amet,tm sample us ansi ghs compliant sds
TRANSCRIPT
SAMPLE US SAFETY DATA SHEET Prepared to ANSI, GHS and OSHA HazCom 2012 Standards
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/ 07/2012
1.1 Identification of the substance or mixture 1.1.1 Mixture name : Fendell Cleaning Solvent Blend No. 3
1.1.2 Product/SDS Code : FCSB No. 3
1.1.3 Product description : Mixture of solvents.
1.2 Uses of the mixture and uses advised against 1.2.1 Uses of the mixture : Flushing and cleaning of proprietary equipments.
1.2.2 Uses advised against : For industrial use only. Not for home use.
1.3 Company Identification 1.3.1 Manufacturer/Supplier : Sao Boso Chemical Company, Ltd.
1.3.2 Contact information
Street address : Fendell Industrial Park
3729 Bensonville Hwy, # A-1 Complex
Any town, Our State, 12345-6789
U.S.A
Telephone number : 1-(877)-000-0000
Fax number : 1-(877)-000-0012
1.3.3 E-mail of contact person : [email protected]
1.4 Emergency telephone number (s) : CHEMTREC: 1-800-424-9300 (USA)
Poison Control Center: 1-800-222-1222 (USA)
National Response Center: 1-800-424-8802 (USA)
1.4.1 Further information obtainable from : Regulatory Affairs
Monday to Friday: 6 am - 6 pm (Pacific Time)
2.1 Classification of the substance or mixture
Product definition : Mixture of solvents.
2.1.1 Emergency Overview : Flammable liquid and vapor. Irritating to eyes, skin, and
respiratory tract. Harmful or fatal if swallowed, if inhaled, and
in contact with skin. May be absorbed through intact skin.
Avoid prolonged contact with skin.
Potential Health Effects : WARNING! FLAMMABLE LIQUID AND VAPOR.
HARMFUL! Keep away from open flame, heat, and static
discharge sources. Aspiration hazard if swallowed. Irritant and
central nervous system depressant. High vapor concentrations
are irritating to the nose, throat, and respiratory tract.
1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING
2. HAZARDS IDENTIFICATION
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 2 of 19
Product Code: FCSB No. 3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
Avoid inhalation of vapor and contact with skin and eyes. May
be harmful or if swallowed. Remove victim to fresh air if
overcome with vapor/mist/fumes due to inhalation. If splashed in
eyes, flush with water for 15 minutes. If in contact with skin,
flush with water and wash with mild soap. In medical emergency,
CALL A PHYSICIAN, OR POISON CONTROL CENTER (1-800-222-1222) IMMEDIATELY.
Note: Read the product Safety Data Sheet completely and thoroughly before using this product.
2.2 Classification according to GHS
GHS Classification
Potential Hazards : Highly flammable liquid and vapor. Irritating to eyes, skin, and
respiratory tract. A component in the product may cause central
nervous system effects. Such central nervous system effects can
include drowsiness, headache, and dizziness. Repeated exposure
may cause skin dryness or cracking.
Hazard symbol(s)
F : Flammable.
Xi : Irritant.
Xn : Harmful.
2.2.1 Additional Information
See section 16 for full text of GHS classification declared above.
2.3 GHS Label elements
Labeling according to GHS
Hazard Class Category Hazard Code Hazard Statement
Flam. Liq. 2 H225 Highly flammable liquid and vapor.
Acute tox. (dermal) 4 H312 Harmful in contact with skin.
Acute tox. (inhalation) 4 H332 Harmful if inhaled.
Acute tox. (oral) 4 H302 Harmful if swallowed.
Aspiration hazard 1 H304 May be fatal if swallowed and enters airways.
Skin corro./irrit. 2 H315 Causes skin irritation.
Serious eye dam./Eye irrit. 1 H318 Causes serious eye damage.
Reprod. tox. D 2 H361d Suspected of damaging fertility or the unborn
Child.
STOT SE: RTI 3 H335 May cause respiratory irritation.
STOT SE: NE 3 H336 May cause drowsiness or dizziness.
STOT SE: RE 2 H373 May cause damage to organs through
Prolonged or repeated exposure.
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 3 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
Hazard Pictograms
Signal word: Danger
Hazard statement(s)
H225 : Highly flammable liquid and vapor.
H302 : Harmful if swallowed.
H304 : May be fatal if swallowed and enters airways.
H312 : Harmful in contact with skin.
H315 : Causes skin irritation.
H318 : Cause serious eye damage.
