appendix i posters and other presentations978-94-015-8295-7/1.pdfs. sarra de, g. m. rios, r veyre...
TRANSCRIPT
APPENDIX I
POSTERS and OTHER PRESENTATIONS
POSTER PRESENTATIONS
Phase equilibria / Modeling
P. J. Smits, J. Gregerowicz, J. W. Shaw, Th. de Loos and J. de Swaan Arons, Complex phase behavior in three-component model reservoir fluids. Unusual retrograde condensation of the heavy liquid phase
C. J. Gregg, F. P. Stein and M. Radosz, Phase equilibria of associating mono- and ditelechelic polyisobutylenes in sub- and supercritical polar and non-polar fluids
N. Van Nhu and F. Kohler, The mixture methane + ethane: Excess properties and phase equilibria calculated from a generalized van der Waals equation of state
G. A. Iglesias-Silva, J. C. Hostle and K. R. Hall, (JE Modelfor multicomponent mixtures
G. X. Jin, A. van Pelt and J. V. Sengers, Critical fluctuations and classical equations of state
M. Gencaslan, P. H. E. Meijer, M. Keskin, and A. H L. Levelt, Closed loops in phase diagrams
P. H. E. Meijer, Generalized Korteweg equatiOns for phase separation near the critical point in binary gas-liquid mixtures
J. R Boulton and F. P. Stein, The constant pressure heat capacity of supercritical mixtures: Carbon dioxide / Acetone
H. A. Matos, M. A. Costa, E. G. de Azevedo and M. N. da Ponte, Ternary phase eqUilibria involving ethylene, 1,8-cineole and d-limonene at 288 and 298 K
P. J. Pereira and M. N. da Ponte, Phase equilibriafor the system carbon dioxide +glycidol in the supercritical region
S. Platin, E. o. Ozer, U. Akman and O. Hortaesu, Equilibrium and extraction studies on the spearmint oil - carbon dioxide system
Spectroscopy / Reactions / Transport
H. Oehel and G. M. Schneider, Near-infrared spectroscopic investigations on phase behavior and dimerization of dodecanoic acid, hexadecanoic acid, d-valerolactam and ecaprolactam in supercritical chlorotrijluoromethane
V. K. Popov, J. A. Banister and M. Poliakoff, Probing supercriticalfluid mixtures using acoustic and photoacoustic methods
775
776
C. B. Roberts, J. Zhang, J. F. Brennecke and J. E. Chateauneut: Laser flash photolysis investigation of diffusion controlled reactions in supercritical fluids
M. C. Bellissent-Funel, U. Buontempo, A. Filabozzi, M. Nardone, and F. P. Ricci, Structure of the He-Xe mixtures near 30 MPa demixing curve at 294 K
M. C. Bellissent-Funel, A. Filabozzi, M. Nardone, F. P. Ricci and M. A. Ricci, Quantum effects in the structure of dense supercritical flUid helium.
J. Luettmer-Strathmann and J. V. Sengers, Transport properties offluids in the critical region
J. A. Banister, M. Poliakoff and S. M. Howdle, Synthetic chemistry in a small-scale supercritical flUid flaw reactor.
M. L. S. Matos Lopes, C. A. Nieto de Castro and J. V. Sengers, Mutual diffusivity of liquid binary mixtures near a critical consolute point.
Computer Simulations
A. A. Chialvo, T award a molecular-based understanding of solute-induced local density, mixed-solute and entrainer effects in dilute near-critical mixtures
P. B. Balbuena, K P. Johnston and P. Rossky, Theory of the effect of a supercritical solvent on a chemical reaction
J. M. Seminario and P. Politzer, Effect of supercritical water on d: A combined DFT and MD approach
Natural Materials
F. Temelli, E. LeBlanc and L. Lu, Supercritical carbon dioxide extraction of oil from atlantic mackerel (Scomber scrombus) and evaluation of protein functionality
M. Goto, M. Sato and T. Hirose, Kinetic study for supercriticalfluid extraction of natural materials
P. C. Simoes and M. N. da Ponte, Mass transfer models in supercritical extraction of natural oils
P. J. P. Carmelo, M. N. da Ponte, Feasibility of super critical fluid extraction to deaCidification of olive oils without affecting their triglyceride content
E. Kiran and H. Balkan, High-pressure extraction and delignification of red spruce with binary and ternary mixtures of acetic acid, water, and carbon dioxide
A. s. Reis Machado, R M. Sardinha, E. G. de Azevedo, and M. N. da Ponte, High pressure de lignification of eucalyptus wood using carbon dioxide containing mixtures
777
J. A. P. Coelho, R L. Mendes, J. M. Novais, S. Cabral, F. Venancio, S. C. Frazao and A F. Palavra, Supercritical fluid extraction from Portuguese Rosemary with carbon dioxide
M. Baptista, AL. Cardoso, M. G. Bernardo-Gil and M. L. Beirao da Costa, SCF extraction of aroma compounds from coriander leaves and rosemary
N. Adasoglu, E. Bolat and S. Dincer, Supercritical fluid extraction of essential oils from lavender flowers
Special Topics
S. Sarra de, G. M. Rios, R Veyre and R Soria, Supercritical carbon dioxide extraction coupled with nanofiltration separation. Interest and preliminary studies
M. A. Zbiec, Application of supercritical fluid extraction for pesticide residue in food analysis
S. Pekyardimci and M. Balaban, Enzyme inactivation by supercritical carbon dioxide
G. Karakas, T. G. Somer, and T. Dogu, Conversion of heavy paraffins to carboxylic acids with carbon dioxide under supercritical conditions
U. Akman and A K Sunol, Supercritical exsorption. Simultaneous sorption and extraction under supercritical-jluid conditions
M. Canel, Extraction of solid fuels with water in sub and supercritical states
M. B. King, J. R Bolt, A Lyddiatt, D. Butler and T. J. Lu, On-going work with supercritical and marginally subcritical fluids at Birmingham, United Kingdom
E. S. Vayisoglu, D. Erbatur, N. G. Erbatur, B. Frere, K D. Bartle and C. E. Snape, Chromatographic and spectroscopic investigation of the supercritical toluene extracts of the maceral concentrates of coals.
