h&m discharge data report - sustainability...

21
Page 0 of 20 H&M DISCHARGE DATA REPORT February 2014

Upload: trinhphuc

Post on 10-Mar-2018

213 views

Category:

Documents


1 download

TRANSCRIPT

Page 1: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 0 of 20

H&M

DISCHARGE DATA REPORT

February 2014

Page 2: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 1 of 20

Table of Contents I. Introduction .................................................................................................................... 2

II. Objectives ...................................................................................................................... 3

III. Methodology .................................................................................................................. 3

IV. Results and Discussion ................................................................................................ 4

Hazardous chemicals detected in incoming and discharged water samples .................. 4 4.1

Comparison of the quantity of detected chemicals in discharge waste water with local 4.2

legislation .................................................................................................................................... 8

Disclosure of discharge data to Institute of Public and Environmental Affairs (IPE) 4.3

platform ..................................................................................................................................... 10

IV. Conclusion and action plan ...........................................................................................10

V. References .....................................................................................................................11

Appendix A: List of Analytes .....................................................................................................12

Appendix B: Standard procedure for environmental sampling ...................................................16

Appendix C: Number of factories that the restricted analytes detected in water samples ..........17

Appendix D: Highest detected concentration of analytes in incoming water in different

countries ...................................................................................................................................18

Appendix E: Possible sources of detected chemicals in manufacturing processes. ..................19

Contact Details: ......................................................................................................................20

Page 3: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 2 of 20

I. Introduction

H&M is highly concerned about protection of environment and health. In 2011, H&M, together with

several Apparels and Footwear brands, formed the Zero Discharge of Hazardous Chemicals (ZDHC)

group, which aims to lead industry to achieve zero-discharge of hazardous chemicals during

manufacturing by 2020.

In 2012, H&M performed the Benchmark study, which provided a snapshot on the situation of

hazardous chemicals discharge in manufacturing. In the study, discharged wastewater and incoming

water of 11 factories in three countries, China, India, and Bangladesh, were tested for 93 analytes

corresponding to 11 hazardous chemical groups. Among these hazardous chemical groups, five

chemical groups were detected in discharged wastewater. However, most detected chemical groups

in discharge wastewater were also detected in incoming water, indicating that the chemicals found in

discharged wastewater were mainly originated from environmental background instead of

manufacturing. These results reflected the restrictive chemical control in supply chain of H&M, but at

the same time revealed that the presence of hazardous chemicals in environmental background

imposes significant challenge in complete elimination of hazardous chemicals in discharged

wastewater. After the benchmark study, H&M has increased the restriction in chemical discharge by

expanding the Manufacturing Restricted List (MRSL)1 from 17 to 139 chemical substances. Besides,

H&M is working closely with stakeholders to drive towards the goal of zero-discharge.

In 2013, H&M continues to pay significant effort to achieve complete elimination of hazardous

chemicals in supply chain. Following the benchmark study in last year, H&M carried out a further

comprehensive study to investigate the discharge of hazardous chemicals during manufacturing. This

study was of an expanded scale, in which discharged wastewater and incoming water of 34 factories

in five production countries, China, Cambodia, Bangladesh, India and Indonesia, were tested for 121

analytes2

corresponding to the 11 hazardous chemical groups. In addition, H&M understands the

responsibility and importance in increasing the transparency of hazardous chemicals discharge to

public. The discharge data collected in this study was disclosed in a public online platform, the

Institute of Public and Environmental Affairs (IPE) (www.ipe.org.cn).

In this report, the results for the study of hazardous chemicals discharge are presented and action

plans to drive towards the goal of zero-discharge are discussed. Besides, the workflow for disclosure

of data to the IPE platform is introduced.

1 H&M Manufacturing Restricted List (MRSL)

https://about.hm.com/content/dam/hm/about/documents/masterlanguage/CSR/Policies/HM%20Chemical%20Re

strictions%20May%202013_Final%20w%20front.pdf

2 The list of analytes are shown in Appendix A.

Page 4: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 3 of 20

II. Objectives

To conduct a further comprehensive study on discharge of hazardous chemicals in manufacturing

and develop action plans to drive towards zero-discharge.

