issued on 05/31/2019 - rel. # 9 on 05/31/2019 # 1 / 18 in ... · wel united kingdom: 123/25 skin...

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 1 / 18

In conformity to Regulation (EU) 2015/830

SECTpON ne pnapmocoehmofp fc mea txitmhpeatsoumxea hpn fc mea efsnhpItapmaeneota

nene Pefnxem onapmocoae

Product name : ECOCLEANProduct code: refer to sales department

ne2e Ralavhpm onapmocoan xtat fc mea txitmhpea fe soumxea hpn xtat hnvotan hghoptm

Emulsifying solvent action cleanserSectors of use:Industrial Manufacturing[SU3], Public domain (administration, education, entertainment, services, craftsmen)[SU22]Product category:Washing and Cleaning Products (including solvent based products)Process categories: Use in closed, continuous process with occasional controlled exposure[PROC2], Transfer of substance or preparation(charging/discharging) from/to vessels/large containers at non-dedicated facilities[PROC8A], Transfer of substance orpreparation (charging/discharging) from/to vessels/large containers at dedicated facilities[PROC8B], Non industrialspraying[PROC11], Treatment of articles by dipping and pouring[PROC13], Application with rollers or brushes[PROC10] Not recommended usesDo not use for purposes other than those listed

ne3e Damholt fc mea txnnloae fc mea thcamI nhmh teaam

AEB SpA - Via Vittorio Arici 104 S.Polo - 25134 Brescia (BS) Italy Tel. +39.030.2307.1 Fax +39.030.2307281E-mail: [email protected] - Internet: www.aeb-group.comE-mail tecnico competente/technical dept.: [email protected]_______________________________________________________ AEB USA111 N Cluff AvenueLodi CA 95240 (USA)Tel: +1 2096258139 Fax: +1 2092248953 Email: [email protected] - Internet: www.aeb-group.com_______________________________________________________ AEB AFRICA (PTY) LTD18 Track Crescent, Cor. Station RoadMontague Gardens 7441 Cape Town (South Africa)Tel.: +27 215512700 - Fax: +27 (0) 215511919Email: [email protected] - Internet: www.aeb-group.com_______________________________________________________ AEB OCEANIA PTY LTD178A Wakaden StreetGriffith NSW 2680T: 1300 704 971Email: [email protected] - Internet: www.aeb-group.com Produced by

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 2 / 18


AEB SpAVia Vittorio Arici 104 S. Polo25134 Brescia

ne4e EsaegapeI malanefpa pxsiae

AEB SpACentralino/Switchboard: +39.030.2307.1 - (h 8.30-12.00 13.30-18.00 GMT +1; Lingua/Language: Italiano, English)______________________________________________________________________________________________ AEB BIOCHEMICAL USASwitchboard: +1 2096258139 (GMT -8; Language: English)______________________________________________________________________________________________ AEB AFRICA (PTY) LTDSwitchboard: +27 215512700 (GMT +1; Language: English, Afrikaans)______________________________________________________________________________________________ AEB OCEANIA PTY LTDSwitchboard: +61 1300 704 971 (GMT +9; Language: English)

SECTpON 2e Hhihent onapmocoehmofp

2ene Clhttocoehmofp fc mea txitmhpea fe soumxea

2.1.1 Classification according to Regulation (EC) No 1272/2008: Pictograms: GHS05 Hazard Class and Category Code(s): Met. Corr. 1, Skin Corr. 1, Eye Dam. 1 Hazard statement Code(s): H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage. H318 - Causes serious eye damage. The product can be corrosive to metals Corrosive product: causes severe skin burns and eye damage. If brought into contact with eyes, the product causes serious damages to eyes, such as an opaque cornea or injury toiris.

2e2e Lhial alasapmt

Labelling according to Regulation (EC) No 1272/2008: Pictogram, Signal Word Code(s): GHS05 - Danger Hazard statement Code(s): H290 - May be corrosive to metals. H314 - Causes severe skin burns and eye damage.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 3 / 18


Supplemental Hazard statement Code(s): EUH208 - Contains 1,2-benzisothiazol-3(2H)-one. May produce an allergic reaction. Precautionary statements:Prevention P260 - Do not breathe vapours/spray. P280 - Wear protective gloves/protective clothing/eye protection/face protection.Response P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water orshower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if presentand easy to do. Continue rinsing. Contains: Sodium metasilicate penthaydrate Contains (Reg.EC 648/2004): < 5% phosphates, EDTA and salts thereof, anionic surfactantsPreservatives: 1,2-benzisotiazol-3(2H)-one

2e3e Omeae ehihent

The substance / mixture does NOT contain substances PBT/vPvB according to Regulation (EC) No 1907/2006, AnnexXIII The use of this chemical agent involves the obligation of "risk assessment" by the employer in accordance with theprovisions of Dlgs n. 81. April 9, 2008. Workers exposed to this chemical agent should not be subject to healthsurveillance if the results of the risk assessment show that, depending on the type and quantity of dangerous chemicalagent and method and frequency of exposure to the agent, there is only a "moderate Risk" for the health and safety ofworkers and that the measures laid down in the Decree are sufficient to reduce the risk. For professional use only

SECTpON 3e Cfsnftomofptopcfeshmofp fp opgeanoapmt

3en Sxitmhpeat

Irrilevant

3e2 Moumxeat

Refer to paragraph 16 for full text of hazard statements

Sxitmhpea Cfpeapmehmofp Clhttocoehmofp ppnau CAS EpNECS REACe

2-Butoxyethanol >=3 < 6% 603-014-00-0 111-76-2 203-905-0

01-2119475

108-36-XXX

X

Acute Tox. 4, H302;

Acute Tox. 4, H312;

Skin Irrit. 2, H315;

Eye Irrit. 2, H319;