OTHER (ORAL) PRESENTATIONS
A. Kruse, H. J. BIeyl and K H. Ebert, First results of the pyrolysis of tert-butylbenzene in supercritical water
Yu. B. Mel'nichenko, Criticalfluctuations in polymer solutions: crossover between tricritical and fluctuation regimes
APPENDIXll
LIST OF PARTICIPANTS
Par
tici
pant
s
(I)
Lom
ba;
(2)
Mer
oni;
(3)
Cum
min
gs;
(4)
Ebe
rt;
(5)
Frit
zer;
(6)
O'C
onne
ll;
(7)
Ric
ci;
(8)
Mel
'nic
henk
o; (
9) D
orey
; (1
0)
deL
oos;
(II
) B
runn
er; (
12)
Rot
h; (
13)
Pete
rs;
(14)
Ful
le;
(15)
Cli
ffor
d; (
16)
Sem
inar
io;
(17)
Ves
ovic
; (1
8) L
uettm
er-S
trat
hman
n;
(19)
Och
el;
(20)
Ast
rid
Kle
intje
ns;
(21)
Bub
ack;
(22
) va
n Pe
lt; (
23)
Giv
en;
(24)
Ste
in;
(25)
Chi
alvo
; (2
6) S
chne
ider
; (2
7) C
anel
; (2
8) G
regg
; (2
9) S
arra
de; (
30)
Tut
kun;
(31
) C
arm
elo;
(32
) O
rbey
; (3
3) A
daso
glu;
(34
) M
atos
; (3
5) O
. E
rbat
ur;
(36)
Sim
oes;
(37
) C
oelh
o; (
38)
Akm
an;
(39)
Mei
jer;
(40
) Pl
atin
; (4
1) N
avar
o; (
42)
Ber
nard
o-G
il; (
43)
Zbi
ec;
(44)
Kru
se;
(45)
Bra
nd;
(46)
Pet
er;
(47)
Bal
buen
a; (
48)
Popo
v; (
49)
Ves
ovic
; (5
0) P
inhe
iro;
(51
) Sa
ndle
r; (
52)
Peky
ardi
mci
; (5
3) J
. Sen
gers
; (54
) B
alka
n; (
55)
Page
; (5
6) G
okm
enog
lu;
(57)
Tem
elli;
(58
) H
eide
man
n; (
59)
Ari
n; (
60)
Kin
g; (
61)
Lev
elt
Sen
gers
(A
nnek
e);
(62)
G.
Erb
atur
; (6
3)
Bol
at;
(64)
Got
o; (
65)
Cal
imli;
(66
) V
an N
hu;
(67)
Mac
hado
; (6
8) G
onca
lves
; (6
9) E
squi
vel;
«7
0)
Deb
ened
etti;
(71
) Pe
reir
a;
(72)
Xio
ng;
(73)
Rob
erts
; (7
4) S
mits
; (7
5) B
anis
ter;
(76
) H
owdl
e; (
77)
Ant
a; (
78)
Kap
lan;
(79
) L
emer
t; (
80)
L. K
lein
tjens
; (8
\)
Kir
an;
(82)
Kar
akas
; (8
3) H
orta
csu;
(84
) G
enca
rsla
n; (
85)
Sim
sek;
(86
) E
rol;
(87)
Pan
agio
topo
ulos
; (8
8) A
vara
nas;
(89
) L
opes
; (9
0) K
eski
n.
(Mis
sing
from
the
pic
ture
are
Akg
erm
an, D
emir
ciog
lu, H
all,
Lee
, Pan
do, R
ados
z, R
enun
cio
and
Suno
l).
