great solutions with small particles · pdf fileimpact resistance, are mechanically and...
TRANSCRIPT
Great Solutions with Small Particles
sachtleben and kemiraTwo experienced titanium dioxide specialists are pooling their activities: the modern
TiO2 plants operated by Sachtleben Chemie and Kemira Pigments will in future
run under unified management. The corresponding joint venture has been set up
by Rockwood Holdings Inc., of which Sachtleben is part, and Finland‘s Kemira Oyj
chemicals group.
known nameThe joint venture bears its own, independent, name: Sachtleben, a name which
stands for 130 years of experience, high-quality products and global awareness.
Customers of many years‘ standing know: you can trust Sachtleben‘s dependability
and performance. This is the tradition that provides the basis for the joint road into a
successful future.
economic benefits for customersSachtleben has strengthened its core capabilities. Its products and competent
services assure extra functions, process advantages and genuine economic benefits.
Sachtleben‘s product portfolio, which includes both titanium dioxide specialities and
inorganic functional additives, assures the company a unique ranking among the
world‘s pigment producers.
more:value
white pigments (TiO2)Anatase and rutile – Sachtleben supplies both of these titanium dioxide modifications.
These white pigments are nontoxic and offer absolutely no hazard to health. Anatase
TiO2 is the focus of production at Duisburg, Germany. The rutile pigments produced
at Pori, in Finland, complement the Duisburg range ideally. The pigment portfolio is
completed by a variety of nano-grade titanium dioxide products.
functional additives (BaSO4 and ZnS)The new company‘s product portfolio also includes inorganic functional additives along-
side the titanium-dioxide-based pigments. Sachtleben is the world‘s largest producer of
synthetic barium sulfate specialities (BaSO4) and also occupies a unique market ranking
in the field of zinc sulfide pigments (ZnS). These functional particles impart useful extra
properties to materials and products, assuring genuine competitive advantages for
Sachtleben customers.
broad range of applicationsTiO
2 particles and functional additives based on barium sulfate and zinc sulfide can be
used in a very broad and diverse range of applications. Sachtleben is a leading supplier
of anatase titanium dioxide to manufacturers of man-made fibers, provides innovative
products for the coatings, plastics and paper industry, and has a high-level presence
in the fields of nano-particle based and environmental products. This expertise is further
augmented with special particles for printing inks, for the cosmetics, pharmaceuticals
and foodstuffs industries and for catalysts. In addition to consistent product qual-
ity, Sachtleben also offers its customers comprehensive advisory and expert technical
services.
more:products
4
*)duisburgporisachtlebenkemira
duisburg and poriIn future, Sachtleben will produce titanium dioxide via the sulfate route at two locations
in Europe: Duisburg, Germany, and Pori, Finland. Modern nanotechnology plants also
operate at both locations. These production activities are independent of one another
but complement each other ideally. Sachtleben is more than doubling its production
capacities.
greater assuredness of supplyCustomers around the globe will benefit from this expansion: siting production at two
high-performance European locations guarantees enhanced flexibility, even greater
assuredness of supply, and a broadened range of anatase and rutile specialities.
more:capacity
5
more:know-how
130 years of traditionInnovation has a long tradition at Sachtleben, reaching back to the year 1878, when
the chemist Dr. Rudolf Sachtleben started development of Lithopone on the basis of
barium sulfate and zinc sulfide. The world‘s first durable ingredient for white paints and
coatings replaced toxic white lead and was considered the apogee of development work
in this field - a valuable and worthwhile achievement. Sachtleben‘s research activities
still enjoy international acclaim today.
concentrated know-howAs a dependable system partner for industry, Sachtleben develops tailor-made solutions
for products and applications jointly with its customers. The new cooperation between
the German and Finnish development departments boosts these capabilities yet again.
Sachtleben now intends to deploy the new concentrated know-how to further acceler-
ate progress in the field of inorganic pigments and to exploit it to achieve innovative
new products and applications. Sachtleben is thus opening up access to new and highly
attractive market segments for its customers.
6
more:sustainability
responsible care and sustainable developmentSustainable economic management has become a synonym for the development of the
viable enterprise of the future, most especially in the chemicals industry, which is com-
mitted to the principles of Responsible Care and Sustainable Development. Sachtleben,
as a multinational, globally active company, implements this commitment everywhere, in
every detail.
three pillars in balanceSachtleben is careful to achieve a balance between the three pillars of sustainability.
