAbatement.pdf · New Mexico Sta Department o and Bihioch Antonio Jamie Nick B Emilio Jared Do Seal