H332 : Harmful if inhaled.
H335 : May cause respiratory irritation.
H336 : May cause drowsiness or dizziness.
H361d : Suspected of damaging fertility or the unborn child.
H373 : May cause damage to organ(s) through prolonged or repeated
exposure.
Precautionary statement(s)
P210 : Keep away from heat/sparks/open flames/hot surfaces – No
smoking.
P233 : Keep container tightly closed.
P261 : Avoid breathing dust/fume/gas/mist/vapors/spray.
P264 : Wash hands with soap and plenty of water after handling.
P280 : Wear protective gloves/protective clothing/eye protection/face
protection.
P310 : Immediately call a POISON CENTER or doctor/physician.
P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.
P501 : Dispose of contents/container to be in accordance with
local/regional/national regulations.
2.4 Other hazards
Substance meets the criteria : No.
for PBT (Persistent,
Bioaccumulative, and Toxic)
Substance meets the criteria : No.
for vPvB (very Persistent and
very Bioaccumulative)
Other hazards which do not : Repeated exposure may cause skin dryness or cracking.
result in classification
This product is considered to be hazardous according to the criteria specified in 29 CFR 1900.1200.
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 4 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
3.1 Description of the substance/mixture : Mixture of solvents.
OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):
3.1.1 Hazardous components
Component CAS No. EC No. Index No. UN No. Percent GHS Classification Type
Butan-2-one 78-93-3 201-159-0 606-002-00-3 1193 40 - 60 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
EUH066
[1]
[2]
Butan-1-ol 71-36-3 200-751-6 603-004-00-6 1120 30 - 60 Flam. Liq. 3, H226
Acute Tox. 4*
, H302
STOT SE 3, H335
Skin Irrit. 2, H315
Eye Dam. 1, H318
STOT SE 3, H336
[1]
[2]
Ethyl hydroxide 64-17-5 200-578-6 603-002-00-5 1987 10 - 40 Flam. Liq. 2, H225 [2]
Propan-2-ol 67-63-0 200-661-7 603-117-00-0 1219 10 - 20 Flam. Liq. 2, H225
Eye Irrit. 2, H319
STOT SE 3, H336
[1]
[2]
Methylbenzene 108-88-3 203-625-9 601-021-00-3 1294 1 - 5 Flam. Liq. 2, H225
Repr. 2, H361d***
Asp. Tox. 1, H304
STOT RE 2, H373**
Skin Irrit. 2, H315
STOT SE 3, H336
[1]
[2]
Xylol 1330-20-7 215-535-7 601-022-00-9 1307 1 - 5 Flam. Liq. 3, H226
Acute Tox. 4*, H332
Acute Tox. 4*, H312
Skin Irrit. 2, H315
[1]
[2]
Components in this product are not known or reported to be carcinogenic in humans by any reference source
including OSHA, IARC, NTP, ACGIH, or EPA.
3.2 Additional information
[1] Substance classified with a health or environmental hazard.
[2] Substance with a workplace exposure limit.
[3] Substance meets the criteria for PBT.
[4] Substance meets the criteria for vPvB.
Occupational exposure limits, if available, are listed in Section 8.
See Section 2 for the full text of the H-codes declared above.
3. COMPOSITION/INFORMATION ON INGREDIENTS
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
4.1 Description of first aid measures
4.1.1 General information : General first aid measures should be followed. In case of
persistent adverse effects, seek immediate medical attention.
Remove contaminated clothing and shoes promptly, and wash
thoroughly before re-use.
4.1.2 Following inhalation : NOTE: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain
and nervous system damage. Intentional misuse by deliberately
concentrating and inhaling the contents may be harmful or fatal.
: Emergency responders should use positive air supplied
respiratory protection when removing the victim from area.
Remove person to fresh air. If not breathing, administer CPR
until help arrives, or the victim starts to breathe on their own.
Give artificial respiration if breathing has stopped. Seek medical
attention immediately.
4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area
thoroughly with water for at least 15 minutes. Use soap if
available. Remove contaminated clothing, including shoes, after
flushing has begun. Wash clothing before re-use. If irritation
persists, seek medical attention.
4.1.4 Following eye contact : Immediately flush affected eye with water for at least 20
minutes. ilt the head to prevent chemical from transferring to
the unaffected eye. Seek medical attention without delay after
flushing.
4.1.5 Following ingestion : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out
with water. Dilute with milk or water. Never give anything to
drink if the victim is unconscious or having convulsions. Seek
medical attention immediately. Contact Poison Control Center at
once.
