hey! there’s lead in my water!

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The world leader in serving science

Hey! There’s Lead in my Water!

The Drinking Water Contamination Issue

Facing Residents of Flint, MI

2

How Does Lead Get Into my Drinking Water?

Lead in Drinking Water

3

How Does Lead Get Into my Drinking Water?

• Most households contain lead pipes or pipes with lead solder joints

Lead in Drinking Water

4

How Does Lead Get Into my Drinking Water?

• Most households contain lead pipes or pipes with lead solder joints

• Corrosive water passes through

the pipes

Lead in Drinking Water

5

How Does Lead Get Into my Drinking Water?

• Most households contain lead pipes or pipes with lead solder joints

• Corrosive water passes through

the pipes

• Chemical reactions take

place between the pipes

and the water

Lead in Drinking Water

6

How Does Lead Get Into my Drinking Water?

• Most households contain lead pipes or pipes with lead solder joints

• Corrosive water passes through

the pipes

• Chemical reactions take

place between the pipes

and the water

• Some of the lead dissolves

into the water

Lead in Drinking Water

7

How Does Lead Get Into my Drinking Water?

• Most households contain lead pipes or pipes with lead solder joints

• Corrosive water passes through

the pipes

• Chemical reactions take

place between the pipes

and the water

• Some of the lead dissolves

into the water

Lead in Drinking Water

Let’s Look at This

in More Detail…

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Lead in Drinking Water

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Lead in Drinking Water

10

Lead in Drinking Water

• Acidic (pH ~4-7)

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Lead in Drinking Water

• Acidic (pH ~4-7)

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Lead in Drinking Water

• Low alkalinity

CO32-

CO32-

CO32-

CO32-

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Lead in Drinking Water

• High temperature

water

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Lead in Drinking Water

• Saline (high levels of dissolved salts)

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Lead in Drinking Water

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Lead in Drinking Water

Attributes of Flint River

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Lead in Drinking Water

• Low pH

Attributes of Flint River

18

Lead in Drinking Water

• Low pH

• High salinity

• High levels of chlorides

Attributes of Flint River

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Lead in Drinking Water

20

There are 3 Common Sources For Chloride in Natural Waters:

Lead in Drinking Water

21

There are 3 Common Sources For Chloride in Natural Waters:

Lead in Drinking Water

Cl-

Cl-

1) Naturally occurring chloride salts

Cl- Cl-

Cl- Cl-

Cl-

Cl-

22

There are 3 Common Sources For Chloride in Natural Waters:

Lead in Drinking Water

2) Runoff from road salts

23

There are 3 Common Sources For Chloride in Natural Waters:

Lead in Drinking Water

3) Water disinfection chemicals

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Lead in Drinking Water

25

Lead in Drinking Water

Challenges in Treating Flint River Water

26

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

Challenges in Treating Flint River Water

27

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

• Chloride reacts with iron pipes to form ferric chloride (FeCl3)

• Reaction with iron ties up chloride that should be disinfecting the water

• Additional chlorine must be added for disinfection

Challenges in Treating Flint River Water

28

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

• Chloride reacts with iron pipes to form ferric chloride (FeCl3)

• Reaction with iron ties up chloride that should be disinfecting the water

• Additional chlorine must be added for disinfection

• Organic matter present in Flint River

Challenges in Treating Flint River Water

29

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

• Chloride reacts with iron pipes to form ferric chloride (FeCl3)

• Reaction with iron ties up chloride that should be disinfecting the water

• Additional chlorine must be added for disinfection

• Organic matter present in Flint River

• Additional chlorine reacts with the organic matter

• Reaction produces trihalomethane (THM) by-products

• THMs well-known for carcinogenic properties

Challenges in Treating Flint River Water

30

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

• Chloride reacts with iron pipes to form ferric chloride (FeCl3)

