BIOMASS ENERGYBIOMASS ENERGY

Biomass consists of all living plant matter as well as Biomass consists of all living plant matter as well as organic wastes derived from plants, humans, marine organic wastes derived from plants, humans, marine life, and animals.life, and animals.In addition trees, grasses, animal dung, as well as In addition trees, grasses, animal dung, as well as sewage, garbage wood construction residues and other sewage, garbage wood construction residues and other components of municipal waste are all examples of components of municipal waste are all examples of biomass biomass

Biomass energy is the first form of energy exploited by man. Biomass is the natural energy for conversion of solar energy to high-energy content products that can be stored transported, and used conveniently.

CHARACTERISTICS OF BIOMASSCHARACTERISTICS OF BIOMASS

• Biomass energy is a renewable• Connected to farming -economics • Multiuse – food, shelter, energy, materials • Environmental concerns include land and water use, fertilizer and

other nutrient requirements • Naturally diffuse and distributed – harvesting and transport and

distribution are important

SOURCE OF BIOMASS ENERGYSOURCE OF BIOMASS ENERGYThe main source of biomass energy is from the sun. Plants grow by the process of photosynthesis in which sunlight transforms two abundant raw materials, water and carbon dioxide, to carbohydrates and other complex organic compounds of great natural and commercial value. The reaction is shown below:

– Average solar incidence is about 4000 W/m2/day– Biomass capture efficiency is ~ 1% – Thin film photovoltaic efficiency is ~ 10%

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The process is intermediate in the formation of glucose/sucrose, cellulose polymers, fuel for plant respiration, or variety of other compounds depicted in the figure below:

RENEWABILITY INDICES AND BIOMASS RENEWABILITY INDICES AND BIOMASS RESOURCESRESOURCES

Semi quantitative measure of the rate of regeneration was proposed by Paul Weisz (1978)

Since biomass is considered as a renewable there is the need to estimate how rapidly it is regenerated in quantities that are useful to humans.

His idea compared the time for regeneration of commercially meaningful quantity of the resource quantity of the resource under scrutiny, Tr to a time at which the resource will be beneficial to mankind Tu

RENEWABILITY INDICES AND RENEWABILITY INDICES AND BIOMASS RESOURCES CONT.BIOMASS RESOURCES CONT.

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Table 10.1 Selected Dimensionless Time Constant Related to the Renewability of Biomass

RENEWABILITY INDICES AND RENEWABILITY INDICES AND BIOMASS RESOURCES CONT.BIOMASS RESOURCES CONT.

BIOMASS RELEVANCE TO ENERGY BIOMASS RELEVANCE TO ENERGY PRODUCTIONPRODUCTION

• BIOMASS UTILIZATION• Figure 10.2 Explain the biological and thermal routes of biomass energy

conversion

ADVANTAGES AND DISADVANTAGESADVANTAGES AND DISADVANTAGES

• Advantages– It is renewable and domestic available– Its disperse nature leverages its potential impact by

enabling it to function as a distributed energy source.– Biomass derived products can substitutes those of plastics

and metalic products which require abundance of energy.– Its use as a source of energy offers another major benefit

to sustainability namely a pathway to manage municipal and agricultural waste.

– It has the potential to combat the atmospheric buildup of the greenhouse gas CO2

– It act as a feedstock and has lower sulfur content

ADVANTAGES AND DISADVANTAGESADVANTAGES AND DISADVANTAGES

• Disadvantages– It has low energy content compared to coal and petroleum derived fuels– Intensive cultivation may stress water resource and deplete soil nutrients– The wide dispersion of biomass combined with the low intensity of

production per unit land areas are serious disadvantages when there is a need to supply huge amounts of energy to a small area.

– It has high cost of transportation

US BIOMASS RESOURCESUS BIOMASS RESOURCES

Estimated Potential Production Rates of Estimated Potential Production Rates of Biomass for Energy in 2050 Biomass for Energy in 2050

• Table 10.2

Estimated Residual Biomass for the USEstimated Residual Biomass for the US

• Table 10.3

Selected Properties of Biomass Selected Properties of Biomass Relevant to its Use as a FuelRelevant to its Use as a Fuel

• Table 10.4

Trace Element Emissions from Wood-Trace Element Emissions from Wood-Fired BoilerFired Boiler

• Table 10.5

THERMAL CONVESION OF BIOMASSTHERMAL CONVESION OF BIOMASS• Biomass to Electricity

– Co-firing with coal to reduce sulfur emissions and smooth a transition to reduced fossil dependency

– Repowering (ie is backlifting an existing generating station to switch to biomass fuel, or add a biomass-fired generator to an existing fossil fueled unit)

– Direct combustion in a Rankine cycle to raise steam to operate a turbine generator

– Various configurations of combined cycles in which the biomass is first gasified and the gas then combusted to generate steam or, in a gas turbine, to provide motive power with the option for extracting additional electricity from the waste heat

