detax gmbh & co. kg safety data sheet · containes polydimethylsiloxanes with functional...

mollosil (Bsase + Catalyst)

Safety Data Sheet

Product code: 10488Print date: 12.05.2015 of 6

DETAX GmbH & Co. KG

according to Regulation (EC) No 1907/2006

SECTION 1: Identification of the substance/mixture and of the company/undertaking


1.1. Product identifier

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture

Professional

Relining material for use in dentistry.

1.3. Details of the supplier of the safety data sheet

DETAX GmbH & Co. KGCompany name:

Carl-Zeiss-StrasseStreet:

D-76275 EttlingenPlace:

Telephone: +49 7243/510-0 Telefax:+49 7243/510-100

e-mail: [email protected]

www.detax.deInternet:

Emergency number:

+49 7243/510-0

This number is only obtainable during office hours (Monday - Thursday 8.00 a.m.

- 5.00 p.m., Friday 8.00 a.m. - 4.00 p.m.)

Responsible Department:

+49 7243/510-0


- 5.00 p.m., Friday 8.00 - 4.00 p.m.)

1.4. Emergency telephone

number:

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture

Classification according to Directive 67/548/EEC or 1999/45/EC

This mixture is not classified as hazardous according to Directive 1999/45/EC.

Classification according to Regulation (EC) No. 1272/2008 [CLP]

This mixture is not classified as hazardous according to Regulation (EC) No. 1272/2008.

2.2. Label elements

No information available.

2.3. Other hazards

SECTION 3: Composition/information on ingredients

3.2. Mixtures

Containes polydimethylsiloxanes with functional groups. + fillers and pigment

catalyst: additionally platinum complex compound.

Chemical characterization

SECTION 4: First aid measures

4.1. Description of first aid measures

Provide fresh air.

After inhalation

Wash with plenty of water. Take off contaminated clothing and wash it before reuse.

After contact with skin

Rinse immediately carefully and thoroughly with eye-bath or water.

After contact with eyes

Revision No: 2,00 Revision date: 07.05.2015 GB - EN

mailto:[email protected]

http://www.detax.de


Safety Data Sheet


DETAX GmbH & Co. KG


Rinse mouth immediately and drink plenty of water.

Seek immediately medical advice. Do not induce vomiting. In case of spontaneous vomiting take care

of an unhindered flow out of the vomit (danger of suffocation).

After ingestion

4.2. Most important symptoms and effects, both acute and delayed


4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Co-ordinate fire-fighting measures to the fire surroundings.

Suitable extinguishing media

5.2. Special hazards arising from the substance or mixture

Non-flammable.

In case of fire: Wear self-contained breathing apparatus.

5.3. Advice for firefighters

SECTION 6: Accidental release measures

Use personal protection equipment.

6.1. Personal precautions, protective equipment and emergency procedures

No special environmental measures are necessary. Clean contaminated objects and areas thoroughly

observing environmental regulations.

6.2. Environmental precautions

Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).

Treat the recovered material as prescribed in the section on waste disposal .

6.3. Methods and material for containment and cleaning up

Safe handling: see section 7

Personal protection equipment: see section 8

Disposal: see section 13

6.4. Reference to other sections

SECTION 7: Handling and storage

7.1. Precautions for safe handling

No special measures are necessary.

Advice on safe handling

No special fire protection measures are necessary.

Advice on protection against fire and explosion

7.2. Conditions for safe storage, including any incompatibilities

Keep container tightly closed.

Requirements for storage rooms and vessels

Do not store with acids, lyes, alcohols, metallic powders and metallic oxides (release of hydrogen is

favoured).

Advice on storage compatibility

Keep only in the original container in a cool, dry and well-ventilated place, away from foodstuffs.

Further information on storage conditions

7.3. Specific end use(s)

Silicone material for denture relinings.



Safety Data Sheet


DETAX GmbH & Co. KG


For use by trained specialist staff.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

8.2. Exposure controls

Take off contaminated clothing. Wash hands before breaks and after work. When using do not eat or

drink.

