1999 organo-magnesium compounds

organo-magnesium compoundsS 1200

26 - 178A New Way to Prepare Grignard Reagent from RX (X: Cl, Br)Using the Mixture of BrCH2CH2Br and I2 as an Initiator. —Using 1,2-dibromoethane and iodine as initiators in the preparation of Grignardreagents reduces the reaction times by a factor of about 2-3. Compared toconventional methods a higher purity of the Grignard compounds is achievedor conventional methods do not yield the Grignard compound at all (no yieldsgiven). — (LI, JING; LIAO, XIANGJUN; LIU, HUA; XIE, QINGLAN; LIU,ZHUN; HE, HILIN; Synth. Commun. 29 (1999) 6, 1037-1039; Inst. Elem.-Org.Chem., Nankai Univ., Tianjin 300071, Peop. Rep. China; EN)

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