biopulping asadi
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The use of enzymes in the pulp and paper industry wasintroduced in the 1986.
Cellulase, xylanase, laccase and lipase
Enzymes innovation fiber modification
Web of Science database ,CAPES portal from 1945 to July
2010 International Patent Classification (IPC)
C12N ,IP=(C12N*) TS=(enzyme and pulp or paper)
1048 documents
602 of the original 1048 documents were strictly related to the
use of enzymes in the processing of pulp and paper
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Xylanase prebleaching technology
8% of Canadas bleached kraft pulp (830,000 tonnes) in 1994
In Scandinavia , 9 mills using xylanase in 1999
In 2002 , 20 mills using xylanase in North America Nissen et al. (1992) xylanases , pH adjustment of pulp from pH 1011 to
68
extremophilic bacteria
Tolan et. al. (1995) enzymes to be more resilient to pH temperatureconditions, for greater delignification
Van der Burgt (2002) xylanase ,more effective
Nagar et al., 2010; Azeri et al., 2010; Bai et al. 2010; Zhang et al., 2010;Kaur and Mahajan, 2011; Joshi and Khare, 2011; Mishra and Thakur, 2011
, more thermostable and highly pH-adaptable
recombinant DNA
mutagenesis
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Biopulping
Fungi as a pretreatment prior to refining
Treatment of wood chips or other lignocellulosicraw materials
White-rot fungi
Improve cooking liquor penetration
lower refining energy requirement
higher strength two-week fungal treatments suggested , wood
weight loss is only 2%
h h h i
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Phanerochaete chrysosporium
Ceriporiopsis subvermispora
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Enzymatic pathways associated with lignin and cellulose degradation by
Phanerochaete chrysosporium. (1) glyoxal oxidase, (2) lignin peroxidase,
(3) manganese peroxidase, (4) laccase, (5) cellobiose dehydrogenase, (6) cellobiose:
quinone oxidoreductase, (7) protease (8) lactonase, (9) endo-1,4--glucanase, (10) exo-
1,4--glucanase, (11) 1,4---glucosidase, (12) glucose-1-oxidase, (13) catalase.
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LigninLignin peroxidaseperoxidase
ManganeseManganese peroxidaseperoxidase
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Ceriporiopsis subvermispora
laccase and Mn-peroxidase Phanerochaete chrysosporium lignin peroxidase (LiP) nonphenolic lignin by , -cleavage Mn-peroxidase , catalyze
selectively delignifying fungi , colonize wood via the raycells uranyl acetate , acidic groups lumen to within the secondary wall easier penetration of the ions into the fiber wall decreased UV for lignin of middle lamellae and
secondary walls
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proteins of defined size
Insulin (5,700 Da) Myoglobin (17,600 Da)
Ovalbumin (44,287 Da)
chelated Mn(III),direct product of Mn-peroxidaseaction
Biodegradation of wood polysaccharides
nonligninolytic fungus,Ophiostoma piliferum, knowncommercially as the Cartapip process
increases the rate of diffusion of NaOH into the wood USDA Forest Products Laboratory in Madison,
Wisconsin
Yadav et all biopulping and its
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Yadav et all, biopulping and its
potential to reduce effluent loads from
bleaching of hardwood Kraft pulp
Ceriporiopsis subvermispora 4.8%
4.7% 32.6% COD 41.5% BOD
12% AOX (organohalogens)
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Albino Fungal Effects on TMP and
Dissolving Pulp Mill OperationsHydrocarbons, Fatty acids, Resin acids, Steroidhydrocarbons, Sterols, Steroid ketones ,
Squalene, -Tocopherol , Sterol esters &triglycerides
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Application of thermoalkalophilic xylanase from Arthrobacter sp.
