environmental protection agency · 2019. 3. 26. · operator name: irish pioneer works...

Company Name: Irish Pioneer Works (Fabricators) Limited Licence No: P0407-01; TA-A Year: 2018, Visit No: 3 Report No: 2018-212

Glenside Environmental Services Doc No: GEN2-001rev13

Rev Date: 19/12/2018 Issued by: QM

Glenside Environmental, Unit 18 Great Island Industrial Park,

Ballincollig, Co. Cork

T: 021 4810016 M: 086 3819387 [email protected] www.glenenv.ie

_______________________________________________________________

Quarter 4 of 2018 Stack Emissions Monitoring Report

for

Irish Pioneer Works (Fabricators) Limited

Kinsale Road, Cork.

EPA Licence REF: P0407-01; TA-A _______________________________________________________________

Report No: 2018-212

Monitoring Date: 23rd November 2018

Test report shall not be reproduced except in full, without written approval of the laboratory.

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http://www.glenenv.ie/




Report Summary:

Job Quotation No: QGE18-019

Operator Licence No: P0407-01; TA-A

Operator Name: Irish Pioneer Works (Fabricators) Limited

Installation: Kinsale Road, Cork.

Contact Name: Colm Cullimore

Phone No: 021 4964299

Monitoring dates: 23rd November 2018

Monitoring Organisation: Glenside Environmental,

Unit 18 Great Island Industrial Park, Ballincollig,

Co. Cork Phone No: (021) 4810016

Email: [email protected]

Report Date: 14th January 2019

Report written by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE2, TE3, TE4

Report approved by: Ewa Piatek

MCERTS reg No: MM07 799

Competency: Level 2

Function: Team Leader

Endorsements: TE1, TE2, TE3, TE4

Signed by: Quality Manager

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Document Revision History

Version Changes Date Changes By

Rev0 Original report issued 14/01/2019 Ewa Piatek

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TABLE OF CONTENTS

PAGE

1. INTRODUCTION........................................................................................................................ 5

2. OBJECTIVES .............................................................................................................................. 5

2.1. SUBSTANCES TO BE MONITORED AT EACH EMISSION POINT ..................................................... 5 2.2. SPECIAL REQUIREMENTS ........................................................................................................ 5

3. MATERIALS AND METHODS ................................................................................................ 6

3.1. PARTICULATES - ISO9096:2017 (HIGH) OR IS EN 13284-1:2017 (LOW) ................................ 6 3.2. METALS – IS EN 14385:2004& MERCURY – IS EN 13211:2001 ........................................... 6 3.3. AMMONIA – IS EN 14791:2017 .............................................................................................. 6 3.4. HYDROGEN CHLORIDE – IS EN 1911:2010 ............................................................................. 6 3.5. VOLUMETRIC FLOW RATE – ISO 16911-1:2013 ..................................................................... 6

4. MONITORING RESULTS ......................................................................................................... 7

4.1. MONITORING RESULTS ........................................................................................................... 7 4.2. REFERENCE CONDITIONS ........................................................................................................ 8 4.3. METHODS AND ACCREDITATION STATUS................................................................................ 9

5. OPERATING INFORMATION............................................................................................... 10

6. MONITORING DEVIATION .................................................................................................. 10

7. ANNEX 1 .................................................................................................................................... 13

7.1. PERSONNEL ........................................................................................................................... 13

8. ANNEX 2 .................................................................................................................................... 14

8.1. DIAGRAM - SAMPLING PLANE OF STACK ................................................................................ 14 8.2. SAMPLING MEASUREMENTS .................................................................................................. 14

9. ANNEX 3 .................................................................................................................................... 15

9.1. RESULTS AND UNCERTAINTY CALCULATIONS FOR STACK A3-4 ............................................ 15 9.2. LABORATORY CERTIFICATES ................................................................................................ 15

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1. Introduction

Glenside Environmental was commissioned by Irish Pioneer Works (Fabricators) Limited to perform air emission monitoring at the facility in Kinsale Road, Cork. The monitoring was carried out as required by Condition 10 and Schedule 1 of Licence P0407-01 for the facility. This report presents details of this monitoring programme.

2. Objectives

2.1. Substances to be monitored at each emission point

Sample Locations Parameter

A3-4

Particulates

Ammonia

Hydrogen Chloride

Lead

Zinc

2.2. Special Requirements There were no special requirements for this monitoring campaign.

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3. Materials and Methods This section provides brief details of the methodologies employed to perform the air emission monitoring. chemiluminescence (cross-flow modulation) for NOx; and a paramagnetic cell for O2 measurements.

3.1. Particulates - ISO9096:2017 (high) or IS EN 13284-1:2017 (low) A sample stream of gas is extracted from the main gas stream at representative sampling points for 30 minutes, with an isokinetically controlled flow rate and measured volume. The dust entrained in the gas sample is separated by a pre-weighed filter, which is then dried and reweighed. Deposits upstream of the filter in the sampling equipment are also recovered and weighed. The increase of mass of the filter and the deposited mass upstream of the filter are attributed to dust collected from the sampled gas, which allows the dust concentration to be calculated.

3.2. Metals – IS EN 14385:2004& Mercury – IS EN 13211:2001 A known volume of flue gas is extracted representatively from a duct or a chimney during a certain period of time at a controlled flow rate following EN13284-1:2017 (Particulates Standard). The dust in the sampled gas volume is collected on a filter. Thereafter, the gas stream is passed through a series of absorbers containing absorption solutions and the filter passing fractions of the specific elements are collected within these solutions.

3.3. Ammonia – IS EN 14791:2017 A sample is extracted from the source and passed through a heated probe and filter into dilute sulphuric acid solutions which collect the gaseous ammonia. The filter collects particulate matter but is not routinely recovered an analysed. The ammonia is analysed by Colorimetry.

3.4. Hydrogen Chloride – IS EN 1911:2010 A known volume of flue gas is extracted representatively from a duct or a chimney during a certain period of time at a controlled flow rate with a heated probe. A heated filter removes the dust in the sampled volume, thereafter the gas stream containing gaseous chlorides is passed through a series of absorbers containing an absorption solution (chloride-free water). The results are calculated from the laboratory results divided by air volume sampled and are converted to mg/m3. Results in kg/h are calculated from concentration of pollutant and stack flow rate. All results are corrected to Standard Temperature and Pressure and if required to Reference Oxygen and Dry conditions. LOD values are obtained from laboratory LOD and the same calculations as per results.

3.5. Volumetric Flow Rate – ISO 16911-1:2013 The volumetric airflow rate was determined from stack velocity measurements calculated in accordance with ISO 16911-1:2013. Airflow rate and temperature profiles were performed at pre-calculated intervals across the stack in order to determine the average velocity profile across the stack diameters.

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4. Monitoring Results Table 4.1 presents the results of the air emission monitoring sampling program carried out at the emission stacks listed below.

4.1. Monitoring Results Results reported are corrected to reference conditions as per Licence requirements.

Emission Point Substances ELV CEMS

Results LOD Results Uncertainty Units Results Units kg/h Date of Monitoring

Start –End Time of Monitoring

A3-4 Particulates 10 n/a 0.5 5.7 0.18 mg/m3 0.07 kg/h 23/11/2018 10:43-11:43

A3-4 Particulates Blank n/a n/a 0.5 0.6 0.02 mg/m3 n/a kg/h 23/11/2018 10:23-10:28

A3-4 Zinc 5 n/a 0.004 2.285 n/a mg/m3 0.03 kg/h 23/11/2018 12:09-12:41

A3-4 Zinc Blank n/a n/a 0.004 0.004 n/a mg/m3 n/a kg/h 23/11/2018 11:52-11:57

A3-4 Lead 2 n/a 0.001 0.002 n/a mg/m3 0.00002 kg/h 23/11/2018 12:09-12:41

A3-4 Lead Blank n/a n/a 0.001 0.001 n/a mg/m3 n/a kg/h 23/11/2018 11:52-11:57

A3-4 Hydrogen Chloride 30 n/a 0.1 <0.1 0.01 mg/m3 0.002 kg/h 23/11/2018 12:58-13:38

A3-4 Hydrogen Chloride Blank n/a n/a 0.1 <0.1 0.01 mg/m3 n/a kg/h 23/11/2018 12:47-12:53

A3-4 Ammonia n/a n/a 0.02 0.40 0.029 mg/m3 0.0315 kg/h 23/11/2018 10:43-11:43

A3-4 Ammonia Blank n/a n/a 0.02 <0.02 0.001 mg/m3 n/a kg/h 23/11/2018 10:23-10:28

A3-4 Water Vapour n/a n/a 0.9 2.6 0.3 % n/a n/a 23/11/2018 10:43-11:43

A3-4 Volumetric Flow 15,500 n/a n/a 12160.9 636.1 m3/hr n/a n/a 23/11/2018 10:13-10:18

Results for Particulates, Metals, HCl, NH3 are within INAB accreditation range.

