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Gasification Technologies Concepts for clean, economic fuel and energy production Rhys Tucker, Principal Process Engineer 5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012 Leipzig, Germany, 21 - 24 May 2012

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Page 1: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification TechnologiesConcepts for clean, economic fuel and energyproduction

Rhys Tucker, Principal Process Engineer

5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany,21 - 24 May 2012

Page 2: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

World‘s largest single-train IGCC: PRENFLO GasificationElcogas, Puertollano, Spain

Feedstock: petcoke / coal with addition of biomass

PRENFLO Gasifier

Gas Treatment

Coal PreparationASU

CombinedCycle

New CO2 capturePilot Plant started-up

Oct 2010

Page 3: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Agenda

� Company

� Gasification Portfolio

� Joint Venture Kepco-Uhde

� Concepts & Projects/Plants

Page 4: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Facts and figures 2010/2011

1921 Friedrich Uhde engineering firm, Dortmund

1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG

1996 Acquisition of Uhde by Krupp

1997 Uhde and Krupp Koppers merge

1999 Krupp and Thyssen merge to form ThyssenKrupp AG

2011 Name changes to ThyssenKrupp Uhde GmbH

Business year 2010/2011 (ThyssenKrupp Uhde Group)

1) acc. to IFRS

History

� Order intake €1,613.3m

� Net sales €1,427.6m 1)

� Equity capital €556.6m 1)

� Workforce 2)

ThyssenKrupp Uhde group (total) ~5,600

- of which ThyssenKrupp Uhde GmbH ~1,800

� Engineering approx. 7.1 million

capacity engineering hours/year2) Figures incl. non-permanent staff

5,600

2,900

World

Europe

Germany 2,300

Page 5: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Agenda

� Company

� Gasification Portfolio

� Joint Venture Kepco-Uhde

� Concepts & Projects/Plants

Page 6: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Gasification PortfolioThyssenKrupp Uhde proprietary Gasification Technologies

PSG PDQ HTW™

Entrained-Flow Fluidised Bed

PRENFLO®

Page 7: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

PRENFLO with Steam Generation

1200 MWth, 42 bar PSG

PRENFLO PSG Features

• dry coal/petcoke powder feed

• 4 horizontal co-annular burners

• membrane wall

• waste heat boiler (PSG)

Page 8: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

PRENFLO with Direct Quench

1200 MWth, 42 bar PDQ

PRENFLO PDQ Features

• dry coal/petcoke powder feed

• 4 horizontal co-annular burners

• membrane wall

• direct water quench

• operation pressure flexible to requirements (25 - 42 bar)

• raw gas temperature outlet of quench (200 - 250 °C)

• slag lock-hopper system

Page 9: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Cyclone

Recycle

Line

Bubbling

Fluidized

Bed

Refractory

Lined

Gasification

Chamber

HTW™ Gasification

Pressurised, fluidised bed

Temperature: 800 - 1000 °C

Pressure: 10 - 30 bar

Operates below ash melting point

� ideal for coals with high ash melting point, biomass, lignite, waste)

Gasification PortfolioThe HTW™ Gasifier

Page 10: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Gasification PortfolioThyssenKrupp Uhde acquires HTW™ Gasification Technology

• HTW™ goes back to 1926 (Winkler Gasification)

• HTW™ technology was previouslyowned by RWE/Rheinbraun

• ThyssenKrupp Uhde acquires theHTW™ technology with all IP rights and know-how from RWE in December 2010

• Main target: low-rank feedstocks, in particular: coals with high ashmelting points, brown coal, lignite, wastes

Page 11: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

PRENFLO®

Entrained-Flow

Gasification

Oil Gasification

HTW™

(High-Temperature Winkler) Fluidised Bed Gasification

Gasification PortfolioDifferent feedstocks require different gasification technologies

Page 12: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Gasification PortfolioTechnology decision tree

HTW PRENFLO PDQ Oil gasif.

