bruker pulse program catalogue - ciencias.ula.ve · d1 presat off-reson. d1 presat pl9 d0 d0 pl12...
TRANSCRIPT
BRUKER
PULSE PROGRAM
CATALOGUE
2D HSQC EXPERIMENTS
©2004: Bruker BioSpin , Teodor Parella 147
Pulse Program Catalogue
NMRGuide4.0
©2004: Bruker BioSpin , Teodor Parella 148
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Phase-cycled:
Phase-cycled and solvent suppression:
Gradient-based:
Phase-sensitive 2D HSQC ( )
Phase-sensitive 2D HSQC with presaturation ( )Phase-sensitive 2D HSQC with off-resonance presaturation ( )
Phase-sensitive ge-2D HSQC using z-filter and selection before t1 ( | )Phase-sensitive ge-2D HSQC using z-filter and selection after t1 ( )Phase-sensitive ge-2D HSQC using echo-antiecho ( | )Phase-sensitive ge-2D HSQC using echo-antiecho and adiabatic pulses for inversion( )Phase-sensitive ge-2D HSQC using echo-antiecho and adiabatic pulses for inversion andrefocusing( )Phase-sensitive ge-2D HSQC using echo-antiecho and adiabatic pulses for inversion andrefocusing and BS effects( )Phase-sensitive ge-2D HSQC using PEP ( )Phase-sensitive ge-2D HSQC using PEP with gradients in back-inept ( )Phase-sensitive ge-2D HSQC using PEP and adiabatic pulses for inversion( |
)Phase-sensitive ge-2D HSQC using PEP and adiabatic pulses for inversion with gradients inback-inept ( )Phase-sensitive ge-2D HSQC using PEP and adiabatic pulses for inversion and refocusing( | )Phase-sensitive ge-2D HSQC using PEP and adiabatic pulses for inversion and refocusing withgradients in back-inept ( )
ge-2D H-X HSQC experiment with X-Y-decoupling during acquisition and withselective Cb/C=O decoupling. ( )
hsqcph
hsqcphprhsqcphps
hsqcgpphhsqcgpph2
hsqcetgp
hsqcetgpsp
hsqcetgpsp.2
hsqcetgpsp.3hsqcetgpsi
hsqcetgpsi2hsqcetgpsisp
hsqcetgpsisp2
hsqcetgpsisp.2
hsqcetgpsisp2.2
hsqcdhetgpsp
HSQCGP
HSQCETGP
HSQCETGPSISP
HSQCETGPSISP.2
1
FROM F2 CHANNEL
Pulse Program Catalogue
NMRGuide4.0
©2004: Bruker BioSpin , Teodor Parella 149
FROM F3 CHANNEL
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Phase-cycled:
Phase-cycled and solvent suppression:
Gradient-based:
Gradient-based and solvent suppression
Phase-sensitive 2D H- N HSQC ( )
Phase-sensitive 2D H- N HSQC using presaturation ( )
Phase-sensitive ge-2D H- N HSQC using echo-antiecho ( | )
Phase-sensitive ge-2D H- N HSQC using PEP ( | )
Phase-sensitive ge-2D H- N HSQC using PEP with gradients in back-inept( )
Phase-sensitive ge-2D H- N HSQC using XY16-CPMG()
Phase-sensitive ge-2D H- N HSQC using water flip-back and echo-antiecho( | )
Phase-sensitive ge-2D H- N HSQC using water flip-back and PEP ( |)
Phase-sensitive ge-2D H- N HSQC using water flip-back and PEP with gradients inback-inept ( )
Phase-sensitive ge-2D H- N HSQC using WATERGATE (3-9-19) ( )
Fast-HSQC, Phase-sensitive ge-2D H- N HSQC using WATERGATE (3-9-19)( | )
Phase-sensitive ge-2D H- N HSQC using water flip-back and WATERGATE(selective pulse) ( | )
1 15
1 15
1 15
1 15
1 15
1 15
1 15
1 15
1 15
1 15
1 15
1 15
hsqcf3ph
hsqcf3phpr
hsqcetf3gp
hsqcetf3gpsi
hsqcetf3gpsi2
hsqcetf3gpxy,hsqcetf3gpxy.2
hsqcetfpf3gp
hsqcetfpf3gpsi
hsqcetfpf3gpsi2
hsqcf3gpph19
fhsqcf3gpph
hsqcfpf3gpphwg
HSQCETF3GP
HSQCETF3GPSI
HSQCETFPF3GP
HSQCETFPF3GPSI
FHSQCF3GPPH
HSQCFPF3GPPHWG
Pulse Program Catalogue
NMRGuide4.0
�
GARP
�X
1H
Gz
�1
y�rec
� �
�
GARP
�X
1H
Gz
�1
y�rec
��
hsqcgpph
d4
G3
d4 d4 d4
d0 d0
G1 G2
hsqcgpph2
d4 d4 d4 d4
G3G1 G2
d0 d0
d0 d0d0 d0
pl12
pl12
GARPX
1H
1H
�1�1
y
�rec�rec
hsqcph
d4
d0 d0
d4 d4 d4
�
hsqcf3ph
GARPX
1H
1H
�1�1
y
�rec�rec
hsqcphpr
d4 d4 d4 d4
�
hsqcf3phpr
d1
presat
pl9
hsqcphps
GARPX
1H
1H
�1�1
y
�rec�recd26
d0 d0 �
d26 d26 d26
GARPX
1H
1H
�1�1
y
�rec�recd26
d0 d0 �
d26 d26 d26
GARPX
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
�
d1
presat
off-reson.
