apparatus for spatially resolved impedance spectroscopy on … · 2014-11-17 · institute for...
TRANSCRIPT
T. Sandersa, T. Baumhöfera, D. U. Sauera, A. Schröderb,
K. Wippermannb, J. Mergelb, D. Stoltenb
aElectrochemical Energy Conversion and Storage Systems
Prof. Dr. rer. nat. Dirk Uwe Sauer
Institute for Power Electronics and Electrical Drives (ISEA) RWTH Aachen University
Univ.-Prof. Dr. ir. R. W. De Doncker
bInstitute of Energy Research, IEF-3: Fuel Cells
Forschungszentrum Jülich GmbH
Apparatus for spatially resolved impedance
spectroscopy on DMFC and PEM Fuel Cells
with special regard to fuel concentration
oscillations in gas channels
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 2
Motivation
“Flipping” effect observed in measurements
Caused by measurement method
Not a consequence of MEA stateSource:
Oscillations in Gas Channels II.I. A. Schneider et al.
Journal of The Electrochemical Society
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 3
Outline
The cause for the measurement effect
Influence of various factors
Model based
An advanced measurement setup
“EIScell” measurement hardware
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 4
Commonly used measurement setup
The full cell is excited by one voltage source
Spatially resolved current measurement n
ACn
I
VZ =
Oxygen flo
w
VAC
I1
I2
I3
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 5
Influence of concentration oscillations
Oxygen flo
w
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 6
Influences
Absolute oxygen concentration
Frequency
Limited Diffusion
Excitation amplitude No influence
1
22
1
21
CqFz
RT
dI
dU=
Spectra: 10 Segments, linear channel
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 7
Advanced measurement setup
Single excitation, sequential measurement
Problem: in-plane resistance
Smaller concentration oscillation amplitude
Influence only from neighboring segments
11 +− ++=
nnn
nn
III
VZ
V1 I1
I2
I3
V2
V3
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 8
Comparison
Cell excitation Single segment excitation
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 9
Comparison (Zoom)
Cell excitation Single segment excitation
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 10
EIScell
54 independent channels
± 2.5 V, ± 2.5 A per channel
AC response from all I,V simultaneously
DC measurements
I-V curves
Automated
Integration of test stand control
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 11
Contacting
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 12
Shunt Resistors
Voltage drop across shunt
resistors leads to an equalization
of measured currents
For the given test cell
resistances below 10mΩ would
be needed
Not suitable for measurement of
small currents
ShuntResistors Segments
In-planeResistances
25 mA
25 mA
25 mA25 mA
25 mA
25 mA
VmmAVmeas µ10101 =Ω⋅=
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 13
Shunt Resistors
Voltage drop across shunt
resistors leads to an equalization
of measured currents
For the given test cell
resistances below 10mΩ would
be needed
Not suitable for measurement of
small currents
ShuntResistors Segments
In-planeResistances
50 mA
25 mA
25 mA32 mA
36 mA
32 mA
VmmAVmeas µ10101 =Ω⋅=
Vdiff
Vdiff
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 14
Compensated Shunt Resistor
Measurement signal range can be optimized (variable shunt resistance)
No influence by wire resistance (Kelvin connection)
Parallel measurement up to high frequencies
mVmAVmeas 111 =Ω⋅=
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 15
First Measurement ResultsO
xygen flo
w
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 16
Summary
“Flipping” in spectra is no result from the MEA state, but a measurement influence caused by concentration oscillations.
By using another measurement setup the effect can be reduced.
Magnitude of improvement dependent on relation between in-plane and
segment impedance
A compensated shunt resistor allows for precise spatially resolved current measurement without affecting the current
distribution.
6/23/2009
T. BaumhöferInstitute for Power Electronics and Electrical Drives Slide 17
Thank you for your attention
T. Sandersa, T. Baumhöfera, D. U. Sauera, A. Schröderb,
K. Wippermannb, J. Mergelb, D. Stoltenb
aElectrochemical Energy Conversion and Storage Systems
Prof. Dr. rer. nat. Dirk Uwe Sauer
Institute for Power Electronics and Electrical Drives (ISEA) RWTH Aachen University
Univ.-Prof. Dr. ir. R. W. De Doncker
bInstitute of Energy Research, IEF-3: Fuel Cells
Forschungszentrum Jülich GmbH
Apparatus for spatially resolved impedance
spectroscopy on DMFC and PEM Fuel Cells
with special regard to fuel concentration
oscillations in gas channels