Protective and hygiene measures

Wear eye/face protection.

Eye/face protection

When handling with chemical substances, protective gloves must be worn with the CE-label including

the four control digits. The quality of the protective gloves resistant to chemicals must be chosen as a

function of the specific working place concentration and quantity of hazardous substances. For special

purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned

above together with the supplier of these gloves.

Hand protection

Wear suitable protective clothing.

Skin protection

In case of inadequate ventilation wear respiratory protection.

Respiratory protection

base: dark red , catalyst: liigth blue

PastePhysical state:

Colour:

9.1. Information on basic physical and chemical properties

SECTION 9: Physical and chemical properties

characteristicOdour:

Test method

pH-Value: not determined

Changes in the physical state

not determinedMelting point:

not determinedInitial boiling point and boiling range:

>100 °C DIN 51755Flash point:

Flammability

not applicableSolid:

not applicableGas:

not determinedLower explosion limits:

not determinedUpper explosion limits:

DIN 51794>400 °CIgnition temperature:

Auto-ignition temperature


not applicableGas:

Decomposition temperature: >180 °C

Not oxidizing.

Oxidizing properties

Vapour pressure:

(at 20 °C)

<10 hPa



Safety Data Sheet


DETAX GmbH & Co. KG


Density (at 20 °C): 1,02 g/cm³ DIN 51757

Water solubility: insoluble

Solubility in other solvents

not determined

not determinedPartition coefficient:

Viscosity / dynamic:

(at 23 °C)

BROOKFIELD300000 mPa·s

not determinedVapour density:

Evaporation rate: not determined

9.2. Other information

not determinedSolid content:

SECTION 10: Stability and reactivity

10.1. Reactivity

No hazardous reaction when handled and stored according to provisions.

10.2. Chemical stability

The product is stable under storage at normal ambient temperatures.

10.3. Possibility of hazardous reactions

Reacts with :

Temperatures > 150°C/ 302 °F.

10.4. Conditions to avoid


10.5. Incompatible materials

The following applies for the silicone content of the product: At temperature of appr. 150°C/ 302 °F a

small amount of formaldehyde can be released by oxidative degradation.

10.6. Hazardous decomposition products

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity

Based on available data, the classification criteria are not met.

For the product itself no toxicological data are available. In products with a comparable composition, a

LD50 (orally, species rat) of > 5000 mg/kg has been found.

Irritation and corrosivity


Sensitising effects


STOT-single exposure


Severe effects after repeated or prolonged exposure


Carcinogenic/mutagenic/toxic effects for reproduction


Aspiration hazard




Safety Data Sheet


DETAX GmbH & Co. KG


This mixture is classified as not hazardous according to regulation (EC) 1272/2008 [CLP].

Additional information on tests

SECTION 12: Ecological information

12.1. Toxicity

The product is not: Ecotoxic.

12.2. Persistence and degradability

The product has not been tested.

12.3. Bioaccumulative potential



12.4. Mobility in soil

12.5. Results of PBT and vPvB assessment

Not identivied as PBT/ vPvB substances


12.6. Other adverse effects

Avoid release to the environment.

Further information

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Advice on disposal

Dispose of waste according to applicable legislation.

Wash with plenty of water. Completely emptied packages can be recycled.

Contaminated packaging

SECTION 14: Transport information

Land transport (ADR/RID)

14.1. UN number: No dangerous good in sense of this transport regulation.

No dangerous good in sense of this transport regulation.14.2. UN proper shipping name:

No dangerous good in sense of this transport regulation.14.3. Transport hazard class(es):

No dangerous good in sense of this transport regulation.14.4. Packing group:

Inland waterways transport (ADN)




14.4. Packing group: No dangerous good in sense of this transport regulation.

Marine transport (IMDG)





Air transport (ICAO)




Safety Data Sheet


DETAX GmbH & Co. KG





14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:

14.6. Special precautions for user

No dangerous good in sense of this transport regulation.

