barrier paper - mitsubishi paper mills€¦ · disposal for the application of many different...
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HiTec Paper.
www.mitsubishi-paper.com
Barrier Paperfor Food Packaging
2
Quality paper is the foundation. Incomparable added value is created by excellent coating. This is our passion: First class HiTec Paper.
Mitsubishi HiTec Paper Passion for First Class HiTec Papers
As a leading international supplier of direct thermal, inkjet, carbonless, label and barrier papers,
we produce first class coated speciality papers for many applications and printing technologies.
Our HiTec papers combine decades of know-how with state-of-the-art coating technology and
professional converting equipment.
The responsible handling of resources is particularly important to us. We manufacture
in the framework of an integrated management system (DIN EN ISO 9001, 14001 and
50001 as well as DIN EN 15593). Our locations in Bielefeld and Flensburg are FSC®
and PEFC™ certified.
We are a flexible medium sized enterprise within the international Mitsubishi
Group. Consistent research and development is the foundation for great
innovation. We develop individual, customized solutions for our customers.
We offer the best global sales network and technical service to our
customers all over the world.
› Huge experience and competence in paper making
› State-of-the-art coating technologies and formulations
› German-Japanese Research & Development
› Wide range of products
› Excellent Technical Service
› Worldwide Sales Network
› High innovative power
› Made in Germany
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Potential threats for foodstuff
water vapour
oxygen
grease /oil
aroma
mineral oils
foodstuff
Curtain coater technology
nozzle
curtain
paper web
B A R R I E R PA P E R
B A R R I E R PA P E R
Protected.Foods, consumers and the environment sustainably protected
In the food industry, packaging is no longer
just about the protection of foods, its storage
or the smooth transport. The focus is on to-
pics such as waste prevention, replacement
of plastic packaging as well as using more
sustainable materials.
In short: innovative solutions that, in addition
to the effi cient protection of packaged
goods, also take into account aspects such
as environmental responsibility and sustain-
ability. Solutions that protect consumers
and the environment. Solutions, such as
our barricote barrier papers for fl exible food
packaging.
As a sustainable high-tech material, paper is
the ideal basis for many food packaging.
At Mitsubishi HiTec Paper, we use renewable
raw materials that are not in competition
with food production. Whether as primary
or secondary packaging - all barricote
products are fully recyclable and therefore
ideally suited for the circular economy.
Environmentally friendly, sustainable and
safe.
Innovations such as barricote are possible
because of our many years of experience in
coating various speciality papers. We have
six different coating technologies at our
disposal for the application of many different
functional, protective and barrier coatings,
including multiple and double-sided coatings.
Our curtain coater technology enables us to
apply coatings in an extremely uniform and
highly effective way, safely and accurately.
AT A GLANCE:
All barricote barrier papers are characteri-
zed by the following features:
› Paper products made from virgin fibers
› Water-based coatings for combinable
barrier functions against
• water vapour
• grease / oil
• oxygen / aroma
• mineral oil migration
› 100 % free of
• plastic films, aluminum, extruded
polymers, varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable
ingredients
› Fully recyclable
› Reverse side offset and flexo printable
Applications: food and non-food packaging
Zusätzlich
Certifi cations
All barricote barrier papers feature
the following certifications:
› direct food contact (e. g. BfR XXXVI)
› ISO 9001, ISO 14001, ISO 50001
› INREKA DIN EN 15593
› FSC® Mix or PEFC™
fullyrecyclable
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B A G W GB A G W G / B A G W G O M
barricote BAG Heat-sealed bags – food permanently protected
Our barrier paper barricote BAG WG* offers an excellent combined barrier against grease and oil as well
as against water vapour. In addition, BAG WGOM** with its oxygen and aroma barrier ensures a long shelf
life of the packaged food. The integrated barrier against mineral oil migration reliably protects against MOSH
/ MOAH impurities - the migration is below current legislation on the protection of packaged food. Another
feature of this particularly universal barrier paper is the certified seawater decomposability.
Due to the very good heat-sealability, both papers are particularly suitable for bag packaging and are intelli-
gent alternatives to film packaging made of PE, PP or BOPP film. Environmentally friendly and sustainable.
BAG WG:
Heat seal strength (sealing duration 1 s)
60 80 100 120 140 160 180 200
7
6
5
4
3
2
1
0
HS BAG WG
Temperature [°C]
Seal
str
engt
h [N
/15
mm
]
Special features
› Durable combined barrier against
• water vapour
• grease / oil
› Very good heat-sealability
General features
› Paper product made from virgin fibers
› 100 % free of
• plastic films, aluminum, extruded polymers,
varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable ingredients
› Reverse side offset and flexo printable
fullyrecyclable
B A R R I E R PA P E R
Applications: heat-sealed bags for dry and
greasy foods and non-foods
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B A G W G / B A G W G O M
B A R R I E R PA P E R
* WG: W – water vapour barrier, G – grease and oil barrier
** WGOM: W – water vapour barrier, G – grease and oil barrier, O - oxygen and aroma barrier, M – mineral oil barrier
Grade Sub-stance
Thick-ness
Water absorptionWater vapour permeability
(DIN 53122-1, 38 °C / 90 % r. H.)
