mirasil silicones for personal care - thirthrajthirthraj.com/images/mirasil.pdf4 methylchlorosilanes...

Mirasil ® Siliconesfor Personal Care

2

Index� Silicones in Bluestar Silicones

• Synthesis …… 3• 4 different chemistries …… 4• What are silicones? Structure, properties …… 5-8

� Personal care range: Mirasil Brand• Brand name & INCI …… 9• Mirasil CM 5 …… 10• Mirasil HMS …… 11• Mirasil DM 50 to DM 5000 …… 12• Mirasil DM 60 000 to DM 500 000 …… 13• Mirasil ADM 211 / ADM 403 …… 14• Mirasil ADMH 395 / ADMH 3900 …… 15• Mirasil ADMH B100 …… 16• Mirasil ADME-P …… 17• Mirasil ADM-E 235C / ADM-E 257C (In development) …… 18• Mirasil ADMH-E 125 …… 19• Mirasil DMCO …… 20• Mirasil C-DMP …… 21• Mirasil C-DM / C-DMB …… 22• Mirasil C-DML …… 23• Mirasil D-DML …… 24• Mirasil PTM …… 25• Mirasil C-DPDM / P-DPDM …… 26• Mirasil Bright …… 27• Mirasil Micropearl 40 …… 28

� Technical and documental support …… 29

3

� Si : silicon the highest concentration on earth after oxygen

2+SiO C Si

polymerization

+Si

CH3

CH3

Cl Cl H2O

3

siloxanes

Si O Si

CH3CH3

CHCH3high Mw

� Hydrolysis

3chlorosilanes

+Si ClCH3 Si

CH3

CH

Cl Cl

� Bluestar direct synthesis

Silicone Synthesis

4

Methylchlorosilanes (MCS)

Intermediates (Cyclics, gums, D5, DM... )

Performanceconcentrates

Emulsions RTV HCR/LSR

silicium

methanol

silica

HCl

Great intermediates

Fine Chemistry

Chemical Specialities &Formulations

Mix & FixCenters®

MeCl

Marketing & Taylor-made

solutions

4 different chemistries

5

What are Silicones?

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3109°°°°

140°°°°

CH3H3C

Inorganic siloxane backbone with methyl/organic pendant groups

-Si-O-Si-O- -CH3

Polydimethylsiloxane polymer “ DIMETHICONE ”

� Various chemical substitutions: phenyl, alkyl,amino, polyether functionalities

6

PROPERTIES

Thermal stability

Resistance to naturalageing

Lubricating and softeningproperties

Exceptionally harmless

Permeable to gas

Spredability

Dielectric properties

Modular hydrophobic andorganophobic properties

Good fire resistance

Modular from release toadhesion

Creativity of the World of Organics (O)

Strength of the Mineral (Si)Strength of the Mineral (Si)

