brian k. hovik · semi-synthetics concentrate contains petroleum oil & water diluted with water...

50
Metalworking Fluids The Whole Perspective Brian K. Hovik Chemetall US IMTS Chicago September 2016 1

Upload: others

Post on 24-Mar-2020

1 views

Category:

Documents


0 download

TRANSCRIPT

Page 1: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Metalworking Fluids The Whole Perspective

Brian K. Hovik

Chemetall US

IMTS Chicago September 2016

1

Page 2: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

About the PresenterBrian K. Hovik

BS in Manufacturing Engineering 1985

MBA Technology Management 2005

Boeing Company 29 years - Retired

Manufacturing Engineering background: All aspects of manufacturing

Coolant and Lubricant involvement since 1990

Coolant & Lubricant Focal for Boeing Co. over 20 years

Coolant maintenance consultant

Member STLE since 1991 STLE Metalworking Fluids Steering Committee member STLE Metalworking Fluids Education and Training Sub-Committee Chair

Member SME since 1985

Chemetall US since 20142

Page 3: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Perspective

3

Page 4: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Perspective

What is your perspective ?

4

Page 5: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MetalworkingFluids

MWF Manufactureror Raw MaterialSupplier

MWF End User

MWF Regulating Agencies

MWF Waste Treatersand/or Haulers

Metalworking Fluid Players

All have a unique perspective 5

Page 6: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Goal of PresentationEducate each group about the other’s unique perspectives

To help grow the industry together in harmony instead of as adversaries

Understand that Metalworking fluids are an asset – not a necessary evil

6

Page 7: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Presentation Topics Key Concepts Metalworking Fluid (MWF) Basics

Definitions Types Functions

The Formulator’s Perspective MWF Formulations & Differentiators REACh Additives/Components

The End User’s Perspective The Perfect MWF Cost Comparisons MWF Selection Issues Performance

The Regulating Agencies’ Perspective Regulation Banned Chemicals OSHA Waste Reduction Manual

The Waste Treatment Perspective Treatment Methods

Market Trends & Industry Insights Summary 7

Page 8: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Key Concepts

8

• All players with regards to Metalworking Fluids have a perspective based on their position in the industry.

• Metalworking Fluids are costly and should be treated as an asset in increasing productivity.

• There will be continuous change in the Metalworking Fluid Industry due to improvements in formulations, pressure from regulatory agencies and world demand.

• Working together to solve issues will enhance productivity, reduce waste and create a safer working environment for the metalworking industry.

Page 9: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Metalworking Fluid Basics –Definitions

Straight oil (neat or cutting oil):Not diluted with water, oil-based with additives

Concentrate:Undiluted fluid prior to addition of waterBlend of mineral oils or organic oils and additives

Emulsion: Oil dispersed within water using an emulsifier

Working fluid: Concentrate diluted with water from concentrate

9

Page 10: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Straight (Neat) Oil Formulation

Petroleum Oil 75 – 95% Boundary lubricants: 5 – 10% Extreme Pressure Additives: 0 – 20%

Chlorinated Paraffin, Sulfates Other additives possible

Metal deactivators Anti-mist or anti-foam

Excellent lubrication – poor cooling

10

Page 11: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Soluble Oil (Emulsifiable Oil)

Petroleum Oil 40 – 70% Diluted with water to form emulsion (milky appearance) Light to Heavy Duty Machining Combines lubrication and cooling Used extensively in all forms of metal cutting/grinding Prone to biological activity and foaming Standardized waste treatment processes Most common type of MWF

11

Page 12: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Synthetics

NO Petroleum Oil Diluted with water to form solution (clear or opaque) Light to Medium Machining Combines medium lubrication with cooling Used in all forms of metal cutting, especially grinding Prone to be harsh on equipment Specialized waste treatment processes