Acute Tox. 4, H332

Sodium metasilicate penthaydrate 2,5 ≤ x < 4,5 10213-79-3 229-912-9

01-2119449

811-37-XXX

X

Met. Corr. 1, H290;

Skin Corr. 1B, H314;

Eye Dam. 1, H318;

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 4 / 18


Sxitmhpea Cfpeapmehmofp Clhttocoehmofp ppnau CAS EpNECS REACe

STOT SE 3, H335

Tetrapotassium pyrophosphate 1,5 ≤ x < 3,5 7320-34-5 230-785-7

01-2119489

369-18-XXX

X

Eye Irrit. 2, H319

Tetrasodium ethylene diamine

tetraacetate0,5 ≤ x < 1,5 64-02-8 200-573-9

01-2119486

762-27-XXX

X

Acute Tox. 4, H302;

Eye Dam. 1, H318;

Acute Tox. 4, H332;

STOT RE 2, H373

1,2-benzisothiazol-3(2H)-one 0 ≤ x < 0,05 613-088-00-6 2634-33-5 220-120-9

Acute Tox. 4, H302;

Skin Irrit. 2, H315;

Skin Sens. 1, H317;

Eye Dam. 1, H318;

Aquatic Acute 1,

H400

SECTpON 4e Foetm hon sahtxeat

4ene Dateeonmofp fc coetm hon sahtxeat

EYES: Remove any contact lenses. Wash immediately with plenty of water for at least 30/60 minutes, opening theeyelids well. Consult a doctor immediately. SKIN: Remove contaminated clothing. Take a shower immediately. Consulta doctor immediately. INGESTION: Give water to drink as much as possible. Consult a doctor immediately. Do notinduce vomiting unless expressly authorized by your doctor. INHALATION: Call a doctor immediately. Bring the subjectto fresh air, away from the accident site. If breathing stops, give artificial respiration. Take appropriate precautions forthe rescuer.

4e2e Mftm osnfemhpm tIsnmfst hpn accaemt, ifme hexma hpn nalhIan

No specific information on symptoms and effects caused by the product is known.

4e3e ppnoehmofp fc hpI ossanohma sanoehl hmmapmofp hpn tnaeohl meahmsapm paanan

Information not available

SECTpON e Foeacogemopg sahtxeat

ene Eumopgxoteopg sanoh

SUITABLE EXTINGUISHING MEDIA The extinguishing media are the traditional ones: carbon dioxide, foam, dust andwater spray. MEANS OF EXTINCTION NOT SUITABLE None in particular.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 5 / 18


e2e Snaeohl ehihent heotopg cefs mea txitmhpea fe soumxea

HAZARDS DUE TO EXPOSURE IN THE EVENT OF FIRE Avoid breathing combustion products.

e3e Anvoea cfe coeacogemaet

GENERAL INFORMATION Use jets of water to cool the containers to prevent product decomposition and thedevelopment of substances potentially hazardous for health. Always wear full fire protection equipment. Collectextinguishing water which must not be discharged into drains. Dispose of contaminated water used for extinction andthe remains of the fire according to the regulations in force. EQUIPMENT Normal fire fighting clothing, such as an opencircuit compressed air breathing apparatus (EN 137), flame retardant (EN469), flame retardant gloves (EN 659) andfirefighter boots (HO A29 or A30).

SECTpON e Aeeonapmhl ealahta sahtxeat

ene Paetfphl neaehxmofpt, nefmaemova aqxonsapm hpn asaegapeI nefeanxeat

6.1.1 For non-emergency personnel:Stop the leak if there is no danger. Wear appropriate protective equipment (including personal protective equipmentreferred to in section 8 of the safety data sheet) to prevent contamination of the skin, eyes and personal clothing. Theseindications are valid both for workers involved in the work and for emergency interventions. 6.1.2 For emergency responders:Eliminate all open flames and possible sources of ignition. Not smoking. Provide adequate ventilation. Evacuate thedanger area and, if necessary, consult an expert.

e2e Epvoefpsapmhl neaehxmofpt

Contain spills with earth or sand. If the product has entered a watercourse, sewers or has contaminated soil or vegetation, notify the authorities. Dispose of the waste material in compliance with the regulations

e3e Mamefnt hpn shmaeohl cfe efpmhopsapm hpn elahpopg xn

6.3.1 Containment: Rapidly recover the product, wear a mask and protective clothing Recover the product for reuse, if possible, or for removal. Possibly absorb it with inert materia or sucked it. Prevent it from entering the sewer system. 6.3.2 Cleaning up: After wiping up, wash with water the area and materials involved 6.3.3 Other information: Vacuum the leaked product into a suitable container. Evaluate the compatibility of the container to be used with theproduct, checking section 10. Absorb the remainder with inert absorbent material. Ensure adequate ventilation of thearea affected by the loss. The disposal of contaminated material must be carried out in accordance with the provisionsof point 13.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 6 / 18


e4e Racaeapea mf fmeae taemofpt

Refer to paragraphs 8 and 13 for more information

SECTpON de Hhpnlopg hpn tmfehga

dene Peaehxmofpt cfe thca ehpnlopg

Avoid contact and inhalation of vapors Wear protective gloves/protective clothing/eye protection/face protection. In residential areas do not use on large surfaces. At work do not eat or drink. See also paragraph 8 below.

de2e Cfpnomofpt cfe thca tmfehga, opelxnopg hpI opefsnhmoiolomoat

Keep in original container closed tightly. Do not store in open or unlabelled containers. Keep containers upright and safe by avoiding the possibility of falls or collisions. Store in a cool and dry place, away from heat sources and direct exposure to sunlight.

de3e Snaeocoe apn xta(t)

Industrial Manufacturing:Handle with extreme caution.Store in a well ventilated place away from heat sources. (7-30°C) Public domain (administration, education, entertainment, services, craftsmen):Handle with care. Store in a ventilated area and away from heat, keep the container tightly closed. (7-30°C) See the annex exposure scenario.

