atlas of infrared absorption lines - nasa is a revised edition of the atlas of infrared absorption...
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NASA Contractor Report 2925
Atlas of Infrared Absorption Lines
Jae H. Park
CONTRACT NSG-1203 NOVEMBER 1977
https://ntrs.nasa.gov/search.jsp?R=19780004665 2018-06-11T23:16:38+00:00Z
TECH LIBRARY KAFB, NU
NASA Contractor Report 2925
Atlas of Infrared Absorption Lines
Jae H. Park The College of William and Mary Williamsburg, Virginia
Prepared for Langley Research Center under Contract NSG-120 3
National Aeronautics and Space Administration
Scientific and Technical Information Office
1977
This is a r ev i sed ed i t i on of t h e Atlas of Infrared Absorpt ion Lines ,
NASA CR-144976. Three absorption bands , HNO (2v ) and CH3CR ( v4 and 3v6)
are added i n t h i s e d i t i o n . I n f r a r e d a b s o r p t i o n l i n e s t r e n g t h ( a t m -' cmm2)
vs. l i n e p o s i t i o n (cm-l) at 300 K f o r 15 gases are shown i n F i g . 1-65 from
500 cm-l t o 7,000 cm . The absorption bands for each gas shown i n t h e atlas
inc luding sources o f da ta are summarized i n Table I.
3 9
0
-1
This atlas was found t o be useful f o r f e a s i b i l i t y s t u d i e s o f remote
sensing of a tmospheric pol lutants and for t h e i d e n t i f i c a t i o n of g a s e s i n
atmospheric absorption spectra. The author hopes t h a t t h i s at las w i l l provide
f o r t h o s e working i n t h e f i e l d of infrared spectroscopy a quick guide t o
obtaining information on (1) what g a s e s c o n t r i b u t e t o e n e r g y a b s o r p t i o n i n
spec t r a l r eg ions o f i n t e re s t and ( 2 ) t h e i r r e l a t i v e s t r e n g t h s i n a b s o r p t i o n .
Spec ia l a t t en t ion shou ld be g iven t o t he s ca l e of l i n e s t r e n g t h . The l i n e s
are grouped into intervals of 100 cm and only those l ines with a s t r eng th -1
with in o f the m a x i m u m value are shown i n each interval . Therefore , sudden
changes appear i n t h e s c a l e s from one i n t e r v a l t o a n o t h e r . More absorpt ion
l ine parameters w i l l be added as they become available, and an updated atlas
w i l l be re leased upon r e q u e s t i n t h e f u t u r e .
.. .
I I 1 I1 I
Table I . Band centers and sources o f da ta shown i n t h e atlas.
I I I, I..
I
""
Gas
H2°
c02
O3
N2°
co
CH4
O2
s02
NO
N02
NH3 HC 2.
HF HN03
CH3CR
v2 v1 V 3 V V 2 3 -__
V V V
2 3 1
v2 V V 1 3
I
I
_. .. "_ - - "
Source of Data
(1595) ( 6.27) McClatchey e t a l . (1973) (3657) ( 2.73) McClatchey e t a l . (1973) (3756) ( 2.66) McClatchey e t a l . (1973)
( 677) (15.0 ) McClatchey e t a l . (1973) (2349) ( 4.26) McClatchey e t a l . (1973)
( 701) (14.3 VcClatchey e t a l . (1973)
(1103) ( 9.07) McClatchey e t a l . (1973)
( 589) (17.0) McClatchey e t a l . (1973) (1285) ( 7.78) McClatchey e t a l . (1973) (2224) ( 4.50) McClatchey e t a l . (1973)
." - " ". . .
(1042) ( 9.60) McClatchey e t a l . (1973)
" ___."_c -"
~~~ ~
v4 I (1306) ( 7.66) McClatchey e t a l . (1973) v2 (1534) ( 6.52) McClatchey e t a l . (1973)
(3019) ( 3.31) McClatchey e t a l . (1973)
0-1 ( A- C ) : (6325) ( 1.58) I- McClatchey e t a l . (1973)
V 3 -. - - .." -. , . -_ _. - __.. ~
1 3 .~ -__~--__-__-
Calfee (1973 , unpublished) Calfee (1973 , unpublished) Calf ee (1973, unpublished)
Abels and Shaw (1966)
Goldman e t a l . (1975) Goldman (1975, p r i v a t e )
Taylor (1973 )
Benedict e t a l . (1956) and T o t h e t a l . (1970)
Goldman e t a1 . (1974) Brockman (1977, p r i v a t e )
~ ~ . " ~ . . - -. i-._ . " - - . -~ . . I
~ . .. -
.. . . . - - - - ." ~" - -
~ ".
.. . - .- - . -~
-. ""- -
l i s t e d i n t h i s t a b l e a l t h o u g h t h e d a t a are p l o t t e d .
2
REFEKENCES
1. Abels, L. L. and J. H. Shaw (1966) Widths and s t r eng ths o f v ib ra t ion - ro t a t ion l i nes i n t he fundamen ta l band of n i t r i c o x i d e . J. Molec. Spectrosc. vol. 20, 11-28
2. Benedict, W. S. , R. Herman, G. E. Moore and S. Silverman (1956) The s t rengths , wid ths and shapes of infrared l ines . 11. The HCll fundamental. Can. J Phys . vol. 34 , 850-875.
3. Goldman, A. , S. C . Schmidt, J. R. Riter and R . M. BJunt (1974) In f r a red spec t r a l r ad iance o f ho t HF and DF i n t h e Av = 1 bands region as seen through an atmospheric path. J . Quant. Spectrosc. Radiat . Transfer vol. 14, 229-307.
4. Goldman, A . , F. S. Bonomo, W. J. Williams and D . G. Murcray (1975) Abso lu te i n t eg ra t ed i n t ens i ty and ind iv idua l l i n e parameters for the 6.2 p band of NO2. J. Quant. Spectrosc. Radiat . Transfer. Vol. 15, 107-112.