4.1.6 Self protection of the first aider : Appropriate personal protective attire should be worn.
4.1.7 Note to the doctor : Suitable medical intervention should be provided based on
symptoms.
4.2 Most important symptoms and : Irritating to eyes, skin, and respiratory tract upon exposure. High
effects, both acute and delayed vapour concentrations are irritating to eyes, nose, throat, and
lungs; may cause unconsciousness or other signs of central
nervous system depression. Frequent or prolonged skin contact
may irritate the skin and cause skin rash (dermatitis). May cause
4. FIRST AID MEASURES
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 6 of 19
Product No: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
skin sensitization, an allergic reaction which becomes evident on
re-exposure to this material. Small amounts of this liquid may be
drawn into the lungs by either swallowing or vomiting. This may
cause severe and delayed health effects such as inflammation of
the lungs (pulmonary edema) and infection of the bronchi
(bronchopneumonia). Ingestion may cause irritation of digestive
track and diarrhea.
4.3 Indication of any immediate : Always get immediate medical attention/advice when symptoms
medical attention and special persist.
treatment needed
Fire Fighting Measures : The following applies to Butan-2-one
FLASHPOINT: 26oF
SPECIFC GRAVITY: 0.806 @ 68o
F
EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%.
AUTOIGNITION TEMPERATURE: 961.0oF.
5.1 Extinguishing media
Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or
extinguish with alcohol type or all purpose type foam, or dry
chemical powder. Try to cover liquid spills with appropriate
foam. Use water spray to cool fire exposed surfaces. Avoid
spraying water directly into storage containers due to danger of
boilover. Shut off fuel to fire if possible to do so without hazard.
If a spill has not ignited, use water spray to disperse the vapors.
Unsuitable extinguishing media : Do not use high volume water jet.
5.2 Special hazards arising from : Flammable liquid; may release vapors that form flammable
the mixture mixtures when temperatures are at or above the flash point.
There is a danger of explosion when container is heated or in
fire. Toxic gases will form upon combustion. Vapor may
may accumulate in low or confined areas or travel to a
considerable distance to a source of ignition and flash back.
Avoid runoff into storm sewers and ditches.
Hazardous combustion products : Smoke, fumes, oxides of carbon, irritating or toxic vapors or
gases.
5.3 Advice for fire-fighters
Protective equipment for : Respiratory and eye protection gear is required for fire
fire fighters fighting personnel. Full protective equipment (Bunker Gear)
5. FIRE FIGHTING MEASURES
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 7 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
and a self-contained breathing apparatus (SCBA) should be
used for all indoor fires and any significant outdoor fires. Use
portable fire extinguisher for small outdoor fires. Use of SCBA
may not be required.
5.4 Additional information : Exposure to decomposition products may cause health
hazards. Cool containers exposed to fire with water spray.
Move unexposed containers from fire area if this can be done
without risk.
6.1 Personal precautions, protective equipment and emergency procedures
6.1.1 For non-emergency personnel :
Protective equipment : Wear suitable personal protective equipment (e.g. clothing,
gloves, safety goggles, and mask/respirator). Ensure adequate
ventilation; remove all sources of ignition. Notify the
appropriate authorities immediately.
Emergency procedures : Eliminate ignition source. Shut off leak if safe to do so. Take
all additional action necessary to prevent and remedy the
adverse effects of the spill. Isolate hazard area and deny entry
to unauthorized or unprotected personnel. Contain spilled liquid
with sand or earth. DO NOT use combustible materials such as
saw dust. Absorb spill with an inert material (e.g., sand or earth).
Then place in a chemical waste container.
6.1.2 For emergency responders : Respiratory and eye protection gear is required for emergency
personal protective equipment responders. Full protective equipment (Bunker Gear) and a
self-contained breathing apparatus (SCBA) should be used for
all indoor fires and any significant outdoor fires. Use portable
fire extinguisher for small outdoor fires. Use of SCBA may not
be required.
6.2 Environmental precautions : Avoid dispersal of spilt material and runoff into soil, storm
sewers and ditches which lead to natural waterways, or the
immediate environment. Inform the relevant authorities if the
product has entered into the environment.
6.2 Methods of containment and cleaning up
6.3.1 On water : If spill in water, remove from water surface by skimming
or with suitable absorbent material and place in appropriate
disposal container. If allowed by local environmental
regulatory agencies, you may use a suitable dispersant.
