may 24, 2019 u.s. environmental protection agency, region 5 re · may 24, 2019 . ms. lauren bumba...
TRANSCRIPT
May 24, 2019 Ms. Lauren Bumba – Remedial Project Manager U.S. Environmental Protection Agency, Region 5 Superfund Division, Remedial Response Branch 77 West Jackson Boulevard Mailcode: SR-6J Chicago, Illinois 60604-3507 RE:
Summary of April 2019 Groundwater Sampling Activities, Remedial Investigation/Feasibility Study (RI/FS) - Ottawa Township Flat Glass Site, Ottawa, LaSalle County, Illinois, PNA168.0016.
Dear Ms. Bumba: On behalf of Pilkington North America, Inc. (PNA), Hull & Associates, Inc. (Hull) hereby submits a summary of the results from the April 2019 semi-annual site-wide groundwater sampling event, undertaken in support of the RI/FS at the Ottawa Township Flat Glass Site (Site). The groundwater monitoring wells and piezometers that were sampled during the April 2019 sampling event are included on Table 1 and Figure 1. Groundwater sampling procedures and laboratory results are summarized below:
1. Groundwater sampling was conducted from April 24 through April 26 at monitoring wells
and piezometers using low-flow techniques, with the exception of MW-5, which was sampled using a disposable bailer due to insufficient water volume for low-flow sampling. Where low-flow techniques were used, groundwater was extracted at a rate of approximately 100 to 400 milliliters per minute and the following field parameters were measured: pH, temperature, conductivity, oxidation-reduction (redox) potential, dissolved oxygen and turbidity. When field parameters stabilized per Hull’s Standard Operating Procedure (SOP), samples were collected in laboratory-prepared containers and immediately placed on ice in a cooler. The Village of Naplate Main and Auxiliary Production Well samples were collected through faucets or spigots at each wellhead, prior to any treatment being conducted. All samples were submitted to TestAmerica, Inc. under chain-of-custody for analyses described below.
2. Samples collected from the monitoring wells and piezometers were analyzed for total
arsenic using U.S. EPA Method 6020 and total dissolved solids (TDS). Field parameters and analytical results for monitoring wells are summarized in Table 1. The laboratory analytical results are located in Attachment A.
3. Water level measurements were collected at all groundwater monitoring wells prior to
sample collection activities. Water levels are summarized on Table 2. Water levels could not be obtained from several monitoring wells located within OU4, including P-15, P-30, P-31 and MW-3, as the access road could not be traversed due to the presence of standing water.
Ms. Lauren Bumba PNA168.0016 May 24, 2019 Page 2
A discussion of the analytical results associated with the Central Plume, originating from the Plaster Pit in Operable Unit 4 (OU4) follows:
1. Arsenic concentrations within the core area of the plume were 1,800 micrograms per liter (ug/L) at MW-6L, 760 ug/L at MW-14, 1,900 ug/L at P-23, and 530 ug/L at PZ-2 (duplicate result 630 ug/L).
2. The detected arsenic concentrations at MW-15 was 36 ug/L, which was substantially lower than the concentration detected during the September 2019 sampling event (1,200 ug/l) and more in line with historical observations which have ranged from 20.4 ug/L to 179 ug/L.
3. Arsenic was also detected in samples collected from monitoring wells MW-16 (260 ug/L),
P-22 (19 ug/L), the upper and middle wells of the MW-6 cluster (17 ug/L and 5.4 ug/L, respectively), and the middle and lower wells of the MW-18 cluster (6.3 ug/L and 14 ug/L, respectively).
4. Arsenic was not detected in samples collected from monitoring wells MW-18U or P-9. 5. TDS in groundwater samples ranged from 230 milligrams per liter (mg/L) at sample location
P-9 to 2,600 mg/L at MW-18M. 6. The concentration of arsenic in the leachate collected from piezometer HP-7 was 54,000
ug/L. The TDS concentration was 29,000 mg/L. 7. Arsenic was not detected in the parent or duplicate sample collected from the Village of
Naplate Main Well (reporting limit of 1 ug/L). The reported concentration of arsenic in the Village of Naplate Auxiliary Well was 1.4 ug/L
A discussion of the analytical results associated with the West Plume, originating from the Original Sand Pond in OU4 follows:
1. Detectable total arsenic concentrations in groundwater ranged from 53 ug/L at MW-4U to 2,000 ug/L at MW-2U. The detected concentration of 2,000 ug/L at MW-2U is substantively lower than the reported concentration of 23,000 ug/L in the October 2017 event and the concentration of 8,200 during the October 2018 events and falls within the historical range of detected concentrations of 440 ug/L to 6,540 ug/L.
2. Arsenic in leachate piezometer HP-5, which is located in the Original Sand Pond, was 16,000 ug/L.
3. TDS concentrations in groundwater ranged from 520 mg/L at sample location P-5 to 3,000 mg/L at MW-2U. The TDS concentration at leachate piezometer HP-5 was 16,000 mg/L.
4. P-30 was not sampled as the access road could not be safely traversed due to the presence
of standing water. A discussion of the analytical results associated with the South Plume, originating from Quarry 1 in Operable Unit 3 (OU3) follows:
Ms. Lauren Bumba PNA168.0016 May 22, 2019 Page 3
HULL & ASSOCIATES, INC. MAY 2019 DUBLIN, OHIO PNA168.0016
1. A substantial number of the monitoring wells reported results as below the detection limit of
<5.0 ug/L, including samples collected from the upper and lower wells of the MW-11 and MW-12 clusters, MW-13L, MW-21, S-2, S-3, S-5, S-6R and S-8.
2. Arsenic was detected in samples collected from monitoring wells MW-11M (5.4 ug/L), MW-
12M (14 ug/L), the upper and middle wells of the MW-13 cluster (17 and 29 ug/L, respectively with a detection of 30 ug/L in the MW-13M duplicate), MW-20 (16 ug/L), MW-22 (310 ug/L), MW-23 (7.5 ug/L) and S-1 (130 ug/L).
3. TDS ranged from 530 mg/L at sample locations S-3 to 3,200 mg/L at S-8.
As discussed in previous correspondence, PNA will continue to sample the Village of Naplate wells for arsenic on a quarterly basis; the next quarterly sampling event is tentatively scheduled for June 2019. The next semi-annual Site-wide groundwater sampling event is tentatively scheduled for October 2019. If you have any questions, please contact me at (513) 460-8632.
Sincerely, W. Lance Turley Senior Consultant ct: Jim Lavrich, PNA Kent Purcell, PNA
AnnMarie Sanford, Pepper Hamilton Tom Wilczak, Pepper Hamilton David Richards, Hull
Hull Project File PNA168
HULL & ASSOCIATES, INC. MAY 2019 DUBLIN, OHIO PNA168.0016
TABLES
PILKINGTON NORTH AMERICA, INC.OTTAWA TOWNSHIP FLAT GLASS SUPERFUND SITE
TABLE 1
RESULTS OF THE APRIL 2019 GROUNDWATER SAMPLING EVENT
ArsenicTotal Dissolved
SolidsTemperature pH
Specific Conductance
ORP TurbidityDissolved Oxygen
ug/L mg/LoC s.u. uS/cm mV NTUs mg/L
HP-7 (leachate) 4/26/2019 PNA168:HP-7:G042619 54,000 29,000 11.5 11.36 14,700 -343 <1 0.54
MW-6L 4/24/2019 PNA168:MW-6L:G042419 1,800 1,100 14.7 7.59 1,420 -57 10 0.92MW-6M 4/24/2019 PNA168:MW-6M:G042419 5.4 1,100 14.7 7.04 1790 43 9 1.08MW-6U 4/24/2019 PNA168:MW-6U:G042419 17 470 15.0 7.29 848 -48 226 1.94MW-14 4/24/2019 PNA168:MW-14:G042419 760 870 13.8 7.88 1,470 -49 29 5.18MW-15 4/24/2019 PNA168:MW-15:G042419 36 610 13.6 8.70 902 -165 9 0.90MW-16 4/24/2019 PNA168:MW-16:G042419 260 1,000 16.3 7.49 1,470 -16 8 0.89MW-18L 4/24/2019 PNA168:MW-18L:G042419 14 1,300 15.2 7.52 2,130 -295 1 1.72MW18M 4/24/2019 PNA168:MW-18M:G042419 6.3 2,600 13.4 11.11 2,570 -299 8 5.26MW-18U 4/24/2019 PNA168:MW-18U:G042419 <5 600 13.0 8.53 947 -209 18 1.51
P-22 4/24/2019 PNA168:P-22:G042419 19 460 14.0 7.59 774 10 6 1.23P-23 4/24/2019 PNA168:P-23:G042419 1,900 860 13.6 7.74 1,440 -135 26 2.20P-9 4/26/2019 PNA168:P-9:G042619 <5 230 12.4 6.39 351 161 <1 8.61
PNA168:PZ-2:G042419 530 550PNA168:PZ-2:G042419A 630 570
HP-5 (leachate) 4/26/2019 PNA168:HP-5:G042619 16,000 7,30012.2 10.81 5,150 -261 3 1.73
MW-2U 4/24/2019 PNA168:MW-2U:G042419 2,000 3,000 12.3 3.48 4,100 482 >1,000 4.32MW-4U 4/24/2019 PNA168:MW-4U:G042419 53 710 13.0 6.94 1,060 -100 68 1.29MW-5 4/25/2019 PNA168:MW-5:G042519 150 950 13.1 6.91 1,280 -99 400 2.23
P-5 4/24/2019 PNA168:P-5:G042419 320 520 10.2 7.64 879 106 5 7.41P-30
MW-11L 4/25/2019 PNA168:MW-11L:G042519 <5 1,600 11.07 7.30 2,490 -53 9.2 0.52MW-11M 4/25/2019 PNA168:MW-11M:G042519 5.4 570 10.88 7.10 847 -80 7.7 0.21MW-11U 4/25/2019 PNA168:MW-11U:G042519 <5 600 11.15 7.20 927 157 259 6.31MW-12L 4/25/2019 PNA168:MW-12L:G042519 <5 760 14.41 8.60 1,080 -37 100 0.58MW-12M 4/25/2019 PNA168:MW-12M:G042519 14 750 13.77 7.50 964 103 108 0.77MW-12U 4/25/2019 PNA168:MW-12U:G042519 <5 670 11.73 6.30 1,000 76 151 1.95MW-13L 4/25/2019 PNA168:MW-13L:G042519 <5 610 11.6 7.81 970 -149 1 6.51
PNA168:MW-13M:G042519 29 540PNA168:MW-13M:G042519A 30 540
MW-13U 4/25/2019 PNA168:MW-13U:G042519 17 540 11.7 7.87 872 -179 4 0.88MW-20 4/25/2019 PNA168:MW-20:G042519 16 810 14.5 7.12 1,190 -81 2 1.72MW-21 4/25/2019 PNA168:MW-21:G042519 <5 570 16.0 7.20 1,080 75 >1,000 6.80MW-22 4/25/2019 PNA168:MW-22:G042519 310 2,600 13.3 8.52 3,200 -233 <1 1.59MW-23 4/26/2019 PNA168:MW-23:G042619 7.5 640 6.3 7.54 999 59 7 8.21
S-1 4/25/2019 PNA168:S-1:G042519 130 1,600 11.9 10.27 1,950 -191 1 6.86S-2 4/25/2019 PNA168:S-2:G042519 <5 1,800 13.90 7.92 2,510 75 3 9.40S-3 4/25/2019 PNA168:S-3:G042519 <5 530 12.8 6.46 852 118 56 9.12S-5 4/25/2019 PNA168:S-5:G042519 <5 620 10.0 7.62 1,030 34 1 10.57S-6R 4/25/2019 PNA168:S-6R:G042519 <5 960 9.92 6.60 1,260 265 31 8.53S-8 4/25/2019 PNA168:S-8:G042519 <5 3,200 17.8 7.53 3,840 -70 3 4.41
PNA168:VON-1:W042519 <1 NT
PNA168:VON-1:W042519A <1 NT
VON-2 4/25/2019 PNA168:VON-2:W042519 1.4 NT 13.2 7.46 838 -56 <1 4.41
P-25 4/25/2019 PNA168:P-25:G042519 <5 420 11.0 6.75 610 117 42 8.34
Notes:a. NT - Not Testedb. Duplicate sample
865 -162 6
Field Parameters
811 -37 36 0.82
Monitored Location
Sample Location
Sample Date Field Sample ID
Groundwater
NA
South
West
P-Z2
Central
VON-1 <1 4.51
MW-13M
4/24/2019
4/25/2019
Not sampled - Inaccessible
1.40
13.1
4/25/2019 14.0 7.34 908 -42.0
7.72
11.9 8.13
HULL & ASSOCIATES, INC.DUBLIN, OHIO 1 of 1
NOVEMBER 2018PNA168.0002.xlsx
HULL & ASSOCIATES, INC. MAY 2019 DUBLIN, OHIO PNA168.0016
FIGURE
HP-5
PZ-2
MW-5
MW-23
MW-22
MW-21MW-20
MW-6UMW-6MMW-6L
MW-4U
MW-2U
MW-16
MW-15MW-14
MW-18UMW-18M MW-18L
MW-13U
MW-13MMW-13L
MW-12U
MW-11UMW-11M
MW-11L
MW-12L
MW-12MS-8
S-5
S-3S-2
S-1
P-9
P-5
S-6R
P-32
P-30
P-25
P-23
P-22
Naplate Village Well
Ottawa Avenue Cemetery Well
Naplate Auxiliary Well
HP-7
HP-6
HP-3
HP-2
HP-1
HP-4
PZ-3
PZ-1
MW-8
MW-3
EX-1MW-9L
MW-7UMW-7M
MW-7L
MW-4L
MW-2L
MW-1UMW-1L
MW-9M
MW-17L
MW-17MMW-17U
S-7
S-4
P-8P-7
P-6
P-4
P-3
P-2
P-1
P-37
P-34
P-33
P-31
P-29P-28
P-27P-26
P-21
P-20P-19
P-18
P-17
P-15
P-13
P-24
P-12P-11
Source: Esri, DigitalGlobe, GeoEye, Earthstar Geographics, CNES/Airbus DS, USDA, USGS, AeroGRID, IGN, and the GIS User CommunityProduced using ArcGIS 10.5
PNA PropertyOrange Wells Part of September 2016 Sampling EventMunicipal / IndustrialHull Leachate PiezometerHull Monitoring PiezometerHull Monitoring Well or Nests (MW-)Monitoring Well (P-, S-)Abandoned WellDecommissioned Well
0 520 1,040260Feet
1:6,000
© 2018, Hull & Associates, Inc.