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4.2. Reference Conditions

Emission Point Reference Temperature Reference Pressure Reference Moisture Reference Oxygen

A3-4 273 K 101.3 kPa No correction No correction

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4.3. Methods and Accreditation Status

Sampling Point Determinant Reference Method Accreditation Status

Accreditation Range:

Analytical Method

Description Subcontracted

Laboratory Laboratory

Accreditation Status

A3-4 Ammonia Wet Chemistry IS EN 14791:2017 INAB 0.25-2000 mg/m3 Colorimetric

Analysis RPS UKAS

A3-4 Velocity,

Temperature, Pressure

ISO 16911-1:2013 INAB

Velocity: 3 – 26 m/s

Temperature: 0-1000oC

Pressure: 30-110 kPa

n/a n/a n/a

A3-4 HCl IS EN 1911:2010 INAB 0.05 - 5000 mg/m3

Ion Chromatography RPS UKAS

A3-4 Metals IS EN 14385:2004 INAB 0.005 – 0.5 mg/m3 ICP MS RPS UKAS

A3-4 Particulates low IS EN 13284:2017 INAB 0.11-50 mg/m3 Gravimetric Analysis RPS UKAS

A3-4 Water Vapour IS EN 14790:2017 INAB 0.9 – 40 %

Gravimetric Analysis n/a n/a

Substances were monitored as per monitoring objectives. Substances were monitored in accordance with the requirements stated in AG2 (Air Emissions Monitoring Guidance Note#2).

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5. Operating Information

Emission Point

Process Status Load

/Feedstock Process Details Fuel

/Feedstock Abatement

System Status of

Abatement System

A3-4 Galvanizing

16 Batches per day, Brightener 1 piece 3 times per shift, Zinc

added once

n/a n/a n/a

6. Monitoring Deviation

Requirements of IS EN 15259 for sampling points A3-4

Measurement plane is located as far downstream and upstream from any disturbances, which could

change direction of flow (bends, fans, partially closed dumpers). (IS EN 15259:2007 6.2.1.b) (AG1

2.2 and 2.1)

Compliant, Note: measuring plane is located as far downstream

and upstream from any disturbances.

Measurement Plane is located in a section of duct with at least five hydraulic diameters of straight duct upstream of the sampling plane. (IS EN 15259:2007

6.2.1.b) (AG1 2.2 and 2.1)

Compliant, Note: measuring plane of duct is located in a section of duct with five hydraulic diameters of straight duct

upstream of the sampling plane. Measurement Plane is located in a section of duct

with at least two hydraulic diameters of straight duct downstream of the sampling plane (five hydraulic

diameters from top of the stack). (IS EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Compliant. Note: measuring plane is located in a section of duct

with five hydraulic diameters from top of stack.

Measurement Plane is located in a section of duct with constant shape and cross-sectional area. (IS

EN 15259:2007 6.2.1.b) (AG1 2.2 and 2.1)

Compliant. Note: measuring plane is located in a section of duct

with constant shape and cross-sectional area. Measurement section is clearly identified and

labelled. (IS EN 15259:2007 6.2.1.f) (AG1 3.4) Compliant,

Note: measuring section is identified and labelled.

Requirements of IS EN 15259:2007 6.2.3.2 for platform, working space and ports size. A3-4

Appropriate working area. Yes, platform has appropriate size.

Safe access to monitoring point. Yes, access is safe. Sufficient ports number

For circular stacks: Small stacks (<0.35m) – 1 port

0.35-1.6m – 2 ports >1.6m – 4 ports

1 port available.

Appropriate port size. Yes, 100 mm.

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Requirements of ISO 16911-1:2013 9.2 (IS EN 15259:2007 6.2.1 c)

for flow, temperature and pressure profile of the stack A3-4

Required number of points were sampled as per ISO 16911-1 requirements.

Yes, 4 points sampled. One port available, 4 points

sampled at one sampling line.

No negative flow. Yes, no negative flow found in the stack flue gasses.

All points sampled swirl check was below 15° Yes, all points sampled swirl check result were below 15°.

Differential pressure higher than 5Pa measured with pitot tube. Yes, differential pressure result was above 5 Pa.

The ratio of highest to lowest local gas velocity is outside (higher than 3:1) of requirements

Yes, Ratio of highest to lowest gas velocity was 1.1:1.

Requirements for sampling of IS EN 13248-1 for

Particulates A3-4 Obtain isokinetic sampling within

–5 % and +15 %. Use the same sampling duration of at least 3 min at

each selected measurement point.

Isokinetic sampling 2.5 % Sampling duration at each selected measurement

point was 15 minutes.

Sampling duration of at least 30 min. Sampling duration was 60 minutes. The field blank value shall not exceed 10 % of the

emission limit value set for the process or 0,5 mg/m3, whichever is greater.

Blank within requirements, below 10% of ELV.

If the angle of flow at any of the sample points is greater than 15o with regard to the stack axis, the

flow criteria are not in compliance with the standard. In the absence of an alternative, compliant sampling

location, the sample points at which the angle of flow is not compliant shall not be sampled. (EA MID

13284-1:2017, Version 1, May 2018, 6.2)

The angle of flow within requirements of lower than 15o with regards to the stack axis.

All points were sampled.

Summary of sampling location compliance. Sampling location not compliant with the standard.

One port available, 4 points sampled at one sampling line.

Requirements of IS EN 14791 for Ammonia A3-4 Ammonia Impinger efficiency is higher than the

requirements of 95% total of concentration in the first impinger (section 6.6.1) or the result of the

second impinge is <LOD.

Yes, second impinge result is <LOD.

The blank reading meets the required target of <10% of the daily limit value.

n/a

Requirements of IS EN 1911 for HCl A3-4 Efficiency requirements: not more than 5 % must be retained in the last absorber in the range of concentration examined; or the content in the last absorber corresponds to a

concentration lower than a concentration corresponding to five times the analytical detection

limit.

Yes, Last impinger concentration is lower than 5x of the analytical LOD.

The blank reading meets the required target of <10% of the daily limit value.

Blank reading within requirements.

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Requirements of IS EN 14385 for Metals A3-4 Probe temperature should be kept at or above

180°C. Yes, probe temperature was kept at 185°C +/-5°C

Absorbers temperature shall be kept below 30°C Yes, absorbers temperature was kept below 30°C +/-2°C.

Absorbers efficiency requirement: If one of the individual metals elements in the last impinger is more than 10% of the total combined

result for that element. (not applicable if the result is less than 1% of the result of total mass of metals or

if the result is less than 30% of the ELV)

Yes, Metals efficiencies within requirements.

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7. Annex 1

7.1. Personnel

Scientist/Technician Name Position Qualification Technical

Endorsements MCERTS Number

Ewa Piatek Team Leader Level 2 TE1, TE2, TE3, TE4 MM07 799

Patrick Power Technician Level 1 - MM12 1183 Jim Nelligan Trainee Trainee - MM17 1427

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8. Annex 2

8.1. Diagram - sampling plane of stack

8.2. Sampling measurements

Determinant A3-4 Units

Number of Ports Sampled 1 -

Number of Points Sampled 4 -

Average Velocity v'a 8.6 Uncertainty 0.2 m/s m/s

Average Pressure 101.225 kPa

Average Temperature 34.5 °C

Stack Diameter 0.75 m

Nozzle Size 6.86 mm

Velocity, temperature and pressure measurements are within INAB accreditation range.

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9. Annex 3

9.1. Results and uncertainty calculations for Stack A3-4

9.2. Laboratory Certificates

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Company Name: Doc NoLicence No: Rev Date:Year: 2018 Visit No: 4 Issued by:Sampling Date:Report No: Flow Calculations for A3-4

Equipment Used:

Equipment :GEN

Equipment No:

Equipment :GEN

Equipment No:

Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ071 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091

Stack Diameter Measurements

Circular with central point

Circular no central point (tangential)

1 0.752 0.753 0.75

Diameter Average: 0.75 m

Stack Area 0.44 m2Sampling Line 1Sampling Points per line 4

Port Depth (m): Port 1: 0.2 Port 2:Wall thickness (m): 0.05

GEN2-002rev2419 December 2018QM

23 November 20182018-212

Irish Pioneer Works (Fabricators) LimitedP0407-01

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23 November 20182018-212


Circular no central point

Point NumberPoint position in stack (m)

Points to be marked on

probe

Point position as % of

diameter1 0.05 0.30 6.72 0.19 0.44 25.03 0.56 0.81 75.04 0.70 0.95 93.3

Note: Sampling point should be located either >3% of the

sampling point length or more than 5 cm whichever is the greater value from the inner

duct wall.

Sampling Points Position

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23 November 20182018-212


Static Pressure: Line 1 Line 2

mmH2O Pa mmH2O PaNote: At least once per line.

Reading 1 32 315 32 315Reading 2 32 315 32 315Reading 3 32 315 32 315Reading 4 32 315 32 315Reading 5 32 315 32 315Average: 32.1 315 32.1 315

Pre-Sampling Pitot Tube Checks:CommentsKIMO Pitot EQ080

Mill 5 Pitot EQ081

None None

Internal Leakage Check

Pressurized pressure: 500 Pa 12 mm H2OTime of leak check: 15 s 15 sLeak Check Result: Pass Pass

Equipment range: 500 500

Readings: Tap 1 315 31

Tap 2 315 31.5

Difference : 0 -0.5

Yes Yes

Requirement:

0.0 -0.1

Swirl Check: °

Within requirements <15°

Point 1 0 YesPoint 2 3 YesPoint 3 2 YesPoint 4 0 Yes

S-tope pitot tube shall be positioned perpendicular to the direction of the flow. The static pressure is than measured using both taps. The difference in the measured static pressure should be < 10Pa

Deformities, Burrs, Damage

Check on stagnation and reference pressure taps:

Difference in the measuredstatic pressure should be less than 0,5 % of the

range of the differential pressurewith aminimum tolerance value of 10 Pa.

