material safety data sheet - grinnell collegematerial safety data sheet according to ansi z400.1-...

Material Safety Data Sheet according to ANSI Z400.1- 2004 and 29 CFR 1910.1200

WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D® Version 1.1 Print Date 01/01/2013

Revision Date 12/05/2012 MSDS Number 350000014153

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1. PRODUCT AND COMPANY IDENTIFICATION

Product information

Trade name : WINDEX® ORIGINAL GLASS CLEANER WITH AMMONIA-D®

Use of the Substance/Mixture

: Hard Surface Cleaner

Company : S.C. Johnson & Son, Inc. 1525 Howe Street Racine WI 53403-2236

Emergency telephone number

: 24 Hour Medical Emergency Phone: (866)231-5406 24 Hour International Emergency Phone: (703)527-3887 24 Hour Transport Emergency Phone: (800)424-9300

2. HAZARDS IDENTIFICATION

Emergency Overview Appearance / Odor : blue / liquid / pleasant

Immediate Concerns

: Avoid contact with skin, eyes and clothing.

Potential Health Effects Exposure routes : Eye, Skin, Inhalation, Ingestion.

Eyes : May cause:

Mild eye irritation

Skin : Prolonged or repeated contact may dry skin and cause irritation.

Inhalation : No adverse effects expected when used as directed.

Ingestion : May cause irritation to mouth, throat and stomach. May cause abdominal discomfort.

Aggravated Medical Condition

: Persons with pre-existing skin disorders may be more susceptible to irritating effects.

3. COMPOSITION/INFORMATION ON INGREDIENTS

This product does not contain hazardous chemicals at or above a reportable level as defined by OSHA 29 CFR 1910.1200 or Canadian Controlled Products Regulations. For additional information on product ingredients, see www.whatsinsidescjohnson.com.




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4. FIRST AID MEASURES

Eye contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Skin contact : Rinse with plenty of water. Get medical attention if irritation develops and persists.

Inhalation : No special requirements

Ingestion : Rinse mouth with water.

5. FIREFIGHTING MEASURES

Suitable extinguishing media

: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Specific hazards during firefighting

: Container may melt and leak in heat of fire.

Further information : Although this product has a flash point below 200 Deg F, it is

an aqueous solution containing an alcohol and does not sustain combustion. Fight fire with normal precautions from a reasonable distance. Standard procedure for chemical fires. Wear full protective clothing and positive pressure self-contained breathing apparatus. In case of fire and/or explosion do not breathe fumes.

Flash point : 85 °C

185 °F Method: ASTM D 56

Lower explosion limit : Note: no data available

Upper explosion limit : Note: no data available

6. ACCIDENTAL RELEASE MEASURES

Personal precautions : No special precautions required.

Environmental precautions : Outside of normal use, avoid release to the environment.

Methods for cleaning up : Soak up with inert absorbent material. Sweep up and shovel into suitable containers for disposal. Dike large spills. Clean residue from spill site.




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7. HANDLING AND STORAGE

Handling

Advice on safe handling : Use only as directed. KEEP OUT OF REACH OF CHILDREN AND PETS.

Advice on protection against fire and explosion

: Normal measures for preventive fire protection.

Storage

Requirements for storage areas and containers

: Keep container closed when not in use. Keep in a dry, cool and well-ventilated place.

Other data : Stable under normal conditions.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Occupational Exposure Limits

ACGIH or OSHA exposure limits have not been established for this product or reportable ingredients unless noted in the table above.

Personal protective equipment

Respiratory protection

No personal respiratory protective equipment normally required.

Hand protection

: No special requirements.

Eye protection

No special requirements.

Skin and body protection

: No special requirements.

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly after handling.

9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid

Color : blue

Odor : pleasant

pH : 10.7




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Boiling point : no data available

Freezing point : no data available

Flash point : 85 °C

185 °F Method: ASTM D 56

Evaporation rate : no data available

Flammability (solid, gas) : Does not sustain combustion.

Auto-ignition temperature : no data available

Lower explosion limit : no data available

Upper explosion limit : no data available

Vapour pressure : no data available

Density : 0.997 g/cm3 at 20 °C

Water solubility : soluble

Viscosity, dynamic : no data available

Viscosity, kinematic : no data available

Volatile Organic Compounds Total VOC (wt. %)*

: 0.5 % - additional exemptions may apply *as defined by US Federal and State Consumer Product Regulations

10. STABILITY AND REACTIVITY

Conditions to avoid : Direct sources of heat.

Materials to avoid : Strong oxidizing agents

Hazardous decomposition products

: Thermal decomposition can lead to release of irritating gases and vapours.

Hazardous reactions : Stable under recommended storage conditions.

11. TOXICOLOGICAL INFORMATION

Acute oral toxicity : LD50 estimated




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> 5,000 mg/kg

Acute inhalation toxicity : LC50

estimated > 2.58 mg/l

Acute dermal toxicity : LD50

estimated > 5,000 mg/kg

Chronic effects Carcinogenicity : no data available

Mutagenicity : no data available

Reproductive effects : no data available

Teratogenicity : no data available

Sensitisation : Not known to be a sensitizer.

12. ECOLOGICAL INFORMATION

Ecotoxicity effects : no data available

13. DISPOSAL CONSIDERATIONS

Observe all applicable Federal, Provincial and State regulations and Local/Municipal ordinances regarding disposal. Consumer may discard empty container in trash, or recycle where facilities exist.

14. TRANSPORT INFORMATION

Land transport

U.S. DOT and Canadian TDG Surface Transportation:




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Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Sea transport

IMDG: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None. Air transport

ICAO/IATA: Proper shipping name not regulated Class: None. UN/ID No.: None. Packaging group None.

15. REGULATORY INFORMATION

Notification status : All ingredients of this product are listed or are excluded from listing on the U.S. Toxic Substances Control Act (TSCA) Chemical Substance Inventory.

Notification status : All ingredients of this product comply with the New Substances Notification requirements under the Canadian Environmental Protection Act (CEPA).

California Prop. 65 : This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm.

Canada Regulations : This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the MSDS contains all the information required by the Controlled Products Regulations.

16. OTHER INFORMATION

HMIS Ratings Health 1

Flammability 2

Reactivity 0

NFPA Ratings




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Health 1

Fire 2

Reactivity 0

Special -

Further information This document has been prepared using data from sources considered to be technically reliable. It does not constitute a warranty, expressed or implied, as to the accuracy of the information contained herein. Actual conditions of use are beyond the seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

Prepared by: SC Johnson Global Safety Assessment & Regulatory Affairs (GSARA)

MATERIAL SAFETY DATA SHEET FILE NO.: N/A NAME OF PRODUCT Scott’s Liquid Gold Wood Cleaner & Preservative (Aerosol) MSDS DATE: 03/29/2013

PAGE 1 OF 4

HMIS Rating: Health (1) Flammability (3) Reactivity (0) HMIS Scale: 4=Very High 3=High 2=Moderate 1=Slight 0=Insignificant SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Scott’s Liquid Gold Wood Cleaner & Preservative (Aerosol) PRODUCT CODES: MANUFACTURER: Scott’s Liquid Gold ADDRESS: 4880 Havana St.

Denver, Co. 80239 EMERGENCY PHONE: 303-373-4860 or consult local poison control center immediately PRODUCT USE: Industrial/Institutional: Wood Care SECTION 2: COMPOSITION/INFORMATION ON INGREDIENTS INGREDIENT: CAS # % WT Exposure Limits: OSHA(PEL) ACGIH (TLV) Hydrotreated Petroleum 64742-56-9 60-90 5mg/m3 Distillates Process oil VM&P Naphtha 64742-89-8 5-10 300 ppm Carbon Dioxide 124-38-9 5-15 10,000 ppm SECTION 3: HAZARDS IDENTIFICATION EMERGENCY OVERVIEW: Contents under pressure. Do not puncture or incinerate container. Do not expose to heat or store at temperatures above 1200F Use in a well-ventilated area. Keep out of Reach of Children ROUTES OF ENTRY: Eye contact. Skin contact. Ingestion. Inhalation. POTENTIAL ACUTE HEALTH EFFECTS MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE: EYES: Stinging or redness SKIN: Redness or irritation INGESTION: Digestive discomfort INHALATION: Prolong exposure may cause nausea, dizziness, and headache. Massive overexposure may cause unconsciousness, death CHRONIC HEALTH HAZARDS: None CARCINOGENICITY OSHA: ( ) ACGIH: ( ) NTP: ( ) IARC: ( ) None: (x) SECTION 4: FIRST AID MEASURES EYES: Flush with water for 15 minutes. SKIN: Rinse thoroughly with soap and warm water. INGESTION: Do not induce vomiting as aspiration pneumonitis may result. INHALATION: Remove to fresh air.


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SECTION 5: FIRE-FIGHTING MEASURES FLAMMABILITY OF THE PRODUCT: Level 3 Aerosol FLASH POINT: 112oF (44oC) METHOD USED: Closed Cup (Liquid) NFPA HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 HMIS HAZARD CLASSIFICATION HEALTH: 1 FLAMMABILITY: 3 REACTIVITY: 0 EXTINGUISHING MEDIA: Water Spray, foam, Carbon Dioxide, Dry Chemical SPECIAL FIRE FIGHTING PROCEDURES: Use self-contained breathing apparatus, avoid breathing fumes. Cool containers in water fog. UNUSUAL FIRE AND EXPLOSION HAZARDS: Vapors may be heavier than air, may travel and flash back. Containers may burst at temperatures above 130oF. Aerosol product – Containers may rocket or explode in heat or fire. HAZARDOUS DECOMPOSITION PRODUCTS: Combustion will release Carbon Monoxide and /or Carbon Dioxide, and other unidentified organic compounds. SECTION 6: ACCIDENTAL RELEASE MEASURES ACCIDENTAL RELEASE MEASURES: Eliminate sources of ignition, avoid breathing vapors, minimize skin contact. In the event of spillage: Use appropriate containment to avoid environmental contamination. Recover liquid with absorbent material. Ventilate spill area. Place in suitable clean, dry containers for disposal by approved methods. SECTION 7: HANDLING AND STORAGE HANDLING AND STORAGE: Avoid unnecessary contact with fumes or liquid. Do not store near heat, sparks, open flames or strong oxidizers. OTHER PRECAUTIONS: Do not puncture or incinerate. Pressurized containers, do not pierce or burn, even after use. SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION VENTILATION : Adequate to minimize vapor RESPIRATORY PROTECTION: Use breathing apparatus in enclosed areas. EYE PROTECTION: None required under normal use conditions. When handling in large quantities or responding to emergency situations, the use of appropriate eye protection is recommended. SKIN PROTECTION: Protective gloves during prolong contact. OTHER PROTECTIVE CLOTHING OR EQUIPMENT: None required under normal use conditions. WORK HYGIENIC PRACTICES: Washing with soap and water after use is recommended as good hygienic practice to prevent possible skin irritation and /or eye irritation from hand contact.


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SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES PHYSICAL STATE & APPEARANCE: Liquid (Aerosol) ODOR: Almond or Lemon pH : not available BOILING POINT: F: 170oF C: 76oC VAPOR PRESSURE (mmHg): not available VAPOR DENSITY (AIR = 1): not available SPECIFIC GRAVITY (H2O = 1): 0.844 EVAPORATION RATE: not available SOLUBILITY IN WATER: None PERCENT VOLATILE: not available SECTION 10: STABILITY AND REACTIVITY

STABILITY: This product is stable CONDITIONS OF INSTABILITY: Do not expose to heat or store at temperatures above 130oF INCOMPATIBILITY (MATERIAL TO AVOID): Strong oxidizers, acids, and alkalies. HAZARDOUS DECOMPOSITION OR BY-PRODUCTS: Combustion will release Carbon Monoxide and /or Carbon Dioxide, and other unidentified organic compounds. HAZARDOUS POLYMERIZATION: Will not occur CONDITIONS TO AVOID (POLYMERIZATION): Heat, open flames, and Aluminum SECTION 11: TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION: EYES: Stinging or redness SKIN: Redness or irritation INGESTION: Digestive discomfort INHALATION: Prolong exposure may cause nausea, dizziness, and headache. Massive overexposure may cause unconsciousness, death CHRONIC HEALTH HAZARDS: None SECTION 12: ECOLOGICAL INFORMATION Not available SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL: Do not puncture or incinerate container. If possible, recycle empty cans to the nearest steel recycling center. Dispose of according to all federal, state and local regulations.


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SECTION 14: TRANSPORT INFORMATION US DOT GROUND PROPER SHIPPING NAME: Consumer Commodity HAZARD CLASS: Limited Quantity ID NUMBER: Not applicable PACKING GROUP: Not applicable IATA AIR TRANSPORTATION ID NUMBER: UN1950 PROPER SHIPPING NAME: Aerosols, Flammable Limited Quantity HAZARD CLASS: 2.1 PACKING GROUP: Not applicable IMDG WATER TRANSPORTATION ID NUMBER: UN1950 PROPER SHIPPING NAME: Aerosols, Flammable Limited Quantity HAZARD CLASS: 2.1 PACKING GROUP: Not applicable MARINE POLUTANT: Not applicable SECTION 15: REGULATORY INFORMATION FEDERAL and STATE SARA title III, Section 313 Toxic chemical Notification & Release Reporting: REGULATIONS

None

California Proposition 65: This product contains the following ingredients which require a warning under the Safe Drinking Water & Toxic Enforcement Act.

None

SECTION 16: OTHER INFORMATION OTHER INFORMATION: Not applicable Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller’s control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations.

MATERIAL SAFETY DATA SHEET

Section 1 -- PRODUCT AND COMPANY IDENTIFICATION DATE OF PREPARATION HMIS CODES

PRODUCT NUMBER Health 0 7500 1 October 11 Flammability 0 Reactivity 0 PRODUCT NAME Sculpt or Coat Water Reducible Coating MANUFACTURER’S NAME Sculptural Arts Coating, Inc. 1200 Forest Hill Drive Greensboro, NC 27410 EMERGENCY TELEPHONE NUMBER (336) 851-0355 INFORMATION TELEPHONE NUMBER (336) 851-0355 Section 2 -- COMPOSITION/INFORMATION ON INGREDIENTS % by WT CAS No. INGREDIENT UNITS VAPOR PRESSURE No information is required here. Section 3 - - HAZARDS IDENTIFICATION ROUTES OF EXPOSURE INHALATION of vapor or spray mist. EYE or SKIN contact with the product, vapor or spray mist. EFFECTS OF OVEREXPOSURE EYES: Irritation. SKIN: Prolonged or repeated exposure may cause irritation. INHALATION: Irritation of the upper respiratory system. In a confined area vapors in high concentration may cause headache, Nausea or dizziness. continued on page 2

7500 page 2 SIGNS AND SYMPTOMS OF OVEREXPOSURE Redness and itching or burning sensation may indicate eye or excessive skin exposure. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None generally recognized. Section 4 - - FIRST AID MEASURES EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention. SKIN: Wash affected area thoroughly with soap and water. Remove contaminated clothing and launder before re-use. INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet. INGESTION: Do not induce vomiting. Get medical attention immediately. Section 5 - - FIRE FIGHTING MEASURES FLASH POINT LEL UEL Not applicable N.A. N.A. FLAMMABILITY CLASSIFICATION Not applicable EXTINGUISHING MEDIA Carbon Dioxide, Dry Chemical, Alcohol Foam UNUSUAL FIRE AND EXPLOSION HAZARDS Closed containers may explode (due to the build up of pressure) when exposed to extreme heat. During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately apparent. Obtain medical attention. SPECIAL FIREFIGHTING PROCEDURES Full protective equipment including self-contained breathing apparatus should be used. Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure build-up and possible autoignition or explosion when exposed to extreme heat. Section 6 - - ACCIDENTAL RELEASE MEASURES STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED Remove all sources of ignition. Ventilate the area. Remove with inert absorbent. continued on page 3

7500 page 3 Section 7 - - HANDLING AND STORAGE STORAGE CATEGORY Not applicable PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally. Keep out of the reach of children. Section 8 - - EXPOSURE CONTROLS/ PERSONAL PROTECTION PRECAUTIONS TO BE TAKEN IN USE Use only with adequate ventilation. Avoid contact with skin and eyes. Avoid breathing vapor and spray mist. Wash hands after using. This coating may contain materials classified as nuisance particulates (listed “as Dust” in Section 2) which may be present at hazardous levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction). Removal of old paint by sanding, scraping or other means may generate dust or fumes that contain lead. Exposure to lead dust or fumes may cause brain damage or other adverse health effects, especially in children or pregnant women. Controlling exposure to lead or other hazardous substances requires the use of proper protective equipment, such as a properly fitted respirator (NIOSH approved) and proper containment and cleanup. For more information, call the National Lead Information Center at 1-800-424-LEAD (in US) or contact your local health authority. VENTILATION Local exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108. RESPIRATORY PROTECTION If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2. When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint or the abrasive. PROTECTIVE GLOVES Wear gloves which are recommended by glove supplier for protection against materials in Section 2. continued on page 4

7500 page 4 EYE PROTECTION Wear safety spectacles with unperforated sideshields. Section 9 - - PHYSICAL AND CHEMICAL PROPERTIES PRODUCT WEIGHT 8.8 - 9.0 lb. / gal. BOILING POINT 212 - 213 F VOLATILE VOLUME 54% EVAPORATION RATE Slower than ether VAPOR DENSITY Heavier than air VOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged) <- 23 g/ l Less Water and Federally Exempt Solvents Section 10 - - STABILITY AND REACTIVITY STABILITY - - Stable CONDITIONS TO AVOID None known. INCOMPATIBILITY None known. HAZARDOUS DECOMPOSITION PRODUCTS By fire: Carbon Dioxide, Carbon Monoxide HAZARDOUS POLYMERIZATION Will not occur. Section 11 - - TOXICOLOGICAL INFORMATION No ingredient in this product is an IARC, NTP, or OSHA listed carcinogen. TOXICOLOGY DATA CAS No. Ingredient Name No data given. continued on page 5

7500 page 5 Section 12 - - ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION No data available. Section 13 - - DISPOSAL CONSIDERATIONS WASTE DISPOSAL METHOD Waste from this product is not hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261. Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/ Provincial, and Local regulations regarding pollution. Section 14 - - TRANSPORT INFORMATION US Ground (DOT) Not Regulated for Transportation. Canada (TDG) Not Regulated for Transportation . Section 15 - - REGULATORY INFORMATION SARA 313 (40 CFR 372.65 C) SUPPLIER NOTIFICATION CAS No. CHEMICAL / COMPOUND % by WT % Element No ingredients in this product are subject to SARA 313 (40 CFR 372.65 C) Supplier Notification. TSCA CERTIFICATION All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory. Section 16 - - OTHER INFORMATION This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. The information contained herein is based on data available to us. However, no warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from the use thereof. Since the use of this information and the conditions of the use of the product are not under our control, it is the user’s obligation to determine conditions of safe use of this product and we assume no liability in connection with the use of this information.