III. Methodology

The study was conducted on 34 factories from five major production countries, (i) China (10 units), (ii)

Cambodia (3 units), (iii) Bangladesh (17 units), (iv) India (2 units) and (v) Indonesia (2 units). (Figure1)

Chemical tests were performed by Bureau Veritas Consumer Product Service Ltd (BVCPs). The

collection of environmental samples was carried out according to international standards as listed in

Appendix B. Particularly, the environmental samples were collected in the period between 2.00-5.00

pm, during which the factories operated under normal load. The collected samples were sent to local

testing laboratories of BVCPs for chemical tests.

Figure 1. Number of factories in different countries included in the present study

Page 5: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 4 of 20

IV. Results and Discussion

Hazardous chemicals detected in incoming and discharged water 4.1

samples

Number of hazardous chemical detected in discharged wastewater and incoming water

The discharged wastewater and incoming water of factories were tested for a total of 121

hazardous chemical analytes1. Among these hazardous chemicals, 33 (27.3%) chemicals were

detected in discharged wastewater and 20 out of the 33 detected chemicals were also detected in

incoming water (Figure 2). These data indicated that incoming water was one of major source

contributing to the hazardous chemicals detected in discharged wastewater.

*The detected analytes is shown in Appendix C

Chemical groups detected in discharged wastewater and incoming water

Chlorophenols, Flame Retardants and Perfluorinated compounds were not detected in both

wastewater and incoming water samples (Table 1). The 33 hazardous chemicals detected in

discharged wastewater belong to 8 chemical groups, 1) APEO, 2) Azo Dyes, 3) Chlorinated

33 (27%)

88 (73%)

20 (16%)

Figure 2. Numbers of detected and non-detected analytes in water

samples

No. of anayltes detected in

waste water

No. of anayltes not -detected

in waste water

No. of anayltes detected in

incoming water

Page 6: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 5 of 20

solvents, 4) Chlorobenzenes, 5) Organotin, 6) Phthalates, 7) Short Chain Chlorinated Paraffins

(SCCPs) and 8) Heavy metals. Among the eight chemical groups detected, five of which, APEO,

Chlorobenzenes, Chlorinated solvents, Heavy metals and Phthalates, were also detected in

incoming water samples (Table 1). However, Azo dyes, SCCPs and Organotin were not detected

in incoming water, indicating that these three chemical groups could be originated from

manufacturing processes. As shown in figure 3, Chlorobenzenes, Heavy metals and Phthalates

were three major chemical groups detected in discharged wastewater.

*Common sources of various hazardous chemicals in manufacturing are shown in Appendix E.

Table 1. List of detected and non-detected chemical groups in incoming and discharged waste

water samples.

Remarks:

√: Chemical analytes detected in water samples

X: Chemical analytes not detected in water samples

Restricted Chemical Groups

Incoming

Water

Discharged Waste

Water

1. Alkylphenols (APs) & Alkylphenol Ethoxylates

(APEOs)

√ √

2. Aromatic Amines in Azo Dyes x √

3. Brominated and Chlorinated Flame Retardants x x

4. Chlorinated solvents √ √

5. Chlorobenzenes √ √

6. Chlorophenols x x

7. Organotin x √

8. Perfluorinated Compounds (PFCs) x x

9. Phthalates √ √

10. Short Chain Chlorinated Paraffins (SCCPs) x √

11. Total heavy metal, except Chromium VI (Cr VI) √ √

Page 7: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 6 of 20

Hazardous chemical groups detected in factories from different countries

The discharge of hazardous chemical groups in factories from different countries is depicted in

Table 2. In China and Indonesia, most chemical groups detected in discharged wastewater were

also detected in significant quantity in incoming water3, indicating that most hazardous chemicals

detected in discharge wastewater could be originated from incoming water and the environmental

water source in these two countries was more polluted. In Bangladesh and Cambodia, most

detected chemical groups in discharged wastewater were not from incoming water3, therefore

