j.bio.innov6 (6), pp: 864-877, 2017 |issn 2277-8330 ...water quality parameters of dharmavaram tank,...
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2017 November Edition |www.jbino.com | Innovative Association
J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
WATER QUALITY PARAMETERS OF DHARMAVARAM TANK, ANANTAPURAMU (DIST), AP, INDIA.
V N Jayaram Naik1, K V Ramanaiah2, and G H Philip3*
1 Department of Zoology, S K University, Anantapuramu 515003, Andhra Pradesh, India. 2 Department of Zoology, S K University, Anantapuramu 515003, Andhra Pradesh, India.
3* Department of Zoology, S K University, Anantapuramu 515003, Andhra Pradesh, India.,
(Received on Date: 5th October 2017 Date of Acceptance: 11st November 2017)
ABSTRACT
Different parameters in Dharmavaram tank, Dharmavaram were estimated from May
2011 to April 2013 to assess the water quality. The different Physico-chemical parameters
like Temperature, pH, TDS, conductivity, salinity, dissolved oxygen, turbidity, alkalinity, free
carbon dioxide, chloride, total hardness, calcium, magnesium, phosphates, sulphates,
silicates, nitrites, nitrates, BOD and COD were carried out by standard methods. These
parameters showed either positive or negative correlation between each other. The
analysis revels this parameters are interrelated with each other. From the data we can be
said that water of this tank is not a good quality for culture of fish as well as drinking for
animals.
Keywords: Dharmavaram tank, Water quality, Physico-chemical Parameters, BOD, COD.
No: of Tables: 2 No: of References: 40
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Naik et al.,
INTRODUCTION
India abounds in water bodies, a
preponderance of them are manmade,
typical of the tropics. The manmade
(artificial) water bodies are generally
called Reservoirs, Ponds and Tanks
though it is not unusual for some of them
to be referred to as lakes. Ponds and
tanks are small in size compared to lakes
and reservoirs. In general, water bodies
that are considered lakes in dry areas
would only be considered ponds in
regions with abundant water resources
where there are more (and large) bodies
of water [1]. The word "tank", is defined as
a container for storing water. The need
for a water tank is as old as civilization,
providing storage of water for drinking,
irrigation, agriculture, fire suppression,
chemical manufacturing, food
preparation as well as many other
applications [2]. Tank is loosely defined
and often used in common parlance to
refer to some of the small irrigation
reservoirs. Thus, a large number of small
man-made lakes are also called tanks in
Andhra Pradesh and are thereby
excluded from reservoir list. Tanks in
Andhra Pradesh are further classified as
perennial and long seasonal [3]. Andhra
Pradesh has (2937 water bodies) 98 small
reservoirs, 2800 Tanks, 32 Medium
reservoirs and 7 large reservoirs with total
surface area of 4,58,507 hectors.
Anantapuramu district has (27 water
bodies) 22 tanks and 5 reservoirs with total
surface area of 6048 hectors [4].The tank
is regularly used for fishing by the local
people besides water is used for washing
animals, tractors and cloths. Natural
calamities are completed beside the
tank and dumping of domestic solid
waste. Due to this the water of
Dharmavaram tank has become
polluted. In India much research has
been carried out with regards to
assessment of water quality of different
tanks some of them are fish pond
conservation in Tanjavur [5], Kolong river
[6], Bolinj Ram mandirtalao [7], Selected
fresh water ponds in Warangal area [8],
Kadamba Tank [9], Urban Pond in
thiruvantapuram district [10], Ponds in
Athiyanoor panchayat [11], Fish pond of
Shahdol [12], Eutrophicated costal lake
[13], Lalpur pond [14], Two temple ponds
of Karnataka [15], and different pond
water of Bilaspur district [16].
The interactions of both the physical and
chemical properties of water play a
significant role in composition, distribution,
abundance, movements and diversity of
aquatic organisms [17]. Quality of water
generally refers to the component of
water which is to be present at the
optimum level for suitable growth of
plants and animals [18]. Qualitative and
quantitative hydrological investigations
and monitoring should be done at
regular basis to study the current status of
the habitat and socio-economic activities
to identify possible solutions [19]. In order
to assess water quality index, we have
carried out the Physico- Chemical
analysis of water and to find the
relationship between different Physico-
Chemical parameters in Dharmavaram
tank. There is no information available on
this till now.