MATERIAL SAFETY DATA SHEET SHEETROCK® Lightweight Setting-Type Joint Compounds Easy Sand™20

MSDS #61-205-001 Page 1 of 9

61205001

SECTION 1 CHEMICAL PRODUCT AND IDENTIFICATION

United States Gypsum Company

550 West Adams Street

Chicago, Illinois 60661-3637

A Subsidiary of USG Corporation

Product Safety: 1 (800) 507-8899

www.usg.com

Version Date: January 1, 2011

Version: 7

PRODUCT(S) SHEETROCK® Lightweight Setting-Type Joint Compounds Easy Sand™20

CHEMICAL FAMILY / GENERAL CATEGORY Joint Treatment

SYNONYMS Joint Compound, Taping Compound, Mud

SECTION 2 HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: ΔWARNING! This product is not expected to produce any unusual hazards during normal use. Exposure to high dust levels may irritate the skin, eyes, nose, throat, or upper respiratory tract. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis).

POTENTIAL HEALTH EFFECTS (See Section 11 for more information)

ACUTE :

Inhalation

Exposure to dust generated during the handling or sanding of the product may cause temporary irritation to eyes, skin, nose, throat, and upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive inhalation. If respiratory symptoms persist, consult physician.

Eyes Dust can cause temporary mechanical irritation of eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult physician.

Skin None known.

Ingestion None known.

CHRONIC:

Inhalation

Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.

Eyes None known.

Skin None known.


http://www.usg.com/


MSDS #61-205-001 Page 2 of 9

TARGET ORGANS: Eyes, skin and respiratory system.

PRIMARY ROUTES OF ENTRY: Inhalation, eyes and skin contact.

CARCINOGENICITY CLASSIFICATION OF INGREDIENT(S) All substances listed are associated with the nature of the raw materials used in the manufacture of this product and are not independent components of the product formulation. All substances, if present, are at levels well below regulatory limits. See Section 11: Toxicology Information for detailed information. MATERIAL IARC NTP ACGIH CAL- 65

Crystalline silica 1 1 A2 Listed

IARC - International Agency for Research on Cancer: 1- Carcinogenic to humans; 2A – Probably carcinogenic to humans; 2B – Possibly carcinogenic to humans; 3 - Not classifiable as a carcinogen; 4 – Probably not a carcinogen

NTP – National Toxicology Program (Health and Human Services Dept., Public Health Service, NIH/NIEHS): 1- Known to be carcinogen; 2- Anticipated to be carcinogens

ACGIH – American Conference of Governmental Industrial Hygienists: A1 – Confirmed human carcinogen; A2 – Suspected human carcinogen; A3 – Animal carcinogen; A4 - Not classifiable as a carcinogen; A5 – Not suspected as a human carcinogen

CAL-65 – California Proposition 65 “Chemicals known to the State of California to Cause Cancer”

Respirable crystalline silica: IARC: Group 1 carcinogen, NTP: Known human carcinogen. The weight percent of crystalline silica given represents total quartz and not the respirable fraction. The weight percent of respirable silica has not been measured in this product.

Food and Drug Administration [CFR Title 21, v.3, sec 184.1409] – Ground limestone is Generally Recognized as Safe (GRAS). POTENTIAL ENVIRONMENTAL EFFECTS: Toxicity studies performed with fish, aquatic invertebrates and aquatic plants showed no toxic effect. (See Section 12 for more information.)

SECTION 3 COMPOSITION, INFORMATION ON INGREDIENTS

MATERIAL WT% CAS #

Plaster of Paris (CaSO4•½H2O) 60-70

Limestone <10

Or Dolomite

Expanded Perlite <10

Mica <10

Vinyl Alcohol Polymer <5

Attapulgite <5

Crystalline Silica <5

26499-65-0

1317-65-3

16389-88-1

93763-70-3

12001-26-2

9002-89-5

12174-11-7

14808-60-7^

All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory and the Canadian Domestic Substances List (DSL).

^The weight percent for silica represents total quartz and not the respirable fraction.

SECTION 4 FIRST AID MEASURES

FIRST AID PROCEDURES

Inhalation Remove to fresh air. Leave the area of exposure and remain away until coughing and other symptoms


MSDS #61-205-001 Page 3 of 9

subside. Other measures are usually not necessary, however if conditions warrant, contact physician.

Eyes In case of contact, do not rub or scratch your eyes. To prevent mechanical irritation, flush thoroughly with water for 15 minutes. If irritation persists, consult physician.

Skin To prevent the drying effect of plaster of paris, wash with mild soap and water. A commercially available hand lotion may be used to treat dry skin areas. If skin has become cracked, take appropriate action to prevent infection and promote healing. If irritation persists, consult physician.

Ingestion Plaster of paris hardens and, if ingested, may result in obstruction of the gut, especially the pyloric region. Drinking gelatin solutions or large volumes of water may delay setting.

MEDICAL CONDITIONS WHICH MAY BE AGGRAVATED: Pre-existing upper respiratory and lung diseases such as, but not limited to, bronchitis, emphysema and asthma. Pre-existing skin diseases such as, but not limited to, rashes and dermatitis.

NOTES TO PHYSICIAN: Treatment should be directed at the control of symptoms and the clinical condition.

SECTION 5 FIRE FIGHTING MEASURES

General Fire Hazards Not expected to burn.

Extinguishing Media Water or use extinguishing media appropriate for surrounding fire.

Special Fire Fighting Procedures Wear appropriate personal protective equipment. See section 8.

Unusual Fire/ Explosion Hazards None known

Hazardous Combustion Products Above 1450º C - decomposes to calcium oxide (CaO) and sulfur dioxide (SO2). Above 800º C – limestone may decompose to calcium oxide (CaO) and carbon dioxide (CO2).

Flash Point Not Determined Auto Ignition Not Applicable

Method Used Not Applicable Flammability Classification Not Applicable

Upper Flammable Limit (UFL) Not Determined

Lower Flammable Limit (LFL) Not Determined Rate of Burning Not Applicable

SECTION 6 ACCIDENTAL RELEASE MEASURES

CONTAINMENT: No special precautions. Wear appropriate personal protective equipment. See section 8.

CLEAN-UP: Use normal clean up procedures. No special precautions.

DISPOSAL: Follow all local, state, provincial and federal regulations. Never discharge large releases directly into sewers or surface waters.

SECTION 7 HANDLING AND STORAGE


MSDS #61-205-001 Page 4 of 9

HANDLING: Avoid dust contact with eyes and skin. Wear the appropriate eye and skin protection against dust (See Section 8). Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Use good safety and industrial hygiene practices. STORAGE: Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities (see Section 10). As a dry powder, dew point conditions or other conditions causing presence of liquid will harden plaster of paris during storage.

SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION

MATERIAL WT% TLV (mg/m3) PEL( mg/m3)


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


10 15(T)/5(R)

10 15(T)/5(R)

10 15(T)/5(R)

10 15(T)/5(R)

3(R) 20 mppcf

(NE) (NE)

(NE) (NE)

0.025(R) 0.1(R)

(T)–Total; (R)–Respirable; (NE)-Not Established; (C)-Ceiling; (STEL)-Short-term exposure limit

(F)-Fume; (Du)-Dust; (M)-Mist

ppm-part per million; f/cc-fiber per cubic centimeter; mppcf- million particles per cubic foot

ENGINEERING CONTROLS: Provide ventilation sufficient to control airborne dust levels. If user operations generate airborne dust, use ventilation to keep dust concentrations below permissible exposure limits. Where general ventilation is inadequate, use process enclosures, local exhaust ventilation, or other engineering controls to control dust levels below permissible exposure limits.

RESPIRATORY PROTECTION: Wear a NIOSH/MSHA-approved respirator equipped with particulate cartridges when dusty in poorly ventilated areas, and if TLV is exceeded. A respiratory program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. If engineering controls are not possible, wear a properly fitted NIOSH/MSHA-approved particulate respirator.

OTHER PERSONAL PROTECTIVE EQUIPMENT:

Eye/Face Wear eye protection, safety glasses or goggles, to avoid possible eye contact.

Skin Wear gloves and protective clothing to prevent repeated or prolonged skin contact.

General Selection of Personal Protective Equipment will depend on environmental working conditions and operations.

SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES

Appearance White to off-white Vapor Density (Air = 1) Not Applicable


MSDS #61-205-001 Page 5 of 9

Odor Low to no odor Specific Gravity (H2O = 1) ~2.96 (Plaster of Paris), ~2.6 (Limestone), ~2.8 (Mica), <1 (Ex. Perlite)

Odor Threshold Not Determined Solubility in water (g/100g) 0.15 - 0.40 (Plaster of Paris); 0.15 (Limestone); Insoluble (Mica)

Physical State Solid/ Powder Partition Coefficient Not Determined pH @ 25 º C ~7 Auto-ignition Temp Not Determined

Melting Point Not Applicable Decomposition Temp 2642ºF/1450ºC

Freezing Point Not Applicable Viscosity Not Applicable Boiling Point Not Applicable Particle Size Varies

Flash Point Not Determined Bulk Density 55-70 lb/ft3 (dry) / 881-1,121 kg/m3 (dry)

Evaporation Rate (BuAc = 1) Not Applicable Molecular Weight ~ 145 g/mole (Plaster of Paris)

Upper Flammable Limit (UFL) Not Determined VOC Content Zero g/L Lower Flammable Limit (LFL) Not Determined Percent Volatile Zero

Vapor Pressure (mm Hg) Not Applicable

SECTION 10 CHEMICAL STABILITY AND REACTIVITY

STABILITY Stable.

CONDITIONS TO AVOID Contact with acids, water, high humidity.

INCOMPATIBILITY Acids. Exposure to water and acids must be supervised because the reactions are vigorous and produce large amounts of heat.

HAZARDOUS POLYMERIZATION None known.

HAZARDOUS DECOMPOSITION Above 1450º C - calcium oxide (CaO) and sulfur dioxide (SO2). Above 800º C – limestone may decompose to calcium oxide (CaO) and carbon dioxide (CO2).

SECTION 11 TOXICOLOGICAL INFORMATION

ACUTE EFFECTS: The acute oral toxicity study [OECD TG 420] of calcium sulfate dihydrate showed that this chemical did not cause any changes even at 2,000 mg/kg b.w. Therefore, the oral LD50 value was more than 2,000-mg/kg b.w. for female rats. Gypsum paste applied experimentally to the eyes of rabbits was not an irritant. Gypsum dust particulate has shown an irritant action on mucous membranes of the respiratory tract and eyes. The sulfate ion has caused gastro-intestinal disturbance in humans following large oral doses. Limited studies involving the repeated inhalation of an (unspecified) calcium sulfate failed to identify any particular target organs in monkeys, rats and hamsters. No evidence of mutagenicity was found in Ames bacterial tests.

CHRONIC EFFECTS / CARCINOGENICITY: Plaster of Paris: Testing of dust from USG plaster of paris has not detected respirable crystalline silica.


MSDS #61-205-001 Page 6 of 9

Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. Smoking in combination with silica exposures increases the risk of cancer. The risk of developing silicosis is dependent upon the exposure intensity and duration.

In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs.

IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1).

Mica: Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.

SECTION 12 ECOLOGICAL INFORMATION

ENVIRONMENTAL TOXICITY: This product has no known adverse effect on ecology. Toxicity studies performed with fish, aquatic invertebrates and aquatic plants showed no toxic effect.

Ecotoxicity value Not determined.

SECTION 13 DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHOD: Dispose of material in accordance with federal, state, and local regulations. Never discharge directly into sewers or surface waters. Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Slurry may plug drains. Trace amounts of residue can be flushed to a drain, using plenty of water.

SECTION 14 TRANSPORT INFORMATION

U.S. DOT INFORMATION: Not a hazardous material per DOT shipping requirements. Not classified or regulated. Shipping Name Same as product name.

Hazard Class Not classified. UN/NA # None. Not classified. Packing Group None. Label (s) Required Not applicable. GGVSec/MDG-Code Not classified. ICAO/IATA-DGR Not applicable.


MSDS #61-205-001 Page 7 of 9

RID/ADR None. ADNR None.

SECTION 15 REGULATORY INFORMATION

UNITED STATES REGULATIONS All ingredients of this product are included in the U.S. Environmental Protection Agency’s Toxic Substances Control Act Chemical Substance Inventory.

MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

Key : NL = Not Listed

SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ)

SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ)

SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313

CERCLA Hazardous Substances: Reportable Quantity (RQ)

CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ)

RCRA Hazardous Waste: RCRA hazardous waste code

CANADIAN REGULATIONS This product has been classified in accordance with the hazard criteria of Controlled Product regulations and the MSDS contains all the information required by the Controlled Products Regulations. All ingredients of this product are included in the Canadian Domestic Substances List (DSL).

MATERIAL WT% IDL Item # WHMIS Classification


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


Not Listed Not Listed

Not Listed D2A


Not Listed D2A

1088 Not Listed



1406 D2A

IDL Item#: Canadian Hazardous Products Act – Ingredient Disclosure List Item #

WHMIS Classification: Workplace Hazardous Material Information System


MSDS #61-205-001 Page 8 of 9

HEALTH

FLAMMABILITY PHYSICAL HAZARD

PERSONAL PROTECTION

Risk and Safety Phrases defined by European Union Directive 67/548/EEC (Annex III and IV) R-Phrase(s): R36/37/38

S-Phrase(s): S51 S38 S39

SECTION 16 OTHER INFORMATION

Label Information

WARNING! When mixed with water, this material hardens and becomes very hot sometimes quickly. DO NOT attempt to make a cast enclosing any part of the body using this material. Failure to follow these instructions can cause severe burns that may require surgical removal of affected tissue or amputation of limb. Dust can cause irritation to eyes, skin and respiratory tract. Use wet-sanding to reduce dust created. Wear eye, skin and respiratory protection as necessary per working conditions. If eye contact occurs flush with water for 15 minutes. Do not ingest. If ingested, call physician. Frequent breathing of mica dust can cause lung disease (pneumoconiosis). Product safety information: 800-507-8899 or usg.com. Customer Service: 800 USG-4-YOU (800 874-4968). KEEP OUT OF REACH OF CHILDREN.

INFORMATION FOR HANDLING AND IDENTIFICATION OF CHEMICAL HAZARDS

0 1 0

* 1 0 1

E

0 = Minimal Hazard

NFPA Ratings: HMIS Ratings: 1 = Slight Hazard

Health: 1 Health: 1 2 = Moderate Hazard

Fire: 0 Fire: 0 3 = Serious Hazard

Reactivity: 0 Reactivity: 1 4 = Severe Hazard

E – Safety glasses, gloves and dust respirator; * - Contains silica

Key/Legend ANSI American National Standards Institute

ACGIH American Conference of Governmental Industrial Hygienists

CAA Clean Air Act

CAS Chemical Abstracts Service (Registry Number)

CERCLA Comprehensive Environmental Response, Compensation and Liability Act of 1980

CFR Code of Federal Regulations

DOT United States Department of Transportation

DSL Canadian Domestic Substances List

EPA United States Environmental Protection Agency

EPCRA Emergency Planning & Community Right-to-know Act

HMIS Hazardous Materials Identification System

IARC International Agency for Research on Cancer

MSHA Mine Safety and Health Administration

NDSL Canadian Non-Domestic Substances List

NFPA National Fire Protection Association

NIOSH National Institute for Occupational Safety and Health


MSDS #61-205-001 Page 9 of 9

OSHA Occupational Health and Safety Administration

PEL Permissible Exposure Limit

PPE Personal Protection Equipment

RCRA Resource Conservation and Recovery Act

SARA Superfund Amendments and Reauthorization Act of 1986

TLV Threshold Limit Value

TSCA Toxic Substances Control Act

UN/NA# United Nations/North America number

WHMIS Workplace Hazardous Material Information System

Prepared by:

Product Safety

USG Corporation


Chicago, IL 60661-3637

The information contained in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. It is the user’s responsibility to satisfy oneself as to the suitability and completeness of this information for his/her own particular use.

END


MSDS #61-205-006 Page 1 of 9

61205006


United States Gypsum Company


Chicago, Illinois 60661-3637

A Subsidiary of USG Corporation

Product Safety: 1 (800) 507-8899

www.usg.com

Version Date: January 1, 2011

Version: 7

PRODUCT(S) SHEETROCK® Lightweight Setting-Type Joint Compounds Easy Sand™45

CHEMICAL FAMILY / GENERAL CATEGORY Joint Treatment





ACUTE :

Inhalation

Exposure to dust generated during the handling or sanding of the product may cause temporary irritation to eyes, skin, nose, throat, and upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive inhalation. If respiratory symptoms persist, consult physician.

Eyes Dust can cause temporary mechanical irritation of eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult physician.

Skin None known.


CHRONIC:

Inhalation

Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.

Eyes None known.

Skin None known.


http://www.usg.com/


MSDS #61-205-006 Page 2 of 9










Food and Drug Administration [CFR Title 21, v.3, sec 184.1409] – Ground limestone is Generally Recognized as Safe (GRAS). POTENTIAL ENVIRONMENTAL EFFECTS: Toxicity studies performed with fish, aquatic invertebrates and aquatic plants showed no toxic effect. (See Section 12 for more information.)


MATERIAL WT% CAS #


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


26499-65-0

1317-65-3

16389-88-1

93763-70-3

12001-26-2

9002-89-5

12174-11-7

14808-60-7^


^The weight percent for silica represents total quartz and not the respirable fraction.



Inhalation Remove to fresh air. Leave the area of exposure and remain away until coughing and other symptoms


MSDS #61-205-006 Page 3 of 9

subside. Other measures are usually not necessary, however if conditions warrant, contact physician.

Eyes In case of contact, do not rub or scratch your eyes. To prevent mechanical irritation, flush thoroughly with water for 15 minutes. If irritation persists, consult physician.









Unusual Fire/ Explosion Hazards None known



Method Used Not Applicable Flammability Classification Not Applicable

Upper Flammable Limit (UFL) Not Determined








MSDS #61-205-006 Page 4 of 9

HANDLING: Avoid dust contact with eyes and skin. Wear the appropriate eye and skin protection against dust (See Section 8). Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Use good safety and industrial hygiene practices. STORAGE: Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities (see Section 10). As a dry powder, dew point conditions or other conditions causing presence of liquid will harden plaster of paris during storage.


MATERIAL WT% TLV (mg/m3) PEL( mg/m3)


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


10 15(T)/5(R)

10 15(T)/5(R)

10 15(T)/5(R)

10 15(T)/5(R)

3(R) 20 mppcf

(NE) (NE)

(NE) (NE)

0.025(R) 0.1(R)

(T)–Total; (R)–Respirable; (NE)-Not Established; (C)-Ceiling; (STEL)-Short-term exposure limit

(F)-Fume; (Du)-Dust; (M)-Mist

ppm-part per million; f/cc-fiber per cubic centimeter; mppcf- million particles per cubic foot










MSDS #61-205-006 Page 5 of 9



Physical State Solid/ Powder Partition Coefficient Not Determined pH @ 25 º C ~7 Auto-ignition Temp Not Determined


Freezing Point Not Applicable Viscosity Not Applicable Boiling Point Not Applicable Particle Size Varies



Upper Flammable Limit (UFL) Not Determined VOC Content Zero g/L Lower Flammable Limit (LFL) Not Determined Percent Volatile Zero



STABILITY Stable.

CONDITIONS TO AVOID Contact with acids, water, high humidity.





ACUTE EFFECTS: The acute oral toxicity study [OECD TG 420] of calcium sulfate dihydrate showed that this chemical did not cause any changes even at 2,000 mg/kg b.w. Therefore, the oral LD50 value was more than 2,000-mg/kg b.w. for female rats. Gypsum paste applied experimentally to the eyes of rabbits was not an irritant. Gypsum dust particulate has shown an irritant action on mucous membranes of the respiratory tract and eyes. The sulfate ion has caused gastro-intestinal disturbance in humans following large oral doses. Limited studies involving the repeated inhalation of an (unspecified) calcium sulfate failed to identify any particular target organs in monkeys, rats and hamsters. No evidence of mutagenicity was found in Ames bacterial tests.



