ammonia, particles and health - unece€¦ · reactions with nitrogen oxides (nox) and sulfur...

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Ammonia, Particles and Health Bert Brunekreef, PhD Institute for Risk Assessment Sciences Utrecht University, NL

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Page 1: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

Ammonia, Particles and Health

Bert Brunekreef, PhDInstitute for Risk Assessment Sciences

Utrecht University, NL

Page 2: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

Ammonia all by itself…

• Odor threshold ~ 3 mg/m3• Irritation at ~20 mg/m3• Outdoor concentrations typically < 0.05 mg/m3

Page 3: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

Ammonia contributes significantly to formation of Secondary Inorganic Aerosols (SIA ~ Ammonium Sulfates and Nitrates) which make up a large part of Fine Particles, PM2.5

Page 4: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 5: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

AE 2013

Page 6: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 7: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 8: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 9: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 10: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

2014

Page 11: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

Current scientific evidence considers the major PM2.5 components ~ equally hazardous; so, the contribution of NH3emissions to adverse health effects of PM2.5 is likely to be large

Page 12: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

2013

Page 13: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

2015

PM2.5

Nitrate

Page 14: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2
Page 15: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

EST 2014

Page 16: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

ACP 2017

UP TO 50% PM2.5 REDUCTION FROM 100% NH3 REMOVAL

Page 17: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

ACP 2017

UP TO 800,000 FEWER DEATHS FROM 100% NH3 REMOVAL

Page 18: Ammonia, Particles and Health - UNECE€¦ · reactions with nitrogen oxides (NOx) and sulfur oxides (SO2) • Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2

Take home messages

• Ammonia (NH3) produces airborne particles (PM) through atmospheric reactions with nitrogen oxides (NOx) and sulfur oxides (SO2)

• Ammonia (>90% agriculture) more important than NOx (~traffic) and SO2 (~shipping, energy)

• All particles ~equally harmful• Huge health benefits expected from NH3

reduction