cover meappsd.daera-ni.gov.uk/ipri/docs/p0052-04a lafarge ireland... · 2019. 4. 2. · monitoring...

ISO/IEC 17025 Accredited Legal Entity, UKAS Accredited Testing Laboratory No. 4279Exova (UK) Ltd trading as Exova Catalyst & Exova Catalyst Ireland

Unit C5, Emery Court, The Embankment Business Park, Stockport, SK4 3GL

Stack Reference

Lafarge Ireland LtdCookstown Works29 Sandholes Road

CookstownBT80 9AR

Primary Site Contact: Jim Buchanan

Installation Name & Address

PPC Permit: P0052/04A/V6

EN 14181 AST Report Commissioned by

A8 - Kiln Exhaust Main Stack (Standby Analyser)

Lafarge Ireland Ltd

Exova Catalyst, 70 Montrose Avenue, Hillington Park, Glasgow, G52 4LAYour Exova Catalyst Contact: John Healey (07826 916 681)

E: [email protected]

Job Reference NumberCEK-2909

Report Approved by

Report Written by

COVER ME

Signature of Report Approver

Version 1Report Version

John Healey

29th May 2018Report Date

TE1 TE2 TE3 TE4MM 03 476

MCERTS Level 2

15th - 16th May 2018Dates of the Monitoring Campaign

Regional Manager

Deputy Regional Manager

TE1 TE2 TE3 TE4MM 04 492

MCERTS Level 2

Iain Wilkie

CAT-14181 (Version X)CEK-2909 Lafarge Ireland Ltd (Cookstown) - A8 Kiln Exhaust Main Stack - AST (Standby Analyser)

SECTION 1A: TITLE PAGE

CONTENTS 2

SECTIONS 1B & 1C: EXECUTIVE SUMMARY

Overall Aim of the Monitoring Campaign & Special Requirements 3

AST Calibration Check Summary 3

Summary of Standard Reference Method & EN 14181 Deviations 4

Conclusions, Discussions and Actions arising from the Sampling 5

SECTION 2: INFORMATION ABOUT THE REGULATED INSTALLATION

Regulatory Information 5

Operational Information and Site Monitoring Provisions 6

Monitoring Provisions at the Installation - Periodic Monitoring 7

Continuous Emissions Monitors (CEM) at the Installation 9

SECTION 3: INFORMATION ABOUT THE MONITORING CAMPAIGN

Test Laboratory Staff 10

Standard Reference Methods (SRMs) 10

SECTION 4B: Data and Calculations - AST

SECTION 5: Results of the Functional Tests

CONTENTS

SECTION 5: Results of the Functional Tests

This test report has been written to fully comply with the requirements in EN 14181:2014 and the Environment Agency's Technical Guidance Note TGN M20, Version 3 (incorporating MID 14181 as Annex A) which was published in June 2015.

Opinions and interpretations expressed herein are outside the scope of Exova Catalyst's UKAS accreditation.

This test report shall not be reproduced, except in full, without the written approval of Exova Catalyst.

CAT-14181 (Version X)2 of 37

Lafarge Ireland LtdCookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)

Job Number: CEK-2909, Version 1Sample Date/s: 15th - 16th May 2018


Overall Aim of the Monitoring Campaign

Special Requirements

AST CALIBRATION CHECK SUMMARY

Parameter Calibration Function as Derived from the

Previous QAL2

Result of Calibration

Test

SECTION 1B

Lafarge Ireland Ltd, Cookstown WorksA8 - Kiln Exhaust Main Stack (Standby Analyser)

15th - 16th May 2018

Exova Catalyst were commissioned by Lafarge Ireland Ltd to carry out stack emissions testing on the A8 - Kiln Exhaust Main Stack (Standby Analyser) Stack at Cookstown Works.

There were no special requirements.

The aim of the monitoring campaign was to perform an AST Calibration Check Exercise on the Continuous Emissions Monitor (CEM), which is installed on the Plant, following the requirements of EN 14181.

Executive Summary (Page 1 of 2)

Calibration Function derived

from QAL2?

Range after AST Extension

@ REF Conditions

Calibration Function that the AST was

performed against (See Conclusion)

Result of Variability

Test

Calibration Range from

Previous QAL2 @ REF

Conditions

All calibration functions relate to mg/m³, unless otherwise stated.

y = 0.9876x + 20.5419

Ammonia Yes y = 1.1299x -1.804

Carbon Monoxide y = 1.064x -3.5405Hydrogen Chloride y = 0.991x -0.4158

Total Particulate Matter y = 0.5384x + 2.3444Total VOCs y = 0.8427x -0.7458

Pass Passy = 0.9708x -0.0951

0 to 21.80 to 16.6Water Vapour (% v/v) Yes y = 0.9708x -0.0951 Pass Pass

Oxygen (% v/v) Yes y = 1.0181x + 0.3301 y = 1.0181x + 0.3301

Pass

PassPass

PassPassPass

PassOxides of Nitrogen (as NO₂) Yes y = 0.9622x + 5.9809 Pass PassSulphur Dioxide Yes

YesYes

YesYes

0 to 60.20 to 12.1

0 to 677.50 to 976.80 to 19.10 to 30.1

Existing Range Still Valid








Existing Range Still Validy = 0.5384x + 2.3444y = 0.8427x -0.7458y = 0.9622x + 5.9809

y = 0.9876x + 20.5419y = 1.064x -3.5405

Pass Passy = 0.991x -0.4158y = 1.1299x -1.804

Pass

PassPass0 to 544.5

The calibration functions, once applied, only remain valid as long as the QAL3 data remains within control limits, and that there are no manual adjustments made to the CEMs other than those allowed to bring the settings back within the QAL3 control limit.





Total Particulate Matter, Total VOCs, Oxides of Nitrogen, Sulphur Dioxide, Carbon Monoxide, Hydrogen Chloride, Ammonia, Water Vapour & Oxygen

15th - 16th May 2018A8 - Kiln Exhaust Main Stack (Standby Analyser)

CONCLUSIONS, DISCUSSIONS & ACTIONS FROM THE SAMPLING EXERCISE

SECTION 1C

Executive Summary (Page 2 of 2)

Lafarge Ireland Ltd, Cookstown Works

The CEM data was corrected using the calibration function derived during the most recent QAL2 campaign. The corrected values passed both the variability and calibration tests as required by EN 14181 and therefore the calibration function is deemed to be valid within the given tolerances. The calibration range derived in the previous QAL2 is still valid.

SUMMARY OF STANDARD REFERENCE METHOD & EN 14181 DEVIATIONS

Parameter Run Deviation

All Parameters All There are no deviations associated with the sampling employed





Regulated Determinands and Emission Limit Values (ELVs)

¹ TGN M20, Version 3

Date CEMs Data Obtained by Exova Catalyst 25th May 2018

Section 2: Information about the Regulated Installation

2020 ¹

Name of the Installation

Value

600

--

30


15th - 16th May 2018

Short-Term ELV (mg/m³)

Daily or 48hr Average ELV (mg/m³)

Date of the Last QAL2 / AST Campaign 1st - 6th November 2017 (Gaseous AST / TPM QAL2)

Cookstown Works

Oxides of Nitrogen (as NO₂) -

--

3035

600

40Hydrogen ChlorideCarbon Monoxide

10- 50

30

Ammonia

-

Determinand

Cement & LimePermit Number P0052/04A/V6

Address of the Installation See Title PageSector of the Installation

REGULATORY INFORMATION

Parameter

800 20

Uncertainty Requirement (%)

Sulphur Dioxide

Total VOCsTotal Particulate Matter

40

¹ TGN M20, Version 3





Process Type and Variations in Emissions

Type of Fuel

Continuous

Yes

No

OPERATIONAL INFORMATION AND SITE MONITORING PROVISIONS

No

Were there any variations in emissions during the EN 14181 test (e.g. Load changes)Will these variations affect the representative nature of the collected data?

A8 - Kiln Exhaust Main Stack (Standby Analyser)15th - 16th May 2018

Are multiple calibration functions required if the emissions vary

Value

Pulverised Coal & Recyled Liquid Fuel Oil

No

Are there any factors that may affect the collected data(e.g. auto-calibrations, plant start up and shut down)

Fuel type used during the EN 14181 test(include proportions for co-incineration)

Was the CEM reading zero for any determinands, if so, was this investigated to ensure it was working?


Continuous or batch process

No

What product was being processed during the tests? Cement

Reviewing historical Plant data, were low emissions expected for any determinands?

No

Parameter


Parameter Value

Abatement

due to different fuel types being used?

ESP

Parameter Value

Running Status On

Type of Abatement System





Duct Characteristics Location of Sampling Platform

Platform Details

Number of Ports - 4.0

cm 9.0Orientation of Duct - Vertical

Safe access available

YesPlatform has vertical base boards (approx. 0.25m high) Yes

Yes

No

Sufficient working area to manipulate probe and operate the measuring instruments

4" BSP

EA Technical Guidance Note M1 / EN 15259 Platform Requirements

YesYes

Platform has 2 levels of handrails (approx. 0.5m & 1.0m high)

Platform has chains / self closing gates at top of ladders

Value

Units Value General Platform Information Value

Type - Circular Permanent / Temporary Platform PermanentDepth m 4.82 Inside / Outside OutsideWidth m -Area m² 18.25Port Depth

-


MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING


Sample Port Size

Access to sample ports unhindered by obstructions

15th - 16th May 2018

Parameter

(Page 1 of 2)

Sampling Location / Platform Improvement Recommendations

EN 15259 Homogeneity Test Requirements

Sampling Plane Validation Criteria (EN 15259)

-

6.0

m/s 5.22 -Highest Gas Velocity

< 15° Yes

- > 5 Pa Yes

--

Yes-

- - - -

Safe access available

Required Compliant

Lowest Differential Pressure Pa 13.5

Maximum Angle of Swirl ° -

No

The sampling location meets all the requirements specified in EA Guidance Note M1 and EN 15259, and therefore there are no improvement recommendations.

