literatu rverzeichn is - springer978-3-642-60224-5/1.pdf · literatu rverzeichn is 1 einleitung und...

Literatu rverzeichn is

1 Einleitung und Obersicht

[1.1] Frank-Kamenetskii DA (1959) Stoff- und Wiirmeiibertragung in der chemischen Kinetik. Springer, Heidelberg

[1.2] Satterfield CN (1970) Mass Transfer in Heterogeneous Catalysis. MIT Press, Cambridge, Massachusetts

[1.3] Aris R (1975) The Mathematical Theory of DiffuSion and Reaction in Permeable Catalysts. Clarendon Press, Oxford (2 Vols.)

[1.4] Boltzmann L (1981) Vorlesungen uber Gastheorie. (Nachdruck) Friedrich Vieweg, Braunschweig

[1.5] Jiittner F (1909) Z. Phys. Chern. 65:595 [1.6] Warburg 0 (1923) Biochern. Zeit. 142:317 [1.7] Damkohler G (1937) in: Eucken A, Jacob M (Hrsg.) Der Chemieingenieur.

Akadernische Verlagsgesellschaft, Leipzig, Bd. lIllI, S. 359 [1.8] Zeldowitsch YB (1939) Acta Phys.-Chim. 10:583 [1.9] Thiele EW (1939) Ind. Eng. Chern. 31:916 [1.10] Wicke E, Kallenbach R (1941) Kolloid. Zeitschr. 97:135 [1.11] Wicke E, Brotz W (1949) Chernie-Ing.-Techn. 21:219 [1.12] Wicke E, Hedden K (1953) Z. Elektrochern. 57:636 [1.13] Beusch H, Fieguth P, Wicke E (1972) Chernie-Ing.-Tech. 44:445 [1.14] Weisz PB, Hicks JS (1962) Chern. Eng. Sci. 17:265 [1.15] Mason EA, Malinauskas AP (1983) Gas Transport in Porous Media: The Dusty

Gas Model. Elsevier, Amsterdam

2 Theoretische Grundlagen

[2.1] Maxwell JC (1860) Phil. Mag. 20:21 [2.2] Deriagin BV, Bakanov SP (1957) Dokl. Akad. Nauk SSSR 115:267 [2.3] Deriagin BV, Bakanov SP (1957) Zh. tekh. Fiz. 27:2056 [2.4] Evans III RB, Watson GM, Mason EA (1961) J. Chern. Phys. 35:2076 [2.5] Evans III RB, Watson GM, Mason EA (1962) J. Chern. Phys. 36:1894 [2.6] Mason EA, Evans III RB, Watson GM (1963) J. Chern. Phys. 38:1808 [2.7] Mason EA, Malinauskas AP (1964) J. Chern. Phys. 41:3815 [2.8] Mason EA, Malinauskas AP (1967) J. Chern. Phys. 46:3199 [2.9] Chapman S, Cowling TG (1970) The Mathematical Theory of Non-Uniform

Gases. Cambridge University Press, Cambridge (3rd Ed.) [2.10] Grad H (1949) Commun. Pure and Appl. Math. 2:331 [2.11] Zhdanov V, Kagan Y, Sozykin A (1962) Soviet Physics JETP 15:596 [2.12] Reif F, (1976) Physikalische Statistik und Physik der Wiirme. Walter de Gruyter,

Berlin [2.13] Boltzmann L (1981) Vorlesungen uber Gastheorie. FriedT. Vieweg & Sohn,

Braunschweig (erweiterter Nachdruck einer bei Ambrosius Barth (Leipzig) in den Jahren 1896-98 erschienenen Ausgabe)

[2.14] Cunningham RE, Williams RJJ (1980) Diffusion in Gases and Porous Media. Plenum Pess, New York

290 Literaturverzeichnis

[2.15] Gornbosi TI (1994) Gaskinetic Theory. Cambridge University Press, Cambridge [2.16] Hirschfelder JO, Curtiss CF, Bird RB (1954) Molecular Theory of Gases and

Liquids. John Wiley & Sons, New York [2.17] Waldmann L (1959) Z. Naturforsch. 14a:589 [2.18] Bosanquet CH (Sept. 27,1944) British T.A. Report 507 [2.19] Pollard W G, Present RD (1948) Phys. Rev. 73:762 [2.20] Monchick L, Munn RJ, Mason EA (1966) J. Chern. Phys. 45:3051 [2.21] Monchick L, Sandler SI, Mason EA (1968) J. Chern. Phys. 49:1178 [2.22] Monchick L, Yun KS, Mason EA (1963) J. Chern. Phys. 39:654 [2.23] Alievski MYa., Zhdanov VM (1969) Soviet Phys. - JETP 28:116 [2.24] Mason EA, Malinauskas AP (1983) Gas Transport in Porous Media: The Dusty-

Gas-Model. Elsevier, Amsterdam [2.25] Schneider P, Gelbin D (1985) Chern. Eng. Sci. 40:1093 [2.26] Fott P, Petrini G, Schneider P (1983) CoIl. Czech. Chern. Commun. 48:215 [2.27] Bird GA (1994) Molecular Gas Dynamics And The Direct Simulation of Gas

Flows. Clarendon Press, Oxford [2.28] Nanbu K (1980) J. Phys. Soc. Japan 49:2042; 49:2050; 49:2055 [2.29] Graham T (1833) Phil. Mag. 2:175; 2:269; 2:351 [2.30] Lang H, Loyalka SK (1972) Z. Naturforsch. 27a: 1307 [2.31] Aris R (1975) The Mathematical Theory of Diffusion and Reaction in Permeable

Catalysts. Clarendon Press, Oxford (2 Vols.) [2.32] Reid RC, Prausnitz JM, Poling BE (1986) The Properties of Gases and Liquids.

McGraw Hill, New York [2.33] Brinkman HC (1947) Appl. Sci. Res. Al:27 [2.34] Beavers GS, Joseph DD (1967) J. Fluid Mech. 30:197 [2.35] Durst F, Haas R, Interthal W (1987) J. Non-Newtonian Fluid Mech. 22:169 [2.36] Jackson R (1977) Transport in Porous Catalysts. Elsevier, Amsterdam [2.37] Wesselingh JA, Krishna R (1990) Mass Transfer. Ellis Horwood, Chichester [2.38] Burghardt A (1986) Chern. Eng. Process 21:229 [2.39] Krishna R (1993) Chern. Eng. Sci. 48:845 [2.40] Krishna R, Wesselingh JA (1997) Chern. Eng. Sci. 52:861 [2.41] Tan Z, Varghese PL (1994) J. Cornp. Phys. 110:327 [2.42] Cercignani C (1975) Theory and Application of the Boltzmann Equation. Elsevier,

Amsterdam [2.43] Babovsky H (1998) Die Boltzmann-Gleichung: Model/bildung - Numerik-

Anwendung. B.G. Teubner Stuttgart, Leipzig [2.44] Schnitzlein K, Hofmann H (1988) Cornput. Chern. Eng. 12: 1157 [2.45] Toor HL (1957) AIChE 13:198 [2.46] Duncan JB, Toor HL (1962) AIChE J 8:38 [2.47] Van Swol F, Heffelfinger GS (1996) Mat. Res. Soc. Symp. Proc. 408:299 [2.48] Heffelfinger OS, Ford DM (1998) Mol. Phys. 94:659 [2.49] Thompson AP, Ford DM, Heffelfinger OS (1998) J. Chern. Phys. 109: 1 [2.50] Ounn RD, King CJ 81969) AIChE J 15:507 [2.51] OmataH, Brown LF (1972) AIChE J 18:967 [2.52] Abed R, Rinker RO (1974) J. Catal. 34:246 [2.53] Youngquist OR (1970) Ind. Eng. Chern. 62:52 [2.54] Abed R, Rinker RO (1973) AIChE J. 19:618 [2.55] Chen OT, Rinker RO (1979) Chern. Eng. Sci. 34:51 [2.56] Hesse D, Koder J (1973) Chern. Eng. Sci. 28:807 [2.57] Hugo P, Wicke E (1968) Chern.-Ing.-Tech. 40:1133 [2.58] Remick RR, Oeankoplis CJ (1974) Chern. Eng. Sci. 29: 1447 [2.59] Klavetter EA, Liapsis AI, Crosser OK, Litchfield RJ(1982) Chern. Eng. Sci. 37:997 [2.60] Feng CF, Stewart WE (1973) Ind. Eng. Chern. Fundam. 12: 143 [2.61] Feng CF, Kostrov VV, Stewart WE (1974) Ind. Eng. Chern. Fundam. 13:5 [2.62] Hesse D, Hugo P (1972) Chern.-Ing.-Tech. 44:1312 [2.63] Haugaard J, Livbjerg H (1998) Chern. Eng. Sci. 53:2941

Literaturverzeichnis 291

[2.64] Wong RL, Denny VB (1975) Chern. Eng. Sci. 30:709 [2.65] Wong RL, Hubbard GL, DennyVE (1976) Chern. Eng. Sci. 31:541 [2.66] Weisz P, Hicks JS (1962) Chern. Eng. Sci. 17:265 [2.67] Kaza KR, Jackson R (1980) Chern. Eng. Sci. 35:1179 [2.68] Kaza KR, Villadsen J, Jackson R (1980) Chern. Eng. Sci. 35:17 [2.69] Smensen JP, Stewart WE (1982) Chern. Eng. Sci. 37:1103 [2.70] Villadsen J, Michelsen M L (1978) Solution o/Differential Equation Models by

Polynomial Approximation. Prentice Hall, Englewood-Cliffs [2.71] Davis ME, Fairweather G, Yamanis J (1982) Chern. Eng. Sci. 27:447 [2.72] Nan HS, Dias MM, Rodrigues AE (1995) Chern. Eng. J. 57:101 [2.73] Park SH, Kim YG (1984) Chern. Eng. Sci. 39:523 [2.74] Park SH, Kim YG (1984) Chern. Eng. Sci. 39:533 [2.75] Otani N, Smith JM (1966) J. Catal. 5:332 [2.76] Balder JR, Petersen EE (1968) J. Catal. 11:195 [2.77] Wakao N, Kimura H, Shibata M (1969) J. Chern. Eng. Japan 2:51 [2.78] Steisel N, Butt JB (1967) Chern. Eng. Sci. 22:469 [2.79] Wakao N, Naruse Y (1974) Chern. Eng. Sci. 29:1304 [2.80] Toei R, Okazaki M, Nakanishi K, Konado Y, Hayashi M, Shiozaki Y (1973)

J. Chern. Eng. Japan 6:50 [2.81] Ryan D, Carbonell RG, Whitaker S (1980) Chern. Eng. Sci. 35:10 [2.82] Fott P, Schneider P (1984) Chern. Eng. Sci. 39:643 [2.83] Berg DA, Harris TJ (1993) Ind. Eng. Chern. Res. 32:2147 [2.84] Garcia-Ochoa F, Santos A (1994) Chern. Eng. Sci. 49:3091 [2.85] Hartig F, Keil F J (1993) Ind. Eng. Chern. Res. 32:424 [2.86] Elnashaie SSEH, Elshishini SS (1993) Modelling, Simulation and Optimization 0/

Industrial Fixed Bed Catalytic Reactors. Gordon and Breach Science Pub!., Langhorn

[2.87] Lee HH (1985) Heterogenous Reactor Design. Butterworth Pub!., Boston [2.88] Veldsink JW, Versteeg GF, van Swaaij WPM (1994) J. Membrane Sci. 92:275 [2.89] Ofori JY, Sotirchos SV (1996) Ind. Eng. Chern. Res. 35:1275 [2.90] Tuchlenski A, Schramm 0, Seidel-Morgenstern A (1997) Chern.-Ing.-Tech.

69:1117 [2.91] Jensen KF, Reyes S (1985) Chern. Eng. Sci. 40:1723 [2.92] Burganos VN, Sotirchos SV (1987) AIChE J. 33:1678 [2.93] Hill TL (1960) Statistical Thermodynamics. Addison-Wesly Pub!., London [2.94] McQuarrie DA (1976) Statistical Mechanics. Harper & Row Publishers,New York [2.95] Chandlers D (1987) Introduction to Modern Statistical Mechanics. Oxford

University Press, Oxford [2.96] Reed TM (1973) Applied Statistical Mechanics. McGraw Hill, New York [2.97] Balian R (1991) From Microphysics to Macrophysics. Springer-Verlag, Heidelberg [2.98] Ben-Nairn A (1992) Statistical Thermodynamics/or Chemists and Biochemists.

Plenum Press, New York [2.99] Kubo R (1981) Statistical Mechanics. North-Holland Pub!., Amsterdam [2.100] Romer H, Fink T (1994) Statistische Mechanik. VCH, Weinheirn [2.101] ReifF (1976) Grundlagen der Physikalischen Statistik und Physik der

Wiirme. Walter de Gruyter, Berlin [2.102] Kuypers F (1997) Klassische Mechanik. Wiley-VCH, Weinheirn [2.103] Press W, Teukolsky SA, Vetterling WT, Flannery BP (1992) Numerical Recipes.

Cambridge University Press, Cambridge [2.104] Zwanzig R (1965) Ann. Rev. Phys. Chern. 16:67 [2.105] Crank J (1975) The Mathematics o/Diffusion. Clarendon Press, Oxford [2.106] Karger J, Ruthven DM (1992) Diffusion in Zeolites and other Microporous

Materials. John Wiley & Sons, New York [2.107] Hinderer J, Keil F J (1996) Chern. Eng. Sci. 51:2667 [2.108] Cracknell RF, Nicholson D, Quirke N (1995) Phys. Rev. Lett. 74:2463


[2.109] Allen MP, Tildesley DJ (1987) Computer Simulation o/Liquids. Clarendon Press, Oxford

[2.110] Frenkel D, Smit B (1996) Understanding Molecular Simulation. Academic Press, San Diego

[2.111] Rubinstein RY (1981) Simulation and Monte Carlo Methods. John Wiley, New York

[2.112] Gubbins KE, Quirke N (Eds.) (1996) Molecular Simulation and Industrial Applications. Gordon and Breach Science Publ., Amsterdam

[2.113] Press WH, Flannery BP, Teukolsky WT, Vetteling WT (1996) Numerical Recipes in FORTRAN 90. Cambridge University Press, Cambridge

[2.114] Metropolis N, Rosenbluth AW, Rosenbluth MN, Teller AN, Teller E (1953) J. Chern. Phys. 21: 1087

[2.115] Binder K, Heermann D (1992) Monte Carlo Simulation in Statistical Physics. Springer-Verlag, Heidelberg

[2.116] Norman GE, Filinov VS (1969) High Temp. (USSR) 7:216 [2.117] Gould H, Tobochnik Y (1996) Computer Simulation Methods. Addison-Wesley,

Reading [2.118] Binder K (Ed.) (1992) in The Monte Carlo Method Condensed Matter PhysiCS.

Springer, Heidelberg [2.119] Heermann DW (1990) Computer Simulation Methods in Theoretical Physics.

Springer, Heidelberg [2.120] Kalos MH, Whitlock PA (1986) Monte Carlo Methods. John Wiley, New York [2.121] Haile JM (1992) Molecular Dynamics Simulation. John Wiley, New York [2.122] Haberlandt R, Fritzsche S, Peinel G, Heinzinger K (1995) Molekulardynamik.

Vieweg, Braunschweig [2.123] Rapaport DC (1995) The Art o/Molecular Dynamics Simulation. Cambridge

University Press, Cambridge [2.124] Rowley RL (1994) Statistical Mechanics/or Thermophysical Property

Calculations. Prentice Hall, Engelwood Cliffs [2.125] van Gunsteren WF, Berendsen HJC (1990) Angew. Chern. 102:1020 [2.126] Gear CW (1971) Numerical Initial Value Problems in Ordinary Differential

Equations. Prentice Hall, Englewood Cliffs [2.127] Bolton K, Nordholm S (1994) J. Comput. Phys. 113:320 [2.128] Berkowitz M, McLammon JA (1982) Chern. Phys. Lett. 90:215 [2.129] Maitland GC, Rigby M, Smith EB, Wakeham WA (1981) Intermolecular Forces:

Their Origin and Determination. Clarendon Press, Oxford [2.130] Rigby M, Smith EB, Wakeham WA, Maitland GC (1986) Forces between

Molecules. Clarendon Press, Oxford [2.131] Bowen JP, Allinger NL (1991) in: Lipkowitz KB, Boyd DB (Eds.) Reviews in

Computational Chemistry. Vol. 2. VCH, Weinheim [2.132] Landis CR, Root DM, Cleveland T (1995) in: Lipkowitz KB, Boyd DB (Eds.)

Reviews in Computational Chemistry. Vol. 6. VCH, Weinheim [2.133] Osawa E, Lipkowitz KB (1995) in: Lipkowitz KB, Boyd DB (Eds.) Reviews in

Computational Chemistry. Vol. 6. VCH, Weinheim [2.134] Gao J (1995) in: Lipkowitz KB, Boyd DB (Eds.) Reviews in Computational

Chemistry. Vol. 7. VCH, Weinheim [2.135] Pettersson I, Liljefors T (1996) in: Lipkowitz KB, Boyd DB (Eds.) Reviews in

Computational Chemistry. Vol. 9. VCH, Weinheim [2.136] Ewald PP (1921) Ann. Phys. 64:253 [2.137] Hansen JP (1986) in: Ciccotti G, Hoover WG (Eds.) Molecular Dynamics

Simulations o/Statistical Mechanics Systems. Proceedings of the 97th Int. "Enrico Fermi" School of Physics, North Holland, Amsterdam

[2.138] Caillol J-M, Levesque D (1991) J. Chern. Phys. 94:597 [2.139] Hautmann J, Klein ML (1992) Mol. Phys. 74:379 [2.140] Darden T, York D, Pedersen L (1993) J. Chern. Phys. 98:10089 [2.141] Leckner J (1989) Physica A 157:826

[2.142] Leckner J (1989) Physica A 176:485 [2.143] Greengard L, Rokhlin V (1987) J. Compo Phys. 73:325 [2.144] Schmidt KE, Lee MA (1991) J. Stat. Phys. 63:1223


[2.145] Ding HQ, Karasawa N, Goddard III WA (1992) J. Chern. Phys. 97:4309 [2.146] Ding HQ, Karasawa N, Goddard III WA (1992) Chern. Phys. Lett. 196:6 [2.147] Esselink K (1995) Compo Phys. Comm. 87:375 [2.148] Tuckerman M, Martyna GJ, Berne BJ (1992) J. Chern. Phys. 97:1990 [2.149] Nicholson D (1997) in: Fraissard J (Ed.) Physical Adsorption: Experiment. Theory

and Applications. Kluwer Academic Publ., Dordrecht [2.150] Nicholson D, Boutin A, Pellenq RJ-M (1996) Mol. Sim. 17:217 [2.151] Weiner SJ, Kollmann DA, Singh UC, Ghio C, Alagona G, Profeta S, Weiner P

(1984) J. Am. Chern. Soc. 106:765 [2.152] Brooks BR, Bruccoleri RE, Olafson BD, States 01, Swaminathan S, Karplus M

(1983) J. Compo Chern. 4:187 [2.153] van Gunsteren WF, Berendsen HJC (1987) Groningen Molecular Simulation

(GROMOS) Library Manual. Bionas, Groningen [2.154] Burkert U, Allinger NL (1982) Molecular Mechanics. Am. Chern. Soc.,

Washington [2.155] Allinger NL, Yuh YR, Lii J-J (1989) J. Am. Chern. Soc. 111 :8551 [2.156] Mayo SL, Olafson BD, Goddard III WA (1990) J. Phys. Chern. 94:8897 [2.157] Kunz RW (1991) Molecular Modellingfor Anwender. B.G. Teubner, Stuttgart [2.158] Rappe AK, Casewit CJ, Colwell KW, Goddard III WA, SkiffWM (1992) J. Arn.

Chern. Soc. 114:10024 [2.159] Maple JR, Thatcher TS, Dinur U, Hagler AT (1990) Chern. Design Autom. News 5:5 [2.160] Berendsen HJ C, Postma JPM, van Gunsteren WF, Di Nola A, Haak JR (1984)

J. Chern. Phys. 81 :3684 [2.161] Hoover WG (1985) Phys. Rev. A 31:1695 [2.162] Ryckaert JP, Cicotti G, Berendsen HJC (1977) J. Compo Phys. 23:327 [2.163] Anderson H C (1983) J. Compo Phys. 89:5115 [2.164] Tobias 01, Brooks III CL (1988) J. Chern. Phys. 89:5115 [2.165] Hanley HJM (1985) in [2.137] [2.166] Duane S, Kennedy AD, Pendleton BJ, Roweth D (1987) Phys. Lett. B 195:216 [2.167] Mehlig B, Heermann DW, Forrest BM (1992) Mol. Phys. 76:1347 [2.168] Mehlig B, Heermann DW, Forrest BM (1992) Phys. Rev. B 45:679 [2.169] Neal RM (1994) J. Compo Phys. 111:194 [2.170] Anderson JB (1995) Adv. Chern. Phys. Vol. XCI, John Wiley, New York [2.171] Voter AF (1997) J. Chern. Phys. 106:4665 [2.172] Car R, Parrinello (1985) Phys. Rev. Lett. 55:2471 [2.173] Remler DK, Madden PA (1990) 70:921 [2.174] Galli R, Pasquarello A (1993) in: Allen MP, Tildesley 01 (Eds.) Computer

Simulation in Chemical PhysiCS. NATO ASI, Kluwer, Dordrecht [2.175] Toxvaerd S (1991) Mol. Phys. 72: 159 [2.176] Esselink K, Loyens L01C, Smit B (1995) Phys. Rev. E 51:1560 [2.177] Vattulainen I, Ala-Nissila T, Kankaala K (1994) Phys. Rev. Lett. 73:2513 [2.178] Zhdanov VP (1991) Elementary Physicochemical Proceses on Solid Surfaces.

Plenum Press, New York [2.179] Chen Y, Yang RT (1997) Stud. Surf. Sci. Catal. 104:487 [2.180] Leach AR (1996) Molecular Modeling. Longman, Singapore [2.181] Schlecht MF (1998) Molecular Modeling on the Pc. Wiley-VCH, New York [2.182] Thompson AP, Ford DM, Heffelfinger GS (1998) J. Chern. Phys. 109:6406 [2.183] van Santen RA, Niemantsverdriet JW (1995) Chemical Kinetics and Catalysis.

Plenum Press, New York [2.184] Gasser RPH (1985) An Introduction to Chemisorption and Catalysis by Metals.

Clarendeon Press, Oxford [2.185] Freund H-J (1995) Ber. Bunsenges. Phys. Chern. 99:1261 [2.186] Freund H-J (1997) Angew. Chern. 109:444


[2.187] Freund H-J (1997) in: Ertl G, Knazinger H, Weitkamp J: Handbook of Heterogeneous Catalysis. Vol. 3, VCH, Weinheim, pp. 911-942

[2.188] Ertl G (1995) Ber. Bunsenges. Phys. Chern. 99:1282 [2.189] Freund H-J, Kuhlenbeck H, Staemmler V (1996) Rep. Prog. Phys. 59:283 [2.190] Hudson JB (1992) Surface Science - An Introduction. Butterworth-Heinemann,

Boston [2.191] Christmann K (1991) Surface Physical Chemistry. SteinkopffVerlag, Darmstadt,

Springer-Verlag, New York [2.192] Henzler M, Gapel W (1994) Oberfliichenphysik des F estkorpers. B. G. Teubner,

Stuttgart [2.193] SomOljai GA (1994) Introduction to Surface Chemistry and Catalysis.

John Wiley, New York [2.194] Prutton M (1994) Introduction to Surface Physics. Clarendon Press, Oxford [2.195] Niemantsverdriet JW (1995) Spectroscopy in Catalysis. VCH, Weinheim [2.196] WoodruffDP, Delchar TA (1994) Modern Techniques of Surface Science.

