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Great Solutions with Small Particles

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Page 1: Great Solutions with Small Particles · PDF fileimpact resistance, are mechanically and chemically stable, and improve rheology. In the white-goods segment, Blanc Fixe crystals assist

Great Solutions with Small Particles

Page 2: Great Solutions with Small Particles · PDF fileimpact resistance, are mechanically and chemically stable, and improve rheology. In the white-goods segment, Blanc Fixe crystals assist

sachtleben and kemiraTwo experienced titanium dioxide specialists are pooling their activities: the modern

TiO2 plants operated by Sachtleben Chemie and Kemira Pigments will in future

run under unified management. The corresponding joint venture has been set up

by Rockwood Holdings Inc., of which Sachtleben is part, and Finland‘s Kemira Oyj

chemicals group.

known nameThe joint venture bears its own, independent, name: Sachtleben, a name which

stands for 130 years of experience, high-quality products and global awareness.

Customers of many years‘ standing know: you can trust Sachtleben‘s dependability

and performance. This is the tradition that provides the basis for the joint road into a

successful future.

economic benefits for customersSachtleben has strengthened its core capabilities. Its products and competent

services assure extra functions, process advantages and genuine economic benefits.

Sachtleben‘s product portfolio, which includes both titanium dioxide specialities and

inorganic functional additives, assures the company a unique ranking among the

world‘s pigment producers.

more:value

Page 3: Great Solutions with Small Particles · PDF fileimpact resistance, are mechanically and chemically stable, and improve rheology. In the white-goods segment, Blanc Fixe crystals assist

white pigments (TiO2)Anatase and rutile – Sachtleben supplies both of these titanium dioxide modifications.

These white pigments are nontoxic and offer absolutely no hazard to health. Anatase

TiO2 is the focus of production at Duisburg, Germany. The rutile pigments produced

at Pori, in Finland, complement the Duisburg range ideally. The pigment portfolio is

completed by a variety of nano-grade titanium dioxide products.

functional additives (BaSO4 and ZnS)The new company‘s product portfolio also includes inorganic functional additives along-

side the titanium-dioxide-based pigments. Sachtleben is the world‘s largest producer of

synthetic barium sulfate specialities (BaSO4) and also occupies a unique market ranking

in the field of zinc sulfide pigments (ZnS). These functional particles impart useful extra

properties to materials and products, assuring genuine competitive advantages for

Sachtleben customers.

broad range of applicationsTiO

2 particles and functional additives based on barium sulfate and zinc sulfide can be

used in a very broad and diverse range of applications. Sachtleben is a leading supplier

of anatase titanium dioxide to manufacturers of man-made fibers, provides innovative

products for the coatings, plastics and paper industry, and has a high-level presence

in the fields of nano-particle based and environmental products. This expertise is further

augmented with special particles for printing inks, for the cosmetics, pharmaceuticals

and foodstuffs industries and for catalysts. In addition to consistent product qual-

ity, Sachtleben also offers its customers comprehensive advisory and expert technical

services.

more:products

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*)duisburgporisachtlebenkemira

duisburg and poriIn future, Sachtleben will produce titanium dioxide via the sulfate route at two locations

in Europe: Duisburg, Germany, and Pori, Finland. Modern nanotechnology plants also

operate at both locations. These production activities are independent of one another

but complement each other ideally. Sachtleben is more than doubling its production

capacities.

greater assuredness of supplyCustomers around the globe will benefit from this expansion: siting production at two

high-performance European locations guarantees enhanced flexibility, even greater

assuredness of supply, and a broadened range of anatase and rutile specialities.

more:capacity

Page 5: Great Solutions with Small Particles · PDF fileimpact resistance, are mechanically and chemically stable, and improve rheology. In the white-goods segment, Blanc Fixe crystals assist

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more:know-how

130 years of traditionInnovation has a long tradition at Sachtleben, reaching back to the year 1878, when

the chemist Dr. Rudolf Sachtleben started development of Lithopone on the basis of

barium sulfate and zinc sulfide. The world‘s first durable ingredient for white paints and

coatings replaced toxic white lead and was considered the apogee of development work

in this field - a valuable and worthwhile achievement. Sachtleben‘s research activities

still enjoy international acclaim today.

concentrated know-howAs a dependable system partner for industry, Sachtleben develops tailor-made solutions

for products and applications jointly with its customers. The new cooperation between

the German and Finnish development departments boosts these capabilities yet again.