According to EN 15259, a Homogeneity Test is required on this stack, however, as far as we are aware, it has not yet been undertaken. Unless agreed otherwise with the respective regulator, we would recommend that the Homogeneity Test be undertaken prior to the next set of emissions testing on this stack, and would be happy to carry out the work. Please contact Exova Catalyst for further details.

Criteria in M1 Units

--

Ratio of Above : 1 1.20

4.85 - -

Yes

- -

Yes

4.34 -

-No Local Negative Flow -

- - -

Lowest Gas Velocity m/s

- -

Traverse 1 - - - -

< 3 : 1

Mean Velocity m/s - - - --

Easy access available Yes

- -





Pro-forma for Site Provisions for Monitoring

Plant Photos

Yes

Compliance with MID 15259


Requirement Notes

Photo 1 Photo 2

A safe and clean working environment with sufficient space and weather protection.

Yes

Easy and safe access to the CEM. Yes

Adequate supplies of reference materials, tools and spare parts.

15th - 16th May 2018

Yes

Compliant

MONITORING PROVISIONS AT THE INSTALLATION - PERIODIC MONITORING


Facilities to introduce the reference materials for gaseous-monitoring systems, both at the inlet of the sampling line (where present), and at the inlet of the CEM.

Yes

(Page 2 of 2)

See the Sampling Plane Validation Criteria table on the previous page.

Sample Points

where = isokinetic point sampled at

= isokinetic point not sampled at

= combustion gases sample point

= non-isokinetic sample point

Line A

Line B

B1

B4

B3

B2

B6

B9

B8

B7

A8A7 A9 A10

A1 A2 A3 A4

B10

B5

A5

A6





Type

ABB CEMAS FTIR-NT

MC 030016

Yes DURAG D-R-230

3.350294.7

3.350294.7

3.350294.7

ExtractiveExtractiveExtractive

YesExtractiveExtractiveExtractive

MC 030016MC 030016Oxygen (Wet)

3.350294.7

Ammonia 0 - 15

Cross-Duct

MC 030016MC 030016

15th - 16th May 2018

Yes

ExtractiveExtractive

ABB CEMAS FTIR-NT

FTIR

0 - 40%Water Vapour 3.350294.7

Total Particulate Matter DURAG D-R-230

Instrument Name

A0 2000 Multi FIDABB CEMAS FTIR-NT

0 - 25%


Extractive 3.350294.7

Nitrogen MonoxideNitrogen DioxideSulphur Dioxide

FID

Measurement Principle

Total VOCs 3.350294.73.350294.7

Optical Light Scattering

Carbon MonoxideHydrogen Chloride

QAL1 Compliant

MC 030015

MC 030016MC 030016

Certified Range (mg/m³)

0 - 7.5 MC 140253

FTIRFTIR

Zirconia

MC 030016

Pressure Yes DURAG D-R-230

ABB CEMAS FTIR-NTABB CEMAS FTIR-NT

Peripheral Determinand Recorded Instrument Name

Temperature

ABB CEMAS FTIR-NT

Main Determinand

0 - 200

Instrument Serial Number

01239225


0 - 15

MCERTS Number

FTIRFTIR

FTIRFTIR


CONTINUOUS EMISSION MONITORs (CEMs) AT THE INSTALLATION

-0 - 750 - 750 - 15

YesYesYesYes

ABB CEMAS FTIR-NTABB CEMAS FTIR-NT

3.350294.7YesYes

YesYes





NOTE 1: Exova Catalyst hold UKAS and MCERTS Accreditation for all Standard Reference Method Tests performed.

NOTE 2: The MU specified in this column is reported as the MU at the Daily ELV (not the MU percentage of concentration measured.)

where: MST stands for Manual Sampling Train

Anthony LovellTechnician

Position Technical EndorsementsMCERTS AccreditationName

Stephen Dick MCERTS Level 2 TE1 TE2 TE3 TE4MCERTS Level 1 MM 16 1397, Expiry: 30/09/2021 None

Gasmet DX4000Total VOCs

0 - 75

Gasmet DX4000Water Vapour 0 -30%

Team Leader

MCERTS Number & Expiry Date

MM 10 1061, Expiry :30/04/2020

Operational (mg/m³)

N/A - SRM0 - 161

0 - 936.9

Instrumental Ranges

Sulphur Dioxide

EN 12619

0 - 75.9 MC 030014 TGN M22 8.1

EN 14789TGN M22FTIR

Paramagnetic CellHoriba PG-350E

0 - 15

MU ²(%)

MC 030014Gasmet DX4000

MST

FTIRFTIR

STANDARD REFERENCE METHODS (SRMs)

Total Particulate Matter

FTIRCarbon Monoxide 0 - 75

EN 13284-1

Ammonia Gasmet DX4000 FTIR N/A

0 - 15

Determinand

8.02.22.41.5

Sick Maihak 3006

Exova Catalyst hold UKAS and MCERTS Accreditation for performing QAL2 and ASTs, to EN 14181.

MCERTS Number

FTIR

0 - 200 MC 030014MC 040036MC 030014

Reference Method

0 - 1159.2TGN M22

Measurement Principle

GravimetricFID

TGN M222.28.9

Oxides of Nitrogen (as NO₂)

0 - 20%0 - 25%

Instrument Name

Certified (mg/m³)

Section 3 - Information about the Monitoring Campaign

TEST LABORATORY STAFF

MC 130223MC 030014

Oxygen (Dry) 0 - 25%

0 - 75

Hydrogen Chloride

TGN M22TGN M22

Gasmet DX4000Gasmet DX4000 MC 030014

MC 0300140 - 624.60 - 16.3

5.43.4

Servomex 4900

Oven Box (1)

Mass View (2)

CAT 13.24Umbilical (2)

Control Box DGM (1)

CAT 4.206Stack Thermocouple (1)

-Digital Temperature Meter CAT 3.34 / 3.54

Heated Probe (2) CAT 5.162 CAT 20.131

5m Heated Line (1)

CAT 12.963 CAT 4.934

Stopwatch

Oven Box (2)

CAT 25.4

Heated Probe (3) CAT 5.11 Ankersmid APP100

Box Thermocouples (2)Umbilical (1) CAT 3.57

Servomex 5200MP -Barometer

-CAT 14.53

Equipment Type Equipment I.D. Equipment Type Equipment I.D. Equipment I.D.Equipment Type

-

-CAT 10.4

Stack Thermocouple (3) CAT 4.995 / 4.0048

Heated Probe (1) CAT 5.4Bernath 3006 FID

CAT 12.721m Heated Line (2)

L-Pitot -

Mass Flow Controller (1)Mass Flow Controller (2) CAT 6.12

CAT 6.111m Heated Line (3) -

CAT 21S.28

Gasmet DX4000 CAT 19.12Stack Thermocouple (2)

Extractive Sampling Instrumental Analysers

Eco Physics CLD 822Mh

CAT 7.38 Horiba PG-350E CAT 39.7 Digital Manometer (1) CAT 3.34Control Box DGM (2)

LIST OF EQUIPMENT

- Horiba PG-250 SRM CAT 9.13 Digital Manometer (2) CAT 3.54

CAT 17.420m Heated Line (1) CAT 20.133

Box Thermocouples (1) CAT 3.57

-ABB AO2020-URAS26

Miscellaneous Items

S-Pitot (1)

CAT 8.4

-

JCT JCC P1 CoolerCAT 4.597

-

1m Heated Line (1) CAT 20.130Gasmet Sampling System

S-Pitot (2) 15m Heated Line (1) -CAT 21P.95 / 105

20m Heated Line (2) -Dual Channel Heater Controller1Kg Check Weight

Last Impinger ArmCallipersTubes Kit Thermocouple

CAT 17.4CAT 4.22 / 4.24 / 4.9993

CAT 23.22CAT 4.217

Easylogger EN-EL-12 Bit -Hioki 5043 (V) CAT 11.94

CAT 3.161Single Channel Heater Controller

500g Check WeightMass View (1) -

-Laboratory Balance CAT 1.18 / 1.18aTape Measure CAT 16.3





Calibration Data

Outliers Data

Reason for Data Pair Removal

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

INPUT

INPUT INPUT 0.00 0.00

5 15/05/2018 14:20 - 15:06 10.56 8.469.34

Time

8

SRM (STP, DRY,

10% O₂) mg/m³

(Page 1 of 3)

7.5612.11

x - xav(A)

y - yav(B)

13.80

12:00 - 12:45

Section 4B - Data and Calculations - AST

TOTAL PARTICULATE MATTER: AST CALCULATIONS

INPUT INPUT 0.00 0.00 INPUT

INPUT

1

-0.75

MAX SRM - MIN SRM

x, CEM (STP, ACTUAL) mg/m³

-0.39

0.00 INPUT

6

43


0.00

0.005INPUTINPUT INPUT 0.00

2.53 2.75(DAILY) DELV (mg/m³)

30

INPUT2 INPUT INPUT

INPUT 0.00 0.00

8.08

9.01 14.15

10.65

-0.12 0.03 8.067 16/05/2018 09:00 - 09:46

10:48 - 11:34

y, SRM (STP, ACTUAL) mg/m³

(A) x (B) (x - xav)² CAL CEM (STP,

ACTUAL) mg/m³

1 15/05/2018 09:35 - 10:20 11.21 9.50 15.27 0.77 0.64 0.49 0.5915/05/2018

0.93 0.56

5.2530

95% CI MU (%)