Edited: 5/24/2019 By: mopel
Figure
File Name: PNA168_02_Fig01_QtrSamp0419.mxd
Site-Wide GroundwaterSampling Results (April 2019)
Ottawa Township Flat Glass SiteQuarterly Sampling Report
Pilkington North America, Inc.Village of Naplate, La Salle County, Illinois
1May 2019DISCLAIMER
Hull & Associates, Inc. (Hull) has furnished this map tothe company identified in the title block (Client) for itssole and exclusive use as a preliminary planning andscreening tool and field verification is necessary toconfirm these data. This map is reproduced fromgeospatial information compiled from third-partysources which may change over time. Areas depictedby the map are approximate and may not be accurateto mapping, surveying or engineering standards. Hullmakes no representation or guarantee as to thecontent, accuracy, timeliness or completeness of anyinformation or spatial location depicted on this map.This map is provided without warranty of any kind,including but not limited to, the implied warranties ofmerchantability or fitness for a particular purpose. Inno event will Hull, its owners, officers, employees oragents, be liable for damages of any kind arising out ofthe use of this map by Client or any other party.
6397 Emerald PkwySuite 200Dublin, Ohio 43016
Phone: (614) 793-8777Fax: (614) 793-9070www.hullinc.com
MW-6M 4/24/2019Arsenic ug/L 5.4
MW-6U 4/24/2019Arsenic ug/L 17
MW18M 4/24/2019Arsenic ug/L 6.3
MW-18U 4/24/2019Arsenic ug/L <5
MW-11M 4/25/2019Arsenic ug/L 5.4
MW-11U 4/25/2019Arsenic ug/L <5
MW-12L 4/25/2019Arsenic ug/L <5
MW-12M 4/25/2019Arsenic ug/L 14
MW-13U 4/25/2019Arsenic ug/L 17
P-25 4/25/2019Arsenic ug/L <5
MW-13L 4/25/2019Arsenic ug/L <5
MW-18L 4/24/2019Arsenic ug/L 14
MW-22 4/25/2019Arsenic ug/L 310
S-5 4/25/2019Arsenic ug/L <5
S-6R 4/25/2019Arsenic ug/L <5
MW-12U 4/25/2019Arsenic ug/L <5
MW-11L 4/25/2019Arsenic ug/L <5
S-3 4/25/2019Arsenic ug/L <5
MW-21 4/25/2019Arsenic ug/L <5
S-8 4/25/2019Arsenic ug/L <5
S-2 4/25/2019Arsenic ug/L <5
MW-20 4/25/2019Arsenic ug/L 16
S-1 4/25/2019Arsenic ug/L 130
HP-7 (leachate) 4/26/2019
Arsenic (ug/L) 54,000
P-5 4/24/2019Arsenic ug/L 320
MW-4U 4/24/2019Arsenic ug/L 53
HP-5 (leachate) 4/26/2019
Arsenic ug/L 16,000
MW-2U 4/24/2019Arsenic ug/L 2,000
P-30 Not SampledArsenic ug/L Inaccessible
MW-5 4/25/2019Arsenic ug/L 150
MW-16 4/24/2019Arsenic ug/L 260
P-23 4/24/2019Arsenic ug/L 1,900
P-22 4/24/2019Arsenic ug/L 19
P-9 4/26/2019Arsenic ug/L <5
MW-14 4/24/2019Arsenic ug/L 760
MW-15 4/24/2019Arsenic ug/L 36
MW-6L 4/24/2019Arsenic ug/L 1,800
MW-23 4/26/2019Arsenic ug/L 7.5
MW-13M 4/25/2019Arsenic ug/L 29Arsenic ug/L 30
P-Z2 4/24/2019Arsenic ug/L 530Arsenic ug/L 630
HULL & ASSOCIATES, INC. MAY 2019 DUBLIN, OHIO PNA168.0016
ATTACHMENT A
Laboratory Analytical Report
ANALYTICAL REPORTEurofins TestAmerica, Chicago2417 Bond StreetUniversity Park, IL 60484Tel: (708)534-5200
Laboratory Job ID: 500-162329-1Client Project/Site: PNA Pilkington - Ottawa
For:Hull & Associates, Inc.6397 Emerald ParkwaySuite 200Dublin, Ohio 43016-2231
Attn: Ms. Monica Williamson
Authorized for release by:5/2/2019 12:26:34 PM
Opal Johnson, Project Manager II(330)[email protected]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Hull & Associates, Inc.Project/Site: PNA Pilkington - Ottawa
Laboratory Job ID: 500-162329-1
Page 2 of 16Eurofins TestAmerica, Chicago
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Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
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Case NarrativeClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa
Job ID: 500-162329-1
Laboratory: Eurofins TestAmerica, Chicago
Narrative
CASE NARRATIVE
Client: Hull & Associates, Inc.
Project: PNA Pilkington - Ottawa
Report Number: 500-162329-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
Eurofins TestAmerica, Chicago attests to the validity of the laboratory data generated by Eurofins TestAmerica facilities reported herein. All analyses performed by Eurofins TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures
described in the application methods. Eurofins TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written
approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the
individual sections below.
This laboratory report is confidential and is intended for the sole use of Eurofins TestAmerica and its client.
RECEIPT
The samples were received on 4/26/2019 11:55 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperature of the cooler at receipt was 2.3º C.
TOTAL RECOVERABLE METALS (ICPMS)Samples PNA168:VON-1:W042519 (500-162329-1), PNA168:VON-1:W042519A (500-162329-2) and PNA168:VON-2:W042519
(500-162329-3) were analyzed for total recoverable metals (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 04/30/2019 and analyzed on 05/01/2019.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
Eurofins TestAmerica, ChicagoPage 3 of 16 5/2/2019
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Detection SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:VON-1:W042519 Lab Sample ID: 500-162329-1
No Detections.
Client Sample ID: PNA168:VON-1:W042519A Lab Sample ID: 500-162329-2
No Detections.