MSDS #61-205-006 Page 6 of 9

Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. Smoking in combination with silica exposures increases the risk of cancer. The risk of developing silicosis is dependent upon the exposure intensity and duration.

In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs.

IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1).

Mica: Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.


ENVIRONMENTAL TOXICITY: This product has no known adverse effect on ecology. Toxicity studies performed with fish, aquatic invertebrates and aquatic plants showed no toxic effect.






Hazard Class Not classified. UN/NA # None. Not classified. Packing Group None. Label (s) Required Not applicable. GGVSec/MDG-Code Not classified. ICAO/IATA-DGR Not applicable.


MSDS #61-205-006 Page 7 of 9

RID/ADR None. ADNR None.



MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


Limestone <10

Or Dolomite


Mica <10


Attapulgite <5


NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

NL NL NL NL NL NL

Key : NL = Not Listed

SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ)

SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ)

SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313

CERCLA Hazardous Substances: Reportable Quantity (RQ)

CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ)

RCRA Hazardous Waste: RCRA hazardous waste code




Limestone <10

Or Dolomite


Mica <10


Attapulgite <5



Not Listed D2A


Not Listed D2A

1088 Not Listed



1406 D2A




MSDS #61-205-006 Page 8 of 9

HEALTH

FLAMMABILITY PHYSICAL HAZARD

PERSONAL PROTECTION

Risk and Safety Phrases defined by European Union Directive 67/548/EEC (Annex III and IV) R-Phrase(s): R36/37/38

S-Phrase(s): S51 S38 S39


Label Information

WARNING! When mixed with water, this material hardens and becomes very hot sometimes quickly. DO NOT attempt to make a cast enclosing any part of the body using this material. Failure to follow these instructions can cause severe burns that may require surgical removal of affected tissue or amputation of limb. Dust can cause irritation to eyes, skin and respiratory tract. Use wet-sanding to reduce dust created. Wear eye, skin and respiratory protection as necessary per working conditions. If eye contact occurs flush with water for 15 minutes. Do not ingest. If ingested, call physician. Frequent breathing of mica dust can cause lung disease (pneumoconiosis). Product safety information: 800-507-8899 or usg.com. Customer Service: 800 USG-4-YOU (800 874-4968). KEEP OUT OF REACH OF CHILDREN.


0 1 0

* 1 0 1

E

0 = Minimal Hazard

NFPA Ratings: HMIS Ratings: 1 = Slight Hazard



Reactivity: 0 Reactivity: 1 4 = Severe Hazard

E – Safety glasses, gloves and dust respirator; * - Contains silica

Key/Legend ANSI American National Standards Institute


CAA Clean Air Act















MSDS #61-205-006 Page 9 of 9






TLV Threshold Limit Value




Prepared by:

Product Safety

USG Corporation


Chicago, IL 60661-3637


END

MATERIAL SAFETY DATA SHEET SHEETROCK® Lightweight Setting Type Joint Compounds Easy Sand™90

MSDS #61-205-009 Page 1 of 9

SHEETROCK Lightweight Setting Type Joint Compounds Easy Sand90 61205009v7


United States Gypsum Company 550 West Adams Street Chicago, Illinois 60661-3637 A Subsidiary of USG Corporation

Product Safety: 1 (800) 507-8899 www.usg.com Version Date: January 1, 2008 Version: 7

PRODUCT(S) SHEETROCK® Lightweight Setting Type Joint Compounds Easy Sand™90

CHEMICAL FAMILY / GENERAL CATEGORY

Joint Treatment





ACUTE :

Inhalation

Exposure to dust generated during the sanding of the product may irritate eyes, skin, nose, throat, and upper respiratory tract. Persons subjected to large amounts of this dust will be forced to leave area because of nuisance conditions such as coughing, sneezing and nasal irritation. Labored breathing may occur after excessive inhalation. If respiratory symptoms persist, consult physician.

Eyes Dust can cause mechanical irritation of eyes. If burning, redness, itching, pain or other symptoms persist or develop, consult physician.

Skin None known.


CHRONIC:

Inhalation

Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.

Eyes None known.

Skin None known.





MSDS #61-205-009 Page 2 of 9








Food and Drug Administration [CFR Title 21, v.3, sec 184.1409] – Ground limestone is Generally Recognized as Safe (GRAS). POTENTIAL ENVIRONMENTAL EFFECTS: This product has no known adverse effect on ecology. (See Section 12 for more information)


MATERIAL WT% CAS #

Plaster of Paris (CaSO4•½H2O) 60-70 Limestone <10 Or Dolomite Expanded Perlite <10 Mica <10 Vinyl Alcohol Polymer <5 Attapulgite <5 Crystalline Silica <5

26499-65-0 1317-65-3 16389-88-1 93763-70-3 12001-26-2 9002-89-5 12174-11-7 14808-60-7


The weight percent for silica represents total quartz and not the respirable fraction.



Inhalation Remove to fresh air. Leave the area of exposure and remain away until coughing and other symptoms subside. Other measures are usually not necessary, however if conditions warrant, contact physician.

Eyes In case of contact, do not rub or scratch your eyes. To prevent mechanical irritation, flush thoroughly with


MSDS #61-205-009 Page 3 of 9

water for 15 minutes. If irritation persists, consult physician.









Unusual Fire/Explosion Hazards None known



Method Used Not Applicable

Upper Flammable Limit (UFL) Not Determined Flammability Classification Not Applicable








MSDS #61-205-009 Page 4 of 9

HANDLING: Avoid dust contact with eyes. Wear the appropriate eye protection against dust (See Section 8). Minimize dust generation and accumulation. Avoid breathing dust. Wear the appropriate respiratory protection against dust in poorly ventilated areas and if TLV is exceeded (see Sections 2 and 8). Use good safety and industrial hygiene practices. STORAGE: Store in a cool, dry, ventilated area away from sources of heat, moisture and incompatibilities (see Section 10). As a dry powder, dew point conditions or other conditions causing presence of liquid will harden plaster of paris during storage.


MATERIAL WT% TLV (mg/m3) PEL( mg/m3) Plaster of Paris (CaSO4•½H2O) 60-70 Limestone <10 Or Dolomite Expanded Perlite <10 Mica <10 Vinyl Alcohol Polymer <5 Attapulgite <5 Crystalline Silica <5

10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 10 15(T)/5(R) 3(R) 20 mppcf (NE) (NE) (NE) (NE) 0.025(R) 0.1(R)

(T)–Total; (R)–Respirable; (NE)-Not Established; (C)-Ceiling; (STEL)-Short-term exposure limit (F)-Fume; (Du)-Dust; (M)-Mist ppm-part per million; f/cc-fiber per cubic centimeter; mppcf- million particles per cubic foot










MSDS #61-205-009 Page 5 of 9



Physical State Solid/ Powder Partition Coefficient Not Determined

pH @ 25 º C ~7 Auto-ignition Temp Not Determined


Freezing Point Not Applicable Viscosity Not Applicable

Boiling Point Not Applicable Particle Size Varies



Upper Flammable Limit (UFL) Not Determined VOC Content Zero

Lower Flammable Limit (LFL) Not Determined Percent Volatile Zero



STABILITY Stable.

CONDITIONS TO AVOID Contact with incompatibles (see below).





ACUTE EFFECTS: The sulfate ion has caused gastro-intestinal disturbance in humans following large oral doses. Limited studies involving the repeated inhalation of an (unspecified) calcium sulfate failed to identify any particular target organs in monkeys, rats and hamsters. No evidence of mutagenicity was found in Ames bacterial tests. Plaster of paris: Oral LD50 rat > 5000 mg/kg; Dermal LD50 – None Determined; Skin Irritation LD50 – None Determined; Eye Irritation LD50– None Determined



MSDS #61-205-009 Page 6 of 9

Crystalline Silica: Exposures to respirable crystalline silica are not expected during the normal use of this product; however, actual levels must be determined by workplace hygiene testing. The weight percent of respirable crystalline silica may not have been measured in this product. Prolonged and repeated exposure to airborne free respirable crystalline silica can result in lung disease (i.e., silicosis) and/or lung cancer. The development of silicosis may increase the risks of additional health effects. The risk of developing silicosis is dependent upon the exposure intensity and duration. In June, 1997, IARC classified crystalline silica (quartz and cristobalite) as a human carcinogen. In making the overall evaluation, the IARC Working Group noted that carcinogenicity in humans was not detected in all industrial circumstances studied. Carcinogenicity may be dependent on inherent characteristics of the crystalline silica or on external factors affecting its biological activity or distribution of its polymorphs. IARC states that crystalline silica inhaled in the form of quartz or cristobalite from occupational sources is carcinogenic to humans (Group 1). Mica: Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). The extent and severity of lung injury correlates with the length of exposure and dust concentration.


ENVIRONMENTAL TOXICITY: This product has no known adverse effect on ecology.






Hazard Class Not classified. UN/NA # None. Not classified. Packing Group None. Label (s) Required Not applicable. GGVSec/MDG-Code Not classified. ICAO/IATA-DGR Not applicable. RID/ADR None. ADNR None.


MSDS #61-205-009 Page 7 of 9



MATERIAL WT% 302

304

313

CER

CLA

CA

A

Sec.

112

RC

RA

C

ode


NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL NL

Key : NL = Not Listed SARA Title III Section 302 (EPCRA) Extremely Hazardous Substances: Threshold Planning Quantity (TPQ) SARA Title III Section 304 (EPCRA) Extremely Hazardous Substances: Reportable Quantity (RQ) SARA Title III Section 313 (EPCRA) Toxic Chemicals: X= Subject to reporting under section 313 CERCLA Hazardous Substances: Reportable Quantity (RQ) CAA Section 112 (r) Regulated Chemicals for Accidental Release Prevention: Threshold Quantities(TQ) RCRA Hazardous Waste: RCRA hazardous waste code




Not Listed Not Listed Not Listed D2A Not Listed Not Listed Not Listed D2A 1088 Not Listed Not Listed Not Listed Not Listed Not Listed 1406 D2A



Risk and Safety Phrases defined by European Union Directive 67/548/EEC (Annex III and IV)


MSDS #61-205-009 Page 8 of 9

HEALTH

FLAMMABILITY

PHYSICAL HAZARD

PERSONAL PROTECTION

R-Phrase(s): R36/37/38

S-Phrase(s): S51 S38 S39 S2


Label Information

Δ WARNING! When mixed with water, this material hardens and becomes very hot – sometimes quickly. DO NOT attempt to make a cast enclosing any part of the body using this material. Failure to follow these instructions can cause severe burns that may require surgical removal of affected tissue or amputation of limb. Dust may cause irritation to eyes, skin, nose, throat and upper respiratory tract. Avoid irritation by reducing exposure to dust. Use in a well-ventilated area or provide sufficient local ventilation. Use wet-sanding to reduce dust created. If dusty, wear a NIOSH/MSHA-approved dust respirator. Wear eye protection. If eye contact occurs, flush thoroughly with water for 15 minutes. If irritation persists, call physician. Wash with soap and water after use. Do not ingest. If ingested, call physician. Prolonged and repeated breathing of respirable mica dust may cause lung disease (pneumoconiosis). Product safety information: (800) 507-8899 or www.usg.com. KEEP OUT OF REACH OF CHILDREN.


0 = Minimal Hazard

NFPA Ratings: HIMS Ratings: 1 = Slight Hazard



Reactivity: 0

0 1 0

Reactivity: 1

* 1 0 1

E 4 = Severe Hazard

E – Safety glasses, gloves and dust respirator

Key/Legend TLV Threshold Limit Value















MSDS #61-205-009 Page 9 of 9




CAA Clean Air Act







Prepared by: Product Safety USG Corporation 550 West Adams Street Chicago, IL 60661-3637


END

of 4

HMIS CodesHealth 2*

Flammability 2Reactivity 0

DATE OF PREPARATIONJan 9, 2013

MATERIAL SAFETY DATA SHEETB54T10431 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBERB54T104

PRODUCT NAMEIndustrial Enamel, Ultradeep Base

MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANY101 Prospect Avenue N.W.Cleveland, OH 44115

Telephone Numbers and WebsitesProduct Information (800) 524-5979

www.sherwin-williams.comRegulatory Information (216) 566-2902

www.paintdocs.comMedical Emergency (216) 566-2917

Transportation Emergency* (800) 424-9300for Chemical Emergency ONLY (spill, leak, fire, exposure, or *

accident)

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure43 64742-88-7 Mineral Spirits

ACGIH TLV 100 PPM 2 mmOSHA PEL 100 PPM

0.1 100-41-4 EthylbenzeneACGIH TLV 20 PPM 7.1 mmOSHA PEL 100 PPMOSHA PEL 125 PPM STEL

15 471-34-1 Calcium CarbonateACGIH TLV 10 mg/m3 as DustOSHA PEL 15 mg/m3 Total DustOSHA PEL 5 mg/m3 Respirable Fraction

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.Prolonged overexposure to hazardous ingredients in Section 2 may cause adverse chronic effects to the following organs or systems:

the liverthe urinary system

SIGNS AND SYMPTOMS OF OVEREXPOSUREHeadache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

B54T104

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UEL6.0

LEL1.0

FLASH POINT101 °F PMCC

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

FLAMMABILITY CLASSIFICATIONCombustible, Flash above 99 and below 200 °F

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSClosed containers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure

build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORYDOL Storage Class II

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEContents are COMBUSTIBLE. Keep away from heat and open flame.Consult NFPA Code. Use approved Bonding and Grounding procedures.Keep container closed when not in use. Transfer only to approved containers with complete and appropriate labeling. Do not take internally.

Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.Wash hands after using.This coating may contain materials classified as nuisance particulates (listed "as Dust" in Section 2) which may be present at hazardous

levels only during sanding or abrading of the dried film. If no specific dusts are listed in Section 2, the applicable limits for nuisance dusts are ACGIH TLV 10 mg/m3 (total dust), 3 mg/m3 (respirable fraction), OSHA PEL 15 mg/m3 (total dust), 5 mg/m3 (respirable fraction).

VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure

limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

When sanding or abrading the dried film, wear a dust/mist respirator approved by NIOSH/MSHA for dust which may be generated from this product, underlying paint, or the abrasive.

PROTECTIVE GLOVESWear gloves which are recommended by glove supplier for protection against materials in Section 2.

EYE PROTECTIONWear safety spectacles with unperforated sideshields.

OTHER PRECAUTIONSIntentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

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SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 8.37 lb/gal 1003 g/lSPECIFIC GRAVITY 1.01

BOILING POINT 300 - 395 °F 148 - 201 °CMELTING POINT Not Available

VOLATILE VOLUME 58%EVAPORATION RATE Slower than

etherVAPOR DENSITY Heavier than air

SOLUBILITY IN WATER Not AvailableVOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

3.71 lb/gal 444 g/l Less Water and Federally Exempt Solvents3.71 lb/gal 444 g/l Emitted VOC

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — StableCONDITIONS TO AVOID

None known.INCOMPATIBILITY

None known.HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDSReports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.Ethylbenzene is classified by IARC as possibly carcinogenic to humans (2B) based on inadequate evidence in humans and sufficient

evidence in laboratory animals. Lifetime inhalation exposure of rats and mice to high ethylbenzene concentrations resulted in increases in certain types of cancer, including kidney tumors in rats and lung and liver tumors in mice. These effects were not observed in animals exposed to lower concentrations. There is no evidence that ethylbenzene causes cancer in humans.

TOXICOLOGY DATACAS No. Ingredient Name64742-88-7 Mineral Spirits

LC50 RAT 4HR Not AvailableLD50 RAT Not Available

100-41-4 EthylbenzeneLC50 RAT 4HR Not AvailableLD50 RAT 3500 mg/kg

471-34-1 Calcium CarbonateLC50 RAT 4HR Not AvailableLD50 RAT Not Available

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.Incinerate in approved facility. Do not incinerate closed container. Dispose of in accordance with Federal, State/Provincial, and Local

regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport.

B54T104

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US Ground (DOT)May be Classed as a Combustible Liquid for U.S. Ground.UN1263, PAINT, 3, PG III, (ERG#128)

DOT (Dept of Transportation) Hazardous Substances & Reportable QuantitiesXylenes (isomers and mixture) 100 lb RQ

Bulk Containers may be Shipped as (check reportable quantities):UN1263, PAINT, COMBUSTIBLE LIQUID, PG III, (ERG#128)

Canada (TDG)May be Classed as a Combustible Liquid for Canadian Ground.UN1263, PAINT, CLASS 3, PG III, (ERG#128)

IMO5 Liters (1.3 Gallons) and Less may be Shipped as Limited Quantity.UN1263, PAINT, CLASS 3, PG III, (38 C c.c.), EmS F-E, , ADR (D/E)S-E

IATA/ICAOUN1263, PAINT, 3, PG III

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element100-41-4 Ethylbenzene 0.1CALIFORNIA PROPOSITION 65

WARNING: This product contains chemicals known to the State of California to cause cancer and birth defects or other reproductive harm.TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.

KIK CUSTOM PRODUCTS Page 1 of 2

Material Safety Data Sheet

Section 1. Chemical Product and Company Identification Product Name/Trade Name Bleach – Regular

REF#40000196

Manufacturer: KIK CUSTOM PRODUCTS

2921 Corder Street

Contact Number:

24 Hour Emergency Contact Number:

Prepared By:

Date Last Revised:

Replaces Date:

Houston, TX 77054

Tel: 905-660-0444

1-800-255-3924

KIK CUSTOM PRODUCTS Laboratory

October 18, 2011 September 27, 2011

Section 2. Hazardous Ingredients Ingredient Concentration CAS# Worker Exposure Limit

Sodium Hypochlorite 1-6.0% 7681-52-9 not established

Sodium Hydroxide <1.0% 1310-73-2 2 mg/m3 – TLV-C*

∗ TLV-C = ACGIH Threshold Limit Value – Ceiling

None of the ingredients in this product are on the IARC or NTP carcinogen lists.

Section 3. Hazards Identification Route of Entry

Skin Yes Eye Yes

Inhalation Yes Ingestion Yes

Effects of Exposure: May cause substantial but temporary eye injury. May irritate skin. When ingested, may cause nausea

and vomiting. Inhalation of vapor will irritate nose, throat and lungs.

Effects of acute exposure: Inhalation of mist or vapor may cause breathing difficulty. Its corrosiveness may cause severe

irritation to eyes and skin. May cause permanent damage if not treated properly. Ingestion can cause corrosion of mucous

membranes, severe esophageal burns and perforation of esophagus or stomach.

Effects of chronic exposure: Not Known.

Under normal consumer use conditions, the likelihood of any adverse health effects is low. The following medical

conditions may be aggravated by exposure to high concentration of vapor or mist: heart conditions or chronic respiratory

problems such as asthma, bronchitis or obstructive lung disease. Some clinical tests conducted on intact skin with sodium

hypochlorite liquid bleach found no sensitization in the test subjects.

Section 4. First Aid Measures

Skin: Remove contaminated clothing. Wash with copious amount of water. If irritation persists, call a

doctor.

Eyes: Flush eyes with cool running water holding eyelids apart to ensure thorough rinsing for 15 minutes.

Remove contact lenses. See a doctor immediately.

Inhalation: Move to fresh air and restore breathing,. If breathing problems develop, call a doctor.

