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IH : Algal Biomass Direct-to-Fuels Technology Algae Biomass Summit 1 October, 2013 CRI Catalyst Company 910 Louisiana, Houston, TX 77002

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Page 1: IH : Algal Biomass Direct-to-Fuels Technologyalgaebiomass.org/wp-content/gallery/2012-algae-biomass-summit/2010… · IH2®: Algal Biomass Direct-to-Fuels Technology Algae Biomass

IH2® : Algal Biomass Direct-to-Fuels Technology

Algae Biomass Summit 1 October, 2013

CRI Catalyst Company

910 Louisiana, Houston, TX 77002

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Disclaimer

This presentation contains forward-looking statements concerning the financial condition, results of operations and businesses

of Royal Dutch Shell. All statements other than statements of historical fact are, or may be deemed to be, forward-looking

statements. Forward-looking statements are statements of future expectations that are based on management’s current

expectations and assumptions and involve known and unknown risks and uncertainties that could cause actual results,

performance or events to differ materially from those expressed or implied in these statements. Forward-looking statements

include, among other things, statements concerning the potential exposure of Royal Dutch Shell to market risks and statements

expressing management’s expectations, beliefs, estimates, forecasts, projections and assumptions. These forward-looking

statements are identified by their use of terms and phrases such as ‘‘anticipate’’, ‘‘believe’’, ‘‘could’’, ‘‘estimate’’, ‘‘expect’’,

‘‘goals’’, ‘‘intend’’, ‘‘may’’, ‘‘objectives’’, ‘‘outlook’’, ‘‘plan’’, ‘‘probably’’, ‘‘project’’, ‘‘risks’’, ‘‘seek’’, ‘‘should’’, ‘‘target’’, ‘‘will’’ and

similar terms and phrases. There are a number of factors that could affect the future operations of Royal Dutch Shell and could

cause those results to differ materially from those expressed in the forward-looking statements included in this presentation,

including (without limitation): (a) price fluctuations in crude oil and natural gas; (b) changes in demand for Shell’s products; (c)

currency fluctuations; (d) drilling and production results; (e) reserves estimates; (f) loss of market share and industry

competition; (g) environmental and physical risks; (h) risks associated with the identification of suitable potential acquisition

properties and targets, and successful negotiation and completion of such transactions; (i) the risk of doing business in

developing countries and countries subject to international sanctions; (j) legislative, fiscal and regulatory developments

including regulatory measures addressing climate change; (k) economic and financial market conditions in various countries

and regions; (l) political risks, including the risks of expropriation and renegotiation of the terms of contracts with governmental

entities, delays or advancements in the approval of projects and delays in the reimbursement for shared costs; and (m)

changes in trading conditions. All forward-looking statements contained in this presentation are expressly qualified in their

entirety by the cautionary statements contained or referred to in this section. Readers should not place undue reliance on

forward-looking statements. Additional factors that may affect future results are contained in Royal Dutch Shell’s 20-F for the

year ended December 31, 2012 (available at www.shell.com/investor and www.sec.gov ). These factors also should be

considered by the reader. Each forward-looking statement speaks only as of the date of this presentation 1 October 2013

Neither Royal Dutch Shell nor any of its subsidiaries undertake any obligation to publicly update or revise any forward-looking

statement as a result of new information, future events or other information. In light of these risks, results could differ materially

from those stated, implied or inferred from the forward-looking statements contained in this presentation.

9/30/2013 2

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Main Points

• Introduction to GTI and CRI

• IH2® Technology Overview

• Algae as Feedstock

• IH2® Product Quality

• IH2® Process Economics

• IH2® Commercial Deployment

• Conclusion

9/30/2013 3

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Introducing Gas Technology Institute

• US 501c3 R&D company founded as IGT in 1941

• Capabilities span natural gas value chain & biomass energy conversion

• Inventor of the IH2® process

• Des Plaines, Illinois USA campus – 250 professional staff

– 18 acre campus with 28 specialized labs totaling 200,000 ft2

• >1,200 patents; 750 licenses; 380 current licenses

• 500 products commercialized with partners

• CRI is the exclusive partner for IH2® technology

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Pilot Scale Gasification Campus Energy & Environmental Technology Center Offices& Labs

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Introducing CRI Catalyst Company

• Wholly owned Shell Catalyst Business with 50+ year history

• Houston based global business – Houston

– London

– Singapore

• Research Facilities – STC Amsterdam

– STC Bangalore

– STC Houston

• Manufacturing Facilities – USA: Martinez, CA; Kansas City, MO; Conshohocken, PA

