document frontpage exploration and production norsk hydro ... · 1. introduction. the vitrinite...

Document frontpageExploration and Production

Norsk Hydro a.s BergenE&P Research Centre

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Statoil fit)Conoco (X)ESSO (a)Norsk Hydro{OD {-X)Arkiv (2}

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GEOCHEMICAL EVALUATION

OF WELL 2 5 / 1 1 - 1 6

Keywords

GEOCHEMISTRY, SOURCE ROCKS, MATURITYOILS, CORRELATION

Pagsv&ppsrKfø Revision PQ. Revtafon date

25/11-16

Department

Proled ttc.

3241Lieens no.

PL 169Dele

12.03 .93

GEOSECTION

Section

Authors

i BASIN MOD./PETR. GEOCHEM.

Postet address:N-5020 Bergen

Office address:Sandsllveien 90&049 Sandsll

Phone:Natlona!: (05) 99 50 00Internat.; +47 5 98 50 00

Telefax:National: 05 99 66 00htemat: +4? 5 99 66 00

Teiex:40632 hydro n

1. INTRODUCTION.

The vitrinite reflectance has been determined by GeoLab UK; TOC and Rock-Evai

pyrolysis analyses were carried out at Norsk Hydro Research Center, Bergen. All

extractions, group type separations, gas chromatography and gas chromatography-mass

spectrometry were carried out by GERG. This report was compiled at Norsk Hydro

Research Center in Bergen,

A list of the samples analyzed is given in Table 1.3.

Geochemistry 25/11-16

WElt

25/11-1625/11-16

TYPECLYSTCLYST

M17141873

%28SSieranes

0 270.45

cra/bbSferørrøs

1.291.02

0.811.21

8578

%

14,310.5

Ts/Tm

0.9S0.92

Table 3.6. Selected biomarker ratios

Geochemistry 25/11 -16

10

WELL.

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

TYPE

RFTRFT

DST#3BDST#1DST#1

RFTDST#1DST#1

•%T€»iPHNGv

u6ss.::23.8018.6057.00100.0023.8021.0025,5021,70

SWUPHUR0.040.210.160,010.670.430.370.66

N3O£EL:.;;:

pjwn ;;.;;;5;1.084.441.249.816.074.623.925.36

0.4?1.942.520.16

18.2513.6711.2715.44

.;.-:; Ni/V >

2,302.290.4961.310.330.340.350.35

Table 4.1.: Quadrant 25 oils bulk parameters.


H

*

WELL

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

TYPE

RFTRFT

DST #3BDST#1DST#1

RFTDST#1DST#1

HEPTANE

RATIO

0.583.91

25,1728.1915.138.132.471.57

ISG-HEPT.

RATIO

0.570.660.670.830.580.370.40.5

MRAHNICITY

0.010.080.570.760.320.190.040.03

A&OMATTC3TY

1.332.550.830.120.843.073.023.46

Tabie 4.2.: Molecular ratios from gasoline range hydrocarbons.


15

25/11-625/1 1-625/11-625/11-625/11-625/11-625/H-625/1-9

25/2-1025/5-125/6-125/8-125/8-425/11-5

25/11-15

tt¥&SSTSSTSSTSSTSSTSSTSSTRFTRPT

DST #3BDST#1DST#1

RFTDST#1DST#1

M

17611773177817811798

1802.518072650225226872276

1750

1688

0.870.890.9

0.910.770.80.80.550.690.710.580.710.830.8

0.83

MFi-2

0.920.970.960.990.870.880.9

0.550.690.710.580.710.830.8

0.83

£c^> ::

0.920.940.940.950.860.880.880.730.810.830.750.820.90.880.9

Table 4.8. Results from GC of aromatic hydrocarbons.


16

25/11-1625/11-1625/11-1625/11-1625/11-1625/11-1625/11-16

25/1-925/2-1025/5-125/6-125/8-125/8-4

25/11-525/11-15

SSTSSTSSTSSTSSTSSTSSTRFTRFT

DST#3BDST#1DST#1

RFTDST#1DSTtl

17611773177817811798

1802.518072650225226872276

1750

1688

0.620.560,570.550.560.570.570.640.660.580.390.560.550.560.58

0.460.840.860.860.890.860.870.830.640.961.230.90.780.910,78

1.161.41

1.180.950.991.022.881.981.731,561.511.481.161.51

828486838584866776724575797579

4.36.15.65.55.65.75.94.65.55.717.46.25.36.35.6

1.311,191,091.20.960.850.943.382.771.530,441.371.361.171.34

Table 4.9. Selected biomarker ratios.


TABLE: 1.2P e t r o l e u m G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e n

STRATIGRAPHY, WELL MOR:25/11-16HYDRO

TOP(ffi)

145.01698.01733.01739.01767.01872.01885.01698.01897.01897.0

BOTTOMCm)

1698.01733.01739.01767.01872.01885.01897.01897.01920,01920.0

Si(kg/t)

0.10.1

0,0

0.2

0.1

S2(kg/t)

1.31.4

0.6

1.2

1.1

SimpleTOC(%)

0.71.1

0.2

0.3

0.6

MeanHI

246126

317

366

250

PI

0.10.1

0.0

0.1

0.1

Tmax VRo

4 35431

431

WeightedSI

(kg/t)

0.10.1

0.0

0.1

S2(kg/t

1.21.4

0.6

1.0

Mean -TOC(%)

0.61.1

0.2

0.4

HI

234126

317

316

TABLE: 1.3P a t r o l e u i i i G e o c h e m i s t r y G r o u p

R e s e a r c h C e n t r e B e r g e n

ANALYSIS PROGRAMME, WELL NOR:25/11-16HYDRO

Depth(Hl)

1355.001380.001408.001428.501470.001488.001505.001565.001582.001599.001616.00

1633.001655.001660.501665.501674.001680.001686.001691.001695.001697.001700.00

1714.001745.001748.001767.001773.001778.001781.001798.001802.501807.001873.00

Lithology

CLYSTCLYSTCLYSTCLYSTCLYSTCLYSTCLYSTCLYSTCLYSTCLYSTCLYST


CLYSTCLYSTCLYSTSSTSSTSSTSSTSSTSSTSSTCLYST

Type

SWCSWCSWCSWCSWCSWCSWCSWCSWCSWCSWC

SWCSWCSWCSWCSWCSWCSWCSWCSWCSWCSWC

COCHSWCSWCCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCH

R-Ev

11111111111

1.1111111111

111

1

Extr

1

11111111

MPLC

1

11111111

latr SatGC PyGC

1

11111111

Isot Biom Vitr VisK

1

11111111

TABLE; 1.3

ANALYSIS PROGRAMME, WELL NOR:25/11-16 (cont'd)

P e t r o l e u m G e o c h e m i s t r y G r o u p


HYDRO

Depth Group/Fm.(m)

Lithology Type

1925.001932,001939.00

LSTLSTLST

swcswcswc

R-Ev Extr MPLC latr SatGC PyGC Isot Biom Vitr VisK

111

R - E v = E o c k B v i l ,

E x t r = E x t r a c t i o n ,

M P L C = S e p a r a t i o n ,

l a t r — l a t r o s c a n ,

S a t G C = S a t u r a t e d G C ,

P y G C = F y r o l y s i s G C ,

I s o t = I s o t o p e ,

. B i o m = B i o m . a c k e r s .

V i t r = V l o | i v e | 5 ,

V i s K = V i s u a l K e i r o g e n

TABLE: 1.3P e t r o l e u m G e o c h e m i s t r y G r o u p


ANALYSIS PROGRAMME, WELL NOR;25/1-9HYDRO

Depth(m)

2650.50

Group/Fm, Lithology Type

OIL

R-Ev Extr

1

MPLC

1

latr SatGC

1

PyGC I sot

1

Biom Vitr VisK

R - £ v =• R o c k E v a l ,



l a t r = l a t r o s c a n ,

S a t G C ^ S a t u r a t e d G C ,

P y G C = P y l o l y s i s G C ,


B i o i = B i o m a r k e r s ,

v i t r = v R o ( a v e ) % ,

V i s K — V i s u a l K e r o g e n



ANALYSIS PROGRAMME, WELL NOR:25/2-1OSHYDRO

Depth(m)

2252.50

Group/Fm. Lithology Type

OIL

R-Ev Extr

.1

MPLC

1

latr satGC

1

PyGC Isot

1

Biom Vit r VisK

H ~ E v K R o c k E v a l ,


M P L C = S e p a r a t i o n , S a t G C

l a t r = I a t r o s c a n , P y G C

= S a t u r a t e d G C ,

= P y r o l y s i s G C ,


B i o m = B i o m a r k e r s ,

V i t r = V R o ( a v e } % ,

V i s i t = V i s u a l K e r r o g e n




Depth(m)

3002.00


OIL

R-Ev Extr

1

MPLC

1

I at r SatGC

1

PyGC I sot

1

Biom Vitr VisK

H - E v = R o c k E v a l ,


M P L C a S e p a r a t i o n , S a t G C

l a t r = l a t r o s c a n , P y G C

= S a t u r a t e d c, c , I s o t

= P y r o - l y s i s G C , B i o »

= I s o t o p e ,

= B i o m a r k e r s ,

V i t r = V H o ( a u e ) % ,

V i s K = V i s u a l K e r o g e n

r

TABLE: 1-3P e t r o l e u m G e o c h e m i s t r y G r o u p



Depth(KV)

2279.70


OIL

R-Ev Extr

1

MPLC latr SatGC

1

PyGC Isot

1

Biom Vitr VisK

R - E v = R o c k E v a l ,



latt* = l a t r o s c a n ,

S a t G C = S a t u r a t e d G C ,

P y G C =• P y r o l y s i s G C ,

I s e t = I s o t o p e ,

B i o m = B i o a a r k e r s ,

v i t r = V E o ( a v e ) % ,

V i s K = V i s u a l K e t o g e n




Depth(IB)

57.82.00

Group/Fm, Lithology Type

OIL

R-Ev Extr

1

MPLC

1

Iatr SatGC

1

PyGC I sot

1

Bioin Vitr VisK

R - E v = K o c k E v a l , M P L C =

E x t r •= E x t r a c t i o n , I a t r =

S e p a r a t i o n ,

I a t r o s - c a t i ,

S a t G C = S a t u r a t e d G C , I s o t

P y G C = P y r o l y s i s G C , B i o m

= I s o t o p e ,

= B i o æ a r k e t S ,

V i t r = V R 6 ( a v e ) % ,

V i s S = V i s u a l K e r o g e n

TABLE: 1.3P e t r o l e u m G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e n


DepthCm}

1750.70

Group/Fm,

LISTA I

Lithology Type

OIL

R-£v Extr

1

MPLC

1

latr SatGC

1

PyGC Isot

1

Biom Vitr VisK

R - E v = R o c k E v a l ,



l a t r = l a t r a s c a n .

S a t G C = S a t u r a t e d G C , I s o t

P y G C = P y r o l y s i s G C , B i o u

= I s o t o p e ,

= B i o m a r k e r s ,

V i t r =• V R o ( a v e ) % ,

V i s K = V i s u a l K e t o g e n



ANALYSIS PROGRAMME, WELL MOR:25/11-5HYDRO

Depth(m)

5790.00


OIL

R--Ev Extr

I

MPLC

1

latr SatGC

1

PyGC I sot

1

Biom Vitr VisK

J - E v = H o c k E v a l , M P L C

E x t r = E x t r a c t i o n , l a t r

= S e p a r a t i o n , S a t G C

= l a t r o s c a n , P y G C

s S a t u r a t e d G C ,

- P y r o l y s i s G C ,

I s o t . = I s o t o p e ,

B i o m a B i o m a r k e r s ,

V i t r = V R o ( a v e ) % ,

V i s K = V i s u a l K e r o g e n

Well I.D.: Norsk Hydro

SampleD( fh

1355140814701505158216331665.51695170217101717172517351742 - 17451745 SWC18 57187018^0IE i

R.o.Avg.

0.320-340.320.340.420.410.400.380.430.430.420.420.420.45NDP0.450.490.500.59

No. ofDeterminations

20202014611201520201443_2346

Table 2.1. Average vitrinite reflectance.