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Naik et al.,
METHODOLOGY
Study area: The study area is located 40
km from Ananthapuramu and it is 2nd
largest tank in Ananthapuramu district.
Geographically it is located at 14.43oN,
77.72o E the source of water to this tank is
from Chitavathi River.[2] It has an average
elevation of 345 meters (1131 feet). It is
famous for handloom silk sarees.
Dharmavaram town as the second
biggest tank in Ananthapuramu district
located on Chitravathi river origin at
Nandi hills, Karnataka. The storage
capacity of this tank is 0.4 TMC.
Dharmavaram tank serves as the main
source of drinking water and for irrigation.
Sample collection and analysis: Water
samples were collected during second
week at monthly interval for a period of
two consecutive years from May 2011 to
April 2013 for the analysis of Physico-
chemical parameters. Water samples
were collected in acid washed 10 liters
polythene containers below the depth of
5- 10 centimetres and collection was
usually completed during morning hours
between 08 AM and 10 AM. Colour and
odour of water was noticed and
recorded. For each sample Temperature,
pH was monitored at the sampling site
using mercury thermometer and digital
pH meter. Immediately after arrival into
the laboratory the conductivity of the
water were measured using the help of
conductivity meter. All parameters were
analyzed by following standard methods.
The chemicals used in the present
investigations were procured from Merck
India. All glass ware used was of corning
grade manufactured by Borosil India Ltd.
Spectrophotometer used for our research
work was ELICO double beam, SL210, UV
VIS Spectrophotometer. Systronics Water
Analyser 371 used with a micro controller
was used for measuring pH, Dissolved
oxygen (DO), Conductivity, Total
Dissolved Solids (TDS), Salinity and
Turbidity in water sample.Six replicates of
each sample were analyzed for each
parameter. Mean of the six replicates
were taken for data analysis.
RESULTS AND DISCUSSION
Temperature: The temperature of water
assessed between 23.25±0.273°C
(December 2011) and 29.7±0.225°C (May
2013) (Fig. A). Temperature showed
significant positive correlation with
Conductivity, Turbidity, DO, BOD, COD,
Alkalinity, Magnesium, Silicates,
Phosphates, Nitrites, Sulphates and
showed significant negatively correlation
with pH, TDS, Total hardness, Carbon
dioxide, Salinity, Chlorides, Calcium,
Nitrates (Table. 1,2). High temperatures
were observed in the month of May due
to clear atmosphere, greater solar
radiation and low water level [20]. During
winter season (December) water
temperature was low due to frequent
clouds, high humidity, high current
velocity and high water level [21], [22].
pH: The pH of water observed in January
2011 was minimum (7.98±0.033) and
maximum in and maximum in the month
of May 2013 (9.98±0.024)(Fig. B). pH
showed positive significant correlation
with Conductivity, Carbon dioxide,
Salinity, Silicates, Phosphates, Nitrates,
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J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
Sulphates and negatively correlated with
Turbidity, TDS, DO, Alkalinity, Chlorides,
Calcium, Magnesium, Nitrites(Table. 1,2).
Maximum pH in the month of May
indicate high rate of photosynthesis [23],
[24].
Conductivity: In this regard the monthly
variability in conductivity of water was
analysed between 3.686±0.217 mS
(November 2011) and 12.5±0.1366 mS
(May 2012) (Fig. C). Conductivity showed
positive significant relation with Turbidity,
TDS, DO, COD, Salinity, Alkalinity,
Chlorides, Calcium, Silicates, Phosphates,
Nitrites, Sulphates and showed negative
significant correlation with Total Hardness,
BOD, Carbon dioxide, Magnesium,
Nitrates(Table. 1,2). The electrical
conductivity values are high in the month
of May due to increased in the
concentration of salts, because of
evaporation [25], the dilution resulted
from precipitation brings down its values
in the month of November [26].
Turbidity: Turbidity of water noticed
between 3.57±0.47 NTU (November 2011)
and 13.16±0.8164 NTU (May 2012)(Fig. D).
