i nnov a t i v e ba r r i e r fi l m ge ne r a t e d by ad v a nc e ... n n o va t i ve ba r r i er...

© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved.

http;//www.dnp.co.jphttp;//www.dnp.co.jphttp://www.dnp.co.jp/international/pack/film/film_1.htmlhttp://www.dnp.co.jp/international/pack/film/film_1.html

I nnovative Barrier FilmII nnovative nnovative BBarrier arrier FilmFilm

I nnovative Barrier Film generated by Advanced Clear Coating TechnologiesI nnovative Barrier Film generated by I nnovative Barrier Film generated by Advanced Clear Coating TechnologiesAdvanced Clear Coating Technologies

© 2011 Dai Nippon Printing Co.,Ltd. All Rights Reserved. 11

ConfidentialConfidentialAgenda

Ⅰ. DNP Introduction

Ⅱ. IB (Innovative Barrier) Film feature


ConfidentialConfidential

DNP IntroductionDNP Introduction



Established : 1876HQ Location : Tokyo, JAPANCapital (as of March 2010) : ¥ 115 billion Annual Sales (as of March 2010) : ¥ 1,580 billion (Consolidated)

¥ 1,090,billion (Non-Consolidated) Number of Employees (as of March 2010)

39,643 (Consolidated)10,539 (Non-Consolidated)

Operations; Information CommunicationLifestyle & Industrial Supplies (incl. Packaging)Electronics

DNP Company Outline



- Books and MagazinesBooks, Magazines, DictionariesTextbooks, Graphic collectionse-books

- Commercial PrintingCatalogs, Calendars, PostersPromotional Publication

- Information Processing ServicesPersonal mail, Business formsCredit/Banking cards, SIM cards Hologram

Information Communication Information Communication

DNP Company Outline



- PackagingFoods, Beverages, Personal care,Home care, Pharmaceuticals

- Decorative materialsInterior and Exterior decorative material for houses, buildings

- Optical material, Industrial materialOptical film for Display, Projector screenSublimation/Thermal transfer ribbonSelf print system

Lifestyle and Industrial Supplies Lifestyle and Industrial Supplies

DNP Company Outline



- DisplaysColor-filter for LCD Organic light emitting display

- Electronic ComponentsPhoto-mask and Lead flame for Semi-conductors products IC-Tag, MEMS

Electronics Electronics

DNP Company Outline



IB (Innovative Barrier) Film feature

(Passive Barrier)(Passive Barrier)



IBIB--Film offersFilm offersFunctions and addedFunctions and added--values to packagevalues to package

FunctionsFunctions AddedAdded--ValuesValues

Excellent Gas BarrierExcellent Gas BarrierSterilizabilitySterilizabilityDirect PrintabilityDirect PrintabilityTransparencyTransparency

MicrowaveMicrowave--abilityabilityEasy ConvertingEasy ConvertingSource ReductionSource ReductionEcoEco--FriendlyFriendly

IB-Film Functions & Added-Values



IBIB--FILMFILM

CVDCVD SiOxSiOx

AlOxAlOxPVDPVD

OPAOPA

PETPET

PETPET

IBIB--ONON

IBIB--PETPET

IBIB--PETPET--PP

DepositionDeposition LayerLayer SubstrateSubstrate IB SubfamilyIB Subfamily

IBIB--FILMs are classified into 3 subfamilies depending on FILMs are classified into 3 subfamilies depending on deposition methods and substratesdeposition methods and substratesCVDCVD : Chemical Vapor Deposition: Chemical Vapor DepositionPVDPVD : Physical Vapor Deposition: Physical Vapor Deposition