Client Sample ID: PNA168:VON-2:W042519 Lab Sample ID: 500-162329-3
Arsenic
RL
1.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
11.4 6020A
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
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Method SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method Method Description LaboratoryProtocol
SW8466020A Metals (ICP/MS) TAL CHI
SW8463005A Preparation, Total Recoverable or Dissolved Metals TAL CHI
Protocol References:
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins TestAmerica, Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200
Eurofins TestAmerica, Chicago
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Sample SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
500-162329-1 PNA168:VON-1:W042519 Water 04/25/19 09:30 04/26/19 11:55
500-162329-2 PNA168:VON-1:W042519A Water 04/25/19 09:30 04/26/19 11:55
500-162329-3 PNA168:VON-2:W042519 Water 04/25/19 09:45 04/26/19 11:55
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162329-1Client Sample ID: PNA168:VON-1:W042519Matrix: WaterDate Collected: 04/25/19 09:30
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 20:49 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162329-2Client Sample ID: PNA168:VON-1:W042519AMatrix: WaterDate Collected: 04/25/19 09:30
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 20:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 8 of 16 5/2/2019
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Client Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162329-3Client Sample ID: PNA168:VON-2:W042519Matrix: WaterDate Collected: 04/25/19 09:45
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 1.4 1.0 ug/L 04/30/19 08:11 05/01/19 20:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 9 of 16 5/2/2019
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Definitions/GlossaryJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
GlossaryThese commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Chicago
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QC Association SummaryJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Metals
Prep Batch: 482789
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A500-162329-1 PNA168:VON-1:W042519 Total Recoverable
Water 3005A500-162329-2 PNA168:VON-1:W042519A Total Recoverable
Water 3005A500-162329-3 PNA168:VON-2:W042519 Total Recoverable
Water 3005AMB 500-482789/1-A Method Blank Total Recoverable
Water 3005ALCS 500-482789/2-A Lab Control Sample Total Recoverable
Analysis Batch: 483261
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020A 482789500-162329-1 PNA168:VON-1:W042519 Total Recoverable
Water 6020A 482789500-162329-2 PNA168:VON-1:W042519A Total Recoverable
Water 6020A 482789500-162329-3 PNA168:VON-2:W042519 Total Recoverable
Water 6020A 482789MB 500-482789/1-A Method Blank Total Recoverable
Water 6020A 482789LCS 500-482789/2-A Lab Control Sample Total Recoverable
Eurofins TestAmerica, Chicago
Page 11 of 16 5/2/2019
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QC Sample ResultsJob ID: 500-162329-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method: 6020A - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 500-482789/1-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483261 Prep Batch: 482789
RL MDL
Arsenic <1.0 1.0 ug/L 04/30/19 08:11 05/01/19 19:30 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482789/2-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483261 Prep Batch: 482789
Arsenic 100 102 ug/L 102 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:VON-1:W042519 Lab Sample ID: 500-162329-1Matrix: WaterDate Collected: 04/25/19 09:30
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483261 05/01/19 20:49 FXG TAL CHITotal Recoverable
Client Sample ID: PNA168:VON-1:W042519A Lab Sample ID: 500-162329-2Matrix: WaterDate Collected: 04/25/19 09:30
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483261 05/01/19 20:52 FXG TAL CHITotal Recoverable
Client Sample ID: PNA168:VON-2:W042519 Lab Sample ID: 500-162329-3Matrix: WaterDate Collected: 04/25/19 09:45
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 08:11 SAH482789 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483261 05/01/19 20:56 FXG TAL CHITotal Recoverable
Laboratory References:
TAL CHI = Eurofins TestAmerica, Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200
Eurofins TestAmerica, Chicago
Page 13 of 16 5/2/2019
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Accreditation/Certification SummaryClient: Hull & Associates, Inc. Job ID: 500-162329-1Project/Site: PNA Pilkington - Ottawa
Laboratory: Eurofins TestAmerica, ChicagoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
California 29039State Program 04-30-19 *
Georgia State Program 4 N/A 04-30-19 *
Georgia State Program 4 939 04-30-19 *
Hawaii State Program 9 N/A 04-30-19 *
Illinois NELAP 5 100201 04-30-19 *
Indiana State Program 5 C-IL-02 04-30-19 *
Iowa State Program 7 82 05-01-20
Kansas NELAP 7 E-10161 10-31-19
Kentucky (UST) State Program 4 66 04-30-19 *
Kentucky (WW) State Program 4 KY90023 12-31-19
Louisiana NELAP 6 30720 06-30-19
Mississippi State Program 4 N/A 04-30-19 *
New York NELAP 2 12019 04-01-20
North Carolina (WW/SW) State Program 4 291 12-31-19
North Dakota State Program 8 R-194 04-30-19 *
Oklahoma State Program 6 8908 08-31-19
South Carolina State Program 4 77001 04-30-19 *
Wisconsin State Program 5 999580010 08-31-19
Wyoming State Program 8 8TMS-Q 04-30-19 *
Laboratory: Eurofins TestAmerica, CantonAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
California 29279State Program 02-23-20
Connecticut State Program 1 PH-0590 12-31-19
Florida NELAP 4 E87225 06-30-19
Illinois NELAP 5 200004 07-31-19
Kansas NELAP 7 E-10336 04-30-19 *
Kentucky (UST) State Program 4 58 02-23-20
Kentucky (WW) State Program 4 98016 12-31-19
Minnesota NELAP 5 039-999-348 12-31-19 *
Minnesota (Petrofund) State Program 1 3506 07-31-19
Nevada State Program 9 OH00048 07-31-19
New Jersey NELAP 2 OH001 06-30-19
New York NELAP 2 10975 03-31-20
Ohio VAP State Program 5 CL0024 09-06-19
Oregon NELAP 10 4062 02-23-20
Pennsylvania NELAP 3 68-00340 08-31-19 *
Texas NELAP 6 T104704517-18-10 08-31-19
USDA Federal P330-16-00404 12-28-19
Virginia NELAP 3 460175 09-14-19
Washington State Program 10 C971 01-12-20 *
West Virginia DEP State Program 3 210 12-31-19
Eurofins TestAmerica, Chicago
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
Page 14 of 16 5/2/2019
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Login Sample Receipt Checklist
Client: Hull & Associates, Inc. Job Number: 500-162329-1
Login Number: 162329
Question Answer Comment
Creator: Scott, Sherri L
List Source: Eurofins TestAmerica, Chicago
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded. 2.3
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
TrueThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
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ANALYTICAL REPORTEurofins TestAmerica, Chicago2417 Bond StreetUniversity Park, IL 60484Tel: (708)534-5200
Laboratory Job ID: 500-162331-1Client Project/Site: PNA Pilkington - Ottawa
For:Hull & Associates, Inc.6397 Emerald ParkwaySuite 200Dublin, Ohio 43016-2231
Attn: Ms. Monica Williamson
Authorized for release by:5/9/2019 8:58:11 AM
Opal Johnson, Project Manager II(330)[email protected]
The test results in this report meet all 2003 NELAC and 2009 TNI requirements for accreditedparameters, exceptions are noted in this report. This report may not be reproduced except in full,and with written approval from the laboratory. For questions please contact the Project Managerat the e-mail address or telephone number listed on this page.
This report has been electronically signed and authorized by the signatory. Electronic signature isintended to be the legally binding equivalent of a traditionally handwritten signature.
Results relate only to the items tested and the sample(s) as received by the laboratory.
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Table of Contents
Client: Hull & Associates, Inc.Project/Site: PNA Pilkington - Ottawa
Laboratory Job ID: 500-162331-1
Page 2 of 79Eurofins TestAmerica, Chicago
5/9/2019
Cover Page . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
Table of Contents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 2
Case Narrative . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
Detection Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
Method Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Sample Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
Client Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Definitions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
QC Association . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 57
QC Sample Results . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Chronicle . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Certification Summary . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Chain of Custody . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 75
Receipt Checklists . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
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Case NarrativeClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Job ID: 500-162331-1
Laboratory: Eurofins TestAmerica, Chicago
Narrative
CASE NARRATIVE
Client: Hull & Associates, Inc.
Project: PNA Pilkington - Ottawa
Report Number: 500-162331-1
With the exceptions noted as flags or footnotes, standard analytical protocols were followed in the analysis of the samples and no problems were encountered or anomalies observed. In addition all laboratory quality control samples were within established control limits, with any exceptions noted below. Each sample was analyzed to achieve the lowest possible reporting limit within the constraints of
the method. In some cases, due to interference or analytes present at high concentrations, samples were diluted. For diluted samples, the reporting limits are adjusted relative to the dilution required.
Eurofins TestAmerica, Chicago attests to the validity of the laboratory data generated by Eurofins TestAmerica facilities reported herein. All analyses performed by Eurofins TestAmerica facilities were done using established laboratory SOPs that incorporate QA/QC procedures
described in the application methods. Eurofins TestAmerica’s operations groups have reviewed the data for compliance with the laboratory QA/QC plan, and data have been found to be compliant with laboratory protocols unless otherwise noted below.
The test results in this report meet all NELAP requirements for parameters for which accreditation is required or available. Any exceptions to NELAP requirements are noted in this report. Pursuant to NELAP, this report may not be reproduced, except in full, without the written
approval of the laboratory.
Calculations are performed before rounding to avoid round-off errors in calculated results.
All holding times were met and proper preservation noted for the methods performed on these samples, unless otherwise detailed in the
individual sections below.
This laboratory report is confidential and is intended for the sole use of Eurofins TestAmerica and its client.
RECEIPT
The samples were received on 4/26/2019 11:55 AM; the samples arrived in good condition, properly preserved and, where required, on ice. The temperatures of the 3 coolers at receipt time were 2.3º C, 3.3º C and 3.6º C.
Receipt Exceptions
Received both bottles for samples 18-20 with date of 042519 and it's in the sample ID. COC has 4/24/19, logged in as 4/25/19. Received both bottles for sample 23 with ID of MW-5, logged per COC.
TOTAL RECOVERABLE METALS (ICPMS)Samples PNA168:P-23:G042419 (500-162331-1), PNA168:P-22:G042419 (500-162331-2), PNA168:P-5:G042419 (500-162331-3),
PNA168:MW-2U:G042419 (500-162331-4), PNA168:MW-4U:G042419 (500-162331-5), PNA168:MW-16:G042419 (500-162331-6), PNA168:MW-6L:G042419 (500-162331-7), PNA168:MW-6M:G042419 (500-162331-8), PNA168:MW-6U:G042419 (500-162331-9),
PNA168:MW-18L:G042419 (500-162331-10), PNA168:MW-18M:G042419 (500-162331-11), PNA168:MW-18U:G042419 (500-162331-12),
PNA168:MW-15:G042419 (500-162331-13), PNA168:MW-14:G042419 (500-162331-14), PNA168:FB-1:G042419 (500-162331-15), PNA168:PZ-2:G042419 (500-162331-16), PNA168:PZ-2:G042419A (500-162331-17), PNA168:MW-13M:G042519 (500-162331-18),
PNA168:MW-13L:G042519 (500-162331-19), PNA168:MW-13U:G042519 (500-162331-20), PNA168:MW-13M:G042519A
(500-162331-21), PNA168:S-5:G042519 (500-162331-22), PNA168:MW-5:G042519 (500-162331-23), PNA168:MW-21:G042519 (500-162331-24), PNA168:MW-22:G042519 (500-162331-25), PNA168:S-1:G042519 (500-162331-26), PNA168:S-2:G042519
(500-162331-27), PNA168:S-8:G042519 (500-162331-28), PNA168:MW-20:G042519 (500-162331-29), PNA168:S-3:G042519 (500-162331-30), PNA168:P-25:G042519 (500-162331-31), PNA168:P-9:G042619 (500-162331-32), PNA168:HP-5:G042619
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Case NarrativeClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Job ID: 500-162331-1 (Continued)
Laboratory: Eurofins TestAmerica, Chicago (Continued)
(500-162331-33), PNA168:HP-7:G042619 (500-162331-34), PNA168:MW-23:G042619 (500-162331-35), PNA168:S-6R:G042519
(500-162331-36), PNA168:MW-12U:G042519 (500-162331-37), PNA168:MW-12M:G042519 (500-162331-38), PNA168:MW-12L:G042519 (500-162331-39), PNA168:MW-11U:G042519 (500-162331-40), PNA168:MW-11M:G042519 (500-162331-41), PNA168:MW-11L:G042519
(500-162331-42), PNA168:FB-2:G042519 (500-162331-43) and PNA168:FB-3:G042619 (500-162331-44) were analyzed for total
recoverable metals (ICPMS) in accordance with EPA SW-846 Method 6020A. The samples were prepared on 04/30/2019 and analyzed on 05/02/2019, 05/03/2019 and 05/08/2019.
Samples PNA168:HP-5:G042619 (500-162331-33)[20X] and PNA168:HP-7:G042619 (500-162331-34)[20X] required dilution prior to
analysis. The reporting limits have been adjusted accordingly.
Arsenic failed the recovery criteria high for the MS and the MSD of sample PNA168:P-23:G042419MSD (500-162331-1) in batch
500-484297.
No additional analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
TOTAL DISSOLVED SOLIDSSamples PNA168:P-23:G042419 (500-162331-1), PNA168:P-22:G042419 (500-162331-2), PNA168:P-5:G042419 (500-162331-3),
PNA168:MW-2U:G042419 (500-162331-4), PNA168:MW-4U:G042419 (500-162331-5), PNA168:MW-16:G042419 (500-162331-6), PNA168:MW-6L:G042419 (500-162331-7), PNA168:MW-6M:G042419 (500-162331-8), PNA168:MW-6U:G042419 (500-162331-9), PNA168:MW-18L:G042419 (500-162331-10), PNA168:MW-18M:G042419 (500-162331-11), PNA168:MW-18U:G042419 (500-162331-12), PNA168:MW-15:G042419 (500-162331-13), PNA168:MW-14:G042419 (500-162331-14), PNA168:FB-1:G042419 (500-162331-15), PNA168:PZ-2:G042419 (500-162331-16), PNA168:PZ-2:G042419A (500-162331-17), PNA168:MW-13M:G042519 (500-162331-18),
PNA168:MW-13L:G042519 (500-162331-19), PNA168:MW-13U:G042519 (500-162331-20), PNA168:MW-13M:G042519A (500-162331-21), PNA168:S-5:G042519 (500-162331-22), PNA168:MW-5:G042519 (500-162331-23), PNA168:MW-21:G042519 (500-162331-24), PNA168:MW-22:G042519 (500-162331-25), PNA168:S-1:G042519 (500-162331-26), PNA168:S-2:G042519 (500-162331-27), PNA168:S-8:G042519 (500-162331-28), PNA168:MW-20:G042519 (500-162331-29), PNA168:S-3:G042519 (500-162331-30), PNA168:P-25:G042519 (500-162331-31), PNA168:P-9:G042619 (500-162331-32), PNA168:HP-5:G042619
(500-162331-33), PNA168:HP-7:G042619 (500-162331-34), PNA168:MW-23:G042619 (500-162331-35), PNA168:S-6R:G042519 (500-162331-36), PNA168:MW-12U:G042519 (500-162331-37), PNA168:MW-12M:G042519 (500-162331-38), PNA168:MW-12L:G042519 (500-162331-39), PNA168:MW-11U:G042519 (500-162331-40), PNA168:MW-11M:G042519 (500-162331-41), PNA168:MW-11L:G042519 (500-162331-42), PNA168:FB-2:G042519 (500-162331-43) and PNA168:FB-3:G042619 (500-162331-44) were analyzed for total dissolved solids in accordance with SM 2540C. The samples were analyzed on 04/27/2019, 04/29/2019, 04/30/2019 and 05/01/2019.