6. ACCIDENTAL RELEASE MEASURES
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 8 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
6.3.2 On ground/floor : Contain spill and absorb with an inert material (e.g., dry sand or
earth). Then place in an appropriate waste container for disposal
according to local regulations. Large spills should be disposed of
via a licensed waste disposal establishment/contractor.
6.3.3 Other information : Contaminated absorbent material may pose similar hazard as the
spill product.
6.4 Reference to other sections See Section 1 for emergency contact information.
See Section 8 for information on appropriate personnel protective equipment.
See Section 13 for additional disposal information.
7.1 Precautions for safe handling
7.1.1 Protective measures : Wear appropriate personal protective equipment. Do not get in
eyes, on skin, or on clothing. Do not breathe vapor or mist.
Do not eat, drink, or smoke when using this product. Use only
with adequate ventilation. Keep away from sources of ignition.
Keep only in original container. Keep tightly closed when not
in use. Do not reuse container. Avoid release to the environ-
ment.
7.1.2 Advice on general occupational : Avoid eating, drinking and smoking in areas where this product
hygiene is handled, used and stored. Wash hands before eating, drinking
and smoking, and at the end of the working period. Contamina-
ted work clothing and protective equipment should not be
brought into eating, smoking and drinking areas. Wash soiled
clothing before re-using.
7.2 Conditions for safe storage, including any incompatibilities
Technical measures and : Store at ambient/room temperature. Protect from extreme cold
storage conditions and heat. Store in a segregated and approved area. Store away
from strong oxidizing agents. Loosen closure cautiously with
non-sparking tools before opening. Keep only in original con-
tainer. Store and use away from sparks, heat, open flames and
other ignition sources. Ground and bond containers and recei-
ving equipment. Store locked up. Store away from direct sun
-light in a dry, cool and well-ventilated area. Containers that
have been opened must be carefully resealed and kept upright
to prevent leakage. Ground and bond containers when
transferring material. Ventilation required along storage floor.
Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic
bottles and containers.
7. HANDLING AND STORAGE
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
7.3 Specific end use(s)
Recommendations : For industrial use only.
Industrial sector specific : Not available.
solutions
There is no workplace exposure data available on the product itself.
8.1 Control parameters
8.1.1 Occupational Exposure Limits (OELs) :
Occupational Exposure Limit (OELs) Values Exposure Limits Long Term Limit
(8-hour period) - TWA
Short Term Limit
(15-minute(s) period) - STEL
Limit Value Type
Chemical Name ppm [mg/m3] ppm [mg/m
3] Letter Code*
Butan-2-one
Health Factor
200
200
200
3,000
590
590
590
-
-
300
300
-
-
885
885
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Butan-1-ol
Health Factor
100
20
50
1,400
300
61
150
-
-
-
-
-
-
-
-
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Ethyl hydroxide
Health Factor
1000
1000
1000
3,300
1900
1880
1900
-
-
-
-
-
-
-
-
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Propan-2-ol
Health Factor
400
200
400
2,000
980
491
980
-
-
400
500
-
-
983
1,225
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Methylbenzene
Health Factor
200
50
100
500
750
188
375
-
-
-
150
-
-
-
560
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Xylol
Health Factor
100
100
100
900
435
434
435
-
-
150
150
-
-
651
655
-
OSHA (PEL)
ACGIH (TLV)
NIOSH (REL)
NIOSH (IDLH)
Exposure limits provided in the above table contains generic information and guidance on air
contaminants in the workplace. Please consult your local exposure values. Federal and State
requirements may differ.
8. EXPOSURE CONTROL/PERSONAL PROTECTION
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 10 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
Recommended monitoring : If this product contains ingredients with exposure limits,
procedures personal, workplace atmosphere or biological monitoring may
be required to determine the effectiveness of the ventilation or
other control measures and/or the necessity to use respiratory
protective equipment. Reference should be made to European
Standard EN 689 for methods for the assessment of exposure
by inhalation of chemical agents and national guidance
documents for methods for the determination of hazardous
substances.
Derived effect levels [DNEL] : See occupational exposure limits table for guidance.
Predicted effect concentrations : Not available.
(PNEC Summary)
8.1 Exposure controls
8.1.1 Appropriate engineering : Provide adequate local exhaust ventilation to maintain worker
controls below exposure limits. The use of mechanical ventilation
controls is recommended whenever this product is used in a
confined space, is heated above ambient temperatures, or is
agitated. Use explosion-proof ventilation equipment.