Note: blow through the pitot impact opening until at least 7.6 cm (3.0 in.) H20 velocity head registers on the manometer;

then, close off the impact opening. The pressure shall remain stable for at least 15 seconds; (2) do the same for the

static pressure side, except using suction to obtain the minimum

of 7.6 cm (3.0 in.) H20.

Stagnation and reference taps within requirements?

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23 November 20182018-212


Absolute pressure of the stack gas:The absolute pressure in the duct is given by the measurement of the atmospheric pressure on the siteand the static pressure measured in the duct.

Barometric (Atmospheric Pressure)Pb 756.887244 mmHg Note: 1mb = 0.75 mmHg (Since1 atmosphere=1013.25 mb = 760 mmHg)Pstatic 32.13264249 mmH2O 760 mmHg = 101325 PaConversion form mmH2O to mmHg 13.6

Atmospheric Pressure: 100910 PaAtmospheric Temperature: 9.00 °C

Ps = 759.2499383 mmHgAbsolute Pressure

101225 Pa of stack

Result 1: Result 2 Result 3: Results Average:

Standard deviation

Stdev as % of the average of

results

Previous measurements

within requirement

Date: 20/02/2018 14/06/2018 17/09/2018CO ppm 15 15 15 15.0 0.0 0.0 YesCO2 % 0.06 0.06 0.06 0.1 0.0 0.0 YesO2 % 20.9 20.9 20.9 20.9 0.0 0.0 Yes

Moisture % 2.2 2.2 2.2 2.2 0.0 0.0 Yes

Molecular Weigh of Dry Gas Stream: Molecular weight of stack gas (wet):

Bwo 0.022Md 28.85

CO2 0.06 %Molecular weight of

water:18

O2 20.90 %

CO 0.0015 % CO ppm 15.00 Ms= 28.61

N2 79.04 %

Md= 28.85

Pitot coefficiency Calibration DataCalibration Date: 24/08/2018

Calibration Date: 24/08/2018



EQ080 KIMO - S Pitot Tube Long

EQ116 KIMO - L type EQ081 Mill 5

EQ113 Andersen

m/sec Cp m/sec Cp m/sec Cp m/sec Cp3.09 0.864 3.14 1.01 3.18 0.842 3.19 0.8285.16 0.859 5.09 1.009 5.13 0.846 5.15 0.841

10.07 0.852 10.2 1.009 10.19 0.846 10.18 0.84415.16 0.853 15.2 1.015 15.16 0.854 15.17 0.84320.33 0.851 20.14 1.017 20.34 0.846 20.6 0.84126.15 0.849 25.97 1.011 26.12 0.53 26.16 0.84

Previous Measurements:

Note: Standard deviation < 20% of the average of results. (AG2 rev4-May2018 -Appendix 1)

𝑃𝑃𝑠𝑠 = 𝑃𝑃𝑏𝑏 +𝑃𝑃𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆𝑆13.6

𝑀𝑀𝑑𝑑 = 44%𝐶𝐶𝐶𝐶𝐶

100+ 3𝐶

%𝐶𝐶𝐶100

+ 𝐶8%𝐶𝐶𝐶𝐶 + %𝑁𝑁𝐶

100𝑀𝑀𝑠𝑠 = 𝑀𝑀𝑑𝑑 1− 𝐵𝐵𝑤𝑤𝑤𝑤 + 18(𝐵𝐵𝑤𝑤𝑤𝑤)

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23 November 20182018-212


Time Start: 10:13 Time End: 10:18

Velocity by Mill 5 Velocity Temperature

Pressure of Stack

ΔPs Pa ΔPs mmH2O √ΔPs mmH2O m/s °C kPaDifferential Pressure

Point 1 58.82 6 2.449 8.6 35 101.225 58.82 PaPoint 2 53.92 5.5 2.345 8.2 34 101.225 53.92 PaPoint 3 63.72 6.5 2.550 9.0 35 101.225 63.72 PaPoint 4 58.82 6 2.449 8.6 34 101.225 58.82 PaTotal Average: 6 2.448424281 8.6 34.5 101.225 58.82 Pa

Uncertainty 0.2Higes to Lowest flow ratio: 1.1 :1 Max flow: 8.98Requirement is Duct Flow ratio of max. to min. <3:1 Min. Flow: 8.25

Note:minimum velocity of the stack gas must generate a differential pressure larger than 5Pa if a Pitot tube is used to carry out the measurement.

0.8460Pitot coefficiency closes to measured velocity value:

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23 November 20182018-212


After-Sampling Pitot Tube Checks:CommentsKIMO Pitot EQ080

Mill 5 Pitot EQ081

None None

Internal Leakage Check

Pressurized pressure: 500 Pa 12 mm H2OTime of leak check: 15 s 15 sLeak Check Result: Pass Pass

Equipment range: 500 200

Readings: Tap 1 315 30.5

Tap 2 313 30.5

Difference : 2 0

Yes Yes

Requirement:

0.4 0.0

Results:Circular StackStack Diameter: 0.75 m

Average velocity: 8.62 m/s1

Average Temperature: 307.50 KAverage Pressure: 101.225 kPaAverage Moisture: 0.0 %Average Oxygen: 0.00 %

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 3.81 m3/s = stack area (m2)*velocity(m/s)Volumetric Flow Rate 13707.8 m3/h = voumetric flow rate (m3/s) *60 *60 Volumetric Flow Rate corrected to STP 12160.9 m3/h =volumertic flow rate (m3/hr)*(273*stack pressure)/(stack temperature*101.3)Volumetric Flow Rate corrected to STP 12160.9 m3/h =volumetric flow rate (m3/hr)*((100-stack moisture)/100)Volumetric Flow Rate corrected to STP 12160.9 m3/h =volumetric flow rate (m3/hr)*((20.9-measured oxygen)/(20.9-reference oxygen))Uncertainty 636.1 m3/h

S-tope pitot tube shall be positioned perpendicular to the direction of the flow. The static pressure is than measured using both taps. The difference in the measured static pressure should be < 10Pa

Note: blow through the pitot impact opening until at least 7.6 cm (3.0 in.) H20 velocity head registers on the manometer; then, close off the impact opening. The pressure shall remain stable for at least 15 seconds; (2) do the same for the static

pressure side, except using suction to obtain the minimumof 7.6 cm (3.0 in.) H20.

Check on stagnation and reference pressure taps:

Stagnation and reference taps within requirements?

Difference in the measuredstatic pressure should be less than 0,5 % of the

range of the differential pressurewith aminimum tolerance value of 10 Pa.

Deformities, Burrs, Damage

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23 November 20182018-212


Uncertainty calculation for Velocity and Volume Flow Rate Measurement by Pitot tube EN ISO 16911-1v1.2 Jan-16Constants Characteristics of pressure sensor used for Delta PGas constant 8.314 J/(K.mol) Enter uncertainties as (95%,k=2) where relevant

Range of Delta P transducer 1000 PaResolution of Delta P transducer 1 PaRepeatability of Delta P transducer 2 % of valueDrift of Delta P transducer 0.1 % of range between calibrationsLack of fit of measurement system 0.1 % of rangeUncertainty in Delta P transducer 2.0 Pa

Enter uncertainties as (95%,k=2) where relevant Water vapour m 2 % relativePitot coefficient, 0.8460 Uncertainty in temperature readout system 2.5 °C CO content mea 0 % relativeExpanded uncerta 0.02 Uncertainty in atmospheric pressure transducer 173.4 Pa CO2 content me 0.06 % relative

Uncertainty in duct area measurement 2.0 % O2 content mea 20.90 % relative

Duct dimensionCircularDiameter 0.75 mArea 0.4 m2

All Pressures should be entered in Pascals, Pa

Atmospheric Pressure, Pa

Stack Pressure, Pa

Static Pressure, Pa meas1, Pa meas2, Pa meas3, Pa meas4, Pa meas5, Pa Delta P, Pa

Stack Temperature, C

Water Vapour Content, % CO, ppm CO2, % N2, % O2, %

dry molecular wt, g/mol

stack molecular wt, g/mol

100910 101225 315 58.82 58.82 58.82 58.82 58.82 59 35 2 15 0.06 79.0 20.90 28.85 28.61100910 101225 315 53.92 53.92 53.92 53.92 53.92 54 34 2 15 0.06 79.0 20.90 28.85 28.61100910 101225 315 63.72 63.72 63.72 63.72 63.72 64 35 2 15 0.06 79.0 20.90 28.85 28.61100910 101225 315 58.82 58.82 58.82 58.82 58.82 59 34 2 15 0.06 79.0 20.90 28.85 28.61100910 101225 315.0 58.8 58.8 58.8 58.8 58.8 58.8 34.5 2.2 15.0 0.1 79.0 20.9 28.85 28.61