TABLE: 3.1f e t r o l e u a G e o c h e m i s t r y G r o u p


HYDROROCK EVAL SCREENING DATA,

Depth(m)

1355,001380.001408.001428.501470.001488.001505.001565.001582.001599.001616.00

1633.001655.001660.501665,501674,001680.001686.001691.001695.00169-7,001700.00

1714.001745.001748.001764,751778.001778.501779.001779.501780.001780.501781.00

WELL NOR:25/11-16

Lithology



CLYSTCLYSTCLYSTSSTSSTSSTSSTSSTSSTSSTSST

Type

swcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswcswc

COCHswcswcCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCH

TmaxDegC

430429427419

4 54478

427

427424432

431

421427424425427427426427

SIkg/t

0.20.20.20.10.00.00.00.00,00.00.1

0.10.10.00.00.00.00.00.10.50.60.1

0.20.00.0

21.849.351.756.659.157.754.660.0

S2kg/t

2.42.72.60.70.70.50.30.60.70.51.6

0.71.70.80.70.91.11.01.02.34.71.4

1.50.70.65.4

19.1.22.124.82.5 .625.422.627.8

TOC%

1.31.51.70.50.40.20.20.40.20.20.4

0.20.20.40.50.30.50.60.51.42.70.9

1.30.20.22.56.06.67.27.47.36.87.7

HI

187171151122168226182150383274410

365874224126253214175192167172144

110300335218316338347344348331360

PI

0.070.060.060.110.010,020.030.050.010.050.06

0.060.030.030.040.030.030.030.050,170.110.05

0.090.040.020.800.720.700.700.700.690.710.68

Analysing Company

F-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGENF-BERGEN



TABLE: 3.1P e t r o l e u i G e o c h e m i s t r y G r o u p

R e s e a r c h C e n t r a B s r g e n

HYDROROCK EVAL SCREENING DATA,

Depth(m)

1781.501782.001782.501783.001783.501784.001784.501788.301788.701789.101789.50

1790.501873.001925.001932.001939.00

WELL NOR:25/11-1.6

Lithology

SSTSSTSSTSSTSSTSSTSSTSSTSSTSSTSST

SSTCLYSTLSTLSTLST

{ eont

Type

COCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCH

COCHCOCHSWCSWCSWC

d)

TmaxDegC

428347425426425428424427426423420

418

SIkg/t

72.564.356.957.750.860.346.437.531.722.38.0

8.80.20.00.00.0

S2kg/t

35.638.123,724.920.827.917.112.811.96.72.5

2.31.20.10.00.0

TOC%

9.49.17.17.36,37,85.74.53.92.71.1

1.10.30.00.00.0

HI

377420335342328359302286307249238

214367350500

PI

0.670.630.710.700.710.680.730.750.730.770.76

0.800.150.00

Analysing Company


F-BERGENF-BERGENF-BERGENF-BERGENF-BERGEN



HYDROSEDIMENT

Depth<m)

1714.001873.00

EXTRACTION PERCENTAGES (GRAVIMETRIC)

Lithology

CLYSTCLYST

, WELL NOR:

Type

COCHCOCH

EGM(rog)

28.029.0

25/11-16

EOM(%)

0.280.29

Hydrocarbons(%)SAT ARO TOTAL

Non Hydrocarbons(%)POL ASP TOTAL

4.1 4.119.8 19.8

TABLE: 3.3

SEDIMENT EXTRACTION RATIOS (GRAVIMETRIC), WELL NOR:25/11-16

P e t r o l e u m G e o c h & m i s t r y G r o u p


HYDRO

Depth(m)

1714.001873.00

Lithology

CLYSTCLYST

Type

COCHCOCH

TOC<%)

1.30.3

EOM/TOC(%) (%)

0.20.9

SAT/TOC

U) (%)SAT/ARO{%) (%)

HC/Non HC(%) (%)

TABLE; 3.4P e t r o l e i ! » G e o c h e m i s t r y G r o u p


SATURATED FRACTION MOLECULAR RATIOS (SEDIMENT SAMPLES), WELL NQR:25/ll-16HYDRO

Depth(m)

1714.001873.00

Lithology

CLYSTCLYST

Type

COCHCOCH

Pristane/nC17

0.50.4

Pristane/Phytane

2.62.8

CPI-

1.1.

I CPI-II

88

nCl7/nCl7+nC27

AnalysingCompany

GERGGERG

TABLE: 3.5

ISOTOPE ANALYSIS RESULTS (SEDIMENT SAMPLES), WELL NOR:25/11-16



HYDRO

Depth(at)

1714.001873.00

Lithology

CLYSTCLYST

Type

COCHCOCH

dl3CExtr

-28.40-28.20

d!3CSAT

-27.90-28.20

d!3CARO

-27.20-28.50

dl3CPOL

dl3CASP

dl3CKero

AnalysingCompany

GERGGERG

TABLE: 4.3

OIL COMPOSITION RATIOS (GRAVIMETRIC), WELL ROR:25/l-9


R e s e a r c h C e n t r a B e r g e n

HYDRO

St.Depth En.Depth Group/Fm(n») <m)

Name

2650.50 2650.50 RFT # 2C

Hydrocarbons {%)SAT ARO TOTAL

53.5 35.6 89.1

Non Hydrocarbons (%)POL ASP TOTAL

8.1 2.8 10.9

SAT/ HC/ARO Non-HC

1.5

TABLE: 4.3P e t r o U u i s G e o c h e m i s t r y G r o u p


HYDROOIL COMPOSITION RATIOS (GRAVIMETRIC),

St.Depth

2252.50

En.Depth Group/Fro(m)

2252.50

WELL MOS

Name

RFT

:.25/2-10S

HydrocarbonsSAT ARO

53.8 32.5

TOTAL

86.3


10.6 3,1 13.7

SAT/ARO

1.7

HC/Non-HC

6.3

TABLE: 4.3

OIL COMPOSITION RATIOS (GRAVIMETRIC), WELL NOR:25/5-l

P e t t o l e u » G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e n

HYDRO

St.Depth En.Depth Group/Pm(m) (m)

Name Hydrocarbons (%)SAT ARO TOTAL


SAT/ HC/ARO Non-HC

2687.00 3002.002687.00 3002.00

DST # 3BDST # 3B

46.851.9

20.831.1

67.783.0

27.912.7

4.44.3

32.317.0

2,21.7

2.14.9

TABLE: 4.3

OIL COMPOSITION RATIOS (GRAVIMETRIC), WELL NOR:25/6-1

P e t r o l e u m G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e n

HYDRO

St. Depth En. Depth Grotip/Fm(m) (m)


Non Hydrocarbons {%!POL ASP TOTAL

SAT/ HC/ARO Non-HC

2276.70 2213.1$ DST # 1 49.3 8.2 57.5 38.8 3.7 42.5 6.0 1.4

TABLE: 4.3

OIL COMPOSITION RATIOS (GRAVIMETRIC), WELL NOR:25/8~1



HYDRO

St.Depth En.Depth Group/Fm(m) (m)



SAT/ EC/ARO Non-HC

5758.00 5782.00 DST # 1 41.1 39.7 80.7 15.1 4.2 19.3 1.0 4.2

TABLE: 4.3


P e t r o l e u m G e o c h e s i s t t y G r o u p


HYDRO

St.Depth En.Depth Group/Fm(m) (m)

Name

1750.70 1750.70 RFT

Hydrocarbons {%)SAT ARO TOTAL

4 4.7 36.8 81.4

Non Hydrocarbons {%}POL ASP TOTAL

14.5 4.1 18.6

SAT/ EC/ARO Mon-HC

1.2 4.4

TABLE: 4.3

OIL COMPOSITION RATIOS (GRAVIMETRIC), WELL NOR:25/Il-5


R e s e a r c h C e n t r e B s t g e n

HYDRO

St. Depth En .'Depth Group/Fm(m) (m)"


Non Hydrocarbons (%}POL ASP TOTAL

SAT/ HC/ARO Non-HC

5740.00 5790.00 DST # 1 49.8 32.2 82.0 14.7 3.3 18.0 1.5 4.6

TABLE- 4.3




HYDRO

St.Depth En-Depth Group/Fm(m) (m)


Non Hydrocarbons (%!POL ASP TOTAL

SAT/ HC/ARO Non-HC

1688.80 1704.10 DST # 1 40.8 39.6 80.4 15.3 4.3 19.6 1.0 4.1

TABLE: 4.4

SEDIMENT EXTRACTION PERCENTAGES (GRAVIMETRIC), WELL NOR:25/1!-16

P e t r o l e u m G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e n

HYDRO

Depth(m)

1764.751767.001773.001778.001778.001781.001781.001782.001783.001784.501790.50

1798.001802.501807.00

Lithology

SSTSSTSSTSSTSSTSSTSSTSSTSSTSSTSST

SSTSSTSST

Type

COCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCHCOCH

COCHCOCHCOCH

EOM(mg)

58.5695.0855.0825.070.979.1

7 50.054.560.059.559.2

447.0381.0491.0

EOM(%)

3.256.958.558.258.65

10.997.50

10.909.847.351.3 4

4.473.814.91

Hydrocarbons!%)SAT ARO TOTAL

Non Hydrocarbons(%)POL ASP

4.33.84.24.94.75.14.44.56.45.1

8.47.5

27.6

TOTAL

4.33.84.24.94.75.14.44.56.45.1

8.47.5

27.6

TABLE: 4.5

ISOTOPE ANALYSIS RESULTS (SEDIMENT SAMPLES), WELL NOR:25/11-16



HYDRO

Depth(m)

1767.001773.00.1778.001781.001798.001802.501807.00

Lithol-ogy

SSTSSTSSTSSTSSTSSTSST

Type

COCHCOCHCOCHCOCHCOCHCOCHCOCH

dl3CExtr

-28.60-28.50-28.50-28.50-28.30-28.20-28.20

dl3CSAT

-29.10-29.10-29.00-29.00-28.80-28.70-28.80

dl3CARO

-27.80-27.80-27.80-27.70-27.80-27.90-27.60

d!3CPOL

dl3C dl3CASP Kero

AnalysingCompany

GERGGERGGERGGERGGERGGERGGERG

Table 4.5 Stable carbon isotope data, oil samples.

HYLAB RESULTS MANAGEMENT : ISOTOPE ANALYSIS RESULTS SELECTED FROM SCREEN

Well

25/1-4

25/1-9

25/2-10S

25/5-1

25/5-1

25/6-1

25/6-1

25/8-1

25/8-1

25/8-4

25/11-5

25/11-5

25/11-15

25/11-15

Type

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

St.Depth

0.00

2650.50

2252.50

2687.00

2687.00

2276.70

2276.70

5758.00

5758.00

1750.70

5740.00

5740.00

1688 ..80

1688.80

En.Depth

0.00

2650.50

2252.50

3002.00

3002.00

2279.70

2279.70

5782.00

5782.00

1750.70

5790.00

5790.00

1704.10

1704.10

Oil Extr

-26.69

-28.40

-28.30

-27.69

-280.28

-27.91

-27.80

-28.50

-26.93

-28.40

-28.50

-26.47

-28.40

Sat

-27.53

-28.60

-28.60

-28.62

-28.50

-28.32

-28.90

-28.40

-29.19

-28.94

-28.90

Aro

-26.70

-28.40

-28.00

-27.35

-27.50

-26.55

-27.00

-28.20

-28.20

-28.10

-28.14

-28.20

NSO

-26.66

-27.11

-26.17

-28.10

Asph Pyro

-27.33

-27.83

-27.75

-28.17

Kero Sample ID

-979970564

-979981623

-979981622

-979981620

-979981620

-979981619

-979981619

-979981618

-979981618

-979967396

-979981617

-979981617

-979979161

-979979161

Dup

1

1

1

1

1

1

1

1

1

1

1

1

1

1

TABLE: 4.6

SATURATED FRACTION MOLECULAR RATIOS (SEDIMENT SAMPLES), WELL NOR:25/11-16

P e t r o l e u m G e o c h e m i s t r y G r o u pR e s e a r c h C e n t r e B e r g e r s

HYDRO

Depth(m)

1767.001773.001778.001781.001798.001802.501807.00

Lithology

SSTSSTSSTSSTSSTSSTSST

Type

COCHCOCHCOCHCOCHCOCHCOCHCOCH

Pristane/nCl7

0.40.60.60.60.60.60.8

Pristane/Phytane

2.01.51.31.32,01.46.2

CPI-I CPI

1.11.31.21.31.11.20.7

-11 nCl7/nC!7+nC27

AnalysingCompany

GERGGERGGERGGERGGERGGERGGERG

Table 4.7 Molecular ratios saturated hydrocarbons, of! samples.

