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    ASSIGNMENT 3: REPORT REVIEW

    I nvestigation of Oi l Remediation Options for Shallow Water Shipwrecks in Newfoundland

    Waters

    Prepared by: Kevin Strowbridge (008801383)

    MSTM-410B

    Bachelor of Technology

    Memorial University of Newfoundland

    Supervisor: Ken Baker

    Facilitator: Aaron Peach

    Revision 4

    November 9, 2015

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    Letter of Transmittal

    155 Ridge Road

    St. Johns, Newfoundland A1B 3S7

    November 9, 2015

    Program CommitteeBachelor of Technology Program

    Marine Institute of Memorial University of Newfoundland

    P. O. Box 4920

    St. Johns, Newfoundland A1C 5R3

    Dear Program Committee:

    In response to your request on September 8, 2015, I have prepared the following report entitled

    Investigation of Oil Remediation Options for Shallow Water Shipwrecks in Newfoundland.This report completes the requirements of both the MSTM 410A and MSTM 410B B-Techcourses.

    My research into the field of shipwreck salvage and oil remedial methods has proved to be a veryrewarding experience. I hope that my report will help to raise awareness of the environmental

    dangers posed by shallow water shipwrecks and provide information on the best methods

    currently available to preform oil remediation of shallow water shipwrecks in Newfoundland

    waters. Additionally, I hope to be able to help theManolis L. Citizens Response Committee byproviding them with information that they can use in their attempts to persuade the Canadian

    federal government to remove the oil from theManolis L. shipwreck.

    I wish to thank my project supervisor, Mr. Ken Baker, my MSTM 410A instructor, ChristopherMcCulloch, my MSTM 410B instructor, Aaron Peach, and my editors, Christine Strowbridge

    and Tracey OKeefe.

    Should you have any questions about this report, you may contact me at

    [email protected]. I look forward to your feedback.

    Sincerely,

    __________________Kevin Strowbridge

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    i

    List of Revisions

    Revision Description Date

    0 Proposal issued for facilitator review July 16, 2015

    1Incorporated facilitator feedback and comments and re-

    issued the proposalAug 13, 2015

    2 Proposal updated and issued for facilitator review Sept 18, 2015

    3 Incorporated facilitator feedback and issued the Introduction Oct 9, 2015

    4Incorporated facilitator feedback and issued full report for

    supervisor and facilitator reviewNov 9, 2015

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    INVESTIGATION OF OIL REMEDIATION OPTIONS Page ii

    Executive Summary

    Shallow water shipwrecks, which, for the purpose of this report, are defined as those

    wrecks within the 50 meter range of water depth, in Newfoundland (NL) waters contain

    hazardous substances, such as petroleum-based oils. Petroleum products that seep from

    shipwrecks are devastating to the environment as they are insoluble in water, toxic, and

    corrosive. The effects of oil spills from shipwrecks depend on several factors, such as the type

    and amount of oil on board at the time of sinking, the characteristics of the affected environment,

    the water temperature and depth, shipwreck location, the condition of the ship at the time of

    sinking, and the length of time the wreck has been submerged. Currently, there are no

    comprehensive methods for environmental risk assessment of shallow water shipwrecks in NL

    waters; which causes difficulty on prioritization for remediation options. Additionally, not all

    available actions can be taken to minimize or eliminate the environmental risks from these

    potentially polluting shipwrecks due to their lack of their applicability and functionality.

    The marine industry utilizes several types of petroleum products; the most common being

    Marine Diesel Oil (MDO), a light distillate fuel, and Heavy Fuel Oil (HFO), a thick residual fuel.

    Three physical properties of these fuels, viscosity, the temperature sensitive measure of a fuels'

    resistance to flow, density, the mass per unit of volume, and specific gravity, the ratio between

    the density of an object and a reference substance, need to be considered when assessing

    shipwrecks. These determine the ability of fuels to flow from a shipwreck and the flow rate of

    leakages.

    The physical properties of petroleum products must be assessed along with the

    environmental conditions in the vicinity of the shipwreck. Since viscosity and density are

    temperature dependent, the annual temperature cycle at selected depths must be investigated in

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    INVESTIGATION OF OIL REMEDIATION OPTIONS Page iii

    order to determine how the petroleum products can be expected to behave. At 50 meters,

    temperatures are in the range of -2 to +2 deg C. The densest marine fuel, HFO, remains in a near

    solid state with a maximum specific gravity of 0.98 at these temperatures, however, its density is

    less than the salt water specific gravity of 1.025, which means it can float.

    In order to make an informed decision as to which oil remedial options should be

    employed, the structural condition of the shipwreck must be assessed. There is sufficient data

    available to allow for accurate steel corrosion rate estimate calculations to be performed. These

    calculations can help with the risk assessment and shipwreck management decision-making

    process. The approximate rate of corrosion in seawater is 0.1 mm/year, however, this rate can

    more than double due to wave energy at the surface. Hull plates are generally thick on ships, but,

    internal holding tanks and plumbing, ducts and vents are substantially thinner and are often the

    first areas to collapse. This can lead to breakup of the hull, which will allow the oil to escape.

    Many oil remedial technologies have been successful globally, such as recovery of the

    entire wreck, sealing the leaking points and using cofferdams, controlled release of pollutants,

    pumping of pollutants from the shipwreck, capping of the entire wreck or of the cargo, or

    shipwreck monitoring. Not all of these oil remedial technologies, however, are suitable for use in

    Newfoundland shallow water shipwrecks.

    The seriousness of a spill does not depend solely on the volume of oil; other factors, such

    as location of shipwreck, physical properties of the oil or other pollutants, prevailing marine

    conditions and sensitivities of the environment must be assessed. It is essential to undertake an

    assessment of both the areas under threat and condition of the shipwreck in order to better

    understand the possible consequences of a spill. Shipwreck risk assessment requires an

    interdisciplinary approach covering analysis of the shipsconstruction, historical data about the

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    ship and documentation from the time of wreckage, corrosion rates, environmental status at the

    wreck site, and environmental effects of the hazardous substance(s) onboard. Risks that have

    severe consequences and a high probability of occurring require a mitigation plan.

    By utilizing theManolis Lshipwreck as a case study, risk factors, such as the corrosion

    rates of steel and risk level, were estimated and a shipwreck risk and remedial options matrix

    developed that can aid in the prioritization of remediation and environmental response options.

    TheManolis Lwas evaluated using all of the analysis methods as laid out in this report and this

    demonstrated the functionality of these methods as applied to an actual shipwreck. The risk score

    was calculated, the level of consequences was determined and a recommendation for an oil

    remediation option for this shipwreck was put forth.

    This report's main recommendations are for decision-makers in the shipwreck oil

    remediation process to consider the corrosion rate of steel as part of a shipwreck risk matrix, the

    creation of a rubric and matrix to analyze each oil remedial option to determine which are best

    suited for shallow water shipwrecks in NL waters, and that the Canadian government should

    immediately remove the oil from the Manolis L shipwreck or cap the entire shipwreck as

    determined by the risk analysis.