Dry gas basis

Uncertainty in stack gas compositionEnter uncertainties as (95%,k=2) where relevant

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23 November 20182018-212


Mean density 1.1327 kg/m3

Circular duct

Flow rate 12160.9 m3/hour

Volume flow rate expanded uncertainty 636.1 m3/hour

Volume flow rate expanded uncertainty 5.2 % of valueVelocity associated uncertaintiesPitot Tube CoefficientExpanded uncertainty (95%, k=2) 0.02Standard uncertainty (Dimensionless) 0.01

Table 1

Delta P Standard uncertanites^2Measurement Point

SD of the mean of the DP measurements

(Standard uncertainty Delta P)^2 u2(Dpi)/4DP2 Velocity (m/s)

Standard uncertainty velocity m/s

Sigma DP See Table 1 1 1.2 1.8 0.000226458 8.6 0.17Resolution uncertainty 0.08 2 1.1 1.7 0.000250496 8.3 0.16Calibration uncertainty 1.00 3 1.3 1.8 0.000207751 9.0 0.17Lack of fit 0.33 4 1.2 1.8 0.000226458 8.6 0.17Drift 0.33 5

67

Molar Mass 8u(H2O) 0.02 9(O2)wet 20.4 10u(O2)wet 2.14 11(CO2)wet 0.1 12u(CO2)wet 0.00 13(CO)wet 0.0 14u(CO)wet 0.00 15Oxygen sensitivity 4.00E-05 16Water sensitivity 1.00E-04 17CO2 sensitivity 1.60E-04 18CO sensitivity 4.00E-08 19

20standard uncertainty 0.000085 kg/mol 0.30 % of value Average 1.2 1.8 0.0 8.6 0.2

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23 November 20182018-212


Temperaturestandard uncertainty 1.25 K 0.41 % of value

Stack static pressurestandard uncertainty 6.30 Pa 2.00 % of value

Stack pressurestandard uncertainty 173.5 Pa 0.17 % of value

Stack gas densitystandard uncertainty 0.0060 kg/m3 0.53 % of value

Standard uncertainty of velocity 0.11 m/sec 1.2 % of value

Expanded uncertainty in velocity 0.2 m/sec 2.5 % of value

Mean velocity 8.62 m/sec

Standard uncertainty of velocity 0.11 m/sec 1.2 % of value

Expanded uncertainty in velocity 0.2 m/sec 2.5 % of value

Volume flow rate associated uncertainties

Circular ductArea uncertainty 0.05 m2

Flow rate standard uncertainty 318.1 m3/h

Volume flow rate expanded uncertainty 636.1 m3/h

Volume flow rate expanded uncertainty 5.2 % of value

Developed for the STA by David Butterfield & Chris Dimopoulos, NPL

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Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: 19 December 2018Year: 2018 Visit No: 4 Issued by: QMSampling Date: 23 November 2018Report No: 2018-212 Isokinetic Samplin for A3-4

Equipment : GEN Equipment No: Equipment :

GEN Equipment

No:Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ080 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091Filter Holder: EQ084 Notes: Do not sample point with higher than 15° flow direction from stack axis.Glass Filter Holder EQ085 If the negative flow was founs point aroud it should not be sampledImpingers: EQ072 If the suitable sampling location could not be found double number od sampling point.Impingers: EQ124Nozzle: EQ08747mm GFA FiltersRun Filter Number: Blank Filter Number:

Determination of Nozzle size: K factor:

ΔH@ 61.5 mmHg calculated on the 02/08/2018 ΔH@ Millenium 61.5Tm 21 °C Meter Temperature estimated ΔH@ Andersen 58.6

Vdessired 1 m3Ts 0 °C K= 8.35Ps 759.249938 mmHgCp 0.846 S-type pitot tube constant Eastimated Volume Metered:θ 60 minutesBwo 0.02(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 2.45ΔP 6 mmH2O

Dn2= 44.56 mm2 EstVmstd= 1.05620 m3

Estimated sampling rate: 17.6 l/min 1.0562 m3/hr

Note: Max sampling flow rate is 23l/min

Dn (calculated 6.68 mm 2.7 5.9 10.96.86 mm 4.38 6.86 12.5 it is recommended to use nozzles with an inside diameter exceeding 8 mm. (IS EN 13284-1:2017)6.86 mm 5.72 7.566.86 mm 5.91 9.12Dn= Used

nozzle size6.86 mm 5.87 10.02

Cross sectional Area of the

36.96 mm2 12.45

Availlable Nozzle sizes

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑

𝑀𝑀𝑠𝑠∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)

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mailto:%CE%94H@

mailto:%CE%94H@

mailto:%CE%94H@


0.021123908 m3

Leak Check:Vacum Pressm3 Time Pass/Fail

Before Blank: -6 0 2 min PassAfter Blank: -7 0 2 min Pass

Before Run: -8 0 2 min PassAfrer Run: -8 0 2 min Pass

Filtration device used: Outside filtration Instack filtration

Sampling requirements:

ParameterFilter Instack /Outstack

Particulates

“In-stack” 1m3/h - 3m3/h (if gases well above acid dew point),“Out-stack” 1m3/h - 10 m3/h (if gases saturated, if gases below acid dew point)

Moisture n/a

Ammonia 0

The temperature at the outlet of trapping unit shall not be greater than 4 °C or by checking visually the amount of silica gel having faded in the

last impinger or cartridge. This amount shall not exceed 50 %

0

Filter temperature

160°C or stack temperature

0

0

Probe temperature

160°C or stack temperature

0

120°C or 20°C above stack gas dew point

Sampling time

min. 30 minutes/ for paharmaceutica dust min 1

hour

1 hour for low moisture below 4%/30 minutes for resutls

above 4%

Min 30 min sampling time

Allowable leak check less than:

Others

When using in-stack filtration, to prevent condensation forming on the filter, the filtration

device should be externally pre-heated to a temperature above the stack gas temperature

or preheated in stack

0

Sample flow 1-3.3 L/min.

Impingers temperature

0

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EPA Export 26-03-2019:03:34:41


Sampling:Stack Diameter 0.75 m Start Time: 10:43:00 End Time:Cross sectional Area of the stack: 0.442 m2 Dry Gas Pressure: 100.910 kPa

Points number: 4 Sampling time at each po 15 min.

Traverse point number Clock Time Pump Vacuum Velocity Heads Sqr roots Velocity

Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp Impinger Temp Tc Filter Temp

K Factor Calculate

d

Velocity of the stack

Actual Flow Of Stack

Actual Sampled Volume

Vmstd at the time of measuring at STP

Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 m3 %

0 -6 6 2.449 43.719 50 583 35 162 3 16 16 7.29 8.62 228.561 5 -6 6 2.449 43.795 50 674 35 162 3 16 17 7.30 8.62 228.56 0.09 0.0856 103.521 10 -6 6 2.449 43.795 50 768 35 162 3 16 17 7.30 8.62 228.56 0.19 0.1739 105.191 15 -6 6 2.449 43.795 50 857 35 162 3 16 17 7.30 8.62 228.56 0.27 0.2576 103.852 20 -6 5.5 2.345 40.145 50 946 35 162 3 16 17 7.30 8.26 218.83 0.36 0.3412 107.772 25 -6 5.5 2.345 40.145 50 1038 35 162 3 16 17 7.30 8.26 218.83 0.46 0.4277 108.062 30 -6 5.5 2.345 40.145 50 1123 35 162 3 16 17 7.30 8.26 218.83 0.54 0.5075 106.873 35 -6 6.5 2.550 47.444 50 1218 35 162 3 16 17 7.30 8.97 237.89 0.64 0.5968 99.083 40 -6 6.5 2.550 47.444 50 1302 35 162 3 16 17 7.30 8.97 237.89 0.72 0.6757 98.163 45 -6 6.5 2.550 47.444 50 1397 35 162 3 16 17 7.30 8.97 237.89 0.81 0.7650 98.784 50 -6 6 2.449 43.795 50 1486 35 162 3 16 17 7.30 8.62 228.56 0.90 0.8486 102.654 55 -6 6 2.449 43.795 50 1575 35 162 3 16 17 7.30 8.62 228.56 0.99 0.9323 102.514 60 -6 6 2.449 43.795 50 1665 35 162 3 16 17 7.30 8.62 228.56 1.08 1.0168 102.50

Average: 6.00 2.45 50.00 34.50 162.00 3.00 #DIV/0! 16.00 16.92 8.62 228.47 As %1082.00 2.5

Gas Sample Temperature at Dry Gas

Meter

11:43:00

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Circular StackStak Diameter: 0.75 m

Average Flow corrected for wall effect: 8.62 m/sAverage Temperature: 307.50 KAverage Pressure: 101.225 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 3.81 m3/sVolumetric Flow Rate 13708.1 m3/h

Flow Rate corrected to STP 12161.1 m3/h

12161.1 m3/h

12161.1 m3/h

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.