12

Page 13: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Semi-Synthetics

Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification

working fluid (light milky color) Light to Heavy Machining Combines lubrication with cooling Used in all forms of metal cutting Formulated to be bio-stable Standard waste treatment processes Most rapidly growing fluid type Combines both lubricity of soluble oil with cleanliness of

synthetics to form a unique working fluid

13

Page 14: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Differences in MWF

14

Synthetic

Semi-Synthetic

Emulsified Oil

Straight Oil

Cooling Ability

Lubricity

Page 15: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Metalworking Fluid Functions that Can impact Processes, Quality and Total Cost Lubrication

Lowers Friction and enhances tool life

Cooling Lowers temperature of workpiece and tool Allows for better part tolerance

Chip Removal (adds liquidity to chip mass vs. dry) Keeps chips from being re-cut Keeps dust and swarf from becoming airborne

Rust Protection Keeps machine tool from rusting (machines are mostly steel) Keeps tools (mostly steel and/or steel holders) from rusting Keeps parts from rusting and/or creating dielectric corrosion

15

Page 16: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

16

• The formulator has many options but also many challenges

• Each formula many contain as many as 20 ingredients

• The change or omission of any of the ingredients can change the product

• Changes in Regulating Agencies regulations can reduce the available chemistry

• This is especially true with regards to anti-microbial pesticides

• Changes in availability and cost for raw materials can adversely affect the product

• Global impact such as REACh (Registration, Evaluation, Authorization and Restriction of Chemicals )

• Performance of the product can be degraded without certain chemistry

• It’s like trying to write a novel using only the Hawaiian alphabet (only 13 letters)

A E I O U H K L M N P W ‘

Page 17: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

REACh

17

• The Registration, Evaluation, Authorization and Restriction of Chemicals (REACh) is an EU regulation released in December of 2006. REAChCompliance is designed to improve the protection of human health and the environment through better identification of the properties of chemical substances.

• The most significant impact of REACh is to mandate chemical manufacturers and importers to determine the hazardous properties of chemicals through testing of thousands of older industrial chemicals.

• These substances will then have to be registered with the European Chemicals Agency (ECHA). REACh compliance is essential to any business looking to sell their products in Europe, and is considered to be the strictest law regulating chemical substances.

Page 18: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Metalworking Fluid Additives/Components of Most Concentrates or Neat oils Reserve Alkalinity Boosters (Amines) Metal Deactivators (Mostly for non-ferrous applications) Extreme Pressure Additives (Cl, P, S) Biocides or Antimicrobial Pesticides Coupling Agents (Glycols, glycol ethers) Emulsifiers (Soaps, Sulfonate, Amides) Lubricity Additives (Fatty esters, Polymers) Defoamers Dyes or Smell-Covering Agents (Pine Oil, Almond Extract etc.) Anti-mist Additives Whetting Agents Corrosion Inhibitors (Mostly ferrous) Anti-Oxidants (Primarily Neat Oils)

18

Page 19: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

Group 2 Base Oil $ 5.45 Reserve Alkalinity Booster $ 1.25 Metal Deactivators $ .65 Extreme Pressure Additive $ 1.54 Biocide $ .85 Coupling Agent $ .40 Emulsifier $ 1.23 Lubricity Additive $ 1.10 Defoamer $ .74 Dye $ .10 Anti-mist Additive $ .40 Whetting Agent $ .32 Corrosion Inhibitor $ .64 TOTAL COST $ 14.67

19

Example: Cost to formulate one gallon of concentrate – Soluble Oil

January 2016

Page 20: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

Group 2 Base Oil $ 6.54 Reserve Alkalinity Booster $ 1.25 Metal Deactivators $ .65 Extreme Pressure Additive $ 1.54 Biocide $ .85 Coupling Agent $ .40 Emulsifier $ 1.23 Lubricity Additive $ 1.10 Defoamer $ .74 Dye $ .10 Anti-mist Additive $ .40 Whetting Agent $ .32 Corrosion Inhibitor $ .64 TOTAL COST $ 15.76 7% total increase