d1
presat
pl9
d0 d0
pl12
pl12
pl12
pl12
pl12
©2004: Bruker BioSpin , Teodor Parella
d0 d0
150
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
�
GARP
�X
1H
1H
GzGz
�1�1
y�rec�rec
� �
�
GARP
�X
1H
1H
GzGz
�1�1
y�rec�rec
��
hsqcgpph
d4
G3
d4 d4 d4
d0 d0
G1 G2
hsqcgpph2
d4 d4 d4 d4
G3G1 G2
d0 d0
d0 d0d0 d0
1JCH
C C C N C C N
H H HH
C
H H
©2004: Bruker BioSpin , Teodor Parella
ppm
10 9 8 7 6 5 4 3 2 1 ppm
20
40
60
80
100
120
140
151
pl12
pl12
GARPX
1H
�1
y
�rec
hsqcph
d4
d0 d0
d4 d4 d4
�
hsqcf3ph
GARPX
1H
�1
y
�rec
hsqcphpr
d4 d4 d4 d4
�
hsqcf3phpr
d1
presat
pl9
hsqcphps
GARPX
1H
�1
y
�recd26
d0 d0 �
d26 d26 d26
GARPX
1H
�1
y
�recd26
d0 d0 �
d26 d26 d26
GARPX
1H
�1
y
�recd4 d4 d4 d4
�
d1
presat
off-reson.
d1
presat
pl9
d0 d0
pl12
pl12
pl12
pl12
pl12
d0 d0
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
hsqcetgpsp.3
�
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
p28
Gz
G1
G2
15N
13C
p14
sp3
p14
sp3
p14
sp3
p14
sp3
pl12
optional
�
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
hsqcdhetgpsp
p28
Gz
G1 G2
13C�
p14
sp313 13C / CO�
p14
sp9
p5m4sp180.p31
G3
p14
sp3
pl12
pl13
�
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
hsqcetgp
p28
GzGz
G1
G2
15N
15N
13C
13C �
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
p28
GzGz
G1
G2
15N
15N
13C
13C
pl12
optional
�
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
hsqcetgpsp
p28
GzGz
G1
G2
15N
15N
13C
13C
p14
sp3
p14
sp3
p14
sp3
p14
sp3pl12
optional
hsqcetgpsp.2
�
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
p28
GzGz
G1
G2
15N
15N
13C
13C
p14
sp3
p14
sp3p24
sp7
p24
sp7
p14
sp3
p14
sp3
pl12
optional
©2004: Bruker BioSpin , Teodor Parella 152
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
hsqcetgpsp.3
�
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
p28
GzGz
G1
G2
15N
15N
13C
13C
p14
sp3
p14
sp3
p14
sp3
p14
sp3
p14
sp3
p14
sp3
p14
sp3
p14
sp3
pl12
optional
�
GARP
�
1H
1H
�1�1
y
�rec�recd4 d4 d4 d4
d0 d0
hsqcdhetgpsp
p28
GzGz
G1 G2
13C�
13C�
p14
sp3
p14
sp313C /�
13CO
13 13C / CO�
p14
sp9
p14
sp9
p5m4sp180.p31
G3
p14
sp3
p14
sp3
pl12
pl13
©2004: Bruker BioSpin , Teodor Parella 153
�
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
hsqcetgp
p28
Gz
G1
G2
15N
13C �
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
p28
Gz
G1
G2
15N
13C
pl12
optional
�
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
hsqcetgpsp
p28
Gz
G1
G2
15N
13C
p14
sp3
p14
sp3pl12
optional
hsqcetgpsp.2
�
GARP
