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Ca lifo rn ia Environmental Protection Ag ency
0 : Air Resources Board
California Air Resources Board Air Monitoring Near
Oil and Gas Operations
Climate Action Team
Public Health Workgroup
Cal EPA Headquarters - Sierra Hearing Room
Sacramento, California
May 23, 2017
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Ca liforn ia Environmental Protection Ag ency
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Outline
• Community monitoring
• Well stimulation treatment (WST)
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Ca liforn ia Environmental Protection Ag ency
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Community Monitoring
Near Oil and Gas Facilities
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Ca liforn ia Environmental Protection Ag ency
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Motivation to Monitor Near Oil and Gas Facilities
• Exposure concerns raised by communities
• Public awareness raised as a result of Aliso Canyon
underground natural gas leak, particularly aging
infrastructure
• California Council on Science and Technology (CCST)
independent review of well stimulation
recommendations:
○ Production generally a concern
○ Measure toxic emissions near production wells
○ Assess public health near all wells
○ Develop policies to limit exposures
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Ca lifornia Environmental Protection Agency
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Modoc
Shasta Lassen
Tehama
Northern Sierra
Placer
Tuok.unne
• Ma~sa
; .... Great Basin Unified
San ~quin valley Unified
\
Kem
Mojave Desert
South Coast
Scale
0 50 100 200 Miles
San Diego Imperia l - -0
0
Legend Oil and Associated Gas Wells
Non-Associated Dry Gas Wells
Air Districts
NOTE: OH and Gas wels presented on this figure are from the Departmeri of Oil and Gas and Geothermal Resources (DOGGR) website GlS shapefite "Al \/VeHs~ (posted 02/16/2016). (http:/M'WW.conservation.ca .gov/dog/maps/Pages/GISMapping2.aspx)
California Oil and Gas Operations
• Third largest oil producer,
15th largest natural gas
producer in US
• Generally, gas wells are
found in northern
California, oil wells further
south
• Gas produced with crude
oil is called associated
gas
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Ca liforn ia Environmental Protection Ag ency
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California Oil and Gas Operations • Oil & Gas Production
• ~ 82,000 active production wells statewide
• ~ 122,000 plugged wells statewide
• Production equipment
• Wastewater percolation ponds
• Central Coast - 3
• Los Angeles - 1
• Central Valley ~ 1,000
• Transmission and compressor stations
• Natural gas underground storage facilities
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Ca lifornia Environmental Protection Agency
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A 0 -
Scale
50 100 -
S!lloyou
La Goleta Gas SoCal Gas Co
200 Miles
Capacrty lnformanon fiom EIA, 2014
Lo-
hnp /l<NN, e,a g,w/cfapr,o/ngqs/ngqa cfm?l_report-RP7
Legend
Working Gas Capacity (Mscf)
>50,000,000 to 100,000,000
Q >10,000,000 to 50,000,000
0 5,000,000 to 10,000,000
Pleasant Creek Gas Pacific Gas & Electric Co
GrHtBIIM\Unafted
llmpenll
.. 2 l
I 2 l f
Natural Gas Underground Storage Facilities
• Thirteen facilities located
throughout California
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Ca liforn ia Environmental Protection Ag ency
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Community Air Monitoring Scope
• Characterize emissions from oil and gas
operations
- Toxics and particulate matter
- Methane and other volatile organic
compounds
• Source testing as necessary
• Health risk assessment if supported by data
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Ca liforn ia Environmental Protection Ag ency
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Related ARB Efforts
• Statewide air quality and greenhouse gas
monitoring network
• Recently adopted regulation - Greenhouse
Gas Emissions Standards for Crude Oil and
Natural Gas Facilities
• Well stimulation air sampling and analysis
• Oil and gas wastewater pond research
• California aerial methane hotspots survey
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Existing Statewide Monitoring Networks Greenhouse Gas Monitoring Sites Air Quality Monitoring Sites
• Site
c::J Air Basin
County
Ca lifornia Environmental Protection Agency
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• Tuscan Buttes
cfhlco
• ARB-operated stations
e ARB-funded station
P. lm Sprfn s
San Bernardino
Mextc.:ill
Sl Ge
H ende
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Public Outreach
• Actively solicit input from stakeholders
- Community members and organizations
- Environmental organizations
- Local air districts and other government agencies
- Other (e.g., academia, research organizations, etc.)