No analytical or quality issues were noted, other than those described above or in the Definitions/Glossary page.
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Detection SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:P-23:G042419 Lab Sample ID: 500-162331-1
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
11900 6020A
Total Dissolved Solids 10 mg/L Total/NA1860 SM 2540C
Client Sample ID: PNA168:P-22:G042419 Lab Sample ID: 500-162331-2
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
119 6020A
Total Dissolved Solids 10 mg/L Total/NA1460 SM 2540C
Client Sample ID: PNA168:P-5:G042419 Lab Sample ID: 500-162331-3
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1320 6020A
Total Dissolved Solids 10 mg/L Total/NA1520 SM 2540C
Client Sample ID: PNA168:MW-2U:G042419 Lab Sample ID: 500-162331-4
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
12000 6020A
Total Dissolved Solids 10 mg/L Total/NA13000 SM 2540C
Client Sample ID: PNA168:MW-4U:G042419 Lab Sample ID: 500-162331-5
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
153 6020A
Total Dissolved Solids 10 mg/L Total/NA1710 SM 2540C
Client Sample ID: PNA168:MW-16:G042419 Lab Sample ID: 500-162331-6
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1260 6020A
Total Dissolved Solids 10 mg/L Total/NA11000 SM 2540C
Client Sample ID: PNA168:MW-6L:G042419 Lab Sample ID: 500-162331-7
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
11800 6020A
Total Dissolved Solids 10 mg/L Total/NA11100 SM 2540C
Client Sample ID: PNA168:MW-6M:G042419 Lab Sample ID: 500-162331-8
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
15.4 6020A
Total Dissolved Solids 10 mg/L Total/NA11100 SM 2540C
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
Page 5 of 79 5/9/2019
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Detection SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-6U:G042419 Lab Sample ID: 500-162331-9
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
117 6020A
Total Dissolved Solids 10 mg/L Total/NA1470 SM 2540C
Client Sample ID: PNA168:MW-18L:G042419 Lab Sample ID: 500-162331-10
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
114 6020A
Total Dissolved Solids 10 mg/L Total/NA11300 SM 2540C
Client Sample ID: PNA168:MW-18M:G042419 Lab Sample ID: 500-162331-11
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
16.3 6020A
Total Dissolved Solids 10 mg/L Total/NA12600 SM 2540C
Client Sample ID: PNA168:MW-18U:G042419 Lab Sample ID: 500-162331-12
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1600 SM 2540C
Client Sample ID: PNA168:MW-15:G042419 Lab Sample ID: 500-162331-13
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
136 6020A
Total Dissolved Solids 10 mg/L Total/NA1610 SM 2540C
Client Sample ID: PNA168:MW-14:G042419 Lab Sample ID: 500-162331-14
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1760 6020A
Total Dissolved Solids 10 mg/L Total/NA1870 SM 2540C
Client Sample ID: PNA168:FB-1:G042419 Lab Sample ID: 500-162331-15
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA150 SM 2540C
Client Sample ID: PNA168:PZ-2:G042419 Lab Sample ID: 500-162331-16
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1530 6020A
Total Dissolved Solids 10 mg/L Total/NA1550 SM 2540C
Client Sample ID: PNA168:PZ-2:G042419A Lab Sample ID: 500-162331-17
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1630 6020A
Total Dissolved Solids 10 mg/L Total/NA1570 SM 2540C
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
Page 6 of 79 5/9/2019
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Detection SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-13M:G042519 Lab Sample ID: 500-162331-18
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
129 6020A
Total Dissolved Solids 10 mg/L Total/NA1540 SM 2540C
Client Sample ID: PNA168:MW-13L:G042519 Lab Sample ID: 500-162331-19
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1610 SM 2540C
Client Sample ID: PNA168:MW-13U:G042519 Lab Sample ID: 500-162331-20
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
117 6020A
Total Dissolved Solids 10 mg/L Total/NA1540 SM 2540C
Client Sample ID: PNA168:MW-13M:G042519A Lab Sample ID: 500-162331-21
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
130 6020A
Total Dissolved Solids 10 mg/L Total/NA1540 SM 2540C
Client Sample ID: PNA168:S-5:G042519 Lab Sample ID: 500-162331-22
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1620 SM 2540C
Client Sample ID: PNA168:MW-5:G042519 Lab Sample ID: 500-162331-23
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1150 6020A
Total Dissolved Solids 10 mg/L Total/NA1950 SM 2540C
Client Sample ID: PNA168:MW-21:G042519 Lab Sample ID: 500-162331-24
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1570 SM 2540C
Client Sample ID: PNA168:MW-22:G042519 Lab Sample ID: 500-162331-25
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1310 6020A
Total Dissolved Solids 10 mg/L Total/NA12600 SM 2540C
Client Sample ID: PNA168:S-1:G042519 Lab Sample ID: 500-162331-26
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
1130 6020A
Total Dissolved Solids 10 mg/L Total/NA11600 SM 2540C
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
Page 7 of 79 5/9/2019
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Detection SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:S-2:G042519 Lab Sample ID: 500-162331-27
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA11800 SM 2540C
Client Sample ID: PNA168:S-8:G042519 Lab Sample ID: 500-162331-28
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA13200 SM 2540C
Client Sample ID: PNA168:MW-20:G042519 Lab Sample ID: 500-162331-29
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
116 6020A
Total Dissolved Solids 10 mg/L Total/NA1810 SM 2540C
Client Sample ID: PNA168:S-3:G042519 Lab Sample ID: 500-162331-30
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1530 SM 2540C
Client Sample ID: PNA168:P-25:G042519 Lab Sample ID: 500-162331-31
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1420 SM 2540C
Client Sample ID: PNA168:P-9:G042619 Lab Sample ID: 500-162331-32
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1230 SM 2540C
Client Sample ID: PNA168:HP-5:G042619 Lab Sample ID: 500-162331-33
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
2016000 6020A
Total Dissolved Solids 14 mg/L Total/NA17300 SM 2540C
Client Sample ID: PNA168:HP-7:G042619 Lab Sample ID: 500-162331-34
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
2054000 6020A
Total Dissolved Solids 54 mg/L Total/NA129000 SM 2540C
Client Sample ID: PNA168:MW-23:G042619 Lab Sample ID: 500-162331-35
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
17.5 6020A
Total Dissolved Solids 10 mg/L Total/NA1640 SM 2540C
Client Sample ID: PNA168:S-6R:G042519 Lab Sample ID: 500-162331-36
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1960 SM 2540C
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
Page 8 of 79 5/9/2019
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Detection SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-12U:G042519 Lab Sample ID: 500-162331-37
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1670 SM 2540C
Client Sample ID: PNA168:MW-12M:G042519 Lab Sample ID: 500-162331-38
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
114 6020A
Total Dissolved Solids 10 mg/L Total/NA1750 SM 2540C
Client Sample ID: PNA168:MW-12L:G042519 Lab Sample ID: 500-162331-39
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1760 SM 2540C
Client Sample ID: PNA168:MW-11U:G042519 Lab Sample ID: 500-162331-40
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA1600 SM 2540C
Client Sample ID: PNA168:MW-11M:G042519 Lab Sample ID: 500-162331-41
Arsenic
RL
5.0 ug/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total
Recoverable
15.4 6020A
Total Dissolved Solids 10 mg/L Total/NA1570 SM 2540C
Client Sample ID: PNA168:MW-11L:G042519 Lab Sample ID: 500-162331-42
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA11600 SM 2540C
Client Sample ID: PNA168:FB-2:G042519 Lab Sample ID: 500-162331-43
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA168 SM 2540C
Client Sample ID: PNA168:FB-3:G042619 Lab Sample ID: 500-162331-44
Total Dissolved Solids
RL
10 mg/L
MDLAnalyte Result Qualifier Unit Dil Fac D Method Prep Type
Total/NA134 SM 2540C
Eurofins TestAmerica, Chicago
This Detection Summary does not include radiochemical test results.
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Method SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method Method Description LaboratoryProtocol
SW8466020A Metals (ICP/MS) TAL CHI
SMSM 2540C Solids, Total Dissolved (TDS) TAL CHI
SW8463005A Preparation, Total Recoverable or Dissolved Metals TAL CHI
Protocol References:
SM = "Standard Methods For The Examination Of Water And Wastewater"
SW846 = "Test Methods For Evaluating Solid Waste, Physical/Chemical Methods", Third Edition, November 1986 And Its Updates.