SECTpON re Eunftxea efpmeflttnaetfphl nefmaemofp

rene Cfpmefl nhehsamaet

===================== Related to contained substances:2-Butoxyethanol:Limit value - Eight hours (mg/m³)/(ppm) AGW Deutschland: 49/10 skinMAK Deutschland: 49/10 skinVLA Espana: 98/20 skinVLEP France: 49/10 skinWEL United Kingdom: 123/25 skinTLV Greece: 120/25AK Magyarország: 98/xVLEP Italia: 98/20 skinRD Lietuva: 50/10 skinTLV România: 150/30 skinMV Slovenija: 98/20 skinOEL EU: 98/20 skinTLV-ACGIH: 97/20

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 7 / 18


Limit value - Short term(mg/m³)/(ppm) AGW Deutschland: 196/40 skinMAK Deutschland: 98/20 skinVLA Espana: 245/50 skinVLEP France: 246/50 skinWEL United Kingdom: 246/50 skinTLV Greece: x/xAK Magyarország: 246/xVLEP Italia: 246/50 skinRD Lietuva: 100/20 skinTLV România: 250/50 skinMV Slovenija: 245/50 skinOEL EU: 246/50 skinTLV-ACGIH: x/x Tetrapotassium pyrophosphate:Limit value - Eight hours (mg / m³) / (ppm) AGW Deutschland: 10 / x inhalable fraction AGW Deutschland: 3 / x breathable fraction Limit value - Short term (mg / m³) / (ppm) AGW Deutschland: x / x AGW Deutschland: x / x - Substance: 2-ButoxyethanolDNELSystemic effects Long term Workers inhalation = 98 (mg/m3)Systemic effects Long term Workers dermal = 125 (mg/kg bw/day)Systemic effects Long term Consumers inhalation = 59 (mg/m3)Systemic effects Long term Consumers dermal = 75 (mg/kg bw/day)Systemic effects Long term Consumers oral = 6,3 (mg/kg bw/day)Systemic effects Short term Workers inhalation = 1091 (mg/m3)Systemic effects Short term Workers dermal = 89 (mg/kg bw/day)Systemic effects Short term Consumers inhalation = 49 (mg/m3)Systemic effects Short term Consumers dermal = 89 (mg/kg bw/day)Systemic effects Short term Consumers oral = 26,7 (mg/kg bw/day)Local effects Short term Workers inhalation = 246 (mg/m3)Local effects Short term Consumers inhalation = 426 (mg/m3)PNECSweet water = 8,8 (mg/l)sediment Sweet water = 34,6 (mg/kg/sediment)Sea water = 0,88 (mg/l)sediment Sea water = 3,46 (mg/kg/sediment)intermittent emissions = 9,1 (mg/l)STP = 463 (mg/l)ground = 3,13 (mg/kg ground) - Substance: Sodium metasilicate penthaydrateDNELSystemic effects Long term Workers inhalation = 6,22 (mg/m3)Systemic effects Long term Workers dermal = 1,49 (mg/kg bw/day)

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 8 / 18


Systemic effects Long term Consumers inhalation = 1,55 (mg/m3)Systemic effects Long term Consumers dermal = 0,74 (mg/kg bw/day)Systemic effects Long term Consumers oral = 0,74 (mg/kg bw/day)PNECSweet water = 7,5 (mg/l)Sea water = 1 (mg/l)STP = 7,5 (mg/l)ground = 1000 (mg/kg ground) - Substance: Tetrapotassium pyrophosphateDNELSystemic effects Long term Workers inhalation = 17,63 (mg/m3)Systemic effects Long term Consumers inhalation = 4,35 (mg/m3)Local effects Long term Workers inhalation = 2,79PNECSweet water = 0,05 (mg/l)Sea water = 0,005 (mg/l)intermittent emissions = 0,5 (mg/l)STP = 50 (mg/l) - Substance: Tetrasodium ethylene diamine tetraacetateDNELSystemic effects Long term Workers inhalation = 1,5 (mg/m3)PNECSweet water = 2,86 (mg/l)Sea water = 0,286 (mg/l)intermittent emissions = 1,56 (mg/l)STP = 55,94 (mg/l)ground = 0,937 (mg/kg ground)

re2e Eunftxea efpmeflt

Appropriate engineering controls:Industrial Manufacturing:No specific monitoring foreseen (act according to good practice and specific rules for the type of risk associated) Public domain (administration, education, entertainment, services, craftsmen):No specific monitoring foreseen (act according to good practice and specific rules for the type of risk associated) 8.2.2 Individual protection measures: (a) Eye / face protection When handling the pure product use safety glasses (EN 166). (b) Skin protection (i) Hand protection When handling the pure product use chemical resistant protective gloves (EN 374-1/EN374-2/EN374-3) or otherprotective equipment, according to the instructions of the employer (ii) Other When handling the pure product, wear full protective clothing (generic workwear / antacid, safety shoes S3-EN ISO

SAFETY DATA SHEET

ECOCLEAN

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20345) or other protective equipment, according to the instructions of the employer (c) Respiratory protection Not needed for normal use.During manual operations in case of insufficient ventilation, use respiratory mask with organic vapour filter - 3, A ( EN405 ) unless otherwise provided by the employer and / or assessments of environmental investigations hygienistic (d) Thermal hazards No hazard to report Environmental exposure controls: Use according to good working practices and avoid to disperse the product into the environment.