SilicaSilica

AluminaAlumina

IB-Film Classification



PETONy

OSi C

Si

O

OSi

C

COHUnwinderUnwinder

RewinderRewinder

SiSi--PrecursorPrecursorReaction GasReaction GasCarrier GasCarrier Gas

ExhaustExhaust

Highly flexible deposition layerHighly flexible deposition layerDurable against physical and thermal stressesDurable against physical and thermal stressesColorless and clearColorless and clearGood bonding strength with substrateGood bonding strength with substrateProcessable on poor heat resistance substratesProcessable on poor heat resistance substrates

PlasmaPlasma

CVD technology enables to produce CVD technology enables to produce carbon containing SiOxcarbon containing SiOx onto substrate, onto substrate, giving the following beneficial characteristics;giving the following beneficial characteristics;

Covalent Covalent bondbond

SiOxCySiOxCy

Chemical Vapor Deposition Process (CVD)



Colorless and high transparencyColorless and high transparencyLarge volume manufacturingLarge volume manufacturingStability of manufacturedStability of manufactured

UnwinderUnwinder

RewinderRewinder

Electron BeamElectron Beam

OO22

Al + OAl + O22 AlOxAlOxReactive evaporation of aluminiumReactive evaporation of aluminium

Aluminium Aluminium vaporvapor

Physical Vapor Deposition Process (PVD)

PVD technology enables to produce PVD technology enables to produce AlOxAlOx onto substrate, onto substrate, giving the following beneficial characteristics;giving the following beneficial characteristics;



＊＊ ○○: Good : Good △△: Poor: Poor ××: Bad or not recommendable: Bad or not recommendable

Direct PrintingDirect Printing (Roto gravia)(Roto gravia)

IBIB--ONON--UBUB

IBIB--PETPET--UBUB

IBIB--PETPET--PXBPXB

○○ ○○ △△

ConvertingConverting& Processing& Processing

SolventSolvent--BaseBaseAdhesive Laminate (approved by FDA)Adhesive Laminate (approved by FDA) ○○ ○○ ○○

Extrusion LaminationExtrusion Lamination--Limit melt temperature or PELimit melt temperature or PE--Limit extrudable PE thicknessLimit extrudable PE thickness

○○300300ººCC2020μμmm


××

Boil TreatmentBoil Treatment ○○9595ººCC ××○○

9595ººCC

Retort TreatmentRetort Treatment ×× ××××

IBIB--PETPET--PIRPIR

○○

○○

○○9595ººCC

○○135135ººCC


Converting & Process-ability Profile

CVD (SiOx) PVD (AlOx)



OXTROXTR :: cc/mcc/m22/day/atm (23/day/atm (23ººC/90%RH)C/90%RH)WVTRWVTR :: g/mg/m22/day (40/day (40ººC/90%RH)C/90%RH)

22--Layer : IBLayer : IB--FILM/adh/PEFILM/adh/PE606033--Layer : IBLayer : IB--FILM/adh/BOPAFILM/adh/BOPA1515/adh/CPP/adh/CPP6060

IB-Film line up & applications ConfidentialConfidential

※These data are based on measurement,but not guaranteed.

Boilable sachetBoilable sachetFlavoring sauce bagFlavoring sauce bag

Laminate TubeLaminate TubePaperboard CartonPaperboard Carton

IBIB--ONON--UBUBIBIB--ONON 1515 0.30.3 1.81.8

IB GradeIB Grade µµmm OXTROXTR WVTRWVTR Typical ApplicationsTypical Applications

IBIB--PETPET--UBUB 1212 0.30.3 0.80.8IBIB--PETPET

IBIB--PETPET--PP

IB SubfamilyIB Subfamily

22--LayerLayer

22--LayerLayer

Retort Retort Medical / Infusion BagMedical / Infusion BagDry Foods, ConfectionaryDry Foods, ConfectionaryIndustrial SuppliesIndustrial SuppliesWaterWater--sensitive product sensitive product

Industrial SuppliesIndustrial SuppliesWaterWater--sensitive product sensitive product IBIB--PETPET--PXBPXB 1212 0.10.1 0.10.1 22--LayerLayer