�
1H
�1
y
�recd4 d4 d4 d4
d0 d0
p28
Gz
G1
G2
15N
13C
p14
sp3p24
sp7
p14
sp3
pl12
optional
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
�
GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
13C
d4 d4
hsqcetgpsisp2
p14
sp3
G3 G3 G4 G4
p14
sp3
pl12
optional
�
GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
13C
d4 d4
hsqcetgpsisp2.2
p14
sp3
G3 G3 G4 G4
p14
sp3
p24
sp7p24
sp7
pl12
�
GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1G2
d0 d0
p28
15N
13C
d4 d4
p14
sp3
hsqcetgpsisp.2
p24
sp7
p24
sp7
p14
sp3pl12
�GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
15N
13C
13C
d4 d4
hsqcetgpsi
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
15N
13C
13C
d4 d4
hsqcetgpsi2
G3 G3 G4 G4
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
15N
13C
13C
d4 d4
hsqcetgpsisp
p14
sp3
p14
sp3
p14
sp3
p14
sp3pl12
pl12
pl12
optional
optional
optional
©2004: Bruker BioSpin , Teodor Parella 154
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
d1
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
15N
13C
13C
d4 d4
hsqcetgpsisp2
p14
sp3
p14
sp3
G3 G3 G4 G4
p14
sp3
p14
sp3
pl12
optional
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
13C
13C
d4 d4
hsqcetgpsisp2.2
p14
sp3
p14
sp3
G3 G3 G4 G4
p14
sp3
p14
sp3
p24
sp7
p24
sp7p24
sp7
p24
sp7
pl12
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
d4 d4 d24 d24
G1G2
d0 d0
p28
15N
15N
13C
13C
d4 d4
p14
sp3
p14
sp3
hsqcetgpsisp.2
p24
sp7
p24
sp7
p24
sp7
p24
sp7
p14
sp3
p14
sp3pl12
©2004: Bruker BioSpin , Teodor Parella 155
�GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
13C
d4 d4
hsqcetgpsi
�
GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
13C
d4 d4
hsqcetgpsi2
G3 G3 G4 G4
�
GARP
�
1H
Gz
� �
��1
y y�rec
d4 d4 d24 d24
G1
G2
d0 d0
p28
15N
13C
d4 d4
hsqcetgpsisp
p14
sp3
p14
sp3pl12
pl12
pl12
optional
optional
optional
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
d1
�GARP
�
1H
Gz
� �
��1
y y�rec
hsqcetf3gpsi
d26
G1 G3
d0 d0
p28
15N
13C
d26 d24 d24 d26 d26�
G2
p14
sp3
pl16
optional
�GARP
�
1H
Gz
� �
��1
y y�rec
hsqcetf3gpsi2
d26
G1 G3
d0 d0
p28
15N
13C
d26 d24 d24 d26 d26�
G2
p14
sp3
G5 G5G4 G4
pl16
optional10 9 8 7 6 5 4 3 2 1 0 ppm
©2004: Bruker BioSpin , Teodor Parella
hsqcetf3gp
�
GARP
�
1H
1H
�1�1
y
�rec�recd26
d0 d0
GzGz
G3
15N
15N
13C
13C
��
1H
1H
�1�1
y
�rec�rec
d0 d0
p28
GzGz
G1
15N
15N
13C
13C
d26 d26 d26�
p14
sp3
p14
sp3
G2
pl16
optional
ppm
6.06.57.07.58.08.59.09.510.0 ppm
102
104
106
108