Pair Date Time

0.59

SUM

0.16 0.09 0.34 8.2811.0317.36 -0.03 2.08 -0.07 0.00 7.95

8.382

15.46

6 15/05/2018 15:25 - 16:11 10.62 8.19 13.19

3 15/05/2018 10.41 10.93


Pair Date

4 15/05/2018 13:15 - 14:02

16/05/2018 10:00 - 10:45

0.12

7.80 12.71

0.21 0.49 0.10 0.04

-1.259.69 7.61-0.66

9.36

-0.05 0.01 8.030.18

-1.08 -1.06 1.14 1.17 7.38

INPUT

x, CEM (ACTUAL)

mg/m³

y, SRM (ACTUAL)

mg/m³

Filter ID Number

(47-XXXX)

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

INPUT

INPUT

8 INPUT INPUT 0.00 0.00

6

10

INPUT0.00 INPUT7

INPUT 0.00 0.000.00

INPUT INPUT 0.00 0.00 INPUTINPUT 0.00

Existing Calibration Function

0.00 INPUT9 INPUT

y = 0.5384x + 2.3444Source of Existing Calibration Function

INPUT INPUT

CEK-2705 Exova Catalyst QAL2

Existing Calibration Range (@ REF Conditions)0 to 30.1 mg/m³





PLOT 1: BAR CHART FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED)

Variability Test Data where CAL = Calibrated using AST calibration functions


Date

TOTAL PARTICULATE MATTER: AST CALCULATIONS (Page 2 of 3)


SRMPressure

COPY CORRECT PLOT 1 BAR CHART

SRMWater

CEMOxygen

CEMOxygen

SRMOxygen


Time CEMTemp

SRMTemp

CEMPressure

PairCAL CAL

CEMWater

CEMWater

0.0

5.0

10.0

15.0

20.0

25.0

30.0

1 2 3 4 5 6 7 8

mg/

m³ (

REF)

Pair

CEM SRM

101.7 101.7

0.0

101.7 101.7

00/01/1900

0 00/01/1900 00:00 0.0 0.0 0.0

101.7

0

0.0

0

91.9

0.0 0.0 0.0

0 00/01/1900

00:000

0.00 0.000

PressurekPa

67 16/05/2018 90.1

96.0 101.7 101.7

1 15/05/2018

94.3

Water Vapour% v/v

Oxygen (DRY)% v/v

Oxygen (DRY)% v/v

Oxygen (DRY)% v/v

15.97 15.41 14.19

0 00/01/1900

10:00 - 10:45

9.989.75 10.26 10.02

95.3

0.00

101.7 101.796.1

00/01/1900

0

9.68 10.19 10.2616.11 15.55 14.59 9.70 10.21

00/01/1900

09:35 - 10:20 93.8

00:00 0.0

90.4 93.7

13.80 0.766 15/05/2018 15:25 - 16:11

101.7

94.3 95.3

8 16/05/2018

0

0.00

0.00

0

00/01/1900

5

2

101.7

15/05/2018 10:48 - 11:34 94.3

Temp°C

0.00 0.00 0.00 0.00

2

-0.228

Filter ID Number

(47-XXXX)

47-4896847-51049

00:00MAX

0.00 0.000.0000.00 0.00

0 0.000:00 0.0

15/05/2018 10:48 - 11:34

12:00 - 12:45

Date Time CAL CEM (ACTUAL)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

000:00 0.00 0.00

15/05/2018

00:0016/05/2018

8.38 13.49 15.27 1.78

13:15 - 14:02 8.08 13.0515/05/2018 14:20 - 15:06

12.11

0.00

15.46 2.42

10:00 - 10:45 7.38 12.19

0.0 0.0

Sd 1.52

0.000 000/01/1900 00:00

09:35 - 10:20

0.00

16/05/2018

00/01/1900

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0

13.49

4

0 00/01/19000 00/01/1900 00:00

0.000.00 0.00 0.00 0.00

8.03 13.04

17.36 4.44

8.06

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

0

Pair

0

712.71 0.52

0.0 0.0

96.6 101.7 101.715/05/2018

15/05/2018 15:25 - 16:11 94.3 96.4 101.7

Temp°C

PressurekPa

13:15 - 14:0215/05/2018 101.7 101.7

4

0.0

13.04 13.19 0.15

00:00 0.0

0.753 15/05/2018 12:00 - 12:45 7.95 12.91

47-5044309:00 - 09:46 12.33

15/05/2018

0.0 0.0 0.000:00

0.0 0.010.40

0.00 0.00 0.00 0.00 0.00 0.00

0.000.00

94.3

00/01/1900

09:00 - 09:46

00:00 0.0 0.0

16.08 15.51 15.18

47-5121547-5096347-5044447-5121647-50449

1

0.00 0.00 0.00 0.00 0.00 0.00

3

7.56

5

8.28 13.40 14.15

0.0 0.0

15/05/2018 14:20 - 15:06

0.00.00.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

Water Vapour% v/v

Water Vapour% v/v

16.09 15.52 16.98 9.68 10.19 10.2216.06 15.49 15.28 9.75 10.26 10.2615.89 15.33 16.14 9.72 10.23 10.0215.50 14.95 15.93 9.98 10.49 10.0615.51 14.96 14.80 10.10 10.61

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00

00/01/1900 00:00





Test of Variability Test of Calibration (Acceptance of Calibration Function)

where N (number of samples) = 8

The variability is accepted if Sd ≤1.5 x Q₀ x Kv The calibration is accepted if D < t0.95 (N-1) x Sd / SQRT (N) + Q₀

PLOT 2: X-Y Plot - REF CAL CEM vs REF SRM Values

Standard Deviation (Sd)

4.59


TOTAL PARTICULATE MATTER: AST CALCULATIONS



1.321.5 x Q₀ x Kv 6.56

Kv for 8 Pairs of Data

t0.95 (N-1)

a) Calibrated Range (10% extension) (mg/m³)

1.52 Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀

Outcome of Variability Test Pass

Q₀ = ELV x (MU / 100) / 1.96

(Page 3 of 3)

Outcome of Calibration Test

0 to 14.8b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 15

New range up to a maximum of 50% of the Daily ELV 0 to 14.8

1.895

5.61Pass

0.9521

Parameter Value Parameter Value

New Calibration Range (REF)

25.0

30.0

35.0 DATE/S: 15/05/2018 to 16/05/2018

COPY APPROPRIATE PLOT 2: X-Y PLOT OF REF CAL CEM vs REF SRM VALUES (choose the graph with or without the AST extension)

-5.0

0.0

5.0

10.0

15.0

20.0

25.0

-5.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0

SRM

mg/

m³ (

REF)

CAL CEM mg/m³ (REF)

TPMCalibration Range





Calibration Data

15/05/2018 -1.66 -2.01

0.00

-0.83 0.43 0.27 7.8519 15/05/2018 -1.10 -1.38 1.52 1.22

(Page 1 of 3)

8.90

11.58 13.78 0.95 9.08

0.04

6 15/05/2018 05:32 - 06:02 11.85

8.26

7.81

4 15/05/2018 03:32 - 04:02 11.84 12.105

13.26 -0.11 0.22 -0.02 0.01 8.19

15/05/2018 08:32 - 09:02

0.00 0.00 0.00 0.00 0.00

15/05/2018

0.37

11.267.42

8.64

2 15/05/2018

9.24


8.123 15/05/2018 02:32 - 03:02 10.60 10.95

6.37

9.90 11.86 -0.52

9.23

18:32 - 19:02

21:32 - 22:02

0.00 0.00

8.9615/05/2018 10:32 - 11:02 11.66

VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS

SRM (STP, DRY,

10% O₂) mg/m³

15 15/05/2018

CAL CEM (STP, WET)

mg/m³

915/05/2018 09:32 - 10:02 11.52 12.15 15.14

1.16 0.89 0.58 8.92

10.88 13.13

8.48

1.72 2.56 2.22

10.48 12.85

11.48 11.89 14.14 0.76

10.49 12.60

0.78 0.33 0.18

8.12

(A) x (B)

14

5.17

7.35

11.96 14.13

18 15/05/2018 17:32 - 18:02

9.548

0.36 0.08

-0.03 -0.25

1.45 1.29

0.00


16 15/05/2018 15:32 - 16:02 10.95 11.08

13:32 - 14:02

13.29

130.01 0.00

1.43 1.15

0 00/01/1900 00:00

-1.85 2.62 2.01

-0.19

0.00 0.00

17 15/05/2018

0.00 0.00

22:32 - 23:020.00

-1.4219:32 - 20:02 9.69 9.32

0.24

10.66 -0.23 0.01

14.83 1.12

12.92 -0.19 0.10 -0.02 0.04

10

10.94 10.70

-0.03

8.88 10.77

0.00

15/05/201815/05/2018 20:32 - 21:02 9.30

0.15

0.65

0.74

11.33 10.85 13.35 0.61 0.13 0.08

x - xav(A)

y - yav(B)

0 00/01/1900 00:00 0.00

11

Pair Date

0.00 0.000.00 0.00

0 00/01/1900 00:00 0.00

16:32 - 17:02

0.81

20 15/05/2018

23

9.61 9.35

10.53

15/05/2018 0.911.49

7.0922 8.44

0.5406:32 - 07:02 12.20

10.719.05

1

1.2711.14

21

8.33-0.05

7 15/05/2018

Time (30-minute Average)