LaminateLaminateStructureStructure

1212 0.20.2 0.50.5 33--LayerLayerIBIB--PETPET--PIRPIR

CVD(SiOx)

PVD(AlOx)

ForRetort

before retortbefore retort

BOPABOPA



0

1

2

3

4

5

OXTROXTR WVTRWVTR OXTROXTR WVTRWVTR

IBIB--ONON--UBUB 0.30.3 1.81.8 1.21.2 2.82.8ON/SiOx(PVD)ON/SiOx(PVD) 0.40.4 0.50.5 2.82.8 3.63.6

Before BoilBefore Boil After BoilAfter Boil•• General Performance General Performance –– High temperature boil sterilizationHigh temperature boil sterilization

•• Characteristics and promising applicationsCharacteristics and promising applications

““9595ººCC××30min30min””

••Good gelboGood gelbo--flex durabilityflex durability••Good flavor barrierGood flavor barrier••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications

--Sachet Sachet --Cup noodle packagingCup noodle packaging

SauceSauce

JapaneseJapanesedressingdressing

ChineseChinesedressingdressing

DippingDippingsaucesauce

VinegarVinegarsoy saucesoy sauce

GoodGood

BadBad

Sensory test for flavor retention Sensory test for flavor retention (40(40ººC/7days)C/7days)

Structure : BaseStructure : Base--ON15/adhesive/PE60ON15/adhesive/PE60OXTR: 23OXTR: 23ººC/90%RH WVTR: 40C/90%RH WVTR: 40ººC/90%RHC/90%RH

PVD ON-SiOx

IB-ON-UB

((competitivecompetitive))

IBIB--ONON--UBUB



0

2

4

6

8

10

12

14

16

0 10 20 50 100

OXTROXTR WVTRWVTR

IBIB--PETPET--UBUB 2323ººC/90%RHC/90%RH 0.30.3

•• General Performance General Performance -- Low Dependency on Temp. and HumidityLow Dependency on Temp. and Humidity

•• Characteristics and promising applicationsCharacteristics and promising applications••Suitable for liquid packagingSuitable for liquid packaging••Good gelboGood gelbo--flex durabilityflex durability••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications

--Laminate Tube Laminate Tube --Paperboard CartonPaperboard Carton--WetWet--tissue pillow pouchtissue pillow pouch

Temp./HumidityTemp./Humidity

3030ººC/90%RHC/90%RH 0.40.44040ººC/90%RHC/90%RH 0.50.5 0.80.8

0.40.40.20.2

GelboGelbo--CyclesCycles

OX

TR (c

c/m

2/da

y/at

m)

OX

TR (c

c/m

2/da

y/at

m)

At 2

3A

t 23 ºº

C/9

0%R

HC

/90%

RH

PVD PET/SiOx

PVD PET/AlOx

IB-PET-UB

Structure: IBStructure: IB--PETPET--UB12/adhesive/PE60UB12/adhesive/PE60

IBIB--PETPET--UBUB



OXTROXTR WVTRWVTR

IBIB--PETPET--PUBPUB 2323ººC/90%RHC/90%RH 0.30.3

•• General Performance General Performance -- Low Dependency on Temp. and HumidityLow Dependency on Temp. and Humidity

•• Characteristics and promising applicationsCharacteristics and promising applications••Suitable for dry food packagingSuitable for dry food packaging••Excellent moisture barrierExcellent moisture barrier••Extrusion coating is availableExtrusion coating is available••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications

--Dry foodsDry foods--Water sensitive articlesWater sensitive articles

Temp./HumidityTemp./Humidity

3030ººC/90%RHC/90%RH 0.30.34040ººC/90%RHC/90%RH 0.40.4 0.50.5

0.20.20.10.1

0.000

0.100

0.200

0.300

0 10 20 30 40Time Intervals (Days)Time Intervals (Days)