Volumetric Flow Rate corrected to STP


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EPA Export 26-03-2019:03:34:41

Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: 19 December 2018Year: 2018 Visit No: 4 Issued by: 0 QMSampling Date: 23 November 2018Report No: 2018-212 Moisture Record and Calculations for A3-4

Equipment used:

Balance: EQ056Weights: EQ063

Balance Check:

Initial Weight: Balance Reading:100g 100.1500g 499.9800g (combined 100g,200g,500g) 799.9

Before

Readings:Impinger 1 + Connection Impinger 2+Connection

Impinger 3+Connection

Impinger 4+Connection Sum:

1 856.4 864.3 654.1 1034.6 3409.42 856.4 864.3 654.1 1034.6 3409.43 856.4 864.3 654.1 1034.6 3409.44 856.4 864.3 654.1 1034.6 3409.45 856.4 864.3 654.1 1034.6 3409.46 856.4 864.3 654.1 1034.6 3409.47 856.4 864.3 654.1 1034.6 3409.48 856.4 864.3 654.1 1034.6 3409.49 856.4 864.3 654.1 1034.6 3409.4

10 856.4 864.3 654.1 1034.6 3409.4Standard Deviation: 0 0 0 0 0Averge: 856.4 864.3 654.1 1034.6 3409.4

After

Readings:Impinger 1+Connection Impinger 2+Connection

Impinger 3+Connection

Impinger 4+Connection Sum:

1 875.7 865.7 655 1034.7 3431.12 875.7 865.7 655 1034.7 3431.13 875.7 865.7 655 1034.7 3431.14 875.7 865.7 655 1034.7 3431.15 875.7 865.7 655 1034.7 3431.16 875.7 865.7 655 1034.7 3431.17 875.7 865.7 655 1034.7 3431.18 875.7 865.7 655 1034.7 3431.19 875.7 865.7 655 1034.7 3431.1

10 875.7 865.7 655 1034.7 3431.1Standard Deviation: 0 0 0 0 0Averge: 875.7 865.7 655 1034.7 3431.1

Note: If balance is moved to other location balance check has to be repeated.

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EPA Export 26-03-2019:03:34:41


Air Volume corrected to STP: 1.016846021 m3

Efficiency: 99.54 %

Stack Conditions:

Average Temperature: 307.5 KAverage Pressure: 101.225 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

12160.87 m3/hr

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :At Standard Temperature and Pressure corrected O2 ref Uncertainty

g/m3 21.3 21.3 2.9 Overall uncertainty is 13.42 % of the measured value% 2.6 2.6 0.3

Note: Overall uncertainty should be lower than +/-20% of the measured value


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Moisture Uncertainty CalculationsMeasured concentration 2.6 % (at STP)Measured Quantities Symbol Value Standard uncertainty UnitsSampled Volume Vm 1.016846021 uVm 0.001 m3Sampled gas Temperature Tm 307.5 uTm 2 kSampled gas Pressure ρm 101.225 uρm 1 kPaEfficiency Ɛ 99.54 %Oxygen content O2,m 0 uO2,m 0.1 % by volumeWater collected in condensation stage 21.70Water collected in adsorption stage 0Wate collected in addidional unit 0.1Water collected in trapping unit m 21.80 um 0.00 gIntermediate calculationsVwc 201.6846021 ^2

9.0 81.2 Efficiency uncertainty 0.02-2.0 3.9 support 0.02-1.0 0.9 calculations 0.00

√water in trapping unit 4.7

water in adsorption stage 0.0Uncertainty Efficiency^2 0.0Volume ^2 1.0Sensityvity coefficiency 380.0Uncertainty efficiency 0.00

Repatability standard devWeight in the field st 0.0 0.0Sampled Volume 0.002 0.0Sampled gas Temperature 0.02 0.0Sampled gas Pressure 0.3 0.2Combined measurement uncertainty 0.17 %

Expanded uncertainty as percentage of measured value 13.42 % measured of value expressed with a level of confidence of 95%(Using a coverage factor k=2)

Expanded uncertainty in units of measurement 0.35 % of water vapour

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EPA Export 26-03-2019:03:34:41

Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: #############Year: 2018 Visit No: 4 Issued by: QMSampling Date: 23 November 2018Report No: 2018-212 Ammonia Results Calculations for A3-4

Ammonia Results:

mg/L as NH3 Volume (ml)Sample reference

number Impinger efficiency check: Absorption efficiency(Impinger 1 should absorb 95% of total NH4):LOD 0.1 n/a 97.1 % or result in second absorber should be <LODBlank Impinger 1+2+Line Wash 0.1 213 1022366

Run Impinger 1 +Line Wash 4.3 94 1022364Impinger 2 0.1 122 1022365

LOD 0.02 mgBlank 0.02 mgRun 0.42 mg

1.016846021 m3

1.043850465 m3

Stack ConditionsAverage Temperature: 307.5 K Average Pressure: 101.225 kPaAverage Oxygen: 0.00 %Average Moisture: 0.00 %Volumertic Flow Rate corrected to STP O2 ref and Moisture 12160.87 m3/hr

Reference ConditionsReference Temperature: 273.15 K Reference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Ammonia Results

Results :mg/m3 mg/m3 kg/hr Uncertainty

Run corrected O2 ref mg/m3NH4 0.42 0.42 0.0051 0.031NH3 0.40 0.40 0.0049 0.029

N 0.33 0.33 0.0040 0.024 Note: Blank result should be < 10% of ELVBlankNH4 0.02 0.02 0.0003 0.002 Blank resu #DIV/0! % of ELVNH3 0.02 0.02 0.0002 0.001 If the blank result is higher than requirements of ELV result should be rejected

N 0.02 0.02 0.0002 0.001LODNH4 0.02 0.02 0.0003 n/aNH3 0.02 0.02 0.0003 n/a

N 0.02 0.02 0.0002 n/a

Wet Air Volume corrected to STP:

Dry Air Volume corrected to STP:

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Uncertainty calculation for EN 14791 Determination of mass concentration of Ammonia, Reference method (taken from SO2 uncertainty STA website)

rev2Run Measurement EquationLimit value (ELV) mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.4 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertainty a Requirement of stdSampled Volume Gas Vm 1.043850465 uVm 0.001 m3

0.10 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 2.00 <2.5 kSampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Concentration in impinger C 2.20 uC 0.066 mg/l 3.00 <5%Impinger solution volume VS 0.216 uVS 0.001 l 0.46 <1%Mass Ammonia m 0.42 um 0.01 mg 3.04 #DIV/0! <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 2 % 2.00 <=2%

Intermediate calculationsFactor for std conds fs 0.89uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55

Corrected volume V 0.93 uV 0.014 m3 1.55

Factor for O2 correction fc 1.00uncertainty components symbol sensitivity coeff u

O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %Corrected Volume (standard V 0.93 m3 0.43 0.01 mg.m-3 #DIV/0! %Mass m 0.42 mg 0.96 0.01 mg.m-3 #DIV/0! %Factor for O2 Correction fc 1.00 0.40 0.00 mg.m-3 #DIV/0! %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 #DIV/0! %

Combined uncertainty 0.01 mg.m-3


Expanded uncertainty in units of measurement 0.03 mg.m-3

Expanded uncertainty as percentqge of limit value #DIV/0! % ELVRequirement in standard is for uncertainty to be < 20% at ELV at standard conditions

sm fVV =

m

refc O

Of

,2

,2

2121

−

−=

cfVmc =

3.101273

100)100( m

m

ms T

Hf

ρ−=

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EPA Export 26-03-2019:03:34:41


Uncertainty calculation for EN 14791 Determination of mass concentration of Ammonia, Reference method (taken from SO2 uncertainty STA website)

Blank

Limit value (10% of ELV) 0 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.0 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertainty a Requirement of stdSampled Volume Gas Vm 1.043850465 uVm 0.001 m3

0.10 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 2.00 <2.5 kSampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Concentration in impinger C 0.05 uC 0.0015 mg/l 3.00 <5%Impinger solution volume VS 213 uVS 0.001 l 0.00 <1%Mass NH3 m 0.02 um 0.00 mg 3.00 #DIV/0! <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 2 % 2.00 <=2%


ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55



O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %Corrected Volume (standard V 0.93 m3 0.02 0.00 mg.m-3 #DIV/0! %Mass m 0.02 mg 0.96 0.00 mg.m-3 #DIV/0! %Factor for O2 Correction fc 1.00 0.02 0.00 mg.m-3 #DIV/0! %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 #DIV/0! %




Expanded uncertainty as percentqge of limit value #DIV/0! % ELV

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Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: 19 December 2018Year: 2018 Visit No: 4 Issued by: QMSampling Date: 23 November 2018Report No: 2018-212 Particulates Results Calculations for A3-4

Paticulates Data:

Certs Results: mg Date analysis completed:LOD Filter: 0.04 10/12/2018

LOD Nozzle Wash: 0.5 Sample reference number:

Blank Filter: 0.17 1022362Blank Nozzle Wash: 0.5 1022363Run Filter: 5.42 1022360Run Nozzle Wash: 0.5 1022361

0.54Blank 0.67Run 5.92

1.016846021 m3

1.043850465 m3

Stack ConditionsAverage Temperature: 307.5 KAverage Pressure: 101.225 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

