measurements of surfactant squeeze-out using … of surfactant squeeze-out using magnetically-...
TRANSCRIPT
Mea
sure
men
ts o
f Sur
fact
ant
Sque
eze-
out U
sing
Mag
netic
ally
-Le
vita
ted
Liqu
id B
ridge
s
Cha
rles
Ros
enbl
att
Dep
artm
ent o
f Phy
sics
Cas
e W
este
rn R
eser
ve U
nive
rsity
Wor
k pu
blis
hed
in C
ollo
ids a
nd S
urfa
ces A
218
, 65
(200
3)
https://ntrs.nasa.gov/search.jsp?R=20060014068 2018-06-25T21:30:14+00:00Z
Liqu
id B
ridge
s•
Liqu
id b
ridge
s: C
olum
ns o
f liq
uid
supp
orte
d by
two
solid
surf
aces
—Th
ese
are
gene
rally
opp
osin
g rig
ht c
ircul
ar
cylin
ders
in 0
g.
•Fo
r a c
ylin
dric
albr
idge
of l
engt
h L
and
diam
eter
d, i
n ze
ro g
, the
max
imum
sl
ende
rnes
s rat
io Λ
[L/d
] = π
[R
ayle
igh]
•In
the
pres
ence
of g
ravi
ty th
e cy
lindr
ical
sh
ape
of a
nax
isym
met
ricbr
idge
tend
s to
defo
rm (s
ee o
ur w
ork
J. C
oll.
Int.
Sci.
213,
592
(199
9))
Prin
cipl
es o
f mag
netic
levi
tatio
n(s
ee o
ur w
ork
inPh
ys. F
luid
s 10,
220
8 (1
998)
)
•Fl
uid
has a
vol
umet
ric m
agne
tic su
scep
tibili
ty χ
. O
n ap
plyi
ng fi
eld
H:
•En
ergy
per
uni
t vol
ume
is U
= -½
χH2
•Fo
rce
per
unit
volu
me
is F
= -∇
U =
½χ∇
H2
= χΗ
∇H
. T
his f
orce
can
be
orie
nted
to
coun
tera
ct g
ravi
ty.
•D
isso
lve
para
mag
netic
man
gane
se c
hlor
ide
tetra
hydr
ate
in w
ater
or g
lyce
rol t
o cr
eate
hig
hly
para
mag
netic
flui
d th
at c
an b
e co
ntro
lled
with
a
re
lativ
ely
smal
l fie
ld.
Thus
the
effe
ctiv
e bo
dy fo
rce
on th
e co
lum
n m
ay b
e co
ntro
lled
by v
aryi
ng th
e cu
rren
t in
the
mag
net—
as
a fu
nctio
n of
tim
e!
App
arat
usTo
p vi
ew
End
view
-3-2-1012
3 x
107
|Hx ∂zHx| (G2 cm
-1)
0.5
0.0
-0.5
-1.0
-1.5
-2.00.
5
0.6
0.7
0.8
0.9
1.0
1.1
1.2
x 10
4
Hx (G)
z (
cm)
H a
nd H
∇H
pro
files
“Far
aday
pol
e pi
eces
” cr
eate
un
iform
forc
e
Reg
ion
of q
uasi
-uni
form
fo
rce
We
have
look
ed a
t sta
bilit
y is
sues
0.0
0.1
0.2
0.3
0.4
1.6
1.8
2.0
2.2
2.4
2.6
2.8
3.0
3.2
Axi
al
Late
ral
Slenderness Ratio Λ
Bon
d N
umbe
r1.
41.
61.
82.
02.
22.
42.
62.
83.
03.
20.
4
0.6
0.8
1.0
1.2
1.4
B =
0.3
55B
= 0.
205
B =
0.0
15
Reduced Volume Vr
Sle
nder
ness
Rat
io Λ
Stab
ility
of c
ylin
dric
al b
ridge
s (V
r=1)
vs.