LIST OF ALL PARTICIPANTS
Canada
R. A. HEIDEMANN
Feral TEMELLI
France
Stephane SARRADE
Germany
Gerd BRUNNER
Michael BUBACK
Klaus EBERT
DirkFULLE
Andrea KRUSE
Yuri B. MEL'NICHENKO
HenningOCHEL
Siegfried PETER
University oj Calgary, Chemical Engineering Department, Calgary, Alberta T2 NIN4, CANADA
University oj Alberta, Department oj Foods Science and Nutrition, Edmonton, Alberta, CANADA T6G 2MB
Laboratoire de Genie des Procedes, Universite Montpellier II - USTL -CC023, Place Eugene Bataillon, 34095 Montpellier Cedex 05, FRANCE
Technische Universitiit Hamburg-Harburg, AB Veifahrenstechnik II, Eicsendoifer Strasse 3B, 27077 Hamburg, GERMANY
Institute for Physikalische Chemie, Universitiit Gottingen, Tammannstrasse 6, D-37077 Gottingen, GERMANY
Institute for Heisse Chemie, Kernjorschungszentrum Karlsruhe, Postfach 3640, 76021 Karlsruhe, GERMANY
Inst. for Physikalische Chemie d. Universitiit Gottingen, Tammannstr. 6, 37077 Gottingen, GERMANY
Kernjorschungszentrum Karlsruhe, Institute for Heisse Chemie Postfach 3640, H7602I Karlsruhe, GERMANY
Max Planck Institute jor Polymer Research, Postfach 314B, 55021 Mainz, GERMANY
Lehrstuhl for Physikalische Chemie II, Ruhr Universitiit Bochum, Universitaetsstr. 150 D-447BO Bochum 1, GERMANY
Institute for Technische Chemie II, Universitiit Erlangen- Nurnberg, Egerlandstr. 3, D-B520-Erlangen, GERMANY
783
784
Gerhard M. SCHNEIDER
Nguyen VAN NHU
Greece
Antonis A VRANAS
Italy
Alberto MERONl
Francesco Paolo RICCI
Netherlands
Ludo A. L. KLEINTJENS,
Theodoor Willem de LOOS
Comelis J. PETERS
Peter Jan SMITS
Portugal
Maria G. BERNARDO-GIL
Ruhr-Universitiit Bochum, Lehrstuhlfor Physikalische Chemie 11, D-44780 Bochum, GERMANY
Institutfor Thermo-und Fluiddynamik, Ruhr Universitiit Bochum, 44780 Bochum, GERMANY
Department of Chemistry, Aristotle University, 54006, Thessaloniki, GREECE
Dipartimento di Fisica, Universita Degli Studi di Milano, Via Celoria, 16, 20133 Milano, ITALY
Departimento di Fisica, Universita degli Studi di Roma "La Sapienza", PIazzale AldoMoro, 2,0015 Roma, ITALY
DSM Reseach, P.G. Box 18, 6160MD Geleen The NETHERLANDS
Laboratory of Applied Thermodynamics and Phase Equilibria, Delft University of Technology, Julianalaan 136, 2628 BL Delft, The NETHERLANDS
Delft University of Technology, Applied Thermodynamics and Phase Equilibria, Julianalaan 136, 2628 BL Delft, The NETHERLANDS
Laboratory of Applied Thermodynamics and Phase Equlibria, Technical University of Delft, Julianalaan 136, 2628 BL Delft, The NETHERLANDS
Department of Chemical Engineering, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL
Paulo J. P. CARMELO
Jose A. P. COELHO
Maria M. L. T. ESQUIVEL
Maria M. B. P. GONCALVES
Manuel L. S. M. LOPES
Ana S. R. MACHADO
Henrique A. S. MATOS
Paulo J. A. PEREIRA
Lidia M. V. PINHEIRO
Pedro M. C. SIMOES
Spain
Juan Antonio ANT A
Enrique LOMBA
Concepcion PANDO
Juan A. Rodriguez RENUNCIO
785
Department oj Chemistry Lab-108, Faculdade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL
Department oj Chemical Engineering, Instituto Superior Tecnico, Complexo -1, Av. Ravisco Pais, 1096 Lisboa Codex, PORTUGAL
Department oj Chemical Engineering, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL
Department ojChemistry, Faculd.ade de Ciencias e Tecnologia, Universidade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL
Department oj Chemistry, Faculty oj Sciences, University ojLisbon, Campo Grande, Edificio Cl, Piso 5, 1700 Lisboa, PORTUGAL
Centro de Tecnologia Quimica e Biologica, Rua da Quinta Grande 6, Apartado 127, 2780 Oeiras, PORTUGAL
Centro Quimico Estrutural, Instituto Superior Tecnico, Av. Rovisco Pais, 1096 Lisboa Codex, PORTUGAL
Department oj Chemistry- Lab. 108, Faculd.ade de Ciencias e Tecnologia, Universid.ade Nova de Lisboa, 2825 Monte de Caparica, PORTUGAL
Faculdade de Farmacio de Lisboa, Universidade de Lisboa, Avenida das Forcas Armadas, 1600, Lisboa, PORTUGAL
Department ojChemistry, Universidade Nova de Lisboa 2825 Monte de Caparica, PORTUGAL
Instituto de Quimica Fisica Rocasolano, CSIC, Calle Serrano 119, E-28006Madrid, SPAIN
Instituto de Quimica Fisica Rocasolano, CSIC, Calle Serrano 119, E-28006Madrid, SPAIN