8.2 Personal protective equipment
8.2.1 Eye and face protection : Safety eyewear complying with an approved standard should be
used when a risk assessment indicates this is necessary to avoid
exposure to liquid splashes, mist, or dust. See OSHA Standard
(29 CFR 1910.133) and applicable State regulations.
8.2.2 Skin protection
Hand protection : Chemical-resistant, impervious gloves complying with an
approved standard should be worn at all times when handling
chemical products if a risk assessment indicates this in necessary.
Refer to 29 CFR 1910.138 if necessary.
Body protection : Personal protective equipment for the body should be selected
based on the task being performed and the risks involved and
should be approved by a specialist before handling this product.
Consult OSHA 29 CFR 1910.136 for direction.
Other skin protection : Appropriate footwear and any additional skin protection mea-
sures should be selected based on the task being performed and
the risks involved and should be approved by a specialist before
handling this product.
8.3 Respiratory protection : Use approved respiratory protection equipment. Respirator
selection should be based on the form and concentration of
contaminants in the air and in accordance with local regulations.
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
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Guidance on respiratory protection is provided in 29 CFR
1910.134.
8.4 Environmental exposure : Emission from ventilation or work process equipment should be
controls checked to ensure they comply with the requirements of envi-
ronmental protection legislation. Ensure that emission is at the
acceptable level.
9.1 Information on physical and chemical properties
Physical state : Liquid.
Colour : Characteristic.
Odour : Solvent odour.
Odour threshold : Not determined.
pH : Not available .
Melting/freezing point [o
F] : Not available.
Initial boiling point/range [o
F] : Not available.
Flash point [o
F] : Not available.
Evaporation rate (n-Butyl Acetate : Not available.
= 1)
Flammability (solid, gas) : Not available.
Upper flammability : Not available.
Lower flammability : Not available.
Vapour pressure, mm Hg @ 75 o
F : Not available.
Vapour density (Air = 1) : Not available .
Relative density : Not available.
Solubility in water, Wt % @ 68 o
F : Not available.
Partition coefficient: n- : Not available.
Octanol/water
Auto-ignition temperature : Not available.
Decomposition temperature : Not applicable.
Viscosity of Liquid, CST @ 25o
C : Not available.
Explosive properties : Not available.
Oxidizing properties : Not available.
9.2 Other information : Experimental material. Certificate of Analysis is not available.
10.1 Reactivity : Reactivity does not occur.
10.2 Chemical stability : Stable under normal conditions.
10.3 Possibility of hazardous reactions : Hazardous polymerization will not occur.
10.4 Conditions to avoid : Open flames and sources of ignition. Incompatible products.
9. PHYSICAL AND CHEMICAL PROPERTIES
10. STABILITY AND REACTIVITY
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
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10.5 Incompatible materials : Strong oxidizing agents.
10.6 Hazardous decomposition products : Burning can produce oxides of carbon.
11.1 Information on toxicological effects
11.1.2 Mixture : There is no data available on the product itself.
11.1.2.1 : Relevant effects:
Component Carcinogenicity
Information on components CAS Registry Carcinogenicity Databases
Constituents/Ingredients CAS No. OSHA-Z NTP IARC ACGIH EPA
Butan-2-one 78-93-3 - - - - Group D
Butan-1-ol 71-36-3 - - - - -
Ethyl hydroxide 64-17-5 - - - Group A4 -
Propan-2-ol 67-63-0 - - Group 3 Group A4 -
Methylbenzene 108-88-3 - - Group 3 Group A4 Group D
Xylol 1330-20-7 - - Group 3 Group A4 Group D
Classifications :
ACGIH : Group A4: Not classifiable as a human carcinogen.
EPA : Group D: Not classifiable as to Human Carcinogenicity.
IARC : Group 3: Not classifiable as to its carcinogenicity to humans.
(b) Irritation
Inhalation : May cause irritation to the nose, throat, and lungs. High
vapor concentrations may cause unconsciousness or other
signs of central nervous system depression.
Skin contact : Frequent or prolonged contact may irritate the skin and
cause skin rash (dermatitis). May cause skin sensitization,
an allergic reaction which becomes evident on re-exposure
to this material.
Eye contact : Severely irritating. If not removed promptly will injure eye
tissue, which may result in permanent damage.
Ingestion : May cause irritation of the digestive tract and diarrhea.
(c) Corrosivity : Severely irritating to eyes. Repeated exposure may cause skin
dryness or cracking.