Bon
d nu
mbe
rSt
abili
ty c
urve
s as f
unct
ion
of V
rat
fixe
d B
ond
num
ber(
s)
Bon
d nu
mbe
r: (
)σ∇χ
−ρ
≡4
dH
21g
B2
2
Rat
io o
f gra
vita
tiona
l for
ce
to su
rfac
e fo
rces
Stab
le b
elow
the
line,
uns
tabl
e ab
ove
the
line)
(Hor
izon
tal b
ridge
)
(Ver
tical
brid
ge)
Gly
cero
l+ m
anga
nese
chl
orid
e te
trahy
drat
e
We
have
look
ed a
t col
laps
e dy
nam
ics
Sequ
ence
of i
mag
es o
f a g
lyce
rol b
ridge
afte
r the
upw
ard
mag
netic
forc
e is
redu
ced
sudd
enly
. B
ridge
col
laps
es o
ver t
ime
due
to g
ravi
ty.
t cor
resp
onds
to ti
me,
in se
cond
s
Mov
ie m
ay b
e vi
ewed
at
http
://liq
-xta
l.cas
e.ed
u/V
ideo
s.htm
We
have
look
ed a
t res
onan
ce b
ehav
ior
Firs
t, se
t tim
eav
erag
edB
ond
num
ber
Bo ef
fby
app
lyin
g ap
prop
riate
d.c
. cu
rren
tio,
and
ther
efor
e Η
∇Η
……
.
Then
, mod
ulat
e m
agne
t cur
rent
. Fo
rce
∝(i o
+δi
sin
ωt)2 ,
and
δBef
f∝
2io
δix
sin
ωt
+ O
(δi2 )
sin2
2ωt
Var
y th
e to
tal b
ody
forc
e si
nuso
idal
ly a
t fre
quen
cy ω
and
exam
ine
the
resp
onse
.
Mov
ie m
ay b
e vi
ewed
at
http
://liq
-xta
l.cas
e.ed
u/V
ideo
s.htm
Mot
ivat
ion:
Inv
estig
ate
“res
pira
tory
dis
tress
sy
ndro
me”
in n
eona
tes.
•D
urin
g re
spira
tion
alve
oli t
o gr
ow a
nd sh
rink
perio
dica
lly•
This
requ
ires d
ynam
icva
riatio
n of
surf
ace
tens
ion
to b
alan
ce
•Pr
emat
ure
infa
nts h
ave
not m
anuf
actu
red
suff
icie
nt su
rfac
tant
(e.g
.,ph
osph
atid
ylch
olin
e).
Thus
thei
r pul
mon
ary
fluid
can
not r
espo
nd
prop
erly
dur
ing
brea
thin
g.
Dyn
amic
surf
ace
tens
ion
RP
σ2=
∆
The
chan
ge o
f sur
face
tens
ion
with
tim
e as
surf
acta
nt m
olec
ules
mov
e be
twee
n th
e su
rfac
e an
d bu
lk
As a
func
tion
of su
rfac
tant
co
ncen
tratio
n:
Rap
idly
redu
ce b
ridge
leng
th in
ze
ro g
ravi
ty
Exam
ine
the
elec
tric
al re
sist
ance
vs
. tim
eof
the
brid
ge w
hen
the
late
ral a
rea
of th
e br
idge
is
redu
ced
sudd
enly
. (I
n ze
ro
effe
ctiv
e gr
avity
the
only
re
leva
nt fo
rce
is su
rfac
e te
nsio
n)
Top
Vie
w
Side
Vie
w
Use
hor
izon
tal b
ridg
e to
det
erm
ine
“squ
eeze
-out
tim
e” o
f sur
fact
ant f
rom
surf
ace.
•M
ixtu
res o
f pa
ram
agne
tic li
quid
(MnC
l 2 . 4H
2O/W
ater
)
•A
dd D
odec
yl tr
imet
hyla
mm
oniu
m c
hlor
ide
(cat
ioni
c su
rfac
tant
)
0 ≤
X ≤
1.5
wt.