20

Example: Cost of base oil increased 20%

February 2016

Page 21: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

Group 2 Base Oil $ 6.54 Reserve Alkalinity Booster $ 1.25 Metal Deactivators $ .65 Extreme Pressure Additive $ 1.69 Biocide $ .85 Coupling Agent $ .44 Emulsifier $ 1.23 Lubricity Additive $ 1.21 Defoamer $ .74 Dye $ .10 Anti-mist Additive $ .44 Whetting Agent $ .32 Corrosion Inhibitor $ .70 TOTAL COST $ 16.16 10% total increase

21

Example: Raw material supplier (5) increased price by 10%

March 2016

Page 22: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

Group 2 Base Oil $ 6.54 Reserve Alkalinity Booster $ 1.25 Metal Deactivators $ .65 Extreme Pressure Additive $ 1.69 Biocide $ .85 Coupling Agent $ .44 Emulsifier $ 2.46 Lubricity Additive $ 1.21 Defoamer $ .74 Dye $ .10 Anti-mist Additive $ .44 Whetting Agent $ .32 Corrosion Inhibitor $ .70 TOTAL COST $ 17.39 16% total increase

22

Example: Raw material supplier discontinued emulsifier – acceptable replacementfound that costs double

April 2016

Page 23: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Formulator’s Perspective

23

• In a four month period, due to cost increases for raw materials(or replacement materials) the cost increased 16%

• Most of these changes are totally out of the hands of the formulator

• Explains why there are periodic price increases

• Most formulators only increase their price about half the increased cost to maintainthe market at a level plane.

• Rarely do costs go down unless the formulator finds a less expensive raw material

• Regulation can also play a part in the cost – Elimination of raw materials

• Formulators are continuously faced with cost increases and reduced raw materialsavailable on the market. It is a never-ending process of finding materialsthat will give the end-user the products they need for a reasonable cost.

Page 24: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

End-User Perspective

24

End-User’s Coolant or Lubricant Wish List

• Low or no VOC Content• Clean Petroleum Content (Group 2 Base Oil)• Extended Sump Stability• No Biocides/Fungicides required (concentrate or tankside)• No Secondary Amines• High Detergency• Low or no Foaming• Extended tool life• Easy maintenance (no special tools or equipment needed)• Manageable overall cost• Cost effective waste treatment and/or recycling

Page 25: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

End-User Perspective

25

Manufacturing Costs Example A: 3 months of production

Purchase Price of one drum Soluble Oil Coolant (initial) $1,200.00 Cost of water to mix at 5% concentration $ 2.22 Labor cost to mix 1100 gallons of coolant (with proportioner) $ 50.00 Cost to maintain 5% concentration for 90 days (coolant) $1,200.00 Cost of water to maintain 5% concentration for 90 days $ 25.60 Defoamer $ 450.00 Biocide $ 340.00 Labor cost to periodically maintain concentration/stability $ 300.00 Labor to remove coolant at end of useful life (90 days) $ 50.00 Cost to waste-treat coolant (1100 gallons) $ 120.00 Labor to waste-treat/transport waste oil (55 gallons) $ 100.00 Transportation costs (initial coolant drums & waste oil) $ 350.00

Total Cost for 90 days use of 110 gallons of coolant $4,187.82

Page 26: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

End-User Perspective

26

Manufacturing Costs Example B: 3 months of production

Purchase Price of one drum Semi-Synthetic Coolant (initial) $1,200.00 Cost of water to mix at 5% concentration $ 2.22 Labor cost to mix 1100 gallons of coolant (with proportioner) $ 50.00 Cost to maintain 5% concentration for 90 days (coolant) $ 600.00 Cost of water to maintain 5% concentration for 90 days $ 12.30 Defoamer $ 0.00 Biocide $ 65.00 Labor cost to periodically maintain concentration/stability $ 75.00 Labor to remove coolant at end of useful life (90 days) $ 50.00 Cost to waste-treat coolant (1100 gallons) $ 120.00 Labor to waste-treat/transport waste oil (55 gallons) $ 100.00 Transportation costs (initial coolant drums & waste oil) $ 350.00