(2nd Ed.), Cambridge University Press, Cambridge [2.197] Zangvill A (1988) Physics at Surfaces. Cambridge University Press, Cambridge. [2.198] Masel Rl (1996) Principles of Adsorption and Reaction on Solid Surfaces.

John Wiley, New York [2.199] Holloway S, Nerskov JK (1991) B~mding at Surfaces. University Press, Liverpool [2.200] van Santen RA (1991) Theoretical Heterogeneous Catalysis. World Scientific,

Singapore [2.201] Fraissard J (Ed.) (1997) Physical Adsorption: Experiment, Theory and

Applications. Kluwer Academic Publishers, Dordrecht [2.202] Rudzinski W, Steele WA, Zgrablich G (Eds.) (1997) Equilibria and Dynamics of

Gas Adsorption on Heterogeneous Solid Surfaces. Elsevier, Amsterdam [2.203] Rudzinski W, Everett HD (1992) Adsorption of Gases on Heterogeneous Surfaces.

Academic Press, London [2.204] Jaroniec M, Madey R (1988) Physical Adsorption on Heterogeneous Solids.

Elsevier, Amsterdam [2.205] Yates IT (1997) Experimental Innovations in Surface Science. AlP Press,

Springer, New York [2.206] Clark A (1970) The Theory of Adsorption and Catalysis. Academic Press, New

York [2.207] Cox PA (1992) Transition Metal Oxides. Clarendon Press, Oxford [2.208] Henrich YE, Cox PA (1994) The Surface Science of Metal Oxides. Cambridge

University Press [2.209] Kiselev VF, Krylov OV (1989) Adsorption and Catalysis on Transition Metals

and their Oxides. Springer-Verlag, Heidelberg (1989) [2.210] Zhdanov VP (1991) Elementary Physico Chemical Processes on Solid

Surfaces.Plenum Press, New York [2.211] Bruch LW, Cole MW, Zaremba E (1997) Physical Adsorption: Forces and

Phenomena. Clarendon Press, Oxford [2.212] Tamaru K (Ed.) (1993) Dynamic Processes on Solid Surfaces. Plenum Press,

New York [2.213] Dines TJ, Rochester CH, Thomson J (Eds.) (1992) Catalysis and Surface

Characterisation. The Royal Society of Chemistry, Cambridge [2.214] Rettner CT, Ashfold MNR (Eds.) (1991) Dynamics of Gas-Surface Interactions.

The Royal Society of Chemistry, Cambridge [2.215] Grunze M, Kreuzer HJ (Eds.) (1987) Kinetics of Interface Reactions. Springer

Verlag, Heidelberg [2.216] Desjonqueres MC, Spanjaard D (1996) Concepts in Surface Physics. (2nd Ed.)

Springer-Verlag, Heidelberg [2.217] Lawley KP (Ed.) (1989) Molecule Surface Interactions, John Wiley, New York [2.218] Unger KK, Rouquerol J, Sing KSW, Kral H (Eds.) (1988) Characterization of

Porous Solids. Elsevier, Amsterdam


[2.219] Rodriguez-Reinoso F, Rouquerol J, Sing KSW (Eds.) (1991) Characterization of Porous Solids II Elsevier, Amsterdam

[2.220] Rouquerol J, Rodriguez-Reinoso F, Sing KSW, Unger KK (Eds.) (1994) Characterization of Porous Solids III. Elsevier, Amsterdam

[2.221] Gregg SJ, Sing KSW (1991) Adsorption, Surface Area and Porosity. Academic Press, London

[2.222] Suzuki M (Ed.) (1993) Fundamentals of Adsorption. Elsevier, Amsterdam [2.223] Valenzuela DP, Meyers AL (1989) Adsorption Equilibrium Data Book. Prentice

Hall [2.224] Langmuir I (1918) 1. Arner. Chern. Soc. 40:1361 [2.225] Brunauer S (1945) The Adsorption of Gases and Vapors. Vol. 1, Princeton

University Press, Princeton, New Jersey [2.226] Fowler RH (1935) Proc. Camb. Philos. Soc. 31 :260 [2.227] Volmer MA, Mahnert P (1925) Z. Physik. Chern. 115:239, 115:253 [2.228] Freundlich H (1909) Kapillarchemie. Akadernische Bibliothek, Leipzig [2.229] Toth J (1971) Acta Chirn. Acad. Sci. Hung. 69:311 [2.230] Sips RJ (1948) 1. Chern. Phys. 16:490 [2.231] Temkin M, Pyzhev V (1940) Acta Physicochirn. URSS 12:327 [2.232] Vasquez N, Muscat A, Madix RJ (1994) Surf. Sci. 301 :83 [2.233] Steele WA (1974) The Interaction of Gases with Surfaces. Pergamon Press,

New York [2.234] Halsey GD, Taylor HS (1947) J. Chern. Phys. 15:624 [2.235] Keil FJ, Schreiber D (1994) Chern.-Ing.-Techn. 66:201 [2.236] Fowler RH (1935) Proc. Camb. Philos. Soc. 31:260 [2.237] Crossley A, King DA (1980) Surf. Sci. 95:131 [2.238] Hill TL (1952) Adv. Catal. 4:211 [2.239] Tovbin YK (1991) Prog. Surf. Sci. 34:1 [2.240] Tovbin YK (1997) in [2.202], S. 105 [2.241] Persson BNJ Surf. Sci. Rep. 15:1 [2.242] Hill TL (1960) An Introduction to Statistical Thermodynamics. Addison-Wesley

Publ. Cornp., London [2.243] Greiner W, Neise L, Stocker H (1987) Theoretische Physik. Bd. 9, Verlag Harri

Deutsch, Frankfurt [2.244] Eyring H, Henderson D, Stover BJ, Eyring EM (1982) Statistical Mechanics and

Dynamics, John Wiley, New York, S. 437 [2.245] Bragg WL, Williams EJ (1934) Proc. Royal Soc. A 145:689 [2.246] Bethe HA, Wills WH (1935) Proc. Roy. Soc. A 150:552 [2.247] Peierls RE (1936) Proc. Camb. Philos. Soc. 32:477 [2.248] Land TA, Michely T, Behm PJ, Hemminger JC, Comsa G (1991) J. Appl. Phys. A

53:414 [2.249] Hoory E, Prausnitz JM (1967) Chern. Eng. Sci. 22: 1025 [2.250] Adamson AW (1990) Physical Chemistry of Surfaces. John Wiley, New York [2.251] Jovanovic DS (1969) Zeit. Koll. u. Polymere 235:1203,1214 [2.252] Adams DJ (1974) Mol. Phys. 28:1241 [2.253] Speedy RJ (1977) 1. Chern. Soc. Faraday Trans. II 73:714 [2.254] SchaafP, Talbot J (1989) 1. Chern. Phys. 91:4401 [2.255] Levesque D, Weis JJ, Hansen JP (1987) in Binder K (Ed.) Applications of the

Monte Carlo Method in Statistical Physics, Springer-Verlag, Heidelberg, S. 37 [2.256] Myers AL, Prausnitz JM (1965) AIChE J 11:121 [2.257] Rudisil EN, LeVan MD (1992) Chern. Eng. Sci. 47: 1239 [2.258] Karavias F, Myers AL (1991) Mol. Sirn. 8:23 [2.259] Sokolowski S, Fisher J (1990) Mol. Phys. 71:393 [2.260] MacElroy JMD, Seaton NA, Friedman SPin [2.202], S. 837 [2.261] Cracknell RF, Nicholson D, Quirke N in: Gubbins KE,Quirke N (1996) Molecular

Simulation and Industrial Applications. Gordon & Breach, Amsterdam, S. 459 [2.262] Nitta T, Kiriyama H, Shigeta T (1997) Langmuir 13:903


[2.263] Brunauer S, Emmett PH, Teller E (1938) J. Am. Chern. Soc. 60:309 [2.264] Nicholson D, Parsonage NG (1982) Computer Simulation and the Statistical

Mechanics of Adsorption. Academic Press, New York [2.265] Dubinin MM, Radushkevich LV (1947) Dok!. Akad. Nank SSSR 55:331 [2.266] Hobson JP (1961) J. Chern. Phys. 34: 1850 [2.267] Cerofolini GF (1972) 1. Low Temp Phys. 6:473 [2.268] Rudzinski W, Sokolowski S, Jaroniec M, Toth J (1975) Z. Phys. Chern. (Leipzig)

256:273 [2.269] Baule B (1914) Annalen der Physik 44: 145 [2.270] Goodman FO (1967) Surf. Sci. 7:391 [2.271] Thomas LB (1967) in: Brundin CL (Ed.) Rarefied Gas Dynamics. Academic

Press, New York, S. 155 [2.272] Arumainayagam CR, Madir RJ, McMaster MC, Suzawa VM, Tulley JC (1990)

Surf. Sci. 226: 180 [2.273] Zwanzig RW (1960) 1. Chern. Phys. 32:1173 [2.274] D'Evelyn MP, Steinruck H-P, Madix RJ (1987) Surf. Sci. 180:47 [2.275] Lapujoulade J, Neil KS (1973) Surf. Sci. 35:288 [2.276] Penka V, Christmann K, Ertl G (1984) Surf. Sci. 136:307 [2.277] Poelsema B, Verheij LK, Comsa G (1985) Surf. Sci. 152/153:496 [2.278] Ehsasi M, Christmann K (1988) 194: 172 [2.279] Christmann K, Ertl G, Schober 0 (1974) 1. Chern. Phys. 60:4719 [2.280] Holloway PJ, Hudson JB (1974) Surf. Sci 43:123 [2.281] Ertl G (1983) 1. Vac. Sci. Technol. Al:1247 [2.282] Morris MA, Bowker M, King DA (1984) in Barmford CH, Tipper CFH,

Compton RG (Eds.) Comprehensive Chemical Kinetics. (Simple Processes at the Gas Solid Interface). Elsevier, Amsterdam, Vol. 19, S. 42

[2.283] Tenner MG, Kuipers EW, Kleyn AW (1979) 89:6552 [2.284] Fecher GH, Bonsering N, Volkmer M, Pawlitzky B, Heinzmann K (1990) Surf.

Sci. Lett. 230:Ll69 [2.285] Langmuir I (1916) Phys. Rev. 8:149 [2.286] Horgan AM, King DA (1969) in Somorjai GA (Ed.) The Structure and Chemistry

of Solid Surfaces. John Wiley, New York [2.287] Ceyer ST (1988) Ann. Rev. Phys. Chern. 39:680 [2.288] Langmuir I (1921) Trans. Faraday Soc. 17:111 [2.289] Kisliuk P (1957) 1. Phys. Chern. Solids 3:95 [2.290] Taylor HS (1925) Proc. Roy. Soc. A 108: 105 [2.291] Roberts JK, Miller AR (1939) Proc. Cambridge Phil. Soc. 35:293 [2.292] Tully JC (1994) Surf. Sci. 299/300:667 [2.293] Kang KC, Mullins CB, Weinberg WH (1990) 1. Chern. Phys. 92:1397 [2.294] Cracknell RF, Nicholson D (1995) Adsorption 1:7 [2.295] Zhu Y, Schmidt LD (1983) Surf. Sci. 129:107 [2.296] Gunter PLI, Niemantsverdriet JW, Ribeiro FH (1997) Catal. Rev.-Sci. Eng. 39:77 [2.297] Zambelli T, Barth N, Wintterlin J, Ertl G (1997) Nature 390:495 [2.298] Redhead PA (1963) Vacuum 12:203 [2.299] Du Z, Sarofin AF, Longwell SP (1990) Energy and Fuels 4:296 [2.300] King DA (1975) Surf. Sci. 47:384 [2.301] Chan CM, Aris R, Weinberg WH (1978) Appl. Surface Sci. 1:360 [2.302] de Jong AM, Niemantsverdriet JW (1990) Surf. Sci. 233:355 [2.303] Haberschaden E, Kiippers J (1984) Surf. Sci. 138:L 147 [2.304] Kang HC, Weinberg WH (1995) Chern. Rev. 95:667 [2.305] Kawasaki K (1966) Phys. Rev. B145:224 [2.306] Lombardo SJ, Bell AT (1988) Surf. Sci. 206: 101 [2.307] Gupta D, Hirtzel CS (1988) Chern. Phys. Lett. 149:527 [2.308] Lombardo SJ, Bell AT (1989) Surf. Sci. 224:451 [2.309] Lombardo SJ, Bell AT (1991) Surf. Sci. Rep. 13:1 [2.310] Dobbs KO, Doren OJ (1993) 1. Chern. Phys. 99:10041


[2.311] Viswanathan R, Burgess DR Jr., Stair PC, Weitz E (1982) J. Vac. Sci. 20:605 [2.312] George AM, DeSantolo AM, Hall RB (1985) Surf. Sci. 159:L425 [2.313] Xiao XD, Zha XD, Daum W, Shen YR (1992) Phys. Rev. B 46:9732 [2.314] Gomer R (1973) Surf. Sci. 38:373 [2.315] Wicke E, Kallenbach R (1941) Kolloid-Z. 17: 135 [2.316] Lozano ML, Tringides MC (1995) Europhys. Lett. 30:537 [2.317] Tringides MC (Ed.) (1997) Surface Diffusion - Atomistic and Collective

Processes. Plenum Press, New York [2.318] Ehrlich G (1982) CRC Cirt. Rev. Solid State Mater. Sci. 10:391 [2.319] King DA (1980) J. Vac. Sci. Techno!' 17:241 [2.320] Grunze M, Kreuzer HJ, Weimer JJ (Eds.) (1988) Diffusion at Interfaces:

Microscopic Concepts. Springer-Verlag, Heidelberg [2.321] Rettner CT, Auerbach DJ, Tully JC, Kleyn AW (1996) 1. Phys. Chern. 100:13021 [2.322] Kapoor A, Yang RT, Wong C (1989) Cata!. Rev.-Sci. Eng. 31:129 [2.323] Naumovets AG, Vedula Yu S (1985) Surf. Sci. Rep. 4:365 [2.324] Sadiq A, Binder K (1983) Surf. Sci. 128:350 [2.325] Kehr K, Binder K (1987) in: Applications of the Monte Carlo Method in Statistical

PhYSics, Springer-Verlag, Heidelberg, S. 181 [2.326] Doll JD, Voter AF (1987) Ann. Rev. Phys. Chern., 38:413 [2.327] Lombardo SJ, Bell AT (1991) Surf. Sci. Rep. 13:1 [2.328] Zhdanov VP (1991) Elementary Physical Processes on Solid Surfaces. Plenum

Press, New York [2.329] Zgrablich G (1997) in: Rudzinski W, Steele WA, Zgrablich G (Eds.) Equilibria

and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces. Elsevier, Amsterdam

[2.330] Carman PC (1952) Proc. Roy. Soc. 213A:250 [2.331] Ash R, Barrer RM, Pope CG (1965) Proc. Roy. Soc. 271a:l [2.332] Barer RM (1963) App!. Mat. Res. 2:129 [2.333] Riekert L (1985) AIChE J 31 :863 [2.334] Higashi K, Ito H, Oishi J (1964) Nuclear Sci. Tech. 1 :293 [2.335] Suzuki M, Fujii T (1982) AIChE 1. 28:380 [2.336] Schneider P, Smith JM (1968) AIChE J 14:886 [2.337] Reed EM, Butt JB (1971) 1. Phys. Chern. 75:133 [2.338] Feng C, Stewart W (1973) Ind. Eng. Chern. Fundam. 12: 143 [2.339] Rieckmann C, Keil FJ (1999) Chern. Eng. Sci. 54:3485 [2.340] Sloot HJ, Smolders CA, van Swaaij WPM, Versteeg GF (1992) AIChE J 38:887 [2.341] Chiang S (1997) Chern. Rev. 97:1083 [2.342] Sladek KJ, Gilliland ER, Baddour RF (1974) Ind. Eng. Chern. Fundam. 13:100 [2.343] Okazaki M, Tamon H, Toei R (1981) AIChE J 27:262 [2.344] Satterfield CN (1970) Mass Transfer in Catalysis. MIT Press [2.345] Haul R, Boddenberg B (1972) in: Boreskov GK (Ed.): The Porous Structure of

Catalysts and Transport Processes in Heterogeneous Catalysts. Akademiai Kiado, Budapest

[2.346] Haynes JM, Miller RJL (1982) in: Rouguerol J, Sing KSW (Eds.): Adsorption at the Gas-Solid and Liquid-Solid Interface. Elsevier, Amsterdam

[2.347] Gomer R (1997) in [2.317], S. 427 [2.348] Gomer R, Wortman R, Lundy R (1957) 1. Chern. Phys. 26: 2376 [2.349] Satterfield CN, Jino H (1968) Ind. Eng. Chern. Fundam. 7:214 [2.350] Meixner DL, George SM (1993) Surf. Sci. 297:27 [2.351] Tabony J. Cosgrove T (1979) Chern. Phys. Lett. 67:103 [2.352] Schneider P, Smith JM (1968) AIChE J 14:886 [2.353] Schreifels JA, Shi S.-K., White JM (1981) App!. Surf. Sci. 7:312 [2.354] Parera JM , Traffano EM, Muso JC, Pieck CL (1983) in: Pajouk GM, Teichner SJ,

Germain JE (Eds.) Spillover of Adsorbed Species. Elsevier, Amsterdam [2.355] Masai M, Nakahara K, Yabashi M, Murata K, Nishiyama S, Tsuruya S (1983) in

[2.354]


[2.356] Do DO, Rice RG (1987) Chern. Eng. Sci. 42:2269 [2.357] Yoshida H, Maekawa M, Nango M (1991) Chern. Eng. Sci. 461 :429 [2.358] Tuchlenski A, Uchytil P, Seidel-Morgenstern A (1998) 1. Membrane Sci. 140:165 [2.359] Pajonk GM (1997) in: Ertl G, KnOzinger H, Weitkamp J (Eds.) Handbook of

Heterogeneous Catalysis. VCH, Weinheim, Vol. 3, S. 1064 [2.360] Conner WC, Falconer JL (1995) Chern. Rev. 95:759 [2.361] Delmon B, Froment GF (1996) Chern. Rev.-Sci. Eng. 38:69 [2.362] Martin 0, Duprez 0 (1993) in: Inui T, Fujimoto K, Uchijima T, Masai M (Eds.)

New Aspects of Spillover Effects in Catalysis. Elsevier, Amsterdam [2.363] Nam YW, Silveston PL (1993) in: Inui K, Fujimoto K, Uchijima T, Masai M

(Eds.) New Aspects of Spillover Effects in Catalysis. Elsevier, Amsterdam, S. 235 [2.364] DePristo AE, Kara A (1990) Adv. Chern. Phys. 77:163 [2.365] Gadzuk JW (1987) Ann. Rev. Phys. Chern. 87:29 [2.366] Kang HC, Weinberg WH (1995) Chern. Rev. 95:667 [2.367] Reed DA, Ehrlich G (1981) Surf. Sci. 162:588 [2.368] Aris R (1983) Ind. Eng. Chern. Fundam. 22:150 [2.369] Tsotsis TT, Sane RC, Webster lA, Goodard JD (1986) 1. CataI. 101:416 [2.370] Darken L (1948) Trans. AIME 175:185 [2.371] Sevick EM, Bell AT, Theodorou ON (1993) 1. Chern. Phys. 98:3196 [2.372] Wang R, Fichthom KA (1993) Phys. Rev. B 48:18288 [2.373] Riccardo JL, Chade MA, Pereyra YD, Zgrablich G (1992) Langmuir 8:1518 [2.374] Uebing C, Gomer R (1991) 1. Chern. Phys. 95:7626 [2.375] Uebing C, Gomer R (1991) J. Chern. Phys. 95:7636 [2.376] Uebing C, Gomer R (1991) 1. Chern. Phys. 95:7641 [2.377] Uebing C, Gomer R (1991) 1. Chern. Phys. 95:7648 [2.378] Uebing C, Gomer R (1994) J. Chern. Phys. 100:7759 [2.379] Viljoen EC, Uebung C (1997) Langmuir 13:1001 [2.380] Pai S, Doren OJ (1993) Surf. Sci. 291: 185 [2.381] Calhoun A, Doren OJ (1993) J. Phys. Chern. 97:2251 [2.382] Fichthom KA, Raut JS (1997) in [2.317], S. 409 [2.383] Conrad EH (1992) Prog. Surf. Sci. 39:65 [2.384] Krishna R (1990) Chern. Eng. Sci. 45: 1779 [2.385] Krishna R (1993) Gas Sep. Purif. 7:91 [2.386] van den Broeke LJP, Krishna R (1995) Chern. Eng. Sci. 50:2507 [2.387] Breck OW (1974) Zeolite Molecular Sieves. John Wiley, New York, S. 636 [2.388] Karger J, Petzold M, Pfeifer H, Ernst S, Weitkamp J (1992) 1. Catal. 136:283 [2.389] Riekert L (1970) Adv. Catal. 21:281 [2.390] Haag WO, Lago RM, Weisz PB (1982) Faraday Discussions 72:317 [2.391] Garcia SF, Weisz PB (1990) 1. Catal. 121:294 [2.392] Garcia SF, Weisz PB (1993) J. CataI. 142:691 [2.393] Garcia SF, Weisz PB (1993) 1. CataI. 144: 109 [2.394] Loos J-BWP, Verheijen PJT, Moulin JA (1992) Collect. Czech. Chern. Commun.

57:687 [2.395] Van den Broeke LJP, Krishna R (1995) Chern. Eng. Sci. 50:2507 [2.396] Do DD, Do H (1993) Chern. Eng. Sci. 48:2625 [2.397] Xiao J, Wei J (1992) Chern. Eng. Sci. 47:1123 [2.398] Xiao J, Wei J (1992) Chern. Eng. Sci. 47:1143 [2.399] Tsikoyiannis JG, Wei J (1991) Chern. Eng. Sci. 46:233 [2.400] Tsikoyiannis JG, Wei J (1991) Chern. Eng. Sci. 46:255 [2.401] Catlow CRA (Ed.) (1992) Modelling of Structure and Reactivity in Zeolites.

Academic Press, New York [2.402] Theodorou ON, Snurr RQ, Bell AT (1996) in: Lehn J-M (Ed.) Compr.ehensive

Supramolecular Chemistry. Pergamon Press, New York, Vol. 7, S. 507 [2.403] Bell AT, Maginn EJ, Theodorou DN (1997) in: Ertl G, KnOzinger H, Weitkamp J

(Eds.) Handbook of Heterogeneous Catalysis.VCH, Weinheim, Vol. 3, S. 1165 [2.404] Demontis P, Suffritti GB (1997) Chern. Rev. 97:2845


[2.405] Nicholson D, Boutin A, Pellenq RJ-M (1996) Mol. Sirn. 17:217 [2.406] van Santen R, Kramer GJ (1995) Chern. Rev. 95:637 [2.407] Sauer J (1999) in: Schleyer PvR (Ed.) Encyclopedia of Computational Chemistry.

