double hull tankers corrosion

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    DOUBLE HULLS & CORROSION

    Dragos Rauta

    INTERTANKO

    The Royal Institue of Naval Architects Conference

    London, 25-26 February 2004

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    People

    the huge size of

    these ships makes

    it impossible to

    learn and train bysimulation

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    Practical logistical problems!

    Height to climb 11 km

    Area to survey 300,000 m2

    Length of weld 1,200 km

    Length longitudinals 58 km

    Bottom area 10,700 m2

    1 % pitting = 85,000 pits

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    for some 120

    years, steel hasbeen the

    common

    mater ial of

    construction

    for ships

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    Ballast tank after more than 20 yearsBallast tank after 16 years

    Ballast tank after 28 years

    the shipping industry

    has done a lot to

    progress thedevelopment of anti

    corrosive methods

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    corrosion can still

    be the number one

    enemy and turn a

    good ship into a

    "rust bucket"

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    DH particularitiesBallast Tanks

    DH/SH areas = 2-2.5 times larger Ballast tanks always wet

    Bottom shell continuously wet, submerged andmuddy

    Accumulations of mud generate a greater threat ofMIC

    DH inner shell subject to large and frequenttemperature fluctuations

    The inner shell coating has a higher crackingpotential due to flexing of the steel, and the impact ofheat on the coating

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    Ref: A study on hul conditin assessment for aged

    double hull tankers- The Shipbuilding Research

    Association of Japan Panel #242 Committee

    (March 2002)

    the insulating effect of

    double hull construction

    DH particularitiesCargo Tanks

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    DH particularitiesCargo Tanks

    the inner shell is at

    same temperature

    as cargo and higher

    temperatureincreases the

    possibility for

    corrosion at that

    location

    Ref: A study on hul conditin assessment for aged double

    hull tankers- The Shipbuilding Research Association of

    Japan Panel #242 Committee (March 2002)

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    DH particularitiesCargo Tanks

    with the introductionof water saturated

    inert gas prior to and

    throughout the

    loaded voyage, the

    vapour space in the

    cargo tanks remains

    humid with the

    humidity varying

    with the diurnalvariations of the gas

    space temperature

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    humidity in both

    cargo tanks and

    ballast tanks isthe excess

    electrolyte in DH

    the anode is the

    iron in the steel

    structure while

    the cathode is

    represented byvarious other

    elements

    including sulphur

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    Corrosion mechanisms at work

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    Fully formed Sulphur

    Crystals as found on

    rust samples from

    Cargo tanks

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    And More Sulphur

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    Corrosion Cell

    found in the InertGas Scrubber Unit

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    Hydrogen induced cracking -

    Pyrophoric Iron Sulphide

    .

    Hydrogen I nduced Cracking (H IC) and can occur where li ttleor no applied or residual tensi le stress exists. I t is manifested as

    blisters or blister cracks oriented parallel to the plate surface.

    Source: Intercorr International - Wet H2S Cracking

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    Hydrogen induced cracking -

    Pyrophoric Iron Sulphide

    Stress Oriented Hydrogen I nduced

    Cracking (SOHIC). SOHIC can have a

    greater effect of serviceabil i ty than H IC

    since it effectively reduces load carrying

    capabil i ties to a greater degree

    Source: Intercorr International - Wet H2S Cracking

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    Carbonic Acid and Wet Rust

    the inert gas needed for a

    VLCC with a cargo

    carrying capacity of

    300,000 m3 can produceas much as 12 tons of

    carbonic acid during one

    voyage

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    The ullage space

    environment is highly

    acidic and steel quality

    should be carefully

    evaluated

    Deck Head Corrosion

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    Pitting as discovered on new double

    hull tankers (MIC)

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    Pitting in the tank bottom plate

    (MIC)

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    COAT ON TANK BOTTOM

    COATING APPLIED

    ON PITTING

    CORROSION

    IN PERFECTCONDITION 5

    YEARS LATER

    NO FURTHER

    PROBLEM

    EXPECTED

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    Coated cargo tank inner bottom

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    The key issue throughout this

    analysis is the continuous high

    humidity in all ballast and cargo

    tanks as well the preservation of amuch higher temperature of the

    oil cargo

    No similar problems for thepre-MARPOL tankers.

    Limited problem for the

    post-MARPOL PL/SBT SH

    tankers. However, the DHdesign has actually created

    the conditions that give

    birth to these problems in

    all cargo and ballast tanks

    of the ship

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    Cargo tank top/bottom coating

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    Current legislation

    Since July 1st 1998 all new build oil tankers

    and bulk carriers must have a corrosion

    prevention system in compliance SOLAS

    Ch II/1 Reg. 3

    2. IMO has also issuedGuidelines for best practices with regard to

    coating through Resolution A.798(19)

    These guidelines require that:

    C l i l i A 798(19)

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    Current legislationA.798(19) Selection/Application/Maintenance of Coatings to

    be agreed by the Shipyard/Shipowner/Paint

    Manufacturer Classification Society (RO) approve these

    measures

    Hard coating + multi-coat with different coloursfor each coat, and the final colour must be light

    Application process should consider surfacepreparation (including steelwork and secondarypreparation), health, safety, environmental &quality control procedures

    The coating maintenance should be based on thedocumentation provided by the paintmanufacturer

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    Pre-striping of blasted tank

    Before 1st coatexcelent job! Proper striping before 2nd coat!

    Performing systems require two coats.

    Additional stripe coats with brush

    should be applied to welds, cut outs andall sharp edges. Sacrificial anodes

    should be installed in cooperation with

    the anode and paint manufacturers to

    avoid side effects

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    IACS/Industry WG on

    Corrosion/Coating

    A revised IACS Unified Interpretation SC 122 for

    the verification of compliance with SLAS II71

    Reg. 3-2 and A.798(19)

    A draft new IACS Unified Regulation for coatingof bottom and top structure of the cargo tanks of

    the oil tankers (new buildings only)

    Draft new IACS Guidelines for coating

    maintenance and repairs for ballast tanks and

    combined cargo/ballast tanks on oil tankers

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    The future

    Paint fit for purpose:

    - Sustain Env. Conditions

    - Elasticity

    - Durability

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    CONCLUSIONS continuous work on anti-corrosive measures

    research on the environmental conditions in thecargo or ballast tanks

    identify the adequacy of the paint

    strict control of the application, thickness of thecoating and the ambient temperature

    coatings less dependent of the accuracy of the filmthickness

    coatings with god properties and flexibility at hightemperatures at which double hull tankers operate

    the high price paid by the ship owners should givethem in return a quality product

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    CONCLUSIONS Class Societies to increase expertise & experience

    Shipbuilders to control the quality of their subcontractors Companies applying the paint to demonstrate experience

    and capability

    Shipowners to buy in expertise to monitor the entirecoating process

    Ship crews to proper monitoring, maintain and repair thecoating

    In return, longer term guarantees

    Last but not least, the industry needs to further research

    and understand the corrosion mechanisms in double hulltankers (cargo and ballast tanks) and to identify thecomponents that create that corrosion

    The elements we acknowledged today might not be theonly factors to be taken into consideration

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    I cannot imagine any condition

    which could cause this ship tofounder. I cannot conceive of any

    vital disaster happening to the

    vessel. Modern ship building hasgone beyond that.

    Capt. Edward J. Smith, H.M.S. Titanic

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    THANK YOU VERY MUCH

    FOR YOUR ATTENTION!