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    MACROMOLECULES1.2 WATER

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    WATER:

    The molecule that supports life

    •  Water is the biological medium on Earth

    •   All   living organisms   require water more than

    any other substance

    •  Most cells are surrounded by water, and cellsthemselves are about 70 –95% water 

    •   The abundance of water is the main reason the

    Earth is habitable.

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    WATER:

    The molecule that supports life

    •   Water is the only common substance to exist in

    the natural environment in all 3 physical states

    of matter:

    •Solid   ice•Liquid

    •Gas   vapour 

    •   Molecules of water participate in many chemicalreactions necessary to sustain life.

    e.g.: hydrolysis of ATP to release energy

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    The Polarity of Water 

    Water’s structure :

    •  Shape like a wide V

    •   2 hydrogen  atoms   joined to   the  oxygen  atom

    by single covalent bonds.

    •  Water is a polar molecule.

    •   The 2 ends of water molecule have

    opposite charges.•The oxygen region has a partial negative charge (2δ-)

    •The hydrogens region have a partial positive charge (δ-)

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    The Polarity of Water 

    Significances features:

    •  Polarity allows water molecules to

    form hydrogen bonds  with each

    other.•   Water is a versatile solvent due to

    its polarity, which allows it to form

    hydrogen bonds easily.

    •   When an ionic compound isdissolved in water, each ion is

    surrounded by a sphere of water 

    molecules called a   hydration

    shell.

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    The Polarity of Water 

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    Properties of Water 

    • Four of water’s properties that facilitate

    an environment for life are:

    1. Cohesive behavior 

    2. Moderation of temperature

    3. Floating of ice on liquid water 

    4. Solvent of life

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    1. Cohesive behavior 

    •   Water molecules form   hydrogen bonds   withother water molecules.

    •   This makes water molecules tend to   stick or 

    stay close together.•  This is called COHESION.

    ADHESION: 

    •   The attraction between   different   kind of 

    molecules.

    •  Example: between water and plant cell walls

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    •   Cohesion helps:

    a. The transport of water & dissolved

    nutrients against gravity in plants.

    •   As water evaporates from leaves,

    •   the unbroken column of water held bycohesive forces within the xylem vessels

    are drawn upwards to the top of trees.

    •   Adhesion of water to the xylemwall;

    •   will resists the downwards pull of gravity.

    1. Cohesive behavior 

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    b. Surface tension,

    •   a measure of how difficult it is to break the surface of a

    liquid. Water has a greater surface tension than other liquids.

    •   This is due to an ordered arrangement of water 

    molecules, hydrogen-bonded to one another and to thewater molecules below.

    1. Cohesive behavior 

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    The high

    surface tension

    of water,

    • allows the

    water strider to

    walk on the

    surface of apond.

    1. Cohesive behavior 

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    2. Moderation of Temperature

    Water’s

    properties:

    Highspecific

    heat

    High heat of

    vaporization

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    2. Moderation of Temperature

    Water moderates air temperature by:

    - absorbing heat from warmer air and

    - releasing the stored heat to cooler air.

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    a. High specific heat:

    •   water can absorbed or release a   relatively large

    amount of  heat  with only  a slight change   in its  own

    temperature.

    2. Moderation of Temperature

    a. Water b. Ethyl alcohol

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    Large bodies of water (e.g. oceans, seas & lakes) have a

    thermally stable environment for aquatic organisms.

     –  Water acts as thermal buffer & prevents large fluctuations in

    body temperature of terrestrial organisms   (enzymes to

    function optimally ).

    2. Moderation of Temperature

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    2. Moderation of Temperature

    b. High heat of vaporization:

     – Heat a liquid must absorb for 1 g to be converted

    to gas

     – As a liquid evaporates, its remaining surfacecools, a process called evaporative cooling

     – Evaporative cooling of water helps   stabilize

    temperatures   in organisms surface and bodies

    of water.

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    • Water’s property:- Lower density of ice

    •   As water cools,

    •   the movement of water molecules slow down

    •   the molecules are farther apart.

    3. Floating of ice on liquid water 

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    3. Floating of ice on liquid water 

    •  Water expands as it freezes

    and the ice is less dense

    than liquid water.

    •   Water reaches its  greatestdensity at 4°C.

    •   If ice sank, all bodies of 

    water would eventually

    freeze solid, making lifeimpossible on Earth

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    3. Floating of ice on liquid water 

    •   At 0ºC & below,•   ice is formed & floats on the surface of water forming a

    insulating layer.

    •   This prevents water from freezing in lower depths.

    •   Therefore aquatic organisms in ponds & lakes can survive inliquid water during winter months.

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    4. Solvent of life

    • Water’s property:

    - Polar molecule

    •   Water can also dissolve

    compounds made of nonionicpolar molecules;

    e.g. sugar (water-soluble)

    •   Large polar molecules such as

    proteins can dissolve in water if they have ionic and polar 

    regions on their surface.

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    4. Solvent of life

    •  Solution :

    • a liquid that is a homogeneous mixture of 2 or

    more substances.

    •  Solvent :

    • the dissolving agent of a solution.

    •   Solute

    • A substance that is dissolved in a solution.•  Aqueous solution

    • in which water is the solvent.

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    4. Solvent of life

    •   A   hydrophilic   substance is one that has an

    affinity for water.

    Example: alcohol 

    •   A hydrophobic substance is one that does nothave an affinity for water.

    Example: Oil   molecules are hydrophobic

    because they have relatively nonpolar 

    bonds.

    •   A colloid is a stable suspension of fine particles

    in a liquid