3 The highest concentration of detected analytes in incoming water listed in Appendix D.

0

5

10

15

20

25

30

35

APEO Azo Chlorinate

d Solvents

Chloroben

zenes

Heavy

metals

Organotin Phthalate

s

SCCPs

Incoming water 3 0 1 6 34 0 12 0

Waste water 6 2 3 10 34 3 11 7

No

. o

f fa

cto

rie

s

Figure3. Number of factories with restricted chemicals detected in water samples

Incoming water

Waste water

Page 8: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 7 of 20

generation of hazardous chemicals during manufacturing in these two countries needs particular

concerns. Among the hazardous chemicals tested, Chlorobenzenes and Heavy metals were

detected in all the five countries, showing the wide distribution of these two chemical groups in

manufacturing and environment and the challenge in elimination of these two chemical groups.

Table 2. Restricted chemical groups detected in different countries

Countries

Chemical Groups Ba

ng

lad

esh

Ch

ina

Ca

mb

od

ia

Ind

ia

Ind

on

esi

a

1. Azo dyes

2. APs & APEOs

3. Chlorinated Solvents

4. Heavy metals (except Cr VI)

5. Chlorobenzenes

6. Organotin

7. Phthalates

8. SCCPs

Chemicals were detected in incoming water samples only

Chemicals were detected in discharged waste water samples only

Chemicals were not detected in both incoming and discharged waste water samples

Chemicals were detected in both incoming and discharged waste water samples

Page 9: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 8 of 20

Comparison of the quantity of detected chemicals in discharge waste 4.2

water with local legislation

In this part, the quantity of detected chemicals in discharged wastewater is compared with the

local legislation limits of waste water in the five countries involved, which indicate the impacts of

hazardous chemicals to environment and health. Legislation limits for three chemical groups,

including 1) Chlorinated solvents, 2) Chlorobenzenes and 3) Heavy metals, were compared here

as only the legislation limits of these chemicals groups were available (Table 3). Different

countries have different restriction level for these hazardous chemicals in wastewater. In

Indonesia, only and Chromium (Cr) is restricted, while in Bangladesh, Cambodia, and India, more

chemicals are restricted (Table 3).

The highest detected concentration of each analytes in this study was applied for the comparison

with local wastewater discharged legislation limits. As shown in Table 3, the concentrations of all

hazardous chemicals detected in this study were lower than the corresponding legislation limits,

therefore fulfilled the relevant country legislations that listed in reference section.

Page 10: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 9 of 20

Table 3. Comparison of the highest detected concentration of analytes in discharged waste water with

corresponding local legislation

Chemicals

Bangladesh China Cambodia India Indonesia

Limit Detected Limit Detected Limit Detected Limit Detected Limit Detected

Arsenic, As 0.2 0.003 0.5 0.005 1 0.008 0.2 0.003 NA 0.002

Cadmium, Cd 0.05 0 0.1 0.002 0.5 0.003 2 0 NA 0.002

Cyanide, CN-

0.1 0.036 NA 0 NA 0 0.2 0 NA NA

Chromium, Cr 0.5 0.204 1.5 0.007 NA 0 2 0.036 1 0.004

Chromium VI 0.1 0 0.5 0 0.5 0 0.1 0 NA 0

Copper, Cu 0.5 0.048 0.5 0.0873* 1 0.016 3 0.084 NA 0.137

Mercury, Hg 0.01 0 0.05 0 0.05 0.0001 0.01 0 NA 0.001

Manganese,

Mn

5 1.59 NA 2.68 NA 0 2 0.114 NA 0.293

Nickel, Ni 1 0.118 1.0 0.004 1 0.024 3 0.09 NA 0.017

Lead, Pb 0.1 0.01 1.0 0.01 1 0.167 0.1 0.067 NA 0.041

Antimony, Sb NA 0.03 NA 0.067 NA 0.003 NA 0.008 NA 0.021

Zinc, Zn 5 0.217 NA 0.391 3 0.133 5 1.057 NA 0.14

Trichlorobenze

ne (sum)

