amet,tm sample us ansi ghs compliant sds

SAMPLE US SAFETY DATA SHEET Prepared to ANSI, GHS and OSHA HazCom 2012 Standards

Product Name: Fendell Cleaning Solvent Blend No. 3 of 19

Product Code: FCSB No.3 Prepared Date: 07/02/2012

Version: 1.00 Printing Date: 07/ 07/2012

1.1 Identification of the substance or mixture 1.1.1 Mixture name : Fendell Cleaning Solvent Blend No. 3

1.1.2 Product/SDS Code : FCSB No. 3

1.1.3 Product description : Mixture of solvents.

1.2 