HYLAB RESULTS MANAGEMENT : SATURATED GC ANALYSIS RESULTS SELECTED FROM SCREEN

Well Type St.Depth En.Depth Pris/Phyt Pris/nC!.7

25/1-9

25/2-10S

25/5-1

25/6-1

25/8-1

25/8-4

25/11-5

25/11-15

25/11-15

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

OIL

2650.50

2252.50

2687.00

2276.70

5758.00

1750.70

5740.00

1688.80

1688.80

2650.50

2252.50

3002.00

2279.70

5782.00

1750.70

5790.00

1704,10

1704.10

1.6

1.4

1.9

2.6

1,6

1.9

1.3

1.6

1.8

10.2

1.40.6

0.6

0.9

1.8

1.0

1.0

1.0

I

2.6

1.2

1.2

1.5

1.1

1.1

1.1

0.9

1.5

CPI(P) Sample ID

-979981623

-979981622

-979981620

-979981619

-979981618

-979967396

-979981617

0.8 -979979161

-979979161

Dup Father ID Type

1

1

1

1

1

1

1

1

1

Vitrinite reflectance readings.

Sample ID; 25/11-16 1355R.o. Aver.: 0.32 (20)Lithology: Silty shale - 100%Fh-->oclast Content: Low

? Vitrinite: 90%Inertinite: 10%Exinite:

UV fluorescence: Spores - low - y; Carbonate - low - yBitumen: Stain - mod; wisps - modVR populations: 1Mineralogy: ForamsGeneral Comments: -0.340.340.360.320.310.290.320.310,280.260-2-8o •-§o. yb0.370.310.310.430.260.360.28

Sample ID: 25/11-16 1408R. o. Aver.. : 0.34 (20)Lithology: Silty shale - 100%Pb \oclast Content: Low

;: Vitrinite: 80%Inertinite: 20%Exinite:

UV fluorescence: Algae - trace - g/y; spores - low - yBitumen; Stain - mod/strong; wisps + blebs - mod/richVR populations: 1Mineralogy:General Comments: -0.270.390.270.300.290.340.340.390.300.280.390 I0.530.300.330.360.380.450.440.27

Sample ID: 25/11-16 1470R.o. Aver.: 0.32 (20)Lithology: Shale - 100%Ph"toclast Content: Low

1 Vitrinite:Inertinite:Exinite: -

UV fluorescence:Bitumen: Stain -VR populations: 1Mineralogy: IronGeneral Comments:0.340.310.330.290.310.300.330.270.440.430.300. --30. -10.290.270.250.310.300.290.36

50%50%

Spores - trace - y-y/olight/mod; wisps - mod

oxide specks—

Sample ID; 25/11-16 1505R.o. Aver.: 0.34 (1)Lithology: Clay Ironstone - 100%P3r*+,oclast Content; Virtually barren

I Vitrinite: OneInertinite: TraceExinite: -

UV fluorescence: Spores - low y + y/oBitumen: Stain - trace; wisps - traceVR populations: 1Mineralogy: Siderite rich; Iron oxide tracesGeneral Comments: -0.34

Sample ID: 25/11-16R.o. Aver.: 0.42 (4}Lithology: Shale - 1001Pb-'toclast Content: Trace

? Vitrinite: TraceInertinite: TraceExinite: -

UV fluorescence:Bitumen: Stain -VR populations: 1Mineralogy: IronGeneral Comments:0.400.350.460.47

1582

Sporeslight

-low - y/o

oxide specksPhytoclasts very degraded

Sample ID: 25/11-16 1633R.o. Aver.: 0.41 (6)Lithology: Shale - 100%Pbv'toclast Content: Trace

P Vitrinite: TraceInertinite: TraceExinite:

UV fluorescence: Spores - low - y + y/oBitumen: Stain - light; wisps - lowVR populations: 1Mineralogy: Iron oxide specksGeneral Comments: Phytoclasts degraded0.430.350.410.450.440.40

Sample ID: 25/11-16 1665.5R.o. Aver.: 0.40 (11)Lithologyt Shale - 100%Ph loclast Content: Low

? Vitrinite: TraceInertinite: 100%Exinite:

UV fluorescence: Spores - mod - y + L.O.Bitumen: Stain - light/mod; wisps - lowVR populations: 1Mineralogy: Iron oxide specksGeneral Comments: -0.400.350.380.470.410.370.410.430.420.360.38

Sample ID: 25/11-16 1695R.o. Aver.: 0.38 (20)Lithology: Shale - 100%Phvtoclast Content: Low - moderate

I Vitrinite: 10%Inertinite: 90%Exinite: -

UV fluorescence: Algae - trace - y; Spores - mod - y-y/oBitumen: Stain - light/mod; wisps + blebs - mod/richVR populations: 1Mineralogy:General Comments: -0.310.350.330.480.390.300.350.420.400.430.35

0. f0.390.380.420.390.380.340.41

Sample ID: 25/11-16 1702R.o. Aver.: 0.4 3 (15)Lithology: Shale - 90%; Cement - 10%Pt loclast Content: Low

Vitrinite: TraceInertinite: 100%Exinite:

UV fluorescence: Spores - mod - y-y/oBitumen: Stain - light; wisps - modVR populations: 1Mineralogy: Iron oxide specksGeneral Comments: -0.540,410.470.380.440,420.480.330.340.410.410 B0.540.420.4 5

Sample ID: 25/11-16 1710R.o. Aver.: 0.43 (20)Lithology: Shale - 100%Ph toclast Content: Low - moderate

; Vitrinite: 10%Inertinite: 90%Exinite: -

UV fluorescence: Spores - mod - y/oBitumen: Stain - light? wisps - mod/richVR populations: 1Mineralogy: Iron oxide specks - rather pyriticGeneral Comments: -0.400.420,490.460.370.480.460.40G.410.450.450 t>0 . ̂ 30.450.360.440.400.430.440.47

Sample ID: 25/11-16 1717R.o- Aver.: 0.42 (20)Lithology: Shale - 70%; Carbonate - 20%; Sand grains - 10%Pb**toclast Content: Low

l; Vitrinite: 10%Inertinite: 90%Exinite:

UV fluorescence: Dino. - low - y; Spores - low/mod - y-y/oBitumen: Stain - light; wisps - ssod/rich in shaleVR populations: 1Mineralogy: Iron oxide specksGeneral Comments: -0.450.430.460.410,410.380.380.390,430.350.400. "-20 . Jl0.360.490.420.480.480.430.41

Sample ID: 25/11-16 1725R.o. Aver.: 0.42 (14)Lithology: Shale - 100%; Coarse carbonate -Pb'-toclast Content: Low

* Vitrinite: Traceinertinite: 100%Exinite:

UV fluorescence: Spores - mod - y-y/oBitumen: Stain - light; wisps - mod/richVR populations: 1Mineralogy: Rather pyritic; Iron oxide specksGeneral Comments: -0.450.380.380.390.430.440.370.360.410.460.510 %

o. A0.43

trace

Sample ID: 25/11-16 1735R.o. Aver.: 0.42 { 4)Lithology: Shale - 1001Ph' %oclast Content: Trace

:: Vitrinite: TraceInertinite: 100%Exinite:

UV fluorescence: Spores - mod - y-y/oBitumen: Stain - light; wisps ~ mod/richVR populations: 1Mineralogy: Pyritic;Iron oxide specksGeneral Comments: -0.400.430.430.43

Sample ID:R.o. Aver.Lithology:

Fhytoclast

25/11-16; 0.45 (3)

Shale - 90%- trace

Content: Trace

1745

Calcite fragments - 10%; Sand grains

Vitrinite:Inertinite:Exinite:

UV fluorescence:Bitumen: Stain -VR populations: 1Mineralogy: IronGeneral Comments:0.460.390.40

3%100%

Algalnil -

wisps - trace - y? Sporeslight; wisps - very low

- trace - y-y/o

oxide specks; glauconite

Sample ID: 25/11-16 1745 SWCR.o. Aver.: NDPLithology: Shale - 100%Ph*̂ |:oclast Content: Very low

I Vitrinite:inertinite: 100%Exinite:

UV fluorescence: Spores - trace - y-y/oBitumen: Virtually no staining or wispsVR populations: -Mineralogy: Shale whiteGeneral Comments: -

Sample ID: 25/11-16 1857R.o. Aver.; 0.45 (2)Lithology: Sandstone - 80%; Shale - 20%Ph-*oclast Content: Trace

f Vitrinite: TwoInertinite: 100%Exinite: -

UV fluorescence:Bitumen: Stain - light; wispsVR populations: 1Mineralogy: Iron oxide staining in most shale cuttings;

glauconite tracesGeneral Comments: Phytoclasts in shale0.440.46

Spores - trace - y-y/omod in a few shale cuttings

Sample ID: 25/11-16 1870R.O. Aver.: 0.49 (3)Lithology: Sandstone - 80%; Shale - 20%Pt" loclast Content: Trace

: Vitrinite: 3Inertinite: TraceExinite: -

UV fluorescence: Algae - trace - g/y; spores - trace - yBitumen: Stain - light; wisps - low in a few shale cuttingsVR populations: 1Mineralogy: Iron oxide staining in some shale cuttingsGeneral Comments: Readings on a single shale cutting0.510.470.50

Sample ID: 25/11-16R.o. Aver.: 0.50 (4)Lithology: Sandstone -Phytoclast Content: Trace

1 Vitrinite: Trace

1890

70%; Shale - 30%

uvBiVR

Inertinite:Exinite: -

fluorescence:tumen: Stain -populations: 1

Mineralogy: ironGeneral Comments:0.0.0.0.

51544747

Trace

Spores - lowlight; wisps

oxide specks—

- y + L.O.; Carbonate- low in shale

+ light staining

low

Spores - low

Sample ID: 25/11-16 1897R.o, Aver.: 0.59 (6)Lithology: Sandstone - 60%Pb.̂ -toclast Content: Very low

I Vitrinite: TraceInertinite: 100%Exinite: -

UV fluorescence:Bitumen: Stain - light; wispsVR populations: 1Mineralogy: Iron oxide specks + stainingGeneral Comments: -0.560.620.540.570.6.60.61

shale - 40%

y/omod in shale

Well I.D.:

SampleD€ |h

1355140814701505158216331665.51695170217101717172517351742 - 174517 4 5 SWC1857187018901, 1?

Norsk Hydro

R.o.Avg.

0.320.340.320.340.420.410.400.380.430.430.420.420.420.45NDP0.450.490.500.59

25/11-16

No. ofDeterminations

20202014611201520201443-2346

OKI

Norsk Hydro Sediments

Sample Inventory

GERG File Number

X2076X2081X2086X2091X2096X2I01X2106X2111X2116

Sample Description

25/11-16 Core #2 (core chips)25/11-16 Core #525/11-16 Core #625/11-16 Core #625/11-16 Core #625/11-16 Core #825/11-16 Core #825/11-16 Core #9

25/11-16 Core #12

Depth

1714 m1761 m1773 m1778 m1781 m1798 m

1802.5 m1807 m1873 m

Norsk-Hydro Sediments

Summary of AU Bioirørkcr Anoiyses

File * Description Total Concetrat ions of Biomsrkers

Diterp Triterp Regular Hono- Tri-

Steranes Aromat Aromat

Steranes Steranes

(ppm) (ppm) (ppm) <ppm) (ppm)

Percent Composition of Biomarkers

Diterp Triterp Regular Mono- Tri•

Steranes Aromot Aromat

Steranes Steranes

(%) (X) (X) (X) (X)

% Tot Arom % Reg Ster

/Tot Ster /Tot Ster

+Arom Ster

(%•> (X)

X2076 25/11-16 Core #2 {Core Chips) 1714 m

X2081 25/11-16 Core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 m

X2096 25/11-16 Core #6 1781 in

X21Q1 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #8 1802.5 m

X2111 25/11-16 Core #9 1807 m

X2H6 25/11-16 Core #12 1873 m

683

242b26

23

212264

12846

7510278130

85

93

66

237245

200

266

197

311238

238

220

4088

729571

140

181

183

4

3866

56

7756104

125

131

B

13.2

1.8

5.6

4.7

6.1

3.3

3,3

3.217.8

25.110.1

17,6

16.0

18,1

18.4

13.0

13.9

13.2

46.4

54.0

46.8

46.9

45.9

43,9

36.6

35.7

60,8

7.819.4

16.8

16.8

16.7

19.B

27.9

27.5

1.1

7.514.6

13.2

13.7

13,2

14.6

19.3

19.7

E.1

24.87

38.64

39.03

39.36

39.40

43.98

56.32

56,93

5.02

24.5

43.6

31.8

30.5

27.8

37.1

32.4

34.2

10.0

Biomarker Sumiary Page 1 22-fSov-92

Norsk-Hydro SedimentsTerparse Concentrations (m/z=19U

File Description

C20

Diterp

Peak A

(ppm)