John Wiley, New York, Vol. 5, S. 3248 [2.408] Derouane EG, Andre J-M, Leherte L, Galet P, Vanderveken D, Vercauteren DP,

Fripiat JG (1990) in: Moffat JB (Ed.) Theoretical Aspects of Heterogeneous Catalysis. Van Nostand Reinhold, New York, S. 1

[2.409] Pisani C (Ed.) (1996) Quantum-Mechanical Ab-initio Calculation of the Properties of Crystalline Materials. Springer-Verlag, Heidelberg, Lecture Notes in Chemistry Vol. 67

[2.410] Dernontis P, Suffritti GB, Alberti A, Quartieri S, Fois ES, Gamba A (1986) Gazz. Chirn. Ital. 116:459

[2.411] Dernontis P, Suffritti GB (1997) Mol. Phys. 91:669 [2.412] Keck JC (1967) Adv. Chern. Phys. 13:85 [2.413] Anderson JB (1975) J. Chern. Phys. 62:2446 [2.414] Voter AF (1997) J. Chern. Phys. 106:4665 [2.415] June RL, Bell AT, Theodorou DN (1990) J. Phys. Chern. 94:8232 [2.416] Keil FJ, Hinderer J, Garayhi AR (1999) Catal. Today 59:637 [2.417] June RL, Bell AT, Theodorou DN (1990) J. Phys. Chern. 94:1508 [2.418] Dernontis P, Suffritti GB, Fois ES, Quartieri S (1990) J. Phys. Chern. 94:4329 [2.419] Dernontis P, Suffritti GB, Mura P (1992) Chern. Phys. Lett. 191:553 [2.420] Gosh M, Yashonath S, Ananthakrishna G, Dernontis P, Suffritti GB (1994)

J. Phys. Chern. 98:9354 [2.421] Bennett CH (1975) in: Nowick AS, Burton JJ (Eds.) Diffusion in Solids: Recent

Developments. Acadernic Press, New York, S. 73 [2.422] Chandler D (1978) J. Chern. Phys. 68:2959 [2.423] Yashonath S, Bandyopadhyay S (1994) Chern. Phys. Lett. 228:284 [2.424] Bandyopadhyay S, Yashonath S, (1995) J. Phys. Chern. 99:4286 [2.425] Yashonath S, Santikary P (1994) J. Phys. Chern. 98:6368 [2.426] Bhattacharjee B, Yashonath S (1997) Mol. Phys. 90:889 [2.427] Derouane EG, Andre J-M, Lucas AA (1987) Chern. Phys. Lett. 137:336 [2.428] Chitra R, Yashonath S (1995) Chern. Phys. Lett. 234: 16 [2.429] Dernontis P, Suffritti GB, Fois ES, Quartieri S (1992) J. Phys. Chern. 96:1482 [2.430] Dernontis P, Suffritti GB (1994) Chern. Phys. Lett. 223:355 [2.431] Demontis P, Suffritti GB (1997) Mol. Phys. 91:669 [2.432] Demontis P, Suffritti GB, TiloccaA (1996) J. Chern. Phys. 105:5586 [2.433] Goodbody SJ, Watanabe K, MacGowan D, Walton JPRB, Quirke N (1991)

J. Chern. Soc. Faraday Trans. 87: 1951 [2.434] Dumont D, Bougeard D (1995) 15:650 [2.435] June RL, Bell AT, Theodorou DN (1992) J. Phys. Chern. 196:1051 [2.436] Nicholas JB, Trouw FR, Mertz JE, Iton LE, Hopfinger AJ (1993) J. Phys. Chern.

97:4149 [2.437] Bennett CH (1977) in: Christofferson RE (Ed.) Algorithmsfor Chemical

Computation. American Chemical Society, Washington [2.438] Nowak AK, den Ouden JJ, Pickett SD, Smit B, Cheetham AK, Post MFM,

Thomas JM (1991) J. Phys. Chern. 95:848 [2.439] Hinderer J, Keil FJ (1996) Chern. Eng. Sci. 51:2667 [2.440] Maginn EJ, Bell AT, Theodorou DN (1993) J. Phys. Chern. 97:4173 [2.441] Frenkel D, Smit B (1996) Understanding Molecular Simulation. Academic Press,

San Diego, Kap. 11 [2.442] Snurr RQ, Bell AT, Theodorou DN (1994) J. Phys. Chern. 98:11948 [2.443] Deem MW, Newsam JM, Creighton JA (1992) J. Am. Chern. Soc. 114:7198 [2.444] Srnit B (1995) Mol. Phys. 85:153 [2.445] Maginn EJ, Bell AT, Theodorou DN (1995) J. Phys. Chern. 99:2057 [2.446] Bates SP, van Well WJM, van Santen RA, Smit B (1996) J. Am. Chern. Soc.

118:6753


[2.447] Frank B, Dahlke K, Emig G, Aust E, Broucek R, Nywlt M (1993) Microporous Materials 1:43

[2.448] Trout BL, Chakraborty AK, Bell AT (1997) Chem. Eng. Sci. 52:2265 [2.449] Wang JG, Li YW, Chen SY, Peng SY (1995) Zeolites 15:288 [2.450] Wang JG, Li YW, Chen SY, Peng SY (1994) Catal. Letters 26:189 [2.451] Flory PJ (1943) J. Amer. Chern. Soc. 63:3083 [2.452] Stockmeyer WH (1943) J. Chern. Phys. 11:45 [2.453] Broadbent SR, Hammersley JM (1957) Proc. Camb. Phi. Soc. 53:629 [2.454] Stauffer D, Aharony A (1992) Introduction to Percolation Theory. Taylor &

Francis, London [2.455] Bunde A, Havlin S (1991) Fractals and Disordered Systems. Springer-Verlag,

Heidelberg [2.456] Feder J (1988) Fractals. Plenum Press, New York [2.457] Adler PM (1992) Porous Media. Butterworth, Boston [2.458] Kesten H (1982) Percolation Theory for Mathematicians. Birkhiiuser, Boston [2.459] Grimmett GR (1989) Percolation. Springer-Verlag, Heidelberg [2.460] Hughes BD, Ninham BW (Eds.) (1983). The Mathematics and Physics of

Disordered Media. Springer-Verlag, Heidelberg [2.461] Deutscher G, Zallen R, Adler J (Hrsg.) (1983) Percolation Structures and

Processes. Adam Hilger, Bristol [2.462] Shante VKS, Kirkpatrick S (1970) Adv. Phys. 20:325 [2.463] Essam JW (1980) Rep. Prog. Phys. 43:833 [2.464] Sahimi M (1994) Applications of Percolation Theory. Taylor & Francis, London [2.465] Fisher ME, Essam JW (1961) J. Math. Phys. 2:609 [2.466] Sykes MF, EssamJW (1964) J. Math. Phys. 5:1117 [2.467] Jerauld GR, Hatfield JC, Scriven LE, Davis HT, (1984) J. Phys. C 17:1519 [2.468] Jerauld GR, Scriven LE, Davis HT (1984) J. Phys. C 17:3429 [2.469] Fisher ME (1971) in: Critical Phenomena: Enrico Fermi Summer School

(Green MS (Ed.». Academic Press, New York [2.470] Leath PL (1976) Phys. Rev. B 14:5046 [2.471] Hoshen J, Kopelman R (1976) Phys. Rev. B 14:3428 [2.472] Herrmann HJ, Stanley HE (1984) Phys. Rev. Lett. 53: 1121 [2.473] Gould H, Tobochnik J (1996) An Introduction to Computer-Simulation Methods.

(2. Auflage) Addison-Wesley, New York [2.474] Gates BC (1992) Catalytic Chemistry. John Wiley, New York [2.475] Gates BC, Katzer JR, Schuit GCA (1979) Chemistry of Catalytic Processes.

McGraw-Hill, New York [2.476] Satterfield CN (1991) Heterogeneous Catalysis in Practice. McGraw-Hill,

New York (2. Auflage) [2.477] Farrauto RJ, Bartholomew CH (1997) Fundamentals of Industrial Catalytic

Processes. Blackie Academic & Professional, London [2.478] Cybulski A, Moulijn JA (Eds.) (1998) Structured Catalysts and Reactors. Marcel

Dekker, New York [2.479] Twigg MV (Ed.) (1996) Catalyst Handbook. Manson Publishing, London

(2. Auflage) [2.480] Ertl G, Knozinger H, Weitkamp J (1997) Handbook of Heterogeneous Catalysis.

VCH, Weinheim (5 Vols.) [2.481] Kripylo P, Wendlandt K-P, Vogt F (1993) Heterogene Katalyse in der chemischen

Technik. Deutscher Verlag fUr Grundstoffindustrie, Leipzig, Stuttgart [2.482] Hagen J (1996) Technische Katalyse. VCH, Weinheim [2.483] Trimm DL (1980) Design of Industrial Catalysts. Elsevier, Amsterdam [2.484] Le Page JF (1987) Applied Heterogeneous Catalysis. Edition Technip, Paris [2.485] Matar S, Hatch LF (1994) Chemistry of Petrochemical Processes. GulfPubl.

Company, Houston [2.486] Moulijn JA, van Leeuwen PWNM, van Santen RA (Eds.) (1993) Catalysis.

Elsevier, Amsterdam


[2.487] Stiles AB, Koch TA (1995) Catalyst Manufacture. Marcel Dekker, New York (2. Auflage)

[2.488] Hougen AO, Watson KM (1948) Chemical Process Principles. John Wiley, New York

[2.489] N01'skov JK, Stoltze P, Nielsen U (1991) Cat. Lett. 9:173 [2.490] Somorjai GA (1994) Introduction to Surface Chemistry and Catalysis. John

Wiley, New York [2.491) Madix RJ (1994) Surface Reactions. Springer-Verlag, Heidelberg [2.492] Thomas JM, Thomas WJ (1996) Principles and Practice of Heterogeneous

Catalysis. VCH, Weinheim [2.493] Taylor HS (1925) Proc. Royal Soc. London A 108: 105 [2.494] Boudart M (1969) Adv. Catal. 20:153 [2.495] Boudart M, Djega-Mariadassou G (1984) Kinetics of Heterogeneous Catalytic

Reactions. Princeton University Press, Princeton, NJ [2.496] Boudart M (1995) Chern. Rev. 95:661 [2.497] Boudart M (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.) Handbook of

Heterogeneous Catalysis. VCH, Weinheim, Bd. 3, S. 958 [2.498] Spencer ND, Schoonmaker RC, SomOljai GA (1982) J. Catal. 74:129 [2.499] Ribeiro FH, Schach von Wittenau AE, Bartholomew CH, Somorjai GA (1997)

Catal. Rev.-Sci. Eng. 39:49 [2.500] Shannon SL, Goodwin JG (1995) Catal. Rev. 95:677 [2.501] Sugai S, Takeuchi K, Ban T, Miki H, Kawasaki K, Kioka T (1993) 282:67 [2.502] Paal Z, Somorjai GA (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.)

Handbook of Heterogeneous Catalysis. VCH, Weinheim, Bd. 3, S. 1084 [2.503] Weinberg WH (1991) in: Rettner CT, Ashford MNR (Eds.) Dynamics of Gas-

Surface Interactions. The Royal Society of Chemistry, Letchworth [2.504] Jennings JR (Ed.) (1991) Catalytic Ammonia Synthesis. Plenum, New York [2.505] Ertl G (1991) in [2.504], S. 109 ff [2.506] Langmuir 1(1918) 1. Am. Chern. Soc. 40:1361 [2.507] Hinshelwood CN (1940) The Kinetics of Chemical Change in Gaseous Systems.

Oxford University Press, Oxford (3. Auflage) [2.508] Hougen OA, Watson KM (1943) Ind. Eng. Chern. 35:529 [2.509] Tschernitz JL, Bornstein S, Beckmann RB, Hougen OA (1946) Trans. AIChE

42:883 [2.510] Yang KH, Hougen OA (1950) Chern. Eng. Prog. 46:146 [2.511] Boudart M (1967) Chern. Eng. Sci. 22:1387 [2.512] Boudart M (1987) Ind. Eng. Chern. Fundam. 25:70 [2.513] Bischoff KB, Froment GF (1962) Ind. Eng. Chern. Fundam. 1: 195 [2.514] Hutchinson HL, Barrick PL, Brown LF (1967) Chern. Eng. Prog. 63:18 [2.515] Shah MJ (1965) Ind. Eng. Chern. 57:18 [2.516] Choudhary VR, Doraiswamy LK (1975) Ind. Eng. Chern. Proc. Des. Dev. 14:227 [2.517] Kittrell JR (1970) Adv. Chern. Eng. 8:98 [2.518] Bard Y (1974) Nonlinear Parameter Estimation. Academic Press, New York [2.519] Dumesic JA, Trevino AA, Milligan BA, Greppi LA, Baise YR, Sarnowski KT,

Beall CE, Kataoka T, Rudd DF (1987) Ind. Eng. Chern. Res. 26: 1399 [2.520] Stewart WE, Caracotsios M, S01'ensen JP (i. Vorber.) Computational Modelling of

Reactive Systems. Butterworth, Stoneham [2.521] Bock HG (1981) in: Ebert KH, Deuflhard P, Jager W (Eds.) Modelling of

Chemical Reaction Systems. Springer, Heidelberg [2.522] Keil FJ (1996) Chern.-Ing.-Tech. 68:639 [2.523] Mezaki R, Inoue H (1991) Rate Equations of Solid-Catalyzed Reactions.

University of Tokyo Press, Tokyo [2.524] Somorjai GA, Rupprechter G (1997) in: Froment GF, Waugh KC (Eds.) Dynamics

of Surfaces and Reaction Kinetics in Heterogeneous Catalysis. Elsevier, Amsterdam; Stud. Surf. Sci. Catal. Vol 109, S. 35

[2.525] Doraiswamy LK (1991) Prog. Surf. Sci. 37:1


[2.526] Boudart M (1956) AIChE J 2:62 [2.527] Weller S (1956) AIChE J 2:59 [2.528] Kipennan SL, Kumbilieva KE, Petrov LA (1989) Ind. Eng. Chern. Res. 28:378 [2.529] Barnard JA, Mitchell DS (1968) J. Catal. 12:376 [2.530] Abhyankar SM, Doraiswamy LK (1979) Can. J. Chern. Eng. 57:481 [2.531] Goyal P, Doraiswamy LK (1970) Ind. Eng. Chern. Proc. Des. Dev. 9:25 [2.532] Weller SW (1992) Catal. Rev.-Sci. Eng. 34:227 [2.533] Luss D (1975) AIChE J 21:865 [2.534] Golikeri SV, Luss D (1972) AIChE J 18:277 [2.535] Coxson PG, BischoffKB (1987) Ind. Eng. Chern. 26: 1239 [2.536] Li G, Rabith H, Toth J (1994) Chern. Eng. Sci. 49:343 [2.537] Ocone R, Astarita G (1993) AIChE J 39:288 [2.538] Okino MS, Mavrovouniotis ML (1998) Chern. Rev. 98:391 [2.539] Corma A, LJapsis F, Monton JB, Weller S (1988) Chern. Eng. Sci. 43:785 [2.540] Krambeck FJ (1994) Chern. Eng. Sci. 49:4179 [2.541] Astarita G, Ocone R (1992) Chern. Eng. Sci. 47:2135 [2.542] Rostrup-Nielsen JR, Schoubye PS, Christiansen LJ, Nielsen PE (1994) Chern.

Eng. Sci. 49:3995 [2.543] Rostrup-Nielsen JR (1995) Chern. Eng. Sci. 50:4061 [2.544] Boudart M (1994) Ind. Eng. Chern. Res. 33:2900 [2.545] Tops0e N-Y (1994) Science 265:1217 [2.546] Stoltze P (1987) Physica Scripta 36:824 [2.547] Stoltze P, Nsrskov JK (1988) J. Catal. 110:1 [2.548] Ovesen CV, Stoltze P, Nsrskov JK, Campbell CT (1992) J. Catal. 134:445 [2.549] Slin'ko MM, Jaeger NI (1994) Oscillating Heterogeneous Catalytic Systems.

Elsevier, Amsterdam [2.550] SchUth F, Henry BE, Schmidt LD (1993) Adv. Catal. 39:51 [2.551] Imbihl R, Ertl G (1995) Chern. Rev. 95:697 [2.552] Ertl G (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.) Handbook 0/

Heterogeneous Catalysis. VCH, Weinheim, Vol. 3, S. 1032 [2.553] Larter R, Showalter K (1997) in: Lipkowitz KB, Boyd DB (Eds.) Reviews in

Computational Chemistry. VCH, Weinheim, Vol. 10, S. 177 [2.554] Arrowsmith DK, Place CM (1992) Ordinary Differential Equations. Chapman and

Hall, London. [2.555] Arrowsmith DK, Place CM (1994) Dynamische Systeme. Spectrum Akademischer

Verlag, Heidelberg [2.556] Jackson EA (1989) Perspectives o/Nonlinear Dynamics. Cambridge University

Press, Cambridge (UK) [2.557] Balakotaiah V, Cambridge University Press, Cambridge (in Vorber.) [2.558] Eiswirth M, Freund A, Ross J (1991) J. Phys. Chern. 95:1294 [2.559] Nettesheim S, von Oertzen A, Rotennund HH, Ertl G (1993) J. Chern. Phys.

98:9977 [2.560] Gorodetskii V, Lauterbach J, Rotermund HH, Block JH, Ertl G (1994) Nature

370:276 [2.561] Jakubith S, Rotennund HH, Engel W, von Oertzen A, Ertl G (1990) Phys. Rev.

Lett. 65:3013 [2.562] Hugo P (1970) Ber. Bunsenges. Phys. Chern. 74:121 [2.563] Beusch H, Fieguth D, Wicke E (1972) Chern.-Ing.-Techn. 44:445 [2.564] Krischer K, Eiswirth M, Ertl G (1992) J. Chern. Phys. 96:9161 [2.565] Kang HC, Weinberg WH (1995) Chern. Rev. 95:667 [2.566] Silverberg M, Ben-Shaul A, Robentrost FJ (1985) J. Chern. Phys. 83:6501 [2.567] ZiffRM, Gulari E, Barshad Y (1986) Phys. Rev. Lett. 50:2553 [2.568] Wicke E, Kumman P, Keil W, Scheifler J (1980) Ber. Bunsen-Ges. Phys. Chern.

4:315 [2.569] Clement E, Leroux-Hugon P, Saner LM (1991) Phys. Rev. Lett. 67: 1661 [2.570] Kang HC, Mullins CB, Weinberg WH (1990) J. Chern. Phys. 92: 1397


[2.571] Meng B, Weinberg WH (1994) J. Chern. Phys. 100:5280 [2.572] Gillespie DT (1977) J. Phys. Chern. 81:2340 [2.573] Jansen APJ (1995) Computer Phys. Commun. 85: 1 [2.574] Gelten RJ, Jansen APJ, van Santen RA, Lukkien JJ, Segers JPL, Hilbers PAJ

(1998) J. Chern. Phys. 108:5921 [2.575] Shustorovich EM (1986) Surf. Sci. Rep. 6: 1 [2.576] Shustorovich E (1990) in: Moffat JB (Ed.) Theoretical Aspects o/Heterogeneous

Catalysis. Van Nostrand Reinhold, New York [2.577] Shustorovich E (1992) in: Ruette F (Ed.) Quantum Chemistry Approaches to

Chemisorption and Heterogeneous Catalysis. Kluwer Academic Publishers, Dordrecht

[2.578] Shustorovich EM, Bell AT (1992) Surf. Sci. 268:397 [2.579] Shustorovich E (1991) (Ed.) Metal-Surface Reaction Energetics. VCH, Weinheim [2.580] Anderson AB, Grimes RW, Hong SY (1987) J. Phys. Chern. 91 :4245 [2.581] Christoffersen RE (1989) Basic Principles and Techniques o/Molecular Quantum

Mechanics. Springer-Verlag, New York [2.582] Katzelnigg W (1994) Einfiihrung in die theoretische Chemie. VCH, Weinheim;

2 Bde. (2. Auflage) [2.583] Levine I (1991) Quantum Chemistry. Prentice Hall, London [2.584] McQUarrie DA (1983) Quantum Chemistry. University Science, Mill ValleY,Calif. [2.585] Pilar FL (1990)Elementary Quantum Chemistry. McGraw Hill, New York, (2nd Ed.) [2.586] Hehre WJ, Radom L, von Schleyer PR, Pople JA (1086) Ab Initio Molecular

Orbital Theory. John Wiley, New York [2.587] Jensen F (1999) Introduction to Computational Chemistry. John Wiley, New York [2.588] Leach AR (1996) Molecular Modelling, Principles and Applications. Longman,

Harlow [2.589] Szabo A, Ostlund NS (1996) Modern Quantum Chemistry. Dover Publ., New

York (Nachdruck) [2.590] Holloway S, NfMskov J (1991) Bonding at Surfaces. Liverpool University Press,

Liverpool [2.591] van Santen RA (1991) Theoretical Heterogeneous Catalysis. World Scientific,

Singapore [2.592] Yoshida S, Sakaki S, Kobayashi H (1994) Electronic Processes in Catalysis, A

Quantum Chemical Approach to Catalysis. VCH, Weinheim [2.593] Ruette F (Ed.) (1992) Quantum Chemistry Approaches to Chemisorption and

Heterogeneous Catalysis. Kluwer Academic Publishers, Dordrecht [2.594] Catlow CRA, Stoneham AM, Thomas JM (Eds.) (1993) New Methods/or

Modelling Processes within Solids and at ther Surfaces. The Royal Society, Oxford University Press, Oxford

[2.595] Desjonqueres MC, Spanjaard D (1996) Concepts in Surface Physics. SpringerVerlag, Heidelberg, (2nd Ed.)

[2.596] Freund H-J, Kuhlenbeck H, Staemmler V (1996) Rep. Prog. Phys. 59:283 [2.597] Heidrich D (Ed.) (1995) The Reaction Path in Chemistry: Current Approaches

and Perspectives. Kluwer Academic Publishers, Dordrecht [2.598] Parr RG, Yang W (1989) Density Functional Theory. Oxford University Press,

Oxford [2.599] Ellis DE (Ed.) (1995) Density Functional Theory o/Molecules, Clusters and

Solids. Kluwer Academic Publishers, Dordrecht [2.600] Seminario JM, Politzer P (Eds.) (1995) Modern Density Functional Theory - A

Tool/or Chemistry. Elsevier, Amsterdam [2.601] Moffat JB (1990) Theoretical Aspects o/Heterogeneous Catalysis. Van Nostrand

Reinhold, New York [2.602] Cox PA (1992) Transition Metal Oxides. An Introduction to their Electronic

Structure and Properties. Clarendon Press, Oxford [2.603] Sauer J (1989) Chern. Rev. 89:199 [2.604] van Santen RA (1990) Chern. Eng. Sci 45:2001


[2.605] van Santen RA, Neurock M (1995) Catal. Rev.-Sci. Eng. 37:557 [2.606] Pyykko P (1988) Chern. Rev. 88:563 [2.607] Simons J, Nichols J (1997) Quantum Mechanics in Chemistry. Oxford University

Press, Oxford [2.608] Roos BO (Ed.) (1992) Lecture Notes in Quantum Chemistry. Springer-Verlag,

Heidelberg [2.609] von Rague Schleyer P (Ed.) (1998) Encyclopedia of Computational Chemistry.

John Wiley, New York (5 Vols.) [2.610] Neurock M, Dixon DA, Coulston (in Vorber.) [2.611] Neurock M, Biernolt WM, Jansen AJ, van Santen RA (1995) J. Am. Chern. Soc.

116:6860 [2.612] van Santen RA, Niernantsverdriet JW (195) Chemical Kinetics and Catalysis.