Wei

ght C

hang

e (g

/pac

kage

)W

eigh

t Cha

nge

(g/p

acka

ge) 90%RH

75%RH

50%RH

Temp.=40ºC constant)

Pouch size: 100mm ×100mContent: Calcium chloride

Structure: IBStructure: IB--PETPET--PUB12/adhesive/PE60PUB12/adhesive/PE60

IBIB--PETPET--PUBPUB



OXTROXTR WVTRWVTR

IBIB--PETPET--PXBPXB 0.10.1

•• General Performance General Performance -- Ultra High Moisture BarrierUltra High Moisture Barrier

•• Characteristics and promising applicationsCharacteristics and promising applications

••Suitable for water sensitive articlesSuitable for water sensitive articles••Excellent moisture barrierExcellent moisture barrier••Direct printableDirect printable••MicrowaveMicrowave--ableable••ApplicationsApplications

--Mouth freshenerMouth freshener--Silicon waferSilicon wafer--Vacuum infusion bagVacuum infusion bag--Price tagPrice tag

Layer #Layer #

0.10.1

0.000

0.100

0.200

0.300

0 10 20 30 40Time Intervals (Days)Time Intervals (Days)

Wei

ght C

hang

e (g

/pac

kage

)W

eigh

t Cha

nge

(g/p

acka

ge)

PXB Double

Pouch size: 100mm ×100mContent: Calcium chloride

Single LayerSingle Layer

OXTR: 23OXTR: 23ººC/90%RH WVTR: 40C/90%RH WVTR: 40ººC/90%RHC/90%RH

PXB12/adh/PE60PXB12/adh/PE60

PXB Single

PUB Single




New grade “IB-PET-PIR” for retort


ConfidentialConfidentialFeature of “IB-PET-PIR”

IBIB--PETPET--PIRPIR consists of AlOx layer using PVD method and wet coating layerconsists of AlOx layer using PVD method and wet coating layeron the PET substrate.on the PET substrate.IBIB--PETPET--PIRPIR has many characteristics which are has many characteristics which are retort treatment resistanceretort treatment resistanceandand high barrier propertieshigh barrier properties..

Colorless and High transparencyColorless and High transparencyLarge volume Large volume manufacturing

● Retort Pouch & Lid● Boil Pouch & Bag● Packaging for microwave● Medical Bag

＋＋

You can use You can use following example!!



• General Performance - Well-balanced gas barrier suitable for retort

OXTR WVTR OXTR WVTR

IB-PET-PIR 0.2 0.5 0.3 0.9

PET/AlOx 0.3 0.5 0.5 0.6

Before Retort After Retort“121ºC×30min”

Structure: Base-PET12/adh/ON15/adh/CPP70 (3-Layer)OXTR(cc/㎡･day･atm): 23ºC/90%RH WVTR (g/㎡･day) : 40ºC/90%RH

(competitive)

OXTR WVTR OXTR WVTR

IB-PET-PIR 0.2 0.5 0.3 1.2

PET/AlOx 0.3 0.5 0.9 1.9

Before Retort After Retort“135ºC×30min”

Structure: Base-PET12/adh/ON15/adh/CPP70 (3-Layer)OXTR(cc/㎡･day･atm): 23ºC/90%RH WVTR (g/㎡･day) : 40ºC/90%RH

(competitive)

※These data are based on measurement,but not guaranteed.