C21

Diterp

B

Cppm)

C22

Diterp

C

(ppm)

C23

Diterp

0

<ppm)

C24

Oiterp

E

(ppm)

C25

Diterp

#1

Cppm)

Unknown

n

Unknown

#3

(ppm)

C24Tetra-

Cyclic#4

C26

Tri eye

#5

Cppm)

C26

Tri eye Unknown

#6 §7

X2076 25/11-16 Core Ml (Core Chips) 17.29 15.59 4.95

X20S1 25/11-16 Core #5 1761 m 0.98 1,42 0.65

X2086 25/11-16 Core «6 1773 m 2.74 A.39 2.05

X2091 25/11-16 Core #6 1778 m 2.94 «.67 1.87

X2096 25/11-16 Core #6 1781 m 3.69 4.79 2.OS

X2101 25/11-16 Core #8 1798 m 2.21 4.20 1.60

X2106 25/11-16 Core #8 1802.5 m 2.46 3.59 1.35

X2111 25/11-16 Core #9 1807 m 2.14 3.48 1.H7

X2116 25/11-16 Core #12 1B73 m 16.18 18.26 3.75

11.89

1.54

5.62

6.49

5.87

5.58

5.10

5.59

12.19

11.84

1.65

4.60

5.37

5.31

4.72

4.58

4.72

9.83

6.01

2.01

4.18

5.15

4.26

4.31

4.14

4.31

4.16

2.06

0.10

0,62

0,29

0.45

0,00

0.00

0.23

0.59

1.42

0.05

0.54

0.5S

0.36

0.35

0.35

0.44

1.58

4,811.76

50

38

85

69

99

08

3.29

1,90

0.71

1.41

1.37

1.10

1.34

1.21

1.30

1.46

1.87

0.47

1.65

1.51

1.70

1.86

1.16

1.70

2.13

1.72

0,32

0,96

1.46

0.95

1.25

0.92

1.01

1.18

Triterparse Analyses Page 1 20-NQV-92


Terpane Concentrations (m/z=l91)

File # Description Unknown

Peek #8

(ppnt)

1.471.04

1.37

2.190,98

3,33

1.791.67

0.56

C28Tricyc

9

(ppm)

0.75

0.65

0.57

1.09

0.78

1.02

0.680.77

0.62

C28Tricyc

#10

4.53

1.03

0.99

1.58

1.33

1.84

1.21

1,37

1,17

C29Tricyc

#11

{ppm)

2.811.35

2.17

3.05

1.95

2.69

2.00

1.931.41

C29Tricyc

#12

(ppm)

3.27

1.26

2,03

3.21

2.27

3.51

2.26

2.42

3.12

C27Hopane

TS

#13

(ppm)

5.60

2.68

3.665.60

3,61

5.803.B8

3.86

3.17

C27Hopsne

TM

mu(ppm)

5.72

2.05

3.07

5.143.00

6.02

4.554.09

3.44

C27Hopene

#15(ppm)

2.77

2.161.03

0.86

0.53

0.96

0.82

0,90

0,65

Unknown

#16

(ppm)

2.75

0.88

0.570.86

0.69

0.81

0.35

0.74

1.31

C28Hopane

#17

(ppm)

4.02

2.69

4.29

5.844.47

9.50

6.076.08

0.87

Unknown

#18(ppm)

0.97

0.33

0.48

0.79

0.44

0.66

0.72

0,441.02

C29

Hopane

#19

(ppm)

16.05

4.99

7.1110.98

7.15

14.10

8.52

8.98

8.96

X2076 25/11-16 Core #2 (Core Chips)

X2081 25/11-16 Core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 m

X2096 25/11-16 Core #6 1781 m

X2101 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #8 1802.5 m

X2111 25/11-16 Core #9 1807 m

X2116 25/11-16 Core #12 1873 m

Triterpane Analyses Page 2


Terpane Concentrations <m/z=191)

File if

X2076

X2081

X2086

X2091

X2096

X2101

X2106X2111X2116

Description

25/11-16 Core #2 (Core Chips)

25/11-16 Core #5 1761 m

25/11-16 Core #6 1773 m

25/11-16 Core #6 1778 m

25/11-16 Core #6 1781 m

25/11-16 Core (KB 1798 m

25/11-16 Core #& 1802.5 m25/11-16 Core #9 1807 m25/11-16 Core #12 1873 m

C29Norhop

Peak #20

{ppm)

2.65

0,85

2.10

2.64

1.91

3.56

1.742.641.63

Diahopane

FCpprn)

2.15

1.12

2.08

3.34

1.69

3.68

1.861.930.65

C29Horetane

#21(ppni)

4.70

0.86

1.84

2.53

1.69

2.94

1.942.13

2.12

C30Oleanane

#22(ppm)

1.40

0.56

0.00

0.10

0.21

0.67

0.120.31

0.87

C30Hopane

#23<ppm)

19.53

7.77

11.42

16.35

11.02

22.73

13.5214.93°,7B

C30

Horetsne

#24Cppra)

6.56

0.66

1.42

2.16

1.37

2.63

1.561.77

3.15

Unknown

#25tppm)

0.89

0.32

0.03

0.12

0.08

0.62

0.050.06

0.51

Unknown

#26(ppm)

0.29

0.34

0.84

1.30

1.06

1.32

0.83

0.960.33

C31Hopane

22S#27

(ppm)

5,10

3,12

5.27

6.89

5.03

9.38

5,95

6.764.08

C31Hopane

22R#28

(ppm)

7.692.07

3.97

4.95

3.63

6.40

4.134.784.40

C31Moretane

#29(ppm)

6.72

0.16

0.91

0.40

0.77

1,10

0.861.051.25

Senrnaeerene

G

(ppm)

0.93

0.51

1.16

1.54

1.09

1.87

1.091.300.63

Tr1terpane Analyses Page 20-Nov 92


Terpane Concentrations

File # Description

C32Hopane

22S

Peak #30

<ppm)

3.51

2.02

3.51

4.27

3.53

6.12

4.16

4.66

2.39

C32Hopane

22R

#31

Cppm)

2.39

1.32

2.54

3.17

2.43

4.09

2.87

3.34

2.20

C32Moretane

#32

Cppm)

0.28

0.30

0.42

0.56

0.43

0.64

0.43

0.55

0.39

C31 bb

Homohop

#33

(ppm)

4.81

0.20

0.33

0.47

3.59

0.23

0.27

0.26

1.20

C33Hopane

22S

«34

<ppm)

3.04

1.34

2.83

3.58

3.59

5.61

3.69

4.27

1.27

C33Hopane

22R

#35

Cppm)

1.93

0.83

1.97

2.39

2.06

2.85

2.05

2.391.00

C34Hopane

22S

#36(ppm)

1.33

1.06

1.66

1.811.81

2.55

1.942.12

0.52

C34Hopane

22R

#37

Cppm)

1.24

0.53

0.98

1.19

1,221.50

1,24

1.220.91

C35Hopane

22S

#38

(ppm)

2.43

0.B7

1.61

1.781,70

2.38

1.78

1.98

0.64

C35Hopane

22R

#39

(ppm)

1.85

0.23

1.18

1.46

1.151.53

1.161.44

0.75


X2081 25/11-16 Core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 177B m

X2Q96 25/11-16 Core #6 1781 m

X2101 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #8 1802.5 m

X2111 25/11-16 Core #9 1807 m

X2116 25/11-16 Core #12 1873 m

TH terpane Analyses Page 4 20-Nov-92


Terpane Percent Compositions (m/z=191)

file * DescriptionC2Q

Diterp

Peak A

m

8.1.

1.62.52.1

3.3

1.32.11.7

11.4

C21Diterp

B

(%)

7.3

2.44.1

3.3

4.3

2.53.12.0

12.9

C22Diterp

C

m

2.3

1.1

1.91.3

1.B

1.01.21.0

2.6

C23Diterp

D

(%)

5.6

2.6

5.44.6

5.2

3.3

4.44.5

8.6

C24Diterp

£

(X)

,5.5

2.B4.33.S

4.7

2.04.03.0

6.9

C25Diterp

#1

(X)

2.8

3.4

3.9

3.7

3,8

2.93.63.5

2.9

own

#2

%)

1.0

0.2

0.60.2

0.4

0.0

0.00.2

0.4

Unknown

#3

(X)

0.7

0.1

0.5

0.4

0.3

0,20.30.'.

1.1

C24Tetra-Cyc1 i c

#4

<X)

2.3

2.9

3.2

3.1

3.4

2,0

3.53.3

2.3

C26Trieye

#5

(%)

0.9

1.21.3

1.0

1.0

0.0

1.11.0

1.0

C26Tricyc

m(X)

0.9

0.0

1.51.1

1.5

1.11.0

1.4\.5

Unknown

#7(X)

0.8

0.50.91.0

0.8

0.70.80.80.8

X2C76 25/11-16 Core #2 (Core Chips)

X2GG1 25/11-16 Cora #5 1761 m

X20S6 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 177S m

X2096 25/11-16 Core #6 1781 m

«101 25/11*16 Cora #fl 179Q m

X2106 25/11-16 Core #8 1S02.5 mX2111 25/11-16 Core #9 1007 mX2116 25/11-16 Core #12 1873 m

Triterpane Analyses Page 1 20-Nov-92

Morsk-Hydro SedimentsTerpane Percent Compositions '(m/z=191)

File Description Unknown

Peak #8

C2BTri eye

C28Tricyc

#10

m

C29Tricyc

#11

£29Tricyc

#12

C27Hopane

TS#13

C27Hopane

TH#14

C27Hopane Unknown

#15 #16

C28Hopane Unknown

#17 #18

G29Hopane

#19

X2076 25/11-16 Core #2 (Core Chips) 0.7 0.4 2.1 1.3 1.5 2.6 2,7 1.3 1.3 1.9 0.5 7.5X2081 25/11-16 Core #5 1761 m 1.7 1.1 1,7 2.3 2.1 4.5 3.4 3.6 1.5 4.5 0.6 8.3X2086 25/11-16 Core #6 1773 m 1.3 0.5 0.9 2,0 1.9 3.4 2.8 1.0 0.5 4,0 0.4 6.6X2091 25/11-16 Core #6 1778 m 1.6 0.8 1.1 2.2 2,3 4.0 3.7 0.6 0.6 4.2 0,6 7.8X2Q96 25/11-16 Core #6 1781 m 0.9 0.7 1.2 1.7 2.0 3.2 2.7 0.5 0.6 4.0 0.4 6.3X2101 25/11-16 Core #8 1798 m 2.0 0.6 1.1 1.6 2.1 3.5 3.6 0,6 0.5 5.7 0.4 8.4X2106 25/11-16 Core #8 1002.5m 1.6 0.6 1.1 1.7 2,0 3.4 4.0 Q.7 0.3 5.3 0,6 7.4X2111 25/11-16 Core #9 1307 m 1.3 0.6 1.1 1,6 1.9 3.1 3.3 0.7 0.6 4.9 0.4 7.2X2116 25/11-16 Core #12 1073 m 0.4 0.4 0.8 1.0 2.2 2.2 2.4 0.5 0.9 0.6 0.7 6.3

Triterpene Arsalyses Page 2 20-NOV-92


Terpane Percent Compositions <m/z=191)

F i le # Descript ion

C29 C29 C30

Norbop Diahopane Horetane CHeananeC30 C30

Hopene Moretane

Peak #20

(X)F

xy

1.0

1,9

1.9

2.4

1.5

2.2

1.6

1.6

0.5

#21(X)

2.21.4

1.7

1.8

1.5

1.8

1,7

1.7

1.5

#22 #23

(X)

#24

Unknown

#25

Unknown

#26

C31

Hopane

22S

#27

C31

Hopane

22R

#28

C31

Moretane Ganrnacerene

#29 G

X2076 25/11-16 Core #2 (Core Chips) 1.2

X2081 25/11-16 Core #5 1761 m 1.4

X2086 25/11-16 Core #6 1773 m 1.9

X2091 25/11-16 Core #6 177B m 1,9

X2096 25/11-16 Core #6 1781 m 1.7

X2101 25/11-16 Core #8 179S m 2.1

X2106 25/11-16 Core #8 1802.5 m 1.5

X2111 25/11-16 Core #9 1807 m 2.1

X2116 25/11-16 Core #12 1873 m 1.2

0.7

0.9

0.0

0.1

0.2

0.4

0.1

0.2

0.6

9.1

13.0

10.6

11.7

9.8

13.6

11.8

12.0

6.9

3.1

1.1

1.3

1.5

1.2

1.6

1.4

1.4

2.2

0.4

0.5

0.0

0,1

0.1

0.4

0,0

0.0

0.4

0.1

0.6

0.8

0.9

0.9

0.8

0.7

0,8

0.2

2.4

5.2

4.9

4.9

4.5

5.6

5.2.