MTCC 5214 in biobleaching of kraft pulp
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Hydrolysis of different chain length xylooliogmers by
cellulase and hemicellulase
Production and partial purification of xylanase from
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Production and partial purification of xylanase from
a new thermophilic isolate
Xylitol production via catalytic hydrogenation
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Xylitol production via catalytic hydrogenation
of sugarcane bagasse dissolving pulp liquid
effluents over Ru/C catalyst
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Enzymatic grafting of simple phenols on flax and sisal pulp fibres
using laccases
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Wood and Cellulose Conference
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Wood and Cellulose Conference
April 9-11, 2000
Syracuse, New York, USA
Chemicals and Biofuels from Hardwood, Fuel Crops and
Agricultural Wastes Expression of white-rot fungi manganese peroxidase
(MnP) in the yeast Pichia pastoris
Site-Directed Mutagenesis ofThermobifida Fusca
Cellulases Cel6A and Cel6B The Biofine Technology: Thermochemical Conversion of
Cellulosic Biomass to Fuels and Chemicals
Improved Cellulases for Bioethanol Production
Laccase Enhancements in Lignocellulosic Biotechnologies
Enhancing Mechanical Pulping with Fungal Pretreatmentin the Wood Yard
Mechanisms in Cellulose Biosynthesis
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PratimaPratima BAJPAI , BIOTECHNOLOGY FOR PULP AND PAPER PROCESSING , SPRINGERBAJPAI , BIOTECHNOLOGY FOR PULP AND PAPER PROCESSING , SPRINGER
20122012
AndrAndr Ferraz,AnaFerraz,Ana MM CCrdovardova, Angela, Angela MachucaMachuca; Wood biodegradation and enzyme production by; Wood biodegradation and enzyme production byCeriporiopsissubvermisporaCeriporiopsissubvermispora during solidduring solid--state fermentation of Eucalyptusstate fermentation of Eucalyptus grandisgrandis
BrazBraz J.J. DemunerDemuner,, NeiNei Pereira Junior, Adelaide M.S.Pereira Junior, Adelaide M.S. AntunesAntunes, Technology Prospecting on Enzymes, Technology Prospecting on Enzymesfor the Pulp and Paper Industryfor the Pulp and Paper Industry
I. D. Reid, R. Bourbonnais, and M. G. Paice , Biopulping and Biobleaching Lignin & lignans 2010Taylor and Francis Group
Yadav et al, biopulping and its potential to reduce effluent loads from bleaching of hardwood Kraftpulp
Dinesh Kumar,et al, Production and partial purification of xylanase from a new thermophilic isolate
HM Baudel, CAM de Abreu and CZ Zaror ,Xylitol production via catalytic hydrogenation ofsugarcane bagasse dissolving pulp liquid effluents over Ru/C catalyst
Elisabetta Aracri et al, Enzymatic grafting of simple phenols on flax and sisal pulp fibres using
laccases Roberta L Farrell,et al, Albino Fungal Effects on TMP and Dissolving Pulp Mill Operations
Rakhee Khandeparkar, Narayan B. Bhosle , Application of thermoalkalophilic xylanase fromArthrobacter sp. MTCC 5214 in biobleaching of kraft pulp
Qing Qing, Charles E. Wyman , Hydrolysis of different chain length xylooliogmers by cellulase andhemicellulase
BRIAN VAN DRIESSEL, BIOREMEDIATION OF A BLEACH PLANT EFFLUENT FROM THEPULP AND PAPER INDUSTRY
http://http://en.wikipedia.org/wiki/Lignin_peroxidaseen.wikipedia.org/wiki/Lignin_peroxidase
http://microbewiki.kenyon.edu/index.php/Phanerochaete_chrysosporhttp://microbewiki.kenyon.edu/index.php/Phanerochaete_chrysosporiumium
http://http://www.micron.ac.uk/organisms/csu.htmlwww.micron.ac.uk/organisms/csu.html
http://http://www.jgi.doe.gov/sequencing/why/csubvermispora.htmlwww.jgi.doe.gov/sequencing/why/csubvermispora.html
http://http://en.wikipedia.org/wiki/Manganese_peroxidaseen.wikipedia.org/wiki/Manganese_peroxidase
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