12160.87 m3/h

Reference ConditionsReference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Particulates Results :mg/m3 mg/m3 kg/hr Uncertainty

corrected to O2 mg/m3LOD 0.5 0.5 0.01 n/aBlank 0.6 0.6 0.01 0.02 Blank result is: 6 % of ELVRun 5.7 5.7 0.07 0.18 If the blank result is higher than requirements of ELV result should be rejected


the field blank value does not exceed 10 % of the lowest emission limit value set for the process or 0,5 mg/m3, whichever is greater;



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Particulates Uncertainty Run CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodrev14Limit value (ELV) 10 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 5.7 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertain Uncertain Requirement of stdSampled Volume Vm 1.043850465 uVm 0.001 m3 0.10 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 0.65 <=1%Sampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Mass particulate m 5.92 um 0.00 mg 0.00 0.00 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 0 % 0.00 <=2%Uncollected Mass UCM 0 mg 0 <=10%(Instack filter - no rinse)Intermediate calculationsFactor for std conds fs 0.89uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55



O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity c Uncertainty contribution Uncertainty as %Corrected Volume (standard con V 0.93 m3 6.12 0.09 mg.m-3 0.88 %Mass m 5.92 mg 0.96 0.00 mg.m-3 0.00 %Factor for O2 Correction fc 1.00 5.67 0.03 mg.m-3 0.27 %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %Uncollected mass UCM 0.00 mg 0.96 0.00 mg.m-3 0.00 %Combined measurement uncertainty 0.09 mg.m-3


Expanded uncertainty in units of measurement 0.18 mg.m-3Requirement in standard is for uncertainty to be < 30% at ELV at standard conditions

Expanded uncertainty as percentage of limit value 1.8 % ELV

sm fVV =

m

refc O

Of

,2

,2

2121

−

−=

cfVmc =

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Particulates Uncertainty Blank CalculationsUncertainty calculation for EN 13284 Determination of low range mass concentration of dust, Manual Gravimetric Methodrev14Limit value (10% of ELV) 1 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.6 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertain Uncertain Requirement of stdSampled Volume Vm 1.043850465 uVm 0.001 m3 0.10 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 0.65 <=1%Sampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Mass particulate m 0.67 um 0.00 mg 0.00 0.00 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 0 % 0.00 <=2%Uncollected Mass UCM 0 mg 0 <=10%(Instack filter - no rinse)Intermediate calculationsFactor for std conds fs 0.89uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55



O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity c Uncertainty contribution Uncertainty as %Corrected Volume (standard con V 0.93 m3 0.69 0.01 mg.m-3 1.00 %Mass m 0.67 mg 0.96 0.00 mg.m-3 0.00 %Factor for O2 Correction fc 1.00 0.64 0.00 mg.m-3 0.31 %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 0.00 %Uncollected mass UCM 0.00 mg 0.96 0.00 mg.m-3 0.00 %Combined measurement uncertainty 0.01 mg.m-3



Expanded uncertainty as percentage of limit value 2.1 % ELV

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GEN Equipment

No:Millennium 5 console: EQ069Andersen Console: EQ106Probe: EQ080 Pitot Tube: EQ081Probe: EQ107 Pitot Tube: EQ113KIMO - Flow Test: EQ079 Kimo S Pitot Tube (Long) : EQ080KIMO - Flow Test: EQ117 Kimo L Pitot Tube : EQ116Rule: EQ083Laser Distance Meter: EQ089KIMO 115 EQ091Filter Holder: EQ084 Notes: Do not sample point with higher than 15° flow direction from stack axis.Glass Filter Holder EQ085 If the negative flow was founs point aroud it should not be sampledImpingers: EQ072 If the suitable sampling location could not be found double number od sampling point.Impingers: EQ124Nozzle: EQ08747mm GFA FiltersRun Filter Number: Blank Filter Number:

Determination of Nozzle size: K factor:

ΔH@ 61.5 mmHg calculated on the 02/08/2018 ΔH@ Millenium 61.5Tm 21 °C Meter Temperature estimated ΔH@ Andersen 58.6

Vdessired 0.5 m3Ts 0 °C K= 8.35Ps 759.249938 mmHgCp 0.846 S-type pitot tube constant Eastimated Volume Metered:θ 30 minutesBwo 0.02(√(∆𝑃𝑃)) 𝑎𝑎𝑎𝑎𝑎𝑎 2.45ΔP 6 mmH2O

Dn2= 44.56 mm2 EstVmstd= 0.52810 m3

Estimated sampling rate: 17.6 l/min 1.0562 m3/hr

Note: Max sampling flow rate is 23l/min

Dn (calculated 6.68 mm 2.7 5.9 10.96.86 mm 4.38 6.86 12.5 it is recommended to use nozzles with an inside diameter exceeding 8 mm. (IS EN 13284-1:2017)6.86 mm 5.72 7.566.86 mm 5.91 9.12Dn= Used

nozzle size6.86 mm 5.87 10.02

Cross sectional Area of the

36.96 mm2 12.45

Availlable Nozzle sizes

Nozzle Measurements:

𝐷𝐷𝑛𝑛2 =𝑉𝑉𝑑𝑑𝑑𝑑𝑠𝑠𝑆𝑆𝑑𝑑𝑑𝑑𝑑𝑑

𝑀𝑀𝑠𝑠(𝑇𝑇𝑠𝑠 + 𝐶73)𝑃𝑃𝑠𝑠

(5.9195 ∗ 10−4)𝐶𝐶𝑝𝑝𝜃𝜃(1 − 𝐵𝐵𝑤𝑤𝑤𝑤)( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎

𝐾𝐾 = 8.04 ∗ 10−5 ∗ 𝐶𝐶𝑝𝑝2 ∗ ∆𝐻𝐻𝐻𝑇𝑇𝑚𝑚 + 𝐶73𝑇𝑇𝑠𝑠 + 𝐶73

∗𝑃𝑃𝑠𝑠𝑃𝑃𝑏𝑏

∗𝑀𝑀𝑑𝑑

𝑀𝑀𝑠𝑠∗ (1 − 𝐵𝐵𝑤𝑤𝑤𝑤)(𝐷𝐷𝑛𝑛)4

𝐸𝐸𝐸𝐸𝐸𝐸𝑉𝑉𝑚𝑚𝑠𝑠𝑆𝑆𝑑𝑑 = 5.9195 ∗ 10−4 ∗ 𝐶𝐶𝑝𝑝𝑃𝑃𝑠𝑠

𝑀𝑀𝑠𝑠 273+𝑇𝑇𝑠𝑠∗ ( ∆𝑃𝑃)𝑎𝑎𝑎𝑎𝑎𝑎 ∗ 𝐷𝐷𝑛𝑛2𝜃𝜃(1 −𝐵𝐵𝑤𝑤𝑤𝑤)

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EPA Export 26-03-2019:03:34:41

mailto:%CE%94H@

mailto:%CE%94H@

mailto:%CE%94H@


0.010561954 m3

Leak Check:Vacum Pressm3 Time Pass/Fail

Before Blank: -6 0 2 min PassAfter Blank: -7 0 2 min Pass

Before Run: -8 0 2 min PassAfrer Run: -8 0 2 min Pass

Filtration device used: Outside filtration Instack filtration


ParameterFilter Instack /Outstack

Metals Outstack0

When using titanium equipment the temperature shall be maintained at 180°C or

higher. 0 Impinger should be kept below 30°C.The length of connections (tubing) from

sampling probe to the absorbers shall be <1 m.

Allowable leak check less than:

Sampling time Probe temperature Filter temperature Impingers temperature Others

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EPA Export 26-03-2019:03:34:41


Sampling:Stack Diameter 0.75 m Start Time: 12:09:00 End Time:Cross sectional Area of the stack: 0.442 m2 Dry Gas Pressure: 100.910 kPa

Points number: 4 Sampling time at each po 8 min.

Traverse point number Clock Time Pump Vacuum Velocity Heads Sqr roots Velocity

Heads

Orfice Settings

Calculated

Orfice Settings

Readings

Gas Sample Volume

Stack Temp

Probe Temp Impinger Temp Tc Filter Temp

K Factor Calculate

d

Velocity of the stack

Actual Flow Of Stack



Isokinetic Ratio

mmHg ΔPs √ΔPs ΔH ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °Cm/s m3/min m3 m3 %

0 -6 6 2.449 44.022 45 1678 35 184 21 183 18 18 7.34 8.62 228.561 4 -6 6 2.449 44.022 45 1754 35 184 21 183 18 18 7.34 8.62 228.56 0.08 0.0710 107.421 8 -6 6 2.449 44.022 45 1832 35 184 21 183 18 18 7.34 8.62 228.56 0.15 0.1440 108.832 12 -6 5.5 2.345 40.353 45 1911 35 184 21 183 18 18 7.34 8.26 218.83 0.23 0.2178 114.662 16 -6 5.5 2.345 40.353 45 1989 35 184 21 183 18 18 7.34 8.26 218.83 0.31 0.2907 114.783 20 -6 6 2.449 44.097 45 2065 35 184 21 183 19 18 7.35 8.62 228.56 0.39 0.3617 109.373 24 -6 6 2.449 44.097 45 2145 35 184 21 183 19 18 7.35 8.62 228.56 0.47 0.4363 109.964 28 -6 6 2.449 44.173 45 2228 35 184 21 183 19 19 7.36 8.62 228.56 0.55 0.5137 110.964 32 -6 6 2.449 44.173 45 2301 35 184 21 183 19 19 7.36 8.62 228.56 0.62 0.5817 109.94

Average: 5.89 2.43 45.00 34.50 184.00 21.00 183.00 18.44 18.22 8.54 226.40 As %623.00 9.9

12:41:00

Gas Sample Temperature at Dry Gas

Meter

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EPA Export 26-03-2019:03:34:41


Circular StackStak Diameter: 0.75 m

Average Flow corrected for wall effect: 8.54 m/sAverage Temperature: 307.50 KAverage Pressure: 101.225 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %

Reeference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Moisture: 0 %Reference Oxygen: 0 %

Mass Emissions Calculations:Volumetric Flow Rate 3.77 m3/sVolumetric Flow Rate 13583.8 m3/h

Flow Rate corrected to STP 12050.9 m3/h

12050.9 m3/h

12050.9 m3/hVolumetric Flow Rate corrected to STP

Note: If the results of isokinetic sampling are to be reported as mass emission, than the flow rate used during isokinetic sampling shall be used.