11. TOXICOLOGICAL INFORMATION
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
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(d) Sensitization : May cause skin sensitization and or respiratory system irritation
due to extended exposure of the preparation above stated occu-
pational exposure limits.
(e) Single dose toxicity : No data available.
(f) Repeated dose toxicity : No data available.
(g) Carcinogenicity : No known significant effects or critical hazards.
(h) Mutagenicity : No information but adverse effects unlikely.
(i) Toxicity for reproduction : No known significant effects or critical hazards.
11.1.2.2 CMR effects : No known significant effects or critical hazards.
(carcinogenic, mutagenic or
toxic for reproduction)
11.2 Potential adverse health effects : Small amounts of this liquid may be drawn into the lungs by
either swallowing or vomiting. This may cause severe and
delayed health effects such as inflammation of the lungs (
pulmonary edema) and infection of the bronchi(broncho-
pneumonia). Ingestion may cause irritation to the digestive
tract or diarrhea.
11.3 Potential chronic health effects : There is no evidence that exposure to Butan-2-one alone
causes progressive or irreversible neurotoxic effects.
However, simultaneous over-exposure to Butan-2-one and
n-Hexane can potentiate the known irreversible neurotoxic
effects of n-Hexane. There is no reported human evidence
that these neurotoxic effects occur when exposure to both
chemicals is maintained below established regulatory limits.
11.4 Other information : The mixture is not likely to be carcinogen in humans.
Note: Ecological testing has not been done on the product. Ecotoxicological information on components of
this product is presented below.
12.1 Toxicity :
Butan-2-one [CAS#: 78-93-3]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Pimephales promelas 3220
Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna > 520
Acute algae toxicity EC3 7 days Scenedesmus quadricauda ≥ 4300
12. ECOLOGICAL INFORMATION
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Product Code: FCSB No.3 Prepared Date: 07/02/2012
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Butan-1-ol [CAS#: 71-36-3]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Pimephales promelas < 1630
Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 1983
Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 500
Ethyl hydroxide [CAS#: 64-17-5]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Alburnus alburnus 10000 - 11500
Acute Daphnia toxicity LC50 48 hour (s) Daphnia magna 9268 - 14221
Acute algae toxicity EC50 Not specified Chlorella pyrenoidosa 9310
Propan-2-ol [CAS#: 67-63-0]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Pimephales promelas 9640
Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 13299
Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 1000
Methylbenzene [CAS#: 108-88-3]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Pimephales promelas 28
Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 11.5
Acute algae toxicity EC50 48 hour (s) Scenedesmus subspicatus 125 - 160
Xylol [CAS #: 1330-20-7]
Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)
Acute fish toxicity LC50 96 hour (s) Cyprinus carpio > 780
Acute invertebrate toxicity LC50 48 hour (s) Palaemonetes pugio 0.85
Acute algae toxicity Mortality Unknown Scenedesmus quadricauda > 200
12.2 Persistence and degradability : No data available for this product.
(Biochemical Oxygen Demand – BOD values)
Substance name Quantity Degradation rate (%) Incubation time Evaluation (inoculum)
Butan-2-one Unknown 83 5 days Sewage
Butan-1-ol Unknown 66 5 days Sewage sludge
Ethyl hydroxide 10 mg/l 74 5 days Filtered sewage seed
Propan-2-ol 10 mg/l 78*
20 days Filtered sewage seed
Methylbenzene Unknown Completely Short duration Sewage seed
Xylol Isomers 72 20 days Activated sewage
* Theoretical Oxygen Demand (ThOD) value.
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 15 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
12.3 Bioaccumulative potential : No data available for this product.
(BCF – Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate
Substance name Estimated BCF log Kow Remarks
Butan-2-one 3 0.29 Low bioaccumulation
Butan-1-ol 3 0.88 Low bioaccumulation
Ethyl hydroxide 3 -0.31 Low bioaccumulation
Propan-2-ol 3 0.05 Low bioaccumulation
Methylbenzene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation
Xylol 6 – 23.4 3.2 Low bioaccumulation
12.4 Mobility in soil : No data available for this product.
Koc – The soil absorption coefficient
Substance name Koc value Remarks (soil mobility)
Butan-2-one 29 Very high mobility
Butan-1-ol 72 High mobility
Ethyl hydroxide 1 Very high mobility
Propan-2-ol 25 Very high mobility
Methylbenzene variable High to moderate mobility
Xylol 39 – 365 for individual isomers Very high to moderate mobility
12.5 Results of PBT and vPvB assessment PBT : No data available.
vPvB : No data available.