Laboratory References:
TAL CHI = Eurofins TestAmerica, Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200
Eurofins TestAmerica, Chicago
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Sample SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID Client Sample ID ReceivedCollectedMatrix
500-162331-1 PNA168:P-23:G042419 Water 04/24/19 08:28 04/26/19 11:55
500-162331-2 PNA168:P-22:G042419 Water 04/24/19 08:56 04/26/19 11:55
500-162331-3 PNA168:P-5:G042419 Water 04/24/19 09:25 04/26/19 11:55
500-162331-4 PNA168:MW-2U:G042419 Water 04/24/19 10:02 04/26/19 11:55
500-162331-5 PNA168:MW-4U:G042419 Water 04/24/19 10:34 04/26/19 11:55
500-162331-6 PNA168:MW-16:G042419 Water 04/24/19 11:15 04/26/19 11:55
500-162331-7 PNA168:MW-6L:G042419 Water 04/24/19 11:54 04/26/19 11:55
500-162331-8 PNA168:MW-6M:G042419 Water 04/24/19 12:20 04/26/19 11:55
500-162331-9 PNA168:MW-6U:G042419 Water 04/24/19 12:51 04/26/19 11:55
500-162331-10 PNA168:MW-18L:G042419 Water 04/24/19 13:29 04/26/19 11:55
500-162331-11 PNA168:MW-18M:G042419 Water 04/24/19 13:58 04/26/19 11:55
500-162331-12 PNA168:MW-18U:G042419 Water 04/24/19 14:27 04/26/19 11:55
500-162331-13 PNA168:MW-15:G042419 Water 04/24/19 15:01 04/26/19 11:55
500-162331-14 PNA168:MW-14:G042419 Water 04/24/19 15:35 04/26/19 11:55
500-162331-15 PNA168:FB-1:G042419 Water 04/24/19 12:35 04/26/19 11:55
500-162331-16 PNA168:PZ-2:G042419 Water 04/24/19 16:15 04/26/19 11:55
500-162331-17 PNA168:PZ-2:G042419A Water 04/24/19 16:15 04/26/19 11:55
500-162331-18 PNA168:MW-13M:G042519 Water 04/25/19 05:44 04/26/19 11:55
500-162331-19 PNA168:MW-13L:G042519 Water 04/25/19 06:12 04/26/19 11:55
500-162331-20 PNA168:MW-13U:G042519 Water 04/25/19 06:37 04/26/19 11:55
500-162331-21 PNA168:MW-13M:G042519A Water 04/25/19 05:44 04/26/19 11:55
500-162331-22 PNA168:S-5:G042519 Water 04/25/19 07:10 04/26/19 11:55
500-162331-23 PNA168:MW-5:G042519 Water 04/25/19 11:00 04/26/19 11:55
500-162331-24 PNA168:MW-21:G042519 Water 04/25/19 12:35 04/26/19 11:55
500-162331-25 PNA168:MW-22:G042519 Water 04/25/19 13:19 04/26/19 11:55
500-162331-26 PNA168:S-1:G042519 Water 04/25/19 13:48 04/26/19 11:55
500-162331-27 PNA168:S-2:G042519 Water 04/25/19 14:23 04/26/19 11:55
500-162331-28 PNA168:S-8:G042519 Water 04/25/19 14:49 04/26/19 11:55
500-162331-29 PNA168:MW-20:G042519 Water 04/25/19 15:24 04/26/19 11:55
500-162331-30 PNA168:S-3:G042519 Water 04/25/19 15:55 04/26/19 11:55
500-162331-31 PNA168:P-25:G042519 Water 04/25/19 16:35 04/26/19 11:55
500-162331-32 PNA168:P-9:G042619 Water 04/26/19 06:13 04/26/19 11:55
500-162331-33 PNA168:HP-5:G042619 Water 04/26/19 06:50 04/26/19 11:55
500-162331-34 PNA168:HP-7:G042619 Water 04/26/19 07:22 04/26/19 11:55
500-162331-35 PNA168:MW-23:G042619 Water 04/26/19 08:11 04/26/19 11:55
500-162331-36 PNA168:S-6R:G042519 Water 04/25/19 08:35 04/26/19 11:55
500-162331-37 PNA168:MW-12U:G042519 Water 04/25/19 10:28 04/26/19 11:55
500-162331-38 PNA168:MW-12M:G042519 Water 04/25/19 11:31 04/26/19 11:55
500-162331-39 PNA168:MW-12L:G042519 Water 04/25/19 13:35 04/26/19 11:55
500-162331-40 PNA168:MW-11U:G042519 Water 04/25/19 15:46 04/26/19 11:55
500-162331-41 PNA168:MW-11M:G042519 Water 04/25/19 16:50 04/26/19 11:55
500-162331-42 PNA168:MW-11L:G042519 Water 04/25/19 17:46 04/26/19 11:55
500-162331-43 PNA168:FB-2:G042519 Water 04/25/19 17:40 04/26/19 11:55
500-162331-44 PNA168:FB-3:G042619 Water 04/26/19 07:10 04/26/19 11:55
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-1Client Sample ID: PNA168:P-23:G042419Matrix: WaterDate Collected: 04/24/19 08:28
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 1900 5.0 ug/L 04/30/19 16:04 05/08/19 11:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 860 10 mg/L 04/27/19 02:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-2Client Sample ID: PNA168:P-22:G042419Matrix: WaterDate Collected: 04/24/19 08:56
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 19 5.0 ug/L 04/30/19 16:04 05/08/19 12:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 460 10 mg/L 04/27/19 02:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 13 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-3Client Sample ID: PNA168:P-5:G042419Matrix: WaterDate Collected: 04/24/19 09:25
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 320 5.0 ug/L 04/30/19 16:04 05/08/19 12:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 520 10 mg/L 04/29/19 05:19 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 14 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-4Client Sample ID: PNA168:MW-2U:G042419Matrix: WaterDate Collected: 04/24/19 10:02
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 2000 5.0 ug/L 04/30/19 16:04 05/08/19 12:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 3000 10 mg/L 04/29/19 05:21 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-5Client Sample ID: PNA168:MW-4U:G042419Matrix: WaterDate Collected: 04/24/19 10:34
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 53 5.0 ug/L 04/30/19 16:04 05/08/19 12:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 710 10 mg/L 04/29/19 05:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 16 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-6Client Sample ID: PNA168:MW-16:G042419Matrix: WaterDate Collected: 04/24/19 11:15
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 260 5.0 ug/L 04/30/19 16:04 05/08/19 12:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1000 10 mg/L 04/29/19 05:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 17 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-7Client Sample ID: PNA168:MW-6L:G042419Matrix: WaterDate Collected: 04/24/19 11:54
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 1800 5.0 ug/L 04/30/19 16:04 05/08/19 12:24 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1100 10 mg/L 04/29/19 05:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-8Client Sample ID: PNA168:MW-6M:G042419Matrix: WaterDate Collected: 04/24/19 12:20
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 5.4 5.0 ug/L 04/30/19 16:04 05/08/19 12:26 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1100 10 mg/L 04/29/19 05:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-9Client Sample ID: PNA168:MW-6U:G042419Matrix: WaterDate Collected: 04/24/19 12:51
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 17 5.0 ug/L 04/30/19 16:04 05/08/19 12:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 470 10 mg/L 04/29/19 05:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 20 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-10Client Sample ID: PNA168:MW-18L:G042419Matrix: WaterDate Collected: 04/24/19 13:29
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 14 5.0 ug/L 04/30/19 16:04 05/08/19 12:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1300 10 mg/L 04/29/19 05:37 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 21 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-11Client Sample ID: PNA168:MW-18M:G042419Matrix: WaterDate Collected: 04/24/19 13:58
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 6.3 5.0 ug/L 04/30/19 16:04 05/08/19 12:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 2600 10 mg/L 04/29/19 05:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 22 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-12Client Sample ID: PNA168:MW-18U:G042419Matrix: WaterDate Collected: 04/24/19 14:27
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 600 10 mg/L 04/29/19 05:42 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 23 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-13Client Sample ID: PNA168:MW-15:G042419Matrix: WaterDate Collected: 04/24/19 15:01
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 36 5.0 ug/L 04/30/19 16:04 05/08/19 12:38 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 610 10 mg/L 04/29/19 05:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 24 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-14Client Sample ID: PNA168:MW-14:G042419Matrix: WaterDate Collected: 04/24/19 15:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 760 5.0 ug/L 04/30/19 16:04 05/08/19 12:39 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 870 10 mg/L 04/29/19 05:47 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 25 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-15Client Sample ID: PNA168:FB-1:G042419Matrix: WaterDate Collected: 04/24/19 12:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 50 10 mg/L 04/29/19 05:50 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 26 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-16Client Sample ID: PNA168:PZ-2:G042419Matrix: WaterDate Collected: 04/24/19 16:15
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 530 5.0 ug/L 04/30/19 16:04 05/08/19 12:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 550 10 mg/L 04/29/19 05:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 27 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-17Client Sample ID: PNA168:PZ-2:G042419AMatrix: WaterDate Collected: 04/24/19 16:15
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 630 5.0 ug/L 04/30/19 16:04 05/08/19 12:45 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 570 10 mg/L 04/29/19 05:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 28 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-18Client Sample ID: PNA168:MW-13M:G042519Matrix: WaterDate Collected: 04/25/19 05:44
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 29 5.0 ug/L 04/30/19 16:04 05/08/19 12:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 540 10 mg/L 04/30/19 02:15 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 29 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-19Client Sample ID: PNA168:MW-13L:G042519Matrix: WaterDate Collected: 04/25/19 06:12
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 12:48 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 610 10 mg/L 04/30/19 02:22 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 30 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-20Client Sample ID: PNA168:MW-13U:G042519Matrix: WaterDate Collected: 04/25/19 06:37
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 17 5.0 ug/L 04/30/19 16:04 05/08/19 12:50 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 540 10 mg/L 04/30/19 02:28 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 31 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-21Client Sample ID: PNA168:MW-13M:G042519AMatrix: WaterDate Collected: 04/25/19 05:44
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 30 5.0 ug/L 04/30/19 16:06 05/03/19 02:49 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 540 10 mg/L 04/30/19 02:30 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 32 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-22Client Sample ID: PNA168:S-5:G042519Matrix: WaterDate Collected: 04/25/19 07:10
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 03:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 620 10 mg/L 04/30/19 02:33 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 33 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-23Client Sample ID: PNA168:MW-5:G042519Matrix: WaterDate Collected: 04/25/19 11:00
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 150 5.0 ug/L 04/30/19 16:06 05/03/19 03:12 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 950 10 mg/L 04/30/19 02:35 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 34 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-24Client Sample ID: PNA168:MW-21:G042519Matrix: WaterDate Collected: 04/25/19 12:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 03:16 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 570 10 mg/L 04/30/19 02:38 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 35 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-25Client Sample ID: PNA168:MW-22:G042519Matrix: WaterDate Collected: 04/25/19 13:19
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 310 5.0 ug/L 04/30/19 16:06 05/08/19 12:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 2600 10 mg/L 04/30/19 02:41 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 36 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-26Client Sample ID: PNA168:S-1:G042519Matrix: WaterDate Collected: 04/25/19 13:48
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 130 5.0 ug/L 04/30/19 16:06 05/08/19 13:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1600 10 mg/L 04/30/19 02:43 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 37 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-27Client Sample ID: PNA168:S-2:G042519Matrix: WaterDate Collected: 04/25/19 14:23
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:08 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1800 10 mg/L 04/30/19 02:46 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 38 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-28Client Sample ID: PNA168:S-8:G042519Matrix: WaterDate Collected: 04/25/19 14:49
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 3200 10 mg/L 04/30/19 02:48 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 39 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-29Client Sample ID: PNA168:MW-20:G042519Matrix: WaterDate Collected: 04/25/19 15:24
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 16 5.0 ug/L 04/30/19 16:06 05/08/19 13:11 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 810 10 mg/L 04/30/19 02:51 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 40 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-30Client Sample ID: PNA168:S-3:G042519Matrix: WaterDate Collected: 04/25/19 15:55
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 530 10 mg/L 04/30/19 02:53 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 41 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-31Client Sample ID: PNA168:P-25:G042519Matrix: WaterDate Collected: 04/25/19 16:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:18 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 420 10 mg/L 04/30/19 02:56 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 42 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-32Client Sample ID: PNA168:P-9:G042619Matrix: WaterDate Collected: 04/26/19 06:13
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:20 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 230 10 mg/L 04/30/19 02:59 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 43 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-33Client Sample ID: PNA168:HP-5:G042619Matrix: WaterDate Collected: 04/26/19 06:50
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 16000 5.0 ug/L 04/30/19 16:06 05/08/19 13:22 20
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 7300 14 mg/L 05/01/19 03:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 44 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-34Client Sample ID: PNA168:HP-7:G042619Matrix: WaterDate Collected: 04/26/19 07:22
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 54000 5.0 ug/L 04/30/19 16:06 05/08/19 13:24 20
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 29000 54 mg/L 05/01/19 03:57 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 45 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-35Client Sample ID: PNA168:MW-23:G042619Matrix: WaterDate Collected: 04/26/19 08:11
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 7.5 5.0 ug/L 04/30/19 16:06 05/08/19 13:25 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 640 10 mg/L 04/30/19 03:06 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 46 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-36Client Sample ID: PNA168:S-6R:G042519Matrix: WaterDate Collected: 04/25/19 08:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:27 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 960 10 mg/L 04/30/19 03:09 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 47 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-37Client Sample ID: PNA168:MW-12U:G042519Matrix: WaterDate Collected: 04/25/19 10:28
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 670 10 mg/L 04/30/19 03:52 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 48 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-38Client Sample ID: PNA168:MW-12M:G042519Matrix: WaterDate Collected: 04/25/19 11:31
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 14 5.0 ug/L 04/30/19 16:06 05/08/19 13:31 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 750 10 mg/L 04/30/19 03:55 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
Page 49 of 79 5/9/2019
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-39Client Sample ID: PNA168:MW-12L:G042519Matrix: WaterDate Collected: 04/25/19 13:35
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 760 10 mg/L 04/30/19 03:58 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-40Client Sample ID: PNA168:MW-11U:G042519Matrix: WaterDate Collected: 04/25/19 15:46
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/08/19 13:34 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 600 10 mg/L 04/30/19 04:01 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-41Client Sample ID: PNA168:MW-11M:G042519Matrix: WaterDate Collected: 04/25/19 16:50
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic 5.4 5.0 ug/L 04/30/19 16:07 05/02/19 19:25 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 570 10 mg/L 04/30/19 04:04 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-42Client Sample ID: PNA168:MW-11L:G042519Matrix: WaterDate Collected: 04/25/19 17:46
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:29 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 1600 10 mg/L 04/30/19 04:07 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-43Client Sample ID: PNA168:FB-2:G042519Matrix: WaterDate Collected: 04/25/19 17:40
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:32 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 68 10 mg/L 04/30/19 04:10 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Client Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Lab Sample ID: 500-162331-44Client Sample ID: PNA168:FB-3:G042619Matrix: WaterDate Collected: 04/26/19 07:10
Date Received: 04/26/19 11:55
Method: 6020A - Metals (ICP/MS) - Total RecoverableRL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:36 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
General ChemistryRL MDL
Total Dissolved Solids 34 10 mg/L 04/30/19 04:13 1
Analyte Dil FacAnalyzedPreparedUnit DResult Qualifier
Eurofins TestAmerica, Chicago
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Definitions/GlossaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Qualifiers
MetalsQualifier Description
4 MS, MSD: The analyte present in the original sample is greater than 4 times the matrix spike concentration; therefore, control limits are not
applicable.