Ingestion: DO NOT INDUCE VOMITING! Drink large amounts of water. Do not give anything by mouth

to a convulsing or unconscious person. See a doctor immediately.

General Advice: If irritation occurs, see a doctor immediately.

KIK CUSTOM PRODUCTS Page 2 of 2

Section 5. Preventative Measures

Protective Equipment

Gloves: Impervious PVC or Neoprene.

Eyes: Safety glasses at the very least. Chemical splash goggles. Face shield also helpful.

Respiratory: Not normally required. Footwear: Protect shoes and feet when using product for floor

cleaning.

LEAK AND SPILL PROTECTION: Small spills: Dilute product by flooding area with large quantity of water and flush to sanitary sewer.

Large spills: Contain run-off by diking with suitable material. Soak up liquid on inert absorbent and

transfer to approved container. Prevent spill from entering sewers or waterways

WASTE DISPOSAL: Reclaim or dispose in accordance with local regulations.

STORAGE REQUIREMENTS: Store in a cool, dry and well-ventilated area.

Section 6. Physical Data State Liquid pH 12.5 maximum

Appearance Clear Pale yellow Specific Gravity 1.040 – 1.050

Odour Typical Bleach Solubility in water complete

Section 7. Fire & Explosion

Not flammable nor explosive

Section 8. Reactivity Data Chemical Stability: Stable under normal use and storage conditions.

Conditions: Temperature above 40 °C, sunlight and metals,

Incompatibility: YES X NO

What Substances? Acids, ammonia, urea, metals & oxidizers.

Reactivity / Conditions: Reacts with other household products containing such chemicals as acids, rust

removers, urea or ammonia to produce hazardous gases such as chlorine and other chlorinated species.

Oxygen is released on contact with metals. Extended contact with metals may cause discoloration or

pitting

Section 9. Regulatory Information WHIMS:

Health: 2

Flammability: 0

Reactivity: 1

DOT : Not Restricted

As the handling and use of products under user's conditions are beyond our control, no warranty, expressed or implied, is made concerning this product. The information contained herein is offered only as a guide to the handling of this specific material and is not intended to be all-inclusive in the manner and conditions of use and handling. The user assumes all risks of use or handling, whether or not in accordance with any directions or suggestions of the manufacturer. Manufacturer shall not be liable to purchaser or any other person for loss or damages directly or indirectly arising from the use of our product.

MATERIAL SAFETY DATA SHEET7/27/2012

MANUFACTURER OR DISTRIBUTOR: Speedball Art Products Co.P.O. Box 51572301 Speedball RoadStatesville, North Carolina 28677

INFORMATION TELEPHONE NUMBER: 704-978-4166EMERGENCY TELEPHONE NUMBER: 1-800-898-7224

SECTION I - PRODUCT IDENTIFICATION

PRODUCT NAME: FABRIC B/P INK PRODUCT NUMBER: FABRIC B/PPRODUCT SIZES: 37, 75, 150 ML BRAND NAME: FABRIC B/P INKPRODUCT CLASS: DRAWING INK

SECTION II - POTENTIAL HEALTH EFFECTS

PERMISSIBLE EXPOSURE LEVEL: SEE SECTION III FOR COMPONENT PEL/TLVsPRIMARY ROUTES OF ENTRY: INHALATION, INGESTION, EYE, SKIN

EFFECTS AND SYMPTOMS OF ACUTE EXPOSURE: CONTACT MAY RESULT IN REDNESS OR PAIN OF THE EYES.

EFFECTS AND SYMPTOMS OF CHRONIC EXPOSURE: NONE EXPECTED

CARCINOGEN LISTING: NTP: NO IARC: NO OSHA: NO

SEE SECTION III FOR COMPONENTS AFFECTED

MEDICAL CONDITIONS USUALLY AGGRAVATED BY OVER EXPOSURE TO THIS PRODUCT: NONE

SECTION III - HAZARDOUS INGREDIENTS

Ingredient CAS #PEL/TLV (MG/M#)

Max % Weight NTP IARC

None

SECTION IV - FIRST AID

FIRST AID MEASURES: NONE REQUIRED. NO ACUTE HEALTH EFFECTS EXPECTED.

SECTION V - FIRE FIGHTING MEASURES

FLASH POINT (METHOD): N/A AUTOIGNITION TEMPERATURE: N/AEXPLOSION LIMITS IN AIR (% BY VOLUME): NOT EXPLOSIVEEXTINGUISHING MEDIA: NO SPECIAL MEDIA REQUIREDFIRE FIGHTING PROCEDURES: NO SPECIAL FIRE FIGHTING PROCEDURES REQUIREDUNUSUAL FIRE & EXPLOSION HAZARDS: NOT COMBUSTIBLE

SECTION VI - SPILL AND LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE A MATERIAL IS SPILLED: Clean up in accordance with all applicable regulations. Absorb spillage with non-

COMPANY: Speedball Art Products Co. 7/27/2012PRODUCT: FABRIC B/P

BRAND NAME: FABRIC B/P INK

Page 2

combustible, absorbent material. For waste disposal, see Section XIII

SECTION VII - HANDLING AND STORAGE

PRECAUTIONS TO BE TAKEN DURING STORAGE AND HANDLING: Good industrial hygiene practice requires that exposure be maintained below the TLV. This is preferably achieved through the provision of adequate ventilation. When exposure cannot be adequately controlled in this way, personal respiratory protection should be employed.

SECTION VIII - EXPOSURE CONTROLS

RESPIRATORY PROTECTION AND SPECIAL VENTILATION REQUIREMENTS: NONE REQUIREDOTHER PROTECTIVE EQUIPMENT (GLOVES, GOGGLES, ETC): NONE REQUIREDWORK/HYGIENE PRACTICES: NONE REQUIREDENGINEERING CONTROLS: NONE REQUIRED

SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES

BOILING POINT: N/A MELTING POINT: N/AVAPOR PRESSURE: N/ASPECIFIC VAPOR DENSITY (AIR=1): N/A SPECIFIC GRAVITY: N/ASOLUBILITY IN WATER: N/A REACTIVITY IN WATER: NON-REACTIVE

SECTION X - STABILITY AND REACTIVITY

HAZARDOUS POLYMERIZATION PRODUCTS: NONESTABILITY: STABLE CONDITIONS TO AVOID: NONEINCOMPATIBILITY (MATERIALS TO AVOID): NONEHAZARDOUS DECOMPOSITION PRODUCTS: NONE

SECTION XI - TOXICOLOGICAL INFORMATION

ACUTE EFFECTS ASSOCIATED WITH USE OF THIS MATERIAL: CONTACT MAY RESULT IN REDNESS OR PAIN OF THE EYES. The summated LD50 is 13770 mg/kg.This product is/is not considered to be a known or suspected human carcinogen by NTP, IARC or OSHA (see section III)

SECTION XII - ECOLOGICAL INFORMATION

NO HARMFUL EFFECTS KNOWN OTHER THAN THOSE ASSOCIATED WITH SUSPENDED INERT SOLIDS IN WATER.

SECTION XIII - DISPOSAL CONSIDERATIONS

RCRA HAZARD CLASS (40 CFR 261): THIS PRODUCT IS NOT CLASSIFIED AS A HAZARDOUS WASTE.WASTE DISPOSAL METHOD: DISPOSE OF IN ACCORDANCE WITH FEDERAL, STATE AND LOCAL REGULATIONS.

SECTION XIV - TRANSPORTATION INFORMATION

U.S. DOT (49 CFR 172.101): THIS IS NOT A HAZARDOUS MATERIAL AS CLASSIFIED BY CFR 172.101.

SECTION XV - REGULATORY INFORMATION



Page 3

CONTENTS OF THIS MSDS COMPLY WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200EPA SARA TITLE III CHEMICAL LISTINGSNONE

SECTION 302.4 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355):NONE

SECTION 313 TOXIC CHEMICALS (40 CFR 372):NONE

INTERNATIONAL REGULATIONS

CANADIAN WHMIS: THIS PRODUCT IS A CONTROLLED PRODUCT UNDER CANADA'S WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM. IT CONTAINS THE FOLLOWING TOXIC OR HIGHLY TOXIC MATERIALS:ALUMINUM OXIDEAMMONIAPROPYLENE GLYCOL

SUPPLEMENTAL STATE COMPLIANCE INFORMATION:

THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) LISTED IN THE STATE OF CALIFORNIA UNDER THEIR SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT OF 1986 (PROPOSITION 65) AS BEING KNOWN TO CAUSE CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM:NONE

THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) LISTED UNDER NEW JERSEY'S RIGHT TO KNOW PROGRAM:ALUMINUM OXIDEAMMONIA

THIS PRODUCT CONTAINS THE FOLLOWING CHEMICAL(S) REQUIRING NOTIFICATION TO THE STATE OF WASHINGTON UNDER THEIR CHILDREN'S SAFE PRODUCTS ACT:NONE

SECTION XVI - OTHER INFORMATION

THIS INFORMATION SHEET IS FOR CONSUMER USE ONLY.



Page 4

!$!C001600,03,001080,012085!$!_____________________________________________Woodhall Stopford, MD, MSPH 7/27/2012



Page 5

COLOR INFORMATION

THIS MSDS APPLIES TO THE FOLLOWING COLORS WHICH ARE ASSOCIATED WITH HAZARDOUS AND/OR NON-HAZARDOUS INGREDIENTS

Product Color Hazardous IngredientBLACK (NONE) WHITE (NONE)



Page 6

BRAND NAMES

THIS MSDS APPLIES TO THE FOLLOWING BRAND NAMES

Brand Name SKUFABRIC B/P INK


HMIS Ratings

Health: 0Flammability: 0Reactivity: 0

Identity : Sperian® Sterile Saline Solution - Product #s: 32-ST1050, 32-ST2050, 32-000440, 32-000445, 32-00446, 32-000448, 32-000449, 32-000451, 32-000452, 32-000454, 32-000455, 32-000456, 32-000457, 32-000458, 32-000460, 32-000461, 32-000462, 32-000463, 32-000465,32-000470, 32-000471, 32-000494, 32-000497, 32-000498Section I

Manufacturer : Sperian Eye & Face Protection, Inc. Emergency Telephone : 1-800-430-5490

Information Telephone : 1-800-543-4842 Address : 825 East Highway 151 Platteville, WI 53818 USA Date prepared : 03/08/11

Section II – Hazardous Ingredients/Identify Information Hazardous Components(Specific Chemical Identity; Common Name(s))

OSHA PEL

ACGIH TLV

Outer limitsrecommended % (optional)

NONE NONE NONE N/A N/A Section III – Physical/Chemical Characteristics Boiling Point : 200°F (93.3°C) Specific Gravity (H2O = 1) : NOT DETERMINED

Vapor Pressure (mm Hg) : 760 Melting Point : N/A

Vapor Density (Air = 1) : NOT DETERMINED Evaporation Rate (Butyl Acetate = 1) : NOT DETERMINED

Solubility in Water : 100%

Appearance and Odor : COLORLESS LIQUID WITH NO DISCERNABLE ODOR.

Section IV – Fire and Explosion Hazard Data Flash Point (Method Used) : N/A Flammable Limits : LEL : N/A UEL : N/A

Extinguishing Media : THIS IS A NONFLAMMABLE AQUEOUS SOLUTION.

Special Fire Fighting Procedures : N/A

Unusual Fire and Explosion Hazards : N/A

Section V – Reactivity Data

Stability : Unstable : NOStable : YES

Conditions to Avoid : THIS PRODUCT IS STABLE AND CONSIDERED NON-REACTIVEUNDER NORMAL CONDITIONS OF STORAGE AND USAGE.

Incompatibility (Materials to Avoid) : NONE KNOWN

Hazardous Decomposition or Byproducts : NONEHazardousPolymeization :

May Occur : NO Will Not Occur : YES

Section VI – Health Hazard DataRoute(s) of Entry : Inhalation? NO Skin? NO Ingestion? YES

Health Hazards (Acute and Chronic) : INGESTION OF VOLUMES IN EXCESS OF 20 LITERS MAY CAUSE GASTRIC IRRITATION.

Carcinogenicity : NTP? NO IARC Monographs? NO OSHA Regulated? NO

Signs and Symptoms of Exposure : N/A

Medical Conditions Generally Aggraveted by Exposure : N/AEmergency First Aid Procedures : NOTES TO PHYSICIAN : IN THE UNLIKELY EVENT OF RAPID INGESTIONS OF LARGE VOLUMESOF THE SOLUTION, INDUCE VOMITING AND OBSERVE THE PATIENT FOR GASTRIC IRRITATION.Section VII – Precautions for Safe Handling and Use Steps to Be Taken in Case Material is Released or Spilled : FLUSH AREA WITH WATER. THE SOLUTION IS NOT RCRAHAZARDOUS WASTE.Waste Disposal Method : N/APrecautions to Be Taken in Handling and Storing : DO NOT FREEZE OR EXPOSE TO TEMPERATURES IN EXCESS OF110°F (43°C) FOR EXTENDED PERIODS.Other Precautions : N/A

Section VIII – Control Measures

Respiratory Protection : N/A

Ventilation : Local Exhaust : N/AMechanical : N/A

Special : N/AOther : N/A

Protective Gloves : N/A Eye Protection : N/A

Other Protective Clothing : N/A

Work Hygienic Practices : N/A

Part #32-005591 Rev. F

Conditions to Avoid : NONE

HMIS Salund: 0 Calificaciones Inflamabilidad: 0 Reactividad: 0

Identidad : Solución estériles Salino de Sperian® - Números de productos: 32-ST1050, 32-ST2050, 32-000440, 32-000445, 32-00446, 32-000448, 32-000449, 32-000451, 32-000452, 32-000454, 32-000455, 32-000456, 32-000457, 32-000458, 32-000460, 32-000461, 32-000462, 32-000463, 32-000465, 32-000470, 32-000471, 32-000494, 32-000497, 32-000498Sección I

Fabricante : Sperian Eye & Face Protection, Inc. Télefono de emergencia : 1-800-430-5490

Télefono de información : 1-800-543-4842 Dococilio : 825 East Highway 151 Platteville, WI 53818 USA Fecha de preparación : 03/08/11

Sección II – Ingredientes peligrosos/identificación de información Componentes peligrosos (Identidad Quimica Especifica; Nombre(s) Común(es))

OSHA1

PEL2

ACGIH3 TLV4

Otros limites recomendados % (opcional)

NINGUNO NINGUNO NINGUNO N/A N/A Sección III – Caracteristicas fisicoquimicas Punto de ebullición: 93.3 °C (200 °F) Gravedad especifica (H2 O = 1) : NO DETERMINADA

Presión de vapor (mm Hg) : 760 Punto de fusión : N/A

Densidad de vapor (Air = 1) : NO DETERMINADA Tasa de evaporación (acetato de butilo = 1) :

Solubilidad en agua : 100 %

Apariencia y olor : LIQUIDO INCOLORO SIN NINGUN OLOR APRECIABLESección IV – Información de peligros de fuego y explosión Punto se inflamación (Método usado) : N/A Limites de inflamación : LEL5: N/A UEL6: N/A

Medios de extinción : ESTE UNA SOLUCIN ACUOSA NO INFLAMABLE.

Procedimientos especiales para la extinción de incendios : N/A

Peligros inusuales de fuego y explosión : N/A

Sección V – Información de reactividad

Estabilidad Inestable : NO Estable : SÍ

Condiciones que deban evitarse : ESTE PRODUCTO ES ESTABLE SE CONSIDERANO REACTIVO BAJO CONDICIONES NORMALES DE USO Y ALMACENAMIENTO.

Incompatibilidad (materials que deben evitarse) : NINGUNO CONOCIDO

Polimerizaciónpeligrosa

Puede occurir: NONo ocurriá: SÍ Condiciones que se deben evitar: NINGUNA

Sección VI – Información de peligros para la salud

Peligros para la salud (agudos y crónica): LA INGESTIÓN DE VOLUMENES MAYORES A 20 LITROS PUEDE PROVOCAR IRRITACIÓN GÁSTRICA.

CARCINOGENIDAD: ¿NTP7? NO ¿Monografias IARC8? NO ¿Regulado por OSHA1? NO

Sintomas y indicios de la exposición: N/A

Condiciones médicas generalmente agravadas por la esposición: N/AProcedimientos de primeros auxilios de emergencia: NOTAS PARA EL MEDICO: EN EL FORTUITO CASE DE UNA INGESTIÓN RAPIDA DEGRANDES VOLUMENES DE LA SOLUCIÓN, PROVOQUE EL VOMITO Y OBSERVE SI SE PRESENTA IRRITACIÓN GÁSTRICA EN EL PACIENTE.Sección VII – Precauciones para uso y manejo seguro Pasos a seguir en caso que el material sea liberado o derramado: LAVE EL ÁREA CON AGUA. LA SOLUCIÓN NO ES UN DESPERDICIO PELIGROSO PARA RCRA9.Método de desecho de desperdicios: N/APrecauciones qu se deban tomar para el manejo y almacenamineto: NO SE CONGELE O EXPONGA A TEMPERATURAS MAYORES A LOS 43°C (110°F) POR PERIODOS EXTENSOS.Otras Precauciones: N/A

Sección VIII – Medidas de control

Protección respiratoria: N/A

Ventilación: Extracción: N/AMecánica: N/A

Especial: N/AOtra: N/A

Cuantes protectores: N/A Protección para ojos: N/A

Otras prendas protectoras: N/A

Prácticas de higiene laboral: N/A

Parte # 32-005591 Rev. F

HOJA DE INFORMACIÓ DESEGURIDAD DEL MATERIAL

NO DETERMINADA

Descomposición o subproductos peligrosos : NINGUNO

Ruta(s) de entrada: ¿Ihalación? NO ¿Cutánea? NO ¿Ingestión? SÍ

1. Occupational Safety and Health Act (Decreto de Salud y Seguridad Ocupacional); 2. Prescriptive Exposure Limit (Limite Prescrito de Exposición); 3. American Conference of GovernmentalIndustrial Hygienists (Conferencia Americana de Higienistas Industriales Guvernamentales); 4. Threshold Limit Value(s) (Valor(es) Limite de Umbral); 5. Lower Explosive Level (Nivel de Explosióninterior); 6. Upper Explosive Limit (Nivel Superior de Explosión); 7. National Toxicology Program (Programa Nacional de Toxicología); 8. International Agency for Research on Cancer (AgenciaInternacional para la investigación del Cáncer); 9. Resources Conservation and Recovery Act (Decreto de Conservación y Recuperación de Recursos).

FICHE SIGNALÉTIQUE HMIS Santé: 0 Classements Inflammabilité: 0

Réactivité : 0

Nom du produit : Solution stériles Salina de Sperian® - Numéros de produit 32-ST1050, 32-ST2050, 32-000440, 32-000445, 32-00446,32-000448, 32-000449, 32-000451, 32-000452, 32-000454, 32-000455, 32-000456, 32-000457, 32-000458, 32-000460, 32-000461, 32-000462, 32-000463, 32-000465, 32-000470, 32-000471, 32-000494, 32-000497, 32-000498Section I

Fabricant : Sperian Eye & Face Protection, Inc. Téléphone (en cas d’urgence) 1-800-430-5490

Téléphone (pour obtenir des informations) : 1-800-543-4842 Adresse : 825 East Highway 151 Platteville, WI 53818 USA Date de la préparation : 03/08/11

Section II – Ingrédients dangereux/Renseignements signalétiques Composants dangereux (Dénomination chimique spécifique ; noms communs)

OSHA PEL

ACGIH TLV

Autres limites recommandées % (facultatif)

NÉANT NÉANT NÉANT SANS OBJET SANS OBJET Section III – Caractéristiques physiques et chimiques Point d’ébullition : 93,3 °C (200 °F) Densité spécifique (H2O = 1) : AUCUNE DONNÉE DISPONIBLE

Tension de vapeur (mm Hg) : 760 Point de fusion : SANS OBJETDensité de vapeur (Air = 1) : AUCUNE DONNÉE DISPONIBLE

Taux d’évaporation (acétate de butyle = 1) : AUCUNE DONNÉE DISPONIBLE

Solubilité dans l’eau : 100 %

Apparence et odeur : LIQUIDE INCOLORE SANS ODEUR DISCERNABLE.