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    v

    Table of Contents

    List of Revisions .............................................................................................................................. i

    Executive Summary ........................................................................................................................ ii

    List of Illustrations ........................................................................................................................ vii

    1.0 Introduction ............................................................................................................................... 1

    1.1 Project Purpose ................................................................................................................... 1

    1.2 Background ......................................................................................................................... 1

    1.3 Scope ................................................................................................................................... 3

    1.4 Methodology ....................................................................................................................... 4

    2.0 Properties of Common Marine Petroleum Products ............................................................... 5

    3.0 Environmental Conditions Data for Newfoundland ............................................................... 7

    4.0 Steel Degradation of Shipwrecks .......................................................................................... 105.0 Oil Remedial Technologies................................................................................................... 13

    5.1 Recovery of the Entire Wreck........................................................................................... 13

    5.2 Sealing the Leaking Points and Using Cofferdams .......................................................... 14

    5.3 Controlled Release of Pollutants ....................................................................................... 15

    5.4 Pumping of Pollutants from the Shipwreck ...................................................................... 15

    5.5 Capping of the Entire Wreck or of the Cargo ................................................................... 16

    5.6 Shipwreck Monitoring ...................................................................................................... 16

    5.7 Summary of Oil Remedial Options................................................................................... 17

    6.0 Shipwreck Risk Analysis Matrix .......................................................................................... 18

    6.1 Shipwreck Remediation Decision Process........................................................................ 18

    6.2 Definition of Risk Factors and Weights Classes ............................................................... 20

    6.2.1 Vessel Type / Tonnage............................................................................................... 21

    6.2.2 Volume of Pollutants ................................................................................................. 21

    6.2.3 Distance from Coast or a Sensitive Area ................................................................... 22

    6.2.4 Environmental Conditions ......................................................................................... 22

    6.2.5 Age and Condition of Shipwreck ............................................................................... 23

    6.3 Risk Analysis .................................................................................................................... 24

    6.3.1 Calculation of Risk Factors ........................................................................................ 24

    6.3.2 Risks with Impacts and Rationales ................................................................................ 25

    6.3.3 Calculating the Risk Score ......................................................................................... 27

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    6.4 Risk Mitigation Strategies................................................................................................. 28

    7.0 Case Study:Manolis L.......................................................................................................... 29

    7.1 Environmental Conditions Data at the Shipwreck Site..................................................... 30

    7.2 Steel Degradation Calculations ......................................................................................... 31

    7.2.1 Verification of the Calculations ................................................................................. 32

    7.3 Risk Factors ...................................................................................................................... 34

    7.4 Calculation of the Risk Score ........................................................................................... 34

    7.5 Recommendation for Appropriate Risk Mitigation Strategies ......................................... 35

    8.0 Conclusions ........................................................................................................................... 36

    9.0 Recommendations ................................................................................................................. 37

    References ..................................................................................................................................... 38

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    vii

    List of Illustrations

    Figures

    Figure 1-1:Manolis LPrior to Sinking

    Figure 2-1: Bunker C Oil

    Figure 3-1: Annual Temperature and Salinity Anomalies at Selected Depths (Top Panels)

    and Their Decadal Means (Bottom Panels)

    Figure 4-1: Effect of Current Velocity on Steel Corrosion Rate

    Figure 4-2: Field Results of Steel Corrosion Rates

    Figure 4-3: Coating and Steel Degradation Rates

    Figure 5-1: Recovery of the Entire Wreck

    Figure 5-2: Leak-Sealing Operations

    Figure 5-3: Cofferdam on theManolis L

    Figure 5-4: Recovering Oil with Booms

    Figure 5-5: Hot-Tapping

    Figure 5-6: Shipwreck Capping

    Figure 5-7: Sonar Image of theManolis L

    Figure 6-1: The Basic Structure of the Decision-Making-Process

    Figure 7-1:Manolis LPrior to Sinking

    Figure 7-2: Notre Dame Bay, Newfoundland

    Figure 7-3 Hull Thickness Survey Results As Measured In 2014 with Measurement

    Locations

    Figure 7-4: Steel Demonstration Piece of Steel Thickness Measured on the Manolis L

    Tables

    Table 2-1: Physical Properties of Marine Oils

    Table 3-1: Results of Various Pressure Conditions at the Shipwreck

    Table 5-1: Summary of Oil Remedial Options

    Table 6-1: Risk Factor Weights for Vessel Type and Tonnage

    Table 6-2: Risk Factor Weights for Volume of Pollutants

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    Table 6-3: Risk Factor Weights for Distance from Coast or a Sensitive Area

    Table 6-4: Risk Factor Weights for Environmental Conditions

    Table 6-5: Risk Factor Weights for Age and Condition of Shipwreck

    Table 6-6 Calculation of Risk FactorsTable 6-7: Risk Events with Impacts and Rationales

    Table 6-8: Qualitative Risk Classification

    Table 6-9: Risk Classification

    Table 6-10: Determination of the Risk Score

    Table 6-11: Risk Mitigation Strategies

    Table 7-1: Structural Steel Corrosion for theManolis L

    Table 7-2: Structural Steel Strength Reductions Due To Corrosion for theManolis L

    Table 7-3: Average Hull Thickness

    Table 7-5: Calculation of the Risk Score for theManolis L

    Table 7-6: Recommended Risk Mitigation Strategies for theManolis L

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    INVESTIGATION OF OIL REMEDIATION OPTIONS Page 1 of 41

    1.0 Introduction

    1.1 Project Purpose

    The purpose of this report is to develop a tool for quantitative risk and remedial options

    assessment of potentially polluting shallow water shipwrecks in Newfoundland (NL) waters.

    This report examines current shipwreck oil remedial options to determine which is best suited for

    shallow water shipwrecks in NL waters. By utilizing the Manolis L shipwreck as a case study,

    risk factors, such as the corrosion rates of steel, can be estimated and a shipwreck risk and

    remedial options matrix developed that can aid in the prioritization of remediation and

    environmental response options.

    1.2 Background

    Shallow water shipwrecks, which, for the purpose of this report, are defined as those

    wrecks within the 50 meter range of water depth, in NL waters contain hazardous substances,

    such as petroleum-based oils, that can cause harm to the marine environment. Oil spills from

    shipwrecks pose a danger to flora and fauna and cause damage to sea and shore ecosystems.

    Many of the petroleum chemicals are toxic, carcinogenic or can be absorbed into the tissues of

    marine organisms (Landquist, H, et al., 2013). These toxins can make it up the marine food

    chain; from plankton to fish to other marine mammals, and even humans.

    Large oil spills caused by bilging or grounding of ships often receive swift environmental

    responses. These catastrophic spills are extensively covered by media as the amount of oil

    dissipated over the water surface underscores the seriousness of the spill (Rogowska, Namienik,

    2010). Shipwrecks can potentially cause spills that are on par with the large oil spills, however,

    because spills from shipwrecks, known as chronic oil spills, are not instantaneous and do not

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    usually cause oil accumulate on the water surface (Landquist, H, et al., 2013), they are often

    ignored by the media and do not receive adequate environmental responses.

    The effects of oil spills from shipwrecks depend on numerous factors, such as the type

    and amount of oil on board at the time of sinking, the characteristics of the affected environment,

    the water temperature and depth, wreck location, the condition of the ship at the time of sinking,

    and the length of time the wreck has been submerged (Landquist, H, et al., 2013).

    Currently, there are no comprehensive methods for environmental risk assessment of

    shallow water shipwrecks in NL waters; which causes difficulty on prioritization of remediation

    options (Alcaro, L.et al., 2007). Additionally, not all available actions can be taken to minimize

    or eliminate the environmental risks from these potentially polluting wrecks due to their lack of

    their applicability to, and functionality in, the subject region, which include:

    recovery of the entire wreck

    sealing the leaking points

    installing an oil capturing device

    controlled release of pollutants

    pumping of pollutants

    capping of the entire wreck or of the cargo

    wreck monitoring

    On January 18, 1985, the 5-year old, 121.85-meter long, steel hulled Liberian cargo

    carrier,Manolis L,as shown in Figure 1-1,went off course and struck Blowhard Rock in Notre

    Dame Bay, NL, at a speed of 14 knots (Transport Canada, 1985, p.2). This resulted in severe

    damage to the hull and ultimately led to the sinking of the vessel in an area identified by

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    Environment Canada as an ecologically sensitive area

    (CPAWS, 2009, p.60). In late March, 2013, a severe

    storm with extreme tidal conditions hit the area and

    caused the shipwreck to shift and experience

    additional hull damage (CBC News, 2015).