Total Cost for 90 days use of 81 gallons of coolant $2,624.52

37% Less

Page 27: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

27

Metal Removal Fluid Selection IssuesSump Life

Machinability

Waste Treatment

Foaming Purchase Cost

Health & Safety

Bio-Stability

$$

$$

Part Cleaning

Page 28: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

MWF Performance

28

• Metalworking Fluids must perform well in three major areas to be anaid to manufacturing and productivity:

• Machinability• Sump Life• Drag Out (residue on chips)

• Other important performance characteristics:

• Waste treatability• Employee Health and Safety• Cleanability• Environmental Impact

Page 29: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant Differences – MachinabilityCoolant Machinability Factor Type Concentration

TEST NORMAL 1.0 2% Synthetic Test Base 2%

Semi-Synthetic C 1.44 Semi-Synthetic 5%

Semi Synthetic E 1.57 Semi-Synthetic 5%

Semi-Synthetic A 1.67 Semi-Synthetic 5%

Semi-Synthetic B 1.67 Semi-Synthetic 5%

Semi-synthetic D 1.67 Semi-Synthetic 5%

Semi-Synthetic F 1.96 Semi-Synthetic 5%

Soluble Oil D 2.06 Soluble Oil 5%

Synthetic C 2.07 Synthetic 10% *

Soluble Oil C 2.07 Soluble Oil 5%

Soluble Oil B 2.32 Soluble Oil 5%

Semi-Synthetic H 2.58 Semi-Synthetic 5%

Semi-Synthetic G 2.93 Semi-Synthetic 5%

Neat Oil A 3.82 Straight Oil 100%

Page 30: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant Differences – Sump LifeCoolant Sump Longevity Factor Type Concentration

TEST NORMAL 1.0 Synthetic 2%

Soluble Oil C 1.7 Soluble Oil 5%

Soluble Oil B 1.7 Soluble Oil 5%

Semi-Synthetic C 1.8 Semi-Synthetic 5%

Soluble Oil D 2.0 Soluble Oil 5%

Semi-Synthetic A 2.1 Semi-Synthetic 5%

Semi-Synthetic F 2.1 Semi-Synthetic 5%

Semi-Synthetic E 2.1 Semi-Synthetic 5%

Semi-Synthetic B 2.2 Semi-Synthetic 5%

Synthetic A 2.2 Synthetic 10%*

Semi-Synthetic H 3.1 Semi-Synthetic 5%

Semi-Synthetic G 3.2 Semi-Synthetic 5%

Page 31: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Sump & Machinability Data - DefinitionsNormal (rating of 1.0) is a control coolant

2% concentration of synthetic coolant (mainly rust inhibitor)

Machinability factor:

The expected tool life of standard tools beyond the normal control using standardtools, feed rates, metal removal rate, on the same CNC machine.

A rating of 1.0 equals 26 passes

Sump longevity factor:

Amount of time the coolant lasts in the test sump before emitting a .003 reading of hydrogen sulfide with a Draeger tube system. (Hydrogen sulfide is the rotten egg smell)

The average human can smell this gas at about .0015, so this is really stinky.