Qualifier
GlossaryThese commonly used abbreviations may or may not be present in this report.
¤ Listed under the "D" column to designate that the result is reported on a dry weight basis
Abbreviation
%R Percent Recovery
CFL Contains Free Liquid
CNF Contains No Free Liquid
DER Duplicate Error Ratio (normalized absolute difference)
Dil Fac Dilution Factor
DL Detection Limit (DoD/DOE)
DL, RA, RE, IN Indicates a Dilution, Re-analysis, Re-extraction, or additional Initial metals/anion analysis of the sample
DLC Decision Level Concentration (Radiochemistry)
EDL Estimated Detection Limit (Dioxin)
LOD Limit of Detection (DoD/DOE)
LOQ Limit of Quantitation (DoD/DOE)
MDA Minimum Detectable Activity (Radiochemistry)
MDC Minimum Detectable Concentration (Radiochemistry)
MDL Method Detection Limit
ML Minimum Level (Dioxin)
NC Not Calculated
ND Not Detected at the reporting limit (or MDL or EDL if shown)
PQL Practical Quantitation Limit
QC Quality Control
RER Relative Error Ratio (Radiochemistry)
RL Reporting Limit or Requested Limit (Radiochemistry)
RPD Relative Percent Difference, a measure of the relative difference between two points
TEF Toxicity Equivalent Factor (Dioxin)
TEQ Toxicity Equivalent Quotient (Dioxin)
Eurofins TestAmerica, Chicago
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QC Association SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Metals
Prep Batch: 482913
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A500-162331-1 PNA168:P-23:G042419 Total Recoverable
Water 3005A500-162331-2 PNA168:P-22:G042419 Total Recoverable
Water 3005A500-162331-3 PNA168:P-5:G042419 Total Recoverable
Water 3005A500-162331-4 PNA168:MW-2U:G042419 Total Recoverable
Water 3005A500-162331-5 PNA168:MW-4U:G042419 Total Recoverable
Water 3005A500-162331-6 PNA168:MW-16:G042419 Total Recoverable
Water 3005A500-162331-7 PNA168:MW-6L:G042419 Total Recoverable
Water 3005A500-162331-8 PNA168:MW-6M:G042419 Total Recoverable
Water 3005A500-162331-9 PNA168:MW-6U:G042419 Total Recoverable
Water 3005A500-162331-10 PNA168:MW-18L:G042419 Total Recoverable
Water 3005A500-162331-11 PNA168:MW-18M:G042419 Total Recoverable
Water 3005A500-162331-12 PNA168:MW-18U:G042419 Total Recoverable
Water 3005A500-162331-13 PNA168:MW-15:G042419 Total Recoverable
Water 3005A500-162331-14 PNA168:MW-14:G042419 Total Recoverable
Water 3005A500-162331-15 PNA168:FB-1:G042419 Total Recoverable
Water 3005A500-162331-16 PNA168:PZ-2:G042419 Total Recoverable
Water 3005A500-162331-17 PNA168:PZ-2:G042419A Total Recoverable
Water 3005A500-162331-18 PNA168:MW-13M:G042519 Total Recoverable
Water 3005A500-162331-19 PNA168:MW-13L:G042519 Total Recoverable
Water 3005A500-162331-20 PNA168:MW-13U:G042519 Total Recoverable
Water 3005AMB 500-482913/1-A Method Blank Total Recoverable
Water 3005ALCS 500-482913/2-A Lab Control Sample Total Recoverable
Water 3005A500-162331-1 MS PNA168:P-23:G042419 Total Recoverable
Water 3005A500-162331-1 MSD PNA168:P-23:G042419 Total Recoverable
Water 3005A500-162331-1 DU PNA168:P-23:G042419 Total Recoverable
Prep Batch: 482914
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A500-162331-21 PNA168:MW-13M:G042519A Total Recoverable
Water 3005A500-162331-22 PNA168:S-5:G042519 Total Recoverable
Water 3005A500-162331-23 PNA168:MW-5:G042519 Total Recoverable
Water 3005A500-162331-24 PNA168:MW-21:G042519 Total Recoverable
Water 3005A500-162331-25 PNA168:MW-22:G042519 Total Recoverable
Water 3005A500-162331-26 PNA168:S-1:G042519 Total Recoverable
Water 3005A500-162331-27 PNA168:S-2:G042519 Total Recoverable
Water 3005A500-162331-28 PNA168:S-8:G042519 Total Recoverable
Water 3005A500-162331-29 PNA168:MW-20:G042519 Total Recoverable
Water 3005A500-162331-30 PNA168:S-3:G042519 Total Recoverable
Water 3005A500-162331-31 PNA168:P-25:G042519 Total Recoverable
Water 3005A500-162331-32 PNA168:P-9:G042619 Total Recoverable
Water 3005A500-162331-33 PNA168:HP-5:G042619 Total Recoverable
Water 3005A500-162331-34 PNA168:HP-7:G042619 Total Recoverable
Water 3005A500-162331-35 PNA168:MW-23:G042619 Total Recoverable
Water 3005A500-162331-36 PNA168:S-6R:G042519 Total Recoverable
Water 3005A500-162331-37 PNA168:MW-12U:G042519 Total Recoverable
Water 3005A500-162331-38 PNA168:MW-12M:G042519 Total Recoverable
Water 3005A500-162331-39 PNA168:MW-12L:G042519 Total Recoverable
Water 3005A500-162331-40 PNA168:MW-11U:G042519 Total Recoverable
Water 3005AMB 500-482914/1-A Method Blank Total Recoverable
Water 3005ALCS 500-482914/2-A Lab Control Sample Total Recoverable
Water 3005A500-162331-21 MS PNA168:MW-13M:G042519A Total Recoverable
Eurofins TestAmerica, Chicago
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QC Association SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Metals (Continued)
Prep Batch: 482914 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A500-162331-21 MSD PNA168:MW-13M:G042519A Total Recoverable
Water 3005A500-162331-21 DU PNA168:MW-13M:G042519A Total Recoverable
Prep Batch: 482915
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 3005A500-162331-41 PNA168:MW-11M:G042519 Total Recoverable
Water 3005A500-162331-42 PNA168:MW-11L:G042519 Total Recoverable
Water 3005A500-162331-43 PNA168:FB-2:G042519 Total Recoverable
Water 3005A500-162331-44 PNA168:FB-3:G042619 Total Recoverable
Water 3005AMB 500-482915/1-A Method Blank Total Recoverable
Water 3005ALCS 500-482915/2-A Lab Control Sample Total Recoverable
Analysis Batch: 483476
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020A 482914500-162331-21 PNA168:MW-13M:G042519A Total Recoverable
Water 6020A 482914500-162331-22 PNA168:S-5:G042519 Total Recoverable
Water 6020A 482914500-162331-23 PNA168:MW-5:G042519 Total Recoverable
Water 6020A 482914500-162331-24 PNA168:MW-21:G042519 Total Recoverable
Water 6020A 482915500-162331-41 PNA168:MW-11M:G042519 Total Recoverable
Water 6020A 482915500-162331-42 PNA168:MW-11L:G042519 Total Recoverable
Water 6020A 482915500-162331-43 PNA168:FB-2:G042519 Total Recoverable
Water 6020A 482915500-162331-44 PNA168:FB-3:G042619 Total Recoverable
Water 6020A 482914MB 500-482914/1-A Method Blank Total Recoverable
Water 6020A 482915MB 500-482915/1-A Method Blank Total Recoverable
Water 6020A 482914LCS 500-482914/2-A Lab Control Sample Total Recoverable
Water 6020A 482915LCS 500-482915/2-A Lab Control Sample Total Recoverable
Water 6020A 482914500-162331-21 MS PNA168:MW-13M:G042519A Total Recoverable
Water 6020A 482914500-162331-21 MSD PNA168:MW-13M:G042519A Total Recoverable
Water 6020A 482914500-162331-21 DU PNA168:MW-13M:G042519A Total Recoverable
Analysis Batch: 484297
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020A 482913500-162331-1 PNA168:P-23:G042419 Total Recoverable
Water 6020A 482913500-162331-2 PNA168:P-22:G042419 Total Recoverable
Water 6020A 482913500-162331-3 PNA168:P-5:G042419 Total Recoverable
Water 6020A 482913500-162331-4 PNA168:MW-2U:G042419 Total Recoverable
Water 6020A 482913500-162331-5 PNA168:MW-4U:G042419 Total Recoverable
Water 6020A 482913500-162331-6 PNA168:MW-16:G042419 Total Recoverable
Water 6020A 482913500-162331-7 PNA168:MW-6L:G042419 Total Recoverable
Water 6020A 482913500-162331-8 PNA168:MW-6M:G042419 Total Recoverable
Water 6020A 482913500-162331-9 PNA168:MW-6U:G042419 Total Recoverable
Water 6020A 482913500-162331-10 PNA168:MW-18L:G042419 Total Recoverable
Water 6020A 482913500-162331-11 PNA168:MW-18M:G042419 Total Recoverable
Water 6020A 482913500-162331-12 PNA168:MW-18U:G042419 Total Recoverable
Water 6020A 482913500-162331-13 PNA168:MW-15:G042419 Total Recoverable
Water 6020A 482913500-162331-14 PNA168:MW-14:G042419 Total Recoverable
Water 6020A 482913500-162331-15 PNA168:FB-1:G042419 Total Recoverable
Water 6020A 482913500-162331-16 PNA168:PZ-2:G042419 Total Recoverable
Water 6020A 482913500-162331-17 PNA168:PZ-2:G042419A Total Recoverable
Water 6020A 482913500-162331-18 PNA168:MW-13M:G042519 Total Recoverable
Water 6020A 482913500-162331-19 PNA168:MW-13L:G042519 Total Recoverable
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QC Association SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Metals (Continued)
Analysis Batch: 484297 (Continued)
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water 6020A 482913500-162331-20 PNA168:MW-13U:G042519 Total Recoverable
Water 6020A 482914500-162331-25 PNA168:MW-22:G042519 Total Recoverable
Water 6020A 482914500-162331-26 PNA168:S-1:G042519 Total Recoverable
Water 6020A 482914500-162331-27 PNA168:S-2:G042519 Total Recoverable
Water 6020A 482914500-162331-28 PNA168:S-8:G042519 Total Recoverable
Water 6020A 482914500-162331-29 PNA168:MW-20:G042519 Total Recoverable
Water 6020A 482914500-162331-30 PNA168:S-3:G042519 Total Recoverable
Water 6020A 482914500-162331-31 PNA168:P-25:G042519 Total Recoverable
Water 6020A 482914500-162331-32 PNA168:P-9:G042619 Total Recoverable
Water 6020A 482914500-162331-33 PNA168:HP-5:G042619 Total Recoverable
Water 6020A 482914500-162331-34 PNA168:HP-7:G042619 Total Recoverable
Water 6020A 482914500-162331-35 PNA168:MW-23:G042619 Total Recoverable
Water 6020A 482914500-162331-36 PNA168:S-6R:G042519 Total Recoverable
Water 6020A 482914500-162331-37 PNA168:MW-12U:G042519 Total Recoverable
Water 6020A 482914500-162331-38 PNA168:MW-12M:G042519 Total Recoverable
Water 6020A 482914500-162331-39 PNA168:MW-12L:G042519 Total Recoverable
Water 6020A 482914500-162331-40 PNA168:MW-11U:G042519 Total Recoverable
Water 6020A 482913MB 500-482913/1-A Method Blank Total Recoverable
Water 6020A 482913LCS 500-482913/2-A Lab Control Sample Total Recoverable
Water 6020A 482913500-162331-1 MS PNA168:P-23:G042419 Total Recoverable
Water 6020A 482913500-162331-1 MSD PNA168:P-23:G042419 Total Recoverable