Plenum Press, New York [2.613] Pettifor D (1995) Bonding and Structure of Molecules and Solids. Clarendon

Press, Oxford [2.614] KerkhofPJAM (1996) Chern. Eng. J. 64:319 [2.615] KerkhofPJAM (1997) Ind. Eng. Chern. Res. 36:915 [2.616] KerkhofPJAM (1998) Lat. Am. Appl. Res. Int. J. 28:15

3 Beschreibung der Porenstruktur von Katalysatortragern

[3.1] Wheeler A (1951) Adv. Catalysis 3:249 [3.2] Rouquerol J, Avnir D, Fairbridge CW, Everett DH, Haynes JM, Pemicone N,

Ramsay JDF, Sing KSW, Unger KK (1994) Pure Appl. Chern. 66:1739 [3.3] Foster RN, Butt JA (1966) AIChE J 12: 180 [3.4] Johnson MFL, Stewart WE (1965) J. Catal. 4:248 [3.5] Carman PC (1937) Flow of Gases Through Porous Media. Butterworth,London [3.6] Epstein N (1989) Chern. Eng. Sci. 44:777 [3.7] Wand C-T, Smith JM (1983) AIChE J 29:132 [3.8] Satterfield CH (1970) Mass Transfer in Heterogeneous Catalysis. MIT Press,

Cambridge (Mass.) [3.9] Camiglia SC (1986) J. Catal. 102:401 [3.10] Aris R (1975) The Mathematical Theory of Diffusion and Reaction in Permeable

Catalysts. (Vol 1), Clarendon Press, Oxford [3.11] Sharratt PN, Mann R (1987) Chern. Eng. Sci. 42:1565 [3.12] Hollewand MP, Gladden LF (1992) Chern. Eng. Sci. 47:1761 [3.13] Bhatia SK (1986) Chern. Eng. Sci. 41:1311 [3.14] Tomadakis MM, Sotirchos SV (1993) Chern. Eng. Sci. 48:3323 [3.15] Reyes S, Jensen KF (1985) Chern. Eng. Sci. 40:1723 [3.16] Mann R, Thomson G (1987) Chern. Eng. Sci. 42:555 [3.17] McGreavy C, Andrade JS, Rajagopal K (1992) Chern. Eng. Sci. 47:2751 [3.18] Fatt I (1956) Pet. Trans., AIME 207:144 [3.19] Okabe A, Boots B, Sugihara K (1992) Spatial Tessalinations: Concepts and

Applications of Voronoi Diagramms. John Wiley & Sons, New York [3.20] Hollewand MP, Gladden L (1992) Chern. Eng. Sci. 47:2752 [3.21] Sharratt PN, Mann R (1987) Chern. Eng. Sci. 42:1565 [3.22] Sahirni M (1988) Chern. Eng. Sci. 43:2981 [3.23] Keil FJ, Rieckmann C (1994) Chern. Eng. Sci. 49:4811 [3.24] Mann R (1993) Trans. Instn. Chern. Engn. 71:551 [3.25] Beeckman JW, Frornent GF, Pisrnen L (1978) Chern.-Ing.-Tech. 50:960 [3.26] Beeckman JW, Frornent GF (1980) Chern. Eng. Sci. 35:805 [3.27] Reyes S, Jensen K (1985) Chern. Eng. Sci. 40:1723 [3.28] Mojarardi R, Sahirni M (1988) Chern. Eng. Sci. 43:2995


[3.29] Patwardhan AV, Mann R (1991) Trans. Instn. chern. Engrs. 69 (A):205 [3.30] Mohanti KK (1981) Ph Thesis (University of Minnesota, Minneapolis) [3.31] Lin C, Cohen MH (1982) J. Appl. Phys. 53:4152 [3.32] Reyes SC, Iglesia E (1991) J. Catal. 129:457 [3.33] Reyes SC, Igelsia E (1993) in: Becker ER, Pereira CJ (Eds.) Computer-Aided

Design of Catalysts. Marcel Dekker, New York, S. 89 [3.34] Mann R (1998) in: Cybulski A, Moulijn JA (Eds.): Structured Catalysts and

Reactors. Marcel Dekker, New York, S 617 [3.35] Pisrnen LM (1974) Chern. Eng. Sci. 29:1227 [3.36] Tornadakis MM, Sotirchos SV (1993) Chern. Eng. Sci. 48:3323 [3.37] Rieckmann C, Keil FJ (1997) Ind. Eng. Chern. Res. 36:3275 [3.38] Rieckmann C (1997) Losung des Problems der Diffusion und Reaktion in drei

dimensionalen Porennetzwerken for allgemeine Kinetiken - Theoretische und experimentelle Untersuchungen. Dissertation, TV Hamburg-Harburg

[3.39] Rieckmann C, Keil FJ (1999) Chern. Eng. Sci. (irn Druck) [3.40] Keil FJ, Schreiber D (1994) Chern.-Ing.-Tech. 66:201 [3.41] Seaton N (1991) Chern. Eng. Sci. 46:1895 [3.42] Keil FJ, Rieckmann C (1994) Chern. Eng. Sci. 49:4811 [3.43] Hollewand MP, Gladden LF (1993) J. Catal. 144:254 [3.44] Hollewand MP, Gladden LF (1995) Chern. Eng. Sci. 50:309 [3.45] Hollewand MP, Gladden LF (1995) Chern. Eng. Sci. 50:327 [3.46] Dullien F AL (1992) Porous Media - Fluid Transport and Pore Structure.

Academic Press, New York [3.47] Dullien FAL (1991) Transport in Porous Media 6:581 [3.48] Adler P (1992) Porous Media - Geometry and Transports. Butterworth-

Heinemann, Boston [3.49] Van Brakel J (1975) Powder Technology 11 :205 [3.50] Sahirni M, Gavalas GR, Tsotsis TT (1990) Chern. Eng. Sci. 45:1443 [3.51] Kaneko K (1994) J. Mernbr. Sci. 96:59 [3.52] Gregg SJ, Sing KSW (1982) Adsorption Surface Area and Porosity. Academic

Press, New York (2. Auflage) [3.53] Sing KSW, Rouquerol J (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.):

Handbook of Heterogeneous Catalysis. Vol. 2, VCH, Weinheirn, S. 427 [3.54] Jerauld GR, Hatfield JC, Scriven LE, Davis HT (1984) J. Phys. C 17: 1519 [3.55] Jerauld GR, Scriven LE, Davis HT (1984) J. Phys. C. 17:3429 [3.56] Brunauer S, Emmett PH, Teller E (1938) J. Arner. Chern. Soc. 60:309 [3.57] Barrett EP, Joyner LG, Halenda PP (1951) J. Amer. Chern. Soc. 73:373 [3.58] Lippens BC, de Boer JH (1965) J. Catal. 4:319 [3.59] Sing KSW (1989) Carbon 27:5 [3.60] Dubinin MM (1960) Chern. Rev. 60:235 [3.61] Dubinin MM, Radushkevich LV (1947) Dokl. Akad. Nauk. SSSR 55:331 [3.62] Stoeckli HF, Houriet JPh, Perret A, Huber U (1979) in: Characterisation of

Porous Solids. SCI, London [3.63] Horvath G, Kawazoe K (1983) J. Chern. Eng. Japan 16:470 [3.64] Dollirnore D, Heal (1964) J. Appl. Chern. 14:109 [3.65] Zgrablich G, Medioroz S, Daza L, Pajares J. Mayagoitia V, Rojan F,

Conner W (1991) Langmuir 7:779 [3.66] AI-Rab FAA, Datta R (1998) Fluid Phase Equilibria 147:65 [3.67] Seaton N, Walton JPRB, Quirke N (1989) Carbon 27:853 [3.68] Barton SS, Evans MJB, Harrison BH (1974) J. Colloid. Interface Sci. 40:462 [3.69] Cranston RW, Inkley FA (1957) Adv. Catal. 9:143 [3.70] Brunauer S, Mikhail RSh, Bodor EE (1967) J. Colloid. Interface Sci. 24:451 [3.71] Saito A, Foley HC (1991) AIChE J 37:429 [3.72] Baksh MSA, Yang RT (1991) AIChE J 37:923 [3.73] Kaminsky RD, Maglara E, Conner W (1994) Langmuir 10:1556 [3.74] Pfeifer P, Avnir D (1983) J. Chern. Phys. 79:3558


[3.75] Conner WC, Lane AM, Hoffman AJ (1984) J. Colloid. Interface Sci. 100:185 [3.76] Karger J, Krause C, Schafer H (1997) GIT Spezial-Chromatographie, S. 26 [3.77] Schneider P, Gelbin D (1985) Chern. Eng. Sci. 40: 1093 [3.78] Scharfenberg R, MeyerhoffK, Hesse D (1996) Chern. Eng. Sci. 51:1889 [3.79] MeyerhoffK, Hesse D (1997) Chern. Eng. Technol. 20:230 [3.80] Seifert J, Emig G (1987) Chern.-Ing.-Tech. 59:475 [3.81] van Brakel J, Modry S, SvataM (1981) Powder Techn. 29:1 [3.82] Modry S, Svata M, van Brakel J (1981) Powder Techn. 29:13 [3.83] Mandelbrot B (1977) Fractals - Form, Chance and Dimension. Freeman, San

Francisco [3.84] Peitgen H-O, Jiirgens H, Saupe D (1992) Bausteine des Chaos - Fraktale. Klett

Cotta und Springer, Stuttgart und Heidelberg [3.85] Peitgen H-O, Jurgens H, Saupe D (1994) Chaos-Bausteine der Ordnung. Klett-

Cotta und Springer, Stuttgart und Heidelberg [3.86] Feder J (1988) Fractals. Plenum Press, New York [3.87] Bamsley M (1993) Fractals Everywhere. Academic Press, San Diego [3.88] Falconer K (1990) Fractal Geometry, Mathematical Foundations and

Applications. John Wiley, New York [3.89] Stauffer D, Stanley HE (1991) From Newton to Mandelbrot. Springer, Heidelberg [3.90] Takayasu H (1991) Fractals in the Physical Sciences. Manchester University Press,

Manchester [3.91] Bunde A, Havlin S (Eds.) (1991) Fractals in Disordered Systems. Springer,

Heidelberg [3.92] Bunde A, Havlin S (Eds.) (1994) Fractals in Science. Springer, Heidelberg [3.93] Avnir D (Ed.) (1989) The Fractal Approach to Heterogeneous Catalysis. John

Wiley, New York [3.94] Rothschild WD (1991) Catal. Rev.-Sci. Eng. 33:71 [3.95] Havlin S, Ben-Avraham D (1987) Adv. Phys. 36:695 [3.96] Sahirni M (1995) Flow and Transport in Porous Media and Fractured Rock.

VCH, Weinheim [3.97] Kaye BH, Clark GG, Kydar Y (1994) Part. Part. Syst. Charact. 11 :411 [3.98] Adler J (1995) Part. Part. Syst. Charact. 12:28 [3.99] Ackermann W-G, Spindler H (1988) Z. Phys. Chernie (Leipzig) 269: 1000 [3.100] Gutfraind R, Sheintuch M, Avnir D (1991) J. Chern. Phys. 95:6100 [3.101] Rothschild (1998) Fractals in Chemistry. John Wiley, New York [3.102] Hegedus LL, McCabe RW (1984) Catalyst Poisoning. Marcel Dekker Inc., New

York [3.1 03] Butt JB, Petersen EE (1988) Activation, Deactivation, and Poisoning of Catalysts.

Academic Press and Harcourt Brace Jovanovich, Publ., New York [3.104] Delrnon B, Frornent GF (Eds.) (1994) Catalyst Deactivation 1994.Stud. Surf. Sci.

Catal. Vol. 88, Elsevier, Amsterdam [3.105] Sahirni M, Tsotsis TT (1985) J. Catal. 96:552 [3.106] Reyes SC, Jensen KF (1985) Chern. Eng. Sci. 40:1723 [3.107] Beyne AOE, Frornent GFA (1993) Chern. Eng. Sci. 48:503 [3.108] Beyne AOE, Frornent GFA (1990) Chern. Eng. Sci. 45:2089 [3.109] Zhang L, Seaton NA (1994) Chern. Eng. Sci. 49:41 [3.110] Mann R, Scharratt PN, Thomson G (1986) Chern Eng. Sci. 41 :711 [3.111] Arbabi S, Sahirni M (1991) Chern. Eng. Sci. 46:1739 [3.112] Arbabi S, Sahirni M (1991) Chern. Eng. Sci. 46:1747 [3.113] Keil FJ, Rieckmann C (1994) Chern. Eng. Sci. 49:4811 [3.114] Keil FJ, Rieckmann C (1993) Hung. J. Ind. Chern. 21 :277 [3.115] Salles J, Thovert JF, Adler PM (1993) Chern. Eng. Sci. 48:2839 [3.116] Krishna AS (1990-91) Catal. Rev.-Sci. Eng. 32:179


4 Diffusion und Reaktion in der Anwendung

[4.1] Thiele EW (1939) Ind. Eng. Chern. 31:916 [4.2] Zeldovich Ia B (1939) Zhur. Fiz. Khirn. 13:163 [4.3] Damkohler G (1937) in: Eucken A (Hrg.) Der Chemie-Ingenieur. Akademische

Verlagsgesellschaft rn.b.H, Leipzig, BdIIIII, S. 359 [4.4] Aris R (1965) Ind. Eng. Chern. Fundam. 4:227 [4.5] BischoffKB (1965) AIChE J 11:351 [4.6] Petersen EE (1965) Chern. Eng. Sci. 20:587 [4.7] Aris R (1957) Chern. Eng. Sci. 6:262 [4.8] Do HD, Do DD (1985) Chern. Eng. Sci. 40:287 [4.9] Do DD (1983) Chern. Eng. Sci. 40:287 [4.10] Schlosser E-G (1974) Chern.-Ing.-Tech. 46:1011 [4.11] Liou J-S, Balakotaiah V, Luss D (1989) AIChE J 35:1509 [4.12] Luss D (1987) in: Carberry JJ, Vanna A (Eds.) Chemical Reaction and Reactor

Engineering. Marcel Dekker, New York [4.13] Doraiswamy LK, Sharma MM (1984) Heterogeneous Reactions: Analysis,

Examples, and Reactor Design. John Wiley, New York (2 Vols.) [4.14] Wijngaarden RJ, Kronberg A, Westerterp KR (1998) Industrial Catalysis. Wiley

VCH, Weinheirn [4.15] Emig G, Dittmeyer R (1997) in: Ertl G, Knoziger H, Weitkamp J (1997)

Handbook of Heterogeneous Catalysis. VCH,Weinheim, Vol. 3, S. 1209 [4.16] Weisz PB, Hicks JS (1962) Chern. Eng. Sci.l7:265 [4.17] Satterfield CN (1970) Mass Transfer in Heterogeneous Catalysis. MIT Press,

Cambridge (Mass.) [4.18] Aris R (1975) The Mathematical Theory of Diffusion and Reaction in Permeable

Catalysts. Clarendon Press, Oxford (2 Vols.) [4.19] Hartig F, Keil FJ (1993) Ind. Eng. Chern. Res. 32:424 [4.20] Sharratt PN, Mann R (1987) Chern. Eng. Sci. 42:1565 [4.21] Hollenwand MP, Gladden LF (1992) Chern. Eng. Sci. 47: 1761 [4.22] Mojaradi R, Sahirni M (1988) Chern. Eng. Sci. 43:2995 [4.23] Rieckmann C, Keil FJ (1997) Ind. Eng. Chern. Res. 36:3275 [4.24] Rieckmann C, Keil FJ (1996) Hung. J. Ind. Chern. 24:295 [4.25] Rieckmann C, DUren T, Keil FJ (1997) Hung. J. Ind. Chern. 25:137 [4.26] Rieckmann C, Keil FJ (1999) Chern. Eng. Sci. 54:3485 [4.27] Keil FJ, Rieckmann C (1993) Hung. J. Ind. Chern. 21:277 [4.28] Keil FJ, Rieckmann C (1994) Chern. Eng. Sci. 49:4811 [4.29] Wheeler A (1951) Adv. Catal. 3:214 [4.30] Luss D (1987) in: Carberry JJ, Vanna A (Eds.) Chemical Reaction and Reactor

Engineering. Marcel Dekker, New York [4.31] Hegedus LL, McCabe RW (1981) Catalyst Poisoning. Marcel Dekker, New York [4.32] Butt JB, Petersen EE (1988) Activation, Deactivation and Poisoning of Catalysts.

Acadernic Press, New York [4.33] Oudar J, Wise H (1985) Deactivation and Poisoning of Catalysts. Marcel Dekker,

New York [4.34] Hughes R (1984) Catalyst Deactivation. Academic Press, New York [4.35] Bartholomew CH, Butt JB (1991) Catalyst Deactivation. Elsevier, Amsterdam [4.36] Bartholomew CH, Fuentes GA (1997) Catalyst Deactivation 1997. Elsevier,

Amsterdam [4.37] Gates BC, Katzer JR, Schuit GCA (1979) Chemistry of Catalytic Processes.

McGraw Hill, New York [4.38] Frornent GF, BischoffKB (1990) Chemical Reactor AnalYSis and Design. John

Wiley, New York (2nd Ed.) [4.39] Levenspiel 0 (1999) Chemical Reaction Engineering. John Wiley, New York

(3rd Ed.)


[4.40] [4.41] [4.42] [4.43] [4.44] [4.45] [4.46] [4.47] [4.48] [4.49] [4.50] [4.51] [4.52] [4.53] [4.54] [4.55] [4.56] [4.57] [4.58] [4.59] [4.60] [4.61] [4.62] [4.63] [4.64] [4.65] [4.66]

[4.67] [4.68] [4.69] [4.70] [4.71]

[4.72]

[4.73]

[4.74]

[4.75] [4.76] [4.77] [4.78] [4.79] [4.80] [4.81] [4.82] [4.83]

[4.84]

[4.85] [4.86] [4.87] [4.88]

Krishna AS (1990/91) Catal. Rev.-Sci.-Eng. 32:279 Butt JB, Wachter CK, Billimora RM (1978) Chem. Eng. Sci. 33:1321 Corella J, Asua JM (1982) Ind. Eng. Chem. Proc. Des. Dev. 21:55 Fuentes GA, Ruiz-Trevino FA (1991) Stud. Surf. Sci. Catal. 68:637 Wheeler A (1951) Adv. Catal. 3:250 Sada E, Wen CY (1967) Chem. Eng. Sci. 22:559 Masamune S, Smith JM (1966) AIChE J 3:384 Sagara M, Masamune S, Smith JM (1967) AIChE J 11: 1226 Kam EKT, Ramachandran PA, Hughes R (1975) J. Catal. 38:283 Hegedus LL (1974) Ind. Eng. Chem. Fundam. 13:190 Dougherty RC, Verykios XE (1987) Catal. Rev.-Sci.-Eng. 29: 101 Gavriilidis A, Varma A (1993) Catal. Rev.-Sci. Eng. 35:399 Sahimi M, Tsotsis TT (1985) J. Catal. 96: 552 Shah N, Ottino JM (1987) Chern. Eng. Sci. 42:73 Bhatia S, Beltramini J, Do DD (1989) Catal. Rev.-Sci. Eng. 31 :431 Beeckman JW, Froment GF (1979) Ind. Eng. Chem. Fundam. 18:245 Beeckman JW, Froment GF (1980) Chem. Eng. Sci. 35:805 Beeckman JW, Froment GF (1982) Ind. Eng. Chern. Fundam. 21:243 Theodorou D, Wei J (1983) J. Catal. 83:205 Mann R, Sharatt PN, Thomson G (1986) Chem. Eng. Sci. 41:711 Beyne AOE, Froment GF (1990) Chem. Eng. Sci. 45:2089 Beyne AOE, Forment GF (1993) Chern. Eng. Sci. 48:503 Arbabi S, Sahimi M (1991) Chem. Eng. Sci. 46:1739 Arbabi S, Sahimi M (1991) Chern. Eng. Sci. 46: 1749 Rieckmann C, DUren T, Keil FJ (1997) Hung. J. Ind. Chern. 25:137 Rieckmann C, Keil FJ (1997) Ind. Eng. Chern. Res. 36:3275 Spry JC, Sawyer WH (1975) Arbeit, die auf dern AIChE National Meeting, Los Angeles, CA, Nov. 16-20, priisentiert wurde. Agrawal R, Wei J (1984) Ind. Eng. Chern. Process Des. Dev. 23:505 Keil FJ, Rieckmann C (1993) Hung. J. Ind. Chern. 21:277 Pereira CJ, Beeckman YW (1989) Ind. Eng. Chern. Res. 29:512 Zhang L, Seaton NA (1996) Chern. Eng. Sci. 51:3257 Van Bekkum H, Flanigen EM, Jansen JC (Eds.) (1991) Introduction To Zeolite Science And Practice. Stud. Surf. Sci. Catal., Vol. 58. Elsevier, Amsterdam Chen NY, Degnan TF, Smith CM (1994) Molecular Transport and Reaction in Zeolites. VCH, New York Chen NY, Garwood WE, Dwyer FG (1996) Shape Selective Catalysis in Industrial Applications. Marcel Dekker, New York (2. Auflage) Beyer HK, KargeJIG, Kiricsi I, Nagy JB (1995) Catalysis By Microporous Materials. Stud. Surf. Sci. Catal., Vol. 94. Elsevier, Amsterdam Haag WO (1994) Stud. Surf. Sci. Catal. 84: 1375 Puppe L (1986) Chemie in unserer Zeit 20: 117 Holderich W, Hesse M, Naumann F (1988) Angew. Chemie 100:232 Chen NY, Degnan TF (Febr. 1988) Chem. Eng. Prog., S. 32 Weitkamp J, Ernst S, Dauns H, Gallei E (1986) Chem.-Ing.-Tech. 58:623 Corma A, Martinez A (1995) Adv. Mater. 7:137 Csicsery SM (1995) Stud. Surf. Sci. Catal. 94: 1 Thomas JM, Bell RG, Catlow CRA (1997) in [4.83], S. 286 Ertl G, Knozinger H, Weitkamp J (1997) Handbook of Heterogeneous Catalysis, Vol. 1. VCH, New York Maxwell IE, John CS (1992) in: Perspectives in Catalysis (Thomas JM, Zamaraev KI (Eds.», Blackwells, Oxford Fripiat JJ (1997) in [4.83], S. 387 Figueras F (1988) Cat. Rev.-Sci. Eng. 30:451 Szostak T, Ingram C (1995) Stud. Surf. Sci. Catal. 94:13 Rao MB, Sircar S (1993) J. Membrane Sci. 85:253


[4.89] Koch S (1997) Entwicklung eines Katalysators auf der Basis aluminiummodifizierter poroser Glaser zur katalysierten Nachverbrennung chlorierter Kohlenwasserstoffe. Dissertation, Institut fUr Technische Chernie, Universitat Karlsruhe (Prof. Weisweiler)

[4.90] Brinker CJ, Sehgal R, Hietala SL, Deshpande R, Smith DM, Loy D, Ashley CS (1994) J. Membrane Sci. 94:85

[4.91] Schneider M, Baiker A (1995) Catal. Rev.-Sci. Eng. 37:515 [4.92] Jamiak C (1997) Angew. Chern. 109:1499 [4.93] Meier WM, Olson DH (Eds.) (1992) Atlas of Zeolite Structure Types (3rd Ed.),

Butterworth,London [4.94] Beck JS, Vartuli JC, Roth WJ, Leonowicz ME, Kresge CT, Schitt KD, Chu CT-W,

Olson DH, Sheppard EW, McCullen SB, Higgins JB, Schlenker JL (1992) J. Am. Chern. Soc. 114: 10834

[4.95] Llewellyn PL, Ciesla U, Decher H, Stadler R, SchUth F, Unger KK (1994) Stud. Surf. Sci. Catal. 84:2013

[4.96] Barrer RM (1978) Zeolites and Clay Minerals. Academic Press, New York [4.97] Weisz PB, Frilette VJ, Maatmann RW, Mower EB (1962) J. Catal. 1:307 [4.98] Kosslick H, Roethe A, Roethe K-P (1994) Chern. Technik (Leipzig) 46:101 [4.99] Weitkamp J, Karge HG, Pfeifer H, Holderich W (Eds.) (1994) Zeolites and

Related Microporous Materials: State of the Art 1994. Stud. Surf. Sci. Catal., Vol. 84, Elsevier, Amsterdam

[4.100] Ernst S (1996) Angew. Chern. 108:67 [4.101] Chen NY, Weisz PB (1967) Chern. Eng. Prog. Symp. Ser. 73:86 [4.102] Tatsumi T, Nakamura M, Yuasa K, Tominaga H (1991) Catal. Lett. 10:259 [4.103] Chen NY, Kaeding WW, DwyerFG (1979) J. Am. Chern. Soc. 101:6783 [4.104] Benito A, CormaA, Garcia H, Primo J (1994) Appl. Catal. A 116:127 [4.105] Derouane EG, GabelicaZ (1980) J. Catal. 65:486 [4.106] Chen NY, Maziuk J, Schwartz AB, Weisz PB (1968) Oil Gas J. 66:154 [4.107] Weitkamp J, Jacobs PA, Martens JA (1983) Appl. Catal. 8:123 [4.108] Chen NY, Garwood WE, Heck RH (1987) Ind. Eng. Chern. Process Des. Develop.