– Leuna, Germany

– Gent, Belgium

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IH2® Technology Overview

• The IH2® process uses catalysts, hydrogen and heat to cost-effectively convert

a wide variety of biomass directly into high purity hydrocarbon “drop in” fuels

(i.e. R100) and/or high quality blend stock (e.g. >R60)

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• The IH2® process takes only minutes to convert biomass to hydrocarbons—

Nature requires millions of years…

• The IH2® process can be integrated into existing refinery, mill, ethanol plant,

agricultural, or recycling operations to create higher value from biomass than

afforded by heat and electrical power sales (NA basis)

• The IH2® process is NOT Gasification/Fischer Tropsch

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• Produce fungible hydrocarbon fuel/blend stock from a broad range of inedible/residual biomass feed at low cost

– maximizes product value; – eliminates availability, regionality, seasonality issues; – enhances project scale/capital efficiency

• Require no infrastructure other than road/rail transport into and out of the production. Can be integrated with existing facilities for even better economics.

– self-sufficient, self-contained and self-sustaining operation minimizes biomass transportation costs, build where the biomass is

• Have minimal unsustainable impact on the surrounding environment

9/30/2013 7

IH2® Technology Overview

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Gasoline, Jet and Diesel Hydrocarbons (67-157 gal/ton) R100 Regular Gasoline (Wood) R100 Intermediate Gasoline (Wood) R60 + Diesel (Wood)

Products

2) Fluidized Bed

Proprietary Catalyst System Renewable H2

340-470C <500psig

1) Feed Conditioning Sizing , Drying & Feeding

1st Stage 2nd Stage

3) Fixed Bed

Proprietary Catalyst System Renewable H2

<500psig

4) SMR C1-C3 Gas Renewable H2

Process

Distilled Hydrocarbon

Hi Pressure Steam

Clean Water

Fertilizer

BioChar

Biogenic CO2

City Waste

Wood/Forest Residue

Energy Crops

Algae

Feed

5) Cyclones

Crop Residue

IH2® Technology Overview

9/30/2013

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9/30/2013 9

IH2® Technology Overview

Wood

(Hard-Soft) Lemna MicroAlgae Bagasse MacroAlgae Corn Stover

Feed wt % C 49.7 46.3 43.1 43.1 34.0 40.2

Feed wt % H 5.8 5.8 6.1 5.0 4.43 5.0

Feed wt % O 43.9 35.7 20.4 35.3 23.6 35.7

Feed wt % N 0.11 3.7 6.5 0.34 4.6 1.0

Feed wt % S 0.03 0.3 0.7 0.10 1.9 0.05

Feed wt % Ash 0.5 8.2 23.1 16.2 29.4 18.1

Feed H/C 1.40 1.50 1.70 1.39 1.56 1.49

Typical % C4+ Liquid

Yield (MAF) (Moisture/Ash Free)

26-30 30 46 30 35 21

C4+ Gallon/Ton (MAF) 86-92 100 157 100 119 67

Product Oxygen b d l b d l b d l b d l b d l b d l

Product TAN# <0.02* <0.05 <0.05 <0.05 <0.05 <0.05

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Wood (Hard-Soft)

Lemna MicroAlgae Bagasse MacroAlgae Corn Stover

Feed wt % C 49.7 46.3 43.1 43.1 34.0 40.2

Feed wt % H 5.8 5.8 6.1 5.0 4.43 5.0

Feed wt % O 43.9 35.7 20.4 35.3 23.6 35.7

Feed wt % N 0.11 3.7 6.5 0.34 4.6 1.0

Feed wt % S 0.03 0.3 0.7 0.10 1.9 0.05

Feed wt % Ash 0.5 8.2 23.1 16.2 29.4 18.1

Feed H/C 1.40 1.50 1.70 1.39 1.56 1.49

Typical % C4+ Liquid

Yield (MAF) (Moisture/Ash Free)

26-30 30 46 30 35 21

C4+ Gallon/Ton (MAF) 86-92 100 157 100 119 67

Product Oxygen b d l b d l b d l b d l b d l b d l

Product TAN# <0.02* <0.05 <0.05 <0.05 <0.05 <0.05

Algae as Feedstock

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Algae as Feedstock

Extracted algae:

• Hydrocarbon yields 100 gal/ MAF ton of extracted algae

• The product split is roughly 70% gasoline and 30% jet/diesel range

Whole algae:

• Hydrocarbon yields range from 157 gal/ MAF ton of wild algae to over 172

gal/ MAF ton of high lipid algae

• The product split is roughly 30% gasoline and 70% jet/diesel range

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Algae as Feedstock

Growth Harvest Extraction

Primary Product(s)