NA 0.0001 NA 0 2 0.001 NA 0 NA 0.0003

Hexachloro-

benzene

NA 0 NA 0 2 0 NA 0 NA 0

1,2 Dichloro-

ethylene

NA 0 NA 0 2.5 0 NA 0 NA 0

Trichloro-

ethylene

NA 0 NA 0 1 0 NA 0 NA 0

Chloroform NA 1.01 NA 0 1 0 NA 0 NA 0

*This is the second highest data among China units. The highest data was obtained from wastewater collected for

further processing, but not directly discharged to environment. Thus, this data is not use for comparison.

Units: parts per million (ppm)

Page 11: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 10 of 20

Disclosure of discharge data to Institute of Public and Environmental 4.3

Affairs (IPE) platform

Each factory unit was required to fill in the chemical test data into a data form issued by IPE. The

filled data form was sent to BVCPs for cross-check and finally uploaded to the IPE platform by

factories. All discharged results of 34 production units are now available in IPE platform:

http://www.ipe.org.cn/En/pollution/discharge_detox.aspx. The uploaded data is freely accessible

by public.

IV. Conclusion and action plan

This study provided a comprehensive picture on discharge of hazardous chemicals in

manufacturing of H&M. Among the 11 chemical groups (121 chemical analytes) tested, 8

chemical groups (33 chemical analytes) were found in discharged wastewater. In coherent with

the benchmark study performed in last year, many chemicals detected in discharged wastewater

could be originated from incoming water. However, some chemical groups, including Azo dyes,

Organotin, and SCCPs, were only detected in discharged wastewater but not in incoming water,

indicating that these chemicals groups could be produced from manufacturing. And, the quantities

of all detected hazardous chemicals in these units were lower than the legislation limits of the

corresponding countries.

H&M will continue to pay every effort in elimination of hazardous chemicals from supply chain. In

order to prevent the use of hazardous chemicals during manufacturing, we will work closely with

our suppliers to work out good chemical management systems and keep close monitoring on the

implementation of the systems. We will keep updating our MRSL to increase the

comprehensiveness of the zero-discharge scheme. We will further enhance the transparency of

hazardous chemical discharge to public by encouraging more factories to disclose their chemical

discharge data.

Page 12: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 11 of 20

V. References

1. The Environment Conservation Rules, 1997

2. Official Journal of the European Union, Directive 2008/105/EC of the European

Parliament and of the Council

3. Discharge standard of water pollutants for dyeing and finishing of textile industry,

GB4287-2012

4. Integrated wastewater discharge standard GB8978-1996

5. The Environment (Protection) Rules, 1986

Page 13: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 12 of 20

Appendix A: List of Analytes

No. Chemical Groups Name of Analytes CAS-No.