Facultad de Quimica, Universidad Complutense, E-28040Madrid, SPAIN
Facultad de Quimica, Universitad Complutense, E-28040 Madrid, SPAIN
786
Turkey
Nalan ADASOGLU
S. Ugur AKMAN
GonencARIN
Hiilya BALKAN
EsenBOLAT
Ayla CALIMLI
Muammer CANEL
Mustafa DEMIRCIOGLU
GayeERBATUR
Oktay ERBATUR
Murat Ismet EROL
Mustafa GENCASLAN
Oner HORTACSU
Giirkan KARAKAS
Mustafa KESKlN
OrliNAVARO
HasanORBEY
Yildiz Technical University, Chemical &Metallurgical Faculty, Chemical Engineering Department, Sisli, Istanbul, TURKEY
Department of Chemical Engineering, Bogazici University, Bebek 80815, Istanbul, TURKEY
Chemical Engineering Department, Gazi University, Maltepe, Ankara, TURKEY
SEKA, Research & Development DiviSion, lzmit, Kocaeli, TURKEY
Chemical & Metallurgical Engineering Faculty, Chemical Engineering Department, Yildiz Technical University, Sisli, Istanbul., TURKEY
Department of Chemical Engineering, Ankara University, 06100, Tandogan, Ankara, TURKEY
Department of Chemistry, Ankara University, BesevlerAnkara, TURKEY
Department of Chemical Engineering, Ege University 35100 Bornova, lzmir, TURKEY
Department of Chemistry, Cukurova University, Adana 01330, TURKEY
Department of Chemistry, Cukurova University, Adana 01330, TURKEY
Department of Chemical Engineering, Ankara University, 06100 Tandogan, Ankara, TURKEY
Department of Physics, Erciyes University, 38039 Kayseri, TURKEY
Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY
Department of Chemical Engineering, Middle East Technical University, Inonil Bu/vari, 06531 Ankara, TURKEY
Department of Physics, Gaziosmanpasa University, Tokat, TURKEY
Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY
Department of Chemical Engineering, Middle East Technical University, Ankara, TURKEY
Sule PEKY ARDIMCI
Sevan PLATIN
Emir Huseyin SIMSEK
Osman TUTKUN
United Kingdom
James A. BANISTER
Anthony A. CLIFFORD
Steve HOWDLE
Muammer KAPLAN
Michael B. KING
Velisa VESOVIC
United States
Aydin AKGERMAN
Perla Beatriz BALBUENA
Jennifer Irene BRAND
Ariel Augusto CHIAL VO
787
Department of Chemistry, Ankara University, 06100 Tandogan, Ankara, TURKEY
Department of Chemical Engineering, Bogazici University, 80815 Bebek, Istanbul, TURKEY
Department of Chemical Engineering, Ankara University, 06100 Tandogan, Ankara, TURKEY
Chemical Engineering Division, TUBITAK - Marmara Research Center, P.K 21, 41470 Gebze- Kocaeli, TURKEY
Department of Chemistry, University of Nottingham, Nottingham Park, Nottingham NG7 2RD, UNITED KINGDOM
School of Chemistry, UniverSity of Leeds, Leeds LS2 9JT, UNITED KINGDOM
Department of Chemistry, University of Nottingham, Nottingham Park, Nottingham NG72RD, UNITED KINGDOM
Department ofChemisry, Nottingham University, Nottingham NG7 2RD, UNITED KINGDOM
School of Chemical Engineering, University of Birmingham, Edgbaston, Birmingham B15 2IT, UNITED KINGDOM
IUPAC Transport Properties Centre, Department of Chemical Engineering and Chemical Tech. Imperial College, London SW7 2AZ, UNITED KINGDOM
Texas A&M University, Chemical Engineering Department, College Station, Texas 77843-3122, USA
Department of Chemical Engineering, University of Texas, Austin, Texas 78712, USA
Department of Chemical Engineering, University of Nebraska-Lincoln, Lincoln, NE 68588-0126, USA
Department of Chemical Engineering, UniverSity of Virginia, Charlottesville, VA 22903-2442, USA
788
Peter T. CUMMINGS University of Virginia, Department of Chemical Engineering, Charlottesville, VA 22903-2442, USA
Pablo G. DEBENEDETTI Princeton University, Chemical Engineering Department, Princeton, NJ 08544-5263, USA
Cameron DOREY Department of Chemistry, University of Central Arkansas, Conway, AR 72035, USA
James A. GIVEN NIST, Thermophysics Division, Gaithersburg, MD 20899, USA
Zeliha GOKMENOGLU Department of Chemical Engineering, University of Maine, Orono, Maine 04469, USA
Christopher James GREGG Department of Chemical Engineering, Lehigh University Bethlehem, PA 18015, USA
Kenneth Richard HALL Department of Chemical Engineering, Texas A &M University, College Station, Texas 77843, USA
Erdogan KIRAN Department of Chemical Engineering, University of Maine, Orono, Maine 04469-5737, USA