Water 6020A 482913500-162331-1 DU PNA168:P-23:G042419 Total Recoverable
General Chemistry
Analysis Batch: 482507
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C500-162331-1 PNA168:P-23:G042419 Total/NA
Water SM 2540C500-162331-2 PNA168:P-22:G042419 Total/NA
Water SM 2540CMB 500-482507/1 Method Blank Total/NA
Water SM 2540CLCS 500-482507/2 Lab Control Sample Total/NA
Analysis Batch: 482569
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C500-162331-3 PNA168:P-5:G042419 Total/NA
Water SM 2540C500-162331-4 PNA168:MW-2U:G042419 Total/NA
Water SM 2540C500-162331-5 PNA168:MW-4U:G042419 Total/NA
Water SM 2540C500-162331-6 PNA168:MW-16:G042419 Total/NA
Water SM 2540C500-162331-7 PNA168:MW-6L:G042419 Total/NA
Water SM 2540C500-162331-8 PNA168:MW-6M:G042419 Total/NA
Water SM 2540C500-162331-9 PNA168:MW-6U:G042419 Total/NA
Water SM 2540C500-162331-10 PNA168:MW-18L:G042419 Total/NA
Water SM 2540C500-162331-11 PNA168:MW-18M:G042419 Total/NA
Water SM 2540C500-162331-12 PNA168:MW-18U:G042419 Total/NA
Water SM 2540C500-162331-13 PNA168:MW-15:G042419 Total/NA
Water SM 2540C500-162331-14 PNA168:MW-14:G042419 Total/NA
Water SM 2540C500-162331-15 PNA168:FB-1:G042419 Total/NA
Water SM 2540C500-162331-16 PNA168:PZ-2:G042419 Total/NA
Water SM 2540C500-162331-17 PNA168:PZ-2:G042419A Total/NA
Water SM 2540CMB 500-482569/1 Method Blank Total/NA
Water SM 2540CLCS 500-482569/2 Lab Control Sample Total/NA
Eurofins TestAmerica, Chicago
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QC Association SummaryJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
General Chemistry
Analysis Batch: 482758
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C500-162331-18 PNA168:MW-13M:G042519 Total/NA
Water SM 2540C500-162331-19 PNA168:MW-13L:G042519 Total/NA
Water SM 2540C500-162331-20 PNA168:MW-13U:G042519 Total/NA
Water SM 2540C500-162331-21 PNA168:MW-13M:G042519A Total/NA
Water SM 2540C500-162331-22 PNA168:S-5:G042519 Total/NA
Water SM 2540C500-162331-23 PNA168:MW-5:G042519 Total/NA
Water SM 2540C500-162331-24 PNA168:MW-21:G042519 Total/NA
Water SM 2540C500-162331-25 PNA168:MW-22:G042519 Total/NA
Water SM 2540C500-162331-26 PNA168:S-1:G042519 Total/NA
Water SM 2540C500-162331-27 PNA168:S-2:G042519 Total/NA
Water SM 2540C500-162331-28 PNA168:S-8:G042519 Total/NA
Water SM 2540C500-162331-29 PNA168:MW-20:G042519 Total/NA
Water SM 2540C500-162331-30 PNA168:S-3:G042519 Total/NA
Water SM 2540C500-162331-31 PNA168:P-25:G042519 Total/NA
Water SM 2540C500-162331-32 PNA168:P-9:G042619 Total/NA
Water SM 2540C500-162331-35 PNA168:MW-23:G042619 Total/NA
Water SM 2540C500-162331-36 PNA168:S-6R:G042519 Total/NA
Water SM 2540CMB 500-482758/1 Method Blank Total/NA
Water SM 2540CLCS 500-482758/2 Lab Control Sample Total/NA
Water SM 2540C500-162331-18 MS PNA168:MW-13M:G042519 Total/NA
Water SM 2540C500-162331-18 DU PNA168:MW-13M:G042519 Total/NA
Water SM 2540C500-162331-19 DU PNA168:MW-13L:G042519 Total/NA
Analysis Batch: 482759
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C500-162331-37 PNA168:MW-12U:G042519 Total/NA
Water SM 2540C500-162331-38 PNA168:MW-12M:G042519 Total/NA
Water SM 2540C500-162331-39 PNA168:MW-12L:G042519 Total/NA
Water SM 2540C500-162331-40 PNA168:MW-11U:G042519 Total/NA
Water SM 2540C500-162331-41 PNA168:MW-11M:G042519 Total/NA
Water SM 2540C500-162331-42 PNA168:MW-11L:G042519 Total/NA
Water SM 2540C500-162331-43 PNA168:FB-2:G042519 Total/NA
Water SM 2540C500-162331-44 PNA168:FB-3:G042619 Total/NA
Water SM 2540CMB 500-482759/1 Method Blank Total/NA
Water SM 2540CLCS 500-482759/2 Lab Control Sample Total/NA
Analysis Batch: 482988
Lab Sample ID Client Sample ID Prep Type Matrix Method Prep Batch
Water SM 2540C500-162331-33 PNA168:HP-5:G042619 Total/NA
Water SM 2540C500-162331-34 PNA168:HP-7:G042619 Total/NA
Water SM 2540CMB 500-482988/1 Method Blank Total/NA
Water SM 2540CLCS 500-482988/2 Lab Control Sample Total/NA
Eurofins TestAmerica, Chicago
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QC Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method: 6020A - Metals (ICP/MS)
Client Sample ID: Method BlankLab Sample ID: MB 500-482913/1-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913
RL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:04 05/08/19 11:54 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482913/2-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913
Arsenic 100 93.2 ug/L 93 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 MSMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913
Arsenic 1900 100 2070 4 ug/L 214 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 MSDMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913
Arsenic 1900 100 2070 4 ug/L 211 75 - 125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: PNA168:P-23:G042419Lab Sample ID: 500-162331-1 DUMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 484297 Prep Batch: 482913
Arsenic 1900 1870 ug/L 0.9 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 500-482914/1-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914
RL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:06 05/03/19 02:42 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482914/2-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914
Arsenic 100 95.9 ug/L 96 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 MSMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914
Arsenic 30 100 127 ug/L 97 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Eurofins TestAmerica, Chicago
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QC Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method: 6020A - Metals (ICP/MS)
Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 MSDMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914
Arsenic 30 100 126 ug/L 96 75 - 125 0 20
Analyte
MSD MSD
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits LimitRPD
RPD
Client Sample ID: PNA168:MW-13M:G042519ALab Sample ID: 500-162331-21 DUMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482914
Arsenic 30 29.1 ug/L 3 20
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 500-482915/1-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482915
RL MDL
Arsenic <5.0 5.0 ug/L 04/30/19 16:07 05/02/19 19:17 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482915/2-AMatrix: Water Prep Type: Total RecoverableAnalysis Batch: 483476 Prep Batch: 482915
Arsenic 100 97.5 ug/L 97 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Method: SM 2540C - Solids, Total Dissolved (TDS)
Client Sample ID: Method BlankLab Sample ID: MB 500-482507/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482507
RL MDL
Total Dissolved Solids <10 10 mg/L 04/27/19 01:32 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482507/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482507
Total Dissolved Solids 250 298 mg/L 119 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Method BlankLab Sample ID: MB 500-482569/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482569
RL MDL
Total Dissolved Solids <10 10 mg/L 04/29/19 04:56 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Eurofins TestAmerica, Chicago
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QC Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method: SM 2540C - Solids, Total Dissolved (TDS) (Continued)
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482569/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482569
Total Dissolved Solids 250 286 mg/L 114 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: Method BlankLab Sample ID: MB 500-482758/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482758
RL MDL
Total Dissolved Solids <10 10 mg/L 04/30/19 02:10 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482758/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482758
Total Dissolved Solids 250 298 mg/L 119 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Client Sample ID: PNA168:MW-13M:G042519Lab Sample ID: 500-162331-18 MSMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758
Total Dissolved Solids 540 250 824 mg/L 112 75 - 125
Analyte
MS MS
DUnitResult Qualifier %Rec
Spike
Added
Sample
Result
Sample
Qualifier
%Rec.
Limits
Client Sample ID: PNA168:MW-13M:G042519Lab Sample ID: 500-162331-18 DUMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758
Total Dissolved Solids 540 546 mg/L 0.4 5
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Client Sample ID: PNA168:MW-13L:G042519Lab Sample ID: 500-162331-19 DUMatrix: Water Prep Type: Total/NAAnalysis Batch: 482758
Total Dissolved Solids 610 618 mg/L 2 5
Analyte
DU DU
DUnitResult Qualifier
Sample
Result
Sample
Qualifier LimitRPD
RPD
Client Sample ID: Method BlankLab Sample ID: MB 500-482759/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482759
RL MDL
Total Dissolved Solids <10 10 mg/L 04/30/19 03:47 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482759/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482759
Total Dissolved Solids 250 262 mg/L 105 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Eurofins TestAmerica, Chicago
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QC Sample ResultsJob ID: 500-162331-1Client: Hull & Associates, Inc.
Project/Site: PNA Pilkington - Ottawa
Method: SM 2540C - Solids, Total Dissolved (TDS)
Client Sample ID: Method BlankLab Sample ID: MB 500-482988/1Matrix: Water Prep Type: Total/NAAnalysis Batch: 482988
RL MDL
Total Dissolved Solids <10 10 mg/L 05/01/19 03:27 1
MB MB
Analyte Dil FacAnalyzedPreparedDUnitResult Qualifier
Client Sample ID: Lab Control SampleLab Sample ID: LCS 500-482988/2Matrix: Water Prep Type: Total/NAAnalysis Batch: 482988
Total Dissolved Solids 250 286 mg/L 114 80 - 120
Analyte
LCS LCS
DUnitResult Qualifier %Rec
Spike
Added
%Rec.
