cheminform abstract: synthesis of alkylarylcarbinols via the reaction of organoboranes with...

1997 alcohols alcohols (benzene compounds) Q 0230 22 - 089 Synthesis of Alkylarylcarbinols via the Reaction of Organoboranes with Arylmethyl Chlorides. — The reaction of (α-chloroaryl)methyl anions, generated in situ with a hindered base at low-temp., with organoboranes and subsequent oxidation provides a useful, high-yield, one-pot synthesis of the title compounds such as (III). Both trialkylboranes and alkylboronic esters can be used as alkylating reagents. — (LI, N.-S.; YU, S.; KABALKA, G. W.; Organometallics 16 (1997) 4, 709-712; Dep. Chem. Radiol., Univ. Tenn., Knoxville, TN 37996, USA; EN) 1

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Page 1: ChemInform Abstract: Synthesis of Alkylarylcarbinols via the Reaction of Organoboranes with Arylmethyl Chlorides

1997 alcohols

alcohols (benzene compounds)Q 0230

22 - 089Synthesis of Alkylarylcarbinols via the Reaction of Organoboraneswith Arylmethyl Chlorides. — The reaction of (α-chloroaryl)methylanions, generated in situ with a hindered base at low-temp., with organoboranesand subsequent oxidation provides a useful, high-yield, one-pot synthesis ofthe title compounds such as (III). Both trialkylboranes and alkylboronic esterscan be used as alkylating reagents. — (LI, N.-S.; YU, S.; KABALKA, G.W.; Organometallics 16 (1997) 4, 709-712; Dep. Chem. Radiol., Univ. Tenn.,Knoxville, TN 37996, USA; EN)

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