Residues

NH3 / S

LP Steam / Hot Water

CO2

HP Steam or HP Steam to Power

Fuel

100 gal/ton MAF

(70% gasoline,

30% jet/diesel)

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Algae as Feedstock

Growth Harvest Extraction Whole Algae

NH3 / S

LP Steam / Hot Water

CO2

HP Steam or HP Steam to Power

Fuel

157 – 172 gal/ton MAF

(30% gasoline, 70%

jet/diesel)

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IH2® Product Quality (Wood)

Hydrocarbon

Water

Total Liquid Product

2nd Gen Catalyst Lab Scale

Total Liquid Product

1st Gen Catalyst Lab Scale

Hydrocarbon

Water

Gas/Jet/Diesel Product

3rd Gen Catalyst Lab Scale

4Q09 “R5” Quality 3Q10 “R25” Quality 2Q12 “R60+” Quality

Gasoline Product

3rd Gen Catalyst

Pilot Plant Scale

Drop In ‘R100’

Jet/Diesel Product

3rd Gen Catalyst

Pilot Plant Scale

>R60 Quality

Advanced catalysts improve product appearance and quality

Water Product

3rd Gen Catalyst

Pilot Plant Scale

Clean, No Carbon

Process & Catalyst

R&D Continues

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IH2® Product Quality (Wood)

Gasoline from IH2®-50 Pilot Plant

Distilled 5 gallons

Passed all ASTM D-4814-10b unleaded gasoline specs as R100 for economy

(86/87 octane) and intermediate (88/89 octane) US grades

For US premium (92/93 octane) add ethanol or sell as renewable RBOB

EN 228 and EN 590 testing set to begin 4Q13

EPA emissions testing (certification) set to begin 4Q13

Diesel from IH2®-50 Pilot Plant

Distilled 2 gallons

Passed all ASTM D-975-11 as No 2 middle distillate fuel

Except Cetane Index & Viscosity

Bangalore Research demonstrating increased cetane and reduce viscosity

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4.7

17.7

4.0

55.0 2.8

2.8

40.5

Feed

1st Stage/2nd Stage

Fractionation

HMU

Ammonium Sulfate

Absorption/Stripping

Utilities & Contingency @ 35%

Installed Equipment Costs $127.5MM • Stand Alone/Green Field (US Gulf Coast basis)

• 2000mt/d wood at 10% moisture

• TIC of $127.5MM results in TCI of $263MM

• HMU (SMR) is largest single expense @ $55mln ~45% TIC

• Feed Stock ~55% of Operating Cost

• No subsidies, tax credits included! $3.96capex/annual gallon

• KBR FEED underway (FEL-2 complete)

• Opex validated by prospective clients

• Minimum Fuel Selling Price:

$1.64/gal (2007) $1.80/gal (2012)

$0.433/L $0.476/L

• Refinery Synergy w/Refinery H2 Supply

- Estimated MFSP $1.36/gal (2007) $1.49/gal (2012)

$0.359/L $0.394/L

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91.31

7.8

2.14

17.3

5.9

29.6

Wood $71.97/dry ton

Other Op Costs: Catalyst, Disposal, etc. Fixed Cost

Depreciation

Avg Income Tax

Avg ROI

Operating Costs Total $1.64/gal*

*Includes $0.1884/gal coproduct credit http://www.osti.gov/bridge/servlets/purl/1059031/1059031.pdf

IH2® Process Economics

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• Bench Scale

– Since 02/2009 @ 0.5kg/hr

• Pilot Scale

– Since 02/2012 @ 50kg/d

– Confirmed bench scale results

– Producing fuels for EPA Registration

– Producing fuels for EN Qualification

– Wood derived gasoline is R100

• Pre Commercial Scale

– BDEP for 5mt/d cellulose done

– 2 showcase licenses awarded since 12/2012

• Commercial Scale

– KBR is CRI’s exclusive commercial engineering partner

– 500 & 1000mt/d stand alone USGC wood FEL-2 completed; FEL-3 begins

– 2 commercial licenses awarded since 06/2013

IH2® Commercial Deployment

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Conclusion

• The IH2® technology produces high quality hydrocarbon fuels and

blend stock directly from biomass

• Feedstock flexible with high product yields

• Presents an opportunity for integration with algae production and/or

extraction facility for better site margin

• Nearly carbon neutral*

• Attractive economics

• Available exclusively from CRI

>94% GHG reduction per Professor David Shonnard at MTU:

http://services.lib.mtu.edu/etd/THESIS/2012/ChemicalEng/maleche/thesis.pdf

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Thank You

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Learn more at

http://www.cricatalyst.com/catalysts/renewables.html