Limits
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:P-23:G042419 Lab Sample ID: 500-162331-1Matrix: WaterDate Collected: 04/24/19 08:28
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 11:58 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482507 04/27/19 02:28 CLB TAL CHITotal/NA
Client Sample ID: PNA168:P-22:G042419 Lab Sample ID: 500-162331-2Matrix: WaterDate Collected: 04/24/19 08:56
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:06 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482507 04/27/19 02:31 CLB TAL CHITotal/NA
Client Sample ID: PNA168:P-5:G042419 Lab Sample ID: 500-162331-3Matrix: WaterDate Collected: 04/24/19 09:25
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:08 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:19 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-2U:G042419 Lab Sample ID: 500-162331-4Matrix: WaterDate Collected: 04/24/19 10:02
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:10 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:21 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-4U:G042419 Lab Sample ID: 500-162331-5Matrix: WaterDate Collected: 04/24/19 10:34
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:20 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:24 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-16:G042419 Lab Sample ID: 500-162331-6Matrix: WaterDate Collected: 04/24/19 11:15
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:22 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:27 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-6L:G042419 Lab Sample ID: 500-162331-7Matrix: WaterDate Collected: 04/24/19 11:54
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:24 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:29 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-6M:G042419 Lab Sample ID: 500-162331-8Matrix: WaterDate Collected: 04/24/19 12:20
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:26 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:32 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-6U:G042419 Lab Sample ID: 500-162331-9Matrix: WaterDate Collected: 04/24/19 12:51
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:27 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:34 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-18L:G042419 Lab Sample ID: 500-162331-10Matrix: WaterDate Collected: 04/24/19 13:29
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:29 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:37 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-18M:G042419 Lab Sample ID: 500-162331-11Matrix: WaterDate Collected: 04/24/19 13:58
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:31 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:39 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-18U:G042419 Lab Sample ID: 500-162331-12Matrix: WaterDate Collected: 04/24/19 14:27
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:36 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:42 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-15:G042419 Lab Sample ID: 500-162331-13Matrix: WaterDate Collected: 04/24/19 15:01
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:38 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:45 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-14:G042419 Lab Sample ID: 500-162331-14Matrix: WaterDate Collected: 04/24/19 15:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:39 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:47 CLB TAL CHITotal/NA
Client Sample ID: PNA168:FB-1:G042419 Lab Sample ID: 500-162331-15Matrix: WaterDate Collected: 04/24/19 12:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:41 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:50 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:PZ-2:G042419 Lab Sample ID: 500-162331-16Matrix: WaterDate Collected: 04/24/19 16:15
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:43 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:52 CLB TAL CHITotal/NA
Client Sample ID: PNA168:PZ-2:G042419A Lab Sample ID: 500-162331-17Matrix: WaterDate Collected: 04/24/19 16:15
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:45 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482569 04/29/19 05:55 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-13M:G042519 Lab Sample ID: 500-162331-18Matrix: WaterDate Collected: 04/25/19 05:44
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:46 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:15 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-13L:G042519 Lab Sample ID: 500-162331-19Matrix: WaterDate Collected: 04/25/19 06:12
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:48 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:22 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-13U:G042519 Lab Sample ID: 500-162331-20Matrix: WaterDate Collected: 04/25/19 06:37
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:04 BDE482913 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:50 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:28 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-13M:G042519A Lab Sample ID: 500-162331-21Matrix: WaterDate Collected: 04/25/19 05:44
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/03/19 02:49 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:30 CLB TAL CHITotal/NA
Client Sample ID: PNA168:S-5:G042519 Lab Sample ID: 500-162331-22Matrix: WaterDate Collected: 04/25/19 07:10
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/03/19 03:08 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:33 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-5:G042519 Lab Sample ID: 500-162331-23Matrix: WaterDate Collected: 04/25/19 11:00
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/03/19 03:12 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:35 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-21:G042519 Lab Sample ID: 500-162331-24Matrix: WaterDate Collected: 04/25/19 12:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/03/19 03:16 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:38 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-22:G042519 Lab Sample ID: 500-162331-25Matrix: WaterDate Collected: 04/25/19 13:19
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 12:57 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:41 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:S-1:G042519 Lab Sample ID: 500-162331-26Matrix: WaterDate Collected: 04/25/19 13:48
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:06 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:43 CLB TAL CHITotal/NA
Client Sample ID: PNA168:S-2:G042519 Lab Sample ID: 500-162331-27Matrix: WaterDate Collected: 04/25/19 14:23
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:08 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:46 CLB TAL CHITotal/NA
Client Sample ID: PNA168:S-8:G042519 Lab Sample ID: 500-162331-28Matrix: WaterDate Collected: 04/25/19 14:49
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:10 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:48 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-20:G042519 Lab Sample ID: 500-162331-29Matrix: WaterDate Collected: 04/25/19 15:24
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:11 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:51 CLB TAL CHITotal/NA
Client Sample ID: PNA168:S-3:G042519 Lab Sample ID: 500-162331-30Matrix: WaterDate Collected: 04/25/19 15:55
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:13 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:53 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:P-25:G042519 Lab Sample ID: 500-162331-31Matrix: WaterDate Collected: 04/25/19 16:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:18 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:56 CLB TAL CHITotal/NA
Client Sample ID: PNA168:P-9:G042619 Lab Sample ID: 500-162331-32Matrix: WaterDate Collected: 04/26/19 06:13
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:20 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 02:59 CLB TAL CHITotal/NA
Client Sample ID: PNA168:HP-5:G042619 Lab Sample ID: 500-162331-33Matrix: WaterDate Collected: 04/26/19 06:50
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 20 484297 05/08/19 13:22 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482988 05/01/19 03:55 CLB TAL CHITotal/NA
Client Sample ID: PNA168:HP-7:G042619 Lab Sample ID: 500-162331-34Matrix: WaterDate Collected: 04/26/19 07:22
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 20 484297 05/08/19 13:24 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482988 05/01/19 03:57 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-23:G042619 Lab Sample ID: 500-162331-35Matrix: WaterDate Collected: 04/26/19 08:11
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:25 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 03:06 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:S-6R:G042519 Lab Sample ID: 500-162331-36Matrix: WaterDate Collected: 04/25/19 08:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:27 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482758 04/30/19 03:09 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-12U:G042519 Lab Sample ID: 500-162331-37Matrix: WaterDate Collected: 04/25/19 10:28
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:29 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 03:52 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-12M:G042519 Lab Sample ID: 500-162331-38Matrix: WaterDate Collected: 04/25/19 11:31
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:31 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 03:55 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-12L:G042519 Lab Sample ID: 500-162331-39Matrix: WaterDate Collected: 04/25/19 13:35
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:32 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 03:58 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-11U:G042519 Lab Sample ID: 500-162331-40Matrix: WaterDate Collected: 04/25/19 15:46
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:06 BDE482914 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 484297 05/08/19 13:34 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 04:01 CLB TAL CHITotal/NA
Eurofins TestAmerica, Chicago
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Lab ChronicleClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Client Sample ID: PNA168:MW-11M:G042519 Lab Sample ID: 500-162331-41Matrix: WaterDate Collected: 04/25/19 16:50
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/02/19 19:25 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 04:04 CLB TAL CHITotal/NA
Client Sample ID: PNA168:MW-11L:G042519 Lab Sample ID: 500-162331-42Matrix: WaterDate Collected: 04/25/19 17:46
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/02/19 19:29 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 04:07 CLB TAL CHITotal/NA
Client Sample ID: PNA168:FB-2:G042519 Lab Sample ID: 500-162331-43Matrix: WaterDate Collected: 04/25/19 17:40
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/02/19 19:32 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 04:10 CLB TAL CHITotal/NA
Client Sample ID: PNA168:FB-3:G042619 Lab Sample ID: 500-162331-44Matrix: WaterDate Collected: 04/26/19 07:10
Date Received: 04/26/19 11:55
Prep 3005A 04/30/19 16:07 BDE482915 TAL CHI
Type
Batch Batch
MethodPrep Type LabAnalystRun
Prepared
or Analyzed
Batch
Number
Dilution
Factor
Total Recoverable
Analysis 6020A 1 483476 05/02/19 19:36 FXG TAL CHITotal Recoverable
Analysis SM 2540C 1 482759 04/30/19 04:13 CLB TAL CHITotal/NA
Laboratory References:
TAL CHI = Eurofins TestAmerica, Chicago, 2417 Bond Street, University Park, IL 60484, TEL (708)534-5200
Eurofins TestAmerica, Chicago
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Accreditation/Certification SummaryClient: Hull & Associates, Inc. Job ID: 500-162331-1Project/Site: PNA Pilkington - Ottawa
Laboratory: Eurofins TestAmerica, ChicagoAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
California 29039State Program 04-30-19 *
Georgia State Program 4 N/A 04-30-19 *
Georgia State Program 4 939 04-30-19 *
Hawaii State Program 9 N/A 04-30-19 *
Illinois NELAP 5 100201 05-30-19 *
Indiana State Program 5 C-IL-02 05-30-19 *
Iowa State Program 7 82 05-01-20
Kansas NELAP 7 E-10161 10-31-19
Kentucky (UST) State Program 4 66 05-30-19 *
Kentucky (WW) State Program 4 KY90023 12-31-19
Louisiana NELAP 6 30720 06-30-19 *
Mississippi State Program 4 N/A 04-30-19 *
New York NELAP 2 12019 04-01-20
North Carolina (WW/SW) State Program 4 291 12-31-19
North Dakota State Program 8 R-194 05-30-19 *
Oklahoma State Program 6 8908 08-31-19 *
South Carolina State Program 4 77001 05-30-19 *
Wisconsin State Program 5 999580010 08-31-19 *
Wyoming State Program 8 8TMS-Q 04-30-19 *
Laboratory: Eurofins TestAmerica, CantonAll accreditations/certifications held by this laboratory are listed. Not all accreditations/certifications are applicable to this report.
Authority Program EPA Region Identification Number Expiration Date
California 29279State Program 02-23-20
Connecticut State Program 1 PH-0590 12-31-19
Florida NELAP 4 E87225 06-30-19
Illinois NELAP 5 200004 07-31-19
Kansas NELAP 7 E-10336 04-30-19 *
Kentucky (UST) State Program 4 58 02-23-20
Kentucky (WW) State Program 4 98016 12-31-19
Minnesota NELAP 5 039-999-348 12-31-19 *
Minnesota (Petrofund) State Program 1 3506 07-31-19
Nevada State Program 9 OH00048 07-31-19
New Jersey NELAP 2 OH001 06-30-19
New York NELAP 2 10975 03-31-20
Ohio VAP State Program 5 CL0024 09-06-19
Oregon NELAP 10 4062 02-23-20
Pennsylvania NELAP 3 68-00340 08-31-19 *
Texas NELAP 6 T104704517-18-10 08-31-19
USDA Federal P330-16-00404 12-28-19
Virginia NELAP 3 460175 09-14-19
Washington State Program 10 C971 01-12-20 *
West Virginia DEP State Program 3 210 12-31-19
Eurofins TestAmerica, Chicago
* Accreditation/Certification renewal pending - accreditation/certification considered valid.
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Page 75 of 79 5/9/2019
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Page 76 of 79 5/9/2019
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Page 77 of 79 5/9/2019
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Page 78 of 79 5/9/2019
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Login Sample Receipt Checklist
Client: Hull & Associates, Inc. Job Number: 500-162331-1
Login Number: 162331
Question Answer Comment
Creator: Scott, Sherri L
List Source: Eurofins TestAmerica, Chicago
List Number: 1
TrueRadioactivity wasn't checked or is </= background as measured by a survey meter.
TrueThe cooler's custody seal, if present, is intact.
TrueSample custody seals, if present, are intact.
TrueThe cooler or samples do not appear to have been compromised or tampered with.
TrueSamples were received on ice.
TrueCooler Temperature is acceptable.
TrueCooler Temperature is recorded. 2.3,3.6,3.6
TrueCOC is present.
TrueCOC is filled out in ink and legible.
TrueCOC is filled out with all pertinent information.
TrueIs the Field Sampler's name present on COC?
FalseThere are no discrepancies between the containers received and the COC.
TrueSamples are received within Holding Time (excluding tests with immediate HTs)
TrueSample containers have legible labels.
TrueContainers are not broken or leaking.
TrueSample collection date/times are provided.
TrueAppropriate sample containers are used.
TrueSample bottles are completely filled.
TrueSample Preservation Verified.
TrueThere is sufficient vol. for all requested analyses, incl. any requested MS/MSDs
N/AContainers requiring zero headspace have no headspace or bubble is <6mm (1/4").
TrueMultiphasic samples are not present.
TrueSamples do not require splitting or compositing.
N/AResidual Chlorine Checked.
Eurofins TestAmerica, ChicagoPage 79 of 79 5/9/2019
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