• Reaction with iron ties up chloride that should be disinfecting the water

• Additional chlorine must be added for disinfection

• Organic matter present in Flint River

• Additional chlorine reacts with the organic matter

• Reaction produces trihalomethane (THM) by-products

• THMs well-known for carcinogenic properties

• Flint River has a naturally low pH

Challenges in Treating Flint River Water

31

Lead in Drinking Water

• Flint River has naturally excessive levels of chloride

• Chloride reacts with iron pipes to form ferric chloride (FeCl3)

• Reaction with iron ties up chloride that should be disinfecting the water

• Additional chlorine must be added for disinfection

• Organic matter present in Flint River

• Additional chlorine reacts with the organic matter

• Reaction produces trihalomethane (THM) by-products

• THMs well-known for carcinogenic properties

• Flint River has a naturally low pH

• Reaction with iron and lack of corrosion inhibitors for water treatment help

maintain low pH

• Acidic environment promotes reaction with lead in pipes

Challenges in Treating Flint River Water

32

Lead in Drinking Water

33

Lead in Drinking Water

• Corrosive Water

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Lead in Drinking Water

• Corrosive Water + Lead Pipes

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Lead in Drinking Water

• Corrosive Water + Lead Pipes = Lead Contaminated Water

Pb

Pb

36

Lead in Drinking Water

37

How Can We Stop Pipes From Corroding?

Lead in Drinking Water

38

How Can We Stop Pipes From Corroding?

Lead in Drinking Water

1. Water Treatment –

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How Can We Stop Pipes From Corroding?

Lead in Drinking Water

1. Water Treatment –

• Filter to reduce the amount of chloride present

• Treat water to adjust pH, salinity, hardness

40

How Can We Stop Pipes From Corroding?

Lead in Drinking Water

1. Water Treatment –

• Filter to reduce the amount of chloride present

• Treat water to adjust pH, salinity, hardness

2. Corrosion Control –

41

How Can We Stop Pipes From Corroding?

Lead in Drinking Water

1. Water Treatment –

• Filter to reduce the amount of chloride present

• Treat water to adjust pH, salinity, hardness

2. Corrosion Control –

• Addition of certain chemicals

affects the chemistry in the water

• They can increase the pH of the water

• They can promote scale growth along the

walls of the pipes

• Orthophosphates found to be most effective

for a range of plumbing materials

42

Lead in Drinking Water

43

Corrosion Control

Lead in Drinking Water

44

Corrosion Control

Lead in Drinking Water

The Plumbing Superhero to Fight Against Corrosion

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Corrosion Control

Lead in Drinking Water

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

46

Corrosion Control

Lead in Drinking Water

• Orthophosphates react to form lead compounds - low solubility

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

47

Corrosion Control

Lead in Drinking Water

• Orthophosphates react to form lead compounds - low solubility

• Insoluble precipitate forms protective layers on inside of pipes

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

48

Corrosion Control

Lead in Drinking Water

• Orthophosphates react to form lead compounds - low solubility

• Insoluble precipitate forms protective layers on inside of pipes

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

Without Corrosion Inhibitors

49

Corrosion Control

Lead in Drinking Water

• Orthophosphates react to form lead compounds - low solubility

• Insoluble precipitate forms protective layers on inside of pipes

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

Without Corrosion Inhibitors

• Water reacts with the lead-containing pipes

50

Corrosion Control

Lead in Drinking Water

• Orthophosphates react to form lead compounds - low solubility

• Insoluble precipitate forms protective layers on inside of pipes

The Plumbing Superhero to Fight Against Corrosion

With Corrosion Inhibitors

Without Corrosion Inhibitors

• Water reacts with the lead-containing pipes

• Lead dissolves, generally as PbCO3 (PbCl2 soluble in hot water)

Pb Pb

Pb

Pb

Pb

51

Lead in Drinking Water

52

How Much is “Too Much” Lead in Drinking Water?