    Additional damage to a shipwreck can increase the risk of oil leakage (Landquist, H., et al.,

    2014). The Notre Dame Bay region relies heavily on tourism and the fishery for its economy

    (CBC News, 2015) and one or more oil spills from the Manolis L shipwreck could be

    environmentally devastating. Even more serious is the possibility of a chronic oil spill, which

    occurs over decades (Landquist, H, et al., 2013).

    TheManolis Lis not an isolated case; shallow water shipwrecks eventually reach a point

    in their decay curve where they experience structural changes that may lead to oil pollution

    (Landquist, H, et al., 2014). Using theManolis Las a case study allows for practical application

    of this projects research and demonstration as to how this can be applied to other shallow water

    shipwrecks in NL Waters.

    1.3 Scope

    The scope of this project includes:

    overview of shallow water shipwreck steel degradation in NL waters

    calculation of the corrosion rate of steel shipwrecks so as to develop a shipwreck risk

    matrix

    summary and analysis of current shallow water shipwreck oil remedial technologies

    creation of a rubric and matrix to analyze each oil remedial option to determine which

    are best suited for shallow water shipwrecks in NL waters

    Figure 1-1:Manolis L Prior to SinkingSource: CBC News

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    recommendations on which oil remedial technologies are best suited for shallow

    water shipwrecks in NL waters

    The scope of this project does not include:

    shipwrecks in water deeper than 60 meters

    shipwrecks outside of 2 kilometers from the coastline

    non-oil carrying vessels

    technology that does not have proven functional and operational profiles

    oil remediation costs

    1.4 Methodology

    The research used to support this project was available literature from secondary sources.

    The literature mainly focused towards three types of sources. The first source was journal articles

    and papers on the topic of structural degradation in shipwrecks by engineers, experts or

    researchers (Kuroda et al., 2008). The second type of source was on the topic of oil remedial

    methods and options in the form of papers published by engineers, experts or researchers in

    periodicals, articles, or magazines (Mazarakos, Andritsos & Kostopoulos, 2012). The third

    source was information and data obtained from companies that operate in the oil remedial sector

    (Environment Canada, 2006). Additional sources were used as needed from the MUN and

    Marine Institute libraries.

    The analysis of the secondary sources was a very critical stage in the development of the

    project report. The analysis was qualitative and:

    described and summarized the research data

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    analyzed the applicability of various remedial methods and options

    forecast outcomes

    The project report considered current shipwreck oil removal technologies (Mazarakos et al.,

    2012) to determine which is best suited for shallow water shipwrecks in NL waters. A shipwreck

    in Notre Dame Bay, NL, the Manolis L, was used as a case study (Transport Canada, 1985) for

    practical application of this projects research and demonstration as to how this can be applied to

    other shallow water shipwrecks in NL Waters.

    2.0 Properties of Common Marine Petroleum Products

    Crude oil, as shown in Figure 2-1, has been the

    most common source of fuel oils for marine use since the

    solid fuel, coal, was phased out in 1912. Britains Queen

    Elizabeth-class battleships were among the first vessels

    designed and built to be powered solely by liquid fuels.

    These vessels were successful and the use of liquid fuels

    spread to general use in the marine shipping industry

    (Dahl, 2001). For the purposes of oil remedial options for shipwrecks, only vessels built after

    1912, therefore, need be considered.

    An understanding of the physical properties of petroleum products is necessary in order

    to develop an understanding of the dangers they pose when they leak from shipwrecks.

    Petroleum products that seep from shipwrecks are devastating to the environment (Landquist, H,

    et al., 2013) as they are insoluble in water, toxic, and corrosive. The marine industry utilizes

    several different types of these products; the most common being Marine Diesel Oil (MDO), a

    Figure 2-1:Bunker C Oil

    Source: Environment Canada

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    light distillate fuel, and Heavy Fuel Oil (HFO), a thick residual fuel. The critical specifications,

    those which affect flow rates and buoyancy, are shown in Table 1-1.

    Oil Type

    Viscosity

    0 Ckg/m*s

    Viscosity

    15 Ckg/m*s

    Density

    0 Ckg/m3

    Density

    15 Ckg/m3

    Specific Gravity

    0 C (SW)T/m3

    Specific Gravity

    15 C (SW)T/m3

    MDO 129 14 996 890 - 920 0.97 0.86 - 0.89

    HFO 883 486 980 960 -1010 0.95 0.93 - 0.98

    Table 2-1:Physical Properties of Marine Oils

    Adapted fromISO 8217:2005 Petroleum products - Fuels (class F) - Specifications of marinefuels, Tables 1 and 2. Retrieved from http://www.chevronmarineproducts.com/products/iso-

    specs.aspx

    Lubricants, hydraulics, and greases are not considered herein as the quantities of each are

    relatively small in comparison to the fuel oils.

    Three physical properties of these fuels, viscosity, the temperature sensitive measure of a

    fuels' resistance to flow, density, the mass per unit of volume, and specific gravity, the ratio

    between the density of an object, and a reference substance, need to be considered when

    assessing shipwrecks. These determine the ability of fuels to flow from a shipwreck and the flow

    rate of leakages (Pounder & Woodyard, 2004). As MDO is the lighter fuel, it will leak easier

    than HFO when an escape route from a shipwreck forms. Lighter oils are able to escape through

    narrow cracks, vent pipes, and broken internal pipes and equipment and tend to form large thin

    oil sheens that can cover large surface areas. Evaporation in open-water spills lessens the

    negative impacts (Milwee, 1996).

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    3.0 Environmental Conditions Data for Newfoundland

    The petroleum products physical properties must be assessed along with the

    environmental conditions of the region under consideration; in this case, Newfoundland. Because

    viscosity and density are temperature dependent, the annual temperature cycle at selected depths

    must be investigated in order to determine how the petroleum products can be expected to

    behave. For the purpose of this report, shallow water depth is deemed to be 50 meters. Figure 1

    shows the water temperatures at both the surface and at 50 meters of depth as measured on

    Newfoundlands northern coastline. This represents the best-case scenario due to the colder, at

    depth, water temperatures which keep heavy fuel oils in a near solid form and less lightly to seep

    from a shipwreck.

    At 50 meters, temperatures are in the range of -2 to +2 deg C (Colbourne, 2004). The

    densest marine fuel, HFO, remains in a near solid state with a maximum specific gravity of 0.98,

    however, its density is less than the salt water specific gravity of 1.025. Since the HFO specific

    gravity is less than the salt water, the HFO will float should it leak from the shipwreck and,

    hence, has the potential to create spills and cause environmental damage.

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    Figure 3-1:Annual Temperature and Salinity Anomalies at Selected Depths (Top Panels) andTheir Decadal Means (Bottom Panels)

    Source: Colbourne, 2004

    Whether oil flows from a ruptured tank depends on more than the viscosity and density of

    the oil. The hydrostatic pressure of the water column will not allow oil to easily escape. If the

    pressure in the tank is higher than the water pressure, the oil will flow out of the tank. If the

    water pressure is higher, then the oil will remain in the tank (Milwee, 1996).

    However, other environmental forces can act on the shipwreck and lead to oil spilling

    from a tank. Subsea currents can create pressure differences that allow the oil to escape. These

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    currents can also force water into tanks, which will displace the oil and force it out of the tank(s)

    (Milwee, 1996).

    The rising and falling of the tides can affect the pressure differential at the wreck site.

    Much like the operation of a displacement pump, a continual tidal cycle can pump oil from the

    tanks of a shipwreck. This force is increased when coupled with tidal or storm surges (Milwee,

    1996). As the tide rises, the water pressure increases and is forced into the tank(s). Later, as the

    tide falls, oil flows out of the tank(s) as the water pressure drops below that of the pressure inside

    of the tank(s). Oil will continue to flow out of the tank(s) until the pressures equalize. Table 1-2

    shows the effect of different pressure situations.