SECTpON re PeItoehl hpn eeasoehl nefnaemoat

rene ppcfeshmofp fp ihtoe neItoehl hpn eeasoehl nefnaemoat

Vhlxa Damaesophmofp samefnPeItoehl hpn eeasoehl nefnaemoat

Appearance Fluorescent yellow fluorescent liquid

Odour Not determined because it is considered not relevant for

characterization of the product

Odour threshold Not determined because it is considered not relevant for


pH 13,5 ± 0,5 (20 ° C)

Melting point/freezing point Not determined because it is considered not relevant for


Initial boiling point and boiling range Not determined because it is considered not relevant for


Flash point Not determined because it is considered not relevant for


Evaporation rate Not determined because it is considered not relevant for


Flammability (solid, gas) Not determined because it is considered not relevant for


Upper/lower flammability or explosive limits Not determined because it is considered not relevant for


Vapour pressure Not determined because it is considered not relevant for


Vapour density Not determined because it is considered not relevant for


Relative density 1,05 ± 0,05 (20 ° C)

Solubility in water

Water solubility miscible in all proportions

Partition coefficient: n-octanol/water Not determined because it is considered not relevant for


Auto-ignition temperature Not determined because it is considered not relevant for


Decomposition temperature Not determined because it is considered not relevant for


Viscosity Not determined because it is considered not relevant for


Explosive properties Not determined because it is considered not relevant for


SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 10 / 18


Vhlxa Damaesophmofp samefnPeItoehl hpn eeasoehl nefnaemoat

Oxidising properties Not determined because it is considered not relevant for


re2e Omeae opcfeshmofp

No data available.

SECTpON nre SmhiolomI hpn eahemovomI

nrene RahemovomI

There are no particular risks of reaction with other substances in normal conditions of use. 2-BUTOXYETHANOL Decomposes due to heat. PENTAHYDRATE SODIUM METASILICATE Aqueous solutions behave as: strong bases.Corrode: aluminum, zinc, tin,aluminum alloys, zinc alloys, tin alloys.

nre2e Ceasoehl tmhiolomI

The product is stable in normal conditions of use and storage.

nre3e PfttoiolomI fc ehihenfxt eahemofpt

In normal use and storage conditions dangerous reactions are not predictable. 2-BUTOXYETHANOL Can react dangerously with: aluminum, oxidizing agents.Peroxide form with: air. PENTAHYDRATE SODIUM METASILICATE Reacts violently with: acids.

nre4e Cfpnomofpt mf hvfon

Avoid overheating.

nre e ppefsnhmoila shmaeohlt

Strong reducing agents and oxidants, strong bases and acids, high temperature materials.

nre e Hhihenfxt naefsnftomofp nefnxemt

2-BUTOXYETHANOL Can develop: hydrogen.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 11 / 18


SECTpON nne Tfuoeflfgoehl opcfeshmofp

nnene ppcfeshmofp fp mfuoeflfgoehl accaemt

ATE(mix) oral = 9.587,2 mg/kg ATE(mix) dermal = 6.864,4 mg/kg ATE(mix) inhal = 35,5 mg/l/4 h (a) acute toxicity: 2-Butoxyethanol: Ingestion - LD50 rat (mg / kg / 24h bw): 615 Skin contact - LC50 rat / rabbit (mg / kg / 24h bw): 405 Inhalation - LD50 rat (mg / L / 4h): 2.2 Sodium metasilicate penthaydrate: Ingestion: Oral LD50 (rat): 1349 mg / Kg Inhalation: LC50 (rat)> 2.06 g / m3Skin: LD50 (rat)> 5000 mg / kg bw. Tetrapotassium pyrophosphate: Ingestion-rat LD50 (mg/kg/bw 24h): > 2000 Skin contact-LC50 rat/coniglio (mg/kg/bw 24h): >2000Inhalation-rat LD50 (mg/l/4h): >1,1 Tetrasodium ethylene diamine tetraacetate: Ingestion - LD50 rat (mg / kg / 24h bw): 1780 Skin contact - LC50 rat / rabbit (mg / kg / 24h bw):> 5000Inhalation - LD50 rat (mg / l / 4h): nd 1,2-benzisothiazol-3(2H)-one: Ingestion - LD50 rat (mg / kg / 24h bw): 1193 Skin contact - LC50 rat / rabbit (mg / kg / 24h bw): 4115 (b) skin corrosion/irritationCorrosive product: causes severe skin burns and eye damage. 2-Butoxyethanol: Not corrosive Sodium metasilicate penthaydrate: Corrosive Tetrapotassium pyrophosphate: Non-corrosive Tetrasodium ethylene diamine tetraacetate: Non-corrosive 1,2-benzisothiazol-3(2H)-one: Corrosive 2-Butoxyethanol: Irritating Sodium metasilicate penthaydrate: Irritating Tetrapotassium pyrophosphate: Non-irritating Tetrasodium ethylene diamine tetraacetate: Not irritating 1,2-benzisothiazol-3(2H)-one: Irritating (c) serious eye damage/irritation: Corrosive product: causes severe skin burns and eye damage. - If brought intocontact with eyes, the product causes serious damages to eyes, such as an opaque cornea or injury to iris. 2-Butoxyethanol: Not corrosive Sodium metasilicate penthaydrate: Corrosive Tetrapotassium pyrophosphate: Non-corrosive Tetrasodium ethylene diamine tetraacetate: Corrosive 1,2-benzisothiazol-3(2H)-one: Corrosive 2-Butoxyethanol: Irritating Sodium metasilicate penthaydrate: Irritating Tetrapotassium pyrophosphate: Irritating Tetrasodium ethylene diamine tetraacetate: Irritating 1,2-benzisothiazol-3(2H)-one: Irritating (d) respiratory or skin sensitization: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Non-sensitizing Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: May cause an allergic reaction. (e) germ cell mutagenicity: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Non-mutagenic

