cheminform abstract: ring-opening of epoxyalcohols by diethylaluminum cyanide. regio- and...

1999 nitriles nitriles (acyclic compounds) P 0350 18 - 067 Ring-Opening of Epoxyalcohols by Diethylaluminum Cyanide. Regio- and Stereoselective Synthesis of 1-Cyano-2,3-diols. — Diethy- laluminum cyanide (II) is a highly selective reagent for the ring opening of 2,3-epoxyalcohols under mild conditions. This methodology provides a convenient route to dihydroxy nitriles and to the corresponding dihydroxy acids. — (BENEDETTI, FABIO; BERTI, FEDERICO; NORBEDO, STEFANO; Tetrahedron Lett. 40 (1999) 5, 1041-1044; Dip. Sci. Chim., Univ. Trieste, I-34127 Trieste, Italy; EN) 1

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Page 1: ChemInform Abstract: Ring-Opening of Epoxyalcohols by Diethylaluminum Cyanide. Regio- and Stereoselective Synthesis of 1-Cyano-2,3-diols

1999 nitriles

nitriles (acyclic compounds)P 0350

18 - 067Ring-Opening of Epoxyalcohols by Diethylaluminum Cyanide. Regio-and Stereoselective Synthesis of 1-Cyano-2,3-diols. — Diethy-laluminum cyanide (II) is a highly selective reagent for the ring openingof 2,3-epoxyalcohols under mild conditions. This methodology provides aconvenient route to dihydroxy nitriles and to the corresponding dihydroxy acids.— (BENEDETTI, FABIO; BERTI, FEDERICO; NORBEDO, STEFANO;Tetrahedron Lett. 40 (1999) 5, 1041-1044; Dip. Sci. Chim., Univ. Trieste,I-34127 Trieste, Italy; EN)

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