5. McClatchey, R . A . , W . S. Benedict, S . A. Clough, D. E. Burch, R . F. Cal fee , K. Fox, L. S. Rothman, and J. S. Garing (1973) AFCRL atmospheric absorption l ine parameters compilation. AFCRL-TR-0096. Environmental Research Papers No. 434.
6 . Taylor, F. M. (1973) Spec t r a l data f o r t h e v2 band of ammonia w i t h a p p l i c a t i o n t o r a d i a t i v e t r a n s f e r i n the a tomsphere of Jupi ter . J. Quant. Spectrosc. Radiat. Transfer , vol. 13, 1181-1217.
7. Toth, R. A . , R. H. Hunt, and E. K. Plyler (1970) L ine s t r eng ths , l i ne w id ths , and d ipo le moment func t ion fo r HCR. J. M O ~ . Spect . , vol. 35, 110-126.
3
H20 I 1 1 . I I I I k . 8 1
500 510 520 530 590 550' 560 570 580 590 600
-b -3 - -9 - c02 ~ ~ ~ l l l l ~ l l l ~ . l . l ~ l ~ l ~ l ~ l ~ l . l . l ~ l l l l l l % ~ 500 510 520 530 590 550
560 570 580 590 600
-P
3 -3 -2
N20
500 510 520 530 590 550 560 5 70 580 590 600
FIG.1 . LINE STRENGTH VS. WAVENUMBER ( 500 FIND 600 CM-!. 20.00- 16.66 MICRCN 1
H20
600 610 620 630 6'40 650 660 670 680 630 700
600 610 620 630 6'40 650 660 670 680 630 700
600 610 620 630 . 690 ti50 680 630 700 "
& 22
& 3 I I I
0 -3 - -Lt so2
t- 600 610 620 630 6'40 650 660 670 680 630 700 a
c3 0 1
W R V E N U M B E R
FIG-2 - L INE STRENGTH VS. WAVENUNBER ( 600 AND 700 CN-1, 16.66- 14.28 MICRON 1
5
3 1 -9 -3 -
-
I I 3 - I I I I I I I I 1 I I 1 1 1 1 A 1 1 1 1 1 1 1 1 1 1 1
H20
700 710 720 730 7LtO 750 760 770 780 790 800
c02 I I , 800
4
3 I I I 1 I I I I : -5 -6
- N20 -
700 710 720 730 790 ,750 760 770 780 790 800
* b - 1 - 2 -
-1
6 700
-
L 13- 710 I 720 1 730 I I I 11 -Ilh 7qO 750 760 770
E
u 780 790 800
0 _1
W F l V E N U M B E R
FIG.3 . LINE STRENGTH VS- WflVENUMBER ( 700 AND 800 Cfl-1, 19.28- 12-50 flICRON 1
6
c02
810 820 830 890 850 860 870 880 890 900
3
-9 I I I I I 1 1 1 1 J .: -Lt - -5 03 -
800 810 820 830 8LtO 850 860 870 880 890 900
3
3 - 1 I I 1 1 1 1 1 1
-5 N20 - -6
-
800 810 820 830 8LtO 850 860 870 880 890 900
. o t
6 1 - 2 -
-1
800
-
k q - l II l i . , l I l , NH3 I 111 I l l 1 i I l l1 1 1 1 1 1 1 II I l l l l lA l l , l I I
810 820 830 840 850 860 870 880 890 900
E -?.I '"-2 - w-3- HN03
L9 0 1
W R V E N U M B E R
FIG-Lt . LINE STRENGTH VS. WFlVENUMBER [ 800 FIND 900 CM-1. 12-50- 11-11 MICRON I
7
4
3 -5 -6
900 910 920 930 990 950 960 970 980
I
300 910 920 930 950 960 970 980
-3
900 910 920 930
1 1 , Ill,' H20
990 1000
c02
990 1000
03 I . . I* 4 1 1 1
990 950 960 970 980 330 1000
N20
950 970 380 390 1000
L
. f - 0- 1
I , " NH3
I
w 900 910 920 930 950 960 970 980 990 1000 I I
E L
b
E W
-J v
a 0 -J
W A V E N U M B E R
FIGS5 - LINE STRENGTH VS- WHVENUMBER [ 900 AND 1000 CM-1. 11.11- 10.00 MICRON I
8
H20
1000 1010 1020 1030 10YO 1050 1060 1070 1080 1090 1100
I c02
1000 1010 1020 1030 10YO 1050 1060 1070 1080 1090 1100
-2 03
1000 1010 1020 1030 lOY0 1050 1060 1070 1080 1090 1100
-
so2
1090 1050 1060 1070 1080 1090 1100
NH3
r x 1010 1020 1030 0
I- o W z _I H
v
0 1
N R V E N U M B E R
FIG-6 . LINE STRENGTH VS. WRVENUMBER [ 1000 AND 1100 CM-1. 10.00- 9.03 MICRON 1
9
::: -9 15 1100 1110 1120 1130 11110- ."IP 1150 1160 I 1170 I 1180 I 1190 I 1200 I CHY
E- m W z 1 Y
u
c3 0 J
W R V E N U M B E R
FIG.7 . LINE STRENGTH V S . WAVENUflBER ( 1!00 AND 1200 Cfl
10
00
00
so2
NH3
N20
1200 1210 1220 1230 1240 1250 1260 1270 1280 1290 1300
IP 1200 A I l l l l l l- 1210 UVI IU u l h l 1220 Ill1 I 1 1230 l l u t I ul 1290 111 Ill1 I I I I IL 1250.. I I I 1 E 6 0 II h 1270 1280 1290 1300 CHq
N
x I :A
:E u -3 4
-Y so2 + 1200 1210 1220 1230 1250 1260 1270 1280 1290 1300
n r
W f l V E N U F l B E R
FIG.8 . LINE STRENGTH VS. WRVENUMBER [ 1200 FIND 1300 CV- ! . 8.33 - 7.69 MICRON
11
A- -1 - -2 H20 - 13 I .- I,,. I u. I 1, .L A I 1L1.1 1 1 1 1 1 1 1300 1310 1 320 1330 1350 1360 1370 1380 1390 190@
b
3 I I I I I I
-2 -1
1300 1310 1320 1330 1 3qO 1350 1360 1370 1380 1330 11100
N20
rl lrsl I I I I I CHq I I 1 - I
1300 1310 1320 1330 13qO 1350 1360 1370 1380 1390 11100
i= 1300 1310 1320 1330 1 3 0 ' 1350 1360 1370 1380 1330 11100 (I
E
W z
W 0 -I
W R V E N U M B E R
FIG.3 * LINE STRENGTH VS. WAVENUNEER ( 1300 AN0 1'400 CM-1, 7.69 - 7.111 MICRON 1
12
H20
11100 11110 11120 11130 11140 11150 11160 11170 1480 1420 1500
I- - -1 11100- 11110 11120 11130 1 W O llt50 11160 1470 11180 1’490 1500
5 -“mllIIuIlI.. m .I 111111111 ~~~~
so2 3
k 1qoo 11110 1920 11130- 111110 1450 11160 11170 1 1180 11120 1500 I I I I I
U
W z -I I.+ - r-9 0 -I
W A V E N U M B E R
FIG-10. LINE STRENGTH V S - WAVENUMBER [ 11100 RND 1500 CM-1, 7-111 - 6-66 MICRON 1
13
. .. I
H20 I uu I , I I l l . h l l I 1. I J.