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 12 / 18


Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available (f) carcinogenicity: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Non-carcinogenic Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available (g) reproductive toxicity: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Non-toxic for reproduction Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available (h) specific target organ toxicity (STOT) single exposure: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Not available Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available (i) specific target organ toxicity (STOT) repeated exposure2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Not available Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available (j) aspiration hazard: 2-Butoxyethanol: Not available Sodium metasilicate penthaydrate: Not available Tetrapotassium pyrophosphate: Not available Tetrasodium ethylene diamine tetraacetate: Not available 1,2-benzisothiazol-3(2H)-one: Not available ===================== Related to contained substances:2-Butoxyethanol: LD50 (rat) Oral (mg/kg body weight) = 615LD50 Dermal (rat or rabbit) (mg/kg body weight) = 405CL50 Inhalation (rat) vapour/dust/mist/fume (mg/l/4h) or gas (ppmV/4h) = 2,2 Tetrasodium ethylene diamine tetraacetate: LD50 (rat) Oral (mg/kg body weight) = 1780 1,2-benzisothiazol-3(2H)-one: LD50 (rat) Oral (mg/kg body weight) = 1193LD50 Dermal (rat or rabbit) (mg/kg body weight) = 4115

SECTpON n2e Eeflfgoehl opcfeshmofp

n2ene TfuoeomI

===================== Related to contained substances:2-Butoxyethanol:Acute toxicity - fish LC50 (mg / l / 96h): nd Acute toxicity - crustaceans EC50 (mg / l / 48h): nd Acute algae toxicity ErC50 (mg / l / 72-96h): nd Chronic toxicity - NOEC fish (mg / l): nd Chronic toxicity - crustaceans NOEC (mg / l): nd Chronic toxicity NOEC algae (mg / l): nd Sodium metasilicate penthaydrate:

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 13 / 18


Acute toxicity - fish LC50 (mg / l / 96h): 1108 Brachydanio rerio Acute toxicity - shellfish EC50 (mg / l / 48h): 1700 Daphnia magna (by analogy) Acute toxicity algae ErC50 (mg / l / 72-96h): 207 Scenedesmus subspicatus Chronic toxicity - NOEC fish (mg / l): nd Chronic toxicity - crustacean NOEC (mg / l): nd Chronic algae toxicity NOEC (mg / l): nd Tetrapotassium pyrophosphate:Acute toxicity - fish LC50 (mg / l / 96h):> 100 Oncorynchus Mykiss Acute toxicity - crustaceans EC50 (mg / l / 48h):> 100 Daphnia magna Acute toxicity alg ErC50 (mg / l / 72-96h):> 100 Chronic toxicity - NOEC fish (mg / l):> 100 Chronic toxicity - crustaceans NOEC (mg / l): nd Chronic algae toxicity NOEC (mg / l): nd Tetrasodium ethylene diamine tetraacetate:Acute toxicity - fish LC50 (mg / l / 96h):> 100 Acute toxicity - crustaceans EC50 (mg / l / 48h): 140 Daphnia magna Acute toxicity ErC50 algae (mg / l / 72-96h):> 100 Chronic toxicity - NOEC fish (mg / l):> 25.7 Danio rerio Chronic toxicity - crustaceans NOEC (mg / l): 25 Daphnia magnaC(E)L50 (mg/l) = 100 NOEC (mg/l) = 25 1,2-benzisothiazol-3(2H)-one:Acute toxicity - fish LC50 (mg / l / 96h): 2.15 Oncorhynchus mykiss Acute toxicity - shellfish EC50 (mg / l / 48h): 2.9 Daphnia magna Acute toxicity algae ErC50 (mg / l / 72-96h): 0.084 Chronic toxicity - NOEC fish (mg / l): nd Chronic toxicity - crustaceans NOEC (mg / l): nd Chronic toxicity algae NOEC (mg / l): ndC(E)L50 (mg/l) = 2,15 Use according to good working practices and avoid to disperse the product into the environment.

n2e2e Paetotmapea hpn nagehnhiolomI

===================== Related to contained substances:2-Butoxyethanol:Solubility in water: 1000 - 10000mg / L Rapidly degradable Sodium metasilicate penthaydrate:Information not available Tetrapotassium pyrophosphate:Not biodegradable Tetrasodium ethylene diamine tetraacetate:NOT rapidly degradable 1,2-benzisothiazol-3(2H)-one:Degradability: no data available

n2e3e Bofheexsxlhmova nfmapmohl

===================== Related to contained substances:2-Butoxyethanol:

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 14 / 18


Partition coefficient: n-octanol / water 0.81 Sodium metasilicate penthaydrate:Information not available Tetrapotassium pyrophosphate:BFC 1.8 Kg / L Tetrasodium ethylene diamine tetraacetate:Information not available 1,2-benzisothiazol-3(2H)-one:Information not available

n2e4e MfiolomI op tfol

===================== Related to contained substances:2-Butoxyethanol:Information not available Sodium metasilicate penthaydrate:Information not available Tetrapotassium pyrophosphate:Information not available Tetrasodium ethylene diamine tetraacetate:Information not available 1,2-benzisothiazol-3(2H)-one:Information not available

n2e e Ratxlmt fc PBT hpn vPvB httattsapm

The substance / mixture does NOT contain substances PBT/vPvB according to Regulation (EC) No 1907/2006, AnnexXIII

n2e e Omeae hnvaeta accaemt

No adverse effects Regulation (EC) No 2006/907 - 2004/648 The (I) surfactant (s) content (s) in this preparation complies (comply) with (i) the biodegradability criteria as laid downin Regulation CE/648/2004 on detergents. All data are held at the disposal of the competent authorities of MemberStates and will be provided, at their direct request or at the request of a detergent manufacturer, to those authorities.