What makes Silicones original

•

•

•

•

•

•

•

••

7

High spreadingEasy wetting

Low intermolecular forces

HydrophobicityOrientates at surface

Low surface tension

Various viscosityWide range of Polymer length

Non occlusivity

Highly polar & strongintermolecular forces

Water resistance

Barrier effect

Spreads easily

Lubricates hair and skin

Low thermal sensitivity

Flexibility of polymer chain

Stability

Minimises pore clogging

Various effect intensity

Properties BenefitsStructure

A unique structure various benefits

Methyl groups

Siloxane chain

Mirasil ®

Product range

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Brand names & INCI

CM 5

ADME-P

DM 50 - 5000

DMCO

High purity products

Emulsions

Dimethicones

HMS

C-DMP

DM 60000 - 500000

MIRASIL PRODUCTS PRODUCT INCI

Dimethicones Copolyols

Cyclopentasiloxane

Water (and)amodimethicone (and) Trideceth-6

Dimethicone

PEG/PPG 22/24 Dimethicone

Hexametildisiloxane

Cyclopentasiloxane (and) PEG/PPG-18/18-Dimethicone

Dimethicone

C-DMC-DMB

PTM

Performance concentrates

C-DPDM

D-DMLD-DML LV & HV

Phenyl functional silicone

P-DPDM

Cyclopentasiloxane (and) Dimethicone Cyclopentasiloxane (and) Dimethiconol

Phenyl TrimethiconeCyclopentasiloxane (and) DiphenylDimethicone

Dimethicone (and) Dimethiconol

Phenyl Trimethicone (and) DiphenylDimethicone

C-DMLC-DML LV & HV

PRODUCT INCI

ADMH-E 125 Water,propoxytetramethylpiperi-dinyldimethicone (and) Trideceth-6

ADM 211 Amodimethicone ADM 403 Amodimethicone

ADMH 395ADMH 3900

ADMH B100

Amino functional silicone

PropoxytetramethylpiperidinylDimethicone

C15-19 alkane (and) Propoxytetramethyl-piperidinyldimethicone

ADM-E 235CWater (and) amodimethicone (and) Trideceth-12 (and) Cetrimonium chloride

BRIGHT C15-19 alkane (and) DiphenylDimethicone

Powder resin Micropearl 40 Polymethylsilsesquioxane

Indevelopment

10

INCI: Cyclopentasiloxane

Mirasil CM 5

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

Features CharacteristicsAdvantages in

formulationCosmetic benefits

Uselevels

��High purity ��Decamethylcyclopentasiloxane > 97.0%��Octamethylcyclotetrasiloxane < 0.9%��Decamethylcyclopentasiloxane + Dodecamethylcyclohexasiloxane >99.7%

��Medium volatile fluid

��Appearance……… .. Clear liquid

��Viscosity (mm 2/s) …………..... 3.9

��Specific gravity (kg/m 3) ……...950

��Refractive index ………… ... 1,395

��Flash point (ºC)……………… ... 80

��Surface tension (mN/m)…… .18,3

��Transient carrier for actives delivery

��Improves pigment distribution

��Excelent spreading properties

��Non comedogenic emolient

��Soft, dry skin feel

1%to

10%

11

INCI: Hexamethyldisiloxane

Mirasil HMS

(CH3)3Si-O-Si(CH3)3

Features Characteristics Advantages in formulation Cos metic benefitsUse

levels

��Not greasy volatile carrier

��Appearance………… .. Clear liquid

��Viscosity (mm2/s) ………… .... 0.65

��Specific gravity (kg/m 3) ….…...760

��Refractive index ………… .. . 1,375

��Flash point (ºC)…………… .……- 5

��Surface tension (mN/m)…… ..15,3

��Improves spreading properties

��Improves pigment distribution

��Excellent spreading properties

��Leaves no residue

��Soft, dry skin feel

0,1%to8%

12

INCI: Dimethicone

Mirasil DM 50 to DM 5 000

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

H3C CH3( )n


levels

Linear polydimethylsiloxane fluids with medium molecular weight

Viscosity: 50 to 1 000 mm 2/s


��Specific gravity (kg/m 3) ……....970

��Refractive index ………… .. . 1,403

��Flash point (ºC)…………… ...…300

��Surface tension (mN/m)……… ..21

Compatibility(with cosmetic ingredients)

�� Skin care: skin protection and softness

�� Sun care: water resistance

�� AP DEO: detackification

0,5%to

15%

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INCI: Dimethicone

Mirasil DM 60 000 to DM 500 000

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

H3C CH3( )n


levels

High molecular weight linear polydimethylsiloxane

Visco: 60000-500000 mm 2/s


��Specific gravity (kg/m 3) ………978

��Refractive index ………… ... . 1,410

��Flash point (ºC)…………… ...…300

��Surface tension (mN/m)……… ..21

Compatibility(with cosmetic ingredients)