1500 1510 1520 1530 15YO 1550 1560 1570 1580 1590 1600
3
I - I I I I I I I I I 3
I -5
N20 - -6 -
1500 1510 1520 1530 15YO 1550 1560 1570 1580 1590 1600
3
3
1
I I I I I I I
- -Y
- -3 - CHY
I500 1510 1520 1530 15YO 1550 1560 1570 1580 1590 1600 - 1 -I
NO2
0
L5 0 1
W R V E N U M B E R
FIG.11. LINE STRENGTH VS- WAVENUMBER ( 1500 AND 1600 CM-1, 6.66 - 6.25 MICRON 1
1 Y
b ilLll,.,ll 1600 1610 11111 I 1620 UII,Ii,lll,I1 1630 II, l l j b l h l , 1 1 1 1 1 1 16qO 1650 1660 1670 1680 1690 1700 H20
~ ~ ~ l l l l l l l l l l l l l l l ! l l I l l i l l ! l l l ~ l l l l l 15 1600 1610’ 1620 1630 llllllllll!lllllullilli.ill 16qo 1650’ 1660 1670 I 1680 I 1690 I 1700 I N20
CHq I I
1600 1610- i 620 1630 1650 1660 1670 1680 1690 1700 I
b -2 NO2 19 1 I I I I
-1
- 1600 1610 1620 1630 16’iO 1650 1660 1670 1680 1690 1700 N
I- (D
Y L
Y
-I Y
(3 0 -I
W R V E N U M B E R
FIG-12. LINE STRENGTH VS- WAVENUMBER [ 1600 AND 17CO CK-1, 6 -25 .- 5-86 MICRON I
15
3
I I - I 3
1 -Lt
N20 - -5 -
1700 1710 1720 1730 1790 1750 1760 1770 1780 1790 1800 -
c
$ 1700 1710 1720 1730 1790 1750 " "~ .I
I- o W z 1 Y
u
c3 0 -I
W A V E N U M B E R
FIG.13. LINE STRENGTH VS. WAVENUMBER ( 1700 AND
"L " -. I. 1760 1770 1780 1790
1800.CM-1, 5.88 - 5.55 MICRON I
NO 1&0
16
H20
1800 1810 1820 I830 1840 1850 1860 1870 1880 1830 1900
7 co2 3 1800 d l 0 1820 1830 1840 1850 1860 1870 1880 1830 1900
-5 N20
1800 I d l 0 -1
1820 1830 1840 1850 1860 1870 1880 1830 1900
W z 1 Y
I
(3 0 _I
W f l V E N U M B E i i
17
-P
2 -2 -3
1300 1310 1920 1930 13YO
3
3 -5 -6
1900 1310 1920 1930
l l I I it. Ill I cl I .I I . ,11., I II 11 I L . ,111 . I H20
1350 1960 1970 1380 1990 2000
c02
1950 1360 1970 1980 1330 2000
N20 I I I I I I I I
1300 1310 1320 1930 13YO 1350 1960 1970 1380 1330 2000
15
L I - I I I I I I I 3
1 -Y - -5 co -
1300 1910 1920 1330 19Y 0 1350 1960 1970 1380 1330 2000
a - - b .
2 3: I I I I I I 1 I 1
-1 .. -2 NO .'
'&) 1900 1310 1920 1330 19Y 0 1350 1360 1370 1380 1390 2000 L
b W z 1 Y
Y
0 a _I
d R V E N U M B E R
F I G - 1 5 . L I N E STRENGTH VS- WAVENUMBER ( 1900 AND 2000 CM-1. 5-26 - 5-00 MICRON 1
18
2000 2010 2020 2030 2090 2050 2060 2070 2080 2090 2100
3 1 -9
2000 2010 2020 2030 20YO 2050 2060 2070 2080 2090 2100
- -5 -
-?U I I In1l1. pI 2 .- - I I I I
2000 20 10- 2020 2030 2090 2050 2060 2070 2080 2090 2100
_i 2000 I I I . I 1 2010 ,.lILIlI-,Ir 2020 I Ill 2030 I 1 kJALL 204 0 2050 2060 2070 2080 2090
W R V E N U M B E R
1 2100
H20
c02
03
co
FIG.16. LINE STRENGTH VS. I.;RVEl\i?iillBEr( [ 2COC AND 3!00 fT!-l. 5.CO - 9.76 MICRON I
19
3
19
-9 -5
2100 21 10 2120 2130 21YO 2150 2160
3
3 -5 -6
2100 21 10 2120 2 130 21YO 2150 2160
H20
2170 2180 2190 2200
c02
2170 2180 2190 2200
i!