Grease resistance OTR Heat-sealability(Cobb300, EN ISO 535) Turpentine test
(according to T454)Palm kernel oil
(DIN 53116) (1 sec., 150 °C, 500 kPa)
BAG WG 87 g/m² 90 μm < 1 g/m² 70 g/(m²*d) > 1800 s Level 1 6.5 N / 15 mm
BAG WGOM 89 g/m² 91 μm 15 g/m² 70 g/(m²*d) > 1800 s Level 1< 100 cc/
(m²*d)6 N / 15 mm
Information about test procedures can be found in the technical data sheets.
Heat seal strength (sealing duration 1 s, 150 °C, 500 kPa)
60 80 100 120 140 160 180 200
7
6
5
4
3
2
1
0
HS BAG WGOM
Temperature [°C]
Seal
str
engt
h [N
/15
mm
]
BAG WGOM:
fullyrecyclable
barricote BAG
Special features
› Durable combined barrier against
• water vapour
• grease / oil
• oxygen / aroma
• mineral oil migration
› Very good heat-sealability
› Particularly high proportion of renewable raw materials
› Certified seawater decomposability
General features
› Paper product made from virgin fibers
› 100 % free of
• plastic films, aluminum, extruded polymers,
varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable ingredients
› Reverse side offset and flexo printable
Applications: heat-sealed bags for dry and
greasy foods and non-foods
6 B A R R I E R PA P E R
W R A P W G / W R A P W G U N I
Special features
› Combined barrier against
• water vapour
• grease / oil
› Excellent freshness effect
› Barrier side hot melt glueable
› Particularly high proportion of renewable raw materials
› Excellent release effect
› Certifi ed seawater decomposability
General features
› Paper product made from virgin fibers
› 100 % free of
• plastic films, aluminum, extruded polymers,
varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable ingredients
› Reverse side offset and flexo printable
Whether wrapped or glued, the speciality paper barricote WRAP WG* is the ideal wrapping
paper for the food industry. The reliable barrier against water vapour and against grease or
oil is complemented by a very good release effect. Barricote WRAP WG contains a particularly
high proportion of renewable raw materials and protects dry and greasy foods in an optimal
way. Safe and highly sustainable.
The barrier paper barricote WRAP WG uni* excels as a combined barrier against water vapour
and grease / oil with very good heat-sealability. WRAP WG uni is the ideal alternative to PE
wrapping materials. For dry, moist or greasy food. Everything stays in shape and fresh.
Well protected.
WRAP WG:
barricote WRAP WGWrapped, glued or heat sealed – Everything stays where it belongs
fullyrecyclable
Applications: wrapping papers for
dry and greasy foods
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WRAP WG uni:
* WG: W – water vapour barrier, G – grease and oil barrier
Grade Sub-stance
Thick-ness
Water absorption Water vapour permeability Grease resistance Heat-sealability(Cobb300, EN ISO 535) (DIN 53122-1, 38 °C / 90 % r. H.) Turpentine test
(according to T454)Palm kernel oil
(DIN 53116) (1 sec., 150 °C, 500 kPa)
WRAP WG 44 g/m² 53 μm 3 g/m² 250 g/(m²*d) > 1800 s Level 1 -
WRAP WG
uni44 g/m² 53 μm 3 g/m² 250 g/(m²*d) > 1800 s Level 1 4 N / 15 mm
barricote WRAP WG
Information about test procedures can be found in the technical data sheets.
B A R R I E R PA P E R
Heat seal strength (sealing duration 1 s, 150 °C, 500 kPa)
60 80 100 120 140 160 180 200
7
6
5
4
3
2
1
0
WRAP WG UNI
Temperature [°C]
Seal
str
engt
h [N
/15
mm
]
fullyrecyclable
Special features
› Combined barrier against
• water vapour
• grease / oil
› Excellent freshness effect
› Barrier side hot melt glueable
› Very good heat-sealability
› Certifi ed seawater decomposability
General features
› Paper product made from virgin fibers
› 100 % free of
• plastic films, aluminum, extruded polymers,
varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable ingredients
› Reverse side offset and flexo printable
Applications: wrapping papers as well as heat-sealed
sachets for dry, moist and greasy foods
Grease barrier test (coloured oil)
barricote WRAP WG uni
No leakage
Wrapping paper without barrier
Turpentine oil seeps through
CONTROL SHEETS
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foodstuff
corrugated cardboard
L I N E R M G
Guideline value „Mineralölverordnung“***
0,7
0,6
0,5
0,4
0,3
0,2
0,1
0
Mineralölmigration (MOAH) in mg pro kg Lebensmittel
Min
eral
oil
mig
rati
on (
MO
AH
) [m
g/kg
]
LINER MG (50 g) LINER MG (85 g)
Mineral Oil Migration (MOAH)
Laminated or glued packaging made from our barrier paper barricote LINER MG* provides an optimal
and secure barrier against the migration of mineral oils and similar substances. The migration is
demonstrably lower than current draft legislation to protect packaged foods. Another advantage of
the water-based coating is the barrier against grease and oil.