%.
•C
ritic
al M
icel
le C
once
ntra
tion
(CM
C) i
s det
erm
ined
from
su
rfac
e te
nsio
n m
easu
rem
ents
usi
ng c
apill
ary
rise
tech
niqu
e.
(Abo
ve C
MC
add
ition
al m
olec
ules
tend
to fo
rm m
icel
les r
athe
r th
an a
dsor
b at
the
surf
ace)
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
01020304050607080
CM
C
Surface Tension (dynes/cm)
Con
cent
ratio
n(w
t%)
•Fo
r eac
h co
ncen
tratio
n X
of s
urfa
ctan
t, br
idge
s of Λ
= 2.
5 ar
e cr
eate
d.
•A
rapi
d ch
ange
of l
engt
h (1
.3 m
m in
500
ms)
forc
es it
to
assu
me
a ne
w sh
ape. Fi
nal s
hape
as t
→ ∞
Mov
emen
t of s
uppo
rt ro
d
Inst
anta
neou
s sha
pe
Ther
e is
a tr
ansi
ent b
uckl
ing
of th
e su
rfac
e af
ter t
he b
ridge
is “
squi
shed
” in
or
der t
o ac
com
mod
ate
the
surf
acta
nt
that
has
not
yet
gon
e fr
om th
e su
rfac
e in
to th
e bu
lk.
As s
urfa
ctan
t is
sque
ezed
-out
into
bul
k, th
e su
rfac
e ar
ea
of th
e br
idge
is re
duce
d to
the
final
eq
uilib
rium
shap
e
Cre
nella
tions
are
due
to:
Indu
ced
capi
llary
wav
es d
urin
g “s
quis
hing
”A
ccom
mod
atio
n of
surf
acta
nt th
at c
anno
t be
sque
ezed
out
from
surf
ace
inst
anta
neou
sly
whe
n th
e br
idge
are
a is
redu
ced
durin
g “s
quis
hing
”
The
rela
xatio
n tim
e of
the
cren
ella
tions
for l
arge
X
is re
late
d to
the
sque
eze-
out t
ime
of th
e su
rfac
tant
, and
ther
efor
e to
the
resp
onse
tim
e of
the
(dyn
amic
) sur
face
tens
ion.
This
rela
xatio
n tim
e is
det
erm
ined
ex
peri
men
tally
by
the
rela
xatio
n of
ele
ctri
cal
resi
stan
ce a
cros
s the
bri
dge
R =
ρL/
A
zr
dz
r fin(
z)
δr(z
,t)
dzz
rR
finL zfin
fin∫ =
=0
2)
(π
ρ
[]dz
tz
rz
rR
finL zfin
inst
∫ =+
=0
2 ),
()
(δ
πρ
Fina
l res
ista
nce:
Inst
anta
neou
s res
ista
nce:
L fin
1. E
ven
orde
r ter
ms a
ll ha
ve p
ositi
ve c
oeff
icie
nts
2.Fr
om v
olum
e co
nser
vatio
n, lo
cal n
egat
ive
δr(z
) ter
ms
are
larg
er
than
loca
l pos
itive
δr(
z) t
erm
s
R ins
t> R
fin
We
can
see
that
Rin
st>
Rfin
:Ex
pand
Rin
stin
pow
ers o
f δr(
z,t),
from
whi
ch
dz
zr
tz
rz
rt
zr
zr
tz
rz
rt
zr
zr
zr
dzR
finfinfin
finL z
fin
L zfin
inst
finfin
+−
+
−
+
+
−
+=
∫∫
==
...)
()
,(
5)
()
,(
4
)(
),
(3
)(
),
(2
)(
)(
432
02
02
δδδ
δ
πρ
πρ
Res
ista
nce
vs. T
ime
05
106.
2
6.4
6.6
6.8
7.0
7.2
7.4
500
ms
trans
latio
n tim
e
Sha
pe re
laxa
tion:
Thi
s is
whe
re th
e ph
ysic
s is
!