14.7. Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code


SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture

EU regulatory information

Additional information

To follow: 850/2004/EC, 79/117/EEC, 689/2008/EC

National regulatory information

- - not water contaminatingWater contaminating class (D):

15.2. Chemical safety assessment

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Abbreviations and acronyms

ADR: Accord européen sur le transport des marchandises dangereuses par Route

(European Agreement concerning the International Carriage of Dangerous Goods by Road )

IMDG: International Maritime Code for Dangerous Goods

IATA: International Air Transport Association

GHS: Globally Harmonized System of Classification and Labelling of Chemicals

EINECS: European Inventory of Existing Commercial Chemical Substances

ELINCS: European List of Notified Chemical Substances

CAS: Chemical Abstracts Service

LC50: Lethal concentration, 50%

LD50: Lethal dose, 50%

The above information describes exclusively the safety requirements of the product and is based on

our present-day knowledge. The information is intended to give you advice about the safe handling of

the product named in this safety data sheet, for storage, processing, transport and disposal. The

information cannot be transferred to other products. In the case of mixing the product with other

products or in the case of processing, the information on this safety data sheet is not necessarily valid

for the new made-up material.

Further Information

(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's safety

data sheet.)


mollosil Adhesive

Safety Data Sheet

Product code: 10528Print date: 20.05.2015 Page 1 of 9

DETAX GmbH & Co. KG



mollosil Adhesive




Professional

Adhesive for denture relinings for use in dentistry.








Emergency number:

+49 7243/510-0


- 5.00 p.m., Friday 8.00 a.m. - 4.00 p.m.)


+49 7243/510-0


- 5.00 p.m., Friday 8.00 - 4.00 p.m.)


number:




Indications of danger: F - Highly flammable, Xi - Irritant

R phrases:

Highly flammable.

Irritating to eyes.

Repeated exposure may cause skin dryness or cracking.

Vapours may cause drowsiness and dizziness.


Hazard categories:

Flammable liquid: Flam. Liq. 2

Serious eye damage/eye irritation: Eye Irrit. 2

Specific target organ toxicity - single exposure: STOT SE 3

Hazard Statements:

Highly flammable liquid and vapour.

Causes serious eye irritation.

May cause drowsiness or dizziness.

2.2. Label elements

Hazardous components which must be listed on the label

ethyl acetate

Signal word: Danger

Pictograms: GHS02-GHS07



http://www.detax.de

mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG


H225 Highly flammable liquid and vapour.

H319 Causes serious eye irritation.

H336 May cause drowsiness or dizziness.

Hazard statements


2.3. Other hazards


3.2. Mixtures

Alkyl silicone resin in organic solvent.


Hazardous components

EC No QuantityChemical name

CAS No Classification according to Directive 67/548/EEC

Index No Classification according to Regulation (EC) No. 1272/2008 [CLP]

REACH No

205-500-4 > 90 %ethyl acetate

F - Highly flammable, Xi - Irritant R11-36-66-67141-78-6

Flam. Liq. 2, Eye Irrit. 2, STOT SE 3; H225 H319 H336 EUH066607-022-00-5

01-2119475103-46

Full text of R-, H- and EUH-phrases: see section 16.



First aider: Pay attention to self-protection! Remove affected person from the danger area and lay

down.

General information

Provide fresh air. In case of accident or unwellness, seek medical advice immediately (show directions

for use or safety data sheet if possible).

After inhalation

Wash with plenty of water. Take off contaminated clothing and wash it before reuse.


After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then

consult an ophthalmologist immediately.


Observe risk of aspiration if vomiting occurs. Rinse mouth immediately and drink plenty of water.



After ingestion






mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG




Carbon dioxide (CO2), Foam, Extinguishing powder.


Water.

Unsuitable extinguishing media


Flammable. Vapours can form explosive mixtures with air.

In case of fire: Wear self-contained breathing apparatus.


Use water spray jet to protect personnel and to cool endangered containers. Suppress

gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do

not allow entering drains or surface water.



Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray.

Avoid contact with skin, eyes and clothes. Use personal protection equipment.


Do not allow uncontrolled discharge of product into the environment. Danger of explosion











If handled uncovered, arrangements with local exhaust ventilation have to be used. Do not breathe

gas/fumes/vapour/spray.


Keep away from sources of ignition. - No smoking. Take precautionary measures against static

discharges. Vapours can form explosive mixtures with air.



Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces,

sparks, open flames and other ignition sources. No smoking.


Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.



Adhesive for silicone based denture relinings.



mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG



Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)200Ethyl acetate141-78-6 - WEL

STEL (15 min)400 - WEL




Appropriate engineering controls

Remove contaminated, saturated clothing immediately. Draw up and observe skin protection

programme. Wash hands and face before breaks and after work and take a shower if necessary .

When using do not eat or drink.


Suitable eye protection: goggles.

Eye/face protection






Suitable are gloves of the following material: Butyl caoutchouc (butyl rubber)

Hand protection

Flame-retardant protective clothing. Wear anti-static footwear and clothing

Skin protection



colourless

liquid:Physical state:

Colour:



Acetic acidOdour:

Test method




72 °C DIN 51356Initial boiling point and boiling range:

3 °C DIN 51755Flash point:

Flammability


not applicableGas:

2,1 vol. %Lower explosion limits:

11,5 vol. %Upper explosion limits:

DIN 51794460 °CIgnition temperature:



mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG



not applicableGas:


Not oxidizing.


Vapour pressure:

(at 20 °C)

97 hPa

Vapour pressure:

(at 50 °C)

375 hPa


Water solubility: partially miscible


not determined



(at 23 °C)







10.1. Reactivity

Flammable, Ignition hazard.




Reacts with : combustible materials.

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form

explosive mixtures with air.









Acute toxicity



mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG


Chemical nameCAS No

SpeciesDoseMethodExposure routes Source

141-78-6 ethyl acetate

RatLD50 >2000 mg/kgoral

RabbitLD50 >2000 mg/kgdermal



Sensitising effects



May cause drowsiness or dizziness. (ethyl acetate)





Aspiration hazard


This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].



12.1. Toxicity


CAS No Chemical name

[h] | [d]Aquatic toxicity Method Dose SourceSpecies

ethyl acetate141-78-6

Acute fish toxicity 96 h OECD 203LC50 >100 mg/l Salmo trutta fario (L)

(Freshwater trout)

Acute algae toxicity 72 hErC50 >100 mg/l Desmodesmus

subspicatus.

Acute crustacea toxicity 48 hEC50 >100 mg/l Daphnia magna (Big water

flea)




SourceValueMethod d

Evaluation

ethyl acetate141-78-6

OECD 301D/ EEC 92/69/V, C.4-E >70% 28



Partition coefficient n-octanol/water

Log PowChemical nameCAS No

141-78-6 0,68ethyl acetate




mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG






Avoid release to the environment.

Further information



Advice on disposal

Do not allow to enter into surface water or drains. Dispose of waste according to applicable legislation.

Wash with plenty of water. Completely emptied packages can be recycled.




14.1. UN number: UN 1866

Resin solution14.2. UN proper shipping name:

314.3. Transport hazard class(es):

II14.4. Packing group:

3Hazard label:

Classification code: F1

Limited quantity: 5 L

Transport category: 2

33Hazard No:

Tunnel restriction code: D/E

Flammable licquid

Other applicable information (land transport)






3Hazard label:

-Marine pollutant:

-Special Provisions:

Limited quantity: 5 L/ 30 kg

F-E, S-EEmS:

Flash point: 3°C c.c.