1

Phthalates

Butyl benzyl phthalate (BBP) 85-68-7

2 Dibutyl phthalate (DBP) 84-74-2

3 Di-2-ethylhexyl phthalate (DEHP) 117-81-7

4 Di-n-octyl phthalate (DNOP) 117-84-0

5 Di-iso-nonyl phthalate (DINP) 28553-12-0 & 68515-48-

0

6 Di-iso-decyl phthalate (DIDP) 26761-40-0 & 68515-49-

1

7 Dimethyl phthalate (DMP) 131-11-3

8 Diethyl phthalate (DEP) 84-66-2

9 Di-n-propyl phthalate (DPRP) 131-16-8

10 Di-iso-butyl phthalate (DIBP) 84-69-5

11 Di-cyclohexyl phthalate (DCHP) 84-61-7

12 Di-n-hexyl phthalate (DnHP) 84-75-3

13 Dinonyl phthalate (DNP) 84-76-4

14 Di-iso-octyl phthalate (DIOP) 27554-26-3

15 Dimethoxyethyl phthalate (DMEP) 117-82-8

16

Brominated Flame Retardants

Polybromobiphenyls (PBBs) Various

17 Tris(2,3-dibromopropyl) phosphate (TRIS) 126-72-7

18 Polybromodiphenyl ethers (PBDEs) Various

19 Tetrabromobisphenol A (TBBPA) 79-94-7

20 Bis(2,3-dibromopropyl) phosphate 5412-25-9

21 Hexabromocyclododecane (HBCDD) 3194-55-6

22 2,2-Bis(bromomethyl)-1,3-propanediol (BBMP) 3296-90-0

23 Chlorinated Flame Retardants

Tris(2-chloroethyl) phosphate (TCEP) 115-96-8

24 Tris(1,3-dichloro-isopropyl) phosphate (TDCP) 13674-87-8

25

Aromatic Amines in Azo Colorants

4-Aminodiphenyl (Biphenyl-4-ylamine or Xenylamine)

92-67-1

26 Benzidine 92-87-5

27 4-Chloro-o-toluidine 95-69-2

28 2-Naphthylamine 91-59-8

29 o-Aminoazotoluene (4-Amino-2`,3-dimethylazobenzne or 4-o-tolyazo-o-toluidine)

97-56-3

30 5-nitro-o-toluidine (2-Amino-4-nitrotoluene) 99-55-8

31 4-Chloroaniline (p-Chloroaniline) 106-47-8

32 4-Methoxy-m-phenylenediamine (2,4-Diaminoanisole)

615-05-4

Page 14: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 13 of 20

No. Chemical Groups Name of Analytes CAS-No.

33

Aromatic Amines in Azo Colorants

4,4`-Diaminodiphenylmethane (4,4`-Methylenedianiline)

101-77-9

34 3,3`-Dichlorobenzidine (3,3`-Dichlorobiphenyl-4,4`-ylenediamine)

91-94-1

35 3,3`-Dimethoxybenzidine (o-Dianisidine) 119-90-4

36 3,3`-Dimethylbenzidine (4,4`-Bi-o-tolidine) 119-93-7

37 4,4`-Methylenedi-o-toluidine (3,3`-Dimethyl- 4,4`-diaminodiphenylmethane)

838-88-0

38 p-Cresidine (6-Methoxy-m-toluidine) 120-71-8

39 4,4`-Methylene-bis-(2-chloraniline) (2,2`-Dichloro-4,4`-methylene-dianiline)

101-14-4

40 4,4`-Oxydianiline 101-80-4

41 4,4`-Thiodianiline 139-65-1

42 o-Toluidine (2-Aminotoluene) 95-53-4

43 4-Methyl-m-phenylenediamine (2,4-Toluenediamine)

95-80-7

44 2,4,5-Trimethylaniline 137-17-7

45 o-Anisidine (2-Methoxyaniline) 90-04-0

46 4-Aminoazobenzene (p-Aminoazobenzene) 60-09-3

47 2,4-Xylidine (2,4-dimethylaniline) 95-68-1

48 2,6-Xylidine (2,6-dimethylaniline) 87-62-7

49 Aniline 62-53-3

50

Organotin Compounds

Monobutyltin (MBT)

Various

51 Dibutyltin (DBT)

52 Dioctyltin (DOT)

53 Tributyltin (TBT)

54 Triphenyltin (TPhT)

55 Tricyclohexyltin (TCyHT)

56 Trioctyltin (TOT)

57 Tripropyltin (TPT)

58

Chlorobenzenes

Chlorobenzene 108-90-7

59 1,2-Dichlorobenzene 95-50-1

60 1,3-Dichlorobenzene, 1,4-Dichlorobenzene 541-73-1, 106-46-7

61 1,2,3-Trichlorobenzene 87-61-6

62 1,2,4-Trichlorobenzene 120-82-1

63 1,3,5-Trichlorobenzene 108-70-3

64 1,2,3,4-Tetrachlorobenzene 634-66-2

65 1,2,3,5-Tetrachlorobenzene, 1,2,4,5-Tetrachlorobenzene

634-90-2, 95-94-3

66 Pentachlorobenzene 608-93-5

67 Hexachlorobenzene 118-74-1

Page 15: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 14 of 20

No. Chemical Groups Name of Analytes CAS-No.