�� Skin care: smooth and silky feel

�� Sun care: water resistance

�� Hair care: high conditioning

1%to

15%

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INCI: Amodimethicone

Mirasil ADM 211 & ADM 403

A = -O-CH3

B =-(CH2)3-NH (CH2)2-NH2

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn


levels

Two different offers

�� ADM 211 v= 1 000 mm 2/s amine content= 12 - 17 meq/100g

�� ADM 403 v= 300 mm 2/s amine content= 25 - 35 meq/100g

��Appearance… .…. Yellowish liquid

��Specific gravity (kg/m 3) …...…..974

��Refractive index ………… ...... 1,405

��Flash point (ºC)…………… .….. 104

��Clear products

�� Easy to handle

�� Color and heat protection

�� Improves wet and dry combing

�� Great cosmetic feel

Hair care:

0,5%to3%

15

INCI: Propoxytetramethylpiperidinyl Dimethicone

Mirasil ADMH 395 & ADMH 3900

�Patented Bluestar Silicones technology

HALStechnology

A = -CH3

B = HALS

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn

(CH2)3 O NH

CH3

CH3

CH3

CH3


levels

�� HALS structure

Two different viscosities �� ADMH 395 (10 000 mPa.s) �� ADMH 3900 (90 000 mPa.s)

��Appearance… .…. Yellowish liquid��Color (Hazen) …………… ...... < 125��Specific gravity (kg/m 3) …...…..975��Refractive index ………… ..... 1,395��Flash point (ºC)…………… .….. 104��Amine content (meq/100g)…17-21


�� No yellowing formulations

�� Color protection



�� Protection against oxidative stress

Hair care:

0,5%to3%

16

INCI: C15-19 alkane (and) PropoxytetramethylpiperidinylDimethicone

Mirasil ADMH B100

HALStechnology

A = -CH3

B = HALS

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn

(CH2)3 O NH

CH3

CH3

CH3

CH3


levels

�� Blend C15-C19 alkane & ADMH 3900 (50:50)

�� Viscosity = 2 000 mPa.s

��Appearance… .…. Yellowish liquid��Color (Hazen) …………… ........ < 50��Specific gravity (kg/m 3) …...…..883��Refractive index ………… ..... 1,428��Flash point (ºC)…………… .…...124��Amine content (meq/100g)..…8-11

�� Low volatility

�� Compatible with cosmetics ingredients

�� Anti-radical and antioxidant


�� Silky and pleasant touch

�� Friendly product

Skin care:

1% - 5%

Hair care:

1% - 3%

17

INCI: Water (and) Amodimethicone (and) Trideceth-6

Mirasil ADME-P

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn

A = -O-CH3

B = -(CH2)3-NH-(CH2)2-NH2

Amodimethicone :


levels

Non ionic micro-emulsion(25 nm particle size)

Silicone content: 27%

��Appearance… .…. Colouless liquid

��Specific gravity (kg/m 3) …..…...995

��pH ………………………..…........ 6-8

��Amine content (meq/100g)...…9-12


�� Simple addition and mixing to water based formulations



�� Imparts soft feel

Hair care

2%to

10%

18

INCI: Water (and) Amodimethicone(and) Trideceth-12 (and) Cetrimonium chloride

Mirasil ADM-E 235C

A = -O-CH3

B = T-(CH2)3-NH (CH2)2-NH2

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn

Amodimethicone :

Features Advantages in formulation Cosmetic benefits Use levels

Cationic emulsion ofan amine-functional siliconepolymer.� MIRASIL ADM-E 235 C

(35% of silicone content)

Conditioner :

2% - 5 %

Styling:

0,5% - 5%

� Provide soft feel to dry hair

� Reduce combing time on wethair

� Very good conditioning additive

� Developed as a conditioningadditive for hair care.