Other applicable information (marine transport)






3Hazard label:


mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG


A3Special Provisions:

Limited quantity Passenger: 1 L/ 30 kg

Y341Passenger LQ:

353IATA-packing instructions - Passenger:

5 LIATA-max. quantity - Passenger:

364IATA-packing instructions - Cargo:

60 LIATA-max. quantity - Cargo:


Warning: Combustible liquid.


not applicable




0,09 % (0,81 g/l)2010/75/EU (VOC):

0,09 % (0,81 g/l)2004/42/EC (VOC):




Observe employment restrictions for young people.Employment restrictions:

1 - slightly water contaminatingWater contaminating class (D):















Relevant R-phrases (Number and full text)

11 Highly flammable.

36 Irritating to eyes.

66 Repeated exposure may cause skin dryness or cracking.

67 Vapours may cause drowsiness and dizziness.

Relevant H- and EUH-phrases (Number and full text)



H336 May cause drowsiness or dizziness.

EUH066 Repeated exposure may cause skin dryness or cracking.


Further Information


mollosil Adhesive

Safety Data Sheet


DETAX GmbH & Co. KG








data sheet.)


Lustrol gloss varnish (base)

Safety Data Sheet


DETAX GmbH & Co. KG







Professional

Lacquer for denture relinings for use in dentistry.








Emergency number:

+49 7243/510-0


- 5.00 p.m., Friday 8.00 a.m. - 4.00 p.m.)


+49 7243/510-0


- 5.00 p.m., Friday 8.00 - 4.00 p.m.)


number:




Indications of danger: F - Highly flammable, Xn - Harmful, Xi - Irritant

R phrases:

Highly flammable.

Harmful by inhalation and in contact with skin.

Irritating to skin.


Hazard categories:

Flammable liquid: Flam. Liq. 2

Skin corrosion/irritation: Skin Irrit. 2

Hazard Statements:

Highly flammable liquid and vapour.

Causes skin irritation.

2.2. Label elements

Signal word: Danger



H315 Causes skin irritation.

Hazard statements



http://www.detax.de


Safety Data Sheet


DETAX GmbH & Co. KG


P280 Wear protective gloves/protective clothing/eye protection/face protection.Precautionary statements


2.3. Other hazards


3.2. Mixtures

Alkyl silicone resin in organic solvent.






REACH No

215-535-7 20 - < 25 %xylene

Xn - Harmful, Xi - Irritant R10-20/21-381330-20-7

Flam. Liq. 3, Acute Tox. 4, Acute Tox. 4, Skin Irrit. 2; H226 H332 H312 H315601-022-00-9

202-849-4 5 - < 10 %ethylbenzene

F - Highly flammable, Xn - Harmful R11-20-48/20-65100-41-4

Flam. Liq. 2, Acute Tox. 4, STOT RE 2, Asp. Tox. 1; H225 H332 H373 H304601-023-00-4




Provide fresh air.

After inhalation

After contact with skin, wash immediately with polyethylene glycol, followed by plenty of water. Take off

immediately all contaminated clothing and wash it before reuse. If skin irritation occurs: Get medical

advice/attention.


After contact with the eyes, rinse with water with the eyelids open for a sufficient length of time , then

consult an ophthalmologist immediately.


Rinse mouth immediately and drink plenty of water.



After ingestion







Carbon dioxide (CO2), Foam, Extinguishing powder.




Safety Data Sheet


DETAX GmbH & Co. KG


Water.

Unsuitable extinguishing media


Flammable. Vapours can form explosive mixtures with air.

Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.


Use water spray jet to protect personnel and to cool endangered containers. Suppress

gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water separately. Do

not allow entering drains or surface water.



Remove all sources of ignition. Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray.

Avoid contact with skin, eyes and clothes. Use personal protection equipment.


Do not allow uncontrolled discharge of product into the environment. Danger of explosion











No special measures are necessary.


Keep away from sources of ignition. - No smoking. Take precautionary measures against static

discharges. Vapours can form explosive mixtures with air.



Keep container tightly closed. Keep in a cool, well-ventilated place. Keep away from heat, hot surfaces,

sparks, open flames and other ignition sources. No smoking.


Do not store together with: Oxidising agent. Pyrophoric or self-heating substances.


Component B of a silicone lacquer for use in dentistry.




Component B of a silicone lacquer for use in dentistry.