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EPA Export 26-03-2019:03:34:41

Company NamIrish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: ###############Year: 2018 Visit No: 4 Issued by: QMSampling Date #############Report No: 2018-212 Metals Results Calculations for A3-4

Run Lab Results LOD Filter LOD Probe W LOD Impingers Filter Rince Impinger 1&2 Impinger 3

µg µg µg/l µg µg µg/l µg/lLead 0.3 0.5 0.3 0.3 0.3 3.0 1.0Zinc 1 1 1 1286 1 348 283

Solutions Volume Impinger 1&2 Impinger 3ml 132 112

Metals0.581723579 m30.597172449 m3

Average Temperature: 307.5 KAverage Oxygen: 0.00 %

12160.87 m3/hrVolumertic Flow Rate corrected to STP O2 ref and Moisture

Wet Air Volume corrected to STP:Dry Air Volume corrected to STP:

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EPA Export 26-03-2019:03:34:41

Company NamIrish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: ###############Year: 2018 Visit No: 4 Issued by: QMSampling Date #############Report No: 2018-212 Metals Results Calculations for A3-4

Reference Conditions:Reference Temperature: 273.15 KReference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

Results :mg in sampling train

mg in sampling train

mg in sampling train

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

mg/m3 at STP/Dry

LOD Run Blank LOD Run Blank LOD Run BlankLead 0.0009 0.0011 0.0005 0.001 0.002 0.001 0.001 0.002 0.001Zinc 0.0022 1.3646 0.0024 0.004 2.285 0.004 0.004 2.285 0.004

Total of Metals 0.0031 1.3657 0.0030 0.005 2.287 0.005 0.005 2.287 0.005

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EPA Export 26-03-2019:03:34:41

Company NamIrish Pioneer Works (Fabricators) LimDoc No GEN2-002rev24Licence No: P0407-01 Rev Date: #############Year: 2018 Visit No: 4 Issued by: QMSampling Dat 23 November 2018Report No: 2018-212 Metals Results Calculations for A3-4

BlankLab Results Filter Rince Impinger 1&2&3

µg µg µg/lLead 0.3 0.2 0.2Zinc 1 1 2

Solutions Volume Impinger 1ml 216

Note: Blank result should be < 10% of ELVIf the blank result is higher than requirements of ELV result should be rejected

If one of the metal elements in the last impinger is more than 10% of the total combined

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EPA Export 26-03-2019:03:34:41

Company NamIrish Pioneer Works (Fabricators) LimDoc No GEN2-002rev24Licence No: P0407-01 Rev Date: #############Year: 2018 Visit No: 4 Issued by: QMSampling Dat 23 November 2018Report No: 2018-212 Metals Results Calculations for A3-4

metals (i.e. the filter, probe rinse and impingers) collected then the result shall berejected, unless the total result is less than 30% of the ELV.

Efficiency Check

kg/hr kg/hr kg/hr Efficiency

Efficiency Requireme

nts ELV

Result as percentage of

ELV

Blank Result as percentage of ELV

LOD Run Blank %0.0000 0.00002 0.0000 10.11 10 2 0% 0%0.0000 0.03 0.0000 2.32 10 5 46% 0%

0.0001 0.03 0.0001 For example ELVs for metals may be:• Cd and Tl combined – 0.05 mg/m3

However, for each group the requirement to pass the absorber efficiency check shall not apply:• to individual metal element(s), where the individual mass of the element in the final result is less than 1% of the

result for the total mass of metals in the group; or• if the total combined result for the metals in the group is less than 30% of the ELV.

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EPA Export 26-03-2019:03:34:41

Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: ##############Year: 2018 Visit No: 4 Issued by: QMSampling Date: #############Report No: 2018-212 Constant Flow Sampling Record for A3-4


GEN Equipme

nt No:

Indicated Reading of instrument under test Measured Flow

Millennium 5 console: EQ069 mm of WATER l/minAndersen Console: EQ106 1 3.021Probe: EQ080 Pitot Tube: EQ081 5 6.697Probe: EQ107 Pitot Tube: EQ113 10 9.708Filter Holder: EQ084 15 11.874Glass Filter Holder EQ085Impingers: EQ072 20 13.669Impingers: EQ124 25 15.272Nozzle: EQ087Run Filter Number: Blank Filter Number:

Sampling flow: 2.00 l/min 0.1 m3/hrAllowable leak check: 0.002 m3

Leak Check:

Vacum Pressure m3 Time Pass/Fail

Before Blank -5 2 min PassAfter Blank -6 2 min PassBefore Run: -5 2 min PassAfrer Run: -4 2 min Pass

Start Time: 12:58:00 End Time: 13:38:00Preheated Probe temperature: 123


ParameterSampling

timeFilter Instack /Outstack

Probe temperature

HCL

100 L sample volume.

Samplng flow 2-3L/min 0

20°C above stack gas dew

point 0

In-stack filtration is possible with effluent without droplets and if gas temperature is at least 20 °C above the

dew point0

Filter temperature OthersImpingers

temperature

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EPA Export 26-03-2019:03:34:41

Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: ##############Year: 2018 Visit No: 4 Issued by: QMSampling Date: #############Report No: 2018-212 Constant Flow Sampling Record for A3-4

00:05:00Dry Gas Pressure: 100.910 kPa

Time Minutes Pump Vacuum Orfice Settings Readings

Gas Sample Volume

Stack Temp

Probe Temp

Cond Temp Tc

Filter Temp

Gas Sample Temperature at Dry Gas Meter



Sample Flow rate

mmHg ΔHVm

(m3/1000) (liters)

°C °C °C °C Inlet °C Outlet °C m3m3 l/min

12:58:00 0 0 1 322 35 123 3 19 1913:03:00 5 0 1 337 35 123 3 19 19 0.015 0.0140 3.013:08:00 10 0 1 352 35 123 3 19 19 0.03 0.0279 3.013:13:00 15 0 1 368 35 123 3 19 19 0.046 0.0429 3.113:18:00 20 0 1 382 35 123 3 19 19 0.06 0.0559 3.013:23:00 25 0 1 398 35 123 3 19 20 0.076 0.0708 3.013:28:00 30 0 1 416 35 123 3 19 20 0.094 0.0875 3.113:33:00 35 0 1 433 35 123 3 20 20 0.111 0.1033 3.213:38:00 40 0 1 448 35 123 3 20 20 0.126 0.1172 3.2

Average: 1.00 34.50 123.00 3.00 #DIV/0! 19.22 19.44

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Company Name: Irish Pioneer Works (Fabricators) Limited Doc No GEN2-002rev24Licence No: P0407-01 Rev Date: 19 December 2018Year: 2018 Visit No: 4 Issued by: QMSampling Date: 23 November 2018Report No: 2018-212 HCL Results Calculations for A3-4

HCl Results:

mg/L as HCl Volume (ml) Sample reference

number Impinger efficiency check: Absorption efficiency(Impinger 1 should absorb 95% of total HCl):LOD 0.05 n/a 56.6 % or result in second absorber should be <LODBlank Impinger 1&2&Line Wash 0.05 188 1022369

Efficiency requirements:Run Impinger 1& Line Wash 0.08 121 1022367 not more than 5 % must be retained in the last absorber in the range of concentration examined;

Impinger 2 0.07 106 1022368 or the content in the last absorber corresponds to a concentration lower than a concentrationcorresponding to five times the analytical detection limit.