12.6 Other adverse effects : No known significant effects or critical hazards.
13.1 Waste treatment methods Product
Methods of disposal : The generation of waste should be avoided or minimized
whenever possible. Empty containers or liners may retain
some product residues. This material and its container must
be disposed of in a safe way. Waste product residue should not
be disposed of via the foul sewer. Consult an expert on the dis-
posal of recovered and surplus material. Incinerate, or recover
by distillation. Ensure disposal is in compliance with current
government requirements and ensure conformity with local
authority regulations.
Packaging waste
Methods of disposal : The generation of waste should be avoided or minimized
whenever possible. Waste packaging should be recycled, or
dispose of according to state and local authority regulations.
Consult your State/Local Land Waste Management Authority.
NOTE: The use of this product should at all times comply with the requirements of environmental
protection and waste disposal legislations/statutes and any local authority requirements.
13. DISPOSAL CONSIDERATIONS
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 16 of 19
Product Code: FCSB No.3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
Special precautions : This material and its container must be disposed of according to
local authority regulations. Empty containers or packaging may
contain some product residue. Avoid dispersal of spilt material
and runoff to come in contact with soil, waterways, drains and
sewers.
DOT ADN/ADNR IMDG ICAO-TI/IATA-DGR
14.1 UN No. 1210 1210 1210 1210
14.2 Proper Shipping
Name
Printing Ink Related
Material
Printing Ink Related
Material
Printing Ink
Related Material
Printing Ink Related
Material
14.3 Transport hazard
class
3
3
3
3
14.4 Classification code
F1
F1
F1
F1
14.5 Packing group II II II II
14.6 Hazard label
14.7 Environmental
hazard
No
No
Marine pollutant:
No
No
14.8 Special provision(s) 163
640C
163
640C
163 Not available
Additional Information Hazard identification
number
33
Ltd. Qty
LQ6
Excpt. Qty
E2
Packaging
P001, PP1, MP19
Portable Tanks and
Bulk Cont.
T4; TP1, TP8
-
-
-
-
-
Ltd. Qty
LQ6
Excpt. Qty.
E2
-
-
-
-
Emergency
schedules (EmS)
Fire
F-E
Spillage
S-D
Ltd. Qty
5l
Excpt. Qty
E2
-
-
-
Passenger and Cargo
Aircraft
Quantity limitation:
1.0L
Packing instructions:
Y341
353 5.0L
Cargo Aircraft only
Quantity limitation:
60.0 L
Packaging instruction:
364
-
-
14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.
14. TRANSPORTATION INFORMATION
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 17 of 19
Product No: FCSB No. 3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
This Safety Data Sheet has been prepared in accordance with HazCom 2012 requirements of OSHA’s
revised Hazard Communication Standard at 29 CFR 1910.1200
15.1 Regulatory Information
TSCA Inventory Status : All components are on the U.S. EPA TSCA Inventory.
SARA Title III/CERCLA :
Protective Action Criteria (PACs) :
Chemical PAC-1 PAC-2 PAC-3 LEL
Butan-2-one 200 ppm 2,700 ppm 4,000 ppm 1,400 ppm
Butan-1-ol 20 ppm 50 ppm 8,000 ppm 14,000 ppm
Ethyl hydroxide 1,800 ppm 3,300 ppm 15,000 ppm 33,000 ppm
Propan-2-ol 400 ppm 400 ppm 1,200 ppm 20,000 ppm
Methylbenzene 200 ppm 1,200 ppm 4,500 ppm 11,000 ppm
Xylol 130 ppm 920 ppm 2,500 ppm 9,000 ppm
Methylbenzene (Toluene) is regulated by the Drug Enforcement Administration and appears on List II (
21 CFR Section 1310.02(b) and 1310.04(f)(2).
Methylbenzene is a Toxic Pollutant under Section 307(a)(1) of the Clean Water Act and is subject to effluent
limitations.
State Regulatory Information : Components of this product are covered under specific State
regulations.
California Proposition 65 : This material contains components which are known
to the State of California to cause cancer, birth defects or other
reproductive harm.
Chemical Weapons Convention List
Schedule I Chemicals
Chemical Weapons Convention List
Schedule II Chemicals
Chemical Weapons Convention List
Schedule III Chemicals
Not listed Not listed Not listed
Chemical CAA RMP CERCLA (RQ) EHS (EPCRA 302) TRI (EPCRA 313)
Butan-2-one Not regulated. Regulated chemical. RQ of
5000 lbs.