A rating of 1.0 equals 3.5 weeks

Page 32: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant Differences – Drag Out on Chips

32

Using Standard Coolant Drag-Out Test Process

Starting Ending

Chip Weight Chip WeightCoolant Manufacturer Coolant Type In Grams In Grams Delta

Neat Oil A A Straight Oil 5875 6305 430Neat Oil B B Straight Oil 5934 6341 407Soluble Oil A B Soluble Oil 5865 6172 307Soluble Oil B C Soluble Oil 5922 6224 302Soluble Oil C B Soluble Oil 5987 6264 277Soluble Oil D D Soluble Oil 5794 6045 251Semi-Synthetic A D Semi-Synthetic 5823 6068 245Semi-Synthetic B E Semi-Synthetic 5791 6033 242Semi-Synthetic C F Semi-Synthetic 5793 5997 204Semi-Synthetic D G Semi-Synthetic 5767 5953 186Semi-Synthetic E H Semi-Synthetic 5919 6097 178Semi-Synthetic F J Semi-Synthetic 5829 5988 159Semi-Synthetic G H Semi-Synthetic 5846 5962 116Semi-Synthetic H H Semi-Synthetic 5891 6001 110Synthetic A F Synthetic 5864 5972 108Synthetic B F Synthetic 5919 6023 104

Synthetic C K Synthetic 5694 5792 98

Page 33: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant/Lubricant Comparison

33

Coolant Machinability Sump Life Drag Out Cleaning ToxicologyWaste

Treatment FoamingBio-

Stability

Neat Oil A 5 1 1 1 3 4 4 1Neat Oil B 5 1 1 2 3 4 4 1Soluble Oil A 4 2 2 3 4 4 2 2Soluble Oil B 4 2 2 3 4 4 1 2Soluble Oil C 3 2 2 3 4 3 2 2Soluble Oil D 3 3 3 3 3 3 2 2Semi-Synthetic A 2 3 3 3 2 3 2 3Semi-Synthetic B 2 3 3 3 2 3 3 2Semi-Synthetic C 2 2 3 3 2 2 2 2Semi-Synthetic D 2 3 4 3 2 3 2 3Semi-Synthetic E 3 3 4 3 2 3 3 3Semi-Synthetic F 3 3 4 3 3 2 2 3Semi-Synthetic G 4 5 5 4 4 3 4 4Semi-Synthetic H 4 5 5 4 4 4 5 4Synthetic A 2 3 5 3 2 4 2 4Synthetic B 2 2 5 4 3 3 2 4Synthetic C 2 2 5 4 2 3 3 3

Coolants/Lubricants scored 1 – 5 based on performance. 5 is best

Page 34: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant/Lubricant Comparison

Coolants/Lubricants scored 1 – 5 based on performance. 5 is best

Coolant Machinability Sump Life Drag Out Cleaning ToxicologyWaste

Treatment FoamingBio-

Stability Total

Neat Oil A 5 1 1 1 3 4 4 1 20Neat Oil B 5 1 1 2 3 4 4 1 21Soluble Oil A 4 2 2 3 4 4 2 2 23Soluble Oil B 4 2 2 3 4 4 1 2 22Soluble Oil C 3 2 2 3 4 3 2 2 21Soluble Oil D 3 3 3 3 3 3 2 2 22Semi-Synthetic A 2 3 3 3 2 3 2 3 21Semi-Synthetic B 2 3 3 3 2 3 3 2 21Semi-Synthetic C 2 2 3 3 2 2 2 2 18Semi-Synthetic D 2 3 4 3 2 3 2 3 22Semi-Synthetic E 3 3 4 3 2 3 3 3 24Semi-Synthetic F 3 3 4 3 3 2 2 3 23Semi-Synthetic G 4 5 5 4 4 3 4 4 33Semi-Synthetic H 4 5 5 4 4 4 5 4 35Synthetic A 2 3 5 3 2 4 2 4 25Synthetic B 2 2 5 4 3 3 2 4 25Synthetic C 2 2 5 4 2 3 3 3 24

Page 35: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Coolant/Lubricant Comparison