Turbidity showed positive significant
correlation with TDS, Total hardness, DO,
COD, Carbon dioxide, Alkalinity,
Magnesium, Nitrites, Sulphates and
showed negative significant correlation
with BOD, Salinity, Chlorides, Calcium,
Silicates, Phosphates, and Nitrates (Table.
1,2). The high turbidity during summer
season (May) might be responsible for the
higher water temperature because
suspended particles absorb heat from the
sunlight making the water warm [27].
Settlement of slit, clay resulting low
turbidity in (November) winter season
[28].
Total Dissolved Solids (TDS): In 2011-12-
year personal observation shows Total
Dissolved Solids (TDS) of water analyzed
between 1848±30.90 ppm (January 2012)
and 4359.66±26.36 ppm (March 2012)
(Fig. E). TDS showed positive significant
correlation with BOD, COD, Carbon
dioxide, Salinity, Alkalinity, Chlorides,
Calcium, Magnesium and showed
negative significant correlation with Total
hardness, DO, Silicates, Phosphates,
Nitrates, Nitrites, and Sulphates (Table.
1,2). Seasonal variations showed
maximum values in summer (March) due
to evaporation of water and low level of
water and minimum during the winter
season (January) settlement of particles
in the sediment [26], [29].
Total Hardness (TH): Our analysis showed
the Total hardness of water was minimum
in September 2011 (330.46±11.09 mg/L)
and maximum in May 2012 (510.11±9.75
mg/L) (Fig. F). Total hardness showed
positive significant correlation with DO,
BOD, Carbon dioxide, Salinity, Alkalinity,
Chlorides, Calcium, Magnesium,
Phosphates, Nitrites, and showed
negative significant correlation with COD,
Silicates, Nitrates and Sulphates (Table.
1,2). Total hardness of water bodies may
be high during the summer season (May)
which may be became higher
temperature causes evaporation of
water decrease in volume of water
increase the concentration of salts and
also due regular addition of large
quantities of sewage and detergents into
water bodies from the nearby residential
localities and minimum in September is
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Naik et al.,
due dilution of concentration of salts with
influx of rain water [29], [30].
Dissolved Oxygen (DO): Analysis of
Dissolved Oxygen (DO) of water in this
study was minimum (6.33±0.016 ppm) in
May 2011 and maximum (9.041±3.4739
ppm) in January 2012 (Fig. G). Dissolved
oxygen (DO) showed positive significant
correlation with COD, Carbon dioxide,
Salinity, Calcium, Magnesium, Nitrites,
Sulphates and showed negative
significant correlation with BOD, Alkalinity,
Chlorides, Silicates, Phosphates, and
Nitrates(Table. 1,2).The maximum DO in
January might be due to low
atmospheric temperature and intensive
photosynthetic activity(31). The minimum
DO was observed during summer months
might be due to high metabolic rate of
organisms [21], [32].
Biochemical Oxygen Demand (BOD):
Monthly variation of Biological Oxygen
Demand (BOD) of water was recorded
low in May 2011 (6.333±1.032 mg/L) and
high in March 2013 (10.64±0.02 mg/L)(Fig.
H). BOD showed positive significant
correlation with Salinity, Calcium, Silicates
and BOD showed negative significant
correlation with COD, Carbon dioxide,
Alkalinity, Chlorides, Magnesium,
Phosphates, Nitrates, Nitrites and
Sulphates (Table. 1,2). Minimum BOD
values are noticed in May where as
maximum was observed in the month of
March because of input organic wastes
and enhanced bacterial activity [29],
[33].
Chemical Oxygen Demand (COD):
Assessment of COD value of water
ranged between 275.1±11.40 mg/L
(November 2011) and 508.68±5.045 mg/L
(April 2013) (Fig. I). COD showed positive
significant correlation with Carbon
dioxide, Salinity, Alkalinity, Phosphates,
and Nitrites COD showed negative
significant correlation with Chlorides,
Calcium, Silicates, Nitrates and Sulphates
(Table. 1,2). The higher values are due to
higher decomposition activities and low
level of water in April. However, minimum
COD are due to low temperature, low
decomposition activities and dilution
effect in November [30], [34].