5.4

2.9

3.6

3.5

3.7

3.5

3.2

3.8

3.6

3.8

3.1

3.1

0.3

0.8

0.3

0.7

0.7

0.7

0.8

0.9

0.4

0.9

1.1

1.1

1.0

1.1

0.9

1.0

0.4

Triterpane Analyses Page 3 ZO-Nov-92


Terpane Percent Compositions (ro/z=191)

File it DescriptionC32

Hopene

22S

Peak #30

«>

1.6

3.4

3.33.0

3.1

3.7

3.6

3.7

1.7

C32Hoparte

22R

#31

m

1.1

2.2

2.4

2.3

2.2

2,42.5

2.71.6

C32Horetane

#32

(%)

0.1

0.5

0.4

0.4

0.4

0.4

0.4

0,40.3

C31 bbHomohop

#33

(%)

2.3

0.3

0.3

0.3

3.20.10.2

0.20.B

C33Hopane

22S

#34

(50

1.4

2.2

2.7

2.6

3.2

3.4

3.2

3.4

0.9

C33Hoparte

Z2R#35

(X)

0.9

1.4

1.8

1.71.81.7

1.8

1.90.7

C34Hopane

22S

#36

(%)

0.6

1.8

1.5

1.3

1,6

1.51,7

1.7

C34Hopane

22R

#37

m

0.6

0.90.9

0.8

1.10.9

1.11.00.6

C35Hopene

22S

m

1.11.5

1.51.3

1,51.4

1.5

1.6

0.5

C35Hopane

22R

#39

i%)

0.9

0,41.1

1.0

1.0

0.91.0

1.20.5


X2081 25/11-16 Core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 m

X2096 25/11-16 Core #6 1781 m

X2101 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #8 1802.5 m

X2111 25/11-16 Core #9 1807 m

X2116 25/11-16 Core #12 1873 m

Tr! terpane Artalyses Page 4

Norsk-Hydro SedimentsTotal % Compositions & Selected Terpane Ratios <m/z=191)

File UTotal Concentration % Compositions of

Description TriterpanesDiterpartes Triterpanes THeyclics Hopenes Moretanes TS/TH

(ppm) Cppm)

Ratios

Hopanes ===========s/ft+s ==3========= Hopane/Moretane

C28/C30 C3D/C29 C31 C32 C33 C34 C35 C29/C29 C30/C30

X2076 25/11-16 Core #2 (Core Chips)X2081 25/11-16 Core #5 1761 raX2086 25/1.1-16 Core #6 1773 mX2091 25/11-16 Core M6 1778 mX2096 25/11-16 Core #6 1781 mX2101 25/11-16 Core #8 1798 mX2106 25/11-16 Core #8 1802.5 mX2111 25/11-16 Core #9 1807 mX2116 25/11-16 Cure #12 1873 m

68fi

24

26

26

23212264

1284675

102

78

130

8593

66

11.811.911.711.611.8

9.4

10.110.215.0

73.282,6ao.681.381,383.683,0S2.573.5

14.34.3

6.1

5.6

5.5

5.6

5.75.9

10.5

0,981.311.191.091.200.960.850.940.92

0.210.350.380.360.410.420.450,410.09

1.221.561.611.491.541.611.591,661.09

0.400.600.570.580.580.590,590,590.48

0.590.600.580.570.590.600.590.580,52

0.610.620.590.600.640,660.640.640.56

0.520.670.630.600.600.630.610.630.36

0.570,790.580.550.600.610.610.580,46

3.415.803.864.344.234.804.394.224.23

2.9811.7?

8.047.57a. 048.648,678,443.10

Triterpane Analyses Page 1 23-Nov-92

Norsk-Hydro SedimentsSterane Concentrations (m/z=217)

C21 C21 C21 C22 C27 CZ7 C27 C2? C28 C28 C28 C28File # Description Sterane Sterane Sterane Sterane Diaster Piaster Diester Diaster Master Piaster Diaster Blaster Diaster Dfaster Dfaster

Peak A

tppoi)

44.11

6.41

15.11

15.80

16.79

14.11

14.33

15.17

59.76

#1(ppm>

43,44

29,96

17.10

17.81

20.00

15.86

18.61

16.69

50.36

B

<ppm)

16.02

6.26

10.89

12.68

9.34

11.26

8.55

10.8927,27

#2(ppm)

19.98

14.07

11.76

12,60

12.60

12.31

12.9213.10

20.25

#3(ppm)

9.43

10.13

13.80

22.40

13.80

23.32

18.91

is , so6.45

#4

(ppm)

7.30

6.12

10.84

14.94

11.35

16.79

12.9912.49

4.21

#5(ppm)

0.10

0.33

0.06

0.04

0.53

0.12

0.020.03

0,17

#6(ppm)

0,13

0.64

0.14

0.12

0.3S

0.22

0.22

0.27

0.39

#7(ppm)

1.97

0.13

1.40

1.92

1.15

2.22

1.511,73

0.79

#8

(ppm)

2.84

3.11

3.44

5.14

3.39

6.09

4.57

4.37

0.81

9

<ppm)

3.81

5.31

4.226.673,89

6.81

6,614.93

1.87

#10

(ppm)

6,01

7.29

7.02

11.33

6.63

1 1.72

8.525.63

1,87

#11(ppm)

3.578.33

5.79

8.86

5.08

9,47

7.13

5.582.21

#12

(ppm)

1.24

1.52

0.48

1.99

0.75

1,84

1.20

1.42

0.56

#13(ppm)

2.07

7.03

1.80

4.57

2.19

4.75

4.31

3.60

0.S3

X2076 25/11-16 Core MZ (Core Chips)X2081 25/11-16 Core #5 1761 raX2086 25/11-16 Core #6 1773 mX2091 25/11-16 Core #6 1778 mX2096 25/11-16 Core #6 1781 mX2101 25/11-16 Core #8 1798 mX2106 25/11-16 Core #3 1802.5 mX2111 25/11-16 Core #9 1807 mX2116 25/11-16 Core #12 1873 m

Regular Sterone analyses Page 1 20-NOV-92

Morsk-Hycfro SedimentsSterane Concentrations <m/z=:217)

File ftC28 C28 C27 C27 C27 C27 C29 C28 C28

Description Oiaster Piaster Diaster aaaS abbR abbS Diaster Diaster aaaR Diaster Diaster OiBSter aoaS Diester abbR(?) + Diester+ Diaster Sterane (?) (?) Sterane (?) (7) Sterane (?) Sterane

Peak #14 #15 #16 #17 #18 #19 #20 #21 #22 #23 #24 #25 #26 #27 #28(ppm) (ppm) (ppra) (ppm) {ppm) (ppm) (ppm) (ppm) (ppm) (ppm) (ppn) <ppm) (ppm) (ppffl) (ppm)

X2076 25/11-16 Core #2 <Cere Chips)X20Q1 25/11-1é Core #5 1761 mX2086 25/11-16 Core #é 1773 mX2091 25/11-16 Core #6 1778 mX2096 25/11-16 Core #6 1781 mX2101 25/11-16 Core #8 1798 mX2106 25/11-16 Core #8 1802.5 mX2111 25/11-16 Core #9 1807 mX2116 25/11-16 Core #12 1873 m

1.81

1.94

2.763.372.693.862.963.601.30

2.753.935,205.264.125.424.234.711.37

0.692.870.741.031.911.501.301.506.89

5.225.526.769.686.61

13.098.999.712.67

3.1820.6211.546.714.099.386.257.991.52

2.5811,264.946.,854.829.486.646.372.73

0.240.120.060.180.160.240.040,100.16

0.170.110.120.090.050.100.030.100.14

7.023.293.555.233.846.575.024.671.86

4.109.049.78

16.4911.3020.4513.9813.902.13

2.304.022.754.963.065,783,623.330.76

0.452.863.224.703,205.683.934.110.56

1.092.601.211.991.202.792.072.310.5Z

1.491,542.363.642.355.312.994.040.31

3.4510.023.395.423.297.414.995.472.03

Regular Sterane Analyses Page 2 20-Hov-92


Sterane Concentrations (jn/z=217)

C28 C28 C29 C29 C29 C29 C30 C30 C30 C30

File if Description abbs Piaster asaR Disster saaS abbR ebbs OiBster aaaR Sterane Sterane Sterane Sterane

Sterane (?) Sterane (?) Sterane Stertfne Sterane (?) Sterane (?) (?) (?) (?)

Peak #29 #30 #31 #32 #33 #34 #35 #36 #37 #38 #39 #40 #41

(ppm) (ppm) (ppm) (ppen) (ppm) (ppm) (ppfli) (ppm) tppm> (ppm) (ppm) (ppm) (ppm)

X2076 25/11-16 Core #2 (Core Chips)X2081 25/11-16 core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 mX2096 25/11-16 Core #6 1781 m

X2101 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #3 1802.5 mX2111 35/11-16 Core #9 1807 mX2116 25/11-16 Core #12 1873 m

2.548.56

4.176.204.47

8.42

5.135.40

o.ao

2.013.543.46

5.213.63

6.47

4.454.200.15

6.042.49

2.082.B52.10

4.43

2.942.950.92

0.430.70

1.29

2.05

1.12

2.38

1.761.70

6.65

3.366.80

4.95

7.484.59

10.61

7.227.42

1.62

6.9613.03

S.82

8.81

5.3912.59

8.56a.54

2.83

2.8011.02

4.65

6.444.30

8,79

6,016.48

0.72

0.43

0,60

0.720.87

0.56

1.38

0.81

0.930,25

9.194.23

3.865.62

3.70

8.46

5.375.67

2.01

1.250.90

1.701.57

1.59

3.62

1.451.59

0.11

1.072.44

1.62

2.431.56

3.39

2.072.21

0.51

0.73

2.84

1.96

2.111.78

3.69

2.302.53

0.72

1.681.02

1.37

1.71

1,212.50

2.04

2.110.46

Regular Sterane Analyses Page 3 ZQ-Nov-92

Norsk-Hydro SedimentsSterane Percent Compositions

File # DescriptionC21 C21 C21 C22 C27 C27 C27 C27 C28 C28 C2S C28

Sterane Sterane Sterane Sterane Diaster Diaster Piaster Piaster DiBster Diaster Draster Diaster Diaster Diaster Diaster

Peak A(X)

1B.62,6

7.6

5.9

8.5

4.5

6.0

6.4

27.1

#1« >

18.312.3

8.6

6.7

10.2S.1

7.8

7.0

22.9

B

(%)

6.8

2.6

5.4

4.8

4.B

3.6

3.6

4.6

12.4

#2

<%)

8.45.8

5,9

4.7

6.4

4.0

5.4

5.5

9.2

#3

(%)

4.0

• 4 . 1

6.9

8.4

7.0

7.5

8.0

7.8

2.9

#4

(%)

3.1

2.5

5.4

5.6

5.8

5.4

5.5

5.21.9

#5

(%)

0.0

0.1

0.0

0.0

0.3

0.0

0.0

0.0

0.1

«6

<%>

0,1

0.3

0.1

0.0

0.2

0.1

0.1

0.1

0.2

#7

C%)

0-80.1

0,7

0.7

0.6

0.7

0.6

0.7

0.4

#8

CX>

1.21.3

1.7

1.9

1.7

2.0

1.9

1.80.4

9(%)

1.6

2.2

2.1

2.5

.2.02.2

2.8

2.1

0.8

#10

C%)

2.53.0

3.5

4.33.4i.a3,6

2.4

0.8

#11

(X)

1.53.4

2.9

3.3

2.6

3.0

3.0

2.3

1.0

#12(%>

0.50,6

0.2

0.7

0.4

0.6

0.5

0.6

0.3

#13

(%>

0.9

2.9

0.9

1.7

1.11.5

1.B

1.50.2

X2076 25/11-16 Core #2 <Core Chips)X2081 25/11-16 Core #5 1761 mX20B6 25/11-16 Core #6 1773 mX2091 25/11-16 Core #6 1778 mX2096 25/11-16 Core #6 1781 inX2101 25/11-16 Core #8 1798 mX2106 25/11-16 Core #8 1802.5 mX2111 25/11-16 Core #9 1807 mX2116 25/11-16 Core #12 1873 m