Safety Data Sheet


DETAX GmbH & Co. KG


Exposure limits (EH40)

Categoryfibres/mlmg/m³ppmSubstanceCAS No Origin

TWA (8 h)100Ethylbenzene100-41-4 441 WEL

STEL (15 min)125 552 WEL

TWA (8 h)50Xylene: mixed isomers1330-20-7 220 WEL

STEL (15 min)100 441 WEL

Biological Monitoring Guidance Values (EH40)

Sampling timeParameter Value Test materialSubstanceCAS No

1330-20-7 Xylene, o-, m-, p- or mixed isomers urine650

mmol/mol

Post shiftmethyl hippuric acid






Wear eye/face protection.

Eye/face protection






Suitable are gloves of the following material: FKM (fluoro rubber)

Hand protection

Flame-retardant protective clothing. Wear anti-static footwear and clothing

Skin protection



colourless


Colour:



BenzeneOdour:

Test method




95 °C DIN 51356Initial boiling point and boiling range:

10 °C DIN 51755Flash point:

Flammability


not applicableGas:

4 vol. %Lower explosion limits:



Safety Data Sheet


DETAX GmbH & Co. KG


32 vol. %Upper explosion limits:




not applicableGas:


Not oxidizing.


Vapour pressure:

(at 20 °C)

29 hPa

Vapour pressure:

(at 50 °C)

1100 hPa




not determined



(at 23 °C)







10.1. Reactivity

Flammable, Ignition hazard.




No known hazardous reactions.

Keep away from sources of heat (e.g. hot surfaces), sparks and open flames. Vapours can form

explosive mixtures with air. Reacts with : strong oxidising agents. The product may attack same plastic

materials.









Acute toxicity




Safety Data Sheet


DETAX GmbH & Co. KG


Chemical nameCAS No


1330-20-7 xylene

RatLD50 4300 mg/kg GESTISoral

RabbitLD50 >1700 mg/kg GESTISdermal

inhalative (4 h) vapour LC50 21,7 mg/l Rat GESTIS

inhalative aerosol ATE 1,5 mg/l

100-41-4 ethylbenzene

RatLD50 3500 mg/kg GESTISoral

RabbitLD50 15400 mg/kg GESTISdermal

inhalative (4 h) vapour LC50 17,2 mg/l Rat



Causes skin irritation.

Sensitising effects








Aspiration hazard


This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP].



12.1. Toxicity



[h] | [d]Aquatic toxicity Method Dose SourceSpecies

xylene1330-20-7

Acute fish toxicity 96 h GESTISLC50 15,7 mg/l

Acute crustacea toxicity 48 h GESTISEC50 8,5 mg/l

ethylbenzene100-41-4

Acute algae toxicity 96 h GESTISErC50 3,6 mg/l





Partition coefficient n-octanol/water

Log PowChemical nameCAS No

100-41-4 3,15ethylbenzene



Safety Data Sheet


DETAX GmbH & Co. KG








Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Further information



Advice on disposal

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of

waste according to applicable legislation.

Non-contaminated packages may be recycled. Handle contaminated packages in the same way as the

substance itself.








3Hazard label:

Classification code: F1


Transport category: -

33Hazard No:

Tunnel restriction code: D/E

Flammable licquid

Other applicable information (land transport)






3Hazard label:

-Marine pollutant:

-Special Provisions:


F-E, S-EEmS:

Flash point: 10°C c.c.

Other applicable information (marine transport)





Safety Data Sheet


DETAX GmbH & Co. KG





3Hazard label:

Limited quantity Passenger: 1 L/ 30 kg

Y341Passenger LQ:

353IATA-packing instructions - Passenger:

5 LIATA-max. quantity - Passenger:

364IATA-packing instructions - Cargo:

60 LIATA-max. quantity - Cargo:


Warning: Combustible liquid.


not applicable




5 % (47,5 g/l)2010/75/EU (VOC):

5 % (47,5 g/l)2004/42/EC (VOC):




Observe employment restrictions for young people.Employment restrictions:

3 - highly water contaminatingWater contaminating class (D):
















10 Flammable.

11 Highly flammable.

20 Harmful by inhalation.

20/21 Harmful by inhalation and in contact with skin.