13
0 -1 N20
2100 2110 2120 2130 21YO 2150 2160 2170 2180 2190 2200
t - 0 -
-1
2100 21 10 2120 2130 2-lYO 2150 2160 2170 2180 2190 2200
co -
-5-1 I . I I _ I l l * . I , I I I ! I I I l l I d 1111III I l l II I I I I I i I I/ I1 , I 1 , I 1 I
w z -I u
Y
El 0 J
W R V E N U M B E R
FIG.17. LINE STRENGTH VS. WVENUMBER 2!JO FINO 2200 CM-!. Y.76 - Y.5'4 MICRON I
20
I
:BIi 2200 iRllliwclrill,l 2210 2220 lllln 2230 l i i i l l l l i l l k ~ l b ~ l 2290 2250 2260 2270 2280 2290 2300 H20
c02
2200 2210 2220 2250 ' 2260 2270 2280 2290 2300
N20 !hL ~I I I_>
2270 2280 2290 2300
- 2210 1 14 2220
t- o
W R V E N U M B E R
LLL 2230 L I I I 22Y 0 2250 2260 2270 2280 2290 2300
co
FIG.18. LINE STRENGTH VS. WAVENUNBER [ 2200 AND 2300 CM-1. q.SI - Lf.3Y NICRON I
21
3 1 -E - -7 H20 - 3: I d L I I , I _ I Ii I 2300 2310 2320 2330 23'40 2350 2360 2370 2380 2390 2900
f
3 0
- 1 c02
2300 2310 2320 2330 23'40 2350 2360 2370 2380 2330 2900
4 -3 I N20 2 -"11 2300 ;I[, 2310 2320 , , 2330 l f i l l l l l jh, I I I
2340 2350 2360 2370 2380 2330 2900
W z
(3 0
A P V E N U M B E R
FiS.!:;'. LINE STRENGTH VS. WHVENLI?!BER [ 2300 FIND 2'400 EM-1. Lf.3'4 9.16 NICRON I c. L2
3
18
-6 -7 H20
2900 2910 2920 2930 2950 2960 2970 2990 2500
c02
2900 2910 2920 2930 2990 2950 2960 2970 2980 2990 2500 J
n r
N20
0
"!"2$50 19 2900 2460 2970 ' 2980 ' 2990 ' ' I 2500 ' CHli
I
t U
W
J
a 0 J
5 - W R V E N U M B E R
FIG.20- LINE STRENGTH VS. WAVENUMBER ( 2'400 AND 2500 CM-1, Lf-16 - '4.00 MICRON I
23
h , l I Ull, , I ll.i,U1 I l , i , ~ i u . i i u H20 I
2500 2510 , 2520 2530 25Y 0 2550 2560 2570 2580 2590 2600
-P
2 -2 -3 N20
2500 2510 2520 2530 2590 2550 2560 2570 2580 2590 2600
3
19
1
I I 1 I
- -9 -
1 1 I
-5 CHY -
2500 2510 2520 2530 2590 2550 2560 2570 2580 2590 2600
HCL I 1 I I I 1 I I I I - 2500 2510 2520 2530 2540 2550 2560 2570 2580 2590 2600
W R V E N U M B E R
FIG.21. LINE STRENGTH VS. WAVENUHBER [ 2500 RND 2600. CH-1, 9-00 - 3.W HICRON I
29
H20
2600 2610 2620 2630 26Y 0 2650 2660 2670 2680 2690 2700
BUIIUIIIIIIII r~20 I I I I
2600 2610 2620 2&0 -~ 26’40 2650 2660 2670 2680 2690 2700 I 1- L
YillM 3 2600 2610 ll / ;I l 2620 11 1 II 2630. Ill lII1lillllilll 26YO 2650 2660 2670 2680 2690 2700 CHq
X c
-.I
2610 2g20
-I
W R V E N U M B E R
I1 2d30 . 2&0 I I 2 6 5 0
1 2660
I 1 I I I I I 1
2670 2680 2690 2700
HCL
FIG.22. LINE STRENGTH VS- WAVENUHBER ( 2600 AND 2700 CM-1. 3-69 - 3.70 MICRON I
25
,. . ... .,,.
