green chemistry shamjidha
TRANSCRIPT
WELCOM
E
GREEN CHEMISTRYwith
ZEOLITE CATALYST
Chemical industry has its share in polluting the environment and today it has realized that the time has come to make the industry more and more efficient not only in terms of profit and yield, but more accountable in terms of pollution abatement and eco-friendliness
This has led to term GREEN CHEMISTRY Traditionally,organic synthesis is highly
logical, but highly inefficient . This situation was allowed to continue mainly because
GREEN CHEMISTRY
ACHIEVMENTS IN GREEN CHEMISTRY Fuel cells for cellular phones Oxidation cracking process – formation ethylene
The synthesis of ibuprofen Safer marine antifouling compound “sea-nine”
Technology eliminating CFC
ZEOLITES
Zeolites are crystalline aluminosilicates with exchangeable cations
The cations can be exchanged with protons that make them acidic solids
Si:Al ratio can vary in zeolites from 1 to infinity No.of acidic sites decreases with increase in the
Si:Al ratio Strength of the acidic sites increases with the
Si:Al ratio There are also Lewis acid sites(tri-coordinated Al) They have micro-pores of entry port size varying
from about 3 to 12A
ZEOLITE STRUCTURE
Zeolites are formed by oxygen-sharing T(Si or Al) atoms, each T atom linked to four oxygen making tetrahedra
These tetrahedra are linked to form rings containing equal no. of oxygen and silicon atoms
The rings share common oxygen(or silicon) forming different polyhedra
The polyhedra then join by sharing common oxygen(or silicon) forming the three dimensional net work structure giving rise to pores
The pores may be all in one direction or many run in several directions
Zeolite pore structure
Reduction of atmospheric oxides of nitrogen(NOx)
Cutting emission of VOCsProcess improvements in CPI.
ZEOLITE ACCOMPLISHMENTS
IMPROVING ZEOLITE PERFORMANCE
CONCLUSION
SALMANUL FARISSRUTHY.K.PSHAMINISUFAIRASHAFEENAMUHAMMED ASLAM
PRESENTED BY,SHAMJITHA.C
Thank
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