Free Carbon dioxide (Free CO2): Results of
the concentration of Free Carbon dioxide
of water in the present study between
2.88±0.040 mg/L (July 2011) and 7.7±1.204
mg/L (May 2012) (Fig. J). Free Carbon
dioxide showed positive significant
correlation with Salinity, Alkalinity,
Calcium, Magnesium, Nitrates and it
showed negative significant correlation
with Chlorides, Silicates, Phosphates,
Nitrites and Sulphates (Table. 1, 2). The
fluctuations in free carbon dioxide values
correspond directly with standing crop of
phytoplankton increases in May, the free
CO2 lower because of greater utilization
of free CO2 for photosynthetic activity in
July [35].
Salinity: The seasonal fluctuation in the
Salinity values ranged from 2658.6±25.59
ppm (November 2011) and 6586.6±210.8
ppm (March 2013) (Fig. K). Salinity
showed significant positive correlation
with Calcium, Nitrates, Nitrites and it
showed negative significant correlation
with Alkalinity, Chlorides, Magnesium,
Silicates, Phosphates and Sulphates
(Table. 1, 2). The differences in the salinity
are attributed to the increase in the
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Naik et al.,
evaporation rate in the month of March
[36].
Alkalinity: Measurement of the Alkalinity
of water during 2011-12 fluctuated
between 25.03±1.67 mg/L (October 2011)
and 67.25±1.767 mg/L (February
2012)(Fig. L) .Alkalinity showed positive
significant correlation with Chlorides,
Calcium, Magnesium, Nitrites and
showed negative significant correlation
with Silicates, Phosphates, Nitrates and
Sulphates (Table. 1,2). The increased
alkalinity during winter (February) was
due to concentration of nutrients in
water, water level decreases result the
death of decay of plants and living
organisms [37].
Chlorides: The seasonal variation in the
Chloride content of the water was a low
level of 77.34±1.298 mg/L in October 2011
and high level of 100.67±0.98 mg/L in May
2012 (Fig. M). Chlorides showed positive
significant with Magnesium, Phosphates,
Nitrates, Nitrites and Sulphates and
showed negative significant correlation
with Calcium, Silicates (Table. 1,2)
.Concentration of higher chlorides in May
could be due to sewage mixing and
increased temperature and evaporation
of water [21].
Calcium (Ca): Determination of the
seasonal variability in the Calcium
content of water was lowest in November
2012 (70.32±0.08 mg/L) and highest in
May 2012 (90.71±0.34 mg/L) (Fig. N).
Calcium showed positive significant
correlation with Phosphates, Nitrites and
negative significant correlation with
Magnesium, Silicates, Nitrates and
Sulphates (Table. 1, 2). The high values of
Ca and Mg in water bodies may be due
to addition of lime and pesticides in an
objective for better production [38].
Magnesium (Mg): Range of Magnesium
of water between 36.39± 1.0488 mg/L
(November 2011) and 74.89±2.42 mg/L
(May 2012)(Fig. O). Magnesium showed
positive significant correlation with
Silicates, Nitrates, Nitrites, Sulphates and
showed negative significant correlation
with Phosphates (Table. 1,2). The
permissible limit of Mg content for drinking
water is 50 mg/L, maximum limit is 150
mg/l [39].
Silicates: The seasonal fluctuation in the
Silicate concentration of water was
between 0.376±0.005 ppm (January 2013)
and 0.788±0.007 ppm (May 2012) (Fig. P).
Silicates showed positive significant
correlation with Phosphates, Sulphates
and showed negative significant
correlation with Nitrates, Nitrites (Table. 1,
2). In the support of this similar trend was
noticed that the average value of silicate
ranged from 0.2 to 0.75 ppm in pond
water of Thiruchunapalli [40].
Phosphates: Phosphate value obtained in
this study ranged between 0.135±0.011
ppm (April 2012) and 0.769±0.008 ppm
(June 2012) (Fig. Q). Phosphates showed
positive significant correlation with Nitrites,
Sulphates and showed negative
significant correlation with Nitrates (Table.