Lloyd L. LEE School of Chemical Engineering and Materials SCience, University of Oklahoma, Norman, OK 73019, USA
Richard Milo LEMERT Department of Chemical Engineering, University of Toledo, Toledo, Ohio 43606-3390, USA
Jutta LVETTMER-STRATHMANN Institute of Physical Science & Technology, University of Maryland, College Park, MD 20742-2431, USA
Mark A. McHUGH The Johns Hopkins University, Chemical Engineering Department,Baltimore, MD 21218, USA
Paul H. E. MEIJER PhysiCS Department, The Catholic University of America, Washington, D.C. 20064, USA
John P. O'CONNELL University of Virginia, Department of Chemical Engineering, Charlottesville, VA 22903-2442, USA
Steven H. PAGE NIST, Building 222/ B156, Gaithersburg, MD 20899, USA
A. Z. P ANAGIOTOPOULOS Cornell University, School of Chemical Engineering, Ithaca, New York 14853-5201, USA
Antonius van PELT Institute for Physical Science and Techn., University of Maryland, !PST Bldg. Room 2112, College Park, MD 20742-2431, USA
Maciej RADOSZ Corporate Research, Exxon Research & Engineering Co., Annandale, New Jersey 08801, USA
Christopher B. ROBERTS Department of Chemical Engineering, University of Notre Dame, Notre Dame, IN 46556, USA
Stanley I. SANDLER
Jorge M. SEMINARIO
J. M. H. LEVELT SENGERS
Jan V. SENGERS
Fred P. STEIN
Aydin K. SUNOL
YanXIONG
Non-Nato Countries
Harald Paulson FRITZER
Motonobu GOTO
V. K. POPOV
Michal ROTH
Maria Alexandra ZBIEC
University of Delaware, Chemical Engineering Department, Newark, DE 19716, USA
Department of Chemistry, University of New Orleans, New Orleans, Louisiana 7014B, USA
Thermophysics Division, NIST, Gaithersburg, MD 20B99, USA
789
Institute for Physical Science & Technology, University of Maryland, College Park, MD 20742, USA
Department of Chemical Engineering, Lehigh University, Bethlehem, PA IBOI5, USA
Department of Chemical Engineering, University of South Florida, Tampa, Florida 33620, USA
Department of Chemical Engineering, University of Maine, 5737 Jenness Hall, Orono, Maine 04469-5737, USA
Institute of Physical & Theoretical Chemistry, Graz University of Technology, Rechbauerstrasse 12, A-BOlO Graz, A USTRlA
Department of Applied Chemistry, Kumamoto University, 2-39-1 Kurokami, Kumamoto B60, JAPAN
Advanced Laser Technologies Dept., Scientific Research Center for Technological Lasers, Russian Academy of Sciences, Troitzk, Moscow Region, 742092, RUSSIA
Institute of Analytical Chemistry, Academy of Sciences of the Czech Republic, Vavery 97,61142 Brno, The CZECH REPUBLIC
Institute of Biotechnology of the Agricultural & Food Industry, Rakowiecka 36, Warsaw 02-532, POLAND
INDEX
Absorption equilibrium 678, 743, 745, 746, 753
Activation volume 465, 467
Activity coefficient models 153
Absorption spectroscopy 499, 500
Adsorption/desorption phenomena 670, 678,744
Alkanes 77,78,88,127,128,130,141,144
Alkanols 129,130
Alkylbenzenes 130
Alumina 707, 709-711, 714-716
Anti-solvent process 719, 725-728, 754
Argon 731
Association 129
Attractive mixtures 300, 301, 370, 439-442, 444
Axial dispersion coefficients 685
BACK 170
Barotropic phenomena 740
Binary interaction parameter 151, 159
Binary mixtures 13,49,75,100,118,127,132, 354, 570
Binodal 69, 567, 581, 593 Bioerodible polymers 723, 725
Bridge fimction 367
Butane 574, 608
Butanol 76
C-H activation 534, 535
Capacity ratio 103,106, 619
Carbon dioxide 78, 81, 88, 92-94, 100-106, 110, 112, 244, 247, 248, 251, 260, 261, 263-266, 278, 442-444, 510, 527-536, 595, 641-650, 731, 741, 742, 746-751
Carbon monoxide 509
Carboxylic acids 130
Carnahan-Starling 52, 110, 165, 167, 169, 262, 613
Ceramics 595, 707-717, 723
791
Chemical potential 370,417,424
Chitosan 565
Chromatography 653, 654
Classification of phase behavior 75,96, 98-102, 118, 119, 120
Closed solubility loop 99
Closure relation 292, 367
Cloud point 570, 591, 599, 601-607, 609, 610, 614,615
Combining rules 150,178,
Compressibility 3-6,10,20-21,93,147,216, 22~231,23~23~25~292,29~29~29~ 30~
303, 304, 342, 343, 345, 353, 358, 398, 399, 406, 439-441, 720, 753
Computer simulation 8, 29, 149, 163, 288, 354, 439, 442-444
