green chemistry shamjidha

20
WELCOME

Upload: chemistrymespni

Post on 16-Apr-2017

820 views

Category:

Education


0 download

TRANSCRIPT

Page 1: Green chemistry shamjidha

WELCOM

E

Page 2: Green chemistry shamjidha

GREEN CHEMISTRYwith

ZEOLITE CATALYST

Page 3: Green chemistry shamjidha
Page 4: Green chemistry shamjidha

Chemical industry has its share in polluting the environment and today it has realized that the time has come to make the industry more and more efficient not only in terms of profit and yield, but more accountable in terms of pollution abatement and eco-friendliness

This has led to term GREEN CHEMISTRY Traditionally,organic synthesis is highly

logical, but highly inefficient . This situation was allowed to continue mainly because

GREEN CHEMISTRY

Page 5: Green chemistry shamjidha

ACHIEVMENTS IN GREEN CHEMISTRY Fuel cells for cellular phones Oxidation cracking process – formation ethylene

The synthesis of ibuprofen Safer marine antifouling compound “sea-nine”

Technology eliminating CFC

Page 6: Green chemistry shamjidha

ZEOLITES

Page 7: Green chemistry shamjidha

Zeolites are crystalline aluminosilicates with exchangeable cations

The cations can be exchanged with protons that make them acidic solids

Si:Al ratio can vary in zeolites from 1 to infinity No.of acidic sites decreases with increase in the

Si:Al ratio Strength of the acidic sites increases with the

Si:Al ratio There are also Lewis acid sites(tri-coordinated Al) They have micro-pores of entry port size varying

from about 3 to 12A

ZEOLITE STRUCTURE

Page 8: Green chemistry shamjidha

Zeolites are formed by oxygen-sharing T(Si or Al) atoms, each T atom linked to four oxygen making tetrahedra

These tetrahedra are linked to form rings containing equal no. of oxygen and silicon atoms

The rings share common oxygen(or silicon) forming different polyhedra

The polyhedra then join by sharing common oxygen(or silicon) forming the three dimensional net work structure giving rise to pores

The pores may be all in one direction or many run in several directions

Zeolite pore structure

Page 9: Green chemistry shamjidha
Page 10: Green chemistry shamjidha
Page 11: Green chemistry shamjidha
Page 12: Green chemistry shamjidha
Page 13: Green chemistry shamjidha
Page 14: Green chemistry shamjidha
Page 15: Green chemistry shamjidha
Page 16: Green chemistry shamjidha

Reduction of atmospheric oxides of nitrogen(NOx)

Cutting emission of VOCsProcess improvements in CPI.

ZEOLITE ACCOMPLISHMENTS

Page 17: Green chemistry shamjidha

IMPROVING ZEOLITE PERFORMANCE

Page 18: Green chemistry shamjidha

CONCLUSION

Page 19: Green chemistry shamjidha

SALMANUL FARISSRUTHY.K.PSHAMINISUFAIRASHAFEENAMUHAMMED ASLAM

PRESENTED BY,SHAMJITHA.C

Page 20: Green chemistry shamjidha

Thank

U