01:32 - 02:02 10.52 10.83

0.00

1.54

12.00


0.43

x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

14.27 1.13 1.28

11.23 -1.02

0.00 0.00 0.000.00 0.00

00:00 0.00

9.61 -2.27 -2.92 6.64

15/05/2018 04:32 - 05:02

-1.40 1.44 1.05

(x - xav)²

07:32 - 08:02 11.45

1.37

0.00 0.00

8.72

0 00/01/1900

12 15/05/2018 11:32 - 12:02

0.00 0.00

15/05/2018 12:32 - 13:02 10.77

15/05/2018 00:32 - 01:02

0.000.00

13.29 0.23 -0.03 -0.01 0.05

1.23

14:32 - 15:02

0.85

10.20

10.69

8.24

3.33 2.75 6.88

8.800.06

11.50 13.74

0.89

10.85 12.89 0.06 0.13 0.01

12.44 14.76

0.81

8.48

Outliers Data


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)

0.00 0.00 0.00 0.00 0.00

Existing Calibration Range (@ REF Conditions)

0.00

8

Existing Calibration Functiony = 0.8427x -0.7458

Source of Existing Calibration Function

0.00 0.00

0 to 19.1 mg/m³

SELECT or TYPE IN

00/01/1900 00:00

0 00/01/1900 00:00

0.00 0.00 0.00

INPUT 0.00 0.00

0.00 0.003 INPUT INPUT

0.00 0.00

0


x, CEM (WET) mg/m³

00:00 0.00

0.00

INPUT INPUT 0.00 0.009 INPUT INPUT 0.00

0.00

5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT

3595% CI MU (%) 30

0.000 00/01/1900

y, SRM (WET) mg/m³

0.00 0.00

1 INPUT2 INPUT INPUT

0.00 0.00

Pair Date


0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00

0.0010 INPUT INPUT 0.00 0.00

0.00MAX SRM - MIN SRM 5.53 SUM 25.72 20.65(DAILY) DELV (mg/m³)

0.00

INPUT 0.00

0.00 0.00





PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)

PLOT 1: GRAPH FOR REFERENCE SRM vs REFERENCE CEM (STANDARDISED) (30 minute rolling averages)

(Page 2 of 3)


COPY PLOT 1: 30/60-MINUTE ROLLING AVERAGE TREND GRAPH INTO HERE

COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE


VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³ (

STP)

Time

VOCs (CEM - 1 min)VOCs (SRM - 1 min)

0.0

5.0

10.0

15.0

20.0

25.0

30.0

35.0

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

VOCs (CEM - 30 min)VOCs (SRM - 30 min)

Variability Test Datawhere CAL = Calibrated using AST calibration functions

MAX0.00 0.00 0.000 00/01/1900

8.48

0.61

9.06 11.23 2.18

00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00

00:00 0.00

14 13:32 - 14:02 8.26

10.74 15.14 4.41

15/05/2018 04:32 - 05:02

08:32 - 09:02 8.92

15/05/2018 9.54

02:32 - 03:02 8.19

1 15/05/2018 00:32 - 01:02 8.12

19 15/05/2018 18:32 - 19:02 7.35

1.9422 15/05/2018 21:32 - 22:02 6.37 8.00 9.61 1.61

9.86

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

14:32 - 15:02

13.78

15.86 15.30 15.54 9.78

19:32 - 20:02 7.42

16.09 15.53 15.77 9.76 10.27 10.1216.05 15.49 15.75

15/05/2018 01:32 - 02:02 8.12 9.90

11.52 14.76

10.29

Date Time (30-minute Average)

CAL CEM (STP, WET)

mg/m³

4 15/05/2018 03:32 - 04:02 9.235

15/05/2018

06:32 - 07:02

7.85

15/05/2018 8.48

2.8110.20 13.29 3.09

17:32 - 18:02

2

11:32 - 12:02 8.24

9.48

3.02

10.1616.25 15.68

16 15/05/2018

9.97

18 15/05/2018

13.26 3.15

Sd

CAL CALCEM

Water Vapour% v/v

CEMWater Vapour% v/v

10.11

10.84

Pair SRMWater Vapour% v/v

CEMOxygen (DRY)% v/v


SRMOxygen (DRY)% v/v

16.21

11.52

17

21 15/05/2018 20:32 - 21:02 7.09 8.83 10.77

15:32 - 16:02

10.00 12.60

15/05/2018 16:32 - 17:02 13.35

15.64 15.93 10.37

8.646 15/05/2018 05:32 - 06:02 9.24

9.97 12.85 2.87

9 15/05/2018

0 00/01/1900

7

2.31

3.07

20 15/05/2018

13.74 3.25

12 15/05/201811 15/05/2018 10:32 - 11:02 9.08 10.89

8.80 10.54

12:32 - 13:02 8.33

15

2.6013 15/05/2018

3.258 15/05/2018 07:32 - 08:02 8.90 10.72 14.13 3.41

23 15/05/2018

10.27 13.29

10.45 10.2116.36 15.79 16.02 9.77

12.89

10.28 10.31

15.83 9.63 10.13 10.02

16.02 15.46 15.72 9.69 10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64

9.62 10.12

9.65

CAL CEM (STP, DRY,

10% O₂) mg/m³

11.25 14.83 3.58

15.98 15.42 15.67 9.72 10.23 10.00

9.96 13.13 3.1712.92 3.03

2.93

10.5011.20 14.27

15.91 9.78

2.89

15.93 15.36 15.63 9.64 10.15

10.0416.16 15.59 15.83 9.94

10.4016.01 15.44 15.61 9.73 10.23 10.13

22:32 - 23:02 6.88

14.14 3.3110 15/05/2018 09:32 - 10:02 8.96

15.90 15.34

00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.0000/01/1900 00:00

3 15/05/2018

0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00

15.60 9.82 10.32 8.95 11.26

10.0116.09 15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.49

10.18 10.70 10.46

0 0.00 0.00 0.00 0.000

8.63 10.7115.77 15.22 15.37 10.14 10.65 10.420.00 0.00 0.00

2.08

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

15.93 15.37 15.65 9.79 10.30 10.0810.29 10.05

10.15 10.5416.17 15.60

15.88 15.32 15.62 9.69 10.19

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

11.8610.17

15.89 15.33 15.57 9.85 10.36 10.1915.84 15.28 15.53 10.06 10.57 10.2715.58 15.03 15.20

10.13

0.00 0.00 0.00

2.38

Time









0.611.5 x Q₀ x Kv 7.89

1.711


Outcome of Calibration Test

Standard Deviation (Sd)

PassOutcome of Variability Test

Mean Difference (D)t0.95 (N-1) x Sd / SQRT (N) + Q₀

Pass

2.885.57

0.9824

Parameter

Q₀ = ELV x (MU / 100) / 1.96 t0.95 (N-1)

Parameter ValueValue

5.36Kv for 23 Pairs of Data


VOLATILE ORGANIC COMPOUNDS: AST CALCULATIONS(Page 3 of 3)


a) Calibrated Range (10% extension) (mg/m³) 0 to 12.7b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 17.5

New range up to a maximum of 50% of the Daily ELV 0 to 12.7


25.0

30.0

35.0

40.0 DATE/S: 15/05/2018 to 15/05/2018


-10.0

-5.0

0.0

5.0

10.0

15.0

20.0

25.0

-5.0 0.0 5.0 10.0 15.0 20.0 25.0 30.0 35.0

SRM

mg/

m³ (

REF)


VOCsCalibration Range





Calibration Data

653.21 0.20 8.35 1.65 0.04 537.57

597.87 583.53100.25

685.46 37.39 32.10 573.3645.59


Pair (A) x (B) (x - xav)² CAL CEM (STP, WET)

mg/m³

00:32 - 01:02

6 15/05/2018 3621.36

10 15/05/2018

549.6754 15/05/2018

56.9515/05/2018 04:32 - 05:02 641.01 622.86 744.09 88.74 80.55 7147.68

3 15/05/2018 02:32 - 03:02

1 15/05/2018

706.9001:32 - 02:02

525.39 506.31

163.08

1091.18

622.76

632.69

511.51

7.85

SRM (STP, DRY,

10% O₂) mg/m³

723.08

-34.45 -31.6715/05/2018

2078.53 581.251879.34

701.17 608.74 513.64

7537.55

556.04

x - xav(A)

y - yav(B)

1200.48 1398.34

4042.94 598.567

550.16 674.04 12.77

2 15/05/2018

Date Time (30-minute Average)

15/05/2018 10:32 - 11:02 527.60

694.29 10.63 16.66

13 15/05/2018 12:32 - 13:0212

453.84

11:32 - 12:02 517.83 510.63 613.13

589.67 574.41

615.86 599.26 712.4605:32 - 06:02

09:32 - 10:02 472.88 473.56 590.06 -79.40 -68.75 5458.41 6303.709 15/05/2018 08:32 - 09:02 521.87 501.74 596.74 -30.40 -40.56

15 15/05/2018 14:32 - 15:02 562.91 558.96

567.33

628.01

634.55 -14.69 -8.15 119.73 215.78 523.25

15/05/2018 15:32 - 16:02 509.78 527.72 -42.49 -14.58

23

20:32 - 21:02 465.46 466.01

0.00

03:32 - 04:02 565.057874.01

0.00 0.00

63.58

177.09 113.04 547.6116

537.59 534.15

00/01/1900

611.17

17 15/05/2018 16:32 - 17:02 555.16 540.65 664.88 2.88 -1.65 -4.76 8.30 540.15

0.00 0.00

512.83 628.39 -26.44 -29.48 779.50 699.18 511.94

1233.24 924.38 508.13460.99

11

15/05/2018 07:32 - 08:02 571.67 550.73 650.53

-86.82 -76.30 6624.17

0.000

540.68 -105.68 -102.04 10783.54 11167.79 435.700 00/01/1900 00:00 0.00 0.00

0.00 0.000

912.36 968.96

22:32 - 23:02 446.60 440.26

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000.00

22 15/05/2018 21:32 - 22:02 646.46

18 15/05/2018 17:32 - 18:02 668.27 654.46 784.56 116.00 112.15 13009.66 13455.66 648.9919 15/05/2018 18:32 - 19:02 583.40 571.61 687.98 31.13 29.31