LINER MG is the ideal basis for safe packaging of dry and greasy food such as pasta, oat flakes,
cereals, coffee and other bulk food. The special barrier function is of course maintained during all
further processing steps such as printing, folding, creasing, etc. Natural and safe.
LINER MG:
barricote LINER MG Glued or laminated – No chance for mineral oil migration
Special features
› Combined barrier against
• mineral oil migration
• grease / oil
› Protective function not reduced by further processing
General features
› Paper products made from virgin fibers
› 100 % free of
• plastic films, aluminum, extruded polymers,
varnishes or laminates
• fluorocarbons
• chlorinated hydrocarbons (PVDC free)
• optical brighteners (OBA free)
› High content of biodegradable ingredients
› Reverse side offset and flexo printable
Grade Substance Thickness Mineral oil migration (Tenax method, DIN EN 14338**) Grease resistance (according to T559)MOSH (C20–C35) MOAH (C16–C35)
LINER MG 50 g/m² 85 g/m²
58 μm100 μm
7 %5 %
20 %10 %
> 12 > 12
barricote LINER MG
Information about test procedures can be found in the technical data sheets.
* MG: M – mineral oil barrier, G – grease and oil barrier ** laminated on carrier with MOSH = 759 mg/kg and MOAH = 277 mg/kg
*** The guideline value of the draft regulation of the German “Mineralölverordnung” (4th draft of the BMEL of March 7, 2017) indicates a maximum transition of 0.5 mg / kg C16-C35 MOAH to foodstuffs.
fullyrecyclable
Applications: lining paper for recycled cardboard and corrugated
cardboard, bags for dry and greasy foods
mineral oils
Liner MG
Grade overview barricote
BAG WG BAG WGOM WRAP WG WRAP WG uni LINER MG
Substance 87 g/m² 89 g/m² 44 g/m² 44 g/m² 50 g/m² 85 g/m²
Thickness 90 μm 91 μm 53 μm 53 μm 58 μm 100 μm
WAT
ER V
APO
UR
Cobb300
(EN ISO 535)< 1 g/m² 15 g/m² 3 g/m² 3 g/m²
Cobb1800
(EN ISO 535)2 g/m² 30 g/m² 15 g/m² 15 g/m²
WVTR
(23 °C/85 % r. h.)< 10 g/(m²*d) 15 g/(m²*d) 110 g/(m²*d) 110 g/(m²*d)
WVTR
(38 °C/90 % r. h.)70 g/(m²*d) 70 g/(m²*d) 250 g/(m²*d) 250 g/(m²*d)
GR
EASE
& O
IL
KIT-Value 12 12 12 12 > 12
Turpentine > 1800 s > 1800 s > 1800 s > 1800 s > 1800 s
Palm kernel oil level 1 level 1 level 1 level 1 level 1
OXYG
EN
OTR < 100 cc/(m²*d)
MIN
ERA
L O
ILS
Hexanes 25–50 g/(m²*d) 5–10 g/(m²*d)
MOSH 7 % 5 %
MOAH 0.4 mg/kg 20 % 10 %
Heat-sealability (1 sec., 150 °C, 500 kPa)
6.5 N / 15 mm 6 N / 15 mm 4 N / 15 mm
Certificationsdirect contact with food (e.g. BfR XXXVI )
ISO 9001, ISO 14001, ISO 50001INREKA DIN EN 15593FSC® Mix or PEFC™
Sea water decomposability
ApplicationsHeat-sealed bags for dry, moist and greasy foods
and non-foods
Heat-sealed bags for dry and greasy foods and
non-foods
Wrapping papers for dry and greasy foods
Wrapping papers and heat-sealed sachets for dry,
moist and greasy food
Laminated paper for recycled cardboard and corrugated cardboard, bags for dry and greasy
foods
G R A D E O V E R V I E W
As a responsible manufacturer, we strive to produce and process
our products in the most environmentally friendly way and to the
highest standards of quality. We take our social responsibility
seriously and are active in various environmental associations
and organizations. Complying with and conforming to rules and
regulations goes without saying. Social commitment is an important
part of our corporate culture.
Certifications:
› FSC® Chain-of-Custody
› PEFC™ Chain-of-Custody
› DIN EN ISO 9001:2015
› DIN EN ISO 14001:2015
› DIN EN ISO 50001:2011
› INREKA DIN EN 15593:2008
Memberships:
› B.A.U.M.
› ChePap Rhein-Ruhr
› Klimapakt Flensburg
› Ökoprofit® Klub OWL
› Two Sides
› Wirtschaft pro Klima
Mitsubishi HiTec Paper Europe GmbH Niedernholz 23 | 33699 Bielefeld | Deutschland Tel: +49 521 2091-682 | [email protected]
www.barricote.com
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