68

Chlorinated Solvents

1,2-Dichloroethane 107-06-2

69 1,1-Dichloroethylene 75-35-4

70 Methylene Chloride 75-09-2

71 cis-1,2-Dichloroethylene 156-59-2

72 trans-1,2-Dichloroethylene 156-60-5

73 Chloroform 67-66-3

74 1,1,1-Trichloroethane 71-55-6

75 Carbon Tetrachloride 56-23-5

76 Trichloroethylene 79-01-6

77 1,1,2-Trichloroethane 79-00-5

78 1,1,1,2-Tetrachloroethane 630-20-6

79 Tetrachloroethylene 127-18-4

80

Chlorophenols

Pentachlorophenol 87-86-5

81 2,3,4,5-Tetrachlorophenol 4901-51-3

82 2,3,4,6-Tetrachlorophenol 58-90-2

83 2,3,5,6-Tetrachlorophenol 935-95-5

84 2,4,6-Trichlorophenol 88-06-2

85 2,3,5-Trichlorophenol 933-78-8

86 2,4,5-Trichlorophenol 95-95-4

87 3,4,5-Trichlorophenol 609-19-8

88 2,3,4-Trichlorophenol 15950-66-0

89 2,3-Dichlorophenol 576-24-9

90 3,4-Dichlorophenol 95-77-2

91 2,4-Dichlorophenol 120-83-2,

92 2,5-Dichlorophenol 583-78-8,

93 2,6-Dichlorophenol 87-65-0,

94 3,5-Dichlorophenol 591-35-5

95 2-Chlorophenol 95-57-8

96 3-Chlorophenol 108-43-0

97 4-Chlorophenol 106-48-9

98 Short Chain Chlorinated Paraffins

Short Chain Chlorinated Paraffins 85535-84-8

Page 16: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 15 of 20

No. Chemical Groups Name of Analytes CAS-No.

99

Heavy Metals

Arsenic (As)

Various

100 Cadmium (Cd)

101 Mercury (Hg)

102 Lead (Pb)

103 Antimony (Sb)

104 Cobalt (Co)

105 Nickel (Ni)

106 Copper (Cu)

107 Zinc (Zn)

108 Chromium (Cr)

109 Manganese (Mn)

110 Chromium VI (Cr VI)

111 Cyanide (CN)

112

Alkylphenols & Alkylphenol Ethoxylates

Octylphenol (OP)

Various 113 Octylphenolethoxylates (OPEOs)

114 Nonylphenol (NP)

115 Nonylphenolethoxylates (NPEOs)

116

Perfluorinated Chemicals

Perfluorooctanoic acid (PFOA) 335-67-1

117 Perfluorooctane sulphonates (PFOS) 2795-39-3

118 Perfluoro-n-hexanoic acid (PFHxA) 307-24-4 6

119 Perfluorohexane sulphonates (PFHxS) 3871-99-6

120 Perfluorobutanoic acid (PFBA) 375-22-4

121 Perfluorobutane sulphonates (PFBS) 29420-49-3

Page 17: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 16 of 20

Appendix B: Standard procedure for environmental sampling

1) US EPA Guidelines – Regulatory monitoring and testing Water and wastewater sampling

2) Australia EPA (Victoria) Guideline – Sampling and Analysis of Waters, Wastewaters, Soils and Wastes.

3) ISO 5667-3, Water Quality – Sampling – Part 3: Guidance on the preservation and handling of water samples

4) ASTM D3976-92 (Reapproved 2010) – Standard Practice for preparation of Sediment Samples for Chemical Analysis.