Development and production of innovative products and intelligent solutions assure
economic growth. Ecological equilibrium achieved by the careful use of resources pro-
tects the environment; a good example of this is the waste-acid recycling plant, which
in 1989 made Sachtleben the first titanium dioxide producers to achieve 100% recycling.
Social progress means, for Sachtleben, assuring its employees‘ futures via continuous
further training, the provision of safe and attractive workplaces, and the implementation
of active industrial health and safety provisions.
7
more:great solutions with small particles
a shared corporate cultureSachtleben exploits synergies and promotes knowledge-transfer in all sectors of its op-
erations, from Research & Development, via Production and Quality Control, up to and
including Logistics and Marketing. Day-to-day cooperation between 1,700 employees
in Germany and Finland is thus giving rise to a shared culture that does not attempt to
suppress differing viewpoints, but regards them, instead, as an enrichment of corporate
life.
new strengthBecause the challenges of global competition are growing, Sachtleben has also grown:
its product portfolio has been broadened, its production capacities expanded, corporate
know-how concentrated, and Sachtleben‘s presence on global markets intensified. The
international Sachtleben network includes personal contacts in more than sixty countries
around the globe. Sachtleben now possesses new strength, thus also strengthening
its customers, to whom Sachtleben will, in future, be able to offer even more – more:
Great Solutions with Small Particles.
8
performance rutile and blanc fixe crystals for paints and coatingsModern coating systems combine high-level decorative and protection functions.
Sachtleben‘s Blanc Fixe (synthetic BaSO4) range of products optimizes the properties
of high-quality paints and coatings. These particles improve gloss values, enhance
impact resistance, are mechanically and chemically stable, and improve rheology. In
the white-goods segment, Blanc Fixe crystals assist in replacing up to 30 percent of
the titanium dioxide needed in powder-coating systems with ultra-low film thickness-
es, achieving top-quality hiding gloss with a simultaneous cut in production costs.
Sachtleben supplies the paints and coatings industry with rutile pigments possessing
excellent whiteness, high scattering power, good gloss values and outstanding resist-
ance to outdoor exposure, for practically all coating systems. Incorporation of these
products into such systems is straightforward, thanks to their good dispersibility.
high-effect nano-titanium dioxide pigmentsSachtleben‘s nano-titanium dioxide pigments permit the achievement of fascinating
optical effects, such as those of the so-called flip-flop finishes used on cars.
These tiny particles are also highly effective in transparent wood protection products
and as a dependable UV barrier in plastics and lacquers. Synthetic barium sulfate
nanoparticles in high-end coatings are also a convincing example of both quality and
cost-efficiency.
coatings
9
matting with hombitan anatase microcrystalsAs an experienced system partner, Sachtleben develops functional products for the
man-made fibers industry, and occupies a pole position globally in high-quality
Hombitan anatase microcrystals for delustration of synthetic fibers. These top-quality
microcrystals are notable for their excellent whiteness, high opacity, minimal abra-
sion, extremely good dispersibility and uniform distribution in the body of the fiber.
They improve the fibers‘ UV stability and prevent discoloration of the polymer.
uv protection with nano-additivesSachtleben also supplies special additives for the production of gloss fibers and for
enhanced UV protection as well as nano-additives that achieve permanent UV block-
ing and are thus particularly kind to the skin and, in addition, chemically stable.
antiblocking particles for transparent filmsSachtleben has set new technological standards with its innovative antiblocking
concept for the films segment. These specially designed particles provide transparent
films with high gloss and assure maximum process dependability.
fibers and film
10
paper
pigments for refined surfacesPaper is a centuries old cultural asset that remains indispensable even in the multi-
media age. Sachtleben supplies suitable TiO2 and BaSO
4 products for use in both the
pulp and/or the coating of high-quality papers and boards. Research has now opened
up outstanding application potentials for synthetic barium sulfate particles, such as
the barytes coating of extra fine photographic papers to assure high-gloss surfaces
and brilliant colours.
barium sulfate additives for enhanced efficiencyA new barium-sulfate-based additive for paper produces clear benefits for high-qual-
ity coated boards (for use in foodstuffs packaging systems, for example): printability
is improved significantly, gloss and colour brilliance are enhanced, and production
costs significantly reduced simultaneously.