7LuILl -5 15 2700 2710 2720 2730
H20 II
2700 2710 2720 2730 2790 2750 2760 2770 2780 2790 2000
15
-9 -4 -5 03
2700 271 0 2720 2730 2740 2750 2760 2770 2780 2730 2800
-h
3 -3 4 1 N20
2700 2710 2720 2730 27YO 2750 2760 2770 2780 2790 2800
CH”I
2750 2760 2770 2780 2790 2800
a 0 -J
W F l V E N U M B E R
FIG-23. LINE STRENGTH VS- WAVENUMBER ( 2700 RND 2800 CM-1, 3.70 - 3-57 MICRON 1
26
3
3 -5 -6 H20
2800 2810 2820 2830 2890 2850 2860 2870 2880 2890 2900
13
-9 I I I I I I I I I J
-9 -5 03
2800 2810 2820 2830 2890 2850 2860 2870 2880 2890 2900
N20 I 1 1 I 1 1
2800 2810 2820 2830 2890 2850 2860 2870 2880 2890 2doo
-P
2 I 4 IlllIl I l luI l IIIUI 11l1llllYll IIlll~lllI l l lu I lo I . I _ I I 1 I 1 1
CHY
2800 2810 2820 2830 28qo 2850 2860 2870 2880 2890 2900
I
I
(3 0 1
W R V E N U M B E R
FIG-29- LINE STRENGTH V S - WRVENUMBER ( 2800 AND 2300 CM-1, 3.57 - 3.99 MICRON I
27
d YI. H20
2900 2910 2920 2930 29YO 2950 2960 2970 2980 2990 3000
15
- I I I I I I 15
1 -q - -5 03 -
2900 2910 2920 2930 29YO 2950 2960 2970 2900 2990 3000
6
2 - I I
"5 I I I I
-P I I
-1 - -2 CH9 -
2900 2910 2920 2930 2990 2950 2960 2970 2980 2990 3000 J
-2 -3 NO2
- 2900 2910 2920 2930 29Y 0 2950 2960 2970 2980 2990 3000 I - ~. . -1 ~ .. -J
u - .. -P-
2 3-
t; I I . I
- I I 1
-3 - -2 -
g 2900 2910 2920 2930 29YO
1 1 - -? I / I I
CH3CL
2950 2960 2970 2900 2990 3300
I I 1 I I I 1 I I 2 -31 I I I I I
2900 29 10 2920 2930 29Y 0 2950 2960 2970 2900 2990 3000
1 1 HCL L 2 .A
L9 0 __I
W R V E N U M B E R
FIG.25. LINE STRENGTH VS. WAVENUMBER ( 2900 AND 3000 C f l L l . 3.Y9 - 3.33. MICRON I
28
' I ~ . I I / i , co2
-9
3000 30 LO 3020 3d30 3&0 3050 3060 3070 3080 3090 3100 1 tP I - I ' - 1"-
) I l 11 I ' 1 , CH9
3000 3010 3020 3030 3040 3050 3d60 3070 3080 3090 3100 1 "
e 300i 3JL10 3 J6d 3090 3100
U -I
. v H V E K U M B E R
F I G - X . LTNL STRENGTH vs- IWENUMZW c 3020 RNS 3123 C Y - ! , 3.33 - 3.22' MICRON 1
23
H20 111 I 11, 1 I II Ill ll I 111
3100 31 10 31 20 3130 31110 3150 3160 3170 3180 3190 3200
2 1 -7 -6 -
I d 3100 I I I I I I l l I I lllllllll l1IlilIlMllil~11II1I 1 1 1 I II I Illill/ I I “ I I ! I I l c02
31 10 3120 3130 31110 3150 3160 3170 3180 3190 3200
b -
3 : I I 1 - I J I I I I
-1 -2
- L
- II CHY
3100 31 10 3120 3130 31110 3150 3160 3170 3180 3190 3200
CH3CL
3170 3180 3190 3200 c - I r in -g- w -3- z 4- HCL -
I I I I I I I I - 3100 3110 3120 3130 31LtO 3150 3160 31 70 3180 3190 3200 1 18- I d
W 0 _I
W R V E N U M B E R
FIG.27- LINE STRENGTH VS. WAVENUMBER [ 3100 AND 3200 CM-1. 3.22 - 3-12 MICRON 1
30
il I I I I I I I I
c02 I I
3230 32LLO 3250 3260 3270 3280 3290 3300
N20 I I I I I I I I I
3200 3210 3220 3230 32Y 0 3250 3260 3270 3280 3290 3300
N A V E N U M B E R
FIG-28. LINE STRENGTH VS- WAVENUMBER ( 3200 AND 3300 CM-1. 3.12 - 3-03 flICRON I
31
3
$4 -3 -Y N 20
3300 3310 3320 3330 3 3 0 3350 3360 3370 3380 3330 3900
FIG.29. LINE STRENG.TH V S - WAVENUNBER ( 3300 RNO 3LfOO CM-1. 3.03 - 2-59 MICRON I
32
H 20
34 10 3420 3430 399G 3950 3960 3970 3490 35arl
c02
0
-P
3 -2 -3 N20
39 00
"
I HF
W R V E N U M B E R
FIG-30- LINE STRENGTH VS- WRVWUMBER ( 3900 AN0 35M CM-1 2-99 - 2-85 MICRON I
33
It I 1 ~ ~ l , , r , ~ ~ l l , , ~ , , ILu il,.,/d H20
3500 35 LO 3520 3530 3590 3550 3560 3570 3580 359n 3600
b -2 c02 -1
3 3500 3510 3520 3530 35’40 3550 3560 3570 3580 3590 3600
N20 I I I I I I I
3500 3510 3520 3530 3590 3550 3560 3570 3580 3590 3600
!”
W R V E N G M B E R
FTG.31- LYRE STRENGTH V S - WAVENUMBER [ 3500 RND 3600 CM-1, 2.85 - 2-77 MICRON I
W R V E N U M B E R
FIG.32. LINE STRENGTH VS- WAVENUNBER
3 i50 3 i m - 3670 3680 3690 3700
( 3600 AND 3700 CN-1. 2.77 - 2.70 MICRON I
HF
35
b- -1 - -2 H20 3 I lI I* 3700 3710 3720 3730 37Y 0 3750 3760 3770 3780 3790 3800
c02 111 , I I 1 J
3700 3710 3720 3730 3740 3750 3760 3770 3780 3790 3800
I h
-Y N20 2 37 00
-3
- cu I
0 d
I E l- a
t- -1 c3
3710 3720 3730 37L10 3 k o 3%0 3;70 3 h O " ."L