Regular Sterane Analyses Page 1 20-NOV-92

Norsk-Hydro SedimentsSterane Percent Compositions <m/i=217)

C28 C28 C27 CZ7 C27 C27 C29 C28 C28File U Description Diaster Diaster Diaster aasS abbR abbs Diaster Piaster aaeR DSaster Diaster Diaster aaaS Diaster abbR

(?) + Diaster+ Diaster Sterane (?) (?) Sterane (?) (?) Sterane <?} SteranePeak #14 #15 #16 #17 #18 #19 #20 #21 #22 #23 #24 #25 #26 #27 #28

{%) (%) (%) a ) (•/•> (X) m c%) (%) {%) a) (%> (%) c%) (%)

X2076 25/11-16 Core «2 (Core Chips)X2081 25/11-16 Core #5 1761 mX2086 25/11-16 Core #6 1773 mX2091 25/11-16 Core «6 1778 mX2096 25/11-16 Core Kb 1781 mX2101: 25/11-16 Core #8 1798 mX2106 25/11-16 Core #8 1802.5 roX2111 25/11-16 Core #9 1807 mX2116 25/15-16 Core #12 1873 m

o.a0.8

1.41.3

1.4

1.21.21.50,6

1.21.6

2.62.0

2.1

1.71.82.0

0.6

0.3

1.2

0.4

0.41.0

0.5

0.50.63.1

2.2E.33.43,63.4

4.2

3.84.1

1.2

1.38.4

S.8

2.5

2.13.0

2,6

3.4

0.7

1.14.6

2.5

2.6

2.5

3,12.8

2.7

1.2

0.1CO

0.0

0.1

0.1

0.1

0.00.0

0.1

0.10.0

0.10.0

0.0

0.0

0.00.0

0.1

3.01.3

1.8

2.02.0

2.12.12.0

0.8

1.73.7

4.9

6.2

5.7

6.6

5.95.S

1,0

1.01.6

1.4

1.91,6

1.9

V.51.4

0.3

0.21.2

1.61.8

1.6

1.8

1,7

1.7

0.3

0.5

1.1

0.6

0.7

0.60.9

0.9

t.O

0.2

0.6

0.6

1.21.41.21.71.31.70.1

1.54.1

1.72.0

1.7

2.42.12.30.9

Regular Sterone Analyses Page 2 20-NOV-92

Marsk-Hydro Sediments

Sterane Percent Compositions (m/z=217)

C28 C28 C29 C29 C29 C29 C30 C30 C30 C30

File # Description ebbS Oiaster aaaR Diaster saaS abbR ebbs Diaster aaa[? Sterane Sterane Sterane Sterane

Sterane (?) Sterane (?) Sterane Sterane Sterane (?) Sterane (?) (?) (?) (?)

Peak #29 #30 #31 #32 #33 #34 #35 #36 «7 #38 #39 #40 .#41

(%) (%) (%) c%) («) (X) c%> (X) (%> <%) «) m i%)


X20B1 25/11-16 Core #5 1761 m

X2086 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 in

X2096 25/11-16 Core #6 1781 m

X2101 25/11-16 Core #8 1793 m

X2106 25/11-16 Core #8 1802.S m

X2111 25/11-16 Core #9 1807 m

X2116 25/11-16 Core #12 1873 m

1.13.52.12,32.3.2.72.2

2.10.4

0.81.4

1.7

2.0

1.8

2.1

1.9

1.8

0.1

2.51.0

1.0

1.1

1.1.1.4

1.21.2

0.4

0.20.3

0.6

0.8

0,6

0.8

0,70.7

3.0

1.42.8

2.5

2.8

2.3

3.4

3.03.1

0.7

2.95.32.9

3.3

2.74.1

3.63.6

1.3

1.24.5

2.3

2.4

2.2

2.8

2.5

2.70.3

0.20.2

0.4

0.3

0.3

0.4

0.3

0.4

0.1

3.91.7

1.9

2.1

1,9

2.72,3

2.4

0.9

0.50.4

0.9

0.6

0.8

1.2

0.6

0.7

0.0

0.51.0

0.8

0.90.8

1.10.9

0.9

0,2

0.31.2

1.00.80.9

1.2

1.0

1.1

0.3

0.70.4

0.70.6

0,6

0.8

0.9

0.9

0.2

Regular Sterane Analyses Page 3 20-Nov-92


Total % Composition & Selected Regular Sterarte Ratios (m/i-217)

Total % Composition

File # Description Regular Steran-es ======== s/R+S =•==:======: ======== aa/bb

Oissteranes C21+C22 C27 C28 C29 C30

(%) (%} (X) <%) (%> C29 C28 C27 C29 C28 C27


X2081 25/11-16 Core #5 1761 m

)(20S6 25/11-16 Core #6 1773 m

X2091 25/11-16 Core #6 1778 m

X2096 25/11-16 Core Hb 1781 m

X2101 25/11-16 Core #8 1798 m

X2106 25/11-16 Core #8 1802.5 m

X2111 25/11-16 Core #9 1807 m

X2116 25/11-16 Core #12 1873 m

23.333.240.747,342,445.744.742.318.4

52,123.227.422.229.917.222.923.571.6

7.616.613.410.79.9

12,411.312.14.0

5.59.7

5.4

6.2

5.6

7.4

6.4

6.8

1.9

9.414.3

9.6

10.79.1

13.011.411.83.3

2.02.9

3.3

2.9

3.1

4 . a3,3

3.6

0.8

0.270.620.560.570.550.560.570.570.45

0.150.510.370.410.360.390.410.440.36

0.430,630.660.6S0.630.670.640.680.59

1.290.460.840.860.860.890.860.871,02

1.190.270.440.420.430.460.500.480.51

2.130.280.631.101,17

1.04

1.09

1.00

1.07

Regular Sterane Analyses Page 1 20-Nov-92

//.

Definitions of Selected Siomarker Parameters

THterpanes (Peak numbers in m/z=191)

Total Diterpanes = Sum of #1 to #8

* Total Triterpanes = Sum of #9 to #39

* X TncycUcs = C#9+#10+#11+#12)*100.0/Total Triterpanes

* % Hopanes = C#13+#15#+17+#19*#23+#27+#aB+#30+#31

+ Sum of #34 to #39}*100.0/Total Triterpanes

* X Moretenes = C#21+#24+#29+#32)*10Q.0/Totat Triterpanes

?! Unknown = C#16+#18+#20+#25+«(26<-#33)*100.0/Totat Triterpanes

TS/TM a #13/#t4

Hopanes C2S/C29 = #16/#19

Hopanes C30/C29 = «3/#19

S/(S+R) C.31 = #27/(#27+#28)

C32 s «0/{#30+#3D

C33 =

C34 =

C35 = #38/C#38+S39)

Kopane/Horetano

C29/C2V =

C30/C30 =

* Used in ternary plots

Definitions of Selected Bioniarker Parameters

Ster3nes (Peak numbers in mfx-2"i7)

* Total Steranes = Sum of #1 to #41

X Diasteranes = (Sun of of UZ to #16 +#2Q+#21+#23+#24+#25+«<27

+#30+#32+#36}*100.0/TOTAL

* % C21+C22 = C#H#2)*tOO.O/Totat Steranes

* % C27 = {#1?+#1B+#19+#22)*100.0/Totet Steranes

* % C28 = <#26+#28+#29+#31)*100.0/Total Sternaes

* % C29 = (#33+#34+#35+#37)MQ0.0/Total Sternees

* % C30 = (iO8+iC9+W0+#41)*1(}0.0/Totat Sternaes

S/CS+R) C29 = (TO)/(#33+#37)

C28 = <#26}/(#26+#31)

C27 = «P17)/{#17+#22>

aaa/abb C29 = (#33+#37)/C*34+#35)

C28 = (#26+#31>/(#28+#29)

C27 = C#17+#22)/(#18+#19)

* % of aoa 20R C27 = #22*100.0/<#22+#31+#37)

* % of aaa 20R C28 = #3i*100.0/{#22+#31+«7)

* % of eaa 20R C29 = #37*100.0/(#22+#31+#37)


Definitions of Selected Biomarker Parameters

Monoaromatized Sterenes (Peak numbers in m/z=253)

* Total » Sum of #1 to #17

<C21+C22)/<C27toC29) = <#1+#2)/Sim of #5 to #17

% of C21/CC21+C2S) ~ #1*100.0/<#1+#t1>

Tri aromat! red Sterane (Peak numbers in in/

* Total = Sum of #1 to H7

CC20+C21)/(C26toCZ8) = (#1+#2)/Sum of #3 to #7

% of C20/CC20+C27) = #1*100.0/<#1+#4>

% of C21/CC21+CZ8) = #2*100.0/(*2+#7)

Tri-/Mono-aromat i zed Ratios

23UC27)/23UC27)+253(C28)

23lCC28)/23t(C28)+253tC29)


File #

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C21Sterane

Peak A(ppm)

8.568.648.710.87

27.7518.2515.5622.36

C21Sterane

Peak #1

(PPm)

7.158,608.080.73

31.7522.0519.5924.83

C21Sterane

Peak B(ppm)

6.007.377.210.56

22.2811.0113.2512.26

C22Sterane

#2(ppm)

4.456.936.500,42

26.5616.1314.5220.93

C27Diaster

#3(ppm)

10.4616.7520.240.8235.4526,1132.8927.80

C27Diaster

#4(ppm)

7.6811.3013.710.5226,3618.0027.2821.33

Diaster

#5(ppm)

0.150.250.190.040.680.651.931.26

Diaster

#6(ppm)

0.180.350.420.051.942.522.380.43

Diaster

#7(ppm)

1.622.311.760.104.572.523.594.38

C27Diaster

#8(ppm}

2,744.184.830.269.326.029.917.37

Regular Sterane Analyses Page 1 3/20/93

File #

>X2026>X2031>X204 6>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C27Diaster

9(ppm)

3.045.855.550.2713.157.3711.6410.58

C28Diaster

#10(ppm)

5.007.728.410.33

18.6210.7910.2513.30

C28Diaster

#11(ppm)

3.025.346.080.35

14.1710,0810.089.32

C28Diaster

#12(ppm)

0.170,721.250.042.500.852,030.66

C28Diaster

#13(ppm)

0.091.232.060.024.312.815.183.48

C28Diaster

#14{ppm)

2.916.132.890.29

24.793.765.633.40

C28Diaster

Peak #15(ppm)

2.406.135.220.30

24.7910.889.15

12.20

Diaster(?) H#16

(ppm)

1.640.821.160.003.661.512.632.20

C27aaaS

i- Diaster +#17

{ppm)

3.144,576.040.47

14.579.97

17.8111.68

C27abbR

Diaster#18

(ppm)

6.9412.7517.171,04

28.2918.8934.4122.32


File #

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-1

25/6-125/8-125/8-425/11-5

25/11-15

C27abbS

Sterane

#19(ppm)

1.644.01

4.760.24

10.486.83

12.27

7.29

Diaater

(?)#20

(ppm)

0.420.17

0.510.080.07

0.100.180.24

Diaster

(?)#21

(ppm)

0.04

0.060.020.000.00

0.100.420.21

C27aaaR

Sterane#22

{ppm)

0.881. 642.440.246.874.308.29

4.99

C29Diaster

#23(ppm)

3.958,58

11.17

0.9617.2713.0933.34

15.09

Diaster

(?)#24

(ppm)

1.463.37

4.290.32

7.554.619.635.03

Diaster(?)#25

<ppm)

1.872.863.350.257.724.86

10.706.16

C28aaaS

Sterane#26

(ppm)

0.250.510.710.112.431.453.211.88

Diaster(?)#27

(ppm)

1.553.074.720.398.225.027.304.55

C28abbR

Sterane#28

(ppm)

0.702.232,760.147.794.86

10.975.99


File #

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C28abbS

SteranePeak #29

(ppia)

1,443.353.590.21

10.365,51

14.286.3.8

Diaster

(?)#30

(ppm)

0.863.624.750.309.765.65

11.386.97

C28aaaR

Sterane#31

(ppm)

0.470.991,120.163.982.316.733.07

Diaster

(?)#32

{ppm)