11
high-purity rutile and anatase basesOf the large range of inorganic products made by Sachtleben, titanium dioxide, in
particular, is especially suitable for applications in catalysis. The sulfate route offers
opportunities to systematically obtain high-purity rutile and anatase bases, the
chemical and physical properties of which can be individually adjusted within broad
limits.
active in heterogeneous and photocatalysisSachtleben‘s titanium dioxide demonstrates its capabilities both in heterogene-
ous catalysis and as a photocatalyst. In the catalytic converter systems installed in
motor-vehicles and power plants, titanium dioxide particles assist in the exhaust-gas
cleaning (DeNOx) process. Micro and nanoparticles also show their special capabili-
ties in waste-water treatment. In plasters and paints, their photocatalytic properties
assure proactive prevention of room-air pollution. Active materials supplied by
Sachtleben are also in successful use for the synthesis of enzymes and of complex
organic molecules.
products containing iron for blast furnacesSachtleben developed Sachtleben developed high-fineness titanium-containing
synthetic additives for the steel industry; this iron/titanium compound
significantly prolongs blast furnace campaigns – another high-efficiency solution
„made by Sachtleben“.
active materials
12
pharmaceuticals / cosmetics / foodstuffs
titanium dioxide of high chemical puritySachtleben‘s titanium dioxide meets the requirements of all the main international
pharmacopoeias and is thus an indispensable additive for the pharmaceuticals and
cosmetics industries. These pigments are used in tablet coatings and assure radiant
whiteness and attractive colorations in toothpastes. X-ray barytes based on pure
synthetic barium sulfate serve as the high-quality basis for the production of X-ray
contrast agents and medical plastics.
state-of-the-art UV-A and UV-B absorbersModern sun-blocker products would be inconceivable without the highly effective
protection provided by UV filters based on ultrafine mineral titanium dioxide particles.
Many people‘s increased awareness of the need for protection against shortwave UV
radiation is, in addition, also opening up new applications in cosmetics for everyday
use. State-of-the-art UV-A and UV-B absorbers are now available, in the form of the
diverse Sachtleben product range.
kosher and halal certificated Sachtleben developed products specifically for the foodstuffs industry. High-purity
titanium dioxide anatase grades meet the requirements of E 171 and the FDA (Food
Additives Ordinance/Tobacco Ordinance) and also have Kosher and Halal certification.
13
plastics
additives for optimum product properties Sachtleben pigments are used in a large and diverse range of applications in the plas-
tics industry. Inorganic additives assist, for example, in the production of UV-barrier
films and durable window systems. Sachtleben additives are also ideal for mechanical
stability, and optimize the impact and bending strength of plastic products.
tailor-made solutions for modern materialsZinc sulfide specialities are soft and white, and are therefore ideal where mechani-
cal loadings are particularly high. They are used primarily in glass-fiber-reinforced
plastics (GRPs). In elastomers and compounds, particles from Sachtleben are incorpo-
rated into temperature-resistant seals and technical components, in the automotive
field, for example. Tailor-made solutions are also available to all customers for use in
composites and polyvinyl chloride.
14
packaging and printing inks
TiO2 specialities for optimum hiding powerSachtleben supplies highly visible benefits for the packaging and printing-ink
industries - the special attraction of the packaging, and the recognizability of the
brand, depend very largely on the printing ink used. Titanium dioxide is the most
commonly used white pigment for production of packaging and printing inks, due to
its optimum hiding power. Sachtleben‘s TiO2 specialities guarantee optimum opacity
and gloss, combined with excellent dispersibility, improving both productivity and
quality. In addition, the soft titanium dioxide white pigments assure low abrasiveness.
diverse applications in the printing industrySachtleben‘s titanium dioxide pigments are the result of many years of experience
and provide a unique diversity of particles and variations. They ensure that both flex-
ible films and metal, paper and board packaging systems can be optimally printed.
15
environmental products
products containing iron for water and cement The purification of both drinking water and waste water is an important field of
application for Sachtleben‘s environmental products. Ferric (III)sulfate is used as an
economic and effective flocculant to eliminate ultrafine suspended matter.