Resistance (a.u.)
Tim
e (s
ec)
R =
ρL/A
0.0
0.2
0.4
0.6
0.8
1.0
1.2
1.4
1.6
0.8
0.9
1.0
1.1
1.2
1.3
1.4
1.5
1.6
1.7
CM
C
Time (s)
Con
cent
ratio
n (w
t%)
τvs
. XFo
r eac
h co
ncen
tratio
n w
e ob
tain
th
e re
laxa
tion
time
For
low
con
cent
ratio
ns, X
< C
MC
(τ
~ 1.
1 s)
Surf
ace
area
dec
reas
eson
tran
slat
ion
of ro
d. I
ncre
ased
surf
acta
nt
dens
ity a
t sur
face
can
be a
ccom
mod
ated
by
surf
ace
due
to it
s sm
all
surf
ace
dens
ity.
Ther
e is
no
need
for s
urfa
ctan
t to
be p
ushe
d in
to b
ulk.
Fast
cap
illar
y w
aves
(> 8
Hz)
are
indu
ced
by th
e vi
brat
ion
durin
g sq
uish
ing
and
resu
lt in
hig
h el
ectri
cal r
esis
tanc
e. (
We
mea
sure
the
enve
lope
dec
ay)
As c
apill
ary
wav
es d
ecay
, ele
ctric
al re
sist
ance
dec
reas
es to
fina
l eq
uilib
rium
val
ue (a
ssoc
iate
d w
ith fi
nal e
quili
briu
m sh
ape)
So, f
or sm
all X
, we
mea
sure
the
deca
y of
cap
illar
y w
aves
, not
of
surf
acta
nt sq
ueez
e ou
t
For
larg
e co
ncen
trat
ions
X >
CM
C (τ
~ 1.
7 s)
Cap
illar
y w
aves
are
dam
ped
very
rapi
dly
for X
> C
MC
, and
do
not
cont
ribu
te to
mea
sure
d si
gnal
dur
ing
deca
y.
Whe
n ro
d tra
nsla
tes,
surf
ace
cann
ot ra
pidl
y ac
com
mod
ate
the
high
er su
rfac
tant
den
sity
su
rfac
e ar
ea is
tem
pora
rily
> eq
uilib
rium
su
rfac
e ar
ea.
Surf
ace
area
rela
xes f
rom
nea
r equ
ilibr
ium
to e
quili
briu
m sh
ape
as
surf
acta
nt is
sque
ezed
out
from
surf
ace.
Res
ista
nce
rela
xes w
ith
surf
ace
topo
grap
hy, w
here
τis
the
sque
eze-
out t
ime
of su
rfac
tant
.
This
is n
ota
diff
usio
n lim
ited
proc
ess,
whi
ch is
abo
ut fo
ur o
rder
s of
mag
nitu
de fa
ster
.
Tak
e ho
me
mes
sage
:M
agne
tic le
vita
tion
has n
umer
ous a
pplic
atio
ns in
stud
ies
of fl
uids
, “so
ft” a
nd “
hard
” co
nden
sed
mat
ter p
hysi
cs,
and
biop
hysi
cs
1.“D
ial i
n” a
ppro
pria
te g
ravi
tatio
nal f
ield
, e.g
., M
artia
n,
Luna
r
2.Th
e fie
ld c
an b
e m
aint
aine
d in
defin
itely
3.Fi
eld
can
be v
arie
d w
ith ti
me
Col
labo
rato
rsPh
ilip
Tayl
orJ.
Iwan
D. A
lexa
nder
Lev
Slob
ozha
nin
Mili
nd M
ahaj
anSh
iyon
g Zh
ang
Neh
a (B
hatt)
Pat
elM
. Rez
a D
odge
Supp
orte
d by
NA
SA u
nder
gra
nts N
AG
3-18
64an
d N
AG
8-17
79