0.00 0.0000:00 0.00 0.00 0.00

15/05/20188426.69 8871.60

20 15/05/2018 19:32 - 20:02 501.71 496.87 598.71 -50.56 -45.44 2297.41 2556.79 488.7321 15/05/2018

0.00 0.00 0.000.00

-35.99

631.77 777.88 94.19 89.47

513.89 611.40 -24.67 -28.42


OXIDES OF NITROGEN (as NO₂): AST CALCULATIONS(Page 1 of 3)


8

x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

19.39 8.42 163.35 376.15

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

565.67

-26.89 967.88

41.22

619.67 1805.52 496.49

15/05/2018 06:32 - 07:02 552.47 550.66

1186.79 504.23

14 15/05/2018 13:32 - 14:02 525.83

Outliers Data

SELECT or TYPE IN

Existing Calibration Function

0.006

0.00 0.00

INPUT 0.00



SELECT or TYPE INSELECT or TYPE IN

INPUT

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

00/01/1900

0

0.004 INPUT INPUT

20

0.00 0.00 0.00 0.00 0.00 0.00

5 INPUT INPUT 0.00

x, CEM (WET) mg/m³

SELECT or TYPE IN

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0

Source of Existing Calibration Function

INPUT 0.00 0.008 INPUT

0.00 0.0000:00 0.00 0.00 0.00

0.00 0.00 0.00MAX SRM - MIN SRM(DAILY) DELV (mg/m³) 80095% CI MU (%)

0.00

INPUT INPUT 0.00 0.00INPUT INPUT 0.00 0.00

2 INPUT INPUT 0.00 0.003 INPUT INPUT 0.00

243.88 SUM 67311.05 73079.91

0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00

0.007 INPUT

9

Pair Date Time (30-minute Average)

0.00

y, SRM (WET) mg/m³

1 INPUT INPUT

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN10

INPUT 0.00

CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)y = 0.9622x + 5.9809

0.00










ys, SRM -


CAL CEM SRM CAL CAL

CEM CEM SRM CEM CEM SRMPair Date Time CAL CEM

0

100

200

300

400

500

600

700

800

900

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

NOx (CEM - 30 min)NOx (SRM - 30 min)

0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

690.49

0.00 0.00 0.00

15.22 15.37 10.14 10.420.00 0.00 0.00 0.00 0.00 0.000.00 0.000.00

-2.51

023

0.00

10.28

549.67 669.82 674.04 4.22

617.08 596.74

15/05/2018 04:32 - 05:02 622.76

00/01/1900 00:00

725.98 712.46 -13.527 15/05/2018 06:32 - 07:02

0.00

0.00 0.00 0.00

14

03:32 - 04:02

15/05/2018

669.32 650.53

15.03 15.20 10.18 10.70 10.4615.84

698.45

05:32 - 06:02756.23 744.09 -12.13

2 15/05/2018 01:32 - 02:02 573.36

15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83

15.59 15.83

10.0215.96

717.87 706.90

8 15/05/2018 07:32 - 08:02

ys, SRM - CAL CEM

-20.34

0 00/01/1900 00:00 0.00 0.00 0.00 0.000

20

16

0.000

10.65

15.53 10.06

9.78 10.29 10.0515.98

9

5

35.85

1 15/05/2018 00:32 - 01:02 511.51 627.28 611.17

15/05/2018

19 15/05/2018 18:32 - 19:02 567.33

15/05/2018 10:32 - 11:02 513.64 615.86 611.40 -4.46

6 15/05/2018

9.63 10.13 10.02

13 15/05/2018 12:32 - 13:02 523.25

-10.97

-18.79

15.86 15.30 15.54

685.46 -12.993 9.94 10.45 10.21

556.04

16.36 15.79 16.02 9.77 10.28 10.3115.93

10.12626.22 634.55

415.37 15.65 9.79 10.30 10.08

15.42

784.00 784.56 0.56

649.10 653.21 4.10

511.9415.49 15.75

00/01/1900 00:00

15/05/2018 13:32 - 14:02

9.95

16.09 15.53 15.77

15.46

546.40 540.68 -5.7222:32 - 23:02 435.700.00

0.00

0.00 0.00 0.000 00/01/1900 00:00

08:32 - 09:02 508.13552.47 590.06 37.60

11

15.67 9.72 10.23 10.0016.02

537.57

15/05/2018

12 15/05/2018 11:32 - 12:02 504.23

15/05/2018 02:32 - 03:02 581.25

10 15/05/2018

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

612.03 613.13 1.10

16.21 15.64 15.93 9.86 10.37 10.1616.25 15.68 15.91 9.78 10.29 10.0416.16

15.72 9.69 10.1916.06 15.50 15.75 9.77

09:32 - 10:02 460.99

598.56

540.15 647.00 664.88 17.8818 15/05/2018 17:32 - 18:02 648.99



SRMWater Vapour% v/v




10.15 10.4016.01 15.44 15.61 9.73 10.23 10.13

-16.11


CAL CEM (STP, WET)

mg/m³

16.05 9.62 10.12

15 15/05/2018 14:32 - 15:02 547.61 663.22 694.29 31.07

9.76 10.2710.01

16.098.32

16.52

15.90 15.34 15.60 9.82 10.32 10.17

15.28

617.91 628.39

15:32 - 16:02 496.49 596.84

19:32 - 20:02 488.73 596.55 598.71 2.1521 15/05/2018 20:32 - 21:02 453.84 565.17 565.67 0.5022 15/05/2018 21:32 - 22:02 628.01 789.14 777.88 -11.26

17 15/05/2018 16:32 - 17:02

15/05/2018

687.9815.89 15.33 15.57 9.85 10.36 10.19

0.00 0.00

10.57 10.2715.58

00/01/1900 00:00 0.00

0.00 0.00 0.00 0.00

0.0015.77

15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.1315.93 15.36 15.63 9.64

15/05/2018

0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00

0.00 0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00

0.00 0.000.00 0.00

0.00 0.00 0.00 0.00 0.00MAX 789.14 Sd

632.69

10.48









Kv for 23 Pairs of Data1.711

0.9824





Standard Deviation (Sd) 16.52 Mean Difference (D) 1.091.5 x Q₀ x Kv 120.29 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 87.53Outcome of Variability Test Pass Outcome of Calibration Test Pass


Q₀ = ELV x (MU / 100) / 1.96 81.63

a) Calibrated Range (10% extension) (mg/m³) 0 to 868b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 400

New range up to a maximum of 50% of the Daily ELV 0 to 400


t0.95 (N-1)

1000

1200 DATE/S: 15/05/2018 to 15/05/2018


-200

0

200

400

600

800

0 200 400 600 800 1000 1200

SRM

mg/

m³ (

REF)


NOxCalibration Range





Calibration Data

0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00

17 15/05/2018 16:32 - 17:02 350.70 354.13 435.50 58.42 62.06 3625.54 3413.40 366.8918 15/05/2018 17:32 - 18:02 290.07 289.06 346.53 -2.20 -3.01 6.62 4.84 307.0219 15/05/2018 18:32 - 19:02 229.08 220.91 265.88 -63.19 -71.16 4496.59 3992.76 246.79

189.71 181.96 220.88 -102.57 -110.11 11293.35 10519.84 207.90

23 15/05/2018 22:32 - 23:02 187.25 177.87 218.44 -105.02 -114.20 11993.55 11029.64 205.470 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00

14 15/05/2018 13:32 - 14:02 289.21 289.63 354.90 -3.07 -2.44 7.47 9.41 306.1615 15/05/2018 14:32 - 15:02 308.49 310.26 385.37 16.22 18.19 295.02 263.16 325.2116 15/05/2018 15:32 - 16:02 327.20 330.17 395.84 34.93 38.10 1330.72 1219.85 343.68

11 15/05/2018 10:32 - 11:02 326.37 324.61 386.20 34.10 32.54 1109.42 1162.66 342.8612 15/05/2018 11:32 - 12:02 300.91 303.51 364.44 8.64 11.44 98.84 74.66 317.7213 15/05/2018 12:32 - 13:02 305.43 308.42 366.39 13.16 16.35 215.14 173.11 322.18

8 15/05/2018 07:32 - 08:02 333.53 335.15 395.89 41.26 43.08 1777.75 1702.60 349.949 15/05/2018 08:32 - 09:02 328.72 329.83 392.28 36.45 37.76 1376.16 1328.43 345.19

10 15/05/2018 09:32 - 10:02 335.86 337.01 419.92 43.59 44.94 1958.77 1899.84 352.24

326.85 400.44 35.07 34.77 1219.46 1229.71 343.825 15/05/2018 04:32 - 05:02 323.81 331.49 396.01 31.53 39.42 1242.93 994.37 340.336 15/05/2018 05:32 - 06:02 311.17 317.29 377.23 18.89 25.22 476.57 356.96 327.857 15/05/2018 06:32 - 07:02 332.46 334.33 396.59 40.18 42.26 1698.04 1614.75 348.88