1,2). The high values of phosphate are
mainly due to rain, surface water runoff,
agriculture runoff, washer man activity,
leaching of phosphate fertilizer in the
month of June [37], [40].
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Nitrates: Fluctuation of the seasonal
variability in the Nitrate concentration in
this study was as low as 0.344±0.002 ppm
in March 2012 and as high as 0.905±0.10
ppm July 2012(Fig. R). Nitrates do not
show positive significant correlation, and
negative significant correlation with
Nitrites, Sulphates (Table. 1,2). Higher
values are due to surface runoff and
domestic sewage and specially washing
activities [41].
Nitrites: Monthly variation of Nitrites
content of water in the present study
ranged between 0.127±0.003 ppm (July
2012) and 1.597±0.255 ppm (April 2013)
(Fig. S). Nitrites showed negative
significant correlation with Sulphates
(Table. 1,2). Similar trend of nitrites in
respective months was also noticed
earlier by researchers who measured
nitrites in fish pond water bodies [41].
Sulphates: Sulphate content of water was
minimum in February 2013 (0.02±0.01
ppm) and maximum in August 2012
(0.74±0.00 ppm) (Fig. T). Agriculture
increases after rains in July and more
fertilizers are used for increasing
productivity. Hence during August
Sulphate concentration in water body
could have increased as a result of runoff
water having relatively large quantities of
organic and mineral sulphur compounds
[42].
CONCLUSION
Dharmavaram Tank water was polluted
by effluents coming from runoff through
the drainage and dyes released from silk
industries, fishing, cleaning vehicles,
washing clothes etc. So the physic-
chemical parameters were beyond the
permissible limits which may cause
harmful effects on cultured fish,
Consuming this water by animals and
using this water for agriculture may
drastically affect the Agricultural
produce.
ACKNOWLEDGEMENT
I am thankful to my research supervisor
Prof.G.H.PHILIP for his fabulous support
and encouragement throughout my
work.
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Table 1: Average correlation values of Dharmavaram tank during 2011-2012
2017 November Edition |www.jbino.com | Innovative Association
J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
Table 2: Average correlation values of Dharmavaram tank during 2012-2013
2011-12Temp pH Cond Turb TDS TH DO BOD COD Free CO2Sali Alka Cl Ca Mg Si PO4 NO2 NO3 SO4
Temp 1
pH 0.211 1
Cond 0.136 0.096 1
Turb 0.048 -0.15 0.074 1
TDS -0.16 -0.06 0.082 0.085 1
TH -0.02 0.078 -0.04 0.034 -0.05 1
DO 0.069 -0.08 0.292 0.24 -0.12 0.077 1
BOD 0.07 0.091 -0.14 -0.13 0.047 0.119 -0.19 1
COD 0.206 0.133 0.224 0.155 0.102 -0.12 0.015 -0.1 1
Free CO2 -0.04 0.06 -0.05 0.129 0.068 0.053 0.08 -0.08 0.235 1
Sali -0.23 0.19 0.048 -0.08 0.105 0.128 0.254 0.205 0.037 0.271 1
Alka 0.039 -0.07 0.016 0.043 0.227 0.052 -0.04 -0.08 0.081 0.097 -0.09 1
Cl -0.01 -0.06 0.002 -0.18 0.077 0.24 -0.01 -0.27 -0.11 -0.06 -0.1 0.141 1