    Pressure Condition Result

    Pressure in Tank = Water Pressure No Leakage

    Pressure in Tank > Water Pressure Oil flows out of tank(s)

    Pressure in Tank < Water Pressure No Leakage

    Table 3-1:Results of Various Pressure Conditions at the Shipwreck

    Source: author

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    4.0 Steel Degradation of Shipwrecks

    In order to make an informed decision as to which oil remedial options should be

    employed, the structural condition of the shipwreck must be assessed. There is ample data

    available to allow for accurate steel corrosion rate estimate calculations to be performed. These

    calculations can help with the risk assessment and shipwreck management decision making

    process.

    Many factors determine the state of steel degradation of a wreck:

    the ship's construction materials

    the wreck becoming covered in sand or silt

    the salinity of the water the level of destruction involved in the ship's loss

    the depth of water at the wreck site

    the strength of tidal currents or wave action at the wreck site

    the exposure to surface weather conditions at the wreck site

    the presence of marine animals that consume the ship's fabric

    temperature

    the acidity (pH) and other chemical characteristics of the water at the site

    It is well known that corrosion rate of steel in seawater is influenced by dissolved

    oxygen, temperature, marine growth and so on, and increases as current velocity increases

    (Kuroda, et al, 2008). Figure 4-1 graphs the effect of current velocity on steel corrosion rate.

    Figure 4-1:Effect of Current Velocity on Steel Corrosion Rate

    Source: Kuroda, et al, 2008

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    The approximate rate of corrosion in seawater is 0.1 mm/year. However, this rate can

    more than double due to wave energy at the surface (MacLeod, 2011). Hull plates are generally

    thick on ships, however, internal holding tanks and plumbing, ducts and vents are substantially

    thinner and are often the first areas to collapse (MacLeod, 2011). This can lead to breakup of the

    hull.

    Corrosion rates for individual ships are affected by dissolved oxygen and temperatures at

    the wreck site (MacLeod, 2010). Baseline corrosion rates do not account for natural events, such

    as storm surges and strong currents. Localized corrosion from pitting or microbes can be

    important factors and, if occurs much faster than the baseline rate, is more likely to cause

    structural failure sooner, however, these cannot be predicted (MacLeod, 2011).

    Through the use of experimentation with steel corrosion rates in salt water, a more

    accurate gauge of corrosion rates can be utilized (Kuroda, et al, 2008). At depths in the 50 meter

    range, the steel corrosion rate values can be taken as 0.21 mm/year, as seen in Figure 4-2.

    Figure 4-2:Field Results of Steel Corrosion RatesSource: Kuroda, et al, 2008

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    The DNV Hull Inspection Manual (DNV, 2007) provides guidance to ship operators on

    maintaining control of ships structural conditions. Figure 4-3 shows the average rates at which

    coating systems breakdown and that steel will degrade once the coatings breakdown. This can be

    applied to sunken ships. Depending upon the coating condition of the ship at the time of loss, the

    coatings will breakdown in approximately 6 years. It then only takes 4 years for the steel to

    degrade to the point where holes will begin to form.

    Figure 4-3: Coating and Steel Degradation Rates

    Source: DNV, 2007

    By considering all of these factors, the following formula can be derived that will provide an

    estimate of the steel corrosion rate:

    Estimated Corrosion (mm) = Corrosion Rate (mm/yr) x [Ship Submersion Time (years) -

    Coating Breakdown (years)]

    This can be extended to arrive at a formula to estimate the remaining steel thickness:

    Estimated Steel Thickness Remaining (mm) = Original Steel Thickness (mm) - Estimated

    Corrosion (mm)

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    5.0 Oil Remedial Technologies

    Many oil remedial technologies have been successful globally. New technology and oil

    remedial methods are continually being developed and improved upon. Several operations can be

    carried out in order to evaluate, minimize and eliminate the environmental risks deriving from

    potentially polluting wrecks:

    recovery of the entire wreck

    sealing the leaking points and using cofferdams

    controlled release of pollutants

    pumping of pollutants from the shipwreck

    capping of the entire wreck or of the cargo

    shipwreck monitoring

    Not all of these oil remedial technologies, however, are suitable for use in Newfoundland

    shallow water shipwrecks. This section aims to provide an overview of each technology along

    with rational towards applicability.

    5.1 Recovery of the Entire Wreck

    Recovery of the entire shipwreck is

    considered to be the best oil remediation option. Not

    only are the oils removed, but also all other

    potentially hazardous materials onboard; such as the

    oily waste, cargo residues, chemicals in the

    equipment, hydraulic oils, lubricants, and greases.

    The wreck removal process is shown in Figure 5-1. Shallow water shipwreck recovery in

    Newfoundland waters is a viable option for vessels that are mainly intact and have not degraded

    substantially (Alcaro et al., 2007).

    Figure 5-1:Recovery of the Entire Wreck

    Source: SMIT Salvage

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    Many shipwrecks, however, are not good candidates for recovery as they are damaged to

    the point of being fragile. Recovery attempts of vessels in this condition can lead to vessel

    breakup; which could cause a greater environmental problem. The longer a vessel remains

    underwater, the more degradation will occur (Milwee, 1996).

    5.2 Sealing the Leaking Points and Using Cofferdams

    Sealing the leaking points, as shown in figure 5-2,

    is a temporary measure that is used to slow the flow of

    oils from a wreck until a more permanent solution can be

    decided upon. It is typically the first option to consider in

    the event of an emergency.

    Sealing can be performed with a variety of tools

    and materials to plug leaks, using either a ROV or diver

    (Alcaro et al., 2007) and is a viable temporary option for shipwrecks in Newfoundland waters.

    Another level of protection can be included

    with this option; use of an oil-capturing system, such

    as a cofferdam (shown in Figure 5-3). Cofferdams can

    be placed over leaking points to trap any leaking oil.

    This oil can then be pumped from the cofferdam on a

    regular basis.

    Cofferdam use must be considered to be temporary solution as they do not prevent the oil

    from leaking from the shipwreck. The shipwreck continues to degrade and, eventually, the oil

    leakages can become too numerous or the seepage flow rate can increase to a point where the

    volume of the cofferdam is inadequate.

    Figure 5-2:Leak-Sealing Operations

    Source: French Navy

    Figure 5-3: Cofferdam on the Manolis L

    Source: CCG

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    5.3 Controlled Release of Pollutants

    This method is implemented by drilling holes in

    the hull of the shipwreck to puncture the tank, thereby

    allowing controlled release of the pollutants (Alcaro et al.,

    2007). The controlled discharge of pollutants, however,

    has limitations. The pollutant must be able to float so that

    it can be captured and collected on the surface by oil

    booms. This can be seen in figure 5-4. Because of the use

    of surface vessels and floating oil booms, ideal sea and weather conditions are required; a rarity

    in Newfoundland.

    5.4 Pumping of Pollutants from the Shipwreck

    The most common option employed to pump

    pollutants from shipwrecks is the hot-tap technique

    (Alcaro et al., 2007), as shown in Figure 5-5. This

    method involves the drilling of several holes in the

    shipwreck hull and installing pipe flanges. This is

    achieved using specialized tools that do not allow

    leakages to occur during the procedure. Several hot-

    tap flanges and holes must be installed in a tank to mount the pump, provide make-up water, and

    insert heating coils. Sometimes it results necessary to heat the transfer line of the pump steam

    into the oil tank to melt the oil and reduce its viscosity, which improves flow.

    Hot-tapping can be performed by divers and ROVs and is a viable option in

    Newfoundland waters.