Coolants/Lubricants scored 1 – 5 based on performance. 5 is best

Coolant Machinability Sump Life Drag Out Cleaning ToxicologyWaste

Treatment FoamingBio-

Stability Total

Semi-Synthetic H 4 5 5 4 4 4 5 4 35Semi-Synthetic G 4 5 5 4 4 3 4 4 33Synthetic A 2 3 5 3 2 4 2 4 25Synthetic B 2 2 5 4 3 3 2 4 25Semi-Synthetic E 3 3 4 3 2 3 3 3 24Synthetic C 2 2 5 4 2 3 3 3 24Soluble Oil A 4 2 2 3 4 4 2 2 23Semi-Synthetic F 3 3 4 3 3 2 2 3 23Soluble Oil B 4 2 2 3 4 4 1 2 22Soluble Oil D 3 3 3 3 3 3 2 2 22Semi-Synthetic D 2 3 4 3 2 3 2 3 22Neat Oil B 5 1 1 2 3 4 4 1 21Soluble Oil C 3 2 2 3 4 3 2 2 21Semi-Synthetic A 2 3 3 3 2 3 2 3 21Semi-Synthetic B 2 3 3 3 2 3 3 2 21Neat Oil A 5 1 1 1 3 4 4 1 20Semi-Synthetic C 2 2 3 3 2 2 2 2 18

Page 36: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Regulating Agency Perspective

36

• The goal and challenge for regulating agencies is to protect the people, environment and workers from hazards related to industrial manufacturing.

• They must balance the risks involved with chemicals and practices to protect and preserve our natural resources along with the impact to our industry.

“If…a chemical substance or mixture…presents or will present an unreasonable risk of injury to health or the environment, the Administrator shall by rule apply…requirements…to the extent necessary to protect adequately against such risk using the least burdensome requirements.” TSCA Sec. 6(a) 15 U.S.C. 2605

Page 37: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Regulating AgenciesIn the United States and Canada the four main agencies that regulate MWF’s are:

EPA – Environmental Protection AgencyOSHA – Occupational Safety and Health AdministrationNIOSH – The National Institute for Occupational Safety and Health OSH – Canadian Centre for Occupational Health and Safety

In addition, many states, counties and cities have implemented regional requirements and/or regulations.

For Example: Washington State - WISHA – Washington Industrial Safety & Health Act

DOSH – Division of Occupational Safety and Health

King County - DPH – Department of Public Health

Seattle - SDPH – Seattle Department of Public Health

Metalworking Fluid End Users & Suppliers must potentially adhere to 7 different agencies37

Page 38: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

RegulationsBusinesses and Industries that come into contact with MWFs are all impacted by various regulations:

MWFRaw Material MWF MWF MWF MWF Waste Haulers

Suppliers Formulators Transporters Distributors End-Users Disposers

OSHA Hazard Communication Standard (HCS) X X X X X X

DOT Hazardous Materials Transportation Act (HMTA) X X X X

EPA Toxic Substances Control Act (TSCA) X X

EPA Federal Insecticide, Fungicide and X XRodenticide Act (FIFRA)

EPA Emergency Planning and X X X X XCommunity Right-to-Know Act (EPCRA)

EPA Clean Air Act (CAA) X X

EPA Clean Water Act (CWA) X X

EPA Resource Conservation X X X X Xand Recovery Act (RCRA)

EPA Toxic Release Inventory (TRI) X X

Comprehensive Environmental ResponseCompensation, and Liability Act (CERCLA/Superfund) X 38

Page 39: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Chemicals Banned by EPA - TSCA

39

• Polychlorinated Biphenyls (PCBs) 1978• Fully Halogenated Chlorofluoroalkanes (aerosol sprays) 1978• Dioxin (about 75 chemicals of this class) 1980• Asbestos 1989• Hexavalent Chromium (Erin Brockovitch) carcinogen 1990

• Mixing Nitrites with: (metalworking fluids) 1984• Mixed mono and diamides of an organic acid• Triethanolamine salts of a substituted organic acid• Triethanolanime salt of tricarboxylic acid• Tricarboxylic acid

• Short Chained Chlorinated Paraffins 2004

• UNDER REVIEW• Medium & Long Chain Chlorinated Paraffins• Secondary Amines• Formaldehyde and Acetaldehyde