Controlled drug delivery 719, 723-725
Copolymer 494,545,546,594,599,601-605, 608-611,613-616
Correlation fimction 5-7,10,17-18,164,191, 212,232,273,277,280,289,290,291,292,294, 296, 299, 300, 301, 302, 305, 306, 307, 330, 344, 37~ 38~ 40~401, 40~ 40~ 439-444
Correlation length 6-8,10,18,231,232,238, 242,247,254,288,291,292,302,327,333,334, 34~ 38~39~401,444
Corrosion 702
Cosolvent effect 103,574
Critical behavior 3-18,51,98,231,233,236, 249, 251, 252, 254, 263, 264, 279, 287, 288, 289, 294, 295, 298, 317, 337, 340, 341, 343, 344, 345, 346, 354, 590
Critical criteria 44
Critical divergences 3-6,9, 14-17,20-21, 196, 22~ 32~ 33~ 34~34~35~35~ 35~ 440
Critical end points 15,21,34,51,63, 68, 85, 88, 98,106,107, 120, 128, 600
Critical exponents 4, 7,8-11. 150, 237, 238, 241,255,292,294,295,327,337,343,345,354, 357
792
Critical fluctuations 5-6,10,231-233,239,240, 24~ 24~ 32~ 331, 33~ 34~ 351, 355
Critical lines 13-14,24-26,51,63, 68, 98, 118, 138, 248
Critical mixture curve 599-601
Critical phenomena 3, 65, 98, 164, 325
Critical point 3-7,39, 61, 66, 72,93, 148, 187, 23~ 23~ 32~ 42~ 593
Crystallization 99, 106, 556, 740, 754
Destruction 697
Devolatilization 619
Dielectric properties 93, 711
Diffusion coefficient 250, 252, 687, 739, 740
Diffusion effects 457, 470, 491
Diffusivity 231, 241, 245, 248, 249
Dilute mixtures 19-29, 193, 196, 200, 208, 288, 439-444
Dimerization 108
Dinitrogen complexes 531
Drying processes 740, 754
Dyeing of fibers 108, 556, 740, 754
Effective diffusivities 687
Eicosene 79
Electrolytes 36,199,210,217,313
Enhancer 103
Enhancement factor 369
Entrainer 103, 677
Environment 669, 754
Enzymatic reactions 456, 458
Equations of state 62,147,183,185,194,197, 274, 299, 589, 620, 763
cubic equations of state 147, 156, 177, 178, 180, 187
extended virial equations of state 147, 157-161
Peng-Robinson equation of state 53, 62, 149,161,178
Redlich-Kwong equation of state 110, 148, 149, 161, 178,202
Van der Waals equation of state 148, 235, 243
virial equations of state 147,151,157-161, 164,202
Estrone 482
Ethane 79,92, 101,263-266,281,530,534, 731, 749,751
Ethylene 86, 87, 530, 533
Excess enthalpy 266
Excess number 370
Experimental techniques 764, 766
Extended classical theory 124
Extraction 697
Extractive effect 103, 106
Film deposition 595, 707, 708, 715, 716
Film stability 731-738
Flory-Huggins model 569
Fluctuation solution theory 191,211,215
Fluid phase equilibria 65, 75, 95, 118, 264, 589, 590,591
Fluid phases 91-112, 118, 481, 499, 739-757
Food applications 769-770
Fractionation 592,599,604,605, 608, 610, 611, 616,619
Fugacity 194
Functional groups 129
Gas-gas equilibrium 81,98
Geothermal energy 740, 755
Gibbs ensemble 288,389,406,418
Gibbs free energy 566
Gibbs stability criterion 39, 60
Gibbs triangle 69
Gibbs-Duhem integration 421
Gillan's method 374
Ginzburg number 243, 256
Glass transition 554, 555
Global phase diagrams 51,52, 63, 100
Group contribution methods 162, 163
Helium 81,430, 731
Helmholtz free energy 232, 233, 235, 236, 242, 252-256, 258, 260, 262, 761
Hexane 79
Hierarchical reference theory 325, 347
High pressure 91-112,425,499,550,592, 641-650, 731
High pressure cells 95-97, 527-531, 590, 647
Homologous series 141
Hydrogen 430,529,531-532,731
Hydrogen bonding 129,402,406,507,602,603, 605, 607-609, 611, 614, 616
Hydrogen chloride 506
Hydrothermal synthesis 740
Hypernetted chain 313, 365
Infrared spectroscopy 504, 514, 527, 530-536
Inorganic materials 596, 707-717
Integral equation calculations 328, 341, 344, 371, 441, 442
Integral equations 164,287,288,289,290,295, 307, 308, 313, 315, 328, 365, 439, 441, 442, 444, 762
Interfacial tension 731-738, 740
Intermolecular interactions 601
Intermolecular potential 276, 414
Ionic fluids 426
Isopycnic conditions 740
Kinetic theory 275, 276, 277
Kinetics 754
Kirkwood-Buff theory 191,215,367,440,441, 712-716 fluctuation integrals 368
Krichevskii parameter 369
Labik's method 376
Lennard-Jones potential 414
mixtures 430-433 Lever rule 72
Light scattering 232, 244, 249, 256, 579, 590, 591, 647-649
Liquid crystalline polymers 727, 728
Liquid crystals 748
Liquid-gas equilibrium see vapor-liquid equil.