    Figure 5-4:Recovering Oil with

    BoomsSource: Markleen Oil Spill

    Technologies

    Figure 5-5:Hot-TappingSource: Markleen Oil Spill

    Technologies

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    5.5 Capping of the Entire Wreck or of the Cargo

    This option aims to completely cover the wreck or the cargo, as shown in Figure 5-6, in

    order to avoid the leakage of pollutants components into the marine environment (Alcaro et al.,

    2007). The advantages of this type of technology include:

    isolation of pollutants and preventing

    their dispersion by the use of capping

    materials with a low permeability to

    fluids

    protection of the shipwreck from any

    contact with fishing equipment or

    other human activities that can cause

    an increase of deteriorating rate

    reduction of the corrosion rate of

    metals and steels

    transformation of pollutants if the

    capping material is added with

    reacting and neutralizing compounds

    The capping material should be made of crushed rocks and is a viable option in

    Newfoundland waters. The large quantity of capping materials and transport to the shipwreck

    site, however, may prove to be obstacles.

    5.6 Shipwreck Monitoring

    Monitoring the shipwreck involves the use of

    sonar, divers, ROVs, magnetometers, and even

    enlisting the help of local residents to report any oil

    spills. An example of a sonar image is shown in

    figure 5-7. Even if sonar imaging provides us with

    the position of a wreck on the bottom, only close

    visual examination (camera, diver or ROV) can

    Figure 5-6: Shipwreck Capping

    Source: DEEPP Pro ect

    Figure 5-7: Sonar Image of the

    Manolis L

    Source: CCG

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    provide us with details (location of holes, leaks, corrosion, etc.) (Alcaro et al., 2007). The French

    Department of Labor authorizes tank diving to a depth of 60 meters. Since this paper considers

    water depths below 60 meters to be shallow water, this is a viable option in Newfoundland

    waters.

    Shipwreck monitoring, however, is not an oil remediation solution. It simply provides

    notice that an oil spill has occurred or is about to occur.

    5.7 Summary of Oil Remedial Options

    This section discussed the various oil remedial options which are in use for shipwreck

    remediation globally. Table 5-1 summaries these options.

    Option Description

    Viable for

    NFLD

    (Y/N)

    Permanent

    Solution

    (Y/N)

    A recovery of the entire wreck Y Y

    B sealing the leaking points and using cofferdams Y N

    C controlled release of pollutants N Y

    D pumping of pollutants from the shipwreck Y Y

    E capping of the entire wreck or of the cargo Y Y

    F shipwreck monitoring Y N

    Table 5-1: Summary of Oil Remedial OptionsSource: Adapted from Alcaro, 2007

    Only options which are viable for Newfoundland waters will be considered further in this

    report. Temporary solutions will be considered further as these are acceptable options in some

    situations.

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    6.0 Shipwreck Risk Analysis Matrix

    The seriousness of a spill does not depend solely on the volume of oil; other factors, such

    as location of shipwreck, physical properties of the oil or other pollutants, prevailing marine

    conditions and sensitivities of the environment must be assessed. It is, therefore, crucial to

    undertake an assessment of both the areas under threat and condition of the shipwreck in order to

    better understand the possible consequences of a spill (Alcaro, et al, 2007).

    Ship wreck risk assessment requires an interdisciplinary approach covering analysis of

    ship construction, historical data about the ship and documentation from the time of wreckage,

    corrosion rates, environmental status at the wreck site, and environmental effects of the

    hazardous substance/s onboard. Consideration of these will lead to the creation of a rubric and

    matrix to analyze each oil remedial technology to determine which are best suited for shallow

    water shipwrecks in NL waters.

    Risks that have severe consequences and a high probability of occurring require a

    mitigation plan.

    6.1 Shipwreck Remediation Decision Process

    The general process of risk management consists of a number of steps, as shown in

    Figure 6-1. Initially it involves an establishment of the context where the scope and goal of the

    risk management work is stated. This is followed by the risk assessment where risk identification

    is performed which implies identification of areas of impact, events, sources of risks and

    potential causes and consequences. Risk assessment also involves a risk analysis process to

    develop an understanding of the risk and to provide input to the subsequent risk evaluation. An

    evaluation of what risks to consider and how to prioritize among them is included in the risk

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    evaluation step, together with a comparison of possible alternatives to mitigate the risks. This

    provides support to the decision-makers on benefits and limitations of possible risk treatment

    alternatives (Landquist, 2013).

    Figure 6-1: The Basic Structure of the Decision-Making-ProcessSource: Adapted from Landquist, 2013

    Shipwrecks need to be assessed and prioritized to ensure that available resources can be used

    efficiently to reduce risk. This proactive approach involves the inspecting and performance of

    corrective actions, when needed, prior to the occurrence of any leakages. A well-structured risk

    assessment that can identify and prioritize shipwrecks is needed for a proactive strategy to be

    effective. Moreover, such an assessment can help prioritize between remedial alternatives and

    provide necessary decision support. Prioritizing sunken vessels will help resource managers and

    governments use resources effectively and assure stakeholders that the problem has been

    carefully assessed.

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    6.2 Definition of Risk Factors and Weights Classes

    Risk assessment involves the overall process of identifying risk, analyzing risk and

    evaluating risk. The aim of risk identification is to identify potential risks and gather relevant

    information on these risks. This identification is critical as risks that are not identified will not be

    considered in the supplementary process.

    Risk management begins with the establishment of the context where the objectives and risk

    criteria are set. Five factors were chosen to build a matrix of wreck threats:

    1. vessel type / tonnage

    2.

    volume of pollutants

    3. distance from coast or a sensitive area

    4. environmental conditions

    5. age and condition of shipwreck

    These components provide a measure of impact that a leaking ship will have on the

    environment. Each factor is classed between 1 (least dangerous) and 10 (most dangerous). Risk

    factors were then summed to produce the final risk rating for a maximum score of 50. Large oil

    tankers found in shallow, near shore waters in areas of high marine biological diversity are

    ranked highest, for example, while smaller ships in deeper waters are of lowest priority.

    Risk Index: Recall that the under riding criteria are:

    ships built after 1910

    steel hulled

    shallow waters (50 m range)

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    6.2.1 Vessel Type / Tonnage

    The tonnage of ships is considered as larger vessels carry larger fuel reserves. Tonnage

    values in the dataset range from 1000 to 50,000 tons. Oil tankers receive more points within the

    scoring due to their significant cargo oil capacity (Grennan, 2010). Table 6-1 shows the risk

    factor weights for vessel type and tonnage.

    Class Description Risk Factor Weights

    A < 2,000 tons 1

    B 2,000 - 2,999 tons 2

    C 3,000 - 3,999 tons 3

    D 4,000 - 4,999 tons 4

    E > 5,000 tons 5

    F Tanker Vessel add 3

    Table 6-1:Risk Factor Weights for Vessel Type and Tonnage

    Source: Adapted from Alcaro, 2007

    6.2.2 Volume of Pollutants

    Unless documentation can prove that vessel tanks are not 100% full, it should be assumed

    that the vessel tanks are 100%. In cases where vessel tank capacities or design drawings are not

    available, capacities from similar ships should be used. The total volume includes the total vessel

    fuel capacity and any cargo that contains pollutants. Table 6-2 shows the risk factor weights for

    volume of pollutants.

    Class Pollutant Volume (m3) Risk Factor Weights

    A < 200 1

    B 200 - 299 2C 300 - 399 3

    D 400 - 500 4

    E > 500 5

    Table 6-2:Risk Factor Weights for Volume of PollutantsSource: Adapted from Alcaro, 2007

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    6.2.3 Distance from Coast or a Sensitive Area

    The distance from shore is a critical factor as any pollutants that leak from a near-shore

    shipwreck will reach the shoreline within a few hours (Alcaro, et al, 2007)). This drastically

    reduces the oil remediation response time. Additionally, near-shore shipwrecks are usually

    located in shallow waters. The reduced depth of the water column means that the pollutant does

    not have the opportunity to dilute or dissipate. Table 6-3 shows the risk factor weights for

    distance from coast or a sensitive area.