� Simple addition and mixingto water based formulations

InDevelopment

19

INCI: Water (and) Propoxytetramethylpiperidinyl Dimethicone(and) Trideceth-6

Mirasil ADMH-E 125

A = -CH3

�Patented Bluestar Silicones technology

B = HALS

A Si

CH3

CH3

O Si O A

CH3

CH3

SiO

B

CH3

Si

CH3

CH3 mn

(CH2)3 O NH

CH3

CH3

CH3

CH3

Propoxytetramethylpiperidinyldimethicone :

HALStechnology


levels

�� HALS structure

Non ionic micro-emulsion(25 nm particle size)

Silicone content: 25%

��Appearance… .…. Yellowish liquid

��Specific gravity (kg/m 3) …...…..995

��pH ………………………….......... 5-7

��Amine content (meq/100g)….…5-7


��No yellowing formulations

�� Simple addition and mixing to water based formulations




�� Protection against oxidative stress

Hair care

2%to

10%

20

INCI: PEG/PPG 22/24 Dimethicone (DMCO)

Mirasil DMCO

y

Si O

Me

Me

Si O

Me

(OE)e

(OP)p

Me3SiO SiMe3

x


levels

��Water soluble or water dispersable silicone polyethers

��Appearance……… .... Limpid liquid��Viscosity (mm 2/s) ……………. 1800��Specific gravity (kg/m 3) …...…1036��Refractive index …………… ... 1,446��Flash point (ºC)……………… .... 180��pH, 10% in water……………… .. 5,5

��Inverse solubility above cloud point temperature

��Low surface tension may increase deposition of other conditioning agent

�� Shampoos: reduce eyes irritation

�� Allow to formulate clear product

0.5%to3%

21

INCI: Cyclopentasiloxane (and) PEG/PPG 18/18 Dimethicone

Mirasil C-DMP

y

Si O

Me

Me

Si O

Me

(OE)e

(OP)p

Me3SiO SiMe3

x

10% PEG/PPG 18/18 Dimethicone dispersed in D5

Inverse emulsifier Water in D5

Features Characteristics Advantages in formulation Cos metic benefits

��Delivery system for emolients, moisterizers, sunscreens, antiperspirant actives and pigments

��Gives stable water in silicone formulations

��Appearance… Slightly grey liquid

��Viscosity (mm 2/s) …………….< 100

��Specific gravity (kg/m 3) …,...… 956

��Non volatil content (%)……… . 10,5

��Flash point (ºC)……………… .... >77

��Allows formulation flexibility

��Clear W/S emulsion technology possible

�� Delivery system for both non polar (oil phase) and polar ingredients (water phase)

�� Wide range of Personal Care applications

22

INCI: Cyclopentasiloxane (and) Dimethicone (C-DM / C-DMB)

Mirasil C-DM & Mirasil C-DMB

( )n

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

CH3 CH3Dimethicone:


levels

Solution of high molecular weight of dimethicone

Two different offers,

�� C-DM v= 3 500mPa.s , solid content = 30%

�� C-DMB v= 6 000mPa.s , solid content = 15%

��Appearance……… .…. Clear liquid


��Refractive index ………… ..... 1,400

��Flash point (ºC)…………… .….. >77

��Surface tension (mN/m)……… .. 16

Easy to handle blend

�� Skin care: smooth dry feel on skin

�� Sun care: long lasting

�� Hair care: soft and silky feel

3%to

10%

23

INCI: Cyclopentasiloxane (and) Dimethiconol

Mirasil C-DML

( )nSi

OSi

OSi

OSi

OSi

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

HO OHDimethiconol:


levels

Solution of high molecular weight of dimethiconol

Three different offers,

�� C-DML v= 6 000 mPa.s, solid content=15%

�� C-DML HV - C-DML LV v= 8 000mPa.s - v= 1 500 mPa,s

��Appearance……… .…. Clear liquid


��Refractive index ………… ..... 1,400

��Flash point (ºC)…………… .….. >70





3%to

10%

24

INCI:Dimethicone (and) Dimethiconol (D-DML)