38 Irritating to skin.

48/20 Harmful: danger of serious damage to health by prolonged exposure through inhalation.

65 Harmful: may cause lung damage if swallowed.



Safety Data Sheet


DETAX GmbH & Co. KG




H226 Flammable liquid and vapour.

H304 May be fatal if swallowed and enters airways.

H312 Harmful in contact with skin.

H315 Causes skin irritation.

H332 Harmful if inhaled.

H373 May cause damage to organs through prolonged or repeated exposure.







Further Information


data sheet.)


Lustrol (Catalyst)

Safety Data Sheet




Lustrol (Catalyst)




Lacquer for denture relinings for use in dentistry.





Indications of danger: T - Toxic, Xn - Harmful, Xi - Irritant

R phrases:

May impair fertility.

May cause harm to the unborn child.

Harmful by inhalation and if swallowed.

Risk of serious damage to eyes.

Toxic: danger of serious damage to health by prolonged exposure if swallowed.

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.

Possible risks of irreversible effects.


Hazard categories:

Acute toxicity: Acute Tox. 4

Serious eye damage/eye irritation: Eye Irrit. 2

Germ cell mutagenicity: Muta. 2

Specific target organ toxicity - repeated exposure: STOT RE 1

Hazardous to the aquatic environment: Aquatic Chronic 3

Hazard Statements:

Harmful if swallowed or if inhaled.


Suspected of causing genetic defects.

Causes damage to organs through prolonged or repeated exposure.

Harmful to aquatic life with long lasting effects.

2.2. Label elements

Hazardous components which must be listed on the label

alkylstannosiloxane

Signal word: Danger


H302+H332 Harmful if swallowed or if inhaled.


H341 Suspected of causing genetic defects.

H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.

Hazard statements


Lustrol (Catalyst)

Safety Data Sheet



P201 Obtain special instructions before use.

P280 Wear protective gloves/protective clothing/eye protection/face protection.

P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if

present and easy to do. Continue rinsing.

P308+P313 IF exposed or concerned: Get medical advice/attention.

P310 Immediately call a POISON CENTER/doctor.

Precautionary statements


2.3. Other hazards


3.2. Mixtures

Silicon-tin-compound with auxilliary matters.






REACH No

300-344-4 45 - < 50 %alkylstannosiloxane

Muta. Cat. 3, Repr. Cat. 1, T - Toxic, Xn - Harmful, Xi - Irritant

R60-61-10-20/22-41-48/25-52-53-68

93925-42-9

Flam. Liq. 3, Muta. 2, Repr. 1, Acute Tox. 4, Acute Tox. 4, Eye Dam. 1, STOT RE 1,

Aquatic Chronic 3; H226 H341 H360D H302 H332 H318 H372 H412

01-2119560586-30




First aider: Pay attention to self-protection! Remove affected person from the danger area and lay

down.

General information

Provide fresh air. When in doubt or if symptoms are observed, get medical advice.

After inhalation

Wash with plenty of water. Immediately remove any contaminated clothing, shoes or stockings.

Medical treatment necessary.


In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes holding

eyelids apart and consult an ophthalmologist.


Rinse mouth immediately and drink plenty of water. Let water be drunken in little sips ( dilution effect).



After ingestion






Lustrol (Catalyst)

Safety Data Sheet





Co-ordinate fire-fighting measures to the fire surroundings.



Non-flammable.

Wear a self-contained breathing apparatus and chemical protective clothing. Full protection suit.


Suppress gases/vapours/mists with water spray jet. Collect contaminated fire extinguishing water

separately. Do not allow entering drains or surface water.



Provide adequate ventilation. Do not breathe gas/fumes/vapour/spray. Avoid contact with skin, eyes

and clothes. Use personal protection equipment.


