biopulping asadi

Upload: rouzbeh-asadi-khansari

Post on 04-Apr-2018

219 views

Category:

Documents


0 download

TRANSCRIPT

  • 7/30/2019 Biopulping Asadi

    1/27

  • 7/30/2019 Biopulping Asadi

    2/27

    The use of enzymes in the pulp and paper industry wasintroduced in the 1986.

    Cellulase, xylanase, laccase and lipase

    Enzymes innovation fiber modification

    Web of Science database ,CAPES portal from 1945 to July

    2010 International Patent Classification (IPC)

    C12N ,IP=(C12N*) TS=(enzyme and pulp or paper)

    1048 documents

    602 of the original 1048 documents were strictly related to the

    use of enzymes in the processing of pulp and paper

  • 7/30/2019 Biopulping Asadi

    3/27

  • 7/30/2019 Biopulping Asadi

    4/27

  • 7/30/2019 Biopulping Asadi

    5/27

  • 7/30/2019 Biopulping Asadi

    6/27

  • 7/30/2019 Biopulping Asadi

    7/27

    Xylanase prebleaching technology

    8% of Canadas bleached kraft pulp (830,000 tonnes) in 1994

    In Scandinavia , 9 mills using xylanase in 1999

    In 2002 , 20 mills using xylanase in North America Nissen et al. (1992) xylanases , pH adjustment of pulp from pH 1011 to

    68

    extremophilic bacteria

    Tolan et. al. (1995) enzymes to be more resilient to pH temperatureconditions, for greater delignification

    Van der Burgt (2002) xylanase ,more effective

    Nagar et al., 2010; Azeri et al., 2010; Bai et al. 2010; Zhang et al., 2010;Kaur and Mahajan, 2011; Joshi and Khare, 2011; Mishra and Thakur, 2011

    , more thermostable and highly pH-adaptable

    recombinant DNA

    mutagenesis

  • 7/30/2019 Biopulping Asadi

    8/27

    Biopulping

    Fungi as a pretreatment prior to refining

    Treatment of wood chips or other lignocellulosicraw materials

    White-rot fungi

    Improve cooking liquor penetration

    lower refining energy requirement

    higher strength two-week fungal treatments suggested , wood

    weight loss is only 2%

    h h h i

  • 7/30/2019 Biopulping Asadi

    9/27

    Phanerochaete chrysosporium

    Ceriporiopsis subvermispora

  • 7/30/2019 Biopulping Asadi

    10/27

    Enzymatic pathways associated with lignin and cellulose degradation by

    Phanerochaete chrysosporium. (1) glyoxal oxidase, (2) lignin peroxidase,

    (3) manganese peroxidase, (4) laccase, (5) cellobiose dehydrogenase, (6) cellobiose:

    quinone oxidoreductase, (7) protease (8) lactonase, (9) endo-1,4--glucanase, (10) exo-

    1,4--glucanase, (11) 1,4---glucosidase, (12) glucose-1-oxidase, (13) catalase.

  • 7/30/2019 Biopulping Asadi

    11/27

    LigninLignin peroxidaseperoxidase

    ManganeseManganese peroxidaseperoxidase

  • 7/30/2019 Biopulping Asadi

    12/27

    Ceriporiopsis subvermispora

    laccase and Mn-peroxidase Phanerochaete chrysosporium lignin peroxidase (LiP) nonphenolic lignin by , -cleavage Mn-peroxidase , catalyze

    selectively delignifying fungi , colonize wood via the raycells uranyl acetate , acidic groups lumen to within the secondary wall easier penetration of the ions into the fiber wall decreased UV for lignin of middle lamellae and

    secondary walls

  • 7/30/2019 Biopulping Asadi

    13/27

  • 7/30/2019 Biopulping Asadi

    14/27

    proteins of defined size

    Insulin (5,700 Da) Myoglobin (17,600 Da)

    Ovalbumin (44,287 Da)

    chelated Mn(III),direct product of Mn-peroxidaseaction

    Biodegradation of wood polysaccharides

    nonligninolytic fungus,Ophiostoma piliferum, knowncommercially as the Cartapip process

    increases the rate of diffusion of NaOH into the wood USDA Forest Products Laboratory in Madison,

    Wisconsin

    Yadav et all biopulping and its

  • 7/30/2019 Biopulping Asadi

    15/27

    Yadav et all, biopulping and its

    potential to reduce effluent loads from

    bleaching of hardwood Kraft pulp

    Ceriporiopsis subvermispora 4.8%

    4.7% 32.6% COD 41.5% BOD

    12% AOX (organohalogens)

  • 7/30/2019 Biopulping Asadi

    16/27

    Albino Fungal Effects on TMP and

    Dissolving Pulp Mill OperationsHydrocarbons, Fatty acids, Resin acids, Steroidhydrocarbons, Sterols, Steroid ketones ,

    Squalene, -Tocopherol , Sterol esters &triglycerides

  • 7/30/2019 Biopulping Asadi

    17/27

    Application of thermoalkalophilic xylanase from Arthrobacter sp.