+ m W z 1 CI
u
m 0 1
W A V E N U M B E R
HF
3t90 ~ . 3800 '
FIG.33. LINE STRENGTH VS. WRVENUil3ER [ 3700 RNU 3803 C M - 1 . 2.70 - 2.63 M i C R O N I
36
I- o W z _I - v
VI 0 1
W A V E N U M B E R
3d90 3dSO 3d60 3d70 3880 3890 3900
FIG.3'4. LINE STRENGTH V S - WAVENUMBER ( 3800 AND 3900 CM-1. 2.63 - 2.56 MICRON 1
37
. r
b - -1
H20 - -2 I -
3300 I I .JL 3310 II,I II 3320 ,I ,I I I 1 II dl1 ,I 1 1 l1 I I .tll~ II 1 I J I1 1,II AI 11 I ul, I 1 1 ~ 1 1 1 1 3330 39Y 0 3350 3960 3970 3380 3990 9000
: t " 1
-8 c02 -3 I L 1 I I
3900 3910 3920 3930 39qO 3950 3960 3970 3980 3330 9000
2
18 I - I I I I I I I I I
-5 N20 - -6
-
3900 3910 3920 3930 33Y 0 3950 3960 3970 3980 3990 9000
CI)
-I 0
W R V E N U M B E R
FIG.35. LINE STRENGTH VS- WAVENUMBER ( 3300 AND '4000 CM-!. 2.56 - 2.50 MICRON 1
38
I
H20
'4 0
Y 000 '4010 lllllllllll '4020 Illill '4030 - '40Y l l l l lIl l l l l l l l l 0 '4050 ~ "1. '4060 " '4070 .I '4080 I I
c02 1
'4090 '4100
N20 I
Y 000 '4010 '4020 '4030 '40Y 0. '4050 '4060 '4070 '4080 '4090 '4 100 I
k a I"
f a - -
3 I -3 - -4
-
3- '4100 I 9110 I 9120 I 9130 I I I 9190 ll ~ - 1 1 1 1 ~ - I . I . 9150 4160 9 170 r l80 I 4190 I: I I I 9200 1 co
a I
2
12 I I I I I I I I : -9
- -3 - co 9200 9210 9220 4230 %?Io 4250 Liz60 9270 9284 9230 9300
9260 W70 9280 q290 W O O
FIG-38. LINE STRENGTH VS. WAVENUNBER [ '4200 AND '4300 CN-1. 2.38 - 2.32 NICRON 1
H20
9300 9310 9320 9330 9390 Y350 9360 9370 9380 9390 w o o
3
- I I I I I I I I I I 119
1 -8 c02 - -2
-
9300 9310 9320 Lf330 93'iO 11350 9360 9370 9380 9390 9900
I"i , / , , 1 1 1 1 1 3 9300 9310 9320 9330 11390 9350 9360
3
I I I I I I
- 2
- -
-9
9300 9310 9320 9330 9390 9350 9 360
- -3 -
I 9370 9380
I 9380
N20
11390 91100
co - Y390 w o o
vli 9950
H20
'4q60 Y500
3
3 I I
-3 -Lf N20
w o o 9'430 '4940 W50 W70 '4'480 W30 '4500 J
W R V E N U M B E R
FIGe'40. LINE STRENGTH VS- WRVENUMBER [ q'400 RND Lf500 CM-1. 2.27 - 2.22 MICRON 1
Lf3
3 1 -5 - -6
-
3 T 9500 I I . I Ill, 9510 I I 9520 I I . 9530 I[. 9590 I . I 9550 llSIll 9560 I U 9570 9580 bl 1 I 9530 i,l. 4600 H20
3
-78- I I I
1 -7
9500 9510 q520 9530 9590 9550 9560 9570 9580 ' 9590 4600
- -8 -
1, c02
'"F: -5 3 9500 9510 9520 9530 "I- 9590 - ~ _ I 9550 ~ 9560 1 . ~ . 9570 I "" ~ 9580 1 1 1 1 ~ 1 l l l l l l l j / / l , 9530 4600 N20
c-9 0 _I
W R V E N U M B E R
FIG-41. LINE STRENGTH V S - WRVENUMEER [ 9500 FIND 9600 CM-1, 2.22 - 2.17 MICRON )
H20
9600 4610 . 4620 9630 Y690 , 4650 9660 9670 4680 9690 9700
-78 ~~~l~l~llllll~ll~ll~l 9600 9610 illll I/ 9620 4630 ' 96YO . 9650 9670 9680 9690 9700 c02
~ ~ ~ ~ l l l l l l l l l l l l l l l l l l ~ l l l l l ~ l l l l , l l l l ~ l l ~ l l l ~ l l l l ~ l l l l ~ l l l 3 9600 9610 9620 Y630 %YO 9650 9660 9670 9680 9690 9700 N20
J v
m 0 1
W R V E N U M B E R
FIG-lf2. LINE STRENGTH VS. WRVENUMBER ( '4600 AND 4700 CM-1. 2 - 1 7 - 2.12 MICRON I
3 1 -5 - -6
-
I III I I I I I k 11 I I I I, 1,111 I I 1111 I I IIII IJ I I I
H20 3 - 1 I I I I I I 4700 4710 9720 9730 9740 4750 4760 9770 4780 Y790 9800 "
3
-2 -6 -5
c02
4700 9720 9730 4740 9750 9760 9770 9780 9790 4800
1.3
I I I I L 1%
1 -9
9700 9710 9720 9730 9790 9750 9760 4770 9780 q790 4800
- -3 - llllllllllllll,lllll,llll I l l l l i l l l l l l i i l r r l l L I I N20
N
E
W Z u 1 Y
L3 0 1
W F l V E N U M B E R
F I G 4 3 - LINE STRENGTH VS- WAVENUMBER ( 9700 RNO W O O CM-1 2-12 - 2-08 MICRON 1
Lf6
I
W R V E N U M B E R
F1G.W. LINE STRENGTH VS- WRVENUMBER [ W O O RND '4300 CN-1. 2.08 - 2.0'4 MICRON 1
H20
'4900 '4910 '4920 '4930 '49'iO '4950 '4960 '4970 '4980 '4990 5000
c02
'4900 '4910 '4920 '4930 '43'40 '4950 '4960 q370 '4980 '4990 5000
-3
. I , I I 2 - I I I I I
1 -5 1 , I 1, N20 i,., -6 -
-
9900 9910 9920 '4930 '49'40 9350 '4360 q970 Y980 q990 5000
W R V E N U M B E R
FIG-LtS. LINE STRENGTH V S - WAVENUMBER ( '4900 AND SO00 CM-1. 2.0'4 - 2.00 MICRON I
Y8
H20
5000 5010 5020 5030 5090 5050 5060 5070 5080 5030 5100
3 -3.