    Class Distance (km) Risk Factor WeightsA > 5 1

    B 3 -4 2

    C 2 -3 3

    D 1 - 2 4

    E < 1 5

    Table 6-3:Risk Factor Weights for Distance from Coast or a Sensitive Area

    Source: Adapted from Alcaro, 2007

    According to Alcro, et al (2007), in a few hours, oil will reach the coast if the shipwreck is

    located 1 km offshore. Within a day, even without the effects of tides or currents, a floating oil

    slick will range from 616 km. In a few days, the distance will range from 1680 km.

    6.2.4 Environmental Conditions

    As shown is previous sections, the environmental conditions at the shipwreck site are an

    important consideration. The salient levels, current velocities and temperatures affect both the

    behaviors of the pollutants and the corrosion rates of the shipwreck. The actions of the tidal cycle

    and storm surges also affect possible outcomes. Table 6-4 shows the risk factor weights for

    environmental conditions.

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    Class Description Risk Factor Weights

    A salient levels > 35 1

    B tidal range > 0.6 m 2

    C > 4 storm surges/ year 3

    D current velocities > 4 m/s 4

    E temperatures > 2 C 5

    Table 6-4:Risk Factor Weights for Environmental Conditions

    Source: Adapted from Alcaro, 2007

    It is possible that more than one of these risk factors can be present simultaneously. As such,

    the total risk factor weight for this consideration is the total sum of all of the weights, 15.

    6.2.5 Age and Condition of Shipwreck

    The length of time since the sinking of a vessel affects how much steel deterioration the

    shipwreck will experience; as shown in previous sections. The amount of damage a vessel

    sustains at the time of loss is an important factor, as well if the vessel remains intact. Table 6-5

    shows the risk factor weights for age and condition of shipwreck.

    Class Description Risk Factor WeightsA 0-9 years underwater 1

    B 10-19 years underwater 2

    Cconsiderable damage at

    time of loss3

    D shipwreck not intact 4

    E > 20 years underwater 5

    Table 6-5:Risk Factor Weights for Age and Condition of Shipwreck

    Source: Adapted from Alcaro, 2007

    It is possible that more than one of these risk factors can be present simultaneously. As such,

    the total risk factor weight for this consideration is the total sum of all of the weights, which is

    12.

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    6.3 Risk Analysis

    Risk analysis allows for the development of a deeper understanding of the potential risks.

    This provides input to the risk evaluation, if there is a need for treatment and also the decision on

    suitable mitigation options.

    The risk analysis requires a method to determine the amount of risk and the possible

    outcomes of these risks. Next, the level of risks must be defined in order to prioritize shipwrecks

    for oil remediation. Finally, the oil remedial options must be evaluated against the risk levels.

    6.3.1 Calculation of Risk Factors

    The determination of the risk factor is based on the ratio of the Class of Distance RF / Class

    of Volume RF:

    Risk Factor (RF) = Class of Distance RF / Class of Volume RF

    These two risk factors are the largest contributors to the size and severity of a potential oil

    spill. Table 6-6 shows the calculation of risk factors.

    Class of

    Distance

    Class of

    Volume RF

    Class of

    Distance

    Class of

    Volume RF

    Class of

    Distance

    Class of

    Volume RF

    1 1 1.00 3 1 3.00 5 1 5.00

    1 2 0.50 3 2 1.50 5 2 2.50

    1 3 0.33 3 3 1.00 5 3 1.67

    1 4 0.25 3 4 0.75 5 4 1.25

    1 5 0.20 3 5 0.60 5 5 1.00

    2 1 2.00 4 1 4.00

    2 2 1.00 4 2 2.00

    2 3 0.67 4 3 1.33

    2 4 0.50 4 4 1.00

    2 5 0.40 4 5 0.80

    Table 6-6 Calculation of Risk FactorsSource: Adapted from Alcaro, 2007

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    6.3.2 Risks with Impacts and Rationales

    All of the risk factors work to increase the probability of a spill occurring. It is currently

    impossible to calculate the probability of a shipwreck releasing pollutants in the shallow waters

    of Newfoundland due to the lack of historical data; which is a good thing as this means that the

    number of spills that have occurred in the subject region is low. The best we can presently

    achieve is a rating system for the severity of risk.

    Even though probabilities cannot currently be estimated, the events that can lead to a possible

    spill can be itemized (Landquist, et al, 2014). The most common are shown in Table 6-7.

    No. Risk Event Rationale

    1 Corrosion Steel corrodes in salt water at a rate that can be calculated

    2 Diving Shipwrecks can be damaged by divers

    3 Landslides/earth quakesShifting of a shipwreck can introduce forces and stresses that

    can cause tanks to rupture

    4 Ship traffic

    Shipwrecks in shallow waters are susceptible to damage from

    ship traffic. Anchors, for example, can puncture a tank on a

    shipwreck

    5 Storms/extreme weatherShifting of a shipwreck can introduce forces and stresses that

    can cause tanks to rupture

    6 TrawlingA collision between a trawl and shipwreck can cause tanks to

    rupture

    Table 6-7:Risk Events with Impacts and RationalesSource: Author

    The risk is based on the consequence of the risks compared to the likelihood of the risks

    occurring. This comparison is illustrated in Table 6-7. Table 6-8 illustrates the degree of

    consequence of each risk factor and the likelihood of a particular risk factor happening. It also

    illustrates the impact potential if such risks are realized.

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    These possible events can be rated on a level of hazard based on the potential for the event to

    occur and the resulting consequences. The impact levels are:

    Minor

    Moderate Serious

    Minor corresponds to wrecks with a limited damage-potential due to the non-polluting

    category of the pollutant or the low risk factor score.

    Moderate denotes wrecks that may have impacts. Special care and monitoring should be

    performed before making a decision: neutralization of the risk or leave the wreck as it is, taking

    into account the accessibility of the pollutants (depth, position of the wreck at the sea bottom,

    location of the wreck, sea conditions, etc.).

    Serious means that potentially very severe effects are expected. These top priority cases

    should receive immediate action plan and mitigation.

    Table 6-8 shows the risk classification with the estimated impact potential and consequences.

    Risk Risk Factor Likelihood ImpactPotential

    Consequence

    1 Corrosion High Serious Serious

    2 Diving Low Minor Serious

    3 Landslides/earth quakes Medium Serious Serious

    4 Ship traffic Medium Serious Serious

    5 Storms/extreme weather High Serious Serious

    6 Trawling Low Minor Serious

    Table 6-8: Qualitative Risk Classification

    Source: Author

    As can be seen in Table 6-9, the consequence for each risk factor is serious. No matter how

    low the likelihood of a risk factor occurring may be, the consequence is that a spill is the end

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    result; which is serious. This serves to highlight the need for oil remediation strategies to be

    considered following the loss of any vessel.

    Consequence

    Likelihood Nil Minor Moderate Major Severe

    Almost Certain 5 10 15 20 25

    Likely 4 8 12 16 20

    Possible 3 6 9 12 15

    Unlikely 2 4 6 8 10

    Rare 1 2 3 4 5

    Impact key

    01-04 = Minor

    05-09 = Moderate

    10-16 = Major

    17-25 = Severe

    Table 6-9:Risk Classification

    Source: Author

    6.3.3 Calculating the Risk Score

    After the five risk factors have been analyzed, the results can be recorded and an overall

    (total) risk score obtained. The higher the risk score, the higher the need for an oil remediation

    strategy. Table 6-10 provides the means to calculate the risk score

    Risk FactorRisk Factor

    Weights

    Max

    Weight

    Vessel type / tonnage 8

    Volume of pollutants 5

    Distance from coast or a sensitive area 5

    Environmental conditions 15

    Age and condition of shipwreck 12

    TOTAL SCORE: 45Impact key

    01-09 = Minor

    10-29 = Moderate

    30-45 = Severe

    Table 6-10:Determination of the Risk Score

    Source: Author

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    6.4 Risk Mitigation Strategies

    As a result of the risk analysis, the utilization of risk mitigation strategies, which, in the case

    of shipwrecks refers to the oil remediation options, in an effort to minimize risks must be

    undertaken. Table 6-11 outlines the risk mitigation strategies, determined for the associated risks

    and is dependent upon the risk score of the shipwreck.