IB-PET-PIR Barrier Property



0.00

0.50

1.00

1.50

2.00

2.50

3.00

3.50

4.00

4.50

5.00

0% 1.50% 2% 2.50% 3%

OXT

R(c

c/m

2 .day

.atm

)

Elongation (%)Elongation (%)

Competitor A: SiOx（P）

Competitor B: AlOx（P）

Competitor C: AlOx（P）

PIR（P）

VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70

(P): PVD

Anti-Elongation Property

• Oxygen barrier property after elongation to specific point



ASTM F392ASTM F3920.00

2.00

4.00

6.00

8.00

10.00

12.00

14.00

OXT

R(c

c/m

OXT

R(c

c/m

22 .day

.atm

).d

ay.a

tm)

Competitor ASiOx（P）

Competitor BAlOx（P）

Competitor CAlOx（P）

PIR（P）

Before gelbo

50 times

10 times20 times

100 times

OX

TR(c

c/m

OX

TR(c

c/m

22 .day

.atm

).d

ay.a

tm)

Oxygen barrierOxygen barrier

Gelbo-Flex Test

(P): PVD

VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70

Twisting and Compress



Retort condition: 30 minLayer structure: VM-PET12 (Retort grade)/Ad/ON15/Ad/CPP70/Ad/ON15/Ad/CPP70

OXTR

Pre-retort

121℃ 125℃ 130℃ 135℃0.00

0.50

1.00

1.50

2.00

2.50

3.00

3.50

0.00

0.25

0.50

0.75

1.00

1.25

1.50

1.75

2.00WVTR

Competitor CAlOx（P）

Competitor ASiOx（P）

Competitor BAlOx（P）

PIR（P）

Pre-retort

121℃ 125℃ 130℃ 135℃

（P）： PVD

Retort Temp. and DurabilityO

XTR

(cc/

mO

XTR

(cc/

m22 .d

ay.a

tm)

.day

.atm

)

WV

TR(g

/mW

VTR

(g/m

22 .day

).d

ay)

IB-PET-PIR keeps a goodbarrier properties until 135℃retort treatment conditions.



IBIB--ONON--UBUB

IBIB--PETPET--UBUB

IBIB--PETPET--RBRB

IBIB--PETPET--PUBPUB


IBIB--ONON

IBIB--PETPET

IBIB--PETPET--PP

CompliesComplies

CompliesComplies

CompliesComplies

CompliesComplies

under investigationunder investigation

EU Regulations*EU Regulations*

CompliesComplies

CompliesComplies

CompliesComplies

CompliesComplies

FDA RegulationsFDA Regulations

CompliesComplies

IB GradesIB GradesIBIBSubfamilySubfamily

** Framework regulations (EC) No.1935/2004Framework regulations (EC) No.1935/2004Commission Directive 2002/72/EC and its amendmentsCommission Directive 2002/72/EC and its amendmentsEuropean Parliament & Council Directive 94/62/ECEuropean Parliament & Council Directive 94/62/ECGerman Food Contact Regulation German Food Contact Regulation Switzerland Food Contact RegulationSwitzerland Food Contact RegulationItalian Food Contact RegulationItalian Food Contact Regulation

IB-Film Compliance Status EU & FDA

IBIB--PETPET--PIRPIR under investigationunder investigation CompliesComplies★ Brand-new grade



25

confectionery Retort food

BeveragePasteurized rice

General foodsIndustrial supplies

（ＰＥＴ substrate）

TypicalTypical aapplicationspplications ２２



Pharmaceutical / Medical Application: Moisture Barrier (IB-PET-PIR, IB-PET-PXB)

- Tablet outer packaging

- Eye drop outer packaging

- Ampoule outer packaging

- Cylinder outer packaging

- Healthcare product packaging (Wet tissue)

- Breath care

- Bath salts

Pharmaceutical / Medical Application: Heat resistance Barrier (IB-PET-PIR)

- Nutritional outer packaging

- Infusion bag

- Pharmaceutical cup lids

- Retort laminated tube

Non Food Application 1



Industrial Material Application: Moisture Barrier (IB-PET-PIR, IB-PET-PXB)

- Ink toner container

- Ink cartridge

- Insulation material

- Flexible display

- Touch panel

- Electric material packaging

- Replacement for thin glass

- E-book

- E-tag

- Inner bag for industrial paper bag

Non Food Application 2



Thank you for your attention.Thank you for your attention.

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