Section IV – Risques d’incendie ou d’explosion Point d’éclair (méthode utilisée) : SANS OBJET Limites d’inflammabilité : LIE : SANS OBJET LSE : SANS OBJET

Moyens d’extinction : CETTE SOLUTION AQUEUSE EST ININFLAMMABLE.

Procédures spéciales de lutte contre l’incendie : SANS OBJET

Risques inhabituels d’incendie et d’explosion : SANS OBJET

Section V – Réactivité

Stabilité Instable : NON Stable : OUI

Conditions à éviter : CE PRODUIT EST CONSIDÉRÉ COMME ÉTANT NON-RÉACTIF ET STABLE DANS DES CONDITIONS NORMALES D’ENTREPOSAGE ET D’USAGE.

Incompatibilité (matériaux à éviter) : AUCUN CONNU

Produits ou sous-produits de décomposition dangereux : NÉANT Polymérisation dangereuse

Peut avoir lieu : NON N’aura pas lieu : OUI Conditions à éviter : NÉANT

Section VI – Risques pour la santéVoies d’exposition : Inhalation ? NON Peau ? NON Ingestion ? OUI

Risques pour la santé (aigus et chroniques) : L’INGESTION DE PLUS DE 20 LITRES RISQUE DE PROVOQUER UNE IRRITATION GASTRIQUE.

Cancérogénicité : NTP ? NON Monographies CIRC ? NON Réglementation OSHA ? NON

Signe et symptômes d’exposition : SANS OBJET

Troubles médicaux généralement aggravés par l’exposition : SANS OBJET Premiers soins : NOTES À L’INTENTION DU MÉDECIN : DANS LE CAS PEU PROBABLE D’UNE INGESTION RAPIDE DE GRANDES QUANTITÉS DE LA SOLUTION, PROVOQUER LE VOMISSEMENT ET OBSERVER LE PATIENT POUR TOUTE IRRITATION GASTRIQUE. Section VII – Précautions à prendre pour une manutention et une utilisation sécuritairesPrécautions à prendre en cas de fuite ou de déversement de matériau : RINCER LA SURFACE À L’EAU. LA SOLUTION N’EST PAS UN DÉCHET DANGEREUX DE LA RCRA DE L’EPA DES ÉTATS-UNIS. Méthode d’élimination des résidus : SANS OBJET Précautions à prendre lors de la manutention et de l’entreposage : NE PAS CONGELER NI EXPOSER À DES TEMPÉRATURES SUPÉRIEURES À 43°C (110 ºF) PENDANT DES PÉRIODES PROLONGÉES. Autres précautions : SANS OBJET

Section VIII – Mesures de contrôle

Protection des voies respiratoires : SANS OBJET

Ventilation : Locale : SANS OBJETMécanique : SANS OBJET

Spéciale : SANS OBJETAutre : SANS OBJET

Gants de protection : SANS OBJET Protection des yeux : SANS OBJET

Autres vêtements de protection : SANS OBJET

Pratiques d’hygiène au travail : SANS OBJET

Pièce n° 32-005591, Rév. F

840 M A T E R I A L S A F E T Y D A T A S H E E T

Complies with OSHA Hazard Communication Standard 29 CFR 1910.1200 Date of Prep: 3/20/09

SECTION 1 SUNNYSIDE CORPORATION FOR INFORMATION: (847) 541-5700 225 CARPENTER AVENUE WHEELING, ILLINOIS 60090 (847) 541-5700 - SUNNYSIDE CORPORATION EMERGENCY TELEPHONE (800) 424-9300 - CHEM TREC Product Class: Ketone Manufacturer's Code: 840 Trade Name: ACETONE NPCA HMIS: Health: 1 Flammability: 3 Reactivity: 0 Product Appearance and Odor: Clear, water-white liquid; typical, pungent odor.

SECTION 2 -- HAZARDOUS INGREDIENTS

OCCUPATIONAL EXPOSURE LIMITS ACGIH ACGIH OSHA OSHA INGREDIENT CAS # PERCENT TLV TLV PEL PEL VAPOR PRESSURE (TWA) (STEL) (TWA) (STEL) Acetone 67-64-1 100% 500 PPM 750 PPM 750 PPM 1000 PPM 213 MM Hg @ 75O F

SECTION 3 -- EMERGENCY AND FIRST AID PROCEDURES INHALATION: Using proper respiratory protection, immediately remove the affected victim from exposure. Administer artificial

respiration if breathing is stopped. If breathing is difficult, qualified medical personnel may administer oxygen and continue to monitor. Keep at rest. Get medical attention immediately.

EYE CONTACT: Flush eyes immediately with water for at least 15 minutes. Get prompt medical attention. SKIN CONTACT: Flush with large amounts of water; use soap if available. Remove grossly contaminated clothing, including shoes,

and launder before reuse. Get medical attention if skin irritation develops or persists. INGESTION: If swallowed, do not induce vomiting. Give victim a glass of water or milk. Call a physician or poison control center

immediately. Never give anything by mouth to an unconscious person.

SECTION 4 -- PHYSICAL DATA The following data represent approximate or typical values. They do not constitute product specifications. Boiling Range: 133° (F) (I.B.P.) Vapor Density: Heavier than air Evaporation Rate: Slower than ether % Volatile By Volume: 100% Weight Per Gallon: 6.60 Lbs. Solubility in Water: Complete

SECTION 5 -- FIRE AND EXPLOSION DATA Flammability Classification: Flammable Liquid - Class IB. Flash Point: 0° (F) (Tag. Closed Cup). Autoignition Temperature: 869O (F) Lower Explosive Limit: 2.5% @ 77O (F) Extinguishing Media: Either allow fire to burn under controlled conditions or extinguish with alcohol resistant foam and dry chemical. Try to

cover liquid spills with foam. Unusual Fire and Explosion Hazards: Extremely flammable. Vapors may cause a flash fire or ignite explosively. Vapors may travel considerable distance

to a source of ignition and flash back. Prevent buildup of vapors or gases to explosive concentrations. Special Fire Fighting Procedures: Use water spray to cool fire exposed surfaces and to protect personnel. Shut off "fuel" to fire. If a leak or spill has not

ignited, use water spray to disperse the vapors.

Trade Name: ACETONE Page 2 of 3

SECTION 6 -- HEALTH HAZARD DATA THRESHOLD LIMIT VALUE: 500 PPM (ACGIH-Time weighted average). EFFECTS OF OVEREXPOSURE Inhalation: Vapors or mist may cause irritation of the nose and throat. Inhilation may cause dizziness, drowsiness, loss of

coordination, disorientation, headache, nausea, and vomiting. In poorly ventilated areas or confined spaces, unconsciousness and asphyxiation may result.

Skin Contact: Prolonged or repeated skin contact may cause irritation, discomfort and dermatitis. Eye Contact: Severely irritating and may injure cornea if not removed promptly. High vapor concentrations are also irritating. Ingestion: Product may be harmful or fatal if swallowed. Material is a pulmonary aspiration hazard. Material can enter lungs

and cause damage. Ingestion of this product may cause central nervous system effects, which may include dizziness, loss of balance and coordination, unconsciousness, coma and even death.

Carcinogenicity: Acetone is not listed by the NTP, IARC, or OSHA.

SECTION 7 -- REACTIVITY DATA Stability: Stable Conditions to Avoid: Heat, sparks and flame. Incompatibility (Materials to Avoid): Caustics, amines, alkanolamines, aldehydes, ammonia, strong oxidizing agents, and chlorinated compounds. Hazardous Decomposition Products: Thermal decomposition may yield carbon monoxide, carbon dioxide, adehydes and keytones. Hazardous Polymerization: Will not occur.

SECTION 8 -- SPILL OR LEAK PROCEDURES Steps to be taken in case material is spilled or released: Remove ignition sources, evacuate area, avoid breathing vapors or contact with liquid. Recover free liquid or stop leak if possible. Dike large spills and use absorbent material for small spills. Keep spilled material out of sewers, ditches and bodies of water. Warn occupants and shipping in surrounding and downwind areas of fire and explosion hazard and request all to stay clear. Waste disposal method: Incinerate under safe conditions; dispose of in accordance with local, state and federal regulations.

SECTION 9 -- SAFE HANDLING AND USE INFORMATION Respiratory Protection: Where concentrations in air may exceed occupational exposure limits, NIOSH/MSHA approved respirators may be

necessary to prevent overexposure by inhalation. Ventilation: Exposure levels should be maintained below applicable exposure limits - see Section 2. This product should not be

used in confined spaces, or in a manner that will allow accumulation of high vapor concentrations. However, for controlled industrial uses when this product is used in confined spaces, heated above ambient temperatures or agitated, the use of explosion proof ventilation equipment is necessary.

Protective Gloves: Chemical resistant gloves (Neoprene or Natural Rubber). Eye Protection: Chemical safety goggles and a face shield. Other Protective Equipment: Impervious clothing or boots where needed, eyewash fecility and a safety shower.

SECTION 10 -- SPECIAL PRECAUTIONS Dept. of Labor Storage Category: Flammable Liquid-Class IB. Hygienic Practices: Keep away from heat, sparks and flame. Keep containers closed when not in use. Avoid eye contact. Avoid

prolonged or repeated contact with skin. Wash skin with soap and water after contact. Additional Precautions: Ground containers when transferring liquid to prevent static accumulation and discharge. Additional information

regarding safe handling of products with static accumulation potential can be ordered by contacting the American Petroleum Institute (API) for API Recommended Practice 2003, entitled "Protection Against Ignitions Arising Out of Static, Lighting, and Stray Currents" (American Petroleum Institute, 1720 L Street Northwest, Washington,DC 20005), or the National Fire Protection Association (NFPA) for NFPA 77 entitled "Static Electricity" (National Fire Protection Association, 1 Batterymarch Park, P.O. Box 9101, Quincy, MA 02269-9101).

Empty Container Warning: "Empty" containers retain residue (liquid and/or vapor) and can be dangerous. Do not pressurize, cut, weld, braze,

solder, drill, grind or expose such containers to heat, flame, sparks or other sources of ignition. They may explode and cause injury or death. Do not attempt to clean since residue is difficult to remove. "Empty" drums should be completely drained, properly bunged and promptly returned to supplier or disposed of in an environmentally safe manner and in accordance with governmental regulations.

Trade Name: ACETONE Page 3 of 3

SECTION 11 -- ADDITIONAL INFORMATION This product contains the following toxic chemical(s) which are subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: APPROXIMATE TOXIC CHEMICAL CAS # % BY WEIGHT NONE NONE NONE SARA Title III Hazard Categories: Immediate (Acute) Health, Delayed (Chronic)

Health, Fire

Common Names: 2-Propanone, Dimethylketone California Proposition 65: This product contains trace amounts of

Benzene, a chemical known to the State of California to cause cancer, and Toluene, a chemical known to the State of California to cause birth defects or other reproductive harm.

TRANSPORTATION (U.S. D.O.T. land transportation in packages of 119 gallons or less)

U.S. D.O.T. Proper Shipping Name: Acetone U.S. D.O.T. I.D Number: UN1090 U.S. D.O.T. Hazard Class: 3 U.S. D.O.T. Packing Group: II U.S. D.O.T. Hazardous Substance: Acetone, RQ 5000 lbs R fer to 49 CFR for additional information. Exceptions or exemptions may exist for smaller quantities. e

Common Name: DENATURED ALCOHOL SOLVENT

Manufacturer: SUNNYSIDE

MSDS Revision Date: 1/25/2006

Grainger Item Number(s): 5KPY5, 5KPY6

Manufacturer Model Number(s):

MSDS Table of ContentsClick the desired link below to jump directly to that section in the MSDS.

SECTION 1 SECTION 2 - HAZARDOUS INGREDIENTS SECTION 3 - EMERGENCY AND FIRST AID PROCEDURES SECTION 4 - PHYSICAL DATA SECTION 5 - FIRE AND EXPLOSION DATA SECTION 6 - HEALTH HAZARD DATA SECTION 7 - REACTIVITY DATA SECTION 8 - SPILL OR LEAK PROCEDURES SECTION 9 - SAFE HANDLING AND USE INFORMATION SECTION 10 - SPECIAL PRECAUTIONS SECTION 11 - ADDITIONAL INFORMATION

834


COMPLIES WITH OSHA HAZARD COMMUNICATION STANDARD 29 CFR 1910.1200

DATE OF PREP: 01/25/06

SECTION 1

Grainger MSDS Lookup http://complyplus.grainger.com/grainger/msds.asp?sheetid=3760008

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SUNNYSIDE CORPORATION225 CARPENTER AVENUEWHEELING, ILLINOIS 60090

EMERGENCY TELEPHONE:(800) 424-9300 CHEM TREC(847) 541-5700 SUNNYSIDE CORPORATION

FOR INFORMATION: (847) 541-5700

PRODUCT CLASS: ALCOHOL-MIXTURE

MANUFACTURER'S CODE: 834

TRADE NAME: DENATURED ALCOHOL SOLVENT

NPCA HMIS:HEALTH 1FIRE 3REACTIVITY 0

PRODUCT APPEARANCE AND ODOR:CLEAR, COLORLESS LIQUID; CHARACTERISTIC ALCOHOL ODOR.

SECTION 2 - HAZARDOUS INGREDIENTS

OCCUPATIONAL EXPOSURE LIMITS:

WT. ACGIH ACGIHINGREDIENT CAS # PERCENT TLV TLV (TWA) (STEL)

ETHYL ACETATE 141-78-6 1.0 400 PPM

ETHYL ALCOHOL 64-17-5 85.7 1000 PPM

SOLVENT NAPHTHA 64742-89-8 0.8 NOT EST.(PETROLEUM) LIGHTALIPHATIC

METHYL ISOBUTYL 108-10-1 1.9 50 PPM 75 PPMKETONE

METHYL ALCOHOL 67-56-1 3.6 200 PPM 250 PPM


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(SKIN)

INGREDIENT OSHA OSHA VAPOR PRESSURE PEL PEL (TWA) (STEL)

ETHYL ACETATE 400 PPM 86 MMHg @ 20 DEG. C

ETHYL ALCOHOL 1000 PPM 40 MMHg @ 55 DEG. F

SOLVENT NAPHTHA NOT EST. NOT KNOWN(PETROLEUM) LIGHTALIPHATIC

METHYL ISOBUTYL 50 PPM 75 PPM 0.75 MMHg @ 50 DEG. FKETONE

METHYL ALCOHOL 200 PPM 250 PPM 96 MMHg @ 20 DEG. C (SKIN)

SECTION 3 - EMERGENCY AND FIRST AID PROCEDURES

INGESTION:IF VICTIM IS CONSCIOUS AND ABLE TO SWALLOW, HAVE VICTIM DRINK WATER OR MILKTO DILUTE. NEVER GIVE ANYTHING BY MOUTH IF VICTIM IS UNCONSCIOUS OR HAVINGCONVULSIONS. CALL A PHYSICIAN OR POISON CONTROL CENTER IMMEDIATELY. INDUCEVOMITING ONLY IF ADVISED TO DO SO BY A PHYSICIAN OR POISON CONTROL CENTER.

INHALATION:IMMEDIATELY REMOVE VICTIM TO FRESH AIR. IF VICTIM HAS STOPPED BREATHING GIVEARTIFICIAL RESPIRATION. IF BREATHING IS DIFFICULT, GIVE OXYGEN. GET MEDICALATTENTION IMMEDIATELY.

EYE CONTACT:IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. IF EASY TODO, REMOVE CONTACT LENSES. GET MEDICAL ATTENTION. IN CASE OF IRRITATION FROMAIRBORNE EXPOSURE, MOVE TO FRESH AIR. GET MEDICAL ATTENTION IF SYMPTOMSPERSIST.

SKIN CONTACT:IMMEDIATELY FLUSH AFFECTED AREA WITH PLENTY OF COOL WATER. REMOVECONTAMINATED CLOTHING AND SHOES. GET MEDICAL ATTENTION IF SYMPTOMS OCCUR.WASH CONTAMINATED CLOTHING BEFORE REUSE. DESTROY OR THOROUGHLY CLEANCONTAMINATED SHOES.


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SECTION 4 - PHYSICAL DATA

THE FOLLOWING DATA REPRESENT APPROXIMATE OR TYPICAL VALUES. THEY DO NOTCONSTITUTE PRODUCT SPECIFICATIONS.

BOILING RANGE: 165 DEG. F. (I.B.P.)

VAPOR DENSITY: HEAVIER THAN AIR

EVAPORATION RATE: SLOWER THAN ETHER

% VOLATILE BY VOLUME: 100%

WEIGHT PER GALLON: 6.78 LBS.

SOLUBILITY IN WATER: APPRECIABLE

SECTION 5 - FIRE AND EXPLOSION DATA

FLAMMABILITY CLASSIFICATION: FLAMMABLE LIQUID - CLASS IB.

FLASH POINT: 41 DEG. F. TAG. CLOSED CUP

AUTOIGNITION TEMPERATURE: 795 DEG. F.

LOWER EXPLOSIVE LIMIT: 3.5% @ 77 DEG. F.

EXTINGUISHING MEDIA: WATER SPRAY, DRY CHEMICAL, CO2, "ALCOHOL" FOAM.

UNUSUAL FIRE AND EXPLOSION HAZARDS:FLAMMABLE. VAPORS MAY CAUSE A FLASH FIRE OR IGNITE EXPLOSIVELY. VAPORS MAYTRAVEL CONSIDERABLE DISTANCE TO A SOURCE OF IGNITION AND FLASH BACK. PREVENTBUILDUP OF VAPORS OR GASES TO EXPLOSIVE CONCENTRATIONS.

SPECIAL FIRE FIGHTING PROCEDURES:WEAR SELF-CONTAINED BREATHING APPARATUS AND PROTECTIVE CLOTHING TO PREVENTCONTACT WITH SKIN AND EYES. WATER MAY BE INEFFECTIVE FOR FIRE FIGHTING, USEWATER SPRAY TO KEEP FIRE-EXPOSED CONTAINERS COOL.

SECTION 6 - HEALTH HAZARD DATA


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THRESHOLD LIMIT VALUE: SEE SECTION 2.

EFFECTS OF EXPOSURE:

INHALATION:HIGH VAPOR CONCENTRATIONS MAY CAUSE UPPER RESPIRATORY TRACT IRRITATION ANDNARCOSIS (SLEEPINESS, DIZZINESS, ETC.)

EYE CONTACT: LIQUID OR VAPOR CAUSES IRRITATION.

SKIN CONTACT: MAY CAUSE IRRITATION AND DEFATTING OF SKIN ON PROLONGEDCONTACT.