(A) x (B) (x - xav)² CAL CEM (STP, WET)

mg/m³

1 15/05/2018 00:32 - 01:02 307.81 306.99 370.57 15.54 14.92 231.91 241.55 324.54

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

y - yav(B)

550.89 409.12 329.173 15/05/2018 02:32 - 03:02 323.97 325.47 394.29 31.70 33.40 1058.77 1004.61 340.494 15/05/2018 03:32 - 04:02 327.34


SULPHUR DIOXIDE: AST CALCULATIONS(Page 1 of 3)



x, CEM (STP, WET)

mg/m³

20 15/05/2018 19:32 - 20:02 205.71 197.46 237.93 -86.56 -94.61 8190.06 7493.36 223.7021 15/05/2018 20:32 - 21:0222 15/05/2018 21:32 - 22:02 174.97 165.91 204.29 -117.30 -126.16 14798.07 13759.25 193.34

2 15/05/2018 01:32 - 02:02 312.50 319.31 381.04 20.23 27.24

Outliers Data

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN


SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.003 INPUT

SUM 69051.65 63897.87(DAILY) DELV (mg/m³) 60095% CI MU (%) 20

2 INPUT INPUT


0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00


x, CEM (WET) mg/m³

y, SRM (WET) mg/m³

1 INPUT INPUT 0.00

INPUT 0.00 0.00


0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

MAX SRM - MIN SRM 231.21

0.00

0 00/01/1900 00:00


5 INPUT INPUT 0.00 0.006 INPUT INPUT 0.00 0.007 INPUT INPUT 0.00 0.008

INPUT INPUT 0.00 0.0010 INPUT INPUT 0.00 0.00

Existing Calibration Function Source of Existing Calibration Functiony = 0.9876x + 20.5419 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)

SELECT or TYPE IN








Pair Date Time CAL CEM CAL CEM SRM CAL

ys, SRM - CAL

CEM CEM SRM CEM CEM SRM




0

50

100

150

200

250

300

350

400

450

500

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

SO₂ (CEM - 30 min)SO₂ (SRM - 30 min)

0.00 0.00

207.90 258.89 220.88 -38.0222 15/05/2018 21:32 - 22:02 193.34

257.67 218.44 -39.240 00/01/1900 00:00 0.00

20 15/05/2018 19:32 - 20:02 223.70 273.05 237.93 -35.1221 15/05/2018 20:32 - 21:02

00/01/1900 00:00 0.00

15.89 15.33

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

10.70 10.4615.77 15.22 15.37 10.14 10.65 10.42

0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00

17 15/05/2018 16:32 - 17:02 366.89 439.47 435.50 -3.9718 15/05/2018 17:32 - 18:02 307.02

15.58 15.03 15.20 10.18

00/01/1900 00:00 0.00 0.00 0.00 0.00

23 15/05/2018 22:32 - 23:02 205.47

0 00/01/1900

370.88 346.53 -24.3619 15/05/2018 18:32 - 19:02 246.79 300.36 265.88 -34.48

15.93 15.36 15.63 9.64 10.15 10.4016.01 15.44 15.61 9.73 10.23 10.1315.90 15.34 15.60 9.82 10.32 10.17

0 00/01/1900

12 15/05/2018 11:32 - 12:02 317.72 385.65 364.44 -21.2113 15/05/2018 12:32 - 13:02 322.18 385.59 366.39 -19.20

16.09 15.53 15.77 9.76 10.27 10.1216.05 15.49 15.75 9.62 10.12 10.01

-17.30

16.09 15.53 15.75 9.71 10.21 10.3416.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.13

09:32 - 10:02 352.24 422.14 419.92 -2.2111 15/05/2018 10:32 - 11:02 342.86 411.10 386.20 -24.89

16.02 9.77 10.28 10.3115.93 15.37 15.65 9.79 10.30 10.0815.86 15.30 15.54 9.78 10.29 10.05

2 15/05/2018 01:32 - 02:02 329.17 400.98 381.04 -19.94


CAL CEM (STP, WET)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

398.00 370.57 -27.42

15.98 15.42 15.67 9.72 10.23 10.00

413.27 396.01 -17.266 15/05/2018 05:32 - 06:02 327.85 397.64 377.23 -20.41







16.21 15.64 15.93 9.86 10.37 10.1616.25 15.68 15.91 9.78 10.29 10.0416.16 15.59 15.83 9.94 10.45 10.2116.36 15.79

1 15/05/2018 00:32 - 01:02 324.54

3 15/05/2018 02:32 - 03:02 340.49 420.53 394.29 -26.244 15/05/2018 03:32 - 04:02 343.82 418.98 400.44 -18.535 15/05/2018 04:32 - 05:02 340.33

242.95 204.29 -38.67

8 15/05/2018 07:32 - 08:02 349.94

15/05/2018

14 15/05/2018 13:32 - 14:02 306.16 369.54 354.90 -14.6315 15/05/2018 14:32 - 15:02 325.21 393.87 385.37 -8.5016 15/05/2018 15:32 - 16:02 343.68 413.14 395.84

421.23 395.89 -25.349 15/05/2018 08:32 - 09:02 345.19 419.20 392.28 -26.93

10

7 15/05/2018 06:32 - 07:02 348.88 421.26 396.59 -24.67

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00

0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

00:00 0.00 0.00 0.00 0.000

0.000.00 0.00 0.00

000:00 0.00 0.00 0.00 0.00

0.00 0.00 0.00MAX 439.47 Sd 10.15

16.02 15.46 15.72 9.69 10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83 9.63 10.13 10.02

15.57 9.85 10.36 10.1915.84 15.28 15.53 10.06 10.57 10.27












Outcome of Variability Test Pass Outcome of Calibration Test Pass


Value Parameter ValueStandard Deviation (Sd) 10.15 Mean Difference (D) 22.981.5 x Q₀ x Kv 90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 64.85

Q₀ = ELV x (MU / 100) / 1.96 61.22 t0.95 (N-1) 1.711Kv for 23 Pairs of Data 0.9824

Parameter

a) Calibrated Range (10% extension) (mg/m³) 0 to 483.4b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300



700

800 DATE/S: 15/05/2018 to 15/05/2018


-100

0

100

200

300

400

500

600

0 100 200 300 400 500 600 700 800

SRM

mg/

m³ (

REF)


SO₂Calibration Range





Calibration Data

21 15/05/2018 20:32 - 21:02 284.76 280.59 340.60 -54.90 -46.25 2539.32 3014.43 299.4422 15/05/2018 21:32 - 22:02 280.92 274.96 338.55 -58.74 -51.88 3047.87

359.0215 15/05/2018 14:32 - 15:02 347.08 333.22 413.90 7.42 6.38 47.35 55.09

0.00 0.00 0.00

0 00/01/1900 00:00

305.4300:00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

23 15/05/2018 22:32 - 23:02 2144.90 2428.273450.89 295.35

0.00 0.00

15/05/2018 13:32 - 14:02 340.76 328.32 402.31 1.10 1.47 1.61 1.20365.75

16 15/05/2018 15:32 - 16:02 354.32 339.65 407.21 14.66 12.81 187.75 214.94 373.46

286.04 344.67 -46.23 -40.80 1886.56 2137.67 308.66

18 15/05/2018 17:32 - 18:02 316.58 305.34 366.04 -23.08 -21.50 496.25 532.73 333.3019 15/05/2018 18:32 - 19:02 301.14 292.09 351.55 -38.52 -34.7520 15/05/2018 19:32 - 20:02 293.42

316.88

17 15/05/2018 16:32 - 17:02 353.77 372.88

0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.000

0.00 0.00

15/05/2018 10:32 - 11:02 352.98 338.40 402.61 13.32 11.55 153.85 177.33 372.0312 15/05/2018 11:32 - 12:02 339.61 326.19 391.67 -0.05 -0.65 0.03 0.00 357.8013 15/05/2018 12:32 - 13:02 346.01 331.98 394.38 6.35 5.14 32.64 40.33 364.61

0.00 0.000.00 0.00 0.00 0.00

0 00/01/1900

0 00/01/1900 00:00

14.71 18.44 362.4311


x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

y - yav(B)


mg/m³

360.75 346.75 420.06 21.09 19.91 419.77 444.68 380.29

1 15/05/2018 00:32 - 01:02 366.94 348.94 421.21 27.28 22.10 602.96 744.41 386.892 15/05/2018 01:32 - 02:02 363.00 346.00 412.89 23.34 19.15 447.03 544.76 382.69


CARBON MONOXIDE: AST CALCULATIONS

15/05/2018 06:32 - 07:02 355.50 339.76 403.03 15.84 12.91 204.50

367.64 349.81 417.90 27.98 22.97 642.59 782.86 387.63

250.80 374.718 15/05/2018 07:32 - 08:02 356.32 341.08 402.89 16.66 14.24 237.16 277.51 375.589 15/05/2018 08:32 - 09:02 351.75 338.15 402.18 12.09 11.31 136.70 146.11 370.72

10

14

15/05/2018 09:32 - 10:02 343.95 330.27 411.53 4.29 3.43

338.92 416.79 14.11 12.07 170.41 199.23

00/01/1900 0.00 0.00

1338.48 1483.56

4 15/05/2018 03:32 - 04:02 383.01 372.30 456.13 43.35 45.46 1970.67 1879.49 403.995 15/05/2018 04:32 - 05:026 15/05/2018 05:32 - 06:02 361.59 345.32 410.55 21.93 405.15 480.83 381.19

3 15/05/2018 02:32 - 03:02

(Page 1 of 3)