26:706 [4.109] Chen NY, Gorring RL, Ireland HR, Stein TR (1977) Oil Gas J. 75:165 [4.110] Tabak SA, Krambeck FJ, Garwood WE (1986) AIChE J 32:1526 [4.111] Yurchak S, Child JE, Beech JH (1990) Dargestellt auf der Tagung NPRA Annual

Meeting, San Antonio, TX (AM-90-37), 25.-27. Man [4.112] van den Berg JP, Robschlliger KHW, Maxwell IE (1989) Dargestellt aufdem 11.

Zeolith-Symposium der North Am. Catal. Soc., Dearborn, 7.-11. Mai [4.113] Avidan AA (1992) Oil Gas J 90:59 [4.114] Venuto PB, Habib ET (1979) Fluid Catalytic Cracking with Zeolite Catalysts.

Marcel Dekker, New York [4.115] Yates JG (1983) Fundamentals of Fluidized-bed Chemical Processes.

Butterworth,London [4.116] Scherzer J (1989) Catal. Rev.-Sci. Eng. 31:215 [4.117] Olson DH, Haag WO (1984) Am. Chern. Soc. Symp. Ser. 248:275 [4.118] WeiJ (1982) J. Catal. 76:433 [4.119] Klemm E, Scheidat H, Emig G (1997) Chern. Eng. Sci. 52:2757 [4.120] Kaeding WW, Chu C, Young LB, Butter SA (1981) J. Catal. 69:392 [4.121] Huang YY, Nicoletti MP, Sailor RA (1990) DeWitt Petrochem. Rev., X-I [4.122] Chang CD, Lang WH, Bell WK (1981) in: Catalysis of Organic Reactions

(Mosher WR (Ed.)). Marcel Dekker, New York, S. 73 [4.123] Chang CD (1983) Catal. Rev.-Sci. Eng. 25:1 [4.124] Chang CD (1984) Catal. Rev.-Sci. Eng. 26:323 [4.125] Kam AY, Lee W (1978) Final Report, DOE Contract EX-76-C-01-2490, U.S.

Dept. of Energy


[4.126] Gierlich HH, Keirn KH, Thiagarajan N, Nitschke E, Kam AY, Daviduk N (1985) Vortrag auf der 2. EPRI Konferenz "Synthetic Fuels-Status and Directions" , San Francisco, 15.-19. April

[4.127] Edwards M, Avidan A (1986) Chern. Eng. Sci. 41:829 [4.128] Biswas J, Maxwell IE (1990) Appl. Catal. 58:1,58:19 [4.129] Bos ANR, Tromp P (1995) Ind. Eng. Chern. Res. [4.130] Schonfelder H, Hinderer J, Werther J, Keil F (1994) Chern.-Ing. -Tech. 66:960 [4.131] SchOnfelder H, Werther J, Hinderer J, Keil F (1994) Chern. Eng. Sci. 49:5377 [4.132] Hinderer J, Keil F (1996) Chern. Eng. Sci. 51:2667 [4.133] Ratnasamy P, Kumar R (1991) Catalysis Today 9:329 [4.134] Taramasso M, Perego G, Notari B (1983) US Patent No. 4410510 [4.135] Roffia P, Leofanti G, Cesana A, Mantegazza M, Padovan M, Petrini G, Tonti S,

Gervasutti P (1990) Stud. Surf. Sci. Catal. 55:43 [4.136] Schulz-EkloffG, Ernst S (1997) in [4.83], S. 374 [4.137] Vaughan DEW, Lussier RJ, Magee JS (1973) US Patent 3775395;

US Patent 3838037 [4.138] Brindley GW, Sernpe1s RE (1977) Clay Miner. 12:229 [4.139] Lahav N, Shani U, Shabtai J (1978) Clays and Clay Minerals 26:107 [4.140] Tatsurni T, Tajirna H, Yamamoto K, Torninaga H (1993) Stud. Surf. Sci. Catal.

77:1073 [4.141] Sahirni M (1990) J. Chern. Phys. 92:5107 [4.142] Dccelli ML, Innes RA, Haru FSS, Hightower JW (1985) Appl. Catal. 14:69 [4.143] Yi X, Shing KS, Sahirni M (1995) AIChE J 41 :456 [4.144] Chen BY, Kim H, Mahanti SD, Pinnavaia TJ, Cai Z X (1994) J. Chern. Phys.

100:3872 [4.145] Yang RT, Baksh MSA (1991) AIChE J 37:679 [4.146] Baksh MS, Kikkinides ES, Yang RT (1992) Ind. Eng. Chern. Res. 31:2181 [4.147] Jaroniec M, Madey R, Choma J, McEnaney B, Mays TJ (1989) Carbon 27:77 [4.148] Dubinin MM (1975) in: Progress and Membrane Science (Cadenhead DA,

Danelli JF, Rosenberg MD (Eds.) Academic Press, New York, Vol. 9, S. 1 [4.149] Jagiello J, Bandosz TJ, Schwarz JA (1997) Langmuir 13:1010 [4.150] Hauthal H (1997) Nachr. Chern. Tech. Lab. 45:611 [4.151] van Santen RA, Kramer GJ (1995) Chern. Rev. 95:637 [4.152] Garayhi AR, Keil FJ (1997) Chern.-Ing.-Tech. 69:980 [4.153] Itoh N, Shindo Y, HarayhaK (1990) J. Chern. Eng. Japan 23:420 [4.154] Nagamoto H, Inoue H (1981) J. Chern. Eng. Japan 14:377 [4.155] Agarwalla S, Lund CRF (1992) J. Mernbr. Sci. 70:129 [4.156] Saracco G, Specchia V (1994) Catal. Rev.-Sci. Eng. 36:305 [4.157] Tsotsis TT, Minet RG,Champagnie AM, Liu PKT (1993) in: Computer-Aided

Design ofCatalysists (Becker ER, Pereira CJ (Eds.» Marcel Dekker, New York, S.471

[4.158] Dalrnon J-A (1997) in [4.83], S. 1387 [4.159] Veldsink JW, van Darnme RMJ, Versteeg GF, van Swaaij WPM (1995) Chern.

Eng. J. 57:115 [4.160] MooreSV, TrimmDL (1977) Carbon 15:177 [4.161] Hu X, Rao GN, Do DD (1993) AIChE J. 39:249 [4.162] Hu X, Do DD, Rao GN (1994) Chern. Eng. Sci. 49:2145 [4.163] Chen YD, Yang RT, Uawithya P (1994) AIChE J. 40:577 [4.164] Ruthven DM (1992) Chern. Eng. Sci. 47:4305 [4.165] Maginn EJ, Bell AT, Theodorou DN (1993) J. Phys. Chern. 97:4173 [4.166] Chiara K, Suzuki M, Kawazol K (1978) J. Colloid Interface Sci. 64:584 [4.167] SokodaA, Kasuh T, Suzuki M (1993) Stud. Surf. Sci. Catal. 80:559 [4.168] Segarra EI, Glandt ED (1994) Chern. Eng. Sci. 49:2953 [4.169] MacElroy JMD, Seaton NA, Friedman SP (1997) Stud. Surf. Sci. Catal. 104:837 [4.170] Rigby AM, Kramer GJ, van Santen R A (1997) J. Catal. 170:1


[4.171] Janowski F, WolfF (1982)Porose Glaser, Herstellung, Eigenschaften und Anwendung. VEB Deutscher Verlag fUr Grundstoffindustrie, Leipzig

[4.172] Unger K (1975) Ber. Bunsenges. physik. Chern. 79:739 [4.173] Wohlfahrt K (1982) Chern. Eng. Sci. 37:283 [4.174] Hammon U, Kotter M (1983) Chern.-Ing.-Tech. 56:455 [4.175] Brinker CJ, Sehgal R, Hietala SL, Deshpande R, Smith DM, Loy D, Ashley CS

(1994) J. Membrane Sci. 94:85 [4.176] Muller A, Reuter H, Dillinger S (1995) Angew. Chern. 107:2505 [4.177] Brinker CJ, Scherer GW (1990) Sol-Gel Science, Academic Press, New York [4.178] Lee S-Y, Aris R (1985) Catal. Rev.-Sci. Eng. 27:207 [4.179] Uchytil J, Kraus M, Schneider P (1986) Appl. Catal. 28: 133 [4.180] Hugo P, Koch H (1978) Chern.-Ing.-Tech. 50:637 [4.181] Parlitz B, Hanke W, Fricke R, Richter M, Roost U, Ohlmann G (1985) J. Catal.

94:24 [4.182] Jerschkewitz H-G, Lischke G, Ohlmann G (1983) Appl. Catal. 6:213 [4.183] Ogino Y, Nakajima S (1967) J. Catal. 9:251 [4.184] Riekert L, Weber W (1977) Chern.-Ing.-Tech. 49:42 [4.185] Liu J, Feng X, Fryxell GE, Wang L-Q, KirnAY, Gong M (1998) Adv. Mater.

10: 161 [4.186] Yang P, Zhao D, Margolese DI, Chmelka BF, Stucky GD (1998) Nature 396:152 [4.187] Vartuli JC, Kresge CT, Roth WJ, McCullen SB, Beck JS, Schmitt KD,

Leonowicz ME, Lutner JD, Sheppard EW (1996) in [4.188] S. 1 [4.188] Moser WR (Ed.) (1996) Advanced Catalysts and Nanostructured Materials -

Modern Synthetic Methods. Academic Press, New York [4.189] Akporiaye DE (1998) Angew. Chern. 110:2594 [4.190] Zones SI, Nakagawa Y, Yuen LT, Harris TV (1996) J. Am. Chern. Soc. 118:7558 [4.191] Lobo RF, Tsapatsis M, Freyhardt CC, Chan I, Chen C-Y, Zones SI, Davis ME

(1997) J. Am. Chern. Soc. 119:3732 [4.192] Widawski G, Rawiso M, Francois B (1994) Nature 369:387 [4.193] Boyett RE, Stevens AP, Ford MG, Cox PA (1996) Zeolites 17:505 [4.194] Willock DJ, Lewis DW, Catlow CRA, Hutchings GJ, Thomas JM(1997) J. Mol.

Catal. 119:415 [4.195] Antonietti M, Berton B, Goltner B, Hentze H-P (1998) Adv. Mater. 10: 154 [4.196] Holland BT, Blanford CF, Stein A (1998) Science 281:538 [4.197] Kong J, Soh HT, Cassell AM, Quate CF, Dai H (1998) Nature 395:878 [4.198] Interrante LV, Hampden-Smith MJ (Eds.) (1998) Chemistry of Advanced

Materials -An Overview. Wiley-VCH, New York [4.199] Honicke D (1991) Chern. Tech. 43:326 [4.200] WieBrneier G, Honicke D (1996) J. Micrornech. Microeng. 6:285 [4.201] WieBrneier G, Honicke D (1996) Ind. Eng. Chern. Res. 35:4412 [4.202] DeLancey GB (1974) Chern. Eng. Sci. 29: 1391 [4.203] Wohlfahrt K (1982) Chern. Eng. Sci. 37:283 [4.204] Hegedus LL (1980) Ind. Eng. Chern. Prod. Des. Dev. 19:533 [4.205] Beeckman JW, Hegedus LL (1991) Ind. Eng. Chern. Res. 30:969 [4.206] Buzanowski MA, Yang RT (1990) Ind. Eng. Chern. Res. 29:2074 [4.207] Eigenson AS (1977) Int. Chern. Eng. 17:332 [4.208] Ohtsuka T (1977) Cat. Rev.-Sci. Eng. 16:291 [4.209] Yen YK, Furlani DE, Weller SW (1976) Ind. Eng. Chern. Proc. Des. Dev. 15:24 [4.210] Ruckenstein E, Tsai MS (1981) AIChE J 27:697 [4.211] Do DD (1984) AIChE J 30:849 [4.212] Rajagopalan K, Luss D (1979) Ind. Eng. Chern. Process Des. Dev. 18:459 [4.213] Pereira C, Beeckmann JW (1989) Ind. Eng. Chern. Res. 28:422 [4.214] Chiang C-L, Yu CH (1990) Chern. Eng. Sci. 45:3002 [4.215] Pereira CJ (1990) Ind. Eng. Chern. Res. 29:512 [4.216] Keil FJ, Rieckmann C (1993) Hung. J. Ind. Chern. 21:277 [4.217] Keil FJ, Rieckmann C (1994) Chern. Eng. Sci. 49:4811


[4.218] AvnirD, Citri 0, Farin D, Ottolenghi M, Samuel J, Seri-Levy A (1989) in: Plath PJ (Ed.) Optimal Structures in Heterogeneous Reaction Systems. SpringerVerlag, Heidelberg

[4.219] Hegedus LL (Ed.) (1987) Catalyst Design. John Wiley, New York [4.220] Becker ER, Pereira CJ (Eds.) (1993) Computer-Aided Design of Catalysts. Marcel

Dekker, New York [4.221] Forster AL (1946) US-Patent 2408164 [4.222] Hegedus LL (Ed.) (1987) Catalyst Design - Progress and Perspectives.

John Wiley, New York [4.223] Becker ER, Pereira CJ (Eds.) (1993) Computer-Aided Design of Catalysts.

Marcel Dekker, New York [4.224] Bell AT (1990) Chern. Eng. Sci. 45:2013 [4.225] Hegedus LL, Pereira C (1990) Chern. Eng. Sci. 45:2027 [4.226] Thomas JM, Zamaraev KI (1994) Angew. Chemie 106:316 [4.227] Sie ST, Krishna R (1998) Rev. Chern. Eng. 14:159 [4.228] Nakamura S, Sieber S (1998) in: Schleyer PvR (Ed.) Encyclopedia of

Computational ChemiStry. John Wiley, New York, Vol. 1, p. 246 [4.229] Kito S, Hattori T, Murakami Y (1989) Appl. Catal. 48:107 [4.230] Kihara K, Tanaka M, Doyama M, Yamamoto R (Eds.) (1993) Computer

Aided Innovation of New Materials II. North-Holland, Amsterdam [4.231] Hattori T, Kito S (1995) Catal. Today 23:347 [4.232] Freeman CM, Catlow CRA, Thomas JM, Brode S (1991) Chern. Phys.

Lett. 186:137 [4.233] Avnir D (Ed.) (1989) The Fractal Approach to Heterogeneous Catalysis. John

Wiley, New York [4.234] Rothschild WD (1991) Catal. Rev.-Sci. Eng. 33:71 [4.235] Farin D, Avnir D (1988) 1. Am. Chern. Soc. 110:2039 [4.236] Avnir D, Farin D, Pfeifer P (1992) New J. Chern. 16:439 [4.237] Bunde A, Havlin S (1994) Fractals in Science. Springer-Verlag, Heidelberg [4.238] Unger KK, Rouquerol J, Sing KSW, Kral H (Eds.) (1988) Stud. Surf. Sci. Catal.

Vol. 39, Elsevier, Amsterdam [4.239] Boudart M (1969) Adv. Catal. 20:153 [4.240] Romeu D, Gomez A, Perez-Ramirez JG, Silva R, Perez OL, Gonzalez AE,

Yacaman MJ (1986) Phys. Rev. Lett. 57:2552 [4.241] Pfeifer P, Kenntner J, Wragg JL, West J, White HW (1989) Proc. Amer. Phys.

Soc. Meetings 34:728 [4.242] Sulikowski B (1993) J. Phys. Chern. 97:1420 [4.243] Rigby SP, Gladden LF (1996) Chern. Eng. Sci. 51:2263 [4.244] Pfeifer P, Avnir D (1983) 1. Chern. Phys. 79:3558 [4.245] Rolle-Kampczyk U, Karger J, Caro J, Noack M, Klobes P, Rohl-Kuhn B (1993) 1.

Colloid Interface Sci. 159:366 [4.246] Pfeifer P, Avnir D, Farin D (1984) 1. Stat. Phys. 36:699 [4.247] Friesen WI, Laidlaw WG (1993) 1. Colloid Interface Sci. 160:226 [4.248] Krohn CE, Thompson AH (1986) Phys. Rev. B 33:6366 [4.249] Schmidt PW (1988) Macromol. Chern. Macromol. Symp. 15:153 [4.250] Schmidt PW (1988) Stud. Surf. Sci. Catal. 39:35 [4.251] Reich MH, Russo SP, Snook IK, Wagenfeld HK (1990) J. Colloid Interface Sci.

135:353 [4.252] Devereux F, Boilot JP, Chaput F, Sapoval B (1990) 65:614 [4.253] Mendelson KS (1986) Phys. Rev B 34:6503 [4.254] Pape H, Schopper JR (1988) Stud. Surf. Sci. Catal. 39:473 [4.255] Pfeifer P (1984) Appl. Surf. Sci. 18:146 [4.256] Gouyet J-F, Rosso M, Sapoval B (1991) in: Bunde A, Havlin S Fractals and

Disordered Systems. Springer-Verlag, Heidelberg [4.257] Barabasi A-L, Stanley HE (1995) Fractal Concepts in Surface Growth. Cambridge

University Press, Cambridge


[4.258] ReifF (1976) Grundlagen der Physikalischen Statistik und der Physik der Wiirme. Walter de Gruyter, Berlin

[4.259] Havlin S, Ben-Avraham D (1987) Adv. Phys. 36:695 [4.260] Russ JC (1994) Fractal Surfaces. Plenum Press, New York [4.261] Gutfraind R, Sheintuch M, Avnir D (1991) J. Chern. Phys. 95:6100 [4.262] Mandelbrot BB (1983) The Fractal Geometry 0/ Nature. Freeman, New York, S. 83 [4.263] Giona M (1992) Chern. Eng. Sci. 47:1503 [4.264] Giona M, Schwalm W A, Androver A, Schwalm MK (1996) Chern. Eng. Sci.

51:2273 [4.265] Giona AR, Giona M, Marelli L (1992) Chern. Eng. Sci. 47:2623 [4.266] Seri-Levy A, Avnir D (1991) Surf. Sci. 248:258 [4.267] Guo X, Zhong B, Peng S (1994) Surf. Sci. 321:2261 [4.268] Elias-Kohav T, Sheintuch M, Avnir D (1991) Chern. Eng. Sci. 46:2787 [4.269] Gutfraind R, Sheintuch M (1992) Chern. Eng. Sci. 47:4425 [4.270] Meakin P (1986) Chern. Phys. Letters 123:428 [4.271] Fichthom KA, ZiffRM, Gulari E (1988) Stud. Surf. Sci. Catal. 38:883 [4.272] Sheintuch M, Brandon S (1989) Chern. Eng. Sci. 44:69 [4.273] Meakin P, Sapoval B (1991) Phys. Rev. A 43:2993 [4.274] Coppens M-O, Frornent GF (1995) Chern. Eng. Sci. 50:1013, 50:1027,49:4897 [4.275] Coppens M-O, Frornent GF (1996) Chern. Eng. Sci. 51:2283 [4.276] Avnir D, Biham 0, Lidar D, Malcai ° (1998) Science 279:39 [4.277] Keil FJ, Hinderer J, Garayhi A (1999) Catal. Today 50:637 [4.278] Saracco G, Neornagnus HWJP, Versteeg GF, Van Swaaij WPM (1999) Chern.

Eng. Sci. 54:1997 [4.279] Guo X-Y, Keil FJ (1999) in: Keil FJ, Mackens W, VoB H, Werther J (Eds.)

Scientific Computing in Chemical Engineering II. Springer Verlag, Heidelberg, S.82

[4.280] Interrante LV, Hampden-Smith MJ (Eds.) (1998) Chemistry 0/ Advanced Materials. Wiley-VCH, New York, Ch. 7, 8

[4.281] Keil FJ (1999) Microporous and Mesoporous Mat. 29:49 [4.282] Kliiner T, Thiel S, Freund HJ, Staemmler V (1998) Chern. Phys. Lett. 294:413 [4.283] Jacobs PW, Sornorjai GA (1998) J. Mol. Catal. A 131:5 [4.284] Cremer PD, Su SC, SornOljai GA, Shen YR (1998) J. Mol. Catal. A 131 :225 [4.285] Hiivecker M, Knop-Gericke A, Schedel-Niederig T, Schlagl R (1998) Angew.

Chemie 110:2049 [4.286] Grasselli RK, Sleight AW (Eds.) (1991) Structure - Activity and Selectivity

Relationships in Heterogeneous Catalysis. Stud. Surf. Sci. Catal., Vol. 67, Elsevier, Amsterdam

[4.287] Davis ME, Suib SL (Eds.) (1993) Selectivity in Catalysis. ACS Symp. Servo Vol. 517, Chern. Soc., Washington

[4.288] Butt JB (1980) Reaction Kinetics and Reactor Design. Prentice Hall, Kap. 4 [4.289] Sauer J, Ugliengo P, Garrone E, Saunders VR (1994) Chern. Rev. 94:2095

5 Experimentelle Methoden

[5.1] Loschrnidt J (1870) Sitzber. Akad. Wiss. Wien 61:367 [5.2] Stefan J (1873) Sitzber. Akad. Wiss. Wien 68:385 [5.3] Waitz K (1882) Ann. Physik 17:201 [5.4] von Obermayer A (1882) Sitzber. Akad. Wiss. Wien 85:147 [5.5] Marrero TR, Mason EA (1972) J. Phys. Chern. Ref. Data 1:3 [5.6] Dunlop PJ, Harris KR, Young DJ (1992) in: Rossiter BW, Baetzold RC (Eds.)

Physical Methods o/Chemistry, Vol. 6: Determination o/Thermodynamic Properties. John Wiley, New York, S. 175

[5.7] Jost W (1960) Diffusion in Solids, Liquids and Gases, Academic Press, New York


[5.8] Cussler EL (1997) Diffusion: Mass Transfer in Fluid Systems. Cambridge University Press, Cambridge (2nd Edition)

[5.9] Ney EP, Armistead FC (1947) Phys. Rev. 71:14 [5.10] van Heijningen RJJ, Feberwee A, van Oosten A, Beenakker JJM (1966) Physica

32:1649 [5.11] van Heijningen RJJ, Harpe JP, Beenakker JJM (1968) Physica 38:1 [5.12] Walker RE, Westenberg AA (1958) J. Chern. Phys. 29:1139 [5.13] Bendt PJ (1958) Phys. Rev. 110:85 [5.14] Harteck P, Schmidt HW (1933) Z. Physik. Chern. (Leipzig) B21 :447 [5.15] Reus KW, Zwakhals CJ, Smit JA (1980) Physica 100C:221 [5.16] Wakeham WA, Nagashirna A, Sengers N (Eds.) (1991) Measurement of the

Transport Properties of Fluids. Blackwell Scientific Publications, Oxford [5.17] Taylor G (1953) Proc. Roy. Soc. (London) 219:186 [5.18] Taylor G (1954) Proc. Roy. Soc. (London) 225:473 [5.19] Aris R (1956) Proc. Roy. Soc. (London) 235:67 [5.20] Giddings JC, Seager SL (1965) Ind. Eng. Chern. Fundam. 1 :277 [5.21] Lauer HH, McManigill D, Board RD (1983) Anal. Chern. 55:1370 [5.22] Roth M, Steger JL, Novotny MY (1987) J. Phys. Chern. 91: 1645 [5.23] Alizadeh A, Nieto de Castro CA, Wakeman WA (1980) Int. J. Thermophys. 1:243 [5.24] Saad H, Gulari E (1984) Ber. Bunsenges. Phys. Chern. 88:834 [5.25] Jonas J (1972) Rev. Sci. Instr. 43:643 [5.26] Cantor DM, Jonas J (1977) J. Mag. Res. 28:157 [5.27] Takahashi S, Hongo M (1982) J. Chern. Eng. Japan 15:57 [5.28] lorntev MB, Tsekhanskaya Yu V (1964) Russ. J. Phys. Chern. 38:485 [5.29] KnaffG, Schliinder EU (1987) Chern. Eng. Proc. 21:101 [5.30] Lai C-C, Tan CoS (1993) Ind. Eng. Chern. Res. 32:1717 [5.31] Liong KK, Wells PA, Foster NR (1991) J. Supercrit. Fluids 4:91 [5.32] Brunner G (1994) Gas Extraction. Steinkopff, Darmstadt, Springer, Heidelberg [5.33] Wicke E, Kallenbach R (1941) Kolloid Zeitsch. 97:135 [5.34] Graham T (1833) Phil. Mag. 2:175,269,351 [5.35] Buckingham E (1904) U. S. Dept. Agr., Bur. Soils, Bull. No. 25 [5.36] Satterfield CN (1970) Mass Transfer in Heterogeneous Catalysis, MIT Press,

Cambridge, Mass. [5.37] Dullien FAL (1979) Porous Media: Fluid Transport and Pore Structure.