INGESTION:CAN CAUSE DEPRESSION OF CENTRAL NERVOUS SYSTEM, NAUSEA, VOMITING, DIARRHEA.INDIVIDUAL RESPONSES TO METHYL ALCOHOL VARY. INGESTION OF LESS THAN 30 ML.HAS BEEN FATAL TO HUMANS. IN GENERAL, A FEW OUNCES MAY CAUSE BLINDNESS ANDDEATH; AS LITTLE AS 4 ML. MAY BE TOXIC IF INGESTED.

CARCINOGENICITY:COMPONENTS OF THIS PRODUCT HAVE NOT BEEN IDENTIFIED AS CARCINOGENS BY NTP,IARC OR OSHA.

SECTION 7 - REACTIVITY DATA

STABILITY: STABLE

CONDITIONS TO AVOID: KEEP AWAY FROM HEAT, SPARKS AND FLAME.

INCOMPATIBILITY (MATERIALS TO AVOID):OXIDIZING MATERIALS CAN CAUSE A VIGOROUS REACTION.

HAZARDOUS DECOMPOSITION PRODUCTS:COMBUSTION WILL PRODUCE CARBON DIOXIDE AND PROBABLY CARBON MONOXIDE.

HAZARDOUS POLYMERIZATION: WILL NOT OCCUR.

SECTION 8 - SPILL OR LEAK PROCEDURES

STEPS TO BE TAKEN IN CASE MATERIAL IS SPILLED OR RELEASED:


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ELIMINATE ALL IGNITION SOURCES. SMALL SPILLS MAY BE COLLECTED WITH ABSORBENTMATERIALS. FOR LARGE SPILLS FLUSH AREA WITH WATER SPRAY, PREVENT RUN OFFFROM ENTERING DRAINS, SEWERS OR STREAMS.

WASTE DISPOSAL METHOD:INCINERATE UNDER SAFE CONDITIONS, OBSERVE ALL FEDERAL, STATE AND LOCAL LAWSCONCERNING HEALTH AND ENVIRONMENT.

SECTION 9 - SAFE HANDLING AND USE INFORMATION

RESPIRATORY PROTECTION:AN APPROPRIATE NIOSH-APPROVED RESPIRATOR FOR ORGANIC VAPOR SHOULD BE WORN IFNEEDED.

VENTILATION:EXPOSURE LEVELS SHOULD BE MAINTAINED BELOW APPLICABLE EXPOSURE LIMITS - SEESECTION 2. THIS PRODUCT SHOULD NOT BE USED IN CONFINED SPACES, OR IN AMANNER THAT WILL ALLOW ACCUMULATION OF HIGH VAPOR CONCENTRATIONS. HOWEVER,FOR CONTROLLED INDUSTRIAL USES WHEN THIS PRODUCT IS USED IN CONFINED SPACES,HEATED ABOVE AMBIENT TEMPERATURES OR AGITATED, THE USE OF EXPLOSION PROOFVENTILATION EQUIPMENT IS NECESSARY.

PROTECTIVE GLOVES: SOLVENT RESISTANT PROTECTIVE GLOVES.

EYE PROTECTION:SAFETY GLASSES WITH SIDE SHIELDS SHOULD BE WORN IN ANY INDUSTRIAL OPERATION.WEAR A FULL-FACE RESPIRATOR, IF NEEDED.

OTHER PROTECTIVE EQUIPMENT:SAFETY SHOWER, EYE WASH, AND WASHING FACILITIES SHOULD BE AVAILABLE.

SECTION 10 - SPECIAL PRECAUTIONS

DEPT. OF LABOR STORAGE CATEGORY: FLAMMABLE LIQUID - CLASS IB.

HYGIENIC PRACTICES:KEEP AWAY FROM HEAT, SPARKS AND OPEN FLAME, KEEP CONTAINERS CLOSED WHEN NOTIN USE. AVOID EYE CONTACT. AVOID BREATHING MIST OR VAPOR. AVOID PROLONGED ORREPEATED CONTACT WITH SKIN. WASH SKIN WITH SOAP AND WATER AFTER CONTACT.

ADDITIONAL PRECAUTIONS:GROUND CONTAINERS WHEN TRANSFERRING LIQUID TO PREVENT STATIC ACCUMULATION


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AND DISCHARGE. ADDITIONAL INFORMATION REGARDING SAFE HANDLING OF PRODUCTSWITH STATIC ACCUMULATION POTENTIAL CAN BE ORDERED BY CONTACTING THE AMERICANPETROLEUM INSTITUTE (API) FOR API RECOMMENDED PRACTICE 2003, ENTITLED"PROTECTION AGAINST IGNITIONS ARISING OUT OF STATIC, LIGHTING, AND STRAYCURRENTS" (AMERICAN PETROLEUM INSTITUTE, 1720 L STREET NORTHWEST,WASHINGTON, DC 20005), OR THE NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)FOR NFPA 77 ENTITLED "STATIC ELECTRICITY" (NATIONAL FIRE PROTECTIONASSOCIATION, 1 BATTERYMARCH PARK, P.O. BOX 9101, QUINCY, MA 02269-9101).

EMPTY CONTAINER WARNING:"EMPTY" CONTAINERS RETAIN RESIDUE (LIQUID AND/OR VAPOR) AND CAN BEDANGEROUS. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OREXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION.THEY MAY EXPLODE AND CAUSE INJURY OR DEATH. DO NOT ATTEMPT TO CLEAN SINCERESIDUE IS DIFFICULT TO REMOVE. "EMPTY" DRUMS SHOULD BE COMPLETELY DRAINED,PROPERLY BUNGED AND PROMPTLY RETURNED TO SUPPLIER OR DISPOSED OF IN ANENVIRONMENTALLY SAFE MANNER AND IN ACCORDANCE WITH GOVERNMENTAL REGULATIONS.

SECTION 11 - ADDITIONAL INFORMATION

THIS PRODUCT CONTAINS THE FOLLOWING TOXIC CHEMICAL(S) WHICH ARE SUBJECT TOTHE REPORTING REQUIREMENTS OF SECTION 313 OF TITLE III OF THE SUPERFUNDAMENDMENTS AND REAUTHORIZATION ACT OF 1986 AND 40 CFR PART 372:

APPROXIMATETOXIC CHEMICAL CAS # % BY WEIGHT

METHANOL 67-56-1 3.6%

METHYL ISOBUTYL KETONE 108-10-1 1.9%

SARA TITLE III HAZARD CATEGORIES: FIRE HAZARD, IMMEDIATE (ACUTE) HEALTHHAZARD.

COMMON NAMES: DENATURED ETHYL ALCOHOL, "TECSOL" 3 SOLVENT, 95%

CALIFORNIA PROPOSITION 65:THIS PRODUCT CONTAINS CHEMICALS KNOWN TO THE STATE OF CALIFORNIA TO CAUSECANCER, AND BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM.

TRANSPORTATION (U.S. D.O.T. LAND TRANSPORTATION IN PACKAGES OF 119 GALLONSOR LESS):

U.S. D.O.T. PROPER SHIPPING NAME: ETHANOL SOLUTIONS


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U.S. D.O.T. HAZARD CLASS: 3

U.S. D.O.T. I.D. NUMBER: UN 1170

U.S. D.O.T. PACKAGING GROUP: II

HAZARDOUS SUBSTANCES:METHANOL RQ 5000 LBS.METHYL ISOBUTYL KETONE RQ 5000 LBS.

REFER TO 49 CFR FOR ADDITIONAL INFORMATION. EXCEPTIONS OR EXEMPTIONS MAYEXIST FOR SMALLER QUANTITIES.


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MSDS ID: 901004 11/04

JELMAR MATERIAL SAFETY DATA SHEET

TARN-X TARNISH REMOVER

Page 1 of 6

SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION Manufacturer: Jelmar Emergency Phone Number: 1(800) 323-5497 (USA) Address: 5550 W. Touhy Ave. Monday – Friday 8:30 A.M. – 4:30 P.M. CST Skokie, IL 60077 Emergency Contact: Chemtrec 1(800) 424-9300 Product Name: Tarn-X Rinse & Wipe MSDS ID: 901004 Chemical Family: Aqueous acidic surfactant solution Formula: Proprietary Mixture

SECTION 2 - HAZARDS IDENTIFICATION PHYSICAL STATE: Liquid COLOR: Clear, water white to slightly hazy ODOR: Chemical EMERGENCY OVERVIEW: Warning! Contains Sulfamic Acid and Thiourea. IRRITATING. TOXIC. HARMFUL OR FATAL IF SWALLOWED. Causes severe burns to eyes, skin and respiratory track. POTENTIAL HEALTH EFFECTS: ROUTES OF EXPOSURE: Eyes, Skin, Inhalation and Ingestion. TARGET ORGANS: Blood, liver, bone marrow, thyroid, reproductive system. Probable carcinogen and mutagen: Thiourea causes cancer in rats. Wash hands thoroughly after use. EYE CONTACT: Can cause blurred vision, redness, pain, severe tissue pain, and eye damage. Effects may vary depending on length of exposure, solution concentration, and first aid measures. SKIN CONTACT: Causes skin irritation. INHALATION: May cause mucous membranes and upper respiratory tract irritation. Symptoms may include burning sensation, coughing, wheezing, laryngitis, shortness of breath, headache, nausea, and vomiting. INGESTION: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause burns to the digestive tract. CHRONIC EFFECTS: Prolonged or repeated exposure may cause reproductive and fetal effects. Laboratory experiments have resulted in mutagenic effects. The International Agency for Research on Cancer (IARC) lists Thiourea as a 2B: Possibly Carcinogenic to Humans. The National Toxicological Program (NTP) lists Thiourea as a Group 2: Reasonably anticipated to be carcinogenic. MEDICAL CONDITIONS AGGRAVATED BY REPEATED OR PROLONGED EXPOSURE TO THE PRODUCT: Skin, eye, blood, liver, heart, and respiratory system disorders. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. DO NOT STORE WITH FOOD. KEEP OUT OF REACH OF CHILDREN.

MSDS ID: 901004 11/04



Page 2 of 6

SECTION 3 - COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS NUMBER OSHA Hazard % by Weight 1. Water 7732-18-5 No 85-95 2. Thiourea 62-56-6 Yes 5 - 7 3. Sulfamic Acid 5329-14-6 Yes 3 – 5 4. Disodium Cocoamphodiproprionate 68604-71-7 No <1.0 5. Methanol 67-56-1 Yes <0.05

SECTION 4 - FIRST AID MEASURES EYE CONTACT: In case of eye contact, immediately rinse eye thoroughly with plenty of water. Remove contact lenses and continue rinsing for at least 15 minutes. Get immediate medical attention. SKIN CONTACT: Can be irritating to skin, prolonged contact can be more severe, no adverse effects during normal usage. In case of skin contact, rinse area for at least 15 minutes. Remove contaminated clothing and shoes; wash thoroughly before reuse. Get immediate medical attention if irritation persists. INHALATION: Not a significant route of exposure. Remove to fresh air. If breathing is difficult, GET MEDICAL ATTENTION IMMEDIATELY. INGESTION: DO NOT induce vomiting. If fully conscious, drink 16 ounces of water. CALL A PHYSCIAN OR POISON CONTROL CENTER IMMEDIATELY. NEVER give an unconscious person anything to ingest,

SECTION 5 – FIRE FIGHTING MEASURES FLAMMABILTY: Not flammable FLASH POINT: None (104º C / 219º F): Method: TOC EXPLOSIVE LIMITS IN AIR: Not available EXTINGUISHING MEDIA: Not flammable. Use appropriate media for area. Water spray, dry chemical, alcohol foam or carbon dioxide, FIRE FIGHTING METHODS: Evacuate area of personnel. Wear protective NIOSH-approved self-contained breathing apparatus. Remain upwind of fire to avoid hazardous vapors and decomposition products. Use water spray to cool fire-exposed containers. Run-off of large quantities of product from fire control may cause pollution. Contact appropriate agencies. HAZARDOUS COMBUSTION PRODUCTS: Sulfur and Nitrogen Oxides, Ammonia, Carbon Dioxide and Carbon Monoxide. FIRE AND EXPLOSION HAZARDS: Large quantities of product may react with some metals, i.e. Aluminum Zinc, and Tin, to release flammable hydrogen gas.

SECTION 6 – ACCIDENTAL RELEASES MEASURES Steps to be taken in Case Material is Released Spilled: Avoid contact with skin and eyes. Small Spill: No special clean-up procedure is necessary for small (less than 1 gallon) spills. Flush spill area with water. Wear rubber gloves. Large Spill: Use personal protection recommended in Section 8. Isolate area and deny entry to unnecessary and unprotected personnel. Dam spill, and absorb with earth, sand or similar material. Place in non-leaking containers. Dispose of collected material according to local, state, and federal regulations. Flush residue with large amount of water. Avoid direct discharge to sewers and surface waters. Report any spill over 25 gallons, if direct discharge to sewers and surface waters has occurred to authorities.

MSDS ID: 901004 11/04



Page 3 of 6

SECTION 7- HANDLING AND STORAGE

STORAGE: Contains Sulfamic Acid and Thiourea. Store in cool, well-ventilated area, away from heat. Keep containers tightly closed. Avoid contact with combustible materials, wood, and organic materials. Store in original container in a secure area away from children and pets. DO NOT STORE NEAR FOOD. HANDLING: Avoid contact with eyes, skin or clothing. May be harmful or fatal if swallowed. Use with adequate ventilation. Avoid breathing vapors or mist. Do not eat, drink, or smoke in work area. Wash hand thoroughly after use. Consumer size containers (12 and 16 fluid ounces and gallon containers), should be rinsed and recycled. Empty 5gallon containers and 55gallon drums, may contain product residue in form of vapor, dried product, or liquid, and can be dangerous. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE THESE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY. DO NOT MIX WITH BLEACH, OR ANY OTHER PRODUCTS AS TOXIC FUMES MAY RESULT. DO NOT STORE WITH FOOD. KEEP OUT OF REACH OF CHILDREN.

SECTION 8 – EXPOSURE CONTROLS / PERSONAL PROTECTION VENTILATION REQUIREMENT: Avoid prolonged breathing mists or dusts of this product. Use with adequate ventilation. Do not use in closed or confined spaces. RESPIRATORY PROTECTION: If product is used in an industrial setting, respiratory protection must be worn if ventilation does not eliminate symptoms or keep levels below recommended exposure limits. If dust or mist is present, wear NIOSH-Approved respirator for mists and dusts, NIOSH-Approved self-contained breathing apparatus, NIOSH-Approved full-facepiece positive-pressure, air-supplied respirator. DO NOT exceed limits established by respirator manufacturer. Emergency responders should wear self-contained breathing apparatus (SCBA) to avoid inhalation of product. EYE PROTECTION: Not required during normal household usage. Industrial users wear safety goggles. Do not wear contact lenses. Emergency responders should wear full eye and face protection. SKIN PROTECTION: Rubber gloves with protective cuff. Emergency responders should wear impermeable gloves. OTHER PROTECTION: Emergency responders should wear chemical type (impermeable) protective clothing and footwear, where direct contact with chemicals in this product is possible. WORK/HYGIENIC PRACTICES: Wash thoroughly with soap and water after use or handling. EXPOSURE GUIDELINES: OSHA ACGIH COMPONENT PEL STEL/C TWA STEL/C

1. Water N.E. N.E. N.E. N.E. 2. Thiourea N.E. N.E. N.E. N.E. 3. Sulfamic Acid N.E. N.E. N.E. N.E. 4. Disodium Cocoamphodiproprionate N.E. N.E. N.E. N.E. 5. Methanol 200ppm N.E. s 200ppm s 250ppm

s 200 ppm + s 250ppm + (s) – Skin N.E. – Not Established

MSDS ID: 901004 11/04



Page 4 of 6

SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES

Boiling point: 103º C / 217º F Specific Gravity: 1.029 - 1.049 Freezing Point (ºF): N.D. Percent Volatiles: (WT%)~90 (Calculated) Melting Point (ºF): N.D. Evaporation Rate: N.D. (n-ethyl acetate=1) Vapor Pressure (MM HG): N.D. Solubility in Water: Soluble Vapor Density: N.D. VOC (WT%): <0.06 (Calculated) pH: 0.85 - 1.05 VOC (LBS/GAL): <005 (Calculated)

SECTION 10 – STABILITY AND REACTIVITY STABILITY: Stable under normal conditions. CONDITIONS TO AVOID: Avoid elevated temperatures. INCOMPATIBLE MATERIALS: Strong oxidizers, nitric acid, chlorine, acrolein, acrylaldehyde, strong bases, and hydrogen peroxide. HAZARDOUS DECOMPOSITION PRODUCTS: May emit ammonia and oxides of sulfur, nitrogen, and carbon. POSSIBILITY OF HAZARDOUS REACTIONS: May occur when in contact with acrylaldehyde.

SECTION 11 – TOXICOLOGICAL INFORMATION ACUTE ORAL EFFECTS: A dose of 5g / kg body weight was given to 5 male and 5 female rats; 10% mortality occurred within 14 days. The acute oral LD50 found to be > 5 g/kg. The product is not toxic by oral ingestion in accordance with FHSA / CPSC Guidelines. SKIN EFFECTS: Slightly irritating to rabbit skin. Draize Score: 0.71 out of 8.00. INHALHATION: N. E.

SECTION 12- ECOLOGICAL INFORMATION ECOTOXICOLOGICAL INFORMATION: Toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment. CHEMICAL FATE INFORMATION: 28-day biodegradation = 60%. The matter is biodegradable.

SECTION 13- DISPOSAL CONSIDERATIONS HAZARDOUS WASTE NUMBER: D002 DISPOSAL METHOD: Dispose of in a permitted hazardous waste management facility following all local, state, and federal regulations. DO NOT PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND OR EXPOSE CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. Follow label warnings, since containers may retain some reside of the product. Processing, use or contamination of this product may change the waste management options. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste identification and disposal methods in compliance with applicable regulations. State and local disposal regulations may differ from federal disposal regulations.

MSDS ID: 901004 11/04



Page 5 of 6

SECTION 14 - TRANSPORTATION INFORMATION

The following Transportation Information applies only to 12 fl oz, 16 fl oz, and 128 fl oz (1 Gallon) packaging: DOT (Department of Transportation Proper Shipping Name): ORM-D DOT Identification Number: N.A. Packaging Group: N.A. The following Transportation Information applies to 5gallon containers and 55gallon drums: DOT Proper Shipping Name: Corrosive Liquid, Toxic, N.O.S. (Contains Sulfamic Acid, Thiourea) Hazard Class: 8 Identification Number: UN2922 Packaging Group: III Label Required: Corrosive, Toxic Reportable Quantity (RQ): 10# Thiourea TDG Classification: Corrosive Liquid, Toxic, N.O.S. (Contains Sulfamic Acid, Thiourea) Class 8, UN2922, PG III IMDG Classification: Corrosive Liquid, Toxic, N.O.S. (Contains Sulfamic Acid, Thiourea) Class 8, UN2922, PG III, U219 IATA Classification: Passenger – NO; Cargo – YES; Packaging Instructions 820 [12fl oz, 16fl oz, and 128fl oz (1 Gallon) packaging] WHIMS (Canada): DIA, D1B, and D2A. This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all the information required by CPR.

