chemistry innovation dachema en

8/9/2019 Chemistry Innovation Dachema En

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The Role of Chemistry in InnovationThe Role of Chemistry in Innovation

Chemistry for Future Energy SupplyChemistry for Future Energy Supply

K. Wagemann, DECHEMA e.V.


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Two hot topics in the present political

discussions

Energ! "uppl!

Climate Change

#Adaptation $ Mitigation%


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&

Energ! in the "usChem

'mplementation Action (lan

) Energ! * Alternati+e energ! sources

) (hoto+oltaic

) uels production -rom iomass

) uel cells

) #Metal%nanoparticles as -uel) Wind power

* Energ! conser+ation) E--icient lighting

) 'nsulation

* Energ! storage) /atteries

) 0as storage

) "upercapacitors


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1

Energ! in the "usChemDeutschland 'A(

) (hoto+oltaics

) uel cells

) E--icient use o- energ! inorganic 3EDs

) E--icient use o- waste heat -rom industrial plants

) 3i'on atteries -or stationar! and moile applications

) "uper caps

) H2 production and storage

) E4haust gas treatment and catal!sis

) 3ight weight materials

) /ioutanol


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Chemistr! and Energ!

) 0erman Coordination 0roup6Chemical aspects o- energ! research7

) DECHEMA 0esellscha-t -8r Chemische Techni9 und/iotechnologie e.V.

) D/0 * Deutsche /unsen 0esellscha-t -8r(h!si9alische Chemie e.V

) 0DCh * 0esellscha-t Deutscher Chemi9er e.V.

) D0MK * Deutsche Wissenscha-tliche 0esellscha-t-8r Erd:l, Erdgas und Kohle e.V.

) VD'0VC * VD'0esellscha-t Ver-ahrenstechni9und Chemieingenieurwesen

) VC' * Verand der Chemischen 'ndustrie e.V.


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;

(osition (aper


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(osition (aper

Thesis

) The demand -or chemical solutions will increase

* uel cells Catal!sts, Electrol!tes, Memranes

* "olar cells =rganic, (ol!meric, Eas! to (rocess "!stems

* /atteries Electrodes, Electrol!tes

* Thermoelectrica >anostructured Materials

* C=2"e?uestration Asorption, Chemical Con+ersion

* Hea+! =ils and Coal #and /iomass% Con+ersion to uels


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Energy Supply Fuels

Bioenergy

Photovoltaics

Fuel cells

Thermoelectrics

Collectors

H2-Prouction

Energy storage

!o"ile "atteries

Stationary "atteries

Supercaps

Chemicals

Energy efficientprouctionprocesses

Catalysis

!icroreaction techn#

$e% reaction meia

Process integration

&'E(s

Superconuctors'ight%eight materials

Thermal insulation

Efficient useof energy

The role o- chemistr!

C=2tilisation


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Chemistr! has a role -or the

-uture energ! suppl!B


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/ac9up

/ac9up


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Chemistr!related C=2Emissions

>umers o- 21, "ource Ministr! o- Economics and Technolog!

Energy

Inustry )total*Chemistry

+ ,. !io# t C&2


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(roduction o- H!drogen

) Alternati+es

* Direct thermal water splitting #without catal!st T 2.5FC%

) catal!tic

) redo4catal!tic

* (hotocatal!tic water splitting at solid sur-aces

* /iomimetic photos!stems in li?uid phase #Gu"!stems%

* /ioh!drogen


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&

(hoto+oltaics

) Thin -ilm solar cells #a"i, C"i, CdTe ...%) Multiandgapcells

Alternati+es

) =rganic semiconductor s!stems

) (hotoelectrochemical cells#0rItJelCells%


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Materials -or Collectors

) Coatings toda!

* /lac9 Chromium

* /lac9 >ic9el

E--icient, ut processing #gal+anisation% not en+ironmentall! enign

) Coatings uture * Al2>&

* Carides

* Ti>=4

/etter e--icienc! #asorption and re-lection%

ut processing costs high


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Thermoelectrical De+ices

) (rinciple

* Materials /i2Te&, /i2"e&, "2Te #GT% (Te, "i0eAllo!s #55 * @ K%

* Energ! "ource 'n general lost heat

* Applications) Energ! independent micro sensors #7sel-powered sensorsL%

) 7sel-powered microde+icesL

) Au4iliar! power s!stems in automoti+es

) Cooling o- (hoto+oltaic de+ices


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Thermoelectrical De+ices

uture Higher E--icienc! using nanostructured materials


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<

C=2"e?uestration

$ tilisation

Caron Capture and "torage Technologies


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C=2"e?uestration

) Gesearch Topics #Chemistr! related%

* Coal 0asi-ication

* C=2Capture) Asorption

) Memranes

* Materials Corrosion

#C=2#l% H2= High "alt Concentration%


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C=2tilisation

) Energ! "torage "!stems

) Dr! Ge-orming

) C=2 as CC/uilding /loc9) Arti-icial (hotos!nthesis

) Microalgae*Culti+ation

) 7/etter (lantsL


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C=2tilisation

) Energ! "torage "!stemsC=2 N H2 CH&=H N H2=

) >ED=(roOect, Papan #since earl! ies%

Papan

Australia

C=2 Me=H

QnCr=catal!st

C= tili ti


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C=2tilisation

"teamless Caron Dio4ide Ge-orming

#Dr! Ge-orming%

) C=2 N CH1 2C= N 2H2

) 'dea E4ploitation o- remote gas -ields

#stranded gas%) Discussion (lat-orms

* Eranet Chemistr!

* "usChemD "eptemer Wor9shop


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C=2tilisation

Arti-icial (hotos!nthesis


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C=2tilisation

Arti-icial (hotos!nthesis

) 0eneral (rolems

* Thermal * "tailit!

* (hoto#o4idati+e%"tailit!

* 3ightHar+esting

) European >etwor9 "olarH#httpwww.-otomol.uu.seors9ning/iomimeticssolarh%


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C=2tilisation

C=2 as C /uilding /loc9

) (rolem 'nertness

&

C=GG2

C

&G2G&

G& G1

&

C=GG2=

C=2

Acetales

CaronatesEster


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2;

C=2tilisation

C=2 as C /uilding /loc9

Acti+ation ! Caroanh!drase

C=2 N H2= HC=& N HN

A9ti+e Center o- Caroanh!drase


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2<

C=2tilisation

Acti+ation o- C=2

) Acti+e "pecies Caramate

M. Antonietti, Angew. Chemie 2


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2@

C=2tilisation

/iore-ineries

) /ioethanol/ioDiesel #st 0eneration%

) /io-uels 2nd 0eneration

* /T3 # TCatal!sts% * 3ignocellulose Ethanol

) /iogas

) Chemical /uilding /loc9s


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C=2tilisation

/iogas

One Alternative: Zinkoxid

H2S+ZnO H2O+ZnS

200-400 °C (!)

H2S-content: pp

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