AshContent

Ash SofteningPoint

Product Gas

Solid Liquid /Gas

High LowLow Rank Fuels

• Lignite

• Peat

• Biomass

High Rank Fuels

• Hard Coal

• Petcoke

• Residues

Normal

(>1200 °C) (<1200 °C)

Low

High Low

> 20% < 20%

CO-richH2-rich

PRENFLO PSG

Feedstock

Reactivity

Page 13: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Agenda

� Company

� Gasification Portfolio

� Joint Venture Kepco-Uhde

� Concepts & Projects/Plants

Page 14: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

• ThyssenKrupp Uhde and largest utility in Korea, KEPCO, form Joint Venture Company for PRENFLO® PSG gasification

• “KEPCO-Uhde Inc.” established in South Korea 14 July 2011.

• First 2 projects launched for KEPCO-Uhde

• JV provides strong synergy, cost and schedule advantages

Dr. Thiemann, CEO ThyssenKrupp Uhde Mr. Kim, CEO KEPCO

Joint Venture Kepco-Uhde

Page 15: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

• PRENFLO® PSG for IGCC and SNG applications including CCS

• Develop standard IGCC model for > 500 MW power output

• Improve efficiency of IGCC and SNG plants

• Integrate CCS solutions

���� Combine leadership strengths of both Joint Venture partners...

Market, Design and License

Research & Development

Joint Venture Kepco-Uhde Tasks of Kepco-Uhde Inc.

Page 16: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Agenda

� Company

� Gasification Portfolio

� Joint Venture Kepco-Uhde

� Concepts & Projects/Plants

Page 17: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Integrated Process Chain for the Production of Synthetic Biofuels

Coal

Petcoke

Wood

Straw, etc.

Feedstocks Pretreatment Gasification Gas Treatment

Torrefaction

Synthesis

GaselTM

Fischer-Tropsch (F-T)

Synthesis and productupgrading

Bio-diesel,

Bio-kerosene

CO-shift

AGR

Milling

Liquid Residues

PRENFLOTM

PDQ

Concepts & Projects/PlantsExample : Entrained Flow PRENFLO PDQ

Page 18: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

BioTfueL

a consortium of partners with complementary core businesses...

R&D Technologies licensors Fuels producers

From R&D to market

From field to wheel

Development and Demonstration of a complete B-XTL process chain

Page 19: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Integrated Process Chain for the Production of Methanol

Domestic

ForestResidues

Feedstocks Pretreatment Gasification Gas Treatment

Grinding,

Drying, Pelletising

CO-Shift

Synthesis

Methanol Synthesis

Fuel Grade Methanol

AGR

HTW

Concepts & Projects/PlantsExample : Fluidised Bed HTW

Page 20: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

VärmlandsMetanol, Sweden HTW Biomass to Methanol Project

Uhde selected as technology

supplier and EPC contractor

Plant Capacity: 100,000 t/a of fuel grade methanol +

district-heating 15 MWth

Feedstock:Domestic forest residue, ~25 t/h

Process:

Fluidized bed gasification (HTW) (eq. 111 MWth)

Page 21: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

The HTW Technology is capable to gasify a wide range of unconventional

feedstocks such as:

Forest and agricultural residuals;

Municipal waste;

Low rank and high ash content coal

R&D activities in order to further increase biomass % content as feedstock;

Joint Venture with KEPCO to accelarate IGCC, CCS and SNG applications;

Advanced concepts for clean, economical and sustainable fuel and energy

production:

BioTfueL: BXTL Project, France

C.GEN: IGCC with CCS in Killingholme, UK

Värmlandsmethanol AB: Biomass to Methanol, Sweden

Confidential Client: Licence and Services Agreement: Biomass to Liquids

OutlookA Cleaner Approach to Feedstocks, Fuels and Power

Page 22: Freiberg 5th ThyssenKruppUhde rev03 · 1921 Friedrich Uhde engineering firm, Dortmund 1952 Friedrich Uhde GmbH becomes a subsidiary of Hoechst AG 1996 Acquisition of Uhde by Krupp

Gasification Technologies5th International Freiberg Conference on IGCC & XtL Technologies - IFC2012

Leipzig, Germany, 21 - 24 May 2012

Thank you for your attention

Questions?

PRENFLO Gasification Plant, Puertollano, Spain

ThyssenKrupp Uhde GmbHFriedrich-Uhde Strasse 15, 44141Dortmund, [email protected]