SECTION 15 – REGULATORY INFORMATION FEDERAL REGULATIONS: TSCA INVENTORY STATUS: All components of this product are listed on the EPA/TSCA Inventory of Chemical Substances. SARA TITTLE III SECTION 311/312 CATEGORY: IMMEDIATE (ACUTE) HEALTH HAZARARD: YES DELAYED (CHRONIC) HEALTH HAZARD: YES FIRE HAZARD: NO SUDDEN RELEASE OF PRESSURE: NO REACTIVE HAZARD: NO SARA SECTIONS302/304/313/HAP: COMPENT RQ (LDS) RQ (LBS) TPQ (LBS) SEC 313 HAP (1*) (2*) (3*) (4*) (5*) 1. Water: N.A. N.A. N.A. NO NO 2. Thiourea: 10 N.A. N.A. YES NO 3. Sulfamic Acid: N.A. N.A. N.A. NO NO 4. Disodium Cocoamphodiproprionate: N.A. N.A. N.A. NO NO 5. Methanol: 5,000 N.A. N.A. YES YES

MSDS ID: 901004 11/04



Page 6 of 6

_______________________________REGULATORY AGENCIES________________________________ *1: CERCLA Reportable Quantity *2: SARA reportable Quantity *3: SARA EHS Threshold Planning Quantity

*4: SARA 313 Toxic Chemical/Category *5: U. S. EPA Hazardous Air Pollutant

INTERNATIONAL CHEMICAL INVENTORY STATUS: EUROPEAN UNION (EINECS) YES JAPAN (METI) YES AUSTRALIA (ACIS) YES KOREA (KECL) YES CANADA (DSL) YES CANADA (NDSL) NO PHILAPINES YES STATES RIGHT TO KNOW: California, New Jersey, Pennsylvania, Minnesota, Massachusetts, and Wisconsin. The following statement is made in order to comply with the California State Drinking Water Act. California Proposition 65: This product contains Thiourea known to the State of California to cause cancer and/or to cause birth defects and other reproductive harm.

SECTION 16 – OTHER INFORMATION NFPA Rating System: Health-2 Flammability-0 Reactivity-0 Precautions to be taken in Handling and Storing: Avoid exposure to excess heat and prevent from freezing. Other Precautions: None required. MSDS ABBREVIATIONS: N. A.: Not Applicable N. D.: Not Determined N.E.: Not Established C: Ceiling Limit HAP: Hazardous Air Pollutant VOC: Volatile Organic Compound Revision: Format Change ANSI Z400.1-2004 October 2004 R. A. Gaudreault Although the information and recommendations set forth herein are presented in good faith and believed to be correct as of the date hereof, JELMAR offers no representations as to the completeness or accuracy thereof. Information is provided upon the condition that the persons receiving it will make their own determination as to its suitability for their purposes prior to use. In no event will JELMAR be responsible for damages of any nature whatsoever resulting from use of or reliance upon said information. NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESSED OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE HEREUNDER WITH RESPECT TO INFORMATION OR THE PRODUCT TO WHICH INFORMATION HEREIN REFERS.

Archive Information

of 4

HMIS CodesHealth 2

Flammability 4Reactivity 0

DATE OF PREPARATIONApr 18, 2013


2000002 00

SECTION 1 — PRODUCT AND COMPANY IDENTIFICATION

PRODUCT NUMBER20000

PRODUCT NAMETRI-FLOW® Superior Lubricant with PTFE

MANUFACTURER'S NAMETHE SHERWIN-WILLIAMS COMPANYConsumer Group - IndustrialCleveland, OH 44115

Telephone Numbers and WebsitesProduct Information www.triflowlubricants.com

Regulatory Information (216) 566-2902www.paintdocs.com

Medical Emergency (216) 566-2917Transportation Emergency* (800) 424-9300

for Chemical Emergency ONLY (spill, leak, fire, exposure, or *

accident)

SECTION 2 — COMPOSITION/INFORMATION ON INGREDIENTS

% by Weight CAS Number Ingredient Units Vapor Pressure10 74-98-6 Propane

ACGIH TLV 1000 PPM 760 mmOSHA PEL 1000 PPM

10 106-97-8 ButaneACGIH TLV 1000 PPM 760 mmOSHA PEL 800 PPM

24 64742-47-8 Heavy Aliphatic SolventACGIH TLV Not Available 1.53 mmOSHA PEL Not Available

41 64742-52-5 Heavy Naphthenic Petroleum OilACGIH TLV 5 mg/m3 as MistOSHA PEL 5 mg/m3 as Mist

2 64741-97-5 Naphthenic OilACGIH TLV 5 mg/m3 as MistOSHA PEL Not Available

3 64742-65-0 Heavy Paraffinic OilACGIH TLV 5 mg/m3 as MistOSHA PEL 5 mg/m3 as Mist

2 34590-94-8 2-MethoxymethylethoxypropanolACGIH TLV 100 ppm (Skin) 0.4 mmACGIH TLV 150 ppm (Skin) STELOSHA PEL 100 ppm (Skin)OSHA PEL 150 ppm (Skin) STEL

2 628-63-7 Amyl AcetateACGIH TLV 100 PPM 4 mmOSHA PEL 100 PPM

SECTION 3 — HAZARDS IDENTIFICATION

ROUTES OF EXPOSUREINHALATION of vapor or spray mist.EYE or SKIN contact with the product, vapor or spray mist.

EFFECTS OF OVEREXPOSUREEYES: Irritation.SKIN: Prolonged or repeated exposure may cause irritation.

INHALATION: Irritation of the upper respiratory system.

20000

page 2 of 4

UEL14.0

LEL0.6

FLASH POINTPropellant < 0 °F

May cause nervous system depression. Extreme overexposure may result in unconsciousness and possibly death.SIGNS AND SYMPTOMS OF OVEREXPOSURE

Headache, dizziness, nausea, and loss of coordination are indications of excessive exposure to vapors or spray mists.Redness and itching or burning sensation may indicate eye or excessive skin exposure.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURENone generally recognized.

CANCER INFORMATIONFor complete discussion of toxicology data refer to Section 11.

SECTION 4 — FIRST AID MEASURES

EYES: Flush eyes with large amounts of water for 15 minutes. Get medical attention.SKIN: Wash affected area thoroughly with soap and water.

Remove contaminated clothing and launder before re-use.INHALATION: If affected, remove from exposure. Restore breathing. Keep warm and quiet.

INGESTION: Do not induce vomiting. Get medical attention immediately.

SECTION 5 — FIRE FIGHTING MEASURES

EXTINGUISHING MEDIACarbon Dioxide, Dry Chemical, Foam

UNUSUAL FIRE AND EXPLOSION HAZARDSContainers may explode when exposed to extreme heat.Application to hot surfaces requires special precautions.During emergency conditions overexposure to decomposition products may cause a health hazard. Symptoms may not be immediately

apparent. Obtain medical attention.SPECIAL FIRE FIGHTING PROCEDURES

Full protective equipment including self-contained breathing apparatus should be used.Water spray may be ineffective. If water is used, fog nozzles are preferable. Water may be used to cool closed containers to prevent pressure

build-up and possible autoignition or explosion when exposed to extreme heat.

SECTION 6 — ACCIDENTAL RELEASE MEASURES

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLEDRemove all sources of ignition. Ventilate the area.Remove with inert absorbent.

SECTION 7 — HANDLING AND STORAGE

STORAGE CATEGORYNot Available

PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGEKeep away from heat, sparks, and open flame. Vapors will accumulate readily and may ignite explosively.During use and until all vapors are gone: Keep area ventilated - Do not smoke - Extinguish all flames, pilot lights, and heaters - Turn off

stoves, electric tools and appliances, and any other sources of ignition.Consult NFPA Code. Use approved Bonding and Grounding procedures.Contents under pressure. Do not puncture, incinerate, or expose to temperature above 120F. Heat from sunlight, radiators, stoves, hot water,

and other heat sources could cause container to burst. Do not take internally. Keep out of the reach of children.

SECTION 8 — EXPOSURE CONTROLS/PERSONAL PROTECTION

PRECAUTIONS TO BE TAKEN IN USEUse only with adequate ventilation.Avoid contact with skin and eyes. Avoid breathing vapor and spray mist.Wash hands after using.

VENTILATIONLocal exhaust preferable. General exhaust acceptable if the exposure to materials in Section 2 is maintained below applicable exposure

limits. Refer to OSHA Standards 1910.94, 1910.107, 1910.108.RESPIRATORY PROTECTION

If personal exposure cannot be controlled below applicable limits by ventilation, wear a properly fitted organic vapor/particulate respirator approved by NIOSH/MSHA for protection against materials in Section 2.

PROTECTIVE GLOVESNone required for normal application of aerosol products where minimal skin contact is expected. For long or repeated contact, wear

chemical resistant gloves.EYE PROTECTION

Wear safety spectacles with unperforated sideshields.OTHER PRECAUTIONS

Intentional misuse by deliberately concentrating and inhaling the contents can be harmful or fatal.

20000

page 3 of 4

SECTION 9 — PHYSICAL AND CHEMICAL PROPERTIES

PRODUCT WEIGHT 6.50 lb/gal 778 g/lSPECIFIC GRAVITY 0.78

BOILING POINT <0 - 500 °F <-18 - 260 °CMELTING POINT Not Available

VOLATILE VOLUME 56%EVAPORATION RATE Faster than

etherVAPOR DENSITY Heavier than air

SOLUBILITY IN WATER Not AvailableVOLATILE ORGANIC COMPOUNDS (VOC Theoretical - As Packaged)

Volatile Weight 48.20% Less Water and Federally Exempt Solvents

SECTION 10 — STABILITY AND REACTIVITY

STABILITY — StableCONDITIONS TO AVOID

None known.INCOMPATIBILITY

None known.HAZARDOUS DECOMPOSITION PRODUCTS

By fire: Carbon Dioxide, Carbon MonoxideHAZARDOUS POLYMERIZATION

Will not occur

SECTION 11 — TOXICOLOGICAL INFORMATION

CHRONIC HEALTH HAZARDSNo ingredient in this product is an IARC, NTP or OSHA listed carcinogen.Reports have associated repeated and prolonged overexposure to solvents with permanent brain and nervous system damage.

TOXICOLOGY DATACAS No. Ingredient Name74-98-6 Propane

LC50 RAT 4HR Not AvailableLD50 RAT Not Available

106-97-8 ButaneLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-47-8 Heavy Aliphatic SolventLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-52-5 Heavy Naphthenic Petroleum OilLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64741-97-5 Naphthenic OilLC50 RAT 4HR Not AvailableLD50 RAT Not Available

64742-65-0 Heavy Paraffinic OilLC50 RAT 4HR Not AvailableLD50 RAT Not Available

34590-94-8 2-MethoxymethylethoxypropanolLC50 RAT 4HR Not AvailableLD50 RAT 5135 mg/kg

628-63-7 Amyl AcetateLC50 RAT 4HR Not AvailableLD50 RAT 6500 mg/kg

SECTION 12 — ECOLOGICAL INFORMATION

ECOTOXICOLOGICAL INFORMATIONNo data available.

20000

page 4 of 4

SECTION 13 — DISPOSAL CONSIDERATIONS

WASTE DISPOSAL METHODWaste from this product may be hazardous as defined under the Resource Conservation and Recovery Act (RCRA) 40 CFR 261.Waste must be tested for ignitability to determine the applicable EPA hazardous waste numbers.Do not incinerate. Depressurize container. Dispose of in accordance with Federal, State/Provincial, and Local regulations regarding pollution.

SECTION 14 — TRANSPORT INFORMATION

Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport (ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport.

US Ground (DOT)May be classed as LTD. QTY. OR ORM-DUN1950, AEROSOLS, 2.1, LIMITED QUANTITY, (ERG#126)

Canada (TDG)May be classed as LTD. QTY. OR ORM-DUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, (ERG#126)

IMOMay be shipped as Limited QuantityUN1950, AEROSOLS, CLASS 2.1, LIMITED QUANTITY, EmS F-D, S-U, ADR (D)

IATA/ICAOUN1950, AEROSOLS, FLAMMABLE, 2.1, LIMITED QUANTITY

SECTION 15 — REGULATORY INFORMATION

SARA 313 SUPPLIER NOTIFICATION(40 CFR 372.65C)CAS No. CHEMICAL/COMPOUND % by WT % Element

Barium Compound 2 0.06CALIFORNIA PROPOSITION 65

WARNING: This product contains a chemical known to the State of California to cause cancer.TSCA CERTIFICATION

All chemicals in this product are listed, or are exempt from listing, on the TSCA Inventory.

SECTION 16 — OTHER INFORMATION

This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR.

The above information pertains to this product as currently formulated, and is based on the information available at this time. Addition of reducers or other additives to this product may substantially alter the composition and hazards of the product. Since conditions of use are outside our control, we make no warranties, express or implied, and assume no liability in connection with any use of this information.

FOX VALLEY SYSTEMS INC -- TRIG-A-CAP MARKING PAINT ETSR2D, SUPERSTRIPE(SUPDAT) -- 8010-00N059803

===================== Product Identification =====================

Product ID:TRIG-A-CAP MARKING PAINT ETSR2D, SUPERSTRIPE(SUPDAT)MSDS Date:06/20/1994FSC:8010NIIN:00N059803MSDS Number: BXTRL=== Responsible Party ===Company Name:FOX VALLEY SYSTEMS INCAddress:640 INDUSTRIAL DRCity:CARYState:ILZIP:60013Country:USInfo Phone Num:708-639-5744Emergency Phone Num:708-639-5744CAGE:1BF99=== Contractor Identification ===Company Name:FOX VALLEY SYSTEMS INCAddress:640 INDUSTRIAL DRBox:City:CARYState:ILZIP:60013Country:USPhone:847-639-5744CAGE:1BF99

============= Composition/Information on Ingredients =============

Ingred Name:SOLVENT NAPHTHA; (PETROLEUM SOLVENT NAPHTHA, HEAVY AROMATIC)CAS:64742-94-5RTECS #:WF3100000Fraction by Wt: <1.0%OSHA PEL:N/K ACGIH TLV:N/K

Ingred Name:STODDARD SOLVENTCAS:8052-41-3RTECS #:WJ8925000Fraction by Wt: 5-15%OSHA PEL:500 PPMACGIH TLV:100 PPM

Ingred Name:PROPANECAS:74-98-6RTECS #:TX2275000Fraction by Wt: 10-20%OSHA PEL:1000 PPM

http://siri.org/msds/f2/bxt/bxtrl.html

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ACGIH TLV:ASPHYXIANT

Ingred Name:TOLUENE (SARA 313) (CERCLA)CAS:108-88-3RTECS #:XS5250000Fraction by Wt: 12-16%OSHA PEL:200 PPM; Z-2ACGIH TLV:50 PPM, SEPA Rpt Qty:1000 LBSDOT Rpt Qty:1000 LBS

Ingred Name:PROPANE, 2-METHYL-; (ISOBUTANE)CAS:75-28-5RTECS #:TZ4300000Fraction by Wt: 15-20%OSHA PEL:N/K ACGIH TLV:N/K

Ingred Name:SOLVENT NAPTHA (PETROLEUM), LIGHT ALIPHATIC; (PETROLEUM SOLVENT NAPHTHA(LIGHT ALIPHATIC))CAS:64742-89-8Fraction by Wt: 20-25%OSHA PEL:N/K ACGIH TLV:N/K

===================== Hazards Identification =====================

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.Routes of Entry: Inhalation:YES Skin:YES Ingestion:YESReports of Carcinogenicity:NTP:NO IARC:NO OSHA:NOHealth Hazards Acute and Chronic:EYES: MAY CAUSE IRRIT, REDNESS, TEARING, BLURRED VISION & CONJUNCTIVITIS. SKIN: PRLNGD/RPTD CONT MAY CAUSE MOD IRRIT & DEFATTING DERM. INHAL: EXCESS INHAL OF VAPS MAY CAUSE HDCHS, NAUS, DROW & IRRIT O F MUC MEMB OF NOSE & THROAT. INGEST: MAY CAUSE NAUSEA. NOTE: TOLUENE APPEARS ON THE NAVY LISTING OF (EFTS OF OVEREXP)Explanation of Carcinogenicity:NOT RELEVANT.Effects of Overexposure:HLTH HAZ: OCCUPATIONAL CHEMICAL REPRODUCTIVE HAZARDS. SEEK CONSULTATION FROM APPROPRIATE HEALTH PROFESSIONALS CONCERNING LATEST HAZARD LIST INFORMATION AND SAFE HANDLING & EXPOSURE INFORMATION .Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

======================= First Aid Measures =======================

First Aid:EYES: FLUSH W/WATER FOR AT LEAST 15 MINS, LIFTING UPPER & LOWER LIDS OCCAS, OBTAIN MED ATTN. SKIN: WASH CONTAMD AREA THORO W/SOAP & WATER. APPLY MOISTURIZING HAND CREAM. INHAL: REMOVE TO FRESH AIR. IF BRTHG IS DFCLT, ADMIN O*2 ONLY IF TRAINED, IF BRTHG HAS STOPPED GIVE ARTF RESP, PREF MOUTH-TO-MOUTH, KEEP PERS WARM, QUIET & OBTAIN MED ATTN. INGEST: ONLY INDUCE VOMIT AT INSTRUCTION OF MD. (SUPDAT)


2 of 4 7/16/13 5:53 PM

===================== Fire Fighting Measures =====================

Flash Point:-40F,-40CLower Limits:1.0%Upper Limits:8.5%Extinguishing Media:FOAM, CARBON DIOXIDE, DRY CHEMICAL.Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUIP. WATER MAY BE USED TO COOL CLSD CNTNRS TO PVNT PRESS BUILD-UP & POSS EXPLOSION WHEN EXPOSED TO EXTREME HEAT.Unusual Fire/Explosion Hazard:SPRAY MIST OR VAPORS FROM CAN PER 400 CUBIC FEET OF AIR MAY REACH LOWER EXPLOSIVE LIMIT & COULD BE IGNITED BY A FLAME SPARK.

================== Accidental Release Measures ==================

Spill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE AREA, WIPE UP W/INERT MATERIAL. DO NOT FLUSH INTO DRAINS. REMOVE RESIDUE W/SUITABLE SOLVENT CLEANER IMMEDIATELY.Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

====================== Handling and Storage ======================

Handling and Storage Precautions:DO NOT STORE AT TEMP >120F. EXPOSURE TO HIGH TEMPERATURES MAY CAUSE BURSTING. AVOID STORING NEAR RADIATOR, STOVE, OPEN FLAME OR DIRECT SUNLIGHT.Other Precautions:DO NOT INCINERATE OR PUNCTURE CAN. CONTENTS UNDER PRESSURE.

============= Exposure Controls/Personal Protection =============

Respiratory Protection:NOT NORMALLY NEEDED IF LOCAL EXHAUST IS SATISFACTORY. IF VENTILATION IS INADEQUATE, USE NIOSH/MSHA APPRVD RESPIRATORY MASK FOR PROTECTION AGAINST SPRAY MIST.Ventilation:REQUIREMENTS VARY W/RATE OF PROD USE. SUPPLEMENT VENT TO KEEP BELOW OSHA & ACGIH PERMISSIBLE LEVELS OF EACH INGREDIENT.Protective Gloves:SOLVENT RESISTANT GLOVES.Eye Protection:ANSI APPRVD CHEM WORKERS GOGGS.Other Protective Equipment:EMERGENCY EYEWASH & DELUGE SHOWER MEETING ANSI DESIGN CRITERIA.Work Hygienic Practices:WHEN USING THIS PRODUCT, DO NOT EAT, DRINK OR SMOKE.Supplemental Safety and HealthTRADENAME/PART #: ATHLETIC PAINT. SPEC GRAV: 0.86-0.958. MATL TO AVOID: METALS AND THEIR ALLOYS SUCH AS MAGNESIUM. FIRST AID PROC: KEEP PERSON WARM, QUIET AND OBTRAIN MED ATTN. NOTE: FOLLOWING A NY FIRST AID, MEDICAL ADVICE SHOULD BE OBTAINED, ESPECIALLY IF SYMPTOMS PERSIST.

