annex: exposure scenarios - schloetter co ltd · emission factor soil 0.01 % receive surf. water...

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Annex: Exposure Scenarios 1. Short title of exposure scenario Manufacture of substance, Distribution of substance SU3; SU8, SU9; ERC1; PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC9; PC19 Control of exposure and risk management measures Contributing exposure scenario Use descriptors covered ERC1: Manufacture of substances Operational conditions Annual amount per site 288,000,000 kg Minimum emission days per year Continuous 300 Emission factor air 0.00 % Emission factor water 0.30 % Emission factor soil 0% Receive Surf. Water (Flow Rate). 18,000 m3/d Dilution factor river 10 Dilution factor coast 100 Other Factors: Environment Indoor use. Risk Management Measures Type of STP Municipal STP Assumed sewage treatment plant flow (m3/d) 2,000 m3/d Exposure estimate and reference to its source Risk Characterization Ratio (RCR) 0.514 Risk from environmental exposure is driven by marine water. Maximum amount of safe use 1,869 kg/d Risk from environmental exposure is driven by marine sediment. Contributing exposure scenario Use descriptors covered ERC1: Manufacture of substances Operational conditions Annual amount per site 288,000,000 kg Minimum emission days per year Continuous 300 Emission factor air 0.001 % Emission factor water 0.05 %

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Page 1: Annex: Exposure Scenarios - Schloetter Co Ltd · Emission factor soil 0.01 % Receive Surf. Water (Flow Rate). 18,000 m3/d Dilution factor river 10 Dilution factor coast 100 Other

Annex: Exposure Scenarios

1. Short title of exposure scenarioManufacture of substance, Distribution of substanceSU3; SU8, SU9; ERC1; PROC1, PROC2, PROC3, PROC8a, PROC8b, PROC9; PC19

Control of exposure and risk management measuresContributing exposure scenario

Use descriptors coveredERC1: Manufacture of substances

Operational conditions

Annual amount per site288,000,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.00 %

Emission factor water0.30 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Dilution factor river10

Dilution factor coast100

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use1,869kg/d

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredERC1: Manufacture of substances

Operational conditions

Annual amount per site288,000,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.001 %

Emission factor water0.05 %

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Emission factor soil0.01 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Dilution factor river10

Dilution factor coast100

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use1,869kg/d

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC1: Use in closed process, no likelihood of exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Exposure estimate and reference to its sourceAssessment method ECETOC TRA v2.0 Worker

Worker - dermal, short-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.3571Assessment method ECETOC TRA v2.0 Worker

Worker - dermal, long-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.1Assessment method ECETOC TRA v2.0 Worker

Worker - inhalative, long-term - localExposure estimate 0.03 mg/m³Risk Characterization Ratio (RCR) 0.001

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

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Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 3.0042 mg/m³Risk Characterization Ratio (RCR) 0.1001Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity240 min 5 days per week

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Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 18.0250 mg/m³Risk Characterization Ratio (RCR) 0.6008Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

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Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 7.5104 mg/m³Risk Characterization Ratio (RCR) 0.2503Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modified

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version: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8a: Transfer of substance or preparation(charging/discharging) from/to ves-sels/large containers atnon-dedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.02

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Assessment method ECETOC TRA v2.0 Worker; modified versionWorker - inhalative, long-term - local

Exposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 4.5063 mg/m³Risk Characterization Ratio (RCR) 0.1502Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

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Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Wear suitable respiratory protection. Effectiveness: 90 %In case no respiratory protection isused:, Reduce duration of activity toless than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC9: Transfer of substance or preparation into smallcontainers (dedicated filling line, including weighing).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Page 9: Annex: Exposure Scenarios - Schloetter Co Ltd · Emission factor soil 0.01 % Receive Surf. Water (Flow Rate). 18,000 m3/d Dilution factor river 10 Dilution factor coast 100 Other

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

* * * * * * * * * * * * * * * *

2. Short title of exposure scenarioPolymer production, Use as MonomerSU3; SU8, SU9; ERC6c; PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9; PC19