Page 40: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

OSHA Funded Metalworking Fluid Waste Reduction Manual - 2005

https://www.osha.gov/SLTC/metalworkingflids/metalworkingfluids_manual.html

40

Topics covered in Manual

• Health Effects• Engineering and Work Practice Controls• Personal Protective Equipment (PPE)• Establishing a MWF Management Program• Instituting An Exposure Monitoring Program• Medical Monitoring of Exposed Employees

Page 41: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Waste Treatment Perspective

41

• Most oils and/or additives in MWFs will eventually be treated and/orseparated from the water content.

• Many methods are used to accomplish this

• Some chemicals cannot be removed from water and are banned

• The end-user must comply with the EPA’s RCRA (Resource Conservation and Recovery Act)

• Many jurisdictions have discharge standards and regulations

Page 42: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Waste Treatment Perspective

42

• Sewer discharge standards restrict pH, “oil and grease”, solids, metals and other components. These standards vary from place to place but some typical effluent criteria are:

Parameter Sewer LimitCOD (Chemical Oxygen Demand) 500 ppmTSS (Total Suspended Solids) 250 ppm (max)pH 6.0 – 9.0Oil and Grease 10 – 100 ppm (max)Metals VariesOther Inorganic compounds Varies

Page 43: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Waste Treatment Perspective

43

Treatment Methods for metalworking fluids effluent:

• Physical Treatment • Evaporation is a standard method to remove the water from the mixed effluent. Either natural evaporation (which can take a long time) or elevated temperature evaporation (using a heater). Air discharge permits are required if using a heat evaporator.

• Membrane Separation is another method of separating the solids and oils from the effluent. Ultra-filtration and Reverse Osmosis are common methods using a membrane (usually less than 2 microns).

• Chemical Treatment• Using inorganic chemicals like aluminum sulfate or ferric chloride to “break” the emulsion between the oil and water. Once separated the oil naturally floats to the surface for skimming.

• Biological Treatment• Using natural occurring bacteria to consume the oily residue of spent metalworking fluids is a common secondary or tertiary method of reducing the contaminates left over from a chemical treatment. NOTE: very smelly

Page 44: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Waste Treatment Perspective

44

• The End-user is almost always impacted by the cost of treating waste MWF

• Reducing the frequency and volume of MWF changes is critical to lowering cost and impact to the waste stream.

• Use products that last longer and still give acceptable performance

• Waste treatment costs will continue to rise

• Elimination of harmful chemistry makes the job of the waste-treater easier

• Hundreds of waste treatment employees get sick or injured due to the toxicity

Page 45: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Market Trends:U.S. metalworking fluids market volume, by product, 2012 - 2022 (Kilo Tons)

source – grandviewresearch.com 45

Page 46: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Industry Insights Global metalworking fluids market size was USD 9.34 billion in 2014 and is expected to witness significant growth over the next seven years owing to increasing demand from the automobile sector in emerging economies including China and India.

The recovery of the automobile sector in the U.S. post the recession in 2008-09 is expected to augment growth over the forecast period. This has been a major factor for growth in North America, especially in the U.S., which has led to manufacturers increasing their production volumes and the region has improved its manufacturing output over the past few years.

Asia Pacific is the largest market owing to a robust manufacturing base in China and India. Strong government initiatives in China to support the manufacturing sector have led to a better production output, which is expected to have a positive impact on the industry.

Crude oil price volatility has impacted base oil price which is used to produce metalworking fluids. Base oil suppliers are at a competitive advantage owing to the oversupply of crude oil. This has resulted in improving their margins over the past couple of years.