================== Physical/Chemical Properties ==================

Vapor Density:HVR/AIR


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Spec Gravity:SUPDATEvaporation Rate & Reference:SLOWER THAN ETHERAppearance and Odor:NONE SPECIFIED BY MANUFACTURER.Percent Volatiles by Volume:70

================= Stability and Reactivity Data =================

Stability Indicator/Materials to Avoid:YESSTRONG OXIDIZING AGENTS, ALKALI & ALKALINE EARTH MTLS SUCH AS SODIUM, POTASSIUM & BARIUM. FINE POWDERS OF LIGHT(SUPDAT)Stability Condition to Avoid:HEAT, SPARKS & FIRE.Hazardous Decomposition Products:THERMAL DECOMPOSITION MAY YIELD CO, CO*2.

==================== Disposal Considerations ====================

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE W/LOCAL, STATE & FEDERAL LAWS. DO NOT PIERCE OR BURN CAN EVEN AFTER USE.

Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.


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SSaavvee TThhiiss MMSSDDSS

MMSSDDSS NNuummbbeerrBJHNJ

NNaattiioonnaall SSttoocckk NNuummbbeerr8010-00F013403

PPrroodduucctt NNaammeeYELLOW TACRY1 TRIG-A-CAP MARKING PAINT

MMaannuuffaaccttuurreerrFOX VALLEY SYSTEMS INC

PPrroodduucctt IIddeennttiiffiiccaattiioonnProduct ID:YELLOW TACRY1 TRIG-A-CAP MARKING PAINT

MSDS Date:07/17/1989

FSC:8010

NIIN:00F013403

MSDS Number: BJHNJ

RReessppoonnssiibbllee PPaarrttyyFOX VALLEY SYSTEMS, INC.

640 INDUSTRIAL DRIVE

CARY , IL 60013

Emergency Phone: (788) 639-5744

Info Phone: (788) 639-5744

Cage: 61527

Browse Data Sheets » Manufacturers » FOX VALLEY SYSTEMS INC » (BJHNJ) YELLOW TACRY1 TRIG-A-CAP MARKING PAINT

YELLOW TACRY1 TRIG-A-CAP MARKING PAINT by FOX VALLEY SYSTEMS INC Material... http://msdsreport.com/ds.cfm?msds=BJHNJ&name=YELLOW TACRY1 TRIG-A-CAP MARKIN...

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CCoonnttrraaccttoorrFOX VALLEY SYSTEMS, INC.

CARY, IL 60013-1948

(708) 639-5744

Cage: 61527

IInnggrreeddiieennttssBUTANE

CAS: 106-97-8

RTECS: EJ4200000

Fraction By Weight: 10-15%

OSHA PEL800 PPM

ACGIH TLV: 800 PPM; 9192

2-BUTOXYETHANOL

CAS: 111-76-2

RTECS: KJ8575000


OSHA PELS, 50 PPM

ACGIH TLV: S, 25 PPM; 9293

PROPANE

CAS: 74-98-6

RTECS: TX2275000


OSHA PEL1000 PPM

ACGIH TLV: ASPHYXIANT; 9192

TOLUENE (SARA III)

CAS: 108-88-3

RTECS: XS5250000


OSHA PEL200 PPM/150 STEL

ACGIH TLV: 50 PPM; 9293

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LIGHT ALIPHATIC NAPHTHA

CAS: 64742-89-8


OSHA PEL300 PPM

ACGIH TLV: 300 PPM


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XYLENES (O-,M-,P- ISOMERS) (SARA III)

CAS: 1330-20-7

RTECS: ZE2100000


OSHA PEL100 PPM/150 STEL

ACGIH TLV: 100 PPM/150STEL;9192

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

LEAD CHROMATE, CR, CHROME GREEN, CHROME YELLOW

CAS: 7758-97-6

RTECS: GB2975000


OSHA PEL0.5 MG/CUM PB

ACGIH TLV: 0.05 MG/CUM CR

HHaazzaarrddssRoutes of Entry: Inhalation:YES Skin:YES Ingestion:YES

Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO

Health Hazards Acute and Chronic:EYES: IRRITATION, REDNESS, TEARING,

BLURRED VISION, & CONJUNCTIVITIS. SKIN: MODERATE IRRITATION,

DEFATTING, & DERMATITIS. INHALATION: HEADACHES, NAUSEA, DROWSINESS,

IRRITATION OF THE MUCOUS MEMBRANE O F NOSE & THROAT, RESPIRATORY

IRRITATION, & ALLERGIC REACTION.

Explanation of Carcinogenicity:LEAD CHROMATE IS CONSIDERED TO BE A

SUSPECT CARCINOGEN.

Effects of Overexposure:INGESTION: DRIED FILM OF PAINT MAY BE

HARMFUL/FATAL & MAY CAUSE LEAD POISONING. INHALATION: SPRAY

MIST/SANDING DUST MAY CAUSE SEVERE BODILY HARM. EYES: IRRITATION,

REDNESS, TEARING, BLURRED VISION, & CONJUNCTIVITIS. SKIN:

DERMATITIS, MODERATE IRRITATION, & DEFATTING.

Medical Cond Aggravated by Exposure:ALLERGIC REACTION, DERMATITIS

FFiirrsstt AAiiddFirst Aid:EYES: FLUSH W/WATER FOR 15 MINUTES & OBTAIN MED ATTN. SKIN:

WASH CONTAMINATED AREA THOROUGHLY W/SOAP & WATER. INHALATION:

REMOVE INDIVIDUAL TO FRESH AIR. IF BREATHING IS DIFFICULT,

ADMINISTER OXYGEN O NLY IF TRAINED. IF BREATHING HAS STOPPED, GIVE

ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. OBTAIN MED ATTN.

INGESTION: INDUCE VOMITING AT THE INSTRUCTION OF A PHYSICIAN.

OBTAIN MED ATTN.


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FFiirree FFiigghhttiinnggFlash Point:-28F

Lower Limits:1.9%

Upper Limits:8.5%

Extinguishing Media:FOAM, CO2, DRY CHEMICAL

Fire Fighting Procedures:WEAR SELF-CONTAINED BREATHING APPARATUS & FULL

PROTECTIVE CLOTHING. WATER MAY BE USED TO COOL CLOSED CONTAINERS.

Unusual Fire/Explosion Hazard:PREVENT PRESSURE

BUILD-UP/AUTOIGNITION/EXPLOSION WHEN EXPOSED TO HEAT. SPRAY

MIST/VAPORS FROM ONE CAN PER 400 CU FT OF AIR MAY REACH LEL.

EXTREMELY FLAMMABLE.

AAcccciiddeennttaall RReelleeaasseeSpill Release Procedures:REMOVE ALL SOURCES OF IGNITION, VENTILATE

AREA, WIPE UP W/INERT MATERIAL.

HHaannddlliinnggHandling and Storage Precautions:CONTENTS UNDER PRESSURE. EXPOSURE TO

HIGH TEMPERATURES MAY CAUSE BURSTING. DON'T INCINERATE OR PUNCTURE

CAN. DON'T STORE AT TEMPS >120 F.

EExxppoossuurree CCoonnttrroollssRespiratory Protection:IF VENTILATION IS INADEQUATE, USE RESPIRATORY

MASK APPROVED BY NIOSH/MESA FOR PROTECTION AGAINST SPRAY MIST. NOT

NORMALLY NEEDED IF LOCAL EXHAUST IS SATISFACTORY.

Ventilation:PROVIDE ADEQUATE LOCAL EXHAUST VENTILATION TO KEEP Protective Gloves:NOT MANDATORY

Eye Protection:RECOMMENDED

Work Hygienic Practices:PRACTICE GOOD HYGIENE, HOUSEKEEPING, & HANDLING

PRACTICES WHEN WORKING W/THIS PRODUCT.

Supplemental Safety and Health

WT/GAL: 8.5-9.5 LBS.

CChheemmiiccaall PPrrooppeerrttiieessVapor Density:>AIR

Evaporation Rate & Reference:SLOWER THAN ETHER

Appearance and Odor:YELLOW PAINT

Percent Volatiles by Volume:70%

SSttaabbiilliittyyStability Indicator/Materials to Avoid:YES

Stability Condition to Avoid:HEAT, SPARKS, RADIATOR, OPEN FLAME, DIRECT

SUNLIGHT, RADIATOR, STOVE, HIGH TEMPS >120F, SOURCES OF IGNITION

Hazardous Decomposition Products:CO, CO2


4 of 5 7/22/13 4:53 PM

© msds report. All rights reserved. Terms And Conditions

DDiissppoossaallWaste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, &

FEDERAL REGULATIONS. DON'T INCINERATE OR PUNCTURE CAN.

Disclaimer (provided with this information by the compiling agencies):

This information is formulated for use by elements of the Department

of Defense. The United States of America in no manner whatsoever,

expressly or implied, warrants this information to be accurate and

disclaims all liability for its use. Any person utilizing this

document should seek competent professional advice to verify and

assume responsibility for the suitability of this information to their

particular situation.


5 of 5 7/22/13 4:53 PM

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GENERAL PAINT & CHEMICALS -- TRU-TEST SUPREME XO-RUST ALUMINUM & (SUPP D -- 8010-00N020477 ======================================================= MSDS Safety Information ======================================================= FSC: 8010 MSDS Date: 07/24/1990 MSDS Num: BLHXQ LIIN: 00N020477 Tech Review: 08/01/1995 Product ID: TRU-TEST SUPREME XO-RUST ALUMINUM & (SUPP D Responsible Party Cage: GENEA Name: GENERAL PAINT & CHEMICALS Address: 201 JANDUS ROAD City: CARY IL 60013 US Info Phone Number: 708-639-5383 Emergency Phone Number: 800-228-5635 Review Ind: N ======================================================= Contractor Summary ======================================================= Cage: GENEA Name: GENERAL PAINT & CHEMICAL Address: 201 JANDUS ROAD City: CARY IL 60013 Country: NK Phone: (312) 639-5383 ======================================================= Ingredients ======================================================= Cas: 64742-88-7 Name: MINERAL SPIRITS. VP: 2.0@20C. % by Wt: 42-47 OSHA PEL: 500 PPM ACGIH TLV: 200 PPM Ozone Depleting Chemical: N ------------------------------ Cas: 108-88-3 RTECS #: XS5250000 Name: TOLUENE (SARA III) % by Wt: <5 OSHA PEL: 200 PPM/150 STEL ACGIH TLV: 50 PPM; 9293 EPA Rpt Qty: 1000 LBS DOT Rpt Qty: 1000 LBS Ozone Depleting Chemical: N ------------------------------ Cas: 111-76-2 RTECS #: KJ8575000 Name: 2-BUTOXYETHANOL % by Wt: 21-26 OSHA PEL: S, 50 PPM ACGIH TLV: S, 25 PPM; 9293 Ozone Depleting Chemical: N ------------------------------ Cas: 141-78-6

RTECS #: AH5425000 Name: ETHYL ACETATE (SARA III) % by Wt: 20-25 OSHA PEL: 400 PPM ACGIH TLV: 400 PPM; 9192 EPA Rpt Qty: 5000 LBS DOT Rpt Qty: 5000 LBS Ozone Depleting Chemical: N ======================================================= Health Hazards Data ======================================================= LD50 LC50 Mixture: NONE SPECIFIED BY MANUFACTURER. Route Of Entry Inds - Inhalation: YES Skin: YES Ingestion: NO Carcinogenicity Inds - NTP: NO IARC: NO OSHA: NO Effects of Exposure: SEVERE EYE IRRITATION, DRYING OF SKIN, EXCESSIVE INHALATION CAUSES HEADACHE, DIZZINESS AND NAUSEA. Explanation Of Carcinogenicity: NOT RELEVANT. Signs And Symptions Of Overexposure: SEE HEALTH HAZARDS. Medical Cond Aggravated By Exposure: NONE KNOWN TO GENERAL PAINT AND CHEMICAL CO. First Aid: EYE: WASH WITH WATER FOR AT LEAST 15 MIN. SKIN: WASH WITH WARM SOAP AND WATER. INHAL: REMOVE TO FRESH AIR. APPLY ARTF RESP IF NECESSARY. GET MED ATTN. INGEST: DO NOT INDUCE VOMIT. KEEP PERSON WARM AND QUIET. GET MED ATTN. ======================================================= Handling and Disposal ======================================================= Spill Release Procedures: ELIMINATE ALL IGNITION SOURCES. CONTAIN SPILL, ABSORB LIQUID CLAY, SAND OR FLOOR ABSORBENT. PREVENT RUN-OFF TO SEWERS, STREAMS OR OTHER BODIES OF WATER. Neutralizing Agent: NONE SPECIFIED BY MANUFACTURER. Waste Disposal Methods: CONTAMINATED ABSORBENT MAY BE DEPOSITED IN A LANDFILL IN ACCORDANCE WITH LOCAL, STATE AND FEDERAL REGULATIONS. Handling And Storage Precautions: KEEP AWAY FROM HEAT SPARKS AND OPEN FLAMES. FOR STORAGE CONDITIONS SEE OSHA 1910.106. Other Precautions: DO NOT TAKE INTERNALLY. AVOID PROLONGED CONTACT WITH SKIN. CONTAINERS SHOULD BE GROUNDED WHEN POURING. AVOID FREE FALL OF MORE THAN 2-3 INCHES WHEN POURING. ======================================================= Fire and Explosion Hazard Information ======================================================= Flash Point Text: <20F,<-7C Extinguishing Media: FOAM, CO2, DRY CHEMICAL, WATER FOG. Fire Fighting Procedures: WEAR NIOSH/MSHA APPRVD SCBA & FULL PROT EQUI(FP N). TREAT AS VOLATILE FIRE. H2O SPRAY MAY BE INEFT. IF H2O SPRAY IS USED, FOG NOZZLES ARE PREFERRABLE. Unusual Fire/Explosion Hazard: CLOSED CONTAINERS MAY EXPLODE WHEN EXPOSED

TO EXTREME HEAT. ISOLATE FROM HEAT, SPARKS AND OPEN FLAME. ======================================================= Control Measures ======================================================= Respiratory Protection: NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR IF TLV LIMITS ARE EXCEEDED. APPROVED MECHANICAL FILTER TO REMOVE SOLID AIRBORNE PARTICLES OF OVERSPRAY DURING SPRAY APPLICATION. Ventilation: PROVIDE SUFFICIENT MECHANICAL(GENERAL AND/OR LOCAL EXHAUST) VENTILATION TO MAINTAIN EXPOSURE BELOW TLV. Protective Gloves: IMPERVIOUS GLOVES (FP N). Eye Protection: CHEMICAL WORKERS GOGGLES (FP N). Other Protective Equipment: IMPERVIOUS CLOTHING AND BOOTS. Work Hygienic Practices: WASH HANDS BEFORE EATING, SMOKING OR USING BATHROOM. DO NOT REUSE CONTAMINATED CLOTHING. Supplemental Safety and Health: MFR TRADE NAME/PART NO:GALVANIZED METAL PRIMER. ======================================================= Physical/Chemical Properties ======================================================= HCC: F2 B.P. Text: 170F,77C Vapor Density: HEAVIER Evaporation Rate & Reference: SLOWER THAN ETHER Appearance and Odor: NONE SPECIFIED BY MANUFACTURER. Percent Volatiles by Volume: 95 ======================================================= Reactivity Data ======================================================= Stability Condition To Avoid: ISOLATE FROM HEAT AND OPEN FLAME. Materials To Avoid: AVOID CONTACT WITH STRONG OXIDIZING AGENTS. Hazardous Decomposition Products: CARBON DIOXIDE, CARBON MONOXIDE. Conditions To Avoid Polymerization: NONE SPECIFIED BY MANUFACTURER. ======================================================= Toxicological Information ======================================================= ======================================================= Ecological Information ======================================================= ======================================================= MSDS Transport Information ======================================================= ======================================================= Regulatory Information ======================================================= ======================================================= Other Information ======================================================= ======================================================= Transportation Information ======================================================= Responsible Party Cage: GENEA Trans ID NO: 25143 Product ID: TRU-TEST SUPREME XO-RUST ALUMINUM & (SUPP D MSDS Prepared Date: 07/24/1990

Review Date: 12/16/1991 Article W/O MSDS: N Multiple KIT Number: 0 Unit Of Issue: NK Container QTY: NK ======================================================= Detail DOT Information ======================================================= DOT PSN Code: GJF Symbols: G DOT Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. Hazard Class: 3 UN ID Num: UN1993 DOT Packaging Group: I Label: FLAMMABLE LIQUID Special Provision: T42 Non Bulk Pack: 201 Bulk Pack: 243 Max Qty Pass: 1 L Max Qty Cargo: 30 L Vessel Stow Req: E ======================================================= Detail IMO Information ======================================================= IMO PSN Code: HIM IMO Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. o IMDG Page Number: 3126 UN Number: 1993 UN Hazard Class: 3.1 IMO Packaging Group: I/II Subsidiary Risk Label: - EMS Number: 3-07 MED First Aid Guide NUM: T ======================================================= Detail IATA Information ======================================================= IATA UN ID Num: 1993 IATA Proper Shipping Name: FLAMMABLE LIQUID, N.O.S. * IATA UN Class: 3 IATA Label: FLAMMABLE LIQUID UN Packing Group: I Packing Note Passenger: 302 Max Quant Pass: 1L Max Quant Cargo: 30L Packaging Note Cargo: 303 Exceptions: A3 ======================================================= Detail AFI Information ======================================================= AFI Symbols: * AFI Proper Shipping Name: FLAMMABLE LIQUIDS, N.O.S. AFI Hazard Class: 3 AFI UN ID NUM: UN1993 AFI Packing Group: I Special Provisions: P3 Back Pack Reference: A7.3 =======================================================

HAZCOM Label ======================================================= Product ID: TRU-TEST SUPREME XO-RUST ALUMINUM & (SUPP D Cage: GENEA Company Name: GENERAL PAINT & CHEMICAL Street: 201 JANDUS ROAD City: CARY IL Zipcode: 60013 Country: NK Health Emergency Phone: 800-228-5635 Date Of Label Review: 10/29/1991 Label Date: 10/29/1991 Chronic Hazard IND: N Eye Protection IND: YES Skin Protection IND: YES Signal Word: DANGER Respiratory Protection IND: YES Health Hazard: Moderate Contact Hazard: Severe Fire Hazard: Severe Reactivity Hazard: None Hazard And Precautions: FLAMMABLE LIQUID.ACUTE: CAUSES SEVERE EYE IRRITATION, DRYING OF SKIN. EXCESSIVE INHALATION CAUSES HEADACHE, DIZZINESS AND NAUSEA. CHRONIC: NONE LISTED BY MANUFACTURER. ======================================================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever expressly or implied warrants, states, or intends said information to have any application, use or viability by or to any person or persons outside the Department of Defense nor any person or persons contracting with any instrumentality of the United States of America and disclaims all liability for such use. Any person utilizing this instruction who is not a military or civilian employee of the United States of America should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation regardless of similarity to a corresponding Department of Defense or other government situation.

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