Control of exposure and risk management measuresContributing exposure scenario

Use descriptors coveredERC6a: Industrial use resulting in manufacture of anothersubstance (use of intermediates)

Operational conditions

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Annual amount per site64,318,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.001 %

Emission factor water0.05 %

Emission factor soil0.01 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Dilution factor river10

Dilution factor coast100

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use417,417kg/d

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC1: Use in closed process, no likelihood of exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Exposure estimate and reference to its sourceAssessment method ECETOC TRA v2.0 Worker

Worker - dermal, short-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.3571Assessment method ECETOC TRA v2.0 Worker

Worker - dermal, long-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.1Assessment method ECETOC TRA v2.0 Worker

Worker - inhalative, long-term - localExposure estimate 0.03 mg/m³

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Risk Characterization Ratio (RCR) 0.001

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 3.0042 mg/m³Risk Characterization Ratio (RCR) 0.1001Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

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Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity240 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 18.0250 mg/m³Risk Characterization Ratio (RCR) 0.6008Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresProvide extract ventilation to points Effectiveness: 90 %

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where emissions occur (LEV).Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 7.5104 mg/m³Risk Characterization Ratio (RCR) 0.2503Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modified

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version: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment methodECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaust

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ventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 6.0083 mg/m³Risk Characterization Ratio (RCR) 0.2003Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 12.0167 mg/m³Risk Characterization Ratio (RCR) 0.4006Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (see

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exposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC5: Mixing or blending in batch processes forformulation of preparations and articles (multistage and/orsignificant contact).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 1.4286

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 0.4Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenarioUse descriptors covered SU3: Industrial uses

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PROC8a: Transfer of substance or preparation(charging/discharging) from/to ves-sels/large containers atnon-dedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

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Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 4.5063 mg/m³Risk Characterization Ratio (RCR) 0.1502Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)

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Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Wear suitable respiratory protection. Effectiveness: 90 %In case no respiratory protection isused:, Reduce duration of activity toless than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC9: Transfer of substance or preparation into smallcontainers (dedicated filling line, including weighing).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequate

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effectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

* * * * * * * * * * * * * * * *

3. Short title of exposure scenarioPolymer production, Use as MonomerSU3; SU8, SU9, SU12; ERC6c, ERC6b; PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b,PROC9; PC19, PC32

Control of exposure and risk management measuresContributing exposure scenario

Use descriptors coveredERC6c: Industrial use of monomers for manufacture ofthermoplastics

Operational conditions

Annual amount per site16,250,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.01 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.

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Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredERC6c: Industrial use of monomers for manufacture ofthermoplastics

Operational conditions

Annual amount per site11,700,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.01 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors covered

ERC6d: Industrial use of process regulators forpolymerisation processes in production of resins, rubbers,polymers

Operational conditions

Annual amount per site16,250,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.01 %

Emission factor water1 %

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Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors covered

ERC6d: Industrial use of process regulators forpolymerisation processes in production of resins, rubbers,polymers

Operational conditions

Annual amount per site11,700,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.01 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredERC6c: Industrial use of monomers for manufacture ofthermoplastics

Operational conditions

Annual amount per site3,250,000 kg

Minimum emission days per year 300

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Continuous

Emission factor air1 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredERC6c: Industrial use of monomers for manufacture ofthermoplastics

Operational conditions

Annual amount per site3,250,000 kg

Minimum emission days per yearContinuous

300

Emission factor air1 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredERC6d: Industrial use of process regulators forpolymerisation processes in production of resins, rubbers,polymers

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Operational conditions

Annual amount per site3,250,000 kg

Minimum emission days per yearContinuous

300

Emission factor air1 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors covered

ERC6d: Industrial use of process regulators forpolymerisation processes in production of resins, rubbers,polymers

Operational conditions

Annual amount per site3,250,000 kg

Minimum emission days per yearContinuous

300

Emission factor air1 %

Emission factor water1 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use105,462 kg