718.48

00:00 0.00 0.00

290.38 283.32 347.94 -49.28 -43.53

Outliers Data

0.00 0.00 0.00 0.00


x, CEM (WET) mg/m³

y, SRM (WET) mg/m³


0.00 0.00


19305.57



(DAILY) DELV (mg/m³)

0.00 0.000.00 0.00


60095% CI MU (%) 20


Existing Calibration Function Source of Existing Calibration Functiony = 1.064x -3.5405 CEK-2320 Exova Catalyst QAL2 Report (Standby Analyser)

7 INPUT INPUT6 INPUT INPUT 0.00 0.00

0.00

0 00/01/1900 0.00 0.00 0.000 00/01/1900 00:000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.008 INPUT INPUT 0.00 0.00

SELECT or TYPE ININPUT INPUT 0.00 0.009

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

3

00:00

MAX SRM - MIN SRM 117.59 SUM 17128.26

0.00 0.00 0.00 0.00 0.00 0.000.00 0.000 00/01/1900 00:00

Existing Calibration Range (@ REF Conditions)

0.00 0.00 0.00

0 to 544.5 mg/m³

4 INPUT INPUT 0.00 0.005 INPUT INPUT 0.00





PLOT 1a: GRAPH FOR STP SRM vs STP CEM (NON-STANDARDISED) (1 minute readings)


COPY PLOT 1a: 1 MINUTE TREND GRAPH INTO HERE



CARBON MONOXIDE: AST CALCULATIONS(Page 2 of 3)


0

100

200

300

400

500

600

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³ (

STP)

Time

CO (CEM - 30 min)CO (SRM - 30 min)

0

100

200

300

400

500

00:0

0

01:0

0

02:0

0

03:0

0

04:0

0

05:0

0

06:0

0

07:0

0

08:0

0

09:0

0

10:0

0

11:0

0

12:0

0

13:0

0

14:0

0

15:0

0

16:0

0

17:0

0

18:0

0

19:0

0

20:0

0

21:0

0

22:0

0

23:0

0

mg/

m³

Time

CO (CEM - 30 min)CO (SRM - 30 min)


0.00 0.00 0.00

15.44 15.61 9.73 10.23 10.1315.90 15.34 15.60 9.82 10.32 10.1715.89 15.33 15.57 9.85 10.36 10.19 -32.10

00:00

Sd 9.210 00/01/1900 00:00 0.00 0.00 0.00 0.00

20 15/05/2018 19:32 - 20:02 308.66 376.76

-32.5823 15/05/2018 22:32 - 23:02 305.43 383.03

17 15/05/2018 16:32 - 17:02

21 15/05/2018 20:32 - 21:02 299.44 372.89 340.60 -32.29

0 00/01/1900 00:00 0.000

00:00

16.06 15.50 15.74 9.75 10.25 10.4915.88 15.32 15.62 9.69 10.19 10.1315.93 15.36 15.63 9.64 10.15 10.4016.01 402.63 366.04 -36.59

19 15/05/2018

0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

15.77

0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00

22 15/05/2018 21:32 - 22:02 295.35 371.13 338.55

15/05/2018 05:32 - 06:02

18:32 - 19:02 316.88 385.66 351.55 -34.11

362.43 434.35 411.53 -22.8211 15/05/2018 10:32 - 11:02 372.03 446.06 402.61 -43.4512 15/05/2018 11:32 - 12:02 357.80 434.30 391.67 -42.6313 15/05/2018 12:32 - 13:02 364.61

-36.16

15.91 9.78 10.29 10.04

15/05/2018 15:32 - 16:02 373.46 448.93 407.21 -41.72

436.37 394.38 -41.99

10 15/05/2018 09:32 - 10:02

9.77 10.28 10.3115.93 15.37

-29.8518 15/05/2018 17:32 - 18:02 333.30

14

9.69

-29.0716

374.71 452.45 403.03 -49.42

16.16 15.5915.79 16.02

15.83 9.94 10.45 10.2116.36





2 15/05/2018380.29 469.68 420.06 -49.62

4 15/05/2018 03:32 - 04:02

01:32 - 02:02 382.69 466.18 412.89 -53.2910.16

16.25 15.68


CAL CEM (STP, WET)

mg/m³

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM

CAL CALCEM

Water Vapour% v/v


15.65 9.79 10.30 10.08

8

15/05/2018

15/05/2018 07:32 - 08:02 375.58 452.10 402.89 -49.209 15/05/2018 08:32 - 09:02 370.72 450.21 402.18 -48.03

1 15/05/2018 00:32 - 01:02 386.89 474.46 421.21 -53.24

13:32 - 14:02 359.02 433.34 402.31 -31.04

10.19 9.9516.06 15.50 15.75 9.77 10.28 10.0215.96 15.39 15.64 9.65 10.15 10.5416.17 15.60 15.83 9.63 10.13 10.0216.09 15.53 15.77 9.76 10.27 10.12

403.99 492.29 456.13470.70 417.90 -52.80

6

10.37

3 15/05/2018 02:32 - 03:02

347.94 -35.090 00/01/1900 00:00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00

00/01/1900

15.22 15.37 10.14 10.65 10.420.00

0.00

0 00/01/1900

381.19 462.33 410.55 -51.787 15/05/2018 06:32 - 07:02

0.00 0.00 0.00

344.67

442.97 413.90

15.86 15.30 15.54 9.78 10.29 10.0515.98 15.42 15.67 9.72 10.23 10.0016.02 15.46 15.72

5 15/05/2018 04:32 - 05:02 387.63

16.21 15.64 15.93 9.86

16.05 15.49 15.75 9.62 10.12 10.0116.09 15.53 15.75 9.71 10.21 10.34

15.84 15.28 15.53 10.06 10.57 10.2715.58 15.03 15.20 10.18 10.70 10.46

0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.000.00 0.00

0.00 0.00 0.00

0.00 0.00

0.00

15 15/05/2018 14:32 - 15:02 365.75

372.88 446.64 416.79

0.000.000.00 0.00 0.00 0.00 0.00 0.00

MAX 492.29

Time









0 to 300



a) Calibrated Range (10% extension) (mg/m³)

Pass Outcome of Calibration Test

0 to 541.5b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 300

New range up to a maximum of 50% of the Daily ELV

CARBON MONOXIDE: AST CALCULATIONS(Page 3 of 3)


Q₀ = ELV x (MU / 100) / 1.96 61.22 1.711Kv for 23 Pairs of Data 0.9824

Standard Deviation (Sd) 9.21 Mean Difference (D) 40.391.5 x Q₀ x Kv 90.22 t0.95 (N-1) x Sd / SQRT (N) + Q₀ 64.51Outcome of Variability Test Pass


t0.95 (N-1)


600

700

800 DATE/S: 15/05/2018 to 15/05/2018


-100

0

100

200

300

400

500

600

-100 0 100 200 300 400 500 600 700

SRM

mg/

m³ (

REF)


COCalibration Range





Calibration Data

0.00

(x - xav)² CAL CEM (STP, WET)

mg/m³

8.54

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000.00

0.00 0.00

0

00/01/1900 00:00 0.00 0.00

0.00 0.00

0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

0 00/01/1900

0.00

00/01/1900 00:00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00

00:00 0.00 0.00 0.00 0.00

0.000.00 0.00

0 00/01/1900 00:00 0.00 0.00

0.000.00

0.00 0.00 0.000.00

0 00/01/1900 00:00

0.00

0

5 15/05/2018 04:32 - 05:02

0.53 8.28

0.70 6.72

0.000 00/01/1900 00:00

1 15/05/2018 00:32 - 01:02 8.07 6.13 7.40 0.02 -0.70 -0.02

0.00 0.00 0.00

0.00

0.00

0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00

0.000

0 00/01/1900

0.99

-0.29

0.98

0.00

00/01/1900 00:00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.000.00

2 15/05/2018

0.00

0 00/01/1900 00:00 0.00 0.00 0.00

0.34 6.9802:32 - 03:02 8.77 7.37 8.93 0.73 0.54 0.39

0.00 0.00 0.00

0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00

03:32 - 04:02 7.46 7.33

8.19 -0.84 0.06 -0.05

0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0.00 0.00 0.00

0.00

y - yav(B)

(A) x (B)

4 15/05/2018

0.00 0.00 0.000

15/05/2018 05:32 - 06:02 7.20 6.89

8.98


HYDROGEN CHLORIDE: AST CALCULATIONS(Page 1 of 3)


3 15/05/2018



x, CEM (STP, WET)

mg/m³

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

x - xav(A)

-0.58 0.49

01:32 - 02:02 9.04 5.96 7.117.58

7.72 7.32 8.74 -0.32 0.48 -0.16 0.10 7.236

0.00

0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

0.00 0.00 0.000.00 0.00

0.00 0.00 0.00 0.00

-0.87 -0.87

0.00

0 00/01/1900 00:00

Outliers Data

0.0000:00 0.00 0.00 0.00


0.00 0.00 0.00 0.00 0.00

40

Pair Date

2

0.00

INPUT

INPUT 0.00

INPUT

0.00 0.00 0.00 0.00

INPUT

0.00

INPUT

INPUT

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN


0.00 0.00

0.00 0.003 INPUT INPUT 0.00

8 INPUT INPUT 0.00 0.009 0.00 0.00


0.00 0.00 0.00


5

0.000 00/01/1900 00:00 0.00 0.00 0.00

SELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE INSELECT or TYPE IN

6 INPUT INPUT


0.0000/01/1900


SELECT or TYPE IN

MAX SRM - MIN SRM 1.86 SUM -0.98 2.67(DAILY) DELV (mg/m³) 1095% CI MU (%)