    Oil Remedial Option

    Risk Identification A B C D E F

    Risk score = Minor Y Y Y Y Y

    Risk score = Moderate N Y Y Y Y

    Risk score = Severe N N Y Y Y/N

    Key

    Option Description

    A recovery of the entire wreck

    B sealing the leaking points and using cofferdams

    C controlled release of pollutants

    D pumping of pollutants from the shipwreck

    E capping of the entire wreck or of the cargo

    F shipwreck monitoring

    Table 6-11:Risk Mitigation StrategiesSource: Author

    Option A is not viable with risk scores above Minor as the shipwreck will have

    deteriorated to the point where recovery of the shipwreck may cause severe environmental

    damage.

    Option B is not viable with risk scores above Moderate as this option is a temporary

    solution and the shipwreck will require permanent solutions.

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    Option F with Severe risk scores receives a Y/N because at this level of risk, oil

    remediation should have already occurred. The wreck should be monitored, however, in the

    event that not all of the oil was captured during the oil remediation process.

    It is expected that all risks are factored in to these strategies. If however, other risks develop,

    it is hoped that their effects may be analysed and appropriate mitigation strategies can be put in

    place.

    7.0 Case Study: Manolis L

    On January 18, 1985, the 5-year old, 121.85-meter

    long, steel hulled Liberian cargo carrier, Manolis L

    (shown in Figure 7-1), went off course and struck

    Blowhard Rock in Notre Dame Bay, NL, at a speed of 14

    knots (Transport Canada, 1985, p.2). This resulted in

    severe damage to the hull and ultimately led to the sinking

    of the vessel in an area identified by Environment Canada as an ecologically sensitive area

    (CPAWS, 2009, p.60). In late March, 2013, a severe storm with extreme tidal conditions hit the

    area and caused the shipwreck to shift and experience additional hull damage. Additional

    damage to a shipwreck will increase the risk of oil leakage (Landquist, H., et al., 2014). The

    Notre Dame Bay region relies heavily on tourism and the fishery for its economy (CBC News,

    2015) and one or more oil spills from the Manolis L shipwreck could be environmentally

    devastating. Even more serious is the possibility of a chronic oil spill, which occurs over decades

    (Landquist, H, et al., 2013).

    Figure 7-1:Manolis L Prior to

    SinkingSource: CBC News

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    TheManolis Lwill be evaluated using all of the analysis methods as laid out in previous

    sections. This will serve to demonstrate the functionality of these methods as applied to an actual

    shipwreck. The risk score will be calculated and a recommendation for an oil remediation option

    will be put forth.

    7.1 Environmental Conditions Data at the Shipwreck Site

    According to (Rao & Gregory, 2009), Notre dame Bay is a 6000 km2inlet of the Atlantic

    Ocean located on the northeast coast of Newfoundland. It contains many islands including Fogo

    Island, Change Islands, Exploits Islands and Twillingate. The tides are semi-diurnal with a height

    difference of approximately 1 m between high and low tides. Fast ice persists in the small bays

    and inlets for most of the season. Notre dame Bay falls within the North Shore Forest ecoregion,

    and is located in the Newfoundland Shelf region of Parks Canadas National Marine

    Conservation Areas System. The subject area is shown in Figure 7-2.

    Figure 7-2:Notre Dame Bay, NewfoundlandSource: Oceanviewer.org

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    7.2 Steel Degradation Calculations

    Based on the field results of steel corrosion rates (Kuroda, et al, 2008), and structural

    information from similar ships built in 1980, table 7-1 shows calculations that were completed

    for theManolis Lusing the following formulas:

    Estimated Corrosion (mm) = Corrosion Rate (mm/year) x [Ship Submersion Time (years) -

    Coating Breakdown (years)]

    Estimated Steel Thickness Remaining (mm) = Original Steel Thickness (mm) - Estimated

    Corrosion (mm)

    Shell Internal 1 Internal 2

    Original Steel Thickness (mm) 19 12 9

    Coating Breakdown (years) 5

    Corrosion Rate (mm/yr) 0.21

    Ship Submersion Time (years) 30

    Estimated Corrosion: 0.235 x 30

    = 7.05 mm

    Estimated Steel Thickness Remaining: 257.05 127.05 97.05

    = 11.95 mm 4.95 mm 1.05 mm

    Table 7-1: Structural Steel Corrosion for the Manolis LSource: Author

    This data can be represented as average strength reductions by dividing the estimated steel

    thickness by the original steel thickness, as shown in table 7-2.

    Shell Internal 1 Internal 2

    Original Steel Thickness (mm) 19 12 9Estimated Steel Thickness Remaining 11.95 4.95 1.05

    average strength reductions 37.11% 58.75% 88.33%

    Table 7-2: Structural Steel Strength Reductions Due To Corrosion for the Manolis L

    Source: Author

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    7.2.1 Verification of the Calculations

    Figure 7-3 shows the hull thickness survey results as measured in 2013 by Seaforth

    Figure 7-3Hull Thickness Survey Results As Measured In 2014 with Measurement Locations

    Source: Seaforth, 2014

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    The average hull thickness is shown in Table 7-3.

    Reading

    No.

    Thickness

    (mm)

    Reading

    No.

    Thickness

    (mm)

    1 13.2 12 9.2

    2 12 13 10.63 4.7 14 10.8

    4 9.6 15 10

    5 13.1 16 11.1

    6 11.7 17 10.2

    7 10.4 18 10

    8 10.4 19 10.6

    9 13.8 20 11.2

    10 10.8 21 9.1

    11 11.3 22 14.1

    10.81 Average

    Table 7-3:Average Hull Thickness

    Source: Adapted from Seaforth, 2014

    It was previously shown that the estimated thickness was 11.95 mm, which means that

    the average thickness is less than the actual field measurements. This can be accounted for if an

    actual variable at the shipwreck site is different than those used in the analysis, for example, a

    higher salient level or current velocity would increase the corrosion rates.

    Figure 7-4 is a demonstration piece that was prepared by the author to demonstrate the

    differences in steel thickness that are shown in Table 7-3.

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    Figure 7-4: Steel Demonstration Piece of Steel Thickness Measured on the Manolis L

    Source: Author

    7.3 Risk Factors

    The risk factor for the Manolis Lis the highest rating, meaning that the likelihood of an

    oil spill is high and the consequences will be "serious".

    7.4 Calculation of the Risk Score

    Table 7-5 shows the calculation of the risk score for theManolis L.

    Risk FactorRisk Factor

    WeightsRationale

    Vessel type / tonnage 5 Manolis Ltonnage is 5,421

    Volume of pollutants 5 522 cu-m recorded at time of loss

    Distance from coast or a sensitive area 5 less than 1 kmEnvironmental conditions 15 all variables are applicable

    Age and condition of shipwreck 5 Manolis Lsank in 1985

    TOTAL SCORE: 35

    Table 7-5: Calculation of the Risk Score for the Manolis LSource: Author

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    The value of the risk score means that theManolis Lis assessed to be serious, whichmeans

    that potentially very severe effects are expected. This is a top priority case and should receive an

    immediate action plan and mitigation.

    7.5 Recommendation for Appropriate Risk Mitigation Strategies

    Based on the analysis, calculations, and oil remediation options currently available and

    applicable, options D or E, as shown in Table 7-6, are the recommended risk mitigation

    strategies.