• Regional and local community meetings
• ARB webpage including schedules, progress, results
• E-mail listserv notifications
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Ca liforn ia Environmental Protection Ag ency
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Community Selection Criteria
Community
Selection
Air Monitoring
Data
Community
Concerns
& Public Input
Density of
Operations
Community
Proximity to
Facilities
CalEnviroScreen Local Air
District Input
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Methods and Resources
• Air monitoring methods
- Mobile vehicle monitoring (screening)
- Trailer mounted stationary monitoring
- Collection of air samples in canisters for analysis
• Data analysis methods
- Source attribution analysis
- Health risk assessment if supported by data
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Mobile Vehicle Monitoring
• Mobile screening to identify areas for investigation
• Supplementary monitoring to fill data gaps among
stationary trailers or to pinpoint sources
• Low emission hybrid-electric fueled vehicle
• State-of-the-art monitors for instant measurements of
methane, carbon dioxide, carbon monoxide, black
carbon and BTEX (benzene, toluene, ethylbenzene,
and xylenes)
• Discrete samples for analysis of toxic VOCs and
aldehydes
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Mobile Monitoring Stations
• Real time monitoring of methane, carbon dioxide,
carbon monoxide, black carbon, particulate matter
(PM), ozone, sulfur compounds (SO2/H2S)
• Hourly VOC speciation using gas chromatograph
• Particle-bound metals with a X-ray fluorescence
• 24-hour integrated canisters and filter based media for
laboratory analyses of toxic VOCs, aldehydes,
mercaptan, toxic metals, and PAHs/SVOC
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Well Stimulation Treatment (WST)
Operations
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Ca liforn ia Environmental Protection Ag ency
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Well Stimulation Treatment Operations in California
• Enhances oil production by making reservoir
more permeable, allowing oil to flow
• Includes hydraulic fracturing, acid
fracturing, matrix acidizing
• Vast majority in four fields in the San Joaquin
Valley
• California WST is unique
• Shallow wells, reservoirs more permeable,
less water use, duration ~<1 day
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Ca liforn ia Environmental Protection Ag ency
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Well Stimulation Treatment Operations in California
• Hydraulic fracturing
• Fluid injection increases pressure in an isolated
section of the well until nearby rock fractures
• Sand injected into fractures to prop them open
• Acid fracturing
• High pressure acidic fluid injection fractures nearby
rock, acid etches fracture walls to create permeability
• Matrix acidizing
• Acid pumped into well at low pressure dissolves rock,
creating permeability
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Senate Bill 4 (2013)
• Set the regulatory framework for WST activities in CA
• Required the Division of Oil, Gas, and Geothermal
Resources (DOGGR) to prepare regulations to ensure
WST is done safely
• Requires DOGGR to issue permits to conduct WST
• Permit application must include detailed
information about fluids used, groundwater
monitoring plan, water management plan
• Requires public disclosure of WST operation details
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SB4: Independent Scientific Review of WST in CA
• Assessment of WST practices, impacts, gaps in data,
potential risks, and alternative practices
• Conducted by California Council on Science and
Technology (CCST) and published in 2015
• Conclusions:
• WST is a potential source of air quality impacts in California and
emissions can be concentrated near production wells
• Emissions from oil production generally is a concern
• Recommendations:
• Additional analysis, measurement and control of toxic air
contaminants (TACs), and assessment of public health near all
wells
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DOGGR Permit Application Process
• Oil and gas operators submit detailed
application to DOGGR
• DOGGR forwards application to ARB and local
air district, among others, for comments
• ARB and district may recommend provisions to
add to permit to address air quality concerns
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ARB Permit Application Comments
• No studies have measured emissions from
WST operations in California
• Operators generally include several TACs in
their proposed WST fluid (e.g. distillates,
ethylene glycol, methanol, phthalic anhydride,
vinylidene chloride-methylacrylate polymer)
• Therefore, ARB has recommended air
monitoring for selected WST operations
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Air Sampling and Analysis During WST Operations
• Requires operators to obtain air samples
before and during WST and analyze the
samples for toxics, aldehydes, PAHs, and
methane
• Air sampling typically over 8-12 hour operation
• ARB will coordinate with OEHHA for health risk
assessment if supported by data
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Ca liforn ia Environmental Protection Ag ency
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Air Sampling and Analysis During WST Operations
• Air sampling began in December 2016
• Limited sampling has been completed in three
oil fields in Kern County
• More data will be collected and analyzed prior
to reporting results
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Ca liforn ia Environmental Protection Ag ency
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Contact Information
WST Permit Sampling and Analysis
Carolyn Lozo, Industrial Strategies Division
(916) 445-1104 [email protected]
Community Air Monitoring Near Oil and Gas Facilities
Carolyn Lozo, Industrial Strategies Division
(916) 445-1104 [email protected]
Ken Stroud, Monitoring and Laboratory Division
(916) 324-7630 [email protected]
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