    MTCC 5214 in biobleaching of kraft pulp

  • 7/30/2019 Biopulping Asadi

    18/27

    Hydrolysis of different chain length xylooliogmers by

    cellulase and hemicellulase

    Production and partial purification of xylanase from

  • 7/30/2019 Biopulping Asadi

    19/27

    Production and partial purification of xylanase from

    a new thermophilic isolate

    Xylitol production via catalytic hydrogenation

  • 7/30/2019 Biopulping Asadi

    20/27

    Xylitol production via catalytic hydrogenation

    of sugarcane bagasse dissolving pulp liquid

    effluents over Ru/C catalyst

  • 7/30/2019 Biopulping Asadi

    21/27

    Enzymatic grafting of simple phenols on flax and sisal pulp fibres

    using laccases

  • 7/30/2019 Biopulping Asadi

    22/27

  • 7/30/2019 Biopulping Asadi

    23/27

  • 7/30/2019 Biopulping Asadi

    24/27

    Wood and Cellulose Conference

  • 7/30/2019 Biopulping Asadi

    25/27

    Wood and Cellulose Conference

    April 9-11, 2000

    Syracuse, New York, USA

    Chemicals and Biofuels from Hardwood, Fuel Crops and

    Agricultural Wastes Expression of white-rot fungi manganese peroxidase

    (MnP) in the yeast Pichia pastoris

    Site-Directed Mutagenesis ofThermobifida Fusca

    Cellulases Cel6A and Cel6B The Biofine Technology: Thermochemical Conversion of

    Cellulosic Biomass to Fuels and Chemicals

    Improved Cellulases for Bioethanol Production

    Laccase Enhancements in Lignocellulosic Biotechnologies

    Enhancing Mechanical Pulping with Fungal Pretreatmentin the Wood Yard

    Mechanisms in Cellulose Biosynthesis

  • 7/30/2019 Biopulping Asadi

    26/27

    PratimaPratima BAJPAI , BIOTECHNOLOGY FOR PULP AND PAPER PROCESSING , SPRINGERBAJPAI , BIOTECHNOLOGY FOR PULP AND PAPER PROCESSING , SPRINGER

    20122012

    AndrAndr Ferraz,AnaFerraz,Ana MM CCrdovardova, Angela, Angela MachucaMachuca; Wood biodegradation and enzyme production by; Wood biodegradation and enzyme production byCeriporiopsissubvermisporaCeriporiopsissubvermispora during solidduring solid--state fermentation of Eucalyptusstate fermentation of Eucalyptus grandisgrandis

    BrazBraz J.J. DemunerDemuner,, NeiNei Pereira Junior, Adelaide M.S.Pereira Junior, Adelaide M.S. AntunesAntunes, Technology Prospecting on Enzymes, Technology Prospecting on Enzymesfor the Pulp and Paper Industryfor the Pulp and Paper Industry

    I. D. Reid, R. Bourbonnais, and M. G. Paice , Biopulping and Biobleaching Lignin & lignans 2010Taylor and Francis Group

    Yadav et al, biopulping and its potential to reduce effluent loads from bleaching of hardwood Kraftpulp

    Dinesh Kumar,et al, Production and partial purification of xylanase from a new thermophilic isolate

    HM Baudel, CAM de Abreu and CZ Zaror ,Xylitol production via catalytic hydrogenation ofsugarcane bagasse dissolving pulp liquid effluents over Ru/C catalyst

    Elisabetta Aracri et al, Enzymatic grafting of simple phenols on flax and sisal pulp fibres using

    laccases Roberta L Farrell,et al, Albino Fungal Effects on TMP and Dissolving Pulp Mill Operations

    Rakhee Khandeparkar, Narayan B. Bhosle , Application of thermoalkalophilic xylanase fromArthrobacter sp. MTCC 5214 in biobleaching of kraft pulp

    Qing Qing, Charles E. Wyman , Hydrolysis of different chain length xylooliogmers by cellulase andhemicellulase

    BRIAN VAN DRIESSEL, BIOREMEDIATION OF A BLEACH PLANT EFFLUENT FROM THEPULP AND PAPER INDUSTRY

    http://http://en.wikipedia.org/wiki/Lignin_peroxidaseen.wikipedia.org/wiki/Lignin_peroxidase

    http://microbewiki.kenyon.edu/index.php/Phanerochaete_chrysosporhttp://microbewiki.kenyon.edu/index.php/Phanerochaete_chrysosporiumium

    http://http://www.micron.ac.uk/organisms/csu.htmlwww.micron.ac.uk/organisms/csu.html

    http://http://www.jgi.doe.gov/sequencing/why/csubvermispora.htmlwww.jgi.doe.gov/sequencing/why/csubvermispora.html

    http://http://en.wikipedia.org/wiki/Manganese_peroxidaseen.wikipedia.org/wiki/Manganese_peroxidase

  • 7/30/2019 Biopulping Asadi

    27/27