Sachtleben‘s SachtoFer products improve the hydraulic setting performance and
sulfate-resistance of cements. The ferrous (II) sulfate salts supplied by Sachtleben
enable the cement industry to reduce the toxic hexavalent chromium content of its
products and minimize health risks associated with the use of cement.
Great Solutions with Small Particles. Sachtleben.
16
61°34‘49“N
21°33‘28“E
pori / finland
17
51° 26‘ 35“N
6° 42‘ 24“ E
more:sachtleben
duisburg / germany
Great Solutions with Small Particles
Sachtleben Chemie GmbH • P.O. Box 17 04 54 • D-47184 Duisburg/Germany Phone: +49 2066 22-0 • Fax +49 2066 22-2000 • [email protected] Sachtleben Pigments Oy • Titaanitie • FIN-28840 Pori, Finland • www.sachtleben.com
06
.00
2.0
9.0
8.e
Sa
chtl
eben
do
es n
ot
gu
aran
tee
the
accu
racy
, to
pic
alit
y, c
orr
ectn
ess,
co
mp
lete
nes
s, q
ual
ity
or
use
fuln
ess
of
any
info
rmat
ion
pro
vid
ed.
An
y lia
bili
ty c
laim
s in
co
nn
ecti
on
wit
h s
uch
info
rmat
ion
are
exc
lud
ed.
04
.11
1.0
1.0
9.e
Sa
chtl
eben
do
es n
ot
gu
aran
tee
the
accu
racy
, to
pic
alit
y, c
orr
ectn
ess,
co
mp
lete
nes
s, q
ual
ity
or
use
fuln
ess
of
any
info
rmat
ion
pro
vid
ed.
A
ny
liab
ility
cla
ims
in c
on
nec
tio
n w
ith
su
ch in
form
atio
n a
re e
xclu
ded
.
Product Information
Sachtleben Pigments Oy A company of Holdings, Inc. Titaanitie • FI-28840 Pori / Finland E-Mail: [email protected] • www.sachtleben.com
R40
5
Classification ISO 591, DIN 55912 R2
CAS no. (TiO2) 13463-67-7
ASTM D476 II
EINECS no. (TiO2) 2366755
Colour Index 77891
Components listed in TSCA, EINECS
Pigment White 6
Plastics
Sales Office Plastics: Phone +49 2066 22 2671 E-Mail: [email protected]
Great Solutions with Small Particles
SACHTLEBEN R405
SACHTLEBEN R405 is alumina surface treated,
hydrophobic titanium dioxide pigment with
fast and excellent dispersibility in various plas-
tics in dry processing as well as in normally
used liquid plasticizers. As a result of its fine
crystal and particle sizes SACHTLEBEN R405
belongs to the family of blue undertone plas-
tics grades.
SACHTLEBEN R405 is particularly recommend-
ed for systems where fineness of pigment
dispersion in plastics is top priority: plasti-
cized PVC, polyolefins, styrenics, engineering
plastics and thermosets. It can also be used in
rubber and linoleum.
Typical properties
Refractive index 2.7
Relative tint reducing power 1800
Oil absorption [g/100 g pigment] 19
TiO2 content [%] min 96
Surface treatment Al2O
3, organic
pH 7 – 8
Moisture when packed [%] max 0.4
Sieve residue (325 mesh) [%] max 0.01
Crystal size (mean) [nm] approx. 190
Specific gravity [g/cm3] 4.1
Bulk density [kg/m3] 900
Bulk density (tamped) [kg/m3] 1000
SACHTLEBEN R405 enables the manufacture of
highly pigmented concentrates, e.g. 70% DOP
dispersions and polyolefin masterbatches.
The manufacture of Sachtleben products is with-
in the scope of the ISO 9001 certified Quality
Management System. The Pori plant also has
an ISO 14001 certified Environmental Manage-
ment System.
Safety PrecautionsPlease see the Material Safety Data Sheet
before handling the material.
Great Solutions with Small Particles
R 62
0 K
Plastics
Sales Office Plastics: Phone +49 2066 22 - 2671 E-Mail: [email protected]
04
.08
7.0
5.0
9.e
Sa
chtl
eben
do
es n
ot
gu
aran
tee
the
accu
racy
, to
pic
alit
y, c
orr
ectn
ess,
co
mp
lete
nes
s, q
ual
ity
or
use
fuln
ess
of
any
info
rmat
ion
pro
vid
ed.