LOD 0.01 mgBlank 0.01 mgRun 0.02 mg

0.126 m3

0.12934619 m3

Stack ConditionsAverage Temperature: 307.5 K Average Pressure: 101.225 kPaAverage Moisture: 0.00 %Average Oxygen: 0.00 %Volumertic Flow Rate corrected to STP O2 ref and Moisture 12160.87 m3/hr

Reference ConditionsReference Temperature: 273.15 K Reference Pressure: 101.325 kPaReference Oxygen: 0 %Reference Moisture: 0 %

HCl Results

Results :mg/m3 mg/m3 kg/hr Uncertainty Note: Blank result should be < 10% of ELV

corrected O2 ref mg/m3Run 0.1 0.1 0.002 0.01 Blank resu 0 % of ELV

Blank 0.1 0.1 0.0009 0.01 If the blank result is higher than requirements of ELV result should be rejectedLOD 0.1 0.1 0.0011 n/a



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Uncertainty calculation for EN 14791 Determination of mass concentration of HCl, Reference method (taken from SO2 uncertainty STA website)

rev2 RunLimit value (ELV) 30 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.1 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertainty a Requirement of stdSampled Volume Gas Vm 0.12934619 uVm 0.001 m3

0.77 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 2.00 <2.5 kSampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Concentration in impinger C 0.08 uC 0.00225 mg/l 3.00 <5%Impinger solution volume VS 0.227 uVS 0.001 l 0.44 <1%Mass m 0.02 um 0.00 mg 3.03 0.01 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 2 % 2.00 <=2%Intermediate calculationsFactor for std conds fs 0.89uncertainty components symbol sensitivity coeff u (in units of fs)

ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55



O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %Corrected Volume (standard c V 0.11 m3 1.15 0.00 mg.m-3 #DIV/0! %Mass m 0.02 mg 7.73 0.00 mg.m-3 #DIV/0! %Factor for O2 Correction fc 1.00 0.13 0.00 mg.m-3 #DIV/0! %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 #DIV/0! %




Expanded uncertainty as percentqge of limit value 0.0 % ELVRequirement in standard is for uncertainty to be < 20% at ELV at standard conditions

sm fVV =

m

refc O

Of

,2

,2

2121

−

−=

3.101273

100)100( m

m

ms T

Hf

ρ−=

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Uncertainty calculation for EN 14791 Determination of mass concentration of HCl, Reference method (taken from SO2 uncertainty STA website)

BlankLimit value (10% of ELV) 3 mg.m-3 Reference oxygen 0 % by volumeMeasured concentration 0.1 mg.m-3 (at reference conditions)Measured Quantities Symbol Value Standard uncertainty Units Uncertaint Uncertainty a Requirement of stdSampled Volume Gas Vm 0.12934619 uVm 0.001 m3

0.77 <=2%Sampled gas Temperature Tm 307.5 uTm 2 k 2.00 <2.5 kSampled gas Pressure ρm 101.225 uρm 1 kPa 0.99 <=1%Sampled gas Humidity Hm 0 uHm 1 % by volume 1.00 <=1%Oxygen content O2,m 0 uO2,m 0.1 % by volume #DIV/0! <=5%Concentration in impinger C 0.025 uC 0.00075 mg/l 3.00 <5%Impinger solution volume VS 188 uVS 0.001 l 0.00 <1%Mass m 0.01 um 0.00 mg 3.00 0.07 <5% of limit valueNote - Sampled gas humidity, temperature and pressure are values at the gas meterLeak L 2 % 2.00 <=2%


ρm 0.009 0.009Hm 0.009 0.009Tm 0.003 0.006ufs 0.014 1.55



O2,m 0.05 0.005Factor for O2 Correction ufc 1.00 0.005 0.48Parameter Value Units Sensitivity coeff Uncertainty contribution Uncertainty as %Corrected Volume (standard c V 0.11 m3 0.63 0.00 mg.m-3 #DIV/0! %Mass m 0.01 mg 7.73 0.00 mg.m-3 #DIV/0! %Factor for O2 Correction fc 1.00 0.07 0.00 mg.m-3 #DIV/0! %Leak L 0.00 mg.m-3 1.00 0.00 mg.m-3 #DIV/0! %




Expanded uncertainty as percentqge of limit value 0.2 % ELV

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Test Certificate Date 10/12/2018

Glenside Environmental

Unit 18

Great Island Industrial Estate

Innishmore

Ballincollig

Cork

Client Order No. 2018-212 IPW Q4

WK18-8316Certificate No.

Issue No. 1

Contact 30/11/2018Date ReceivedEwa Piatek

Description 3 solutions for HCL Technique IC Stack

Analysis Method Accreditation Method LOD UncertaintyParameter

C27 0.05ug/ml 7.00%Hydrochloric acid UKAS

Sample No. 1022367 212-08 HCL A3-4 Impinger 1 & line wash

run

Method

C27(U)Hydrochloric acid 0.08 µg/ml 121 ml

Sample No. 1022368 212-09 HCL A3-4 Impinger 2 run Method

C27(U)Hydrochloric acid 0.07 µg/ml 106 ml

Sample No. 1022369 212-10 HCL A3-4 Blank Method

C27(U)Hydrochloric acid <0.05 µg/ml 188 ml

RPS Laboratories Ltd. Unit 12. Waters Edge Business Park. Modwen Road. Salford. M5 3EZ

Tel: (0161) 872 2443 Fax: (0161) 877 3959

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Date 10/12/2018Test Certificate


1Issue No.

Client Glenside Environmental

Approved By Date

Tammy IllingworthTested By 04/12/2018Date

For and on authority of RPS Laboratories Ltd.

Method Symbols (U) Analysis is UKAS Accredited

(N) Analysis is not UKAS Accredited

Concentration values (mg/m3 and ppm) are not covered by the scope of UKAS accreditation.

Results stated as ml are refering to the sample volume.

Analysis carried out on samples 'as received'

This document may not be reproduced other than in full, except with the written approval of the issuing laboratory.

RPS Laboratories terms and conditions apply - a copy is available on request.

06/12/2018

10/12/2018

Joanne Dewhurst

Operational Manager


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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Unit 18


Innishmore

Ballincollig

Cork



Issue No. 1


Description 7 samples for Lead & Zinc Technique ICP Stack

Sample No. 1022370 212-11 Metals Filter Method

M31-BSEN14385(U)<0.3 ugLead

M31-BSEN14385(U)1286 ugZinc

Sample No. 1022371 212-12 Metals Impinger 1 & 2 Method

M31-BSEN14385(U)3 ug/l 132 mlsLead

M31-BSEN14385(U)348 ug/lZinc

Sample No. 1022372 212-13 Metals Impinger 3 Method

M31-BSEN14385(U)1 ug/l 112 mlsLead

M31-BSEN14385(U)283 ug/lZinc

Sample No. 1022373 212-14 Metals Rinse Method

M31-BSEN14385(U)0.3 ug 90 mlsLead

M31-BSEN14385(U)<1 ugZinc

Sample No. 1022374 212-15 Metals Filter Blank Method

M31-BSEN14385(U)<0.3 ugLead

M31-BSEN14385(U)1 ugZinc

Sample No. 1022375 212-16 Metals Impinger Blank Method

M31-BSEN14385(U)<0.2 ug/l 216 mlsLead

M31-BSEN14385(U)<2 ug/lZinc


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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1Issue No.


Sample No. 1022376 212-17 Metals Rinse Blank Method

M31-BSEN14385(U)<0.2 ug 92 mlsLead

M31-BSEN14385(U)<1 ugZinc

Approved By Date

Calum GreenTested By 05/12/2018Date

Joanne Dewhurst

Operational Manager









Lora McKerracher 10/12/2018

11/12/2018


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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Unit 18


Innishmore

Ballincollig

Cork



Issue No. 1


Description 3 solutions for NH3 Technique IC Stack

Analysis Method Accreditation Method LOD UncertaintyParameter

A6 0.1 µg/ml 8.00%Ammonia UKAS

Sample No. 1022364 212-05 NH3 A3-4 Impinger 1 & Line wash

run

Method

A6(U)Ammonia 4.3 µg/ml 94 mg/m³

Sample No. 1022365 212-06 NH3 A3-4 Impinger 2 run Method

A6(U)Ammonia <0.1 µg/ml 96 mg/m³

Sample No. 1022366 212-07 NH3 A3-4 blank Method

A6(U)Ammonia <0.1 µg/ml 207 mg/m³


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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1Issue No.


Approved By Date

Tammy IllingworthTested By 03/12/2018Date









Lora McKerracher 05/12/2018

05/12/2018

Joanne Dewhurst

Operational Manager


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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Unit 18


Innishmore

Ballincollig

Cork

Client Order No. 2018-212-IPW Q4


Issue No. 1


Description 2 filters & 2 washes for TPM Technique Gravimetric Stack

Sample No. 1022360 212-01 Particulates A3-4 Filter Run Method

D9(U)5.42 mgTotal particulate matter

Sample No. 1022361 212-02 Particulates A3-4 Filter Blank Method

D9(U)0.17 mgTotal particulate matter

Sample No. 1022362 212-03 Particulates A3-4 Nozzle wash run Method

D9(U)<0.5 mgTotal particulate matter

Sample No. 1022363 212-04 Particulates A3-4 Nozzle wash blank Method

D9(U)<0.5 mgTotal particulate matter


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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1Issue No.


Approved By Date

Alessia TamburriTested By 07/12/2018Date

Joanne Dewhurst

Operational Manager









Kirstie Davenport 10/12/2018

10/12/2018


Tel: (0161) 872 2443 Fax: (0161) 877 3959

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environmental protection agency · 2019. 3. 26. · operator name: irish pioneer works...

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