Emerging economies including India, China, Brazil, Russia, and other Southeast Asian countries have been witnessing significant growth in the industrial manufacturing sector. Increasing production and exploration activities of crude oil in Asia Pacific, especially from Chinese petroleum companies, has been a major factor in influencing demand for the product in the region over the past few years.

source – grandviewresearch.com 46

Page 47: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Industry InsightsRegional InsightsAsia Pacific metalworking market accounted for over 40% of the global volume share in 2014. Positive outlook towards the manufacturing sector in China, Malaysia, and India in light of growing domestic consumption coupled with favorable regulations to attract investments is expected to augment expansion. Moreover, high consumption of metalworking fluids in the automotive sector is expected to promote demand over the forecast period.

North America market was USD 2.70 billion in 2014 and is expected to witness significant rise on account of high consumption of the product in the automobile sector in the U.S. Robust manufacturing base of automobile industry coupled with growing demand in Germany, and Russia is expected to augment demand in Europe over the forecast period.

47

Page 48: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Industry Insights

Product InsightsSemi-synthetic based products are expected to increase their penetration over the next seven years owing to their excellent machining capabilities. Captive consumption of the product by companies which are integrated across the value chain has contributed toward growth.

Mineral based metalworking fluids market exceeded USD 4.50 billion in 2014 on account of its low price and abundant availability. For instance, small and medium scale producers opt for mineral oil based products owing to their price sensitive customers.

Application InsightsNeat cutting oil accounted for 44.5% of the global volume in 2014. The market is expected to witness significant growth owing to its increasing demand from the automobile, aerospace, marine and defense sectors.

Water soluble cutting oils are the second largest segment accounting for 726.3 kilo tons in 2014. They are used in a concentrated form which has led to a rise in their penetration levels over the past few years. Also, adoption of new coolant cycling programs to improve lubrication system and machining process will fuel its demand over the forecast period.

48

Page 49: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

Summary

49

Each player in the Metalworking Fluids industry has a unique perspective

The MWF formulator is under constant pressure to produce products that enhance productivity for their customers. Regulations and changes in raw material availability will mean continuous change/improvement.

Regulating agencies are continuously monitoring the industry and the products or ingredients used in Metalworking Fluids. Their goal is to minimize or eliminate chemistry that is harmful to the environment or health of workers and citizens.

End users of Metalworking Fluids are continuously looking for products that will help them be more productive, lower costs and keep their workers and environment safe. Changes that are passed down from Raw Material manufacturers and in turn from Formulators can impact their productivity.

Waste Treatment companies and facilities face a constant battle to treat the waste from industrial effluent, much that comes from spent MWF. Reducing the volume and complexity of chemistry that flows their way will go a long way in making our environment and citizens safe.

Meaningful discussions amongst all four main players together has been fruitful in educating each about their unique situations and to help grow the industry together in harmony instead of as adversaries

Metalworking fluids are an asset. They enhance productivity and allow industry to provide products faster, cheaper and reduce waste.

Page 50: Brian K. Hovik · Semi-Synthetics Concentrate contains petroleum oil & water Diluted with water to form part solution & part emulsification working fluid (light milky color) Light

References

Metalworking Fluids, 2nd Editiion, Jerry P. Byers CRC Press 2006

Metalworking Fluids – Mechanisms and Performance, E. Brinkmeier, D. Meyer, A>G> Uesmann-Cordes, C. Herrmann Elsevier Publishing 2015

TLT Magazine STLE, February, 2016 EPA and Chlorinated Paraffins

EPA Premanufacture Notification TSCA review of Medium Chain & Long Chain Chlorinated Paraffins

Metalworking Fluids (MWFs) for Cutting and Grinding - Elsevier B.V 2016

Selecting the Perfect Metalworking Fluid, Tribology and Lubrication Technology Mag. March, 2009

http://www.techinsider.io/epa-only-restricts-9-chemicals-2016-2/#nitrites-mixed-with-p6-mixed-mono-and-diamides-of-an-organic-acidpp7-triethanolamine-salts-of-a-substituted-organic-acidpp8-triethanolanime-salt-of-tricarboxylic-acidpp9-tricarboxylic-acidp-6

50