Ca -0.14 -0.06 0.017 -0 0.528 0.041 0.055 0.146 -0.12 0.1 0.054 0.093 -0.2 1
Mg 0.039 -0.01 -0.03 0.109 0.017 -0.2 0.091 -0.27 0.158 0.005 -0.11 0.002 0.022 -0.25 1
Si 0.238 0.154 0.007 -0.19 -0.13 -0.21 -0.13 0.024 -0.04 -0.16 -0.04 -0.06 -0.35 -0 0.059 1
PO4 0.122 0.175 0.146 -0.39 -0.07 0.099 -0.01 -0.11 0.166 -0.1 -0.1 -0.02 0.168 0.003 -0.02 0.095 1
NO2 -0.07 0.108 -0.1 -0.13 -0.03 -0.2 -0 -0.15 -0.06 0.123 0.009 -0.09 0.029 -0.34 0.078 -0.01 -0.07 1
NO3 0.061 -0.16 0.02 0.141 -0.06 0.087 0.269 -0.26 0.125 -0.12 0.112 0.074 0.142 0.004 0.068 -0.11 0.061 -0.09 1
SO4 0.132 0.125 0.021 0.002 -0.06 0.268 0.087 -0.12 -0.17 -0.27 -0.27 -0.11 0.27 -0.11 0.03 0.006 0.141 -0.02 -0.06 1
Table 5.5. Average Correlation values of Samples collected from Dharmavaram Tank during 2011-12
2012-13Temp pH Cond Turb TDS TH DO BOD COD Free CO2Sali Alka Cl Ca Mg Si PO4 NO2 NO3 SO4
Temp 1
pH -0.09 1
Cond 0.164 -0.02 1
Turb -0.05 -0.17 0.143 1
TDS 0.26 0.103 0.031 -0.05 1
TH 0.061 0.104 0.045 0.02 -0.07 1
DO -0.09 0.123 0.152 0.299 -0.03 -0.02 1
BOD -0.16 -0.06 -0.02 -0.02 -0.01 -0.05 0.026 1
COD 0.086 0.114 -0.02 -0.16 0.168 0.114 0.003 -0.07 1
Free CO2 -0.18 -0.05 0.002 0.05 -0.2 -0.12 -0.15 -0.17 -0.08 1
Sali -0.05 0.153 -0.04 -0.1 -0.28 -0.09 0.024 0.181 -0.07 0.268 1
Alka 0.137 -0.14 -0 0.311 -0.05 0.004 0.011 -0.1 0.119 -0.01 -0.09 1
Cl -0.06 0.025 -0.15 -0.14 -0.05 0.113 -0.19 0.053 -0.13 0.074 0.129 -0.06 1
Ca 0.05 0.308 0.024 -0.01 0.015 0.11 0.468 -0.19 0.16 -0.08 0.072 0.105 -0.1 1
Mg 0.006 0.193 -0.05 -0.06 0.309 -0.04 0.128 0.011 -0.03 -0.07 -0.04 -0.28 0.103 -0.02 1
Si -0.04 0.105 0.007 0.025 0.057 -0.13 -0.17 -0.03 -0.23 0.221 0.149 -0.03 0.101 -0.04 -0.13 1
PO4 -0.14 0.031 0.093 -0.1 0.003 -0.08 -0.26 0.149 0.05 -0.04 0.123 -0.65 0.183 0.23 -0.07 0.149 1
NO2 0.111 -0.32 0.163 -0.06 0.16 -0.02 -0.01 0.105 0.285 0.195 -0 0.025 0.232 -0.05 -0.13 0.11 0.136 1
NO3 -0.23 -0.04 -0.06 0.07 -0.41 0.232 0.117 0.019 0.154 -0.14 0.063 0.12 -0.01 0.405 -0.14 -0.12 0.061 -0.08 1
SO4 -0.25 -0 -0.04 -0.25 -0.02 -0.02 -0.04 0.162 0.068 0.206 -0.04 -0.18 -0.12 0.085 0.008 -0.05 0.064 -0.03 -0.08 1
Table 5.6. Average Correlation values of Samples collected from Dharmavaram Tank during 2012-13
2017 November Edition |www.jbino.com | Innovative Association
J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
2017 November Edition |www.jbino.com | Innovative Association
J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
2017 November Edition |www.jbino.com | Innovative Association
J.Bio.Innov6 (6), pp: 864-877, 2017 |ISSN 2277-8330 (Electronic)
Naik et al.,
Variation in Temperature (A), pH (B), Conductivity (C), Turbidity (D), TDS (E), TH (F), DO
(G), BOD (H), COD (I), Co2 (J), Salinity (K), Alkalinity (L), Chlorides (M), Calcium (N),
Magnesium (O), Silicates (P), Phosphates (Q), Nitrates (R), Nirites (S) and Sulphates (T) water
samples collected from Dharmavaram tank during 2011-2013.