Lead in Drinking Water

53

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

Lead in Drinking Water

54

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

• Safe Water Drinking Act (SWDA) and Lead

Copper Rule (LCR)

Lead in Drinking Water

55

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

• Safe Water Drinking Act (SWDA) and Lead

Copper Rule (LCR)

• Maximum Contaminant Level

• Goal Concentration = 0 µg/L Pb

• Action Level Concentration = 15 µg/L Pb

Lead in Drinking Water

56

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

• Safe Water Drinking Act (SWDA) and Lead

Copper Rule (LCR)

• Maximum Contaminant Level

• Goal Concentration = 0 µg/L Pb

• Action Level Concentration = 15 µg/L Pb

Centers for Disease Control and Prevention (CDC)

Lead in Drinking Water

57

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

• Safe Water Drinking Act (SWDA) and Lead

Copper Rule (LCR)

• Maximum Contaminant Level

• Goal Concentration = 0 µg/L Pb

• Action Level Concentration = 15 µg/L Pb

Centers for Disease Control and Prevention (CDC)

• No safe concentration for Pb in blood

Lead in Drinking Water

58

How Much is “Too Much” Lead in Drinking Water?

Environmental Protection Agency (EPA)

• Safe Water Drinking Act (SWDA) and Lead

Copper Rule (LCR)

• Maximum Contaminant Level

• Goal Concentration = 0 µg/L Pb

• Action Level Concentration = 15 µg/L Pb

Centers for Disease Control and Prevention (CDC)

• No safe concentration for Pb in blood

• Blood lead levels (BLLs) containing 5 µg/dL could indicate

exposure to high levels of Pb

Lead in Drinking Water

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Lead in Drinking Water

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Lead in Drinking Water

Health Effects From Exposure to Lead

61

• Well-known toxin

Lead in Drinking Water

Health Effects From Exposure to Lead

62

• Well-known toxin

• Affects most organ systems in humans

• Infants/children experience more severe effects

Lead in Drinking Water

Health Effects From Exposure to Lead

63

• Well-known toxin

• Affects most organ systems in humans

• Infants/children experience more severe effects

• Symptoms in adults include:

Lead in Drinking Water

Health Effects From Exposure to Lead

64

• Well-known toxin

• Affects most organ systems in humans

• Infants/children experience more severe effects

• Symptoms in adults include:

• Joint and muscle pain

• Abdominal pain

• Headaches

• High blood pressure

• Memory loss

Lead in Drinking Water

Health Effects From Exposure to Lead

65

• Well-known toxin

• Affects most organ systems in humans

• Infants/children experience more severe effects

• Symptoms in adults include:

• Joint and muscle pain

• Abdominal pain

• Headaches

• High blood pressure

• Memory loss

• Symptoms in children include:

Lead in Drinking Water

Health Effects From Exposure to Lead

66

• Well-known toxin

• Affects most organ systems in humans

• Infants/children experience more severe effects

• Symptoms in adults include:

• Joint and muscle pain

• Abdominal pain

• Headaches

• High blood pressure

• Memory loss

• Symptoms in children include:

• Developmental delays (physical and mental)

• Loss of appetite

• Abdominal pain

• Stunted growth

Lead in Drinking Water

Health Effects From Exposure to Lead

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Lead in Drinking Water

68

Lead in Drinking Water

How Much Lead is in Your Drinking Water?

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Lead in Drinking Water

How Much Lead is in Your Drinking Water?

70

• Contact your local water municipality

• Collect and submit a water sample for testing

Lead in Drinking Water

How Much Lead is in Your Drinking Water?

71

• Contact your local water municipality

• Collect and submit a water sample for testing

Lead in Drinking Water

How Much Lead is in Your Drinking Water?

Additional Resources

72

• Contact your local water municipality

• Collect and submit a water sample for testing

Lead in Drinking Water

How Much Lead is in Your Drinking Water?

Additional Resources

• EPA document: Actions You Can Take to Reduce Lead in Drinking Water

(http://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=20001R4V.txt)

73

• Contact your local water municipality

• Collect and submit a water sample for testing

Lead in Drinking Water

How Much Lead is in Your Drinking Water?

Additional Resources

• EPA document: Actions You Can Take to Reduce Lead in Drinking Water

(http://nepis.epa.gov/Exe/ZyPDF.cgi?Dockey=20001R4V.txt)

• WHO guidelines and general education for lead

(http://www.who.int/ipcs/features/lead..pdf)

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