SECTpON n3e Dotnfthl efptonaehmofpt

n3ene Whtma meahmsapm samefnt

Reuse, if possible. Product residues are to be considered special hazardous waste. The dangerousness of the wastethat partly contains this product must be assessed according to the laws in force. Disposal must be entrusted to anauthorized waste management company, in compliance with national and local regulations. Waste transportation maybe subject to ADR. CONTAMINATED PACKAGING Contaminated packaging must be sent for recovery or disposal incompliance with national waste management regulations.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 15 / 18


SECTpON n4e Tehptnfem opcfeshmofp

n4ene UN pxsiae

ADR/RID/IMDG/ICAO-IATA: 3266 If subject to the following characteristics is ADR exempt: Combination packagings: per inner packaging 1 L per package 30 KgInner packaging placed in skrink-wrapped or stretch-wrapped trays: per inner packaging 1 L per package 20 Kg

n4e2e UN nefnae teonnopg phsa

ADR/RID/IMDG: LIQUIDO INORGANICO CORROSIVO, BASICO, N.A.S.ADR/RID/IMDG: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.ICAO-IATA: CORROSIVE LIQUID, BASIC, INORGANIC, N.O.S.

n4e3e Tehptnfem ehihen elhtt(at)

ADR/RID/IMDG/ICAO-IATA: Class : 8ADR/RID/IMDG/ICAO-IATA: Label : 8ADR: Tunnel restriction code : EADR/RID/IMDG/ICAO-IATA: Limited quantities : 1 LIMDG - EmS : F-A, S-B

n4e4e Phekopg gefxn

ADR/RID/IMDG/ICAO-IATA: II

n4e e Epvoefpsapmhl ehihent

ADR/RID/ICAO-IATA: Product is not environmentally hazardousIMDG: Marine polluting agent : No

n4e e Snaeohl neaehxmofpt cfe xtae

The transport must be carried out by authorized vehicles for the transport of dangerous goods in accordance with therequirements of the applicable Edition of the agreement A.D.R. and national provisions. The transport must be carriedout in the original packaging and in packages that are made from materials resistant to content and not likely togenerate with this dangerous reactions. The process of loading and unloading of dangerous goods have receivedadequate training on the risks presented by prepared and on possible procedures to be taken in the event of emergencysituations

n4ede Tehptnfem op ixlk heefenopg mf Appau pp fc MARPOLd3tdr hpn pBC Cfna

Transport in bulk is not foreseen

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 16 / 18


SECTpON n e RagxlhmfeI opcfeshmofp

n ene ShcamI, eahlme hpn apvoefpsapmhl eagxlhmofpttlagotlhmofp tnaeocoe cfe mea txitmhpea fe soumxea

===================== Related to contained substances:Tetrapotassium pyrophosphate:D. Lgs. n. 2/3/1997 52 (classification, packaging and labelling of dangerous substances). Legislative Decree No.3/14/2003 65 (classification, packaging and labelling of dangerous preparations). Legislative Decree No. 25 2/2/2002(risks related to chemical agents at work). D.M. 2/26/2004 Work (occupational exposure limits); D.M. 4/3/2007(implementation of Directive No. 2006/8/EC). Regulation (EC) No 1907/2006 (REACH), Regulation (EC) no 1272/2008(CLP), Regulation (EC) no 790/2009. Legislative Decree No. 238 September 21, 2005 (Seveso Ter). Restrictions relating to the product or contained substances (All. XVII Reg. EC 1907/2006): not applicableSubstances in Candidate List (art. 59 Reg. EC 1907/2006): the product does not contain SVHCSubstances subject to authorisation (Ann. XIV Reg. CEC 1907/2006): the product does not contain SVHCReg. EC 648/04: see 2.2Reg. (EU) n. 1169/2011: see 2.2 REGULATION (EU) No 1357/2014 - waste:HP8 - Corrosive

n e2e Ceasoehl thcamI httattsapm

No chemical safety assessment was carried out by the supplier

SECTpON n e Omeae opcfeshmofp

n ene Omeae opcfeshmofp

Points modified compared to previous release: 2.1. Classification of the substance or mixture, 2.2. Label elements Description of hazard statements set out in paragraph 3 H302 = Harmful if swallowed. H312 = Harmful in contact with skin. H315 = Causes skin irritation. H319 = Causes serious eye irritation. H332 = Harmful if inhaled. H290 = May be corrosive to metals. H314 = Causes severe skin burns and eye damage. H318 = Causes serious eye damage. H335 = May cause respiratory irritation. H373 = May cause damage to organs through prolonged or repeated exposure . H317 = May cause an allergic skin reaction. H400 = Very toxic to aquatic life. Classification based on data of all mixture components Main normative references: Reg. (CE) n. 1907 del 18/12/06 REACH (Registration, Evaluation and Authorisation of CHemicals) et seq.

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 17 / 18


Reg. (CE) 1272/2008 CLP (Classification Labelling and Packaging) et seq.Regulation (EC) n. 648 of 31/03/04 (on detergents) et seq.Regulation (UE) n. 1169/2011 (on the provision of food information to consumers)Directive 2012/18/EU (on the control of major-accident hazards involving dangerous substances) et seq. Procedure used to classify under CLP mixture (Reg . EC 1272/2008): bridging principle Training required: This document must be submitted to the employer to determine the possible need for appropriatetraining for workers to ensure protection of human health and the environment. n.a.: not applicablen.d.: not availableADR: Accord europèen relative au transport International des merchandises dangereuses par route (EuropeanAgreement concerning the International Carriage of Dangerous Goods by Road)ATE: Acute Toxicity EstimatBFC: BioconCentration FactorBOD: Biochemical Oxigen DemandCAS: Chemical Abstract Service numberCAP: Centre AntiPoisonCE/EC number EINECS (European Inventory of existing Commercial Substances) e ELINCS (European List of notifiedChemical Substances)CL50/LC50: Lethal Concentration 50DL50/LD50: Lethal Dose 50COD: Chemical Oxygen DemandDNEL: Derived No Effect LevelEC50: half maximal Effective ConcentrationERC: Enviroment Release ClassesEU/UE: European UnionIATA: International Air Transport AssociationICAO: International Civil Aviation OrganizationIMDG: International Maritime Dangerous Goods codeKow: Octanol water partition coefficientNOEC: No Observed Effect ConcentrationOEL: Occupational Exposure LimitPBT: Persistent Bioaccumulative and ToxicPC: Product CategoriesPNEC: Predicted No Effect ConcentrationPROC: Process CategoriesRID: Règlement concernent le transport International ferroviaire des merchandises dangereuses (Regulationsconcerning International rail transport of dangerous goods)STOT: Target Organ Systemic ToxicitySTOT (RE): Repeated ExposureSTOT (SE): Single ExposureSTP: Sewage Treatment PlantsSU: Sector of UseSVCH: Substance of Very High ConcernTLV: Threshold Limit ValuevPvB: Very Persistent Very Bioaccumulative References and Sources:• ECHA Registered Substances:• https://echa.europa.eu/web/guest/information-on-chemicals/registered-substances• SDS supplier• GESTIS DNEL Database: http://www.dguv.de/ifa/gestis/gestis-dnel-datenbank/index-2.jsp• GESTIS International Limit Value: http://limitvalue.ifa.dguv.de