110
112
114
116
118
120
122
124
126
128
1JNH
C C C N C C N
H H HH
C
H H
156
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
©2004: Bruker BioSpin , Teodor Parella
�GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
hsqcetf3gpsi
d26
G1 G3
d0 d0
p28
15N
15N
13C
13C
d26 d24 d24 d26 d26�
G2
p14
sp3
p14
sp3
pl16
optional
�GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
hsqcetf3gpsi2
d26
G1 G3
d0 d0
p28
15N
15N
13C
13C
d26 d24 d24 d26 d26�
G2
p14
sp3
p14
sp3
G5 G5G4 G4
pl16
optional
157
hsqcetf3gp
�
GARP
�
1H
�1
y
�recd26
d0 d0
Gz
G3
15N
13C
��
1H
�1
y
�rec
d0 d0
p28
Gz
G1
15N
13C
d26 d26 d26�
p14
sp3
G2
pl16
optional
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
hsqcetfpf3gp
�
GARP
�
1H
�1
y
�recd26
d0 d0
Gz
G3
15N �
GARP
�
1H
�1
y
�rec
d0 d0
Gz
G1
15N
d26
d26 d26
�
G2
�
G4 G5
-x-x
hsqcfpf3gpphwg
�GARP
1H
�1
y
�recd26
d0 d0
Gz
G3
15N
GARP
1H
�1
y
�rec
d0 d0
Gz
G1
15N
d26
d26 d26
�
G2
�
-x-x
G3
-x
13C
13C
p11
sp1
-x
optional
pl16
pl16
�
1H
Gz
�1
y
�rec
G3
fhsqcf3gpph
d26
15N
G3
d26
G2
p14
sp3
G2
13C
�
G1 G1
d26 d26
d0 d0
GARPGARP
pl16
optional
-x
�
1H
Gz
�1
y�rec
G3
hsqcf3gpph19
d26
15N
G3
d26
G2
�
G1
d26 d26p28
d0 d0
GARPGARP
pl16
p29
sp11
p11
sp1
p29
sp11
p8
sp13
©2004: Bruker BioSpin , Teodor Parella
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
hsqcetfpf3gpsi2
d26
G1 G3
d0 d015N
15N
13C
13C
d26 d24 d24 d26 d26�
G2
p8
sp13
p8
sp13
�
GARP
�
1H
1H
GzGz
� �
��1�1
y y�rec�rec
hsqcetfpf3gpsi
d26
G1 G3
d0 d015N
15N
13C
13C
d26 d24 d24 d26 d26�
G2
p8
sp13
p8
sp13
G5 G5G4 G4
pl16
pl16
optional
optional
158
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
d1
hsqcetfpf3gp
�
GARP
�
1H
1H
�1�1
y
�rec�recd26
d0 d0
GzGz
G3
15N
15N �
GARP
�
1H
1H
�1�1
y
�rec�rec
d0 d0
GzGz
G1
15N
15N
d26
d26 d26
�
G2
�
G4 G5
-x-x
hsqcfpf3gpphwg
�GARP
1H
1H
�1�1
y
�rec�recd26
d0 d0
GzGz
G3
15N
15N
GARP
1H
1H
�1�1
y
�rec�rec
d0 d0
GzGz
G1
15N
15N
d26
d26 d26
�
G2
�
-x-x
G3
-x
13C
13C
13C
13C
p11
sp1
p11
sp1
-x
optional
©2004: Bruker BioSpin , Teodor Parella
pl16
pl16
�
1H
1H
GzGz
�1�1
y
�rec�rec
G3
fhsqcf3gpph
d26
15N
15N
G3
d26
G2
p14
sp3
p14
sp3
G2
13C
13C
�
G1 G1
d26 d26
d0 d0
GARPGARP
pl16
optional
-x
�
1H
1H
GzGz
�1�1
y�rec�rec
G3
hsqcf3gpph19
d26
15N
15N
G3
d26
G2
�
G1
d26 d26p28
d0 d0
GARPGARP
pl16
159
p29
sp11
p29
sp11
p11
sp1
p11
sp1
p29
sp11
p29
sp11
p8
sp13
p8
sp13
�
GARP
�
1H
Gz
� �
��1
y y�rec
hsqcetfpf3gpsi2
d26
G1 G3
d0 d015N
13C
d26 d24 d24 d26 d26�
G2
p8
sp13
�
GARP
�
1H
Gz
� �
��1
y y�rec
hsqcetfpf3gpsi
d26
G1 G3
d0 d015N
13C
d26 d24 d24 d26 d26�
G2
p8
sp13
G5 G5G4 G4
pl16
pl16
optional
optional
Pulse Program Catalogue
NMRGuide4.0
d1
d1
d1
d1
d1
d1
hsqcetf3gpxy
�
GARP
�
1H
1H
�1�1
y
�rec�recd1
d0 d0
GzGz
G3
15N
15N
13C
13C
��
1H
1H
�1�1
y
�rec�rec
d0 d0
GzGz
G1
15N
15N
13C
13C
d26 d26 d26�
p14
sp3
p14
sp3
G2
pl16
optional
d26 ��
xy16
xy16
xy16
xy16
loop loop
hsqcetf3gpxy.2
�
GARP
�
1H
1H
�1�1
y
�rec�recd1
d0 d0
GzGz
G3
15N
15N
13C
13C
��
1H
1H
�1�1
y
�rec�rec
d0 d0
GzGz
G1
15N
15N
13C
13C
d26 d26 d26�
p14
sp3
p14
sp3
G2
pl16
optional
d26 ��
xy16
xy16
xy16
xy16
loop loop
G2
�
G1
©2004: Bruker BioSpin , Teodor Parella 160
Pulse Program Catalogue
NMRGuide4.0
%d0%93%d0%a3%d0%97%20%d0%93%d0%b0%d0%b7 %d0%97%d0%b0%d0%b2%d0%be%d0%b4%d1%81%d0%ba%d0%b0%d1%8f%20%d0
%d0%b5 %d0%b5%d0%ba%d1%80%d0%b0%d0%bd %d0%b4%d0%be%d1%80%d0%b0%d0%bd%d0%b8%d0%ba%d0%b8 %d0%bb%d1%8e%
%d0%9c%d0%b0%d0%b3 %d0%95%d0%ba%d0%b1 %d0%a2%d0%b5%d1%85%d0%bd%d0%be%d0%bb%d0%be%d0%b3%d1%96%d1%97%2
%d0%9f%d0%be%d0%bb%d0%be%d0%b6%d0%b5%d0%bd%d0%b8%d0%b5 %d0%9f%d0%be%d1%81%d0%bb%d1%8b%20%d0%9f%d0%be
%d0%9a%d0%b0%d1%82%d0%b0%d0%bb%d0%be%d0%b3 %d0%9c%d0%be%d0%bb %d0%a1%d0%bf%d0%b5%d1%86 %d1%83%d0%ba%
%d0%93%d0%90%d0%a3%d0%97%20%20%d0%a0%d0%9f%d0%a6%20%d0%b3 %d0%a3%d0%bb%d0%b0%d0%bd %d0%a3%d0%b4%d1%8
%d0%a3%d1%87%d0%b5%d0%b1%d0%bd%d1%8b%d0%b9%d0%9f%d0%bb%d0%b0%d0%bd %d0%a4%d1%83%d0%bd%d0%b4%d0%9c%d0
1060204 %d0%bb%d0%b8%d1%81%d1%82%d0%be%d0%b2%d0%ba%d0%b0 %d0%bf%d0%be %d1%82%d0%b5%d0%bf%d0%bb%d0%be
%d0%9d%d0%b0%d0%b2%d1%87%d0%b0%d0%bb%d1%8c%d0%bd%d0%be %d0%bc%d0%b5%d1%82%d0%be%d0%b4%d0%b8%d1%87%d0
%d0%a1%d0%b1%d0%be%d1%80%d0%bd%d0%b8%d0%ba%20%d0%9c%d0%b5%d0%b4 %20%d0%b7%d0%b0%d0%b2 %20%d0%b4%d0%b
%d1%81%d0%b8%d1%81%d1%82%d0%b5%d0%bc%d0%b0 %d0%bd%d0%b0%d0%bf%d0%be%d0%bb%d1%8c%d0%bd%d0%be%d0%b3%d0
%d0%9c%d0%b0%d0%b3 %d0%95%d0%ba%d0%b1 %d0%91%d1%96%d0%be%d1%82%d0%b5%d1%85%d0%bd%d0%be%d0%bb%d0%be%d
%d0%9a%d0%a3%d0%a8%d0%9d%d0%86%d0%a0%d0%95%d0%9d%d0%9a%d0%9e%20%d0%9e %d0%90 %d0%9e%d0%91%d0%9b%d0%8
%d0%9f%d1%80%d0%be%d0%b3%d1%80%d0%b0%d0%bc%d0%bc%d0%b0 %d0%a1%d1%8a%d0%b5%d0%b7%d0%b4%d0%a2%d0%b5%d1
%d0%bf%d1%80%d0%be%d0%b5%d0%ba%d1%82%d0%b8%d1%80%d0%be%d0%b2%d0%b0%d0%bd%d0%b8%d0%b5 %d0%b2%d0%bd%d1
%d0%a8%d0%b0%d0%b1%d0%bb%d0%be%d0%bd %d0%a0%d0%9f %d0%b0%d1%81%d0%bf%d0%b8%d1%80%d0%b0%d0%bd%d1%82%d
%d0%a3%d1%87%d0%b5%d0%b1%d0%bd%d0%b8%d0%ba%d0%b8%20%d0%98%d0%b7%d0%b4 %d0%b2%d0%b0%20%d0%9c%d0%98%d0