Sachtleben now intends to deploy the new concentrated know-how to further acceler-

ate progress in the field of inorganic pigments and to exploit it to achieve innovative

new products and applications. Sachtleben is thus opening up access to new and highly

attractive market segments for its customers.

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more:sustainability

responsible care and sustainable developmentSustainable economic management has become a synonym for the development of the

viable enterprise of the future, most especially in the chemicals industry, which is com-

mitted to the principles of Responsible Care and Sustainable Development. Sachtleben,

as a multinational, globally active company, implements this commitment everywhere, in

every detail.

three pillars in balanceSachtleben is careful to achieve a balance between the three pillars of sustainability.

Development and production of innovative products and intelligent solutions assure

economic growth. Ecological equilibrium achieved by the careful use of resources pro-

tects the environment; a good example of this is the waste-acid recycling plant, which

in 1989 made Sachtleben the first titanium dioxide producers to achieve 100% recycling.

Social progress means, for Sachtleben, assuring its employees‘ futures via continuous

further training, the provision of safe and attractive workplaces, and the implementation

of active industrial health and safety provisions.

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more:great solutions with small particles

a shared corporate cultureSachtleben exploits synergies and promotes knowledge-transfer in all sectors of its op-

erations, from Research & Development, via Production and Quality Control, up to and

including Logistics and Marketing. Day-to-day cooperation between 1,700 employees

in Germany and Finland is thus giving rise to a shared culture that does not attempt to

suppress differing viewpoints, but regards them, instead, as an enrichment of corporate

life.

new strengthBecause the challenges of global competition are growing, Sachtleben has also grown:

its product portfolio has been broadened, its production capacities expanded, corporate

know-how concentrated, and Sachtleben‘s presence on global markets intensified. The

international Sachtleben network includes personal contacts in more than sixty countries

around the globe. Sachtleben now possesses new strength, thus also strengthening

its customers, to whom Sachtleben will, in future, be able to offer even more – more:

Great Solutions with Small Particles.

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performance rutile and blanc fixe crystals for paints and coatingsModern coating systems combine high-level decorative and protection functions.

Sachtleben‘s Blanc Fixe (synthetic BaSO4) range of products optimizes the properties

of high-quality paints and coatings. These particles improve gloss values, enhance

impact resistance, are mechanically and chemically stable, and improve rheology. In

the white-goods segment, Blanc Fixe crystals assist in replacing up to 30 percent of

the titanium dioxide needed in powder-coating systems with ultra-low film thickness-

es, achieving top-quality hiding gloss with a simultaneous cut in production costs.

Sachtleben supplies the paints and coatings industry with rutile pigments possessing

excellent whiteness, high scattering power, good gloss values and outstanding resist-

ance to outdoor exposure, for practically all coating systems. Incorporation of these

products into such systems is straightforward, thanks to their good dispersibility.

high-effect nano-titanium dioxide pigmentsSachtleben‘s nano-titanium dioxide pigments permit the achievement of fascinating

optical effects, such as those of the so-called flip-flop finishes used on cars.

These tiny particles are also highly effective in transparent wood protection products

and as a dependable UV barrier in plastics and lacquers. Synthetic barium sulfate

nanoparticles in high-end coatings are also a convincing example of both quality and

cost-efficiency.

coatings

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matting with hombitan anatase microcrystalsAs an experienced system partner, Sachtleben develops functional products for the

man-made fibers industry, and occupies a pole position globally in high-quality

Hombitan anatase microcrystals for delustration of synthetic fibers. These top-quality

microcrystals are notable for their excellent whiteness, high opacity, minimal abra-

sion, extremely good dispersibility and uniform distribution in the body of the fiber.