-9. 3 c02 ~ l ~ , , , , ~ j j ~ I
5000 5010 5020 5030 5090 5050 5060 5070 5080 5030 5100
l l l l l l 5010
k J R V E N U M B E R
5030 5090 5050 5060 5070 I
5080 5030
FIG.96. LINE STRENGTH VS. WRVENUMBER [ 5000 AND 5100 CM-1. 2-00 - 1.36 MICRON I
Lf9
-P 1 -2 - -3
5100 51 10 5120 5130 51qO 5150 5160 5170 5180 5190 5200
- H20 2 h I I1 1 1111
c02 1llc1. I I I . . , I , ,
5100 51 10 5120 5130 51qO 5150 5160 5170 5180 5190 5200
3
I I I I I I :: 3
1 --
-5
5100 5110 5120 5130 51qo 5150 5160 5170 5180 5190 5200
N20 -.
- I I
E
-I v
C J 0 1
W A V E N U M B E R
FIG.97. LINE STRENGTH VS. WRVENUMBER [ 5100 RND 5200 CM-1. 1.96 ’ 1.92 MICRON I
50
. ”. . . ..
W z
W R V E N U M B E R
5230 52LfO 5250 5260 5270 5280 5230 5300
FIG.q8. LINE STRENGTH VS- WRVENUMBER f 5200 RND 5300 CM-1. 1-92 - 1.88 MICRON 1
51
-7 1 -2 - -3 H20 - ::A 5300 5310 IIII II Ill 5320 I I 1 I II
5330 5390 5350 5360 5370 5380 5390 5400
I ~ ~ 1 1 1 1 1 1 I l l l l l l l l l l l l l l I I I I I LO2 I I I I
5300 5310 5320 5330 53YO 5350 5360 5370 5380 5330 5400
w - 9 1 z -5 I HCL Y 191 I I I I I I l h - 5300 5310 5320 5330 5390 5350 5360 5370 5380 5330 5900 CI) 0 -I
W R V E N U M B E R
FIG.93. LINE STRENGTH VS. WAVENUMBER [ 5300 AND 5900 CM-1. 1.88 - 1.85 MICRON 1
52
cl 0 1
W R V E N U M B E R
FIG-SO. LINE STRENGTH V S - WRVENUMBER [ W O O RNO 5500 CM-1. 1.85 - 1.81 MICRON I
I
-P 1 -2
5500 5510 5520 5530 55qO 5550 5560 5570 5580 5590 5600
- -3 -
I .I, I dl H20 :m 1 I I 11 J , I I I I J I I I t 0 - 1 I . Id
-9
I I I I I - I I I A?
1 -8 - -3 c02 -
5500 5510 5520 5530 55qO 5550 5560 5570 5580 5530 5600 U
c-9
-I 0
W R V E N U M B E R
FIG-51- LINE STRENGTH VS- WRVENUMBER [ 5500 RNO 5600 CM-1. 1-81 - 1-78 HICRON 1
5Lf
H20
5600 5610 5620 5630 5650 5660 5670 5680 5690 5700
''1 J .
-9 c02 1 i?
5600 5610 5d20 5690 5650 5660 5670 5680 5690 5700
.. "1 . . ~. 1 I 1 5610 5 i20 5630
c-9 0 -I
W A V E N U M B E R
I I I I I I I I I 5650 5660 5670 5680 5690 5700
HCL
FIG.52. LINE STRENGTH VS. WRVENUVBER [ 5600 AND 5700 CV-1s 1.78 - 1.75 VICRON 1
55
3 1 ' -Lf - -5 . H20 -
3ihl I . I L bl 111 I L I II,II111 Ill 1 1 1 I l l I I Ill I , . I I I I -1 III I llllllilil ~ 1 1 1 , 1 1 1 1 1 I 5700 5710 5720 5730 57LtO 5750 5760 5770 5780 5790 5800
3 :!! -3 5700 5710 5720 5730 57YO 5750 I 5760 I 5770 I 5780 I 5730 I 5800 I c02
!:I, 1 , I l l , I l1 1, j I l 1 , 1 l1 I I; , 1 z -3 HCL " LA -2 - 5700 5710 5720 5730 57YO 5750 5760 5770 5780 5790 5800
2
W F l V E N U M B E R
FIG-53- L INE STRENGTH V S - WAVENUMBER ( 5700 FIND 5800 Cfl-1, 1.75 - 1.72 MICRON I
56
1 k- a z W E
HCL I - 5800 5810 5820 5d30 5890 5860 5d70 5d80 5890 59DO 5d50
L9 0 -1
.~ I ~ ~.I
W R V E N U M B E R
F1G.W. LINE STRENGTH V S - WRVENUMBER ( 5800 RND 5900 CM-1. 1.72 - 1.69 MICRON )
57
3
I I I I I I
- 3
I -6
- -7 -
1 I H20
5300 5310 5220 5330 53LtO 5350 5360 5370 5980 5320 6000 I
3
I - I I -78
I -7
- -8 -
1 1 1 . . J I I I 11.1 I l l Ill1 I . I l l l l l l l l l l l l l l l I
c02
5200 5210 5920 5930 52LtO 5350 5260 5270 5280 5390 6000
W z _I H
v
m 0 J
N R V E N U M B E R
FIG.55. LINE STRENGTH V S - WRVENUMBER [ 5900 AND 6000 CM-1. 1 - 6 9 - 1.66 MICRON I
58
6000 6010 6020 6030 6090 6050 6060
6000 6010 6020 6030 6090 6050 6060
W z 1 v
L!3 0 _I
W R V E N U M B E R
FIG-56. LINE STRENGTH VS- WAVENUMBER I 6000 FIND 6100 CM-I
6070 ll I I I 6080 Lll" 6090 6100 H20
c02
6070 6080 6090 6100
1.66 - 1-63 MICRON I
59.
