cheminform abstract: synthesis of alkylarylcarbinols via the reaction of organoboranes with...
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1997 alcohols
alcohols (benzene compounds)Q 0230
22 - 089Synthesis of Alkylarylcarbinols via the Reaction of Organoboraneswith Arylmethyl Chlorides. — The reaction of (α-chloroaryl)methylanions, generated in situ with a hindered base at low-temp., with organoboranesand subsequent oxidation provides a useful, high-yield, one-pot synthesis ofthe title compounds such as (III). Both trialkylboranes and alkylboronic esterscan be used as alkylating reagents. — (LI, N.-S.; YU, S.; KABALKA, G.W.; Organometallics 16 (1997) 4, 709-712; Dep. Chem. Radiol., Univ. Tenn.,Knoxville, TN 37996, USA; EN)
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