They improve the fibers‘ UV stability and prevent discoloration of the polymer.

uv protection with nano-additivesSachtleben also supplies special additives for the production of gloss fibers and for

enhanced UV protection as well as nano-additives that achieve permanent UV block-

ing and are thus particularly kind to the skin and, in addition, chemically stable.

antiblocking particles for transparent filmsSachtleben has set new technological standards with its innovative antiblocking

concept for the films segment. These specially designed particles provide transparent

films with high gloss and assure maximum process dependability.

fibers and film

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paper

pigments for refined surfacesPaper is a centuries old cultural asset that remains indispensable even in the multi-

media age. Sachtleben supplies suitable TiO2 and BaSO

4 products for use in both the

pulp and/or the coating of high-quality papers and boards. Research has now opened

up outstanding application potentials for synthetic barium sulfate particles, such as

the barytes coating of extra fine photographic papers to assure high-gloss surfaces

and brilliant colours.

barium sulfate additives for enhanced efficiencyA new barium-sulfate-based additive for paper produces clear benefits for high-qual-

ity coated boards (for use in foodstuffs packaging systems, for example): printability

is improved significantly, gloss and colour brilliance are enhanced, and production

costs significantly reduced simultaneously.

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11

high-purity rutile and anatase basesOf the large range of inorganic products made by Sachtleben, titanium dioxide, in

particular, is especially suitable for applications in catalysis. The sulfate route offers

opportunities to systematically obtain high-purity rutile and anatase bases, the

chemical and physical properties of which can be individually adjusted within broad

limits.

active in heterogeneous and photocatalysisSachtleben‘s titanium dioxide demonstrates its capabilities both in heterogene-

ous catalysis and as a photocatalyst. In the catalytic converter systems installed in

motor-vehicles and power plants, titanium dioxide particles assist in the exhaust-gas

cleaning (DeNOx) process. Micro and nanoparticles also show their special capabili-

ties in waste-water treatment. In plasters and paints, their photocatalytic properties

assure proactive prevention of room-air pollution. Active materials supplied by

Sachtleben are also in successful use for the synthesis of enzymes and of complex

organic molecules.

products containing iron for blast furnacesSachtleben developed Sachtleben developed high-fineness titanium-containing

synthetic additives for the steel industry; this iron/titanium compound

significantly prolongs blast furnace campaigns – another high-efficiency solution

„made by Sachtleben“.

active materials

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pharmaceuticals / cosmetics / foodstuffs

titanium dioxide of high chemical puritySachtleben‘s titanium dioxide meets the requirements of all the main international

pharmacopoeias and is thus an indispensable additive for the pharmaceuticals and

cosmetics industries. These pigments are used in tablet coatings and assure radiant

whiteness and attractive colorations in toothpastes. X-ray barytes based on pure

synthetic barium sulfate serve as the high-quality basis for the production of X-ray

contrast agents and medical plastics.

state-of-the-art UV-A and UV-B absorbersModern sun-blocker products would be inconceivable without the highly effective

protection provided by UV filters based on ultrafine mineral titanium dioxide particles.

Many people‘s increased awareness of the need for protection against shortwave UV

radiation is, in addition, also opening up new applications in cosmetics for everyday

use. State-of-the-art UV-A and UV-B absorbers are now available, in the form of the

diverse Sachtleben product range.

kosher and halal certificated Sachtleben developed products specifically for the foodstuffs industry. High-purity

titanium dioxide anatase grades meet the requirements of E 171 and the FDA (Food

Additives Ordinance/Tobacco Ordinance) and also have Kosher and Halal certification.

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13

plastics

additives for optimum product properties Sachtleben pigments are used in a large and diverse range of applications in the plas-

tics industry. Inorganic additives assist, for example, in the production of UV-barrier

films and durable window systems. Sachtleben additives are also ideal for mechanical

stability, and optimize the impact and bending strength of plastic products.

tailor-made solutions for modern materialsZinc sulfide specialities are soft and white, and are therefore ideal where mechani-

cal loadings are particularly high. They are used primarily in glass-fiber-reinforced

plastics (GRPs). In elastomers and compounds, particles from Sachtleben are incorpo-

rated into temperature-resistant seals and technical components, in the automotive

field, for example. Tailor-made solutions are also available to all customers for use in

composites and polyvinyl chloride.

