ChemInform Abstract: A Chemical Evidence of Regiochemistry in the Diels—Alder Reaction of 4-Oxygenated Quinolinequinones with 1-Methoxy-3-trimethylsilyloxy-1,3-butadienes

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  • 1999 fused pyridine derivatives

    fused pyridine derivativesR 0450

    43 - 143A Chemical Evidence of Regiochemistry in the DielsAlder Re-action of 4-Oxygenated Quinolinequinones with 1-Methoxy-3-trimethylsilyloxy-1,3-butadienes. The DielsAlder reaction of4-oxygenated 6-bromo- and 7-bromoquinolinequinones such as (I) and (IV)proceeds completely regioselectively to yield the corresponding regioisomericazaanthraquinones (III) and (V). These results confirm the regiochemistry inDielsAlder reactions of the corresponding non-halogenated quinolinones ina chemical mean. (HORIGUCHI, YOSHIE; TOMODA, KATSUHIRO;SANO, TAKEHIRO; Heterocycles 51 (1999) 7, 1669-1680; Showa Coll. Pharm.Sci., Machida, Tokyo 194, Japan; EN)

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