0 00/01/1900

SELECT or TYPE IN

00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.000.00

0 0.00 0.000

00/01/190000:00

0.004 INPUT INPUT 0.00 0.00


x, CEM (WET) mg/m³

y, SRM (WET) mg/m³

1








CAL CEM SRM ys, SRM - Pair Date Time



CAL CALCAL CEM


CEM CEM SRM CEM CEM SRM

0.0

2.0

4.0

6.0

8.0

10.0

12.0

14.0

16.0

18.0

20.0

00:0

0

00:3

0

01:0

0

01:3

0

02:0

0

02:3

0

03:0

0

03:3

0

04:0

0

04:3

0

05:0

0

05:3

0

mg/

m³

Time

HCl (CEM - 30 min)HCl (SRM - 30 min)

0.00 0.00 0.00

0.00

00:00 0.000.00 0.000.00 0.00

15/05/2018 00:32 - 01:02 7.58

16.36 15.7910.22 8.93

0.00

00:00

00:00 0.00

00/01/19000.00

0 00/01/1900

0.00

00/01/1900

00/01/1900 00:00 0.00

0.00 0.00 0.000 00/01/1900

00/01/1900 00:00 0.00 0.00 0.00

0.00

0.000.00

0.00 0.000 00/01/1900 00:00 0.00

0

00:00 0.00

0.00 0.0000/01/1900 00:00 0.00

0

0 00/01/1900

0.00

0.00

0.00 0.00

0.00

00.00

0.00

0.00 0.00 0.00 0.00

-1.294 15/05/2018 03:32 - 04:02 6.98 8.50 8.98

15.86

0.00

00:00

00:00

00/01/1900

CAL CEM (STP, DRY,

10% O₂) mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

ys, SRM - CAL CEM


0.00

0.00 0.00 0.00 0.00 0.00 0.000.00

10.40 7.11 -3.293

00.00 0.00 0.00

0

15/05/2018 02:32 - 03:02 8.28

15.93 15.37 15.65 9.79 10.30 10.08

10.1615.64

0.00 0.00 0.00

1 15.93 9.86 10.37

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0.00 0.00

15.30 15.54 9.78

CAL CEM (STP, WET)

mg/m³

9.29

MAX 10.40 Sd 1.43

00:00 0.00

16.25 15.68 15.91 9.78

0.00 0.00 0.00 0.00 0.00 0.00

6 15/05/2018 05:32 - 06:02 6.72 8.15

7.40 -1.892 15/05/2018 01:32 - 02:02 8.54

0 00/01/1900 00:00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

10.0416.16 15.59 15.83 9.94 10.45 10.21

16.02 9.77 10.28 10.31

0.00 0.00 0.00

8.19 0.04

0.47

0

00/01/1900 00:00 0.00

0.000 00/01/1900

0

5

00/01/1900 00:00 0.00 0.00 0.00 0.00

15/05/2018 04:32 - 05:02 7.23 8.78 8.74 -0.05

0 00/01/1900 0.0000:00 0.00 0.00 0.00

0

0 00/01/1900 0.00

00:00 0.00 0.00

0.000 00/01/1900 00:00 0.00 0.00 0.00

0.00 0.00

10.29

0.00 0.0000/01/1900 00:00

0 00/01/1900 00:00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.00

0 00/01/1900 00:00 0.00 0.00 0.00 0.000 00/01/1900 00:00 0.00 0.00 0.00 0.000 00:0000/01/1900 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00

0.00

10.29 10.05

0.00 0.000

0.00 0.00 0.00

0.00 0.00 0.00 0.00

0.00

0.00 0.00







16.21

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.00

0.00 0.00 0.00 0.00 0.00 0.00

0.00

0.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00 0.00 0.00 0.000.00 0.00 0.00









Value Parameter ValueStandard Deviation (Sd) 1.43 Mean Difference (D)

t0.95 (N-1) x Sd / SQRT (N) + Q₀2.86

2.015Kv for 6 Pairs of Data 0.9329

Parameter

Q₀ = ELV x (MU / 100) / 1.96 2.04 t0.95 (N-1)

Outcome of Calibration Test Pass


1.001.5 x Q₀ x Kv 3.22Outcome of Variability Test Pass




a) Calibrated Range (10% extension) (mg/m³) 0 to 11.4b) Calibrated Range (50% of Daily ELV) (mg/m³) 0 to 5



12.0

14.0

16.0 DATE/S: 15/05/2018 to 15/05/2018


-4.0

-2.0

0.0

2.0

4.0

6.0

8.0

10.0

12.0

-2.0 0.0 2.0 4.0 6.0 8.0 10.0 12.0 14.0 16.0

SRM

mg/

m³ (

REF)


HClCalibration Range





Calibration Data

32.71

0.00

-3.17

15:32 - 16:02 29.03 28.11 33.70 -1.61 -1.98 3.19 2.59 30.99

0.08

15/05/2018 07:32 - 08:02 32.89

00/01/1900 00:00

34.14

0.00 0.00 0.00 0.00 0.00

29.50 30.31 36.04 -1.14 0.22 -0.25 1.30 31.52

00/01/1900 00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900

15/05/2018 03:32 - 04:02 30.55 31.16 38.18 -0.09 1.07 0.01

15/05/2018 05:32 - 06:02

33.1213 15/05/2018 12:32 - 13:02 31.82 30.72 36.50

69.06 8.72 36.15

09:32 - 10:02 32.2533.97 32.86 39.10 3.34 2.77 9.24 11.13 36.58

12 15/05/2018

31.90

0.00 0.00 0.00 0.00

0.00

-0.57 -1.05 0.32

36.47 -1.06 -0.40 0.4215/05/2018 22:32 - 23:02 29.57 29.69

0.0000/01/1900 00:00 0.00

00:00

1415

15/05/2018 18:32 - 19:02

1.13 31.610

15/05/2018

0.000.00 0.00

39.62 2.29

0 0.00

25.90

1.81 4.09 5.08

2.76 3.66

22 15/05/2018 21:32 - 22:02 25.47

1.80 4.13 5.23 35.40

01:32 - 02:02 25.84

(Page 1 of 3)


Pair Date

15/05/2018 00:32 - 01:02 28.68 28.24 34.0916.24 14.58

y, SRM (STP, WET)

mg/m³

SRM (STP, DRY,

10% O₂) mg/m³

15/05/2018

30.07 29.05 34.96 0.60

-4.19 21.65 26.64 26.9823

17

7 15/05/2018 06:32 - 07:02 33.59

0

18 15/05/2018 17:32 - 18:02 30.19 29.37

31.89 -5.16

0.00 0.000.00

34.4221 15/05/2018 20:32 - 21:02 31.51 31.10 37.75 0.87 1.00 0.88 0.76 33.80

33.16

0.74

38.04 1.43 1.48 2.11 2.03

10 15/05/2018

15/05/2018 13:32 - 14:02 32.55

1.61 0.61 0.98 2.60

15/05/2018

2.25

5

11 15/05/2018 10:32 - 11:02

31.91

11:32 - 12:02 30.91

14:32 - 15:02 32.92

30.43 36.54 0.28

32.3119

31.53

8 37.69 35.369 15/05/2018 08:32 - 09:02 33.83

16


AMMONIA: AST CALCULATIONS

29.23

6.62

26.823.81 30.61

4 -0.0933.70 -3.52 -1.88 12.39 28.8315/05/2018

3.61

3 15/05/2018 02:32 - 03:02 27.4728.50

x - xav(A)

y - yav(B)


mg/m³

130.83 -3.82 -4.252 15/05/2018


x, CEM (STP, WET)

mg/m³

6.75 10.02

20 15/05/2018 19:32 - 20:02 32.06 31.57

16:32 - 17:02 31.86 30.92 38.02 1.22 0.82 1.00 1.49

34.97

34.19

39.34 2.95 3.07

0.00 0.00

36.42

27.96 33.87

28.21

-1.95 -1.85

0.00

0.34

0.32 0.20

4.46 10.2231.49 37.45 3.20 1.40

35.21 -0.45 -0.73

30.70 38.26

1.91 1.44

-2.13

1.18 0.63

34.63

1.3938.64

0.09

32.17

04:32 - 05:02 27.12

0.00

Daily

Outliers Data

INPUT INPUT 0.00


INPUT 0.00 0.00

00:00 0.00

98.60

00/01/1900 00:00

0.003 INPUT

0.00 0.00

00/01/19000.00 0.00 0.00 0.00

INPUT

00:00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.000 00/01/1900

0.00

8 INPUTINPUT

1




0.00

9 INPUT 0.00 0.0010 INPUT INPUT 0.00 0.00

0.00INPUT 0.00

0

SELECT or TYPE IN

0

00/01/1900

0.00 0.000.00

0.00 0.00 0.00 0.00

0

00:00 0.00

7 INPUT6 INPUT INPUT 0.00 0.00

4 INPUT INPUT5 INPUT INPUT 0.00 0.00

INPUT 0.00 0.00

125.39ELV (mg/m³) 5095% CI MU (%) 40



0.00 0.00 0.00 0.00 0.00

x, CEM (WET) mg/m³

y, SRM (WET) mg/m³

0.00 0.00


SELECT or TYPE IN


MAX SRM - MIN SRM 8.78 SUM

0.00 0.000.00 0.00

2INPUT






Variability Test Datawhere CAL = Calibrated using AST calibration functionsCAL


(Page 2 of 3)

Time CAL CEM CAL

CEM CEM

AMMONIA: AST CALCULATIONS

Pair Date

Section 4B - Data and Calculat

cover meappsd.daera-ni.gov.uk/ipri/docs/p0052-04a lafarge ireland... · 2019. 4. 2. · monitoring...

Documents