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packaging and printing inks

TiO2 specialities for optimum hiding powerSachtleben supplies highly visible benefits for the packaging and printing-ink

industries - the special attraction of the packaging, and the recognizability of the

brand, depend very largely on the printing ink used. Titanium dioxide is the most

commonly used white pigment for production of packaging and printing inks, due to

its optimum hiding power. Sachtleben‘s TiO2 specialities guarantee optimum opacity

and gloss, combined with excellent dispersibility, improving both productivity and

quality. In addition, the soft titanium dioxide white pigments assure low abrasiveness.

diverse applications in the printing industrySachtleben‘s titanium dioxide pigments are the result of many years of experience

and provide a unique diversity of particles and variations. They ensure that both flex-

ible films and metal, paper and board packaging systems can be optimally printed.

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environmental products

products containing iron for water and cement The purification of both drinking water and waste water is an important field of

application for Sachtleben‘s environmental products. Ferric (III)sulfate is used as an

economic and effective flocculant to eliminate ultrafine suspended matter.

Sachtleben‘s SachtoFer products improve the hydraulic setting performance and

sulfate-resistance of cements. The ferrous (II) sulfate salts supplied by Sachtleben

enable the cement industry to reduce the toxic hexavalent chromium content of its

products and minimize health risks associated with the use of cement.

Great Solutions with Small Particles. Sachtleben.

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61°34‘49“N

21°33‘28“E

pori / finland

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51° 26‘ 35“N

6° 42‘ 24“ E

more:sachtleben

duisburg / germany

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Great Solutions with Small Particles

Sachtleben Chemie GmbH • P.O. Box 17 04 54 • D-47184 Duisburg/Germany Phone: +49 2066 22-0 • Fax +49 2066 22-2000 • [email protected] Sachtleben Pigments Oy • Titaanitie • FIN-28840 Pori, Finland • www.sachtleben.com

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Product Information

Sachtleben Pigments Oy A company of Holdings, Inc. Titaanitie • FI-28840 Pori / Finland E-Mail: [email protected] • www.sachtleben.com

R40

5

Classification ISO 591, DIN 55912 R2

CAS no. (TiO2) 13463-67-7

ASTM D476 II

EINECS no. (TiO2) 2366755

Colour Index 77891

Components listed in TSCA, EINECS

Pigment White 6

Plastics

Sales Office Plastics: Phone +49 2066 22 2671 E-Mail: [email protected]

Great Solutions with Small Particles

SACHTLEBEN R405

SACHTLEBEN R405 is alumina surface treated,

hydrophobic titanium dioxide pigment with

fast and excellent dispersibility in various plas-

tics in dry processing as well as in normally

used liquid plasticizers. As a result of its fine

crystal and particle sizes SACHTLEBEN R405

belongs to the family of blue undertone plas-

tics grades.

SACHTLEBEN R405 is particularly recommend-

ed for systems where fineness of pigment

dispersion in plastics is top priority: plasti-

cized PVC, polyolefins, styrenics, engineering

plastics and thermosets. It can also be used in

rubber and linoleum.

Typical properties

Refractive index 2.7

Relative tint reducing power 1800

Oil absorption [g/100 g pigment] 19

TiO2 content [%] min 96

Surface treatment Al2O

3, organic

pH 7 – 8

Moisture when packed [%] max 0.4

Sieve residue (325 mesh) [%] max 0.01

Crystal size (mean) [nm] approx. 190

Specific gravity [g/cm3] 4.1

Bulk density [kg/m3] 900

Bulk density (tamped) [kg/m3] 1000

SACHTLEBEN R405 enables the manufacture of

highly pigmented concentrates, e.g. 70% DOP

dispersions and polyolefin masterbatches.