Academic Press, New York [5.38] Haynes HW (1988) Catal. Rev.-Sci. Eng. 30:563 [5.39] Park I-S, Do DD, Rodrigues AE (1996) Catal. Rev.-Sci. Eng. 38:189 [5.40] Segschnieder C (1994) Charakterisierung des Trager- und Beladungsmittelein

flusses bei Fliissigfilm-Tragerkatalysatoren (SLPC) mittels stationarer und instationarer Diffusionsmessungen. Dissertation, TU Hamburg-Harburg

[5.41] Barrer RM (1939) Trans. Faraday Soc. 35:628 [5.42] Barrer RM (1941) Diffusion in and through Solids. Cambridge University Press,

Cambridge [5.43] Weisz PB, Schwarz AB (1962) J. Catal. 1 :399 [5.44] WeiszPB (1957)Z. Physik. Chern., N. F. 11:1 [5.45] Ruthven DM (1984) Principles of Adsorption and Adsorption Processes. John

Wiley, New York [5.46] Scott DS, Dullien FAL (1962) AIChE J 8:113 [5.47] Schneider P, Smith JM (1986) AIChE J 14:886 [5.48] Barrer RM, Skirrow G (1948) J. Polym. Sci. 3:549 [5.49] Eberly PE, Vohsberg DB (1965) Trans. Faraday Soc. 61:2724 [5.50] Villet RH, Wilhelm RH (1961) Ind. Eng. Chern. 53:837 [5.51] Ponzi M, Papa J, Rivarola JBP, Zgrablich G (1977) AIChE J 23:347 [5.52] Satterfield CN, SarafSK (1965) Ind. Eng. Chern. Fundam. 4:451 [5.53] Cadle PJ, Satterfield CN (1968) Ind. Eng. Chern. Fundam. 7:192 [5.54] Okazaki M, Tamon H, Toei R (1981) AIChE J 27:262


[5.55] AsaedaM, Watanabe J, Matono Y, KojimaK, Toei R(1981) 1. Chern. Eng. Japan 14:13

[5.56] Yang RT, Liu R-T (1982) Ind. Eng. Chern. Fundam. 21:262 [5.57] Rieckmann C, Keil FJ (1999) Chern. Eng. Sci. (irn Druck) [5.58] Barrer RM, Grove DM (1951) Trans. Faraday Soc. 47:826 [5.59] Barrer RM, Grove DM (1951) Trans. Faraday Soc. 47:837 [5.60] Barrer RM, Barrie JA (1952) Proc. Roy. Soc. 213A:250 [5.61] Carman PC, Raal FA (1954) Trans. Faraday Soc. 50:842 [5.62] Goodknight RC, KlikoffWA, Fatt I (1960) 1. Phys. Chern. 64:1162 [5.63] Goodknight RC, Fatt I (1961) 1. Phys. Chern. 65:1709 [5.64] Gilbilaro LG, Gioia F, Greco G (1970) Chern. Eng. 1. 1 :85 [5.65] Burghardt A, Smith 1M (1979) Chern.Eng. Sci. 34:267 [5.66] Dogu G, Smith 1M (1975) AIChE J 21:58 [5.67] Dogu G, Smith 1M (1976) Chern. Eng. Sci. 31:123 [5.68] Amost D, Schneider P (1994) Chern. Eng. Sci. 49:393 [5.69] Biswas J, Do DD, Greenfield PF, Smith 1M (1987) Appl. Catal. 32:217 [5.70] Biswas J, Do DD, Greenfield PF, Smith 1M (1987) Appl. Catal. 32:235 [5.71] Nakano Y, Takazawa A, Kimura M (1982) 1. Chern. Eng. Japan 15:70 [5.72] Nakano Y, Akai K, Suzuki S, Asahina M, Tsuneshige Y (1986) Chern. Eng. Sci.

41:3205 [5.73] Dogu T, Cabbar C, Dogu G (1993) AIChE J 39:1895 [5.74] Lu ZP, Loureiro 1M, Rodriguez AE (1992) AIChE J 38:416 [5.75] Baiker A, New M, Richarz W (1982) Chern. Eng. Sci. 37:643 [5.76] Novak M, Schneider P (1990) Appl. Catal. 66:209 [5.77] Bardakci T, Gasner LL (1981) Thermochirnica Acta 45:233 [5.78] Valus J, Schneider P (1981) Appl. Catal. 1 :355 [5.79] Cui CL, Schweick D, Villermaux J (1989) Chern. Eng. Process 26:121 [5.80] Rieckmann C, Keil FJ (1996) Hung. J. Ind. Chern. 24:295 [5.81] Rieckmann C, Keil FJ (1997) Ind. Eng. Chern. Res. 36:3275 [5.82] Amost D, Schneider P (1995) Chern. Eng. 1. 57:91 [5.83] Schneider P, Gelbin D (1985) Chern. Eng. Sci. 40:1093 [5.84] McGreavy C, Siddiqui MA (1980) Chern. Eng. Sci. 35:3 [5.85] Burghardt A, Rogut J, Gotkowska J (1988) Chern. Eng. Sci. 43:2463 [5.86] Capek P, Hejtmanek V, Solcova 0, Klusacek K, Schneider P (1997) Catalysis

Today 38:31 [5.87] Sotirchos S (1992) Chern. Eng. Sci. 47:1187 [5.88] Roiter VA, Komeichuk GP, Leperson MG, Stukanowskaia NA, Tolchina BI

(1950) Zh. Fiz. Fhirn. 24:459 [5.89] Hegedus LL, Petersen EE (1974) Cat. Rev.-Sci. Eng. 9:245 [5.90] Quingfeng G, Shaofen L, Hui L (1993) Chinese 1. Chern. Eng. 1:213 [5.91] Kopa~ T, Dogu G, Dogu T (1996) Chern. Eng. Sci. 51:2201 [5.92] Hegedus LL, Petersen EE (1973) Chern. Eng. Sci. 28:345 [5.93] Scott DS, Lee W, Papa J (1974) Che. Eng. Sci. 29:2155 [5.94] Gangwal SK, Hudgins RR, Bryson AW, Silveston PL (1971) Can. 1. Chern. Eng.

49:113 [5.95] Cresswell DL, Orr NH (1982) in: Petho A, Noble RD (Eds.) Residence Time

Distribution Theory in Chemical Engineering. Verlag Chemie, Weinheirn [5.96] Sharma RK, Cresswell DL, Newson EJ (1991) Ind. Eng. Chern. Res. 30:1428 [5.97] Solcova 0, Schneider P (1994) Chern. Eng. Sci. 49:401 [5.98] Wicke E (1939) Kolloid-Zeitschr. 86:167 [5.99] Wicke E (1939) Kolloid-Zeitschr. 86:295 [5.100] Wicke E (1940) Kolloid-Zeitschr. 93:129 [5.101] Bohernen J, Purnell JH (1961) J. Chern. Soc. 360 [5.102] Fejes P, Czaran L (1961) Hung. Acta Chim. 29:171 [5.103] Giddings JC, Seager SL (1960) 1. Chern. Phys. 33:1579 [5.104] Bournia A, Coull J, Houghton G (1961) Proc. Royal Soc. A261:227


[5.105] Taylor G (1953) Proc. Royal Soc. 219A:186 [5.106] Taylor G (1954) Proc. Royal Soc. 223A:446 [5.107] Taylor G (1954) Proc. Royal Soc. 225A:473 [5.108] Aris R (1956) Proc. Royal Soc. 235A:67 [5.109] Levenspie! 0, Smith W K (1957) Chern. Eng. Sci. 6:227 [5.110] Suzuki M, Smith JM (1975) Adv. Chromatogr. 13:213 [5.111] Cresswell DL, Orr NH (1982) in: PethO A, Noble RD (Eds.) Residence Time

Distribution Theory. Verlag Chemie, Weinheim [5.112] Kubin M (1965) Colln. Czech. chern. Commun. 30: 1104 [5.113] Kucera E (1965) J. Chromatogr. 19:237 [5.114] Schneider P, Smith JM (1968) AIChE J 14:762 [5.Il5] Suzuki M (1990) Adsorption Engineering. Kodansha Elsevier, Tokyo (Kap. 6) [5.116] Haynes HW (1988) Cata!. Rev.-Sci. Eng. 30:563 [5.117] Hays JF, Clements WC, Harris TR (1967) AIChE J 13:373 [5.118] Gangwal SK, Hudgins RR, Bryson AW, Silveston PL (1971) Can. J. Chern. Eng.

49:113 [5.119] Gangwal SK, Hudgins RR, Silveston PL (1979) Can. J. Chern. Eng. 57:609 [5.120] Gelbin D, Wolft H-J, Neinass J (1982) Chern. Tech. 34:559 [5.121] Lapidus L, Amundson NR (1952) J. Phys. Chern. 56:984 [5.122] Klinkenberg A (1954) Ind. Eng. Chern. 46:2285 [5.123] Rosen JB (1952) J. Chern. Phys. 20:387 [5.124] Rosen JB (1954) Ind. Eng. Chern. 46:1590 [5.125] Rasmuson A, Neretnieks I (1980) AIChE J 26:686 [5.126] Rasmuson A (1982) Chern. Eng. Sci. 37:787 [5.127] Ma YH, Mance! C (1973) Adv. Chern. 121:392 [5.128] Haynes HW, Sharma PN (1973) AIChE J 19:1043 [5.129] Hashimoto N, Smith JM (1973) Ind. Eng. Chern. Fundarn. 12:353 [5.130] Boniface H, Ruthven DM (1985) Chern. Eng. Sci. 40:1401 [S.131] Haynes HW (1986) AIChE J32:1750 [5.132] Carta G (1988) Chern. Eng. Sci. 43:2877 [5.133] Kumar R, Duncan RC, Ruthven DM (1982) 60:493 [5.134] Hsu L-KP, Haynes HW (1981) AIChE J 27:81 [5.135] Hsiang CS, Haynes HW (1977) Chern. Eng. Sci. 32:678 [5.136] Langer G, Roethe A, Roethe K-P, Gelbin D (1978) tnt. J. Heat Mass Trans. 21:751 [5.137] van Deemter JJ, Zuiderweg FJ, Klinkenberg A (1956) Chern. Eng. Sci. 65:271 [5.138] Dixon AG, Ma YH (1988) Chern. Eng. Sci. 43:1297 [5.139] Pazdernik 0, Schneider P (1981) J. Chromatogr. 207:181 [5.140] Fu CC, Ramesh MSP, Haynes HW (1986) AIChE J 32:1848 [5.141] Forni L, Viscardi CF, OlivaC (1986) J. Cata!' 97:469 [S.142] Chiang AS, Dixon AG, Ma YH (1984) 39: 1461 [5.143] Shah DB, Ruthven DM (1977) AIChE J 23:804 [S.144] Ruthven DM, Derrah RI, Loughlin KF (1973) Can. J. Chern. 51:3S14 [5.145] Eic M, Ruthven DM (1988) Zeolites 8:472 [5.146] Schneider P (1986) Chern. Eng. Sci. 41:1759 [5.147] Karger J, Ruthven DM (1992) Diffusion in Zeolites and other Microporous Solids.

John Wiley & Sons, New York [S.148] Post MFM (1991) Stud. Surf. Sci. Cata!' 58:391 [5.149] Ruthven DM (1994) Process Techno!. Proc. (Separation Technology) 11:1 [5.150] Rees LVC (1994) Stud. Surf. Sci. Cata!' 84: 1133 [5.151] Chen NY, Degnan TF, Smith CM (1994) Molecular Transport and Reaction in

Zeolites. VCH, New York [5.152] Karger J, Pfeifer H (1994) in: NMR Techniques in Catalysis (Bell AT, Pines A

(Eds.)) Marcel Dekker, New York [S.153] Karger J, Fleischer G (1994) Trends in Analytical Chemistry 13:145 [5.154] Gladden L (1993) TransI ChernE, Part A 71:657


[5.155] Callaghan PT (1991) Principles of Nuclear Magnetic Resonance Microscopy. Clarendon Press, Oxford

[5.156] Jobic H, Bee M, Caro J, Karger J, BUlow M (1989) J. Chern. Soc. Faraday Trans. 85:4201

[5.157] Datema KP, den Ouden CJJ, Ylstra WD, Kuipers HPCE, Post MFM (1991) J. Chern. Soc. Faraday Trans. 87:1935

[5.158] Germanus A, KargerJ, Pfeifer H (1984) Zeolites 4:188 [5.159] Germanus A, Karger J, Pfeifer H, Samulevick NN, Zhdanov SP (1985) Zeolites

5:91 [5.160] Karger J (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.) Handbook of

Heterogeneous Catalysis. VCH, Weinheim, Vol. 3,S. 1252 [5.161] Forste C, Germanus A, Karger J, Mobius G, Bulow M, Zhdanov SP,

Feoktistova NN (1989) Isotopenpraxis 24:48 [5.162] Grenier Ph, Meunier PG, Gray J, Karger J, Xu Z, Ruthven DM (1994) Zeolites

14:242 [5.163] Karger J, Pfeifer H (1987) Zeolites 7:90 [5.164] Heink W, Karger J, Pfeifer H, Salverda P, Daterna KP, Nowak A (1992) 1. Chern.

Soc. Faraday Trans. 88:515 [5.165] Caro J, Karger J, Finger G, Pfeifer H, Schallner R (1976) Z. Phys. Chern.

(Leipzig) 257:903 [5.166] Laidler KJ (1987) Chemical Kinetics. Harper and Row, New York [5.167] Atkins PW (1990) Physical Chemistry. Oxford University Press, Oxford (4th Ed.) [5.168] Hong U, Karger J, Pfeifer H, Muller U, Unger KK (1991) Z. Phys. Chern.

(Leipzig) 173 :225 [5.169] Hinderer J, Keil FJ (1996) Chern. Eng. Sci. 51:2667 [5.170] Karger J, Petzold M, Pfeifer H, Ernst S, Weitkamp J (1992) 1. Catal. 136:283 [5.171] Karger J (1992) Phys. Rev. A45:4173 [5.172] Hahn K, Karger J, Kukla V (1996) Phys. Rev. Lett. 76:2762 [5.173] Karger J, Keller W, Pfeifer H, Ernst S, Weitkamp J (1995) Microporous Mat.

3:401 [5.174] Hahn K, Karger J (1995) 1. Phys. A: Math. Gen. 28:3061 [5.175] Riekert L (1970) Adv. Catal. 21 :281 [5.176] Volter J, Caro J, BUlow M, Fahlke B, Karger J, Hunger M (1988) Appl. Catal.

42:15 [5.177] Karger J, Pfeifer H, Caro J, Bulow M, Schlodder H, Mostowitz R, Volter J (1987)

Appl. Catal. 29:21 [5.178] Hong U, Karger J, Pfeifer H (1991) 1. Am. Chern. Soc. 113:4812 [5.179] Nivarthi SS, McCormick AV (1995) 1. Phys. Chern. 99:4661 [5.180] Hong U, Karger J, Hunger B, Feoktistova NN, Zhdanov SP (1992) 1. Catal.

137:243 [5.181] Snurr RG, Hagen A, Ernst H, Schwarz HB, Ernst S, Weitkamp J, Karger J (1996)

1. Catal. 163:130 [5.182] Ernst H, Ernst S, Karger J, Roser T, Schwarz HB, Snurr RQ, Weitkamp J (1995)

Stud. Surf. Sci. Catal. 94:748 [5.183] Datema KP, den Ouden CJJ, Ylstra WD, Kuipers HPCE, Post MFM, Karger J

(1991) 1. Chern. Soc. Faraday Trans. 87:1935 [5.184] Gorring RL (1973) 1. Catal. 31:13 [5.185] Karger J, Ruthven DM (1989) Zeolites 9:267 [5.186] Cavalcante CL, Eic M, Ruthven DM, Occelli ML (1995) Zeolites 15:293 [5.187] HungerM (1997) Catal. Rev.-Sci. Eng. 39:345 [5.188] Haw JF (1994) in: Bell AT, Pines A (Eds.) NMR Techniques in Catalysis. Marcel

Dekker, New York, S. 139 [5.189] Caro J, Jobic H, BUlow M, Karger J, Zibrowius B (1993) Adv. Catal. 39:351 [5.190] Sears VF (1966) Can. 1. Phys. 44:1299 [5.191] Jobic H, Bee M, Kearley GJ (1992) Zeolites 12:146 [5.192] Hall PL, Ross DK (1981) Mol. Phys. 42:673


[S.193] Jobic H (1994) in: Irnelik B, Vedrine JC (Eds.) Catalyst Characterization. Plenum Press, New York, S. 347

[S.194] Marshall W, Lovesey S (1971) Theory of Thermal Neutron Scattering. Oxford University Press, Oxford

[S.19S] Jacobs WPJH, de Haar YO, van Santen RA, de Graaf LA (1994) J. Phys. Chern. 98:2180

[S.196] Jobic H, Bee M, Karger J, Vartapetian RS, Balzer C, Julbe A (199S) J. Mernbr. Sci. 108:71

[S.197] Karge HG, Niessen W (1991) Catalysis Today 8:4S1 [S.198] Niessen W, Karge HG (1993) Micropor. Mat. 1:1 [S.199] Niessen W, Karge HG (1994) Stud. Surf. Sci. Catal. 84:1191 [S.200] Schuth F (1992) J. Phys. Chern. 96:7493 [S.201] SchUth F, Demuth D, Kallus S (1994) Stud. Surf. Sci. Catal. 84:1223 [S.202] Eic M, Goddard M, Ruthven DM (1988) Zeolites 8:327 [S.203] Eic M, Ruthven DM (1988) Zeolites 8:472 [S.204] BUlow M, Micke A (199S) Adsorption 1:29 [S.20S] Micke A, BUlow M, Kocirik M (1994) J. Phys. Chern. 98:924 [S.206] Micke A, BUlow M, Kocirik M, Struve P (1994) J. Phys. Chern. 98:12337 [S.207] Bulow M, Micke A (1993) J. Chern. Soc. Faraday Trans. 90:2S8S [S.208] Yasuda Y (1976) J. Phys. Chern. 80:1867 [S.209] Van den Broeke LJP, Bakker WJW, Kapteijn F, Moulijn JA (1999) Chern. Eng.

Sci. S4:24S [S.210] Bakker WJW, Kapteijn F, Poppe J, Moulijn JA (1996) J. Membrane Sci. 117:S7 [S.211] Bein T (1996) Chern. Mater. 8:1636 [S.212] Xiao J, Wei J (1992) Chern. Eng. Sci. 47:1123 [S.213] Van den Broeke LJP, Kapteijn F, Moulijn JA (1999) Chern. Eng. Sci. S4:2S9 [S.214] Keil FJ, Hinderer J, Garayhi AR (1999) Catal. Today SO:637 [S.21S] Yasuda Y (1982) J. Phys. Chern. 86:1913 [S.216] Yasuda Y, Sugasawa G (1984) J. Catal. 88:S30 [S.217] Yasuda Y, Yamamoto A (198S) J. Catal. 93:176 [S.218] Yasuda Y (1994) Heterogen. Chern. Rev. 1:103 [S.219] Micke A, Kocirik M, Caro J (1990) J. Chern. Soc. Faraday Trans. 86:3087 [S.220] BUlow M, Micke A (1990) ZEUS-Zeolite Uptake Simulator-Software. Dechema

Monographien, Bd. 118, S. 349 [S.221] BUlow M, Schodder H, Rees LVC, Richards RE (1986) Stud. Surf. Sci. Catal.

28:S79 [S.222] Van den Begin NG, Rees LVC (1989) Stud. Surf. Sci. Catal. 49:91S [S.223] Van den Begin NG, Rees LVC, BUlow M (1989) Zeolites 8:287 [S.224] Shen D, Rees LVC (1991) Zeolites 11:684 [S.22S] Shen D, Rees LVC (1991) Zeolites 11:666 [S.226] Rees LVC, Shen D (1994) Stud. Surf. Sci. Catal. 87:S63 [S.227] Sun LM, Meunier F, Karger J (1993) Chern. Eng. Sci. 48:72S [S.228] Sun LM, Bourdin V (1993) Chern. Eng. Sci. 48:3783 [S.229] Brandani S (1998) Chern. Eng. Sci. S3:2791 [S.230] Ruthven DM, Brandani S (1997) in: Fraissard J (Ed.) Physical Adsorption:

Experiment, Theory and Applications. NATO ASI Series C Vol. 491, Kluwer Academic Publishers, Dordrecht

[S.231] Barrer RM (1951) Diffusion in and through Solids. Cambridge University Press, Cambridge

[5.232] Parvar AR, Hayhurst DT (1984) in: Bisio A (Eds.) Proc. 6th Int. Zeolites Conf., Butterworth, Guildford, S. 217

[5.233] Wernick DL, Osterhuber EJ (1984) in: Bisio A (Ed.) Proc. 6th Int. Zeolites Conf., Butterworth, Guildford, S. 122

[5.234] Wernick DL, Osterhuber EJ (1985) J. Membrane Sci. 22:137 [5.235] Shah DB, Chokchai-acha S, Hayhurst DT (1993) J. Chern. Soc. Faraday Trans.

89:3161

[5.236] Shah DB, Liou HY (1994) Zeolites 14:541 [5.237] Sun MS, Talu 0, Shah DB (1996) AIChE J 42:3001 [5.238] Talu 0, Sun M S, Shah D B (1998) AIChE J 44:681


[5.239] Bourdin V, Gennanus A, Grenier P, Karger J (1996) Adsorption 2:205 [5.240] Bourdin V, Grenier F, Meunier F, Sun DM (1996) AIChE J 42:700 [5.241] Ruthven DM, Lee LK (1981) AIChE J 27:654 [5.242] Doelle H-J, Riekert L (1979) Angew. Chern. 91:309 [5.243] Biilow M, Karger J, Kocirik M, Voloscuk M (1981) Z. Chern. 21:175 [5.244] Doelle H-J, Heering J, Riekert L (1981) J. Catal. 71:27 [5.245] Prinz D, Riekert L (1986) Ber. Bunsenges. Phys. Chern. 90:413 [5.246] Biilow M, Lorenz P, Mieth W, Struve P, Samulevic NN (1983) J. Chern. Soc.