Do not allow to enter into surface water or drains.














No special fire protection measures are necessary.



Keep container tightly closed. Keep locked up. Store in a place accessible by authorized persons only.

Provide adequate ventilation as well as local exhaustion at critical locations.


Do not store with strong oxidising materials.


Keep only in the original container in a cool, dry and well-ventilated place, away from foodstuffs.



Component A of a silicone lacquer for use in dentistry .





Lustrol (Catalyst)

Safety Data Sheet






Appropriate engineering controls





Suitable eye protection: goggles.

Eye/face protection






Suitable are gloves of the following material: Butyl caoutchouc (butyl rubber) , FKM (fluoro rubber) , CR

(polychloroprene, chloroprene rubber)

Hand protection

Wear suitable protective clothing.

Skin protection



colourless


Colour:



characteristicOdour:

Test method




>200 °C DIN 51356Initial boiling point and boiling range:

>100 °C DIN 51755Flash point:

Flammability


not applicableGas:

not determinedLower explosion limits:

not determinedUpper explosion limits:




not applicableGas:


Not oxidizing.



Lustrol (Catalyst)

Safety Data Sheet



Vapour pressure:

(at 20 °C)

<1 hPa




not determined



(at 23 °C)

BROOKFIELD<80 mPa·s






10.1. Reactivity

No hazardous reaction when handled and stored according to provisions.




Reacts with : strong oxidising agents.

Higher temperatures advance the formation of flammable vapours, therefore don't expose the product

to increased temperatures.




No known hazardous decomposition products.




Acute toxicity

Harmful if swallowed or if inhaled.

For the product itself no toxicological data are available. In products with a comparable composition a

LD50 (orally, species rat) of >2000 mg/kg has been found.

ATEmix calculated

ATE (oral) 1095,2 mg/kg; ATE (inhalative aerosol) 3,286 mg/l

Chemical nameCAS No


93925-42-9 alkylstannosiloxane

ATE 500 mg/kgoral

inhalative vapour ATE 11 mg/l



Lustrol (Catalyst)

Safety Data Sheet





Sensitising effects





Causes damage to organs through prolonged or repeated exposure. (alkylstannosiloxane)


Suspected of causing genetic defects. (alkylstannosiloxane)

Aspiration hazard


This mixture is classified as hazardous according to regulation (EC) No. 1272/2008 [CLP]. Special

hazards arising from the substance or mixture!



12.1. Toxicity

Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.











Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil.

Further information



Advice on disposal

Do not allow to enter into surface water or drains. Do not allow to enter into soil/subsoil. Dispose of

waste according to applicable legislation.

This material and its container must be disposed of as hazardous waste. Handle contaminated

packages in the same way as the substance itself.









Lustrol (Catalyst)

Safety Data Sheet



Inland waterways transport (ADN)




14.4. Packing group: No dangerous good in sense of this transport regulation.











14.5. Environmental hazards

noENVIRONMENTALLY HAZARDOUS:











Observe employment restrictions for young people. Observe employment

restrictions for child bearing mothers and nursing.

Employment restrictions:

3 - highly water contaminatingWater contaminating class (D):
















Lustrol (Catalyst)

Safety Data Sheet




10 Flammable.

20/22 Harmful by inhalation and if swallowed.

41 Risk of serious damage to eyes.

48/25 Toxic: danger of serious damage to health by prolonged exposure if swallowed.

52 Harmful to aquatic organisms.

53 May cause long-term adverse effects in the aquatic environment.

60 May impair fertility.

61 May cause harm to the unborn child.

68 Possible risks of irreversible effects.


H226 Flammable liquid and vapour.

H302 Harmful if swallowed.

H302+H332 Harmful if swallowed or if inhaled.

H318 Causes serious eye damage.


H332 Harmful if inhaled.

H341 Suspected of causing genetic defects.

H360D May damage the unborn child.

H372 Causes damage to organs through prolonged or repeated exposure.

H412 Harmful to aquatic life with long lasting effects.







Further Information


data sheet.)


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