Mirasil D-DML

( )nSi

OSi

OSi

OSi

OSi

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

HO OH

Dimethiconol:


levels

Solution of high molecular weight of dimethiconol

Three different offers,

�� D-DML v= 6000 mPa.s,

�� D-DML HV - D-DML LV v= 9 000mPa.s - 1 500 mPa.s,

��Appearance……….…. Clear liquid


��Refractive index …………..... 1,400

��Flash point (ºC)……………..... >130





3%to

10%

25

INCI: Phenyl Trimethicone

Mirasil PTM

[(CH3)3Si-O]3-Si-C6H5


levels

��Easily emulsified gloss agent ��Resistant to oxidation

��Appearance………… ... Clear liquid

��Viscosity (mm 2/s) ………….…… 22

��Specific gravity (kg/m 3) …...… 990

��Refractive index …………… . 1,459

��Flash point (ºC)…………… .… > 100

��Surface tension (mN/m)……… .. 21

��Easy to incorporate

��SPF booster in sun care formulations

�� gloss�� softness�� reduces tackiness

0,5%to5%

26

INCI: Cyclopentasiloxane (and) Diphenyl Dimethicone (C-DPDM)Phenyl Trimethicone (and) Diphenyl Dimethicone (P-DPDM)

Mirasil C-DPDM & Mirasil P-DPDM

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

( )n( )p CH3H3C

C6H5

C6H5

Diphenyl Dimethicone


levels

Blend of high molecular weight Diphenyl Dimethicone

Two differnt offers,

�� C-DPDM v = 2 000 mPa.s, solid content = 15%

�� P-DPDM v =12 000 mPa.s, diphenyldimethicone content = 18%




��Flash point (ºC)…………… ...… > 75

��Easy to incorporate

��Good compatibility with vegetable oils

�� Skin care: unique silky feel

�� Sun care: water resistant

�� Hair care: antistatic and gloss effects

2%to

10%

27

INCI: C15-19 alkane (and) Diphenyl Dimethicone

Mirasil BRIGHT

SiO

SiO

SiO

SiO

Si

CH3 CH3 CH3 CH3 CH3

CH3 CH3 CH3 CH3 CH3

( )n( )p CH3H3C

C6H5

C6H5

Diphenyl Dimethicone


levels

�� Blend of high molecular weight Diphenyl Dimethicone

�� High refractive index

Diphenyldimethicone content: 20%


��Viscosity (mm 2/s) ………….…1 500



��Flash point (ºC)…………… ...… 124

�� Compatible with cosmetic ingredients:pigments and SPF

�� Easy to use

�� Provide hair shine

�� Film barrier protection

�� Anti-humidity effect long lasting

�� Non sticky effect

0,5%to5%

28

INCI: Polymethylsilsesquioxane

Mirasil Micropearl 40

��Highly pure sphericalsilicone resin particles

��3 dimension network

Features Cosmetic benefitsAdvantages in formulationUse

levelsCharacteristics

��Physical form……… Spherical��Color ……………… ........ White��Specific gravity (kg/m3) ..1300��Refractive index ……… .. 1,43��Particle size (micra)…… ... 4��pH……………………….… 5 - 9

�� Easy and uniformdispersion in cosmeticformulations

� Water repellence� Excelent lubricity� Soft focus effect� Non greasy touch

0,2to5

29

Technical and documental support

� Mirasil brochure

� TDS and MSDS available for all Mirasil references

� Attestation Ingredient status of Bluestar Silicones Cosmetic Raw Material for all the Mirasil references (ongoing)

� R&D organization • Design labs in St. Fons (France)

• Technology oriented labs • Projects for new silicones

• Technical service lab in Sta. Perpetua (Spain)• Market and application oriented lab • Support to the existing range

� Mirasil samples kits

� Bluestar Silicones for Personal Care: www.bluestarsilicones.com

mirasil silicones for personal care - thirthrajthirthraj.com/images/mirasil.pdf4 methylchlorosilanes...

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