SAFETY DATA SHEET

ECOCLEAN

Issued on 05/31/2019 - Rel. # 9 on 05/31/2019 # 18 / 18


This msds was made in good faith by AEB technical Office on the basis of the information available at the date of thelast revision. The person in charge must regularly inform the employees about the specific risks they encounter whenusing this substance/product. The information contained here relate only to the substance/the preparation indicated andmay not apply if the product is used improperly or in combination with others. Nothing contained herein shall beconstrued as a guarantee, either express or implied. It is the responsibility of the user to ensure the opportunities andcompleteness of the information contained herein for their own particular use. *** this tab annuls and replaces any previous edition. (IIXX) Changes to the previous edition: labelling variation

Rel.#9 on 05/31/19 ECOCLEAN

AISE GEIS.2.1.a.v1 Version: 1.0, May 2014

Using a professional product in a semi closed system

Operational conditions

Maximum duration 480 minutes per day.

Process conditions Process is carried out at room temperature.

No LEV needed; good general ventilation at

workplace is sufficient.

Risk management measures

Conditions and measures related to

personal protection equipment

(PPE), hygiene and health evaluation

No PPE necessary.

Good practise advice

Don’t eat or drink, don’t smoke, no

open flame

Wash hands after use

Avoid contact with damaged skin

Do not mix with other products

Spillage instructions Dilute with water and mop up.

Additional good practice advice Follow the product instructions as specified on the

label or in the product information sheet and use

good occupational hygiene practices as specified in

Section 7 of the SDS of the used product.

Enviromental measures

Prevent that the undiluted product reaches surface waters.


Properties of product composition

In Section 2 of the SDS of products and on the label the classification of the undiluted

product is provided.

The classification of a product is based on the classified ingredients in the products. All

ingredients contributing to the classification of the mixture are mentioned in Section 3 of the

SDS.

Relevant limit values of the ingredients on which the exposure assessment is based, are

stated in Section 8 of the SDS.

This product may contain sensitizing ingredients, that may cause an allegric reaction in

certain people. Section 2 of the SDS states these ingredients, when applicable to the

product.

Use descriptors

SU 22 Professional use

PC 35 Washing and cleaning product

PROC 2 Use in closed, continuous process with occasional controlled exposure

ERC 8a Wide dispersive indoor use of processing aids in open systems

If appropriate AISE SpERC 8a.1.a.v2 may apply: Wide dispersive use in

"Down the drain" cleaning and maintenance products that are treated by a

municipal STP.

Disclaimer: This is a generic document for communicating conditions of safe use of a product. If a GEIS code is

mentioned in Section 1 of the SDS of a product, the formulator of that product declares that all substances in the

mixture are present in such concentration, that the use of the product within the conditions of the GEIS CSP

documents is safe, according to the GEIS Formulator Guidance. When available, this safe use is ensured by

evaluating the results of the chemical safety assessments as performed by the raw material suppliers. When no

chemical safety assessment has been carried out by the supplier for an ingredient that contributes to the

classification of the mixture, the formulator has performed a safety assessment himself.

Following Occupational Health legislation, the employer of workers that use products that are assessed as safe

following GEIS conditions remains responsible for communicating relevant use information to employees. When

developing workplace instructions for employees, Generic Exposure Information Sheets should always be

considered in combination with the SDS and the label of the product. The GEIS Guidance for End Users provides

more information.

The A.I.S.E. or the NVZ are under no conditions liable for any damage, no matter of what kind, which is the direct

or indirect consequence of acts and/or decisions (partly) based on the contents of this document.


AEB ES.2.1.a.v1 Version: 1.0, May 2014

Using a professional product in a semi closed system










No PPE necessary.



open flame

















SDS.





product.

Use descriptors

SU 3 Industrial uses


PROC 2 Use in closed, continuous process with occasional controlled exposure




municipal STP.

Disclaimer: This is a generic document for communicating conditions of safe use of a product the employer of

workers that use products that are assessed as safe remains responsible for communicating relevant use

information to employees. When developing workplace instructions for employees, Information Sheets should

always be considered in combination with the SDS and the label of the product.


AISE GEIS.8a.1.a.v1 Version: 1.0, May 2014

Transfer of professional product to a container (bottle/bucket/machine)




In case of dilution, tap water at a maximum

temperature of 45 degrees Celcius is used.







Use gloves and safety goggles. See Section 8 of the

SDS of this product for specifications.

Training of the worker in relation to proper use and

maintenance of the PPE must be ensured.



open flame

















SDS.





product.

Use descriptors



PROC 8a Transfer of substance or preparation (charging/discharging) from/to

vessels/large containers at non-dedicated facilities




municipal STP.




documents is safe, according to the GEIS Formulator Guidane. When available, this safe use is ensured by








more information.