Liquid-liquid equilibrium 98
Liquid-liquid-vapor equilibria 15-16, 65, 68, 70-81, 98-102, 120
Long range 289, 291, 292, 298, 300, 301, 302, 303, 307, 388, 389
Lower critical end point (LCEP) 68, 79, 80, 83,120 .
Lower critical solution temperature (LCST) 8~ 9~ 56~ 56~ 571, 57~ 600
Macromolecular phase separations 541, 565, 57~ 58~ 59~ 591, 594
793
Mass transfer coefficients 686, 740, 745, 751
Materials processing 594,595,707,708,715, 716, 719-728
Mean-field lattice-gas model 164, 589, 634-637
Metal-nitrous oxide complexes 533
Methane 79
Mixing rules 110-111,148,150,154,159, 177-181, 183, 185, 187, 614
Mobile phase 653, 656, 658, 659
Moderator 103,105,106,743,745,746
Modifiers 659-661, 663, 668, 743
Modar-process 699, 701, 702
Molecular dynamics 163,164,288,387,388, 39~ 39~ 401, 402, 40~ 43~ 442-444
Molecular fluids 167, 168,211,304,305,307, 394, 395, 406
Molecular interactions 163,211,439,441-444
Molecular simulation 163, 164, 387, 388, 389, 390, 401, 406, 411, 763
Monte Carlo simulation 163,164,287,288, 294,295,300,307,401,406,411,415
Multi-component mixtures 53, 66, 112, 154-156,159,180,214,592,646-648
N aphthelene 86
Near-critical mixtures 13-34,191,223, 439-444, 648
Near-critical solvents 19-36,127,128,129,130, 132, 141
Near-infrared spectroscopy 107, 504
Neutron scattering 232, 256
Nitrogen 96, 531, 731
Nitrous oxide 533
Non-classical dihydrogen complexes 531-532
Non-ideal mixtures 177, 181
Oil sands and oil shales 740
Optical fiber 528
Optical high-pressure cells 95, 96, 500, 502, 531, 562, 580, 590, 647
Organometallic photochemistry 527-537
Ornstein-Zernike equation 191,212,217,289, 329,341,350,366,441,442
Osmotic susceptibilities 15, 18
794
Overloading 655, 656, 662, 663
Oxidation 697
Oxides 707-717
Packed column 657. 659
Partial molar properties 27-28. 36. 192. 198. 222. 631. 63~ 63~ 67~ 753
Partial molar volwne 368. 465
Particle formation 596,708,719,723-728,753, 754
Partition coefficients 103.106.619. 620, 622. 631, 637, 745
Pelargonic acid 731
Pendant-drop method 731
Peng-Robinson equation of state 53, 62. 149. 161, 178
Pentane 78,574
Percus-Yevick 313. 365
Performance 595,596
Perturbed hard chain theory (PHCT) 168-170,172
pH 708, 710, 711. 713-717
Phase behavior 16.65.91-112. 118. 178. 180, 185. 187. 451. 591. 593. 594. 641-650
Phase diagrams 13, 65, 91-112, 118, 599, 600, 619,726
Phase equilibria 65,91-112,118,146,177,178. 411. 731. 745
Phase rule 66. 123
Phase separation kinetics 541.579. 740
Phase transformations 72
Phase transitions 91-112.233,234
Picard's method 372
Plait point 248. 251, 252
Polar fluids 154. 161. 170
Poly-aromatic hydrocarbons 136. 137. 144
Poly (dimethyl siloxane) 561
Poly (ethylene-co-acrylic acid) 599
Poly (ethylene-co-methyl acrylate) 599
Poly (ethylene terephthalate) 558
Poly (methyl methacrylate) 557
Poly (vinyl alcohol) 565
Polycarbonate 559
Polyethylene 87. 491. 493. 520. 541. 559. 563. 573, 574, 576. 593. 594. 597. 602-604. 608. 613. 621
Polypropylene 541. 576
Polystyrene 545. 552. 557. 571, 572. 574. 576, 597
Polymer gels 589. 597
Polymeri~r~tion 53~ 55~59~ 619
Polymer modification 541
Polymerproces,sing 541.589.599.619
Polymer properties 554. 589
Polymer solutions 257. 427. 541. 565. 569. 589. 768
Polymer swelling 556. 597. 632. 634. 636
Polymerization 455.461.491.518.520,541. 542-554
Preparative chromatography 654. 658. 660. 668
Pressure jump techniques 541.579
Production-scale chromatography 654
Propane 81. 136
Prostaglandins 658. 659, 661
Protein powders 719.726.727
P, T -projection 70
P,T,x diagram 69,120.570
Quadruple point 121
Quaternary systems 105
Quantitative spectroscopy 107.499.509.512. 514
R134a 262
Raman spectroscopy 527-529
Rapid expansion 592.596.707.708.715.716, 719-725. 753
Reaction equilibriwn 699
Reaction rate 56. 699
Reactions 56.449.487.512.527-537,564.683. 754
Recycling 541. 564. 589. 598. 658. 742. 743
Redlich-Kwong equation of state 52. 54. 56. 62. 110. 148. 149. 161. 178
Renormalizationgroup 164.236,239,245, 255. 258. 331