Page 18: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 17 of 20

Ap

pe

nd

ix C

: N

um

be

r o

f fa

cto

rie

s t

ha

t th

e r

es

tric

ted

an

aly

tes

de

tec

ted

in

wa

ter

sa

mp

les

Page 19: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 18 of 20

Appendix D: Highest detected concentration of analytes in incoming water in

different countries Analytes Bangladesh China Cambodia India Indonesia

Butyl benzyl phthalate (BBP)

ND ND ND ND 0.002

Dibutyl phthalate (DBP)

ND ND 0.001 ND ND

Di-2-ethylhexyl phthalate (DEHP)

ND 0.0108 0.003 ND ND

Di-iso-butyl phthalate (DIBP)

ND 0.0034 0.001 ND ND

Chlorobenzene ND 0.00117 ND ND ND

1,2,4-Trichlorobenzene ND ND ND ND 0.00034

Methylene Chloride ND ND ND ND 0.272

Total Arsenic (As)

0.0013 0.00297 0.003 0.0017 0.004

Total Cadmium (Cd)

ND 0.00604 0.0004 0.0002 0.0004

Total Mercury (Hg)

ND ND 0.0006 ND 0.00025

Total Lead (Pb)

0.0067 0.00203 0.0132 0.0289 0.01

Total Antimony (Sb)

0.0011 0.0032 0.0138 ND 0.076

Total Cobalt (Co)

ND 0.00233 0.0033 ND 0.002

Total Nickel (Ni)

ND 0.0311 0.0606 0.0326 0.02

Total Copper (Cu)

0.0383 0.151 0.0108 0.0535 0.136

Total Zinc (Zn)

0.3846 0.504 0.342 0.47606 0.117

Total Chromium (Cr)

0.011 0.0297 ND ND 0.006

Total Manganese (Mn)

1.3754 0.376 ND 0.1102 0.474

Nonylphenol (NP)

ND 0.00212 ND ND 0.002

Nonylphenolethoxylates (NPEOs)

ND ND ND ND 0.015

Remarks:

ND: Not detected

Units: parts per million (ppm)

Page 20: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 19 of 20

Appendix E: Possible sources of detected chemicals in manufacturing

processes.4

Detected chemicals in discharged waste water

Possible sources

Azo Dyes 1) Used as colorants in dyes and pigments, such as Acid Dyes ,

Basic Dyes , Pigments, Reactive Dyes, Direct Dyes & Disperse

Dyes.

2) Act as polyurethane based cross linker/emulsions (2,4-

toulenediamine /4-methyl-m-phenylenediamine).

Heavy Metals 1) Present in metals or alloys, such as metal pipings in factory for

transporting raw water.

2) Present in metal complex dyestuffs, Fluro pigments, paints, & dye-

fixing agents.

3) The chemicals used in analysis for in house chemical tests, i.e.,

titrations (Mercuric sulphate / chloride, Potassium Dichromate)

4) Impurities from metal salts used in Effluent Treatment Plant (ETP)

and other activities

Alkylphenols (APs) & Alkylphenol Ethoxylates (APEOs)

1) Used in manufacturing of detergents, example soaping of dyed/

printed fabrics.

2) Used as emulsifying agent in pigment preparations and colorant

preparations

Chlorobenzenes 1) Used as solvent in dye industry, disinfectant, household toilet and

floor cleaners.

Chlorinated Solvents 1) Used in scouring

2) As Carriers for Disperse Dyeing

3) Removal of oil in machine / garments

4 The possible sources of each detected chemical groups listed in table are not claimed to be complete.

Page 21: H&M DISCHARGE DATA REPORT - Sustainability Reportingsustainability.hm.com/content/dam/hm/about... · H&M DISCHARGE DATA REPORT February 2014 . Page 1 of 20 ... India, and Bangladesh,

Page 20 of 20

Organotin Compounds 1) Mainly used as antifouling agents in liquid pigments or as a

fungicide.

Phthalates

1) Generally used as softener for plastics (plasticizers).

2) Present in print paste, plastisol ink, table gums for positional

printing.

3) Present in adhesives

Short Chain Chlorinated Paraffins (SCCPs)

1) Commonly present in oil based chemicals, e.g spinning /knitting

oil, de-dusting oils, or other types of industrial oils.

2) Present in spot removers, degreasing chemicals for printing mesh

cleaning / machinery, printing chemicals, & table gums.

Contact Detail:

H&M Hennes & Mauritz

AB:

Anna Eriksson

[email protected]