    Oil Remedial Option

    Risk Identification A B C D E F

    Risk score = Severe N N Y Y N

    D pumping of pollutants from the shipwreck

    E capping of the entire wreck

    Table 7-6:Recommended Risk Mitigation Strategies for the Manolis L

    Source: Author

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    8.0 Conclusions

    The purpose of this report was to develop a tool for quantitative risk and remedial options

    assessment of potentially polluting shallow water shipwrecks in NL waters. This report

    examined current shipwreck oil remedial options and determined which are best suited for

    shallow water shipwrecks in NL waters. By utilizing the Manolis L shipwreck as a case study,

    risk factors, such as the corrosion rates of steel and levels of consequences, were estimated and a

    shipwreck risk and remedial options matrix developed that can aid in the prioritization of

    remediation and environmental response options.

    It was shown that the effects of oil spills from shipwrecks depend on numerous factors,

    such as the type and amount of oil on board at the time of sinking, the characteristics of the

    affected environment, the water temperature and depth, shipwreck location, the condition of the

    ship at the time of sinking, and the length of time the wreck has been submerged. A quantitative

    approach was developed for the subject region and wreck depth and location from shore that can

    be used as a tool in the shipwreck mitigation process in setting priority levels to different

    shipwrecks.

    Current shipwreck oil remedial techniques and shipwreck management strategies were

    investigated and their applicability to, and functionality in, the subject region were analyzed. Not

    all of the current oil remediation options are applicable and were, therefore, removed from the

    list of acceptable options.

    Expanded further, a method was developed to perform a risk analysis that led to an

    overall risk score that can be used in the decision-making process. An evaluation of which risks

    to consider and how to prioritize among them was included in the risk evaluation steps along

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    with a comparison of possible oil remediation options, which may provide support to the

    decision-makers on benefits and limitations of possible risk treatment alternatives.

    The case study investigated, the Manolis L, was evaluated using all of the analysis

    methods as laid out in this report. This demonstrated the functionality of these methods as

    applied to an actual shipwreck. The risk score was calculated, the level of consequences were

    determined and a recommendation for an oil remediation option for this shipwreck was put forth.

    9.0 Recommendations

    Based on the information outlined in this report, the following set of recommendations

    are encouraged:

    Decision-makers in the shipwreck oil remediation process should consider the corrosion

    rate of steel shipwrecks as part of a shipwreck risk matrix.

    The creation of a rubric and matrix to analyze each oil remedial option to determine

    which are best suited for shallow water shipwrecks in NL waters.

    Alternatives to the current shallow water shipwreck oil remedial technologies should be

    researched.

    A database of potentially polluting shipwrecks in NL waters should be developed and

    each ship analyzed for risk and consequences and prioritized for remediation, if needed.

    The Canadian government should immediately remove the oil from theManolis L

    shipwreck or cap the entire shipwreck as determined by the risk analysis of this report.

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    References

    Alcaro, L., Amato, E., Cabioch, F., Farchi, C., Gouriou, V., Wrubl, C. (2007) Development of

    European guidelines for potentially polluting shipwrecks. D.G. Environment, Civil

    Protection Unit, Institute of Marine Sciences (ISMAR).

    CBC News. (2015, January 16). Manolis L a time bomb for more oil leaks, warn residents.

    Retrieved October 1, 2015 from http://www.cbc.ca/news/canada/newfoundland-

    labrador/manolis-l-a-time-bomb-for-more-oil-leaks-warn-residents-1.2911960

    Colbourne, E. B. (2004). Decadal Changes in the Ocean Climate in Newfoundland and

    Labrador Waters from the 1950s to the 1990s. 2004.J. Northw. Atl. Fish. Sci., 34: 43-61.

    doi:10.2960/J.v34.m478

    DET NORSKE VERITAS (DNV) (Ed.). (2007). DNV Hull Inspection Manual (Vol. MTP NO

    864). Hvik: DET NORSKE VERITAS.

    Emergencies Science and Technology Division, Environment Canada (2006).Bunker C fuel oil.

    Retrieved October 7, 2015, from http://www.etc-

    cte.ec.gc.ca/databases/oilproperties/pdf/web_bunker_c_fuel_oil.pdf

    Dahl, Erik J. (2001).Naval Innovation: From Coal to Oil. Joint Forces QuarterlyVolume 27,

    pp. 50-56. Institute for National Strategic Studies, Nation Defense University,

    Washington, D.C.

  • 7/25/2019 Manolis L - Kevin Strowbridge Report

    49/51

    INVESTIGATION OF OIL REMEDIATION OPTIONS Page 39 of 41

    Grennan, D. (2010) What is the current state of the art for assessment, salvage and response

    technologies?International Corrosion Workshop, Newport News, VA.

    Kuroda, T., Takai, R., Kobayashi, Y., Tanaka, Y., & Hara, S. (2008). Corrosion rate of

    shipwreck structural steels under the sea. OCEANS 2008 - MTS/IEEE Kobe Techno-

    Ocean, 08(978-1-4244-2126-8).

    Landquist, H., Hassellv, I., Rosn, L., Lindgren, J., & Dahllf, I. (2013). Evaluating the needs

    of risk assessment methods of potentially polluting shipwrecks.Journal of Environmental

    Management Vol 119 (2013), pp 85-92.

    Landquist, H., Rosn, L., Lindhe, A., Norberg, T., Hassellv, I., Lindgren, J., & Dahllf, I.

    (2014). A fault tree model to assess probability of contaminant discharge from

    shipwrecks.Marine Pollution Bulletin, 88, 239-248.

    MacLeod, Ian. 2010. Modeling Corrosion, Assessment of Complicating Factors Panel.

    International Corrosion Workshop, Newport News, VA. October 2010.

    Mazarakos, D.E., Andritsos, F., Kostopoulos, V. (2012). Recovery of oil-pollutant from

    shipwrecks:DIFIS project, International Journal of Structural Integrity, Vol. 3 Iss: 3 pp.

    285 - 319

    Milwee, W. (1996).Modern marine salvage. Centreville Md.: Cornell Maritime Press.

  • 7/25/2019 Manolis L - Kevin Strowbridge Report

    50/51

    INVESTIGATION OF OIL REMEDIATION OPTIONS Page 40 of 41

    Pounder, C., & Woodyard, D. (2004). Pounder's marine diesel engines and gas turbines (8th

    ed.). Oxford: Elsevier Butterworth Heinemann.

    Rao, A., Outhouse, L., Gregory, D. (2009). Special marine areas in Newfoundland and

    Labrador, areas of interest in our marine backyards. Canadian Parks and Wildlife

    Society (CPAWS), Newfoundland and Labrador Chapter.

    Rogowska J, Namienik J (2010) Environmental implications of oil spills from shipping

    accidents. Rev Environ Contam Toxicol 206:95114

    Seaforth Geosurveys Inc. (2014)ROV support operations report removal and reinstallation of

    cofferdam, hull thickness measurements and HD video survey of the shipwreck M.V.

    Manolis L, Blow Hard Rock, NL. Dartmouth, NS.

    Symons, L., Michel, J., Delgado, J., Reich, D., Rench McCay, D., Chmidt Etkin, D., & Elton, D.

    (2014). The Remediation of Underwater Legacy Environmental Threats (RULET) risk

    assessment for potentially polluting shipwrecks in u.s. waters. 2014 International Oil

    Spill Conference.

    Symons, L., Michel, J., Delgado, J., Reich, D., McCay, D., Etkin, D., Helton, D. (2014) The

    Remediation of Underwater Legacy Environmental Threats (RULET) Risk Assessment

    for Potentially Polluting Shipwrecks in U.S. Waters, 2014 International Oil Spill

    Conference, Abstract 299454

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    51/51

    INVESTIGATION OF OIL REMEDIATION OPTIONS Page 41 of 41

    Transport Canada, Investigation report into the circumstances attending the grounding,

    abandonment and sinking of the Liberian vessel "Manolis L." in Notre Dame Bay,

    Newfoundland on January 17, 1985, Ottawa: Marine Casualty Investigations, 1985