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Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC1: Use in closed process, no likelihood of exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Exposure estimate and reference to its sourceAssessment method ECETOC TRA v2.0 Worker

Worker - dermal, short-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.3571Assessment method ECETOC TRA v2.0 Worker

Worker - dermal, long-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.1Assessment method ECETOC TRA v2.0 Worker

Worker - inhalative, long-term - localExposure estimate 0.03 mg/m³Risk Characterization Ratio (RCR) 0.001

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its sourceAssessment method ECETOC TRA v2.0 Worker; modified version, ECETOC

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TRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 3.0042 mg/m³Risk Characterization Ratio (RCR) 0.1001Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity240 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.

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Worker - dermal, long-term - localExposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 18.0250 mg/m³Risk Characterization Ratio (RCR) 0.6008Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 7.5104 mg/m³

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Risk Characterization Ratio (RCR) 0.2503Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditionsConcentration of the substance acrylic acid

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Content: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 6.0083 mg/m³Risk Characterization Ratio (RCR) 0.2003Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor Indoor

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Exposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 12.0167 mg/m³Risk Characterization Ratio (RCR) 0.4006Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC5: Mixing or blending in batch processes forformulation of preparations and articles (multistage and/orsignificant contact).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 min

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Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 1.4286

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 0.4Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8a: Transfer of substance or preparation(charging/discharging) from/to ves-sels/large containers atnon-dedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment methodECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation of

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dermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modified

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version: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 4.5063 mg/m³Risk Characterization Ratio (RCR) 0.1502Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Wear suitable respiratory protection. Effectiveness: 90 %In case no respiratory protection isused:, Reduce duration of activity toless than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³

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Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC9: Transfer of substance or preparation into smallcontainers (dedicated filling line, including weighing).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

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* * * * * * * * * * * * * * * *

4. Short title of exposure scenarioPolymer productionSU3; SU8, SU9; ERC6a; PROC1, PROC2, PROC3, PROC4, PROC5, PROC8a, PROC8b, PROC9; PC19

Control of exposure and risk management measuresContributing exposure scenario

Use descriptors coveredERC6a: Industrial use resulting in manufacture of anothersubstance (use of intermediates)

Operational conditions

Annual amount per site64,318,000 kg

Minimum emission days per yearContinuous

300

Emission factor air0.001 %

Emission factor water0.05 %

Emission factor soil0.01 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Dilution factor river10

Dilution factor coast100

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use417,417kg/d

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC1: Use in closed process, no likelihood of exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor Indoor

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Exposed skin area Palm of one hand (240 cm²)Exposure estimate and reference to its sourceAssessment method ECETOC TRA v2.0 Worker

Worker - dermal, short-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.3571Assessment method ECETOC TRA v2.0 Worker

Worker - dermal, long-term - localExposure estimate 100 µg/cm²Risk Characterization Ratio (RCR) 0.1Assessment method ECETOC TRA v2.0 Worker

Worker - inhalative, long-term - localExposure estimate 0.03 mg/m³Risk Characterization Ratio (RCR) 0.001

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²

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Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 3.0042 mg/m³Risk Characterization Ratio (RCR) 0.1001Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC2: Use in closed, continuous process with occasionalcontrolled exposure.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity240 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.1429

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 40 µg/cm²Risk Characterization Ratio (RCR) 0.04Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 18.0250 mg/m³Risk Characterization Ratio (RCR) 0.6008Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC3: Use in closed batch process (synthesis or

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formulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 7.5104 mg/m³Risk Characterization Ratio (RCR) 0.2503Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC3: Use in closed batch process (synthesis orformulation).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

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Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitable

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respiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 6.0083 mg/m³Risk Characterization Ratio (RCR) 0.2003Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC4: Use in batch and other process (synthesis) whereopportunity for exposure arises.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity60 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143Assessment method ECETOC TRA v2.0 Worker; modified version, ECETOC

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TRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 12.0167 mg/m³Risk Characterization Ratio (RCR) 0.4006Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC5: Mixing or blending in batch processes forformulation of preparations and articles (multistage and/orsignificant contact).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 1.4286

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.