– Thermal of hydrothermal conversion of the biomass to other fuels that, after substantial cleaning, are combusted to generate steam or motive power, or fed to a fuel cell for direct conversion to electricity

BIOMASS TO FUELSBIOMASS TO FUELS

Bioethanol in the United StatesBioethanol from Corn

• Corn grain is the feedstock – with a current capacity of ~144 M dry tons – equivalent to 10 – 14 B gallons of ethanol – ~10% of U.S. fuel consumption

Current ethanol production is ~2 B gallons • Liquid fuel additive/replacement – environmentally friendly oxygenate – fuel flexible cars can use blends up to 85% ethanol Subsidized heavily to make it competitive with gasoline

PRESENT TECHNOLOGY FOR PRODUCTION OF PRESENT TECHNOLOGY FOR PRODUCTION OF BIOETHANOL FROM GRAIN CORN FEEDSTOCKBIOETHANOL FROM GRAIN CORN FEEDSTOCK

TRANSIONING TO BIOREFINERIESTRANSIONING TO BIOREFINERIES

BIOMASS TO ELECTRICITYBIOMASS TO ELECTRICITY EXAMPLE OF US INSTALLED CAPACITY

CHALLENGES TO BIOMASS BASED CHALLENGES TO BIOMASS BASED ELECTRICITY PRODUCTIONELECTRICITY PRODUCTION

• Low heat to power efficiency of combustion steam turbines – 18-24% (14,000-19,000 Btu/kWh)

• Alkali and other trace metal deposits and emissions

• Particulate Deposits and Emissions

• NOx Emissions

• Cost of Electricity – $0.065 – 0.08/kWh

• Lower Energy Density

– Oxygen = 30-45 wt % dry basis

• Use of Land, Water, Nutrients • Displacement of Higher Value Crops

BIOCONVERSIONBIOCONVERSIONBioconversion or biochemical processing refers to the direct or adaptive use of the chemistry of living things to transform one substance to another eg. Fermentation

BIOGAS~ 50%vol CH4, 50%vol CO2

– From Anaerobic Digestion of wet Biomass – Animal, Human Wastes – Sewage Sludge – Crop Residues

• By-Products: Nitrogen-rich Sludge (Fertilizer) and Fewer Pathogens

• Extensive Use in India and China (Millions of Digesters); Industrialized Countries (Stockyards, Municipal Sewage, ~5000 Digesters)

• Major Goals – Environmental Neutralization of Waste – Fertilizer From Waste

BIOGAS FROM ANAEROBIC DIGESTIONBIOGAS FROM ANAEROBIC DIGESTION

• Gas Production Rate– 0.2 Nm3/m3/day Floating or Fixed Cover Digesters

(Villages: China, India)– 4-8 Nm3/m3/day industrial Scale Technology (Dilute

Industrial, Municipal Wastes)

• Estimated Costs of Biogas $/million Btu– Household 11.6

– Village 5.8

– Industrial 0.7-1.1

OVERALL PROCESS CHEMISTRY FOR PRODUCTION OVERALL PROCESS CHEMISTRY FOR PRODUCTION OF BISGAS BY ANAEROBIC DIGESTION OF WET OF BISGAS BY ANAEROBIC DIGESTION OF WET

BIOMASSBIOMASS

COMPLEX ORGANIC MATTER

SHORT CHAIN ACIDSALCOHOLS, H2 etc.

CH4 CO2 MINERAL AND NITROGEN-RICH EFFLUENT SLURY

Bacteria that promote fermentation and acetic acid fermentation

Bacteria that promote methane formation

• 35-55ºC• Process Variables: pH, feed-rate & C/N ratio, solids residence

time (SRT), hydraulic residence time (HRT), stirring • Simple technologies SRT and HRT of order weeks

FIXED DOME SMALL SCALE ANAEROBIC FIXED DOME SMALL SCALE ANAEROBIC DIGESTERDIGESTER

• FIGURE 10.7

FLOATING COVER SMALL SCALE ANAEROBIC FLOATING COVER SMALL SCALE ANAEROBIC DIGESTERDIGESTER

• FIGURE 10.8

POTENTIAL ADVERSE ENVIRONMENTAL IMPACTS OF POTENTIAL ADVERSE ENVIRONMENTAL IMPACTS OF BIOMASS PRODUCTION AND UTILIZATION FOR BIOMASS PRODUCTION AND UTILIZATION FOR

ENERGYENERGY

OPPORTUNITIES FOR BIOMASSOPPORTUNITIES FOR BIOMASS

• Reducing Greenhouse Gas CO2

• Restoring Forest Resources

• Renewable Carbon Source for Energy Future Dominated by Non-Carbon Based Electricity, e.g. Nuclear, Geothermal, and Solar. Biomass Becomes Significant Raw Material for:

– Liquid Hydrocarbon Fuels–Chemicals– Other High Value Products