An
y lia
bili
ty c
laim
s in
co
nn
ecti
on
wit
h s
uch
info
rmat
ion
are
exc
lud
ed.
The productMicronized white pigment on a titanium diox-
ide (Rutile) basis, inorganically and organically
coated.
Typical properties High lightening power
Extremely good dispersibility
Excellent resistance to light and
outdoor exposure
ApplicationsSAchtlEbEn R 620 K is extremely well suited for
all plastics. Due to its high resistance to outdoor
exposure, it is used in particular in products for
outdoor use, such as window-profiles, PVc and
polyolefin films, etc.
SACHTLEBEN R 620 K
Product Information
StorageKeep the product unstacked in dry and closed
rooms at normal temperature and air humidity.
to achieve best possible results, we recommend
storage under the conditions stated above and
use within 12 months from delivery.
Sachtleben chemie Gmbh A company of holdings, Inc. P.O. Box 17 04 54 • D-47184 Duisburg / Germany E-Mail: [email protected] • www.sachtleben.de
Technical data
titanium dioxide classification DIn 55912 t1 R2
color index c.I. 77891, Pigment white 6
tiO2 [%] c 101101 A approx. 90
Surface treatment Al2O
3, SiO
2, organic
Density [g/ml] DIN EN ISO 787, Part 10 approx. 4.2
Rel. lightening power1) [%] h 562 approx. 90
Fineness of grind in DOP2) [µm] Sc 2007 < 20
1) PVc-P 2) White paste in DOP
04
.11
3.0
1.0
9.e
Sa
chtl
eben
do
es n
ot
gu
aran
tee
the
accu
racy
, to
pic
alit
y, c
orr
ectn
ess,
co
mp
lete
nes
s, q
ual
ity
or
use
fuln
ess
of
any
info
rmat
ion
pro
vid
ed.
A
ny
liab
ility
cla
ims
in c
on
nec
tio
n w
ith
su
ch in
form
atio
n a
re e
xclu
ded
.
Coatings Paper Plastics
Product Information
Sachtleben Pigments Oy A company of Holdings, Inc. Titaanitie • FI-28840 Pori / Finland E-Mail: [email protected] • www.sachtleben.com
Sales Office Plastics: Phone +49 2066 22 2671 E-Mail: [email protected] Sales Office Coatings: Phone +358 10 430 1000 E-Mail: [email protected] Sales Office Paper: Phone +49 2066 22 2609 E-Mail: [email protected]
R66
0
Classification ISO 591, DIN 55912 R2
CAS no. (TiO2) 13463-67-7
ASTM D476 II, IV
EINECS no. (TiO2) 2366755
Colour Index 77891
Components listed in TSCA, EINECS
Pigment White 6
The manufacture of Sachtleben products is with-
in the scope of the ISO 9001 certified Quality
Management System. The Pori plant also has
an ISO 14001 certified Environmental Manage-
ment System.
Great Solutions with Small Particles
SACHTLEBEN R660
Safety PrecautionsPlease see the Material Safety Data Sheet
before handling the material.
SACHTLEBEN R660 TiO2 pigment belongs to a
group of modern alumina-silica-polyol surface
treated multipurpose rutile grades. It has high
outdoor durability, excellent dispersibility and
very good optical properties such as bluish
clean undertone, gloss and opacity.
Fast wetting and easy dispersibility perform-
ance of SACHTLEBEN R660 makes it an ideal
multipurpose grade for paint production by a
high speed dissolver alone or by a combina-
tion of HSD and a bead mill.
Typical properties
Refractive index 2.7
Relative tint reducing power 1850
Oil absorption [g/100 g pigment] 21
TiO2 content [%] min 93
Surface treatment Al2O
3-SiO
2, organic
pH 7.6 – 8.6
Moisture when packed [%] max 0.4
Sieve residue (325 mesh) [%] max 0.01
Crystal size (mean) [nm] approx. 220
Specific gravity [g/cm3] 4.0
Bulk density [kg/m3] 800
Bulk density (tamped) [kg/m3] 1000
As SACHTLEBEN R660 is a multipurpose grade
it is recommended equally to decorative and
industrial coatings, solvent and water-based
systems. It can also be used in paper coatings,
PVC and polyolefin plastics.