Repulsive mixtures 370. 398. 439-442. 444
Residence time 300
Sanchez-Lacombe model 541 576
Scale-up 655. 662. 743. 755
Scaling law 236. 237. 252, 327. 342. 343. 345. 354.357
Selectivity 103, 105, 106,206,481, 484, 489, 619 743,745
Separation factor 103, 106
Short range 287, 289, 291, 301, 302, 303, 304, 388,390
Simple fluids 307, 394, 396, 406
Soil 673, 697, 754
Solid-fluid equilibria 87, 106, 120, 202, 678
Solid matrices 595, 669
Solid-liquid-Ii quid-vapor equilibria 68,84, 121
Solid-liquid-vapor equilibria 15, 65, 85, 87, 107, 121, 138
Solubility 15,87,106, lJO, 193, 200, 565, 570, 641, 676, 707-717, 745
Solute retention 631, 633, 642
Solute-solute interactions 439, 440, 442-444
Solute-solvent 287, 289, 301, 302, 303, 388, 389, 400,401
Solvent-solvent 289, 301, 303, 400
Spectroscopic process control 512, 522
Specific heat capacity 236, 237, 239, 253, 260, 261,265
Spices 740, 742
Spinodal 217,313, 316, 342, 343, 567, 581, 582, 591, 720
Stability criterion 39, 40, 42
Stationary phase 653, 656, 657
Statistical associating fluid theory (SAFn 171,172,541,576,589,598,610,613-615,619, 620
Statistical mechanics 163,191, 2lJ, 287, 289, 387
Stearic acid 731
Stereoregularity 546
Stereoregulation 672
Sterilization offood 754
Structure factor 232,233,237
Supercritical anti solvent (SAS) 620, 621
Supercritical aqueous solutions 222, 288, 307, 389, 399, 401, 707-717, 754
Supercritical extraction 206,592,619,669, 675, 690, 731
Supercritical fluid chromatography 92, 98, 103, 631-639, 641-646, 653, 740, 742-753, 765
Capacity ratio 740, 745, 750
Density programmed 747
Detectors 746
Diffusion coefficients 749-751
Efficiency 746
Gradient techniques 745, 749
HETP values 746, 751, 749
Resolution 745
Retention time 745
Retention volume 745
795
Supercritical fluid extraction 91, 98, 103, 433,592, 645-650, 670, 680, 702, 740, 741-743, 755
Coal 742
Countercurrent distillation 743
Decaffeination of coffee and tea 740, 742, 743
Hops 740, 742
Membrane technologies 743
Supercritical fluids 91-112, 196, 200, 231, 243, 287, 288, 289, 293, 300, 307, 308, 387, 388, 390, 398, 400, 406, 425, 449, 482, 527, 541, 543, 551, 561,570,598, 619, 739, 741, 753, 761
Supercritical processing 541,594, 596, 707, 708, 715, 716, 719-728, 743
Supercritical solubility 15,32-34,707-717
Supercritical water 4,24,91,281,401,402,452 697, 707-717, 754
Supercritical water oxidation (SCWO) 697, 698, 699, 702
Surface tension 731-738, 740
T acticity 546
Ternary mixtures 103, 434, 574, 575, 622
Tertiary oil recovery 740, 755
Test particles 417
Tetradecane 81
Thermal conductivity 233, 238-240, 243, 244, 246, 248, 250, 251, 274, 276, 277, 279, 280, 281
Thermal diffusivity 233, 239, 240, 246-248
Thermodynamic properties 93, 192, 197, 208, 211, 232, 233, 236, 252, 254, 258, 260-265, 287, 289, 290, 294, 298, 299, 303, 387, 631, 739, 740
Thermodynamics 631-639, 711, 712
Time-resolved spectroscopy 524
Tobacco expansion 754
Tocopherols 658, 661, 662, 663
Transition-state theory 462
Transport properties 93,231,273,274,278, 279, 281, 388, 396, 398, 400, 739
Tricritical phenomena 60, 63, 99, lJ8, 123, 124
796
Tricritical points 61,62,63, 123, 124, 129
Tridecane 81
Triglycerides 127
Triphenylmethane 81
T-x projections 70
Upper critical end point (UCEP) 68, 78-84, 120
Upper critical solution temperature (UCST) 84, 98-102, 567, 568, 571, 575, 593, 600
Van der Waals equation of state 148
Van Konynenburg and Scott classification 75,99,117,118,120
Vapor-liquid equilibrium 98, 177, 178, 183, 261-262,265, 641-650
Virial equations of state 147, 151, 157-161, 164,202
Viscosity 233, 238, 239, 241, 245, 246, 248, 249, 274, 275, 276, 277, 279, 280, 281, 390, 396, 397, 400, 560-563, 731, 739
Waste treatment 91, 598, 669, 697, 740, 754
Water 4, 24, 30, 31, 32, 76, 81, 281, 288, 305, 389,401-406,415,425,452,697, 698, 707-717, 754
Weekly attractive mixtures 370
Wet air oxidation 697, 698, 699
Wiener-Hopf decomposition 377
Wood 564, 742
~on 81, 52~ 532