0.18

0.450.520.122.27

1.170.002.21

C29aaaS

Sterane#33

(ppm)

1.252.984.950.27

10.486.49

16.767.81

C29abbR

Sterane#34

(ppm)

1.3.83.78

5.390.37

12.328.74

19.179.63

C29abbS

Sterane

#35(ppm)

0.993.243.510.208.566.47

13.777.66

Diaster

(?)#36

(ppm)

0.120.340.320.011.370.931.621.11

C29aaaR

Sterane#37

(ppm)

0.711.533.600.438.355.3313.115,62

C30Sterane

(?)#38

(ppm)

0.340.411.140.043.942.605.662.11


G30 C30 C30File # Description Sterane Sterane Sfcerane

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

#39(ppm)

0.330.851.410.103.152.326.202.33

#40(ppm)

0.360.831.220.114.082.534.633.17

#41(ppm)

0.310.420.600.033.111.744.811.98


File # DescriptionC21 C21 C21 C22 C27 C27

Sterane Sterane Sterane Sterane Diaster Diaster Diaster Diaster Diaster

Peak A Peak #1 Peak B #2 #3 #4 #5 #6 #7

>X2026>X2031>X2046>X2051>X2056>X2061>X20 66>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

8.75.24.56.95.76.13.46.5

7.25.14.25.86.57.44.27.2

6.14.43.74.54.63.72.93.6

4.54.13.33.35.55.43.16.1

10.610.010.46.57.38,87.18.1

7.86,87.14.15.46.15.96.2

0.20,10.10,30.10.20.40.4

0.20.20.20.40.40.80.50.1

1.61.40.90.80.90,80.81.3


File #

>X2026>X2031>X204 6>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C27Diaster

#8

(*)

2.82.52.52.11.92.02.12.1

C27Diaster

9

3.13.52.92.12.72.52.53.1

C28Diaster

#10(%)

5.14.64.32.. 63.83.62.23.9

C28Diaster

#11(%)

3.13.23.12.82.93.42.22.7

C28Diaster

#12(%)

0.20.40.60.30.50.30.40.2

C28Diasfcer

#13(%)

0.10.71.10.20.90.91.11.0

C28Diaster

#14

(%)

2.93.71.52.35.11.31.21.0

C28Diaster

Peak #15(%)

2.43.72.72.45.13.72.03.6

Diaster(?) H#16(%)

1.70.50.60.00.80.50.60.6

C27aaaS

- Diaster#17{%)

3.22.73.13.73.03.43.83.4

Regular Starane Analyses Page 7 3/20/93

File #

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

DescriptionH

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C27abbR

'<• Diaster#18(%)

7.07.68.88.35.86.47.46.5

C27abbS

Sterane#19{%)

1.72.42.41.92.22.32.62.1

Diaster(?)#20<%)

0.40.10.30.60.00.00,00.1

Diaster

(?)#21(%)

0.00.00.00.00.00.00.1O.I

C27aaaR

Sterane#22(%)

0.91.01.31.91.41.41.81.5

C29Diaster

#23

(%)

4.05.15.77.63.64.47.24.4

Diaster(?)#24

(%>

1.52.02.22.51.61.62.11.5

Diaster

C?)#25(%)

1.91.71.72.01.61.62.31.8

C28aaaS

Sterane#26«%)

0.30.30.40.90.50.50.70.5

Diaster(?)#27

(%)

1.61.82.43.11.71.71.61.3


File f

>X2026>X2031>X204 6>X2051>X2056>X2G61>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C28abbR

Sterane#28(%)

0.71.31.41.11.61.62.41.7

C28abbS

SteranePeak #29

(%•)

1.52.01.81.72.11.93.11.9

Blaster

(?)#30(%)

0.92.22.42.42.01.92.52.0

C28aaaR

Sterane#31

(%)

0.50.60.61.30,80.81.40.9

Diaster

(?)#32

(%)

0.20.30.31.00.50.40.00.6

C29aaaS

Sterane#33<%)

1.31.82.52,12.22.23.62.3

C29abbR

Sterane#34

(%)

1.42.32.82.92.52.94.12.8

C29abbS

Sterane#35

{%)

1.01.91.81.61.82.23.02.2

Diaster

(?)#36

{%)

0.10.20.20.10.30.30.30.3

C29aaaR

Sterane#37

•{%)

0.70.91.93.41.71.82.81.6


C3.0 C30 C30 C30File # Description Sterane Sterane Sterane Sterane

#38 #39 #40 #41

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

0.30.20.60.30.80.91.20.6

0.30.50.70.80.60,81.30.7

0.40.50.60.90.80.91.00.9

0.30.30.30.20.60.61.00,6


File # DescriptionDiasteranes

Total % CompositionRegular Steranes

C21+C22 C27 C28 C29 C30

C29 C28 C27

>X2026>X2031>X2046>X2Q51>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

52.254.853.246.349.146.945.146,4

26.518.915.720.522.322.713.623.4

12.713.715.615.812.413.515.713.5

2.94.24.24.95.14.87.65.0

4.46.99.0

10.18.29.1

13.58.9

1.41.52.22.22.93.14.62.8

0.640.660.580.390.560.550.560-58

0.350.340.390.410.380.390.320.38

0.780.740.710.660.680.700.680.70


File #

>X2026

>X2031>X2G46

>X2051>X2056>X2061

>X2066>X2071

Description

25/1-9

25/2-10

25/5-125/6-1

25/8-125/8-4

25/11-525/11-15

C29

0.830.64

0.961.23

0.900.78

0.910.78

= aa/bb =

C28

0,340.27

0.29

0.770.35

0.360.390.40

C2 7

0.47

0.37

0.390,55

0.550.550,560.56

TOTALSTERANES

<ppm)

9916719413486297464344

#3TOTAL

C21+C22STERANES

(ppm)

11.615.5314.581.15

58.3138.1834.1145.76

#4TOTAL

C27 (R+S.)STERANES

Cppm)

4.026.218.480.71

21.4414.2726.116.67

#5C27(R)/C29(R)

Ratio

1.241.070.680.560.820.810.630.89

#6D1ASTINDEX

4.514.524.001.892.883.092.312,95

ppiC27

(ppm)

12.623.030.42.060.240.072.846.3


File # Deacriptionn OF REG STER FOR TERNC28 C29

ppm OF aaa20R STER FOR TERN

C30 C27 C28 C29

(ppm) (ppm) (ppm) (ppm) (ppm) (ppm)

>X2026>X2031>X2046>X2051

>X2056>X2061>X2066>X2071

25/1-925/2-10

25/5-125/6-125/8-125/8-4

25/11-525/11-15

2.97.18.2

0.624.614.135.2

1.7.3

4.311.517.51.3

39.7

27.062.830.7

1.32,54.40.3

14.39.2

21,39.6

12207485

01104

273

12408

5136


File # Description

C20Diterp

Peak A(ppm)

C21Diterp

B(ppm)

C22Diterp

C(ppm)

C23Diterp

D

{ppm}

C2 4Diterp

E

C25Diterp

#1

Unknown

#2(ppm)

11 15 34 26

>X2026

>X2031>X2046>X2051

>X2056>X2061>X2066>X2071

25/1-925/2-10

25/5-125/6-125/8-125/8-4

25/11-525/11-15

2.061.911.820.34

5.363.353.304.90

2.462.47

2.92

0.358.335.16

4.516.62

1.591.331.24

0.143.98

2.332.152.39

2.723.68

4.170.19

11.66

7.636.479.52

2,723.453.05

0.2510.597.04

6.258.62

2.293.42

2.760.09

9.856.426.677.91

0.410.32

0.20

0.020.540.27

0.330.00

Triterpane Analyses Page 1 3/20/93

File # Description

>X2026>X2031>X2046>X2051>X2Q56>X2061>X2066>X2071

25/1-925/2-102.5/5-125/6-125/8-125/8-425/11-525/11-15

Unknown

#3(ppm)

6

0.410.460.560.251.120.980.621.00

C24Tetra-Cyclic

#4(ppm)

80

1.572.623.740.158.836.035-507.11

C26Tricyc

#5{ppm)

42

0.981.520.990.104.012.352.402.88

C26Tricyc

#6(ppm)

10

0.881.521.030.053.683.292.863.26

Unknown

Peak #7(ppm)

72

0.371.120.980-082.461.461.892.10

Unknown

#8(ppm)

15

1.301.951.920.112.733.502.744.51

C28Tricyc

9(ppm)

38

0.630.780.750.092.051.662.582.06


File #

>X2026>X2031>X204 6>X2051>X2056>X2061>X20 66>X2Q71

Deacription

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C28Tricyc

#10(ppm)

18

0.681.241.570,063.742.474.462.82

C29Tricyc

#11(ppm)

73

1.592.892.830.176.263,746.974.79

C29Tricyc

#12{ppm)

20

1.202.561.890.166.674.077.915.08

C27Hopane

TS#13

(PPm)

170

3.215.856.120.18

13.539.0614.3210.01

C27Hopane

TM#14

(ppm)

406

0.952.113.990.419.896.68

12.277.45

C27Hopane

#15(ppm)

44

0.670.551.100.023.431.881.582.02

Unknown

#16{ppm)

235

0.520.800.770.062.531.403.831.68


File # DescriptionC28

Hopane

#17(ppm)

Unknown

Peak #18(ppm)

C29Hopane

#19(ppm)

C29Norhop

#20<ppm)

Diahopane

Peak F(ppm)

C29Mo ret ane

#21(ppm)

C30Oleanane

#22(ppm)

84 60 758 212 487 108

>X2026>X2031>X2046>X2051>X2056>x2oei>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

0.830.823.050.39

11.506.22

13.287.42

0.330,000.760.041.430.962.300.72

2.767.15

14.670.87

24.4415.3436.1115.81

0.992.421.370.138.103.467.945.79

1.162.404.150.225.213.917.954.41

0.471.202.140.455.692.606.683.71

0.150.090.3.10.031,260.120.530.76


File # Description

>X2026>X2031>X204 6>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C30Hopane

#23(ppm)

1177

4.0410.5619.821.29

32.4521.4448.3423.02

C30Moretane

#24(ppm)

129

0.631.542.760.514.693.047.553.11

Unknown

#25(ppm)

131

0.070.110.110.050.800.551.710.75

Unknown

#26(ppm)

389

0.160.270.350.040.470.003.210.58

C31Hopane

22S#27

(ppm)

375

1.653.187.940.5411.828.0218.518.64

C31Hopane

22R#28

(ppm)

489

1.342.685.280.578.516.1314.306.04

C31Moretane

Peak #29(ppm)

278

0.260.540.830.322.201.071.111.38


File #

>X2026>X2031>X204 6>X2051>X2056>X2061>X2066>X2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

Gammacerene

Peak G(ppm)

0.221.421.700.072.911.615.323.58

C32Hopane

22S#30

(ppm)

157

1.122.174.630.397.304.9312.015.99

C32Hopane

22R#31

(Ppm}

215

0.841.613.420.425.543.978.134.37

C32Moretane

#32(ppm)

36

0.030.120.190.160.260.231.860.27

C31 bbHomohop

#33(ppm)

87

0.070,090.100.040.500.491.310.45

C33Hopane

22S#34

(ppm)

89

0.781.262.830.236.093.898.764.87

C33Hopane

22R#35

{ppm)

96

0.471.162.100.194.042.835,953.38


File # Description

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C34Hopane

22S#36

(ppm)

68

0.590.792.320.033.522.284.192.73

C34Hopane

22R#37

<ppm)

74

0.480.651.300.082.791.392.201.64

C35Hopane

22S#38

(ppm)

7

0.370.751.560.082.992.093.652.45

C35Hopane

22R#39

(ppm)

3

0.390.411.550.052.201.522.381.61

C20Diterp

Peak A(%)

0.1

4.172,221.403.251.931.871.022.33

C21Diterp

B{%)

0.1

4.982.872.253.353.002.881.393.15

C22Diterp

C(%)

0.1

3.221.550.961.341.431.300.661.14



Diterp

D

(%)

C24Diterp

E

<%>

C25Diterp

#1

Unknown

#2

Unknown

#3(%)

C24Tetra-Cyclic

#4{%)

C26Tricyc

#5

< % • )