AEB ES.8a.1.a.v1 Version: 1.0, May 2014

Transfer of professional product to a container (bottle/bucket/machine)


















open flame

















SDS.





product.

Use descriptors



PROC 8a Transfer of substance or preparation (charging/discharging) from/to

vessels/large containers at non-dedicated facilities




municipal STP.




always be considered in combination with the SDS and the label of the product..


AISE GEIS.8b.1.a.v1 Version: 1.0, May 2014

Transfer of professional product via a dedicated system (bottle/machine)










No PPE necessary.



open flame

















SDS.





product.

Use descriptors



PROC 8b Transfer of substance or preparation (charging/discharging) from/to

vessels/large containers at dedicated facilities




municipal STP.




documents is safe, according to the GEIS Formulator Guidance.. When available, this safe use is ensured by








more information.




AEB ES.8b.1.a.v1 Version: 1.0, May 2014

Transfer of professional product via a dedicated system (bottle/machine)










No PPE necessary.



open flame

















SDS.





product.

Use descriptors



PROC 8b Transfer of substance or preparation (charging/discharging) from/to

vessels/large containers at dedicated facilities




municipal STP.




always be considered in combination with the SDS and the label of the product..


AISE GEIS.10.1.b.v1 Version: 1.0, May 2014

Brushing a concentrated professional product


















open flame









Environmental measures








SDS.





product.

Use descriptors



PROC 10 Roller application or brushing




municipal STP.

Disclaimer: This is a generic document for communicating conditions of safe use of a product. If a GEIS

code is mentioned in Section 1 of the SDS of a product, the formulator of that product declares that all

substances in the mixture are present in such concentration, that the use of the product within the

conditions of the GEIS CSP documents is safe, according to the GEIS Formulator Guidance. When

available, this safe use is ensured by evaluating the results of the chemical safety assessments as

performed by the raw material suppliers. When no chemical safety assessment has been carried out by

the supplier for an ingredient that contributes to the classification of the mixture, the formulator has

performed a safety assessment himself.

Following Occupational Health legislation, the employer of workers that use products that are

assessed as safe following GEIS conditions remains responsible for communicating relevant use

information to employees. When developing workplace instructions for employees, Generic Exposure

Information Sheets should always be considered in combination with the SDS and the label of the

product. The GEIS Guidance for End Users provides more information.

The A.I.S.E. or the NVZ are under no conditions liable for any damage, no matter of what kind, which

is the direct or indirect consequence of acts and/or decisions (partly) based on the contents of

this document.


AEB ES.10.1.b.v1 Version: 1.0, May 2014

Brushing a concentrated professional product


















open flame









Environmental measures








SDS.





product.

Use descriptors

SU 3 Industrial uses.


PROC 10 Roller application or brushing




municipal STP.

Disclaimer: This is a generic document for communicating conditions of safe use of a product the employer of workers

that use products that are assessed as safe remains responsible for communicating relevant use information to

employees. When developing workplace instructions for employees, Information Sheets should always be considered in

combination with the SDS and the label of the product.


AISE GEIS.11.1.b.v1 Version: 1.0, May 2014

(Trigger) spraying of a professional product


















open flame

















SDS.





product.

Use descriptors



PROC 11 Non-industrial spraying




municipal STP.


mentioned in Section 1 of the SDS of a product, the formulator of that product declares that all substances in the mixture

are present in such concentration, that the use of the product within the conditions of the GEIS CSP documents is safe,

according to the GEIS Formulator Guidance. When available, this safe use is ensured by evaluating the results of the

chemical safety assessments as performed by the raw material suppliers. When no chemical safety assessment has been

carried out by the supplier for an ingredient that contributes to the classification of the mixture, the formulator has




developing workplace instructions for employees, Generic Exposure Information Sheets should always be considered

in combination with the SDS and the label of the product. The GEIS Guidance for End Users provides more information.

The A.I.S.E. or the NVZ are under no conditions liable for any damage, no matter of what kind, which is the direct or

indirect consequence of acts and/or decisions (partly) based on the contents of this document.


AEB ES.11.1.b.v1 Version: 1.0, May 2014

(Trigger) spraying of a professional product


















open flame

















SDS.





product.

Use descriptors



PROC 11 Non-industrial spraying




municipal STP.




combination with the SDS and the label of the product..


AISE GEIS.13.1.a.v1 Version: 1.0, May 2014

Treatment of articles by dipping or pouring with a professional products


















open flame

















SDS.





product.

Use descriptors



PROC 13 Treatment of articles by dipping andpouring




municipal STP.


mentioned in Section 1 of the SDS of a product, the formulator of that product declares that all substances in the mixture

are present in such concentration, that the use of the product within the conditions of the GEIS CSP documents is safe,

according to the GEIS Formulator Guidance. When available, this safe use is ensured by evaluating the results of the

chemical safety assessments as performed by the raw material suppliers. When no chemical safety assessment has been

carried out by the supplier for an ingredient that contributes to the classification of the mixture, the formulator has




developing workplace instructions for employees, Generic Exposure Information Sheets should always be considered

in combination with the SDS and the label of the product. The GEIS Guidance for End Users provides more information.

The A.I.S.E. or the NVZ are under no conditions liable for any damage, no matter of what kind, which is the direct or

indirect consequence of acts and/or decisions (partly) based on the contents of this document.


AEB ES.13.1.a.v1 Version: 1.0, May 2014

Treatment of articles by dipping or pouring with a professional products


















open flame

















SDS.





product.

Use descriptors



PROC 13 Treatment of articles by dipping andpouring




municipal STP.




combination with the SDS and the label of the product..

issued on 05/31/2019 - rel. # 9 on 05/31/2019 # 1 / 18 in ... · wel united kingdom: 123/25 skin...

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