The manufacture of Sachtleben products is with-

in the scope of the ISO 9001 certified Quality

Management System. The Pori plant also has

an ISO 14001 certified Environmental Manage-

ment System.

Safety PrecautionsPlease see the Material Safety Data Sheet

before handling the material.

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Great Solutions with Small Particles

R 62

0 K

Plastics

Sales Office Plastics: Phone +49 2066 22 - 2671 E-Mail: [email protected]

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The productMicronized white pigment on a titanium diox-

ide (Rutile) basis, inorganically and organically

coated.

Typical properties High lightening power

Extremely good dispersibility

Excellent resistance to light and

outdoor exposure

ApplicationsSAchtlEbEn R 620 K is extremely well suited for

all plastics. Due to its high resistance to outdoor

exposure, it is used in particular in products for

outdoor use, such as window-profiles, PVc and

polyolefin films, etc.

SACHTLEBEN R 620 K

Product Information

StorageKeep the product unstacked in dry and closed

rooms at normal temperature and air humidity.

to achieve best possible results, we recommend

storage under the conditions stated above and

use within 12 months from delivery.

Sachtleben chemie Gmbh A company of holdings, Inc. P.O. Box 17 04 54 • D-47184 Duisburg / Germany E-Mail: [email protected] • www.sachtleben.de

Technical data

titanium dioxide classification DIn 55912 t1 R2

color index c.I. 77891, Pigment white 6

tiO2 [%] c 101101 A approx. 90

Surface treatment Al2O

3, SiO

2, organic

Density [g/ml] DIN EN ISO 787, Part 10 approx. 4.2

Rel. lightening power1) [%] h 562 approx. 90

Fineness of grind in DOP2) [µm] Sc 2007 < 20

1) PVc-P 2) White paste in DOP

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Coatings Paper Plastics

Product Information

Sachtleben Pigments Oy A company of Holdings, Inc. Titaanitie • FI-28840 Pori / Finland E-Mail: [email protected] • www.sachtleben.com

Sales Office Plastics: Phone +49 2066 22 2671 E-Mail: [email protected] Sales Office Coatings: Phone +358 10 430 1000 E-Mail: [email protected] Sales Office Paper: Phone +49 2066 22 2609 E-Mail: [email protected]

R66

0

Classification ISO 591, DIN 55912 R2

CAS no. (TiO2) 13463-67-7

ASTM D476 II, IV

EINECS no. (TiO2) 2366755

Colour Index 77891

Components listed in TSCA, EINECS

Pigment White 6

The manufacture of Sachtleben products is with-

in the scope of the ISO 9001 certified Quality

Management System. The Pori plant also has

an ISO 14001 certified Environmental Manage-

ment System.

Great Solutions with Small Particles

SACHTLEBEN R660

Safety PrecautionsPlease see the Material Safety Data Sheet

before handling the material.

SACHTLEBEN R660 TiO2 pigment belongs to a

group of modern alumina-silica-polyol surface

treated multipurpose rutile grades. It has high

outdoor durability, excellent dispersibility and

very good optical properties such as bluish

clean undertone, gloss and opacity.

Fast wetting and easy dispersibility perform-

ance of SACHTLEBEN R660 makes it an ideal

multipurpose grade for paint production by a

high speed dissolver alone or by a combina-

tion of HSD and a bead mill.

Typical properties

Refractive index 2.7

Relative tint reducing power 1850

Oil absorption [g/100 g pigment] 21

TiO2 content [%] min 93

Surface treatment Al2O

3-SiO

2, organic

pH 7.6 – 8.6

Moisture when packed [%] max 0.4

Sieve residue (325 mesh) [%] max 0.01

Crystal size (mean) [nm] approx. 220

Specific gravity [g/cm3] 4.0

Bulk density [kg/m3] 800

Bulk density (tamped) [kg/m3] 1000

As SACHTLEBEN R660 is a multipurpose grade

it is recommended equally to decorative and

industrial coatings, solvent and water-based

systems. It can also be used in paper coatings,

PVC and polyolefin plastics.