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Worker - dermal, long-term - localExposure estimate 400 µg/cm²Risk Characterization Ratio (RCR) 0.4Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8a: Transfer of substance or preparation(charging/discharging) from/to ves-sels/large containers atnon-dedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

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Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 4.5063 mg/m³Risk Characterization Ratio (RCR) 0.1502Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenarioUse descriptors covered SU3: Industrial uses

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PROC8b: Transfer of substance or preparation(charging/discharging) from/to vessels/large containers atdedicated facilities

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Wear suitable respiratory protection. Effectiveness: 90 %In case no respiratory protection isused:, Reduce duration of activity toless than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors covered

SU3: Industrial usesPROC9: Transfer of substance or preparation into smallcontainers (dedicated filling line, including weighing).

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

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Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of both hands (480 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness ., Alternatively:, Reduceduration of activity to less than 15 minExposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.7143

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 200 µg/cm²Risk Characterization Ratio (RCR) 0.2Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 15.0208 mg/m³Risk Characterization Ratio (RCR) 0.5007Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

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5. Short title of exposure scenarioUse in laboratoriesSU22; SU8, SU9, SU24; ERC1; PROC15; PC19, PC21

Control of exposure and risk management measuresContributing exposure scenario

Use descriptors coveredERC1: Manufacture of substances

Operational conditions

Annual amount per site288,000,000 kg

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Minimum emission days per yearContinuous

300

Emission factor air0.00 %

Emission factor water0.30 %

Emission factor soil0 %

Receive Surf. Water (Flow Rate).18,000 m3/d

Dilution factor river10

Dilution factor coast100

Other Factors: Environment Indoor use.Risk Management MeasuresType of STP Municipal STPAssumed sewage treatment plant flow (m3/d) 2,000 m3/dExposure estimate and reference to its sourceRisk Characterization Ratio (RCR) 0.514

Risk from environmental exposure is driven by marinewater.

Maximum amount of safe use1,869kg/d

Risk from environmental exposure is driven by marine sediment.

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC15: Use a laboratory reagent.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity480 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresProvide extract ventilation to pointswhere emissions occur (LEV).

Effectiveness: 90 %

Use suitable chemically resistantgloves.

Effectiveness: 80 %

In case no suitable local exhaustventilation is present:, Wear a suitablerespiratory protection with adequateeffectiveness .Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modified

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version: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

Worker - inhalative, long-term - localExposure estimate 3.0042 mg/m³Risk Characterization Ratio (RCR) 0.1001Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

Contributing exposure scenario

Use descriptors coveredSU3: Industrial usesPROC15: Use a laboratory reagent.

Operational conditions

Concentration of the substanceacrylic acidContent: >= 0 % - <= 100 %

Physical state liquid

Duration and Frequency of activity240 min 5 days per week

Indoor/Outdoor IndoorExposed skin area Palm of one hand (240 cm²)Risk Management MeasuresUse suitable chemically resistantgloves.

Effectiveness: 80 %

Exposure estimate and reference to its source

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, short-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.0714

Assessment method

ECETOC TRA v2.0 Worker; modified version, ECETOCTRA modified version: Reduction factor for local exhaustventilation (LEV) has not been used for the calculation ofdermal exposure estimates., ECETOC TRA modifiedversion: Use of gloves has been considered additionally.Worker - dermal, long-term - local

Exposure estimate 20 µg/cm²Risk Characterization Ratio (RCR) 0.02Assessment method ECETOC TRA v2.0 Worker; modified version

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Worker - inhalative, long-term - localExposure estimate 18.0250 mg/m³Risk Characterization Ratio (RCR) 0.6008Guidance to Downstream UsersFor scaling see: http://www.ecetoc.org/tra Please note that a modified version has been used (seeexposure estimates)

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