12
-8 6KX7 - 61 10 6120 I 6130 I 6140 I I I 1 L 1 I .. I. I H20
1 -7 - -0
-
6150 6160 6170 6180 6190 6200
c02
6100 61 IO 6120 6130 61LfO 6150 6160 6170 6180 6190 6200
E
W A V E N U M B E R
FIG.57. LINE STRENGTH VS. WAVENUMBER ( 6100 AND 6200 CM-1
60
1.63 - 1 61 MICRON I
-12 I 02 . I 1 . . I A - 6200 6220 6230 6;Y 0 6 $50 6;60 ' 6270 6&0 6230 6300
. - . . N
rl 0 J
W R V E N U M B E R
FIG-58. LINE STRENGTH VS- WRVENUMBER [ 6200 RND 6300 CM-1. 1.61 - 1.58 MICRON I
61
r
3
I I I I I I I I
- -78
1 -7 - -8
-
I H20
6300 6310 6320 6330 6340 6350 6360 6370 6380 6390 6900
3 1 -5
c02 - -6 -
3, 6300 I II w Ill 1 1 6310 6320 6330 6390 6350 6360 6370 6380 6330 6900
3
I I I I I I I I I
- 3
1 -5
co - -6 -
6300 6310 6320 6330 6390 6350 6360 6370 6380 6390 6400
-7%
3 9 I I I 1
- -11
- -12 -
- 6300 6310 6320 6330 6340 llLll 6350
6360 6370 6380 6390 6YOO
El 0 -I
W R V E N U M B E R
FIG-59- LINE STRENGTH VS- WAVENUMBER [ 6300 AND 6400 CM-1. 1.58 - 1.56 MICRON 1
62
Iy/ -7 19 6900 I I I I I 1 H20
6910 61t20 6930 69Y 0 6950 6960 6970 6980 6990 6500
3 -6 -7
- -
-!-I 6900 I I I I Ill I I I I I 1 I I I I I 6910 6920 6q30 6990 6950
I
Lull 6960
c02
6970 6980 6990 6500
W A V E N U M B E R
FIG-GO. LINE STRENGTH VS- WAVENUMBER [ 6'400 AND 6500 CM-1. 1.56 - 1-53 MICRON '1
63
3 1 -5
H20 - 76 -
3 - 1 6500 l l l l l l 6510 1 1 1 ~ 1 1111Il 6520 IIIIIIII I I I I I i lh I 1 1 J 1 1 6530 65’40 . 6550 . 6560 6570‘ 6580 6590 6600
:x I -6 - -7 c02 -93 I I J I I I 6500 6510 6520 6530 65’40 6550 6560 6570 6580 6590 6600
W R V E N U M B E R
FIG-61. LINE STRENGTH VS. WRVENUMBER [ 6500 AND 6600 CM-1, 1.53 - 1.51 MICRON I
W z -1 - Y
c9 0 -I
W R V E N U M B E R
FIG.62. LINE STRENGTH V S - WRVENUMBER [ 6600 AND 6700 CM-1. 1.51 - 1.L19 MICRON I
65
H20
6700 6710 6720 6730 67qO 6750 6760 6770 6780 6790 6800
-6 -7
3 6700 6710 6720
ul UllI 6730 i 67YO
M 6780
c02
6790 6800
I
c3 0 _I
W F l V E N U M B E R
FIG-63. LINE STRENGTH VS. WRVENUMBER ( 6700 AN0 6800 CM-1. 1.q3 - 1 - 9 7 MICRON 1
66
-7 E02 18 t I
6800 6810 6i320 6830 6890 6850 6860 6870 6880 6890 6900 1 ~~
a
1 Y
Cl 0 -I
W R V E N U M B E R
FIG-6'4. LINE STRENGTH VS. WRVENUMBER ( 6800 RND 6900 CM-1, 1.'47 - 1.94 MICRON 1
I
67
H20 I . I I I [
6900 6910 6920 6930 69’40 6950 6960 6370 6980 6330 7000
c02 I l k I L I
6900 69 10 6920 6930 69’40 6950 6960 6970 6980 6990 7000 - J
E
0 _I
W R V E N U M B E R
FIG-65. LINE STRENGTH V S - WRVENUMBER ( 6900 RND 7000 CM-1. 1*’4’4 - 1.Lt2 MICRON 1
68
1. Report No. 2. Government Accerrion No.
NASA CR-2925 4. l j t l e and Subtitle
Atlas of Inf ra red Absorp t ion Lines
7. Author(s1
Jae H . Park
9. Performing Organization Name and Address
College of William and Mary Williamsburg, Virginia 23185
2. Sponsortng Agency Name and Address
National Aeronautics and Space Administration Washington D. C . 20546
3. Recipient's C a t a l c g No.
"
5. Report Date November 19 7 7
6. Performing Organiz'ation Code
8. Performing Organlzation Report No.
10. Work Unit No.
I ? . Confract or Grant No
NSG 1203
13. Type of Repor t and Period Covered
Contractor Report
14. Sponsoring Agency Code -
5. Supplementary Notes
This report supercedes NASA CR-144976. Langley technical rnoni tor - Jae H. Park Fina l Report
6. Abstract
This at las o f i n f r a r e d a b s o r p t i o n l i n e s c o n t a i n s a b or t i o n l i n e p a r a m e t e r s ( l i n e s t r e n g t h vs . wavenumber) from 500 t o 7000 cm f o r 1 5 gases : H20 CO 03, N20, CO C H 4 , 02 , SO2) N O , NO2, NH, HCR, HF, HNO, and CH,CR.
-9 2'
J 3 2
- " '. Key Words (Suggerred by Author(s))
- ." . Spectroscopy Pol lut ion In f r a red Absorption m i s s i o n Remote Sensing
. . ., - ._
Dlstrlbutlon Statement
Unclas s i f i ed - Unlimited
S u b j e c t Category 46 1. Security Clanif. (of this report) 20. Security Clasrif. (of this p a g e ) 22. Rice' 21 . No. of Pages
~. ~"
Unclass i f ied $4.50 68 Unclass i f ied I] . For sale by the Natlonal Technlcal lnformatlon Servlce. Sprlnefleld. Virginla 22161
NASA-Langley, 1977