Not regulated. Regulated chemical.
Butan-1-ol Not regulated. Regulated chemical. RQ of
5000 lbs.
Not regulated. Regulated chemical.
Ethyl hydroxide Not regulated. Not regulated. Not regulated. Not regulated.
Propan-2-ol Not regulated. Not regulated. Not regulated. Regulated chemical.
Methylbenzene Not regulated. Regulated chemical. RQ of
1000 lbs.
Not regulated. Regulated chemical.
Xylol Not regulated. Regulated chemical. RQ of 100
lbs.
Not regulated. Regulated chemical.
15. REGULATORY INFORMATION
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 18 of 19
Product No: FCSB No. 3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date:07/07/2012
NOTE : This Safety Data Sheet was created as a teaching aid for
freelance safety data sheet writers. The mixture is fictitious.
Product : The product was classified in accordance with GHS
Classification of hazardous substances/mixtures and OSHA’s
requirements.
HMIS Code Hazard Rating NFPA Rating
1 = Health
3 = Flammability
0 = Reactivity
B = Personal Protective Equipment
HMIS/NFPA color scheme: Health = Blue; Red = Fire; Yellow = Reactivity; White = PPE
16.1 Indication of changes
Date of previous issue : No previous validation.
Revisions : To comply with OSHA’s regulations.
Nature of version : Conforms to GHS, ANSI, and OSHA HazCom 2012 Format.
Version : 1.00
Date of issue : 07 July, 2012.
Prepared by : Theodore M. Amet, Regulatory Research Analyst
16.2 Abbreviations and acronyms
ACGIH: American Conference of Governmental Industrial Hygienists;
ADR: Accord européen sur le transport des merchandises dangereuses par Route (European Agreement
concerning the International Carriage of Dangerous Goods by Road);
CAA: Clean Air Act;
CAS#: Chemical Abstract Service Registry Number;
CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act;
CFR: Code of Federal Regulations;
DOT: Department of Transportation;
EINECS: European Inventory of Existing Commercial chemicals Substances;
EHS: Extremely Hazardous Substances;
EPA: Environmental Protection Agency;
EPCRA: Emergency Planning and Community Right-to-Know Act;
GHS: Globally Harmonized System of Classification and Labelling of Chemicals;
IARC: International Agency for Research on Cancer;
IATA: International Air Transport Association;
IATA-DGR: Dangerous Goods Regulations by the “International Air Transport Association” (IATA);
ICAO: International Civil Aviation Organization;
ICAO-TI: Technical Instructions by the “International Civil Aviation Organization” (ICAO);
16. OTHER INFORMATION
Product Name: Fendell Cleaning Solvent Blend No. 3 Page 19 of 19
Product No: FCSB No. 3 Prepared Date: 07/02/2012
Version: 1.00 Printing Date: 07/07/2012
IDLH: Immediately Dangerous to Health or Life;
IMDG: International Maritime Code for Dangerous Goods;
LEL: Lower Explosion Limit;
NIOSH: National Institute for Occupational Safety and Health;
NTP: National Toxicology Program;
OSHA: Occupational Safety and Health Administration;
PEL: Permissible Exposure Limit;
REL: Recommended Exposure Limit;
RID: Règlement international concernant le transport des merchandises dangereuses par chemin de fer
(Regulations Concerning the International Transport of Dangerous goods by Rail);
RMP: Risk Management Program;
RQ: Reportable Quantity;
SARA: Superfund Amendment and Reauthorization Act;
STEL: Short Term Exposure Limit;
TLV: Threshold Limit Value;
TRI: Toxic Release Inventory;
TSCA: Toxic Substances Control Act;
TWA: Time Weighted Average.
16.3 Key literature references : CAMEO Chemicals;
and sources of data ESIS (Existing chemical Substances Information System);
OSHA - Chemical Sampling Information (CSI) – OELs;
TOXNET;
Information from technical literature;
Internet research;
Substance Material Safety Data Sheets.
DISCLAIMER
This document was compiled as a service to freelance U.S. Safety Data Sheets writers. Information included
within this material is based on data gathered from many sources. No warranty is expressed regarding the
accuracy of data obtained from various chemical, health, toxicological, and environmental databases.
Responsibility for the accuracy and completeness of information contained herein rests with users who must
satisfy themselves that the data is appropriate for their needs. It is always a good practice to consult a sectional
expert when writing sections of the safety data sheets to clarify and simplify technical matters.
END OF SAMPLE SAFETY DATA SHEET