0.2 0.2 0.5 0-4 0.1 1.2 0.6

>X2Q26>X2031>X2046>X2051>X2056>X206X>X2066>X2071

25/1-925/2-1025/5-12.5/6-125/8-125/8-425/11-525/11-15

5.504.283.221.824.194.271,994.53

5.504.012.352.393.813.941 - 924.10

4.633.982.130.863.543.592.053.76

0.830.370.150.190.190.150.100.00

0.830.540.432.390.400.550.190.48

3.183.052.881.433.183.371.693.38

1.981.770.760.961.441.310.741.37


File # Description, Tricyc

#6

Unknown

Peak #7

Unknown

#8

C28Tricyc

9

C28Tricyc

#10

C29Tricyc

#11

C29Tricyc

#12

>X2026>X2031>X2046

>X2051>X2056

>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-1

25/8-125/8-4

25/11-525/11-15

0.1

1.781,77

0.790.481.32

1.840.88

1,55

1.1

0.751.300.76

0.7 60.890.82

0.581.00

0.2

2.632.27

1.481.05

0.981.960.84

2.15

0.6

1.280.910.58

0.860.74

0.930.79

0.98

0.3

1.381.441.210.57

1.351.381.37

1.34

1.1

3.223.36

2.181.63

2.252.09

2.152.28

0.3

2.432.981.461.532.402.282.432,42



HopaneTS#13

{*)

C27Hopane

TM#14

< • % >

C27Hopane

#15

Unknown

#16

<%)

C28Hopane

#17

{%)

Unknown

Peak #18(%)

C29Hopane

#19<%)

.2.5 5.9 0.6 3.4 1.2 0.9 11.1

>X2026>X2031>X2046>X2051>X20S6>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

6.506.814.721.724.875.074.414.76

1.922.463.083.923.563.733.783.54

1.360.640.850.191.231.050.490.96

1.050.930.590.570.910.781.180.80

1.680.952.353.734.143.484.093.53

0.670.000.590,380.510.540.710.34

5.598.32

11.328.328.798.58

11.117.52


File # Description

>X2026>X2031>X204 6>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C29Norhop

#20

Diahopane

Peak F

3.1

C29Moretane

#21

7.1

C30Oleanane

#22

1.6

C30Hopane

#23

C30Moretane

#24

17.2 1.9

Unknown

#25

<*)

1.9

2.002.821.061.242.911.932.442.75

2.352,793.202.101.872.192.452.10

0.951.401.654.302.051,452.061.76

0.300.100.240.290.450.070.160.36

8.1812.2915.2912.3311.6711.9914.8810.95

1.281.792.134.881.691.702.321.48

0.140.130.080.480,290.310.530.36


File # Description Unknown

#26

(%)

C31Hopane

22S#27

(%)

C31Hopane

22R#28<%)

C31Moretane

Peak #29

Gammacerene

Peak G

(%)

C32Hopane

22S#30(%>

C32Hopane

22R#31«%)

5.7 5.5 7.1 4,1 2.3 3.1

>X2026>X2031>X2046>X2051>X2Q56>X2061>X2066>X2071

25-/1-925/2-102-5/5-125/6-125/8-125/8-425/11-525/11-15

0.320.310.270.380.170.000.990.28

3.343.706.125.164.254.485.704.11

2.713.124.075.453.063.434.402.87

0.530.630.643.060.790.600.340.66

0.451.651.310.671.050.901.641.70

2.272.533.573.732.632.763.702.85

"1.701.872.644,021.992.222.502.08



Moretane

#32

X%)

C31 bbHomohop

#33<%}

C33Hopane

22S#34

{%)

C33Hopane

22R#35<%)

C34Hopane

22S#36(%)

C34Hopane

22R#37{%)

C35Hopane

225#3.8(%)

0.5 1.3 1.3 1.4 1.0 1.1 0.1

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

0.060.140.151.530.090.130.57

0.13

0.140.100.080.38

0.180.27

0.400.21

1.581.472.18

2.202.192 .17

2.702.32

0.951.351.62

1.821.451.58

1.831.61

1.190.921.790.291.271.27

1.29

1.30

0.970.761.000.761.000.780.680.78

0.750.871.200.761.081.171.121.17


File # Description

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C35 centration % Compositions ofHopane Triterpanes22R Diterpanes Triterpanes Tricyclics Hopanes Moretanes#39(%) (ppm) (ppm) {%) {%) (%)

0.0 81

0.790.481.200.480.790.850.730.77

13.8416.2615.961.36

49,7731.9329.3539.96

5642

30.2861.94

103.988.27

206.01131.66272.88151.04

3.6

19.6816.978.717.6212.8213.359.96

13.83

80.0

75.0075.2583.9674.1279.5380.1581.7978.19

T5/TM

16.5

4.595.495.6917.416.235.276.305.61

0.42

3.382.771.530.441.371.361.171.34


File # Description

>X202 6>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

Ratios

Hopanes ====== ===== s/R+S ===

C28/C30 C30/C29 C31 C32 C33 C34

0.07

= ne/Moretane

C35 C29/C29 C30/C30

1.55 0.43 0.42 0.48 0.48 0.71

0.210.080.150.300.350.290.270.32

1.461.481.351.481.331.401.341.46

0.550.540.600.490.580.570.560.59

0.570.570.580.480.570.550.600.58

0.620.520.570.550.600.580.600.59

0.550.550.640.270.560.620.660.62

0.490.650.500.620.580.580.610.60

1.56 9.12

5.875.966.861.934.305.905.414.26

6.416.867.182.536.927.056.407.40


File # Description Carotane

{ppm)

TOTALDITERP

TOTALTRITERP

#10TricyclRatio

#11ExtendedHOPANESRatio

#12C28

HOPANESRatio

#13Oleanane

Ratio

{ppm} (ppm)

5 .0 5642 0 . 2 9 1 4 . 6 0 0.07 0 .09

>X2026>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1Q25/5-125/6-125/8-125/8-425/11-525/11-15

0.060.190.120.090.180.190.400.18

13.8416.2615.961.3649.7731.9329.3539.96

30,2861.94

103.988.27

206.01131.66272.88151.04

2.361.420.730.781,201.330.621.46

1,411.241.160.851.221.021.061.08

0.210,080.150.300.350.290,270.32

0.040.010.020.020.040.010.010.03


File # Description

>X20.26>X2031>X2046>X2051>X2056>X2061>X2066>X2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

#14

TS/TM

#15C30

HOPANE

(ppm)

'AKE TERNARY

TRICYCLICS

(ppm)

HOPANES

(ppm)

MORETANES

(ppm)

0.42

3.382.771.530.441.371.361.171.34

1177,0

4.0410.5619.821.29

32.4521.4448.3423.02

201 4511

5.9610,519.060.63

26.4117.5827.1820.89

22.714.6.6187.306.13

163.85105.53223.18118.10

930

1.393.405.921.44

12.846.94

17.208.47


Norsk-Hydro Well #25 OilsMonoaromatized Steranes (m/z=253)

Concentrations o£ Monoaromatized Steranes (m/z=253)C21 C22 Unknown Unknown C27 Unknown C27 C27 C28 C27+C28

bS bR aS bS aR+aSFile #

A2026A2031A2046A2051A2056A2061A20 66A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

Peak #1(pptn)

0.390.390.770.063.191.750.222.39

#2{ppm)

0.190.220.560.011.280.650. 770.84

#3tppm}

0.020.270.580.101.500.871.051.25

#4(ppm)

1.092.154.13Q-1211.996.998.749.57

#5(ppm)

0.200.360.790.053.862.052.853.21

#6(ppm)

0.821.653.440.108.885,156.347.16

#7(ppm)

1.212.525.550.27

14.219.08

10.8011.90

#8{ppm)

0.330.531.040.104.572.673,493.88

#9{ppm)

0.430.661.040.062.581.471.802.09

#10(ppm)

0.501.253.120.295.243.824.054,75

Aromatized Sterane Analyses Page 1 3/20/93

File #

A2026

A2031A204 6A2051A2056

A2061A2066A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-5

25/11-15

C28bR

#11(ppm)

0 .821.602.520.156.44

3.734.29

4.48

C29

bS#12

(ppm)

1.37

1.782.150.06

6.364.134.594.84

C29

(?)#13

(ppm)

0.020.080.230.021.27

0.860.76

1.18

C29(?)#14

(ppm)

0.430.882.230.213.902.62

2.593.27

C29bR

#15{ppm)

0.210.380.400.101.84

1.241.301.77

C28aR

#16(ppm)

0.370.500.650.06

1.961.381.371.83

C29aR

#17(ppm)

0.430.610.770.062.21

1.451,321.85


Norsk-Hydro Well #25 OilsMonoaromatized Steranes (m/z=253)

File #

A2026A2031A2046A2051A2056A2061A2066A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C21

Peak #1(%)

4,422.462.573.303.923.510.383.61

Percent Compositions ofC22 Unknown

#2(%}

2.151.391.870.551.571.301.371.27

#3(%)

0.231.711.945.491.851.741.861.89

Unknown

#4(%)

12.3413.5813.786.59

14.7514.0115.5214.44

Monoaromatized.C27bS#5<%}

2.272.272.642.754.754.115.064.84

Unknown

#6(%)

9.2910.4211.485.49

10.9310. 3211.2610.81

SteranesC27bR#7(%)

13.7015.9218.5214.8417.4818,1919.1717.96

C27aS#8(%)

3.743.353.475.495.625.356.205.86

C28bS#9(%)

4.874.173.473.303.172.953.203.15

C27+C28aR+aS

#10(%)

5.667.90

10.4115.936.457.657.197.17


C29 C29

(?) (?)File # Description #11 #12 #13 #14

C28bR#11

C29bS#12

C29bR#15

C28aR#16

C29aR

#17

A2026A2031A2046A2051A2056A2061A2066A2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

9.2910.118.418.247.927.477.626,76

15.5211.247,173.307.828.278.157.30

0.230.510.771.101.561.721.351.78

4.875.567.44

11.544.805.254.604,94

2.382.401,335.492.262.482.312.67

4.193.162.173.302.412.762.432.7 6

4.873.852,573.302.722.912.342.79


Norsk-Hydro Well #25 OilsTriarosnatized Steranes {m/z™231)

File #

A2026A2031A2046A2051A2056A2061A2066A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

C-20Peak #1{ppm)

5.676.849.650.26

23.0715.3015.971.6.02

Concentrations ofTriaromat;ed

C-21#2

(ppm)

3.014.554.570.2513.349.279.169.60

C-26#3

(Ppm)

0.370.810.870.023.012.142.052.89

SteraniC-27*

#4(ppm)

0.872.122.690.057.965.775.468.06

C-28#5

(ppm)

0.551.241.670.033.622.712.663.54

C-27/28#6

{ppm)

0.561.461.860.035.833.924.045.50

C-28*#7

(PP»)

0.361.081.500.044.633.013.204.29


File #

A2026A2031A2046A2051A2056A2061A2066A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

Percent composition of

C-20Peak #1

(%)

4.9.7837.7942.4138.2437,5436.3237.5432.10

Triaromat:edC-21

#2(%)

26.4325.1420.0036.7621.7122.0121.5319.24

C~26#3

(%)

3.254.483.812.944.905.084.825.79

Steran;C-27*

#4

<%)

7.6411.7111.777.35

12.9513.7012.8316.15

C-28#5(%)

4.836.857.314.415.896.436.257.09

C-27/28#6

{%)

4.928.078.144.419-499.319.50

11.02

C-28*#7

{%)

3.165.976.565.887.537.157.528.60


File #

A2026A2031A2046A2051A2056A2061A2066A2071

Description

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

Selected Ratios of Mono & Triaromatized

MonoaromatizedSterane

C21+22/C27-29

0.080-050.060.050.070.060.020.06

C21/C21+28

<%>

32.2319.6023.4028.5733.1331.934.77

34.79

Steranes#25 Oils

Triaromatized

C20+21/C2 6-28

3.201.701.663 • 001.451.401.441.06

C20/C20+C27

(%)

86.7076.3478.2783.8774.3572.6274.5266.53

Steranes

C21/C21+28

(%)

89.3280.8275.2986.2.174.2375.4974.1169.11


File # Description

Tri/Monoaroraatized Steranes

to be extrac

DTAS 231(C27)/231(C27)+253{C28)

231(C28)/231(028}+253(C29)

A2026A2Q31A2046A2051A2056A2061A2066A2071

25/1-925/2-1025/5-125/6-125/8-125/8-425/11-525/11-15

76.2162.9362.4175.0059.2458.3359.0751.34

66.9276.2672.1245.4575,5279.7075.217 9.41

36.0052,1756.1820.0053.3452.8154.9854.24

Aromatized Stefane Analyses Page 3/20/93

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