Faraday Trans. 78: 1099 [5.247] Nijhuis TA, van den Broeke LJP, van de Graaf 1M, Kapteijn F, Makkee M,

Mou1ijn JA (1997) Chern. Eng. Sci. 52:3401 [5.248] Gleaves JT, Ebner JR, Kuechler TC (1988) Catal. Rev.-Sci. Eng. 30:49 [5.249] Gleaves JT, Yablonskii GS, Phanawadee P, Schuunnann Y (1997) Appl. Catal. A:

General 160:55 [5.250] WoodruffDP, Delchar TA (1994) Modern Techniques of Surface Science.

Cambridge University Press, Cambridge (2nd Ed.) [5.251] Imelik B, Vedrine JC (Eds.) (1994) Catalyst Characterization. Physical

Techniques for Solid Materials. Plenum Press, New York [5.252] Niemantsverdriet JW (1995) Spectroscopy in Catalysis. VCH, Weinheim [5.253] Thomas 1M, Thomas WJ (1996) Principles and Practice of Heterogeneous

Catalysis. VCH, Weinheim (Kap. 3) [5.254] Wachs IE (Ed.) (1992) Characterization of Catalytic Materials. Butterworth

Heinemann, Boston [5.255] Henzler M, Gopel W (1994) Oberfliichenphysik des Festkorpers. B.G.Teubner,

Stuttgart [5.256] Joyner RW, van Santen RA (Eds.) (1993) Elementary Reaction Steps in

Heterogeneous Catalysis. Kluwer Academic Publishers, Dordrecht [5.257] Ertl G, Kiipers J (1986) Low Energy Electrons and Surface Chemistry. Verlag

Chemie, Weinheim [5.258] Dror S (1991) Scanning Force Microscopy. Oxford University Press, Oxford [5.259] Ibach H (1991) Electron Energy Loss Spectrometers. Springer-Verlag, Heidelberg [5.260] Ferguson IF (1989) Auger Microprobe Analysis. A. Hilger, New York [5.261] Carlson TA (1975) Photoelectron and Auger Spectroscopy. Plenum Press,

New York [5.262] Thompson M (1985) Auger Electron Microscopy. John Wiley, New York [5.263] Yates JT, Madey TE (1987) Vibrational Spectroscopy of Molecules on Surfaces.

Plenum Press, New York [5.264] Hudson JB (1992) Surface Science: An Introduction. Butterworth-Heinemann,

Boston [5.265] O'Conner DJ, Sexton BA, Smart RSC (Eds.) (1992) Surface Analysis Methods in

Materials Science. Springer Series in Surface Science, Vol. 23. Springer-Verlag, Heidelberg

[5.266] Park RL, Lagally MG (Eds.) (1985) Solid State Physics: Surfaces, Methods of Experimental Physics, Vol. 22. Academic Press, New York

[5.267] StOhr J (1992) NEXAFS Spectroscopy. Springer Series in Surface Sciences, Vol. 25. Springer-Verlag, Heidelberg

[5.268] Rossiter BW, Baetzold RC (Eds.) (1993) Investigations of Surfaces and Interfaces, Part A. Physical Methods ofChemistra, Vol. 9A. John Wiley & Sons, New York

[5.269] Giinterodt HJ, Wiesendanger R (Eds.) (1992) Scanning Tunneling Microscopy I: General Principles and Applications to Clean and Adsorbate Covered Surfaces. Springer Series in Surface Sciences, Vol. 20. Springer-Verlag, Berlin

[5.270] Somorjai GA (1994) Introduction to Surface Chemistry and Catalysis. John Wiley, New York


[5.271] Surface Science Band 299/300 [5.272] Gunter PLJ, Niemantsverdriet JWH, Ribeiro FH, Somorjai GA (1997) Catal. Rev.

Sci. Eng. 39:77 [5.273] Dumesic JA, Rudd DF, Aparicio LM, Rekoske JE, Trevino AA (1993) The Micro

kinetics of Heterogeneous Catalysis. American Chemical Society, Washington [5.274] Ertl G (1991) in: Jennings JR (Ed.) Catalytic Ammonia Synthesis: Fundaments

and Practice, Fundamental and Applied Catalysis. Plenum Press, New York [5.275] Yates IT (1998) Experimental Innovations in Surface Science. Springer-Verlag,

New York [5.276] Stoltze P, Nsrskov JK (1985) Phys. Rev. Lett. 55:2502 [5.277] Stoltze P (1995) in: Nielsen A (Ed.) Ammonia: Catalysis and Manufacture.

Springer-Verlag, Heidelberg [5.278] Askgaard TS, Nsrskov JK, Ovesen CV, Stoltze P (1995) J. Catal. 156:229 [5.279] Ovesen CV, Stoltze P, Nsrskov JK, Campbell CT (1992) 134:445 [5.280] Ovesen CV, Clausen S, Hammersksi B, Steffensen G, Askgaard T,ChorkendorrfI,

Nsrskov JK, Rasmussen PB, Stoltze P, Taylor P (1996) J. Catal. 158: 170 [5.281] Alstrup I, Tavares MT (1992) J. Catal. 135:147 [5.282] Alstrup I, ChorkendorffI, Ullmanns S (1993) Surf. Sci. 293: 133 [5.283] Muhler M, Rosowski F, Hinrichsen 0, Hornung A, Ertl G (1996) Stud. Surf Sci.

Catal.l0l:317 [5.284] Ertl G (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.) Handbook of

Heterogeneous Catalysis. VCH, Weinheim, Vol. 3, S. 1032 [5.285] Stoltze P (1987) Physica Scripta 36:824 [5.286] Pendry JB (1974) Low Energy Electron Diffraction. Academic Press, London [5.287] Van Hove MA, Tong SY (1979) Surface Crystallography by LEEDS. Springer

Series on Chemical Physics, Vol. 2, Springer-Verlag, Heidelberg [5.288] Andersson S, Pendry JB (1980) J. Phys. C. - Solid State Phys. 13:3547 [5.289] Chiang S (1997) Chem. Rev. 97:1083 [5.290] Vickermann JC, Bronn A, Reed NM (Eds.) (1989) Secondary Ion Mass

Spectrometry. Oxford University Press, Oxford [5.291] Graybeal JD (1988) Molecular Spectroscopy. Mc Graw Hill, New York [5.292] Weekman VW (1974) AIChE J 20:833 [5.293] Kapteijn F, Coevert P, Moulijn JA (1982) J. Phys. E 15:1064 [5.294] Christoffel EG (1989) Laboratory Studies of Heterogeneous Catalytic Processes.

Elsevier, Amsterdam [5.295] Doraiswamy LK, Tajbl DG (1974) Catal. Rev.-Sci. Eng. 10:177 [5.296] Pratt KC (1980) in: Anderson JR, Boudart M (Eds.) Catalysis; Science and

Technology. Springer-Verlag, Heidelberg, S. 174 [5.297] Anderson JR, Pratt KC (1985) Introduction to Characterization and Testing of

Catalysts. Academic Press, New York [5.298] Kochloefl K (1975) Chemie-Technik 4:443 [5.299] Kapteijn F, Moulijn JA (1997) in: Ertl G, Knozinger H, Weitkamp J (Eds.)

Handbook of Heterogeneous Catalysis. VCH, Weinheim, S. 1189 [5.300] Adler R (Ed.) (1987) Verfahrenstechnische Berechnungsmethoden. Teil5, VCH,

Weinheim, S. 96 ff. [5.301] Bennett CO (1976) Catal. Rev.-Sci. Eng. 13:121 [5.302] Biloen P (1983) J. Mol. Catal. 21:17 [5.303] Kobayashi H, Kobayashi M (1974) Catal. Rev.-Sci. Eng. 10:139 [5.304] Kobayashi M (1982) Chem. Eng. Sci. 37:393 [5.305] Gleaves IT, Ebner JR, Kueckler TC (1988) Catal. Rev.-Sci. Eng. 30:49 [5.306] Gleaves IT, Yablonski GS, Phanawadee P, Schuurman Y (1997) Appl. Catal. A:

General 160:55 [5.307] Dekker FHM, Klopper G, Bliek A, Kapteijn F, Moulijn JA (1994) Chern. Eng.

Sci. 49:4375 [5.308] Miradatos C (1991) Catal. Today 9:83


[5.309] Tarnaru K (1991) in: Andersen JR, Boudart M (Eds.) Catalysis: Science and Technology. Vol. 9, Springer-Verlag, Heidelberg

[5.310] Wojciechowski BW (1997) Catal. Today 36:167 [5.311] Rice NM, Wojciechowski BW (1997) Catal. Today 36:191 [5.312] Asprey SP, Rice NM, Wojciechowski BW (1997) 36:209 [5.313] Box GEP, Hunter WG, Hunter JS (1978) Statistics/or Experimenters. John Wiley,

New York [5.314] Hoffmann U, Hofmann H (1971) Einfohrung in die Optimierung. VCH, Weinheirn [5.315] Keil FJ (1996) Chem.-Ing.-Techn. 68:639 [5.316] Edgar TF, Himmelblau DM (1988) Optimization o/Chemical Processes. Mc Graw

Hill, New York [5.317] Frornent GF, Bischoff KB (1990) Chemical Reactor Analysis and Design. John

Wiley, New York (2nd Ed.) [5.318] Weller SW (1992) Catal. Rev.-Sci. Eng. 34:227 [5.319] Boudart M, Djega-Mariadassou G (1984) Kinetics 0/ Heterogeneous Catalytic

Reactions. Princeton University Press, Princeton [5.320] Mezaki R, Inoue H (1991) Rate Equations o/Solid-Catalized Reactions.

University of Tokyo Press, Tokyo [5.321] Weitkamp J (1997) in: Ertl G, Krozinger H, Weitkamp J (Eds.) Handbook 0/

Heterogeneous Catalysis. VCH, Weinheirn, S. 1376 [5.322] Rase HF (1977) Chemical Reactor Design/or Process Plants. Vol. 1. John Wiley,

New York, S. 222 [5.323] Kokes RJ, Tobin H, Emmett PH (1955) J. Arner. Chern. Soc. 77:5860 [5.324] Meijer R, Kapteijn F, Moulijn JA (1994) Fuel 73:723 [5.325] Berty lM (1974) Chern. Eng. Progr. 70:78 [5.326] Carberry 11 (1980) in: Anderson R, Boudart M (Eds.) Catalysis: Science and

Technology. Springer-Verlag, Heidelberg, S. 131 [5.327] Trambouze P, Landeghern HV, Wauquier JP (1988) Chemical Reactors. Editions

Technip, Paris, S. 539 [5.328] Borman PC, Bos ANR, Westerterp KR (1994) AIChE J 40:862 [5.329] Kolaczkowski ST, Ullah U (1989) Chern. Eng. Sci. 44:2843 [5.330] Nelles J (1987) Chern. Techn. 39:328 [5.331] Durnesic JA, Rudd DF, Aparicio LM, Rekoske JE, Trevino AA (1993) The Micro

kinetics o/heterogeneous Catalysis. Arnerical Chemical Society, Washington [5.332] Stewart WE, Caracotsios M, Sorensen JP (i. Vorber.) Computational Modelling 0/

Reactive Systems. Butterworth, Stoneham [5.333] Van der Linde SC, Nijhuis TA, Dekker FHM, Kapteijn F, Moulijn JA (1997)

Applied Catalysis A 151:27 [5.334] Renken A (1990) Chem.-Ing.-Tech. 62:724 [5.335] Rothaernel M, Baems M (1996) Ind. Eng. Chern. Res. 35:1556 [5.336] Yablonskii GS, Shekhtman SO, Chen S, Gleaves JT (1998) Ind. Eng. Chern. Res.

37:2193 [5.337] Dekker FHM, Bliek A, Kapteijn F, Moulijn JA (1995) Chern. Eng. Sci. 50:3573 [5.338] Asadullin RM (1998) Theoret. Found. Chern. Eng. 32:136 [5.339] Jonkers G, Vonkernan KA, van der Waal SWA, van Santen RA (1992) Nature

355:63 [5.340] Anderson BG, de Gauw FlMM, Noordhoek NJ, van I1zendoom LJ, van Santen

RA, de Voigt MJA (1998) Ind. Eng. Chern. Res. 37:815 [5.341] Rodriguez JA, Goodman DW (1991) Surf. Sci. Rep. 14:1 [5.342] Jensen JA, Rider KB, Salmeron M, Sornorjai GA (1998) Phys. Rev. Lett. 80: 1228 [5.343] Havecker M, Knop-Gericke A, Schedel-Niedrig T, SchlOgl R (1998) Angew.

Chern. 110:2049 . [5.344] Garayhi A, Keil FJ (irn Druck) Chernische Technik (Leipzig) [5.345] Bennett CO (1967) AIChE 1. 13:891


[5.346] Bennett CO (1976) Catal. Rev.-Sci. Eng. 13:121 [5.347] Kobayashi H, Kobayashi M (1974) Catal. Rev.-Sci. Eng. 10: 139 [5.348] Kobayashi M (1982) Chern. Eng. Sci. 37:393 [5.349] Kobayashi M (1982) Chern. Eng. Sci. 37:403 [5.350] Fiolitakis E, Hofmann, H (1983) J. CataI. 80:328 [5.351] Muller E, Hofmann H (1987) Chern. Eng. Sci. 42:1705 [5.352] Muller-Erlwein E, Hofmann H (1986) Chern.-Ing.-Tech. 58:986 [5.353] Muller-Erlwein E, Hofmann H (1987) Chem.-Ing.-Tech. 59:956 [5.354] Capek P, Klusacek K (1994) Chern. Eng. Sci. 49:4095 [5.355] Nilsson R, Andersson A (1996) CataI. Today 32:11 [5.356] Nilsson R, Andersson A (1997) Ind. Eng. Chern. Res. 36:5207 [5.357] Pyatnisky YI, Ilchenko NI (1996) Catal. Today 32:21 [5.358] Do DD, Rice RG (1982) Chern. Eng. Sci. 37: 1471 [5.359] Do DD, Rice RG (1984) Chern. Eng. Sci. 39:1 [5.360] Do DD, Rice RG (1985) Chern. Eng. Sci. 40:291 [5.361] Hu X, King B, Do DD (1994) Gas Sep. Purif. 8:175 [5.362] Hu X, King B, Do DD (1994) Gas Sep. Purif. 8:187 [5.363] Bwyer SM, Bennett CO (1982) J. Catal. 75:275 [5.364] Efstathiou AM, Chafik T, Bianchi D, Bennett CO (1994) J. Catal. 147:24 [5.365] Connestra AF, Nett LC, Herz RK (1997) J. Catal. 172:346 [5.366] Waugh KC (1988) Appl. Catal. 43:315 [5.367] Tuchlenski A, Uchytil P, Seidel-Morgenstern A (1998) J. Mernbr. Sci. 140: 165 [5.368] Kapteijn F, Meijer R, Moulijn JA (1992) Energ. & Fuels 6:494 [5.369] Seidel-Morgenstern A, VollgrafK-D, Zahn A, Hofmann H (1997) Chern.-Ing.

Tech. 66: 1378 [5.370] Dettmer M, Renken A (1983) Chern.-Ing.-Tech. 55:146 [5.371] Renken A, Doepper R, Schmid M (1989) Dechema Monographie 120, VCH

Verlag, Weinheirn [5.372] Zaza Ph, Randall H, Doepper R, Renken A (1994) Catal. Today 20:325 [5.373] Golay S, Doepper R, Renken A (1998) Appl. Catal. A 172:97 [5.374] Thullie J, Renken A (1993) Chern. Eng. Sci. 48:3921 [5.375] Marwood M, Van Vyve E, Doepper R, Renken A (1994) Catal. Today 20:437 [5.376] Marwood M, Doepper R, Prairie M, Renken A (1994) Chern. Eng. Sci. 49:4801 [5.377] Randall H, Doepper R, Renken A (1997) Ind. Eng. Chern. Res. 36:2996 [5.378] Randall H, Doepper R, Renken A (1996) Can. J. Chern. Eng. 74:586 [5.379] Randall H, Doepper R, Renken A (1998) Appl. Catal. B 17:357 [5.380] Rahakama K, Salmi T (irn Druck) Chern. Eng. Sci. [5.381] Klusacek K, Schneider P (1982) Chern. Eng. Sci. 37:1523 [5.382] Sica AM, Valles EM, Gigola CE (1978) J. CataI. 51:115 [5.383] Cider L, SchOon N-H (1991) Appl. CataI. 68:191 [5.384] Suzuki T, Ikenaga N, Matsui N, Nakagawa K (irn Druck) Chern. Eng. Sci. [5.385] Cullis CF, Keene DE, Trimm DL (1970) J. CataI. 19:378 [5.386] Polinski LM, Naphtali LM (1963) Adv. Catal. 19:241 [5.387] Evnochides SK, Henley EI (1970) J. Polymer Sci. 8:1987 [5.388] Van-Den-Begin NG, Rees LVC in: Jacobs PA, van Santen RA (Eds.) (1989)

Zeolites: Facts, Figures, Future. Elsevier, New York, S. 915 [5.389] Jordi RG, Do DD (1992) J. Chern. Soc., Farad. Trans. 88:2411 [5.390] Yasuda Y (1976) J. Phys. Chern. 80:1867


[5.391] Sun LM, Meunier F, Grenier Ph, Ruthven DM (1994) Chern. Eng. Sci. 49:373 [5.392] Sun LM, Meunier F, Kiirger I (1993) Chern. Eng. Sci. 48:715 [5.393] Bourdin V, Grenier Ph, Meunier F, Sun LM (1996) AIChE J. 42:700 [5.394] Leder F, Butt JB (1966) AIChE J. 12:1057 [5.395] Lynch DT, Walters NP (1990) Chern. Eng. Sci. 45:1089 [5.396] Lorenz WJ (1989) Dechema Monographie 120, VCR-Verlag, Weinheim, S. 151

Sachverzeichnis

u s-Darstellungen 29Si Magic Angle Spinning (MAS) Abbruchradius ab-initio-Verfahren Ablagerung abriebfeste Matrix Adsorbat Adsorbat -Adsorbat -W echselwirkung Adsorption Adsorption auf der Oberfliiche Adsorption von Multikomponentengasen Adsorptionsenergie Adsorptionsenergieverteilung Adsorptionsgeschwindigkeit Adsorptionsgeschwindigkeit nach Langmuir Adsorptionsgleichgewichtskonstante Adsorptionsisotherme Adsorptionskinetik Adsorptionskurve Adsorptionsmolekiile Adsorptionspotential nach Polanyi Adsorptionsstelle Adsorptionsvorgiinge Adsorptionswiirme des Atoms Adsorptionswiirme Aerogele AES (Auger Electron Spectroscopy) AES-Versuchsanordnung AFM (Atomic Force Microscopy) Aggregation von Reaktanten Akkomodationskoeffizient aktives Zentrum aktivierter Kohlenstoff aktivierter ProzeB Aktivierungsenergie Aktivkohle Alkane Alkylierung von Toluol allgemeines Grahamsches Gesetz Alumophosphate AMBER Ammoniaksynthese amorpher Festkorper amorpher Kohlenstoff Analytik von Mehrkomponentengemischen

167 217

46,48 141, 143

117,161,185 202

55 68,90,104

2,54 ff, 59, 89, 124,217,240,246 248

71 58,88

204 81 86

l30 59 ff, 66, 67, 71,100,108,167,217

75ff 82

169 168

84 ff, 94 140 142

55,56,57,58,65,114,125,196 191, 192

270 271 268 140

76, 77 87, 126, 127,266

191,192 94, 102

90,98,109 207 112 117 240 194 52

127, l37, 221 170 217 274

326 Sachverzeichnis

Anhaftung anionische Clays anomale Diffusion Aromatisierung Arrheniusgleichung Atomic Superposition and Delocalization (ASED) Auger-Elektronenspektroskopie (AES) Ausbeute iiuBere Transporthemmungen iiuBerer Kreislaufreaktor Autoklav axialer Dispersionskoeffizient Backbone-Cluster Barrett, Joyner und Halenda (BJH) Baule-Modell Bedeckung Bedeckungsgrad Benzol Berty-Reaktor Bethe-Gitter Bethe-Peierls-Isotherme bewegliche Precursoren bidisperses Gitter Bildverarbeitung biniirer Diffusionskoeffizient Binary Friction Model Bindungsrotation Bindungswinkel BoBo-Reaktor Boltzmann-Faktor Boltzmann-Gleichung Boltzmann-Konstante Boltzmannsche StoBintegral Boltzmann-Verteilung Bond Order Conservation principle (BOC) Bond-Order-Conservation-Morse-Potential-Methode (BOC-MP) Bond-Perkolation Bom-Oppenheimer-Approximation Bosanquet-Gleichung Box-Dimension Box-Ziihl-Methode Bragg-Williams-Approximation Broglie-Wellenliinge Bronstedt-Siiurezentren Brunauer, Emmett und Teller (BET-Methode) Brunauer-Emmett-Teller-Isotherme (BET) Buckingham-Potential Cab-O-Sil Calcinierung Cantor-Menge Carbeniumionen-Modell Carberry-Reaktor Carbon Molecular Sieves (CMS) Carbons

76 205

152,204,210,217,219 201

110, 184 143 95

211 266 277 275 246

118, 119 167 78

129,130 57,96

113 277

120,161, 190 69 87

162 170 227

5,25,211 50 49

279 37

1,5,6,8,9 28 9

28 197 141

118,119 143

26,109,162 173 172

69, 70 43

196 152, 167

75 51

221 212

175,222 198

277,279 206 ff

191,206,208

Catalyst Design CATALYST II-Programm CFF chaotisches VerhaIten Chapman-Enskog-Niiherung CHARMM chemische Reaktion chemische Turbulenz chemischer Diffusionskoeffizient Chemisorption Chemisorptionswlirme chirale Katalyse Clays Clusterberechnung Clusterbildung Configurational Bias Monte Carlo (CBMC) Configurational-Bias-Monte-Carlo-Methode (CBMC) connectivity COPS Coulomb-Krafte Coulomb-Wechselwirkung Cracken Cyc1isierung Darcy-Gesetz Darcysche Gesetz Darken-Gleichung Defekte d-Elektronen d-Elektronenbander Desaktivierung Desorption Desorption der Produkte Desorptionsenergie Desorptionsgeschwindigkeit Desorptionsgeschwindigkeitskonstante Dewaxing-Process DichtefunktionaItheorie (DFT) Diederwinkel Differentialreaktoren Diffusion Diffusion der Edukte Diffusion der Produkte Diffusion in Fraktalen Diffusion in Zeolithen DiffusionslReaktionsphanomen DiffusionslReaktionsproblem DiffusionsIReaktionszelle Diffusionsbarriere Diffusionsbriicke Diffusionseffekt Diffusionsenergiebarriere Diffusionsgleichung Diffusionsgleitung Diffusionshemmung

Sachverzeichnis 327

266 135 52

138 5,8

52 1, 115

138 103

2,56,57,186 57

205 108,185,212

197 225 44

114 159 166 50 50

201 201 237

19 36,207

270 125 57

3,179,185 ff,276 2,55,58,88,96,98,124,240

181 92

89,91 88

200 143 49

276 1,5,96,181,217

181 181

216 ff 191 ff,248

163 2

22 19

227,231 228 104 33

5 182

328 Sachverzeichnis

DiffusionskoeffIzient 7, 108, 109, 11 0, 113, 207, 248 DiffusionskoeffIzienten aus gaschromatographischen Messungen 243 DiffusionskoeffIzienten in iiberkritischen Gasen 231 Diffusionsvorglinge 2 Diffusionszelle 95, 233, 234, 235 Dimension 172, 177 Direct Simulation Monte Carlo (DSMC) 10 Dispersion des Katalysators 271 Dispersionsmodell 245 Dispersionswechselwirkung 51 Disproportionierung 201 Dissoziation 55,83 dissoziative Adsorption 63 DLA Cluster 224 donationlbackdonation mechanism 145 dreidimensionale Modelle 240 dreidimensionale Porenraummodelle 159 ff dreidimensionales Gitter 116, 161, 189 dreidimensionales Gittermodell 160,214 dreidimensionales ZSM-5-Gitter 117 DREI-DING 52 Druckverlust 247 Dual Control Volume Grand Canonocal Molecular Dynamics (DCV-GCMD) 53 Dubinin-Astakkov-Gleichung 204 Dubinin-Radushkevich-Gleichung (DR) 168 Dubinin-Radushkevich-Isotherme 75 Dufour-Effekt 228 Dusty-Gas-Modell (DGM) 1,2,5 ff, 99,163,183,185,211,217 Edukt-Selektivitat 199 EELS 272 Effective Medium Approximation 180 effektive Oberflache 217 effektive Reaktionsgeschwindigkeitskonstante 162 effektiver DiffusionskoeffIzient 1,3,156 einfache Porenrnodelle 153 ff Einfangswahrscheinlichkeit 80 Einkristallflache 267 Einstein-Gleichung 34 Einstein-Relation 33, 110, 255 Einzelpelletdiffusionsreaktor 3, 100,241 ff Einze1pelletstrangreaktor 241, 242 e1astische Riickstreuung III elastische Streuung 76 elektrische Felder 115 Elektronenrnikroskopie 217 Elementarprozesse 143 Elementarschritte 267 Eley-Rideal-Ansatz 163,275 Eley-Rideal-Mechanismus 58, 126 ff enantiomerenreine chirale Gruppen 192 Enantiomerentrennung 192 Energieband 145 Energieerzeugungsfunktion 183 Entmetallisierung 119

Ergodenhypothese Erwartungswerte Ethenselektivitat Euler-Gleichung Eulersche Gleichungen Ewald-Summation extended-Huckel-Niiherung (EHT) Exzesszustandssumme f(a)-Kurve Feldelektronenspektroskopie (FEM) F eldemissionsfluktuationsmethode Feldionenspektroskopie (FIM) Ferminiveau F estbettreaktor feste Losung von Reaktanten F estkorperdiffusion Ficksche Gesetz Finite-Size-Scaling Flammenionisationsdetektor flexibles Gitter floating molecules Flory-Huggins-Gleichung Flugzeitrnethode Fluid-Catalytic-Cracking-ProzeB (FCC) Fluktuations-FEM F olgereaktion formselektive Katalyse auf der auBeren Oberflache formselektive Katalyse F ormse1ektivitat Foster-Butt-Porenmodell Fouling Fourier-Transformations-Infrarotspektroskopie (FT -IR) Fourier-Transformations-PFG NMR Fowler-Adsorptionsisotherme Fracton-Dimension Fraktale fraktale Dimension fraktale Membranen fraktale Struktur freie Energie Frequency Response Methode (FR) Freundlich-Isotherme funktionelle organische Zeolith-Analoga GaslFeststoff-Katalyse Gaschrornatographie Gasdiffusionskoeffizient Gasphasendiffusion Gastheorie GauB-Radau-AIgorithmus GauBsche Normalverteilung GCMC-Methode Gelbildung geometrische Effekte Gesamtbindungsordnung

Sachverzeichnis 329

28 38

202 1, 10

11 50

143 38

178 94 94 94

148 201 171 187 96

121 260 111 111 74 76

201 98

185 199

194, 198 115,199

154 186 258 256

65,69 220

117, 171 ff, 172, 173,216 ff, 219 217,218

225 3, 140

125 261

63, 136 192

2, 124 227

3 97 6

47 218

74 117 126 141

330 Sachverzeichnis

geschichtete Doppe1hydroxide (LDH) Geschwindigkeits-Autokorre1ationsfunktion geschwindigkeitsbestimmender Schritt Geschwindigkeits-Verlet-Algorithmus Gibbsche Fundamentalgleichung Gift Gittergas Gittergasmodell Gittermodell Gitterschwingung Gleichgewichtsthermodynamik Gleitungsreibung Grahamsche Diffusionsgesetz Grahamsche Gesetz Green-Kubo-Formel Green-Kubo-Relation GREG (Generalized Regression Software) GREG-Pack groBkanonische Zustandssumme groBkanonisches Ensemble groBkanonisches MC (GCMC)-Verfahren Haftkoeffizient Haftung Haftwahrscheinlichkeit Hamilton-Funktion Hamilton-Operator harte Kugeln harte-Kugel-Modell Hartree-Fock-Methode Hebelgesetz HEED (High Energy Electron Diffraction) He1iumpyknometer Henry-Koeffizient Henry-Konstante heterogene Porenstruktur Heterogenitat der Oberfliiche Hill-De Boer-Gleichung Hochdruck-Niederenergie-Rontgenabsorptionsspektroskopie HOMO Hooksche Gesetz hopping Hopping-Mechanismus Hoshen-Kopeiman-Algorithmus Hougen-Watson-Kinetik hydrierende Entmetallisierung Hydrierung Hysteresekurven HZSM-5 ideales Gas importance sampling Impulsraum in situ Diffusionsmessungen inelastische StoBe inelastische Streuung

205 35

133 47

1,10 128 62 68 80

III 59

5 13

17,24,26 35 33

280 135 68

38,43 44

83, 128 77,83 83,87

29 145 71 77

143 69

268 154 246 97

184 64,136,237

70 216 146 49 94

102, 107,208 122, 123

128 190,213

206 166 110 38 39

27,39 256

8 76

instationiirer Betrieb der WKZ Integralgleichungsmethode Integralreaktoren Integrodifferentialgleichung intrakristalliner Diffusionskoeffizient Ionenstrahlen IR Ising-Modell Isomerisierungsreaktion Isomerisierungsschritte isosterische Adsorptionswiirme IUP AC-Klassifikation Jelliumpotential Johnson-Stewart-Porenmodell Jovanovic-Gleichung Kanalkreuzung kanonisches Ensemble Kapillarkondensation Katalysatoraktivitiit Katalysatordesaktivierung Katalysatordesign Katalysatortrager Katalysatorvergiftung Katalyse katalytisch aktive Oberflache katalytisch aktives Zentrum Kelvin-Gleichung Keramiken kinetische Kopplung Klassifikation nach Brunauer Kleinwinkelrontgenstreuung Knudsen-Diffusion Kochkurve Kohlenstoff-Molsieb Kohlenstoffnanorohrchen Kohlenwasserstoffe Kohlenwasserstoffe in Zeoli then Kohleverbrennung Koksbildung im ZSM-5 kombinatorische Chemie kompakte Inseln Kompensationseffekt Kompositkatalysatoren Kompressibilitatsfaktor Konfigurationsintegral Konfigurationsraum konfigurelle Diffusion konkurrierende Adsorption Kontinuumbeschreibung Kontinuum-Modell konvektiver FluB konvektiver Transport Komgrenzendiffusion Korrelationsenergie

Sachverzeichnis 331

238 71

276 9

260 271 272

68 128 200

74 153 78

154 71

111 28,37,38,43, 111

206 124

185 ff 3,215 ff

151,158, 192,211 186 185

2 151 152

191,206 135 61

170,217 5,6,7,96,107,152,206,214

173 206,207

108 201 198 117 190 274 140 136 202 103 38

27,38 21,36, 107ff, 152, 196, 199,206,213,214

62 128

137ff, 181 ff 6 7

187 143

332 Sachverzeichnis

Korrelationsfunktion Korrelationsliinge korrigierte Diffusionskoeffizient Kraftkonstante Kubo-Green-Beziehung Kugelreaktor Laborreaktoren Labyrinthfaktor Langevin Dynamics Langevin-Bewegungsgleichung Langmuir-Adsorptionsisotherme Langmuir-Freundlich-Isotherme Langmuir-Hinshelwood- Hougen-Watson-Kinetik (LHHW) Langmuir-Hinshelwood-Ansatz Langmuir-Hinshelwood-Hougen-Watson-Ansatz Langmuir-Hinshelwood-Kinetik Langmuir-Hinshelwood-Mechanismus Langmuir-Hinshelwood-Reaktion Langmuir-Isotherme Langmuir-Konstante Larmor-Frequenz Laser Laser induzierte Desorption (LID) Laserpuls latente Poren laterale AbstoBung laterale Wechselwirkung leap-frog LEED (Low Energy Electron Diffraction) Lennard-Jones-Parameter Lennard-Jones-Potential Lennard-Jones-Wechselwirkungspotentiale Liouvillescher Satz Lorentz-Berthelot-Mischungsregel Loschmidt-Zelle LUMO Lumping-Methode M4lS MacElroy Magic-Angle-Spinning-NMR (MAS NMR) Magnetic Resonance Imaging (MRI) Makrogitter Makropore Makroporenbildner Makroporendiffusionskoeffizient MAPO mari Markov-Kette MassendurchfluBregler Mastergleichung Maxwell-Boltzmann-Verteilung MCM-41 MCM-48 MCM-50

31 104, 121

114 49

103 183 274

14 53 81

60,61,62,87, 131 72

128 ff, 135 163 275

128, 189 58, 126 ff

218 64, 68, 130, 136

61 250

95 95 95

166 57

63,93 47

268 48

46,51,56,80,109 210

9 51

228 146 137 194 210 256 217 162

153, 156 212 246 194 132 40

280 53 45

194,212 212 212

MeALPOs mean field approximation Mean-Transport-Pore-Modell (MTPM) Mehrkomponentendiffusionskoeffizient Mehrschichtenadsorption Melamin Membran Membranreaktor Membrantrennverfahren Memoryfunktion Menger-Schwamm Mesopore Messung von Diffusionskoefftzienten in Gasen Metalle Metalloxidoberflachen Methanol to Gasoline Methanolsynthese Metropolis-Algorithmus M -Forming-Process Michaelis-Menten-Kinetik MikrolMakroporenmodell Mikrogitter mikrokanonisches Ensemble mikrokinetische Analyse mikrokinetischer Ansatz mikrokinetisches Modell Mikropore Mikroporendiffusionskoeffizient mikroporose Materialien mikroporose Medien mikroporose Systeme mikroporose Trager Mikropulsreaktor Mikroreaktoren Mikrowaage Millersche Indizes Minimum Image Mischkatalysator mittlere quadratische Verschiebung MM2 MM3 mobile Adsorption

Sachverzeichnis 333

194 137

8,24,238 258

67 212

25,108,206 99 26 32

175 153 227 206 144 201 183

37,40,42,70 200 133 153 162 52

280 267 128

153, 156 246

191,248 2,3 185 152 276 275 265 127 48

130 255

52 52 70

Mobil's Olefin To Gasoline and Destillate (MOGD) Modelle der Katalysatordesaktivierung Modellkatalysatoren

201 188

267,268 200

2,44,73,75,87,104,109,139,169,210 207

6,7,152,206 191 198 76

Molecular Traffic Control Effect Molekulardynamik Molekulardynamik-Methode molekulare Diffusion molekulare Diffusionskoeffizient Molekularsieb-Effekt Molekularstrahlexperiment Molekiildynamik Momentenmethode

44 ff, 95 240,246

334 Sachverzeichnis

Monomer-Dimer-Modell 140 Monomer-Monomer-Modell 140 Monte Carlo 70,71,73,75,87,92,93,95,104,106,109,128,139,169,179, 207, 208, 273 Monte-Carlo-Methode 2, 36, 68 Monte-Carlo-Rechnung 2 Monte-Carlo-Simulation 36 ff Morse-Potential 141 most abundant reacting intermediate 132 most abundant reactive intermediate (mari) 137 MTG-ProzeB 201 MTG-Synthese 202 MTO-Synthese 202 multifraktale Analysen 222 multifraktale Geometrie 218 Multifraktale 177 multifunktionelle Apparate 206 Multikomponentendiffusion 1, 19,36, 183, 185,208 Multikomponentengemisch 255 Multipolentwicklung 50 n-Alkane 114 nanoporose Kohlenstoffmembran 192 Navier-Stokes-Gleichung 1, 10, 11 NEMD 114 Netzwerk 184 ff Netzwerkmodell 160, 163,225 Nichtgleichgewichts-MD 114 Nichtgleichgewichtsphanomen 31 niederenergetische Elektronenbeugung (LEED) 95 n-Komponenten Adsorptionsiostherme 72 NMR 248 NMR Imaging 152 NMR Relaxation eines Fluids im porosen Medium 217 nonequilibrium molecular dynamics NEMD 52 Nose-Hoover-Thermostat 52 NOx-Reduktion 204 Oberflachenatome 269 Oberflachenaufrauhung 106 Oberflachendiffusion 6,7,22,36,58,94 ff, 96, 97, 98, 99,100,104,107,158,187,206 Oberflachendiffusionskoeffizient 96, 98 Oberflachendiffusionsstrom 138 Oberflachenrauhigkeit 171 Olefin To Gasolin (MOG) 201 Olefinse1ektivitat 202 OIigomerisierung 201 optimale Verteilung der katalytischen Aktivitat 189 Optimierung 3, 275 Optimierung der Porenstruktur 165,211 ff,213 Optimierung der Struktur von Katalysatortragern 211 Orbitaliiberlappung 145 Orientierung von Molekiilen in ZeoIithkanalen 259 ortho/para-W asserstoffzelle 22 Ortsraum 39 osmotische Diffusion 19 osziIlierende Reaktion 137,267

Oxychlorierung Paarverteilungsfunktion Palladiummembran paradox of surface catalysis Paraffine Parallelbiindelmodell Parallelporenmodell Parallelreaktion PARFIT partielle Oxidation Partikeldichtefunktion Partikelporositat Pauli-Prinzip Pelettierdruck periodische Randbedingungen Perkolation Perkolationsc1uster Perkolationsphanomen Perkolationsschranke Perkolationstheorie Permeabilitat PFG-NMR PFG-NMR-Methode Phasenraum Phasenfibergangsphanomen Phasenumwandlung photoelektrischer Effekt Photonenkorrelationsspektroskopie (PCS) Physisorption Pillared Clays Poiseuille-Stramung Polymere Polymerisation Poreneingangsablagerung Poreneingangsvergiftung Porengeometrie Porenmodelle Porennetzwerk Porennetzwerke flir be1iebige Systeme kinetischer Gleichungen Porenoberflache Porenradien Porenradienverteilung Porenstruktur Porenstrukturoptimierung Porenverstopfung Porenwirkungsgrad porase Medien Porositat Porositats-Tortuositatsfaktor Positron Emission Profiling (PEP) Positron Emission Tomography (PET) Potentialbarriere Potentiale Potentialtopf

Sachverzeichnis 335

188 30

206 136 201 184

153, 190 185 135 206 30 97

146 211 48

204 122

185 ff 118,161

117ff, 159, 179ff, 189,214 7, 14, 152,237

114 100, 165

27 117 187 270 232

2,56 191,203 ff

206 206 117 188 188

7 151 ff

118, 163 185 170 207

152,211 3,151 3, 152

3 181

1,5,96 153, 164

7 257 257

94,116,215 49 88

336 Sachverzeichnis

Pradiktor-Korrektor-Methode Precursor Precursor-Adsorption Precursor-Mechanismus precursor-moderierte Adsorption Precursorzustand Prekusor Prinzip von Sabatier Produkt-Selektivitat Promotor Propagator pseudohomogenes Medium pseudohomogenes Reaktormodell Pulsed Field Gradient NMR (pFG NMR)

46 140 85

126 87 87 58

124 199 128 253 240

1

Pulsed Gradient Spin Echo, Nuclear Magnetic Resonance-Methode (PGSE-NMR) Pulsreaktoren

98,249 152 275 285 230

Pulsverfahren Punktquellenverfahren quantenchemische Methode Quantenmechanik quasielastische Lichtstreuung Quasielastische Neutronenstreuung (QUENS) Quecksilberporosimetrie QUENS QUENS-Methode Random Walker Random-Pore-Modell rare events Rastertunnelmikroskopie rationale Synthesestrategien RA ITLE-Algorithmus Rauhigkeit der reaktiven Oberfliiche raurnzeitliche Strukturbildung Rayleigh-Peaks Reaktion Reaktionen auf katalytischen Oberflachen Reaktionsdimension Reaktionsgeschwindigkeit Reaktionsgeschwindigkeitskonstante Reaktionsordnung Reaktionspfade Reaktionswahrscheinlichkeit Reaktionszyklus Redispergierung Reflexions-Infrarotspektroskopie (IR) Resonanzintegral Reverse Spillover Richardson-Darstellung Richtungsanisotropie Rontgenbeugung Rontgen-Diffraktometrie Rontgen-Photoelektronenspektroskopie (XPE) RotoBerty-Reaktor Riickadsorption

2, 109 141 232 256

152, 153, 15~ 169,217 114,248,256 ff

100,256 ff 218 155 53 94

212 52

221 140 233

1,2,58,181,217 124 ff

221 125 255 130 143

116,222 124, 125

188 95

145 101 218 106 269 152 96

278 96

Riickbindung Riickdiffusion SANS SAPO-34 SAPOs Satzreaktor Saure-Base-Katalyse SAXS Scanning Tunneling Microscopy (STM) Scharmittel SchrOdinger-Gleichung SchwerOifraktionen Schwingungsfrequenz Selbstiihnlichkeit Selbstdiffusion Selbstdiffusionskoeffizient Selbstorganisation Selektivitat des Ubergangszustandes Selektivitat Selektivitatssteuerung seltenes Ereignis semiempirische Verfahren SHAKE-Algorithmus shape selectivity Shell Poly-Gasoline and Kero (SPGK) Sierpinski-Dreieck Silikalit SIMS (Secondary Ion Mass Spectroscopy) Single-Crystal-Membrane-Methode (SCM) Single-File-Diffusion Sintern Sinterung Site-Perkolation Skaleninvarianz Skalierung Skelettisomerisierung Smectite Sorptionsmessung spatio-temporal patterns spatio-temporal structures

Sachverzeichnis 337

146 231 217 202 194 275 116

170,217 70,94

28 143 213 109 172 33

35,102,112,229,255 212 199

3,128, 185, 186,211,217,225 202 110 141 52

199 201 174

110, 112, 113 270 263

108,255 124, 187

187 119 172 164 201 203

154,265 ff 140 268

Spektroskopische Methoden zur Untersuchung von Festkorperoberfiachen Spillover

266 ff 100, 101

233 103 102 213 184 211 191 234

Spinning-Basket -Reaktor Sprungdiffusionskoeffizient Sprungmechanismus SSZ-31 stabile Betriebspunkte Standzeit Standzeit der Katalysatoren stationarer Betrieb der WKZ statistische Mechanik statistische Therrnodynarnik Steady State Isotope Technique for Kinetic Analysis (SSITKA) Stefan-Maxwell-Gleichung

26 ff 59

127 8

338 Sachverzeichnis

Stefan-Rohr Steuerung des Sol-Gel-Prozesses sticking Stickstoff-Sorption . STM (Scanning Tunneling Spectroscopy) Stopp-Effekt StoBparameter Stromungsgeschwindigkeit Stromungsmodellierung Struktur-Aktivitats-Beziehung Strukturfaktor strukturinsensitiv strukturinsensitive Reaktion Strukturkonstante struktursensitiv struktursensitive Reaktion Struktursensitivitat Summenfrequenzerzeugung Surface Science Surface-Science-Methode Surface-Science-Verfahren Szintillationszahler TAP-2-Reaktor T AP-Reaktor Taylor-Dispersion TeilchengroBeneffekt Teilchenstromdichte Ternkin-Adsorptionsisotherme Temkin-Isotherme Temperature Programmed Desorption (TPD) Temperature Programmed Reduction (TPR) Temperature-Scanning-Reaktor (TSR) temperaturprogrammierte Desorption (TPD) temperaturprogrammierte Desorptionsspektren (TPD) temperaturprogrammierte Oxidation (TPO) Template Temporal-Analysis-of-Products-Reaktor (TAP) Teufelskamm Teufelstreppe Texturparameter theoretische Chemie theoretische Trennstufe (HETP) Theorie des Obergangszustandes Thermal-Frequency-Response-Methode (TFR) thermisch induzierte Konvektion thermische Abbau thermische Diffusion

26 212

76,81 152 268 289

79 246

1 268

30 217 126 168 217 126 127 216 75

3 2,268

233 281 281

231 ff 268

82 65

136 273 273 275

90, 126 140 99

212 266 225

175,176,222 152

141 ff 247

110,114 254,264 ff

23 187 23

127 103 135 103

thermisches Aufrauhen thermodynamischer Faktor thermodynamisches Gleichgewicht thermodynamisches Potential Thiele-Modul Torsion Tortuositat

1,182,188,202,234 50

14,154,155,156, 158, 15~ 184,211,237

Toth-Gleichung Toth-Isotherme TPD-Spektren TPD-Versuchsanordnung TracerdiffusionskoeffIzient Transition State Theory Transportdiffusionskoeffizient Transportkoeffizient Transportpore TransportprozeB Transportwiderstand trapping TSR-Reaktor (Temperature Scanning Reactor) turbulente Stromung Turnover Frequency (TOF) Turnover-Einheiten Ubergangsmetalloberflache iiberkritische Bedingungen iiberkritische Gase UFF Ultrahochvakuum umgekehrte Diffusion Umweltprozesse United Atoms Model van-Deemter-Relation van-der-Waals-Potential van-der-Waals-Radien van-der-W aals-Wechselwirkung van-Krevelen-Ansatz verallgemeinerte Stefan-Maxwell-Gleichungen Verdampfungs-lKondensationsvorgange Verdampfungsrohr von Stefan Vergiftung Verkokung Verlet-Algorithmus Verlet-artige Algorithmen Verlust katalytisch aktiver Materialien Versuchsplanung Verteilung der aktiven Zentren Verteilungsfunktion Verzweigungsgrad Vinylacetat aus Ethen Volterra-Integralgleichung Voronoi-Gitter Vycor Vycor-Glas Vycor-Glaser Wahrscheinlichkeitsdichte Warmebad Warmebadeffekt Warmeleitfahigkeitsdetektor (WLD) WarmeleitfahigkeitsmeBzelle Washburn-Gleichung Wassergas-Reaktion

Sachverzeichnis 339

71 64

90, 143 273

102, 105 53

35,103,113 8,27

8,25,165 1, 151

184 76

281 10

126 221

83 3

231 ff 52

267 19,23

137 112 247

51 107

50,148,196 275

17 187 230 124

117,162,186,256 47 46

186 275 184 30

159,160, 189,214 225 260 160 191

97,206 206,211

218 111 115 239 235 169 137

340 Sachverzeichnis

Wechselwirkungsenergie Wechselwirkungspotential Wellenfrontanalyse Wicke-Kallenbach-Experimente Wicke-Kallenbach-Zelle Window-Effekt Wirbelschicht Wirkungsgrad Woodsches Metall XPS (X-Ray Photoemission Spectroscopy) XPS-Versuchsanordnung Xylol-Isomerisierung Young-Laplace-Gleichung zeitabhiingige SchrOdinger-Gleichung Zeit-Autokorrelationsfunktion Zeitkorrelationsfunktion Zeitkorrelationskoeffizient zeitlich veriinderliche Porenstrukturen Zeolith Zero-Length-Column (ZLC) Zero-Length-Column-Chrornatographie (ZLC) ZEUS-Simulator ZnO-Bett ZSM-23 Zufallsfluktuationen Zufallslaufer Zufallslaufermodell Zufallszahlengenerator Zustandssumme zweidimensionale quadratische Gitter Zwei-Kolbenmethode Zweizentrenwechselwirkung

69 30, 116

282 162

3,99, 152,234 ff, 263 ff 256 202 189 170 270 270 II7 169 128 94 34 32

179 ff 108,110, 185, 191, 193 ff, 212, 248 ff

248 259 262 187 194

81 162 255

37 28,31,38,70

190 229 141

literatu rverzeichn is - springer978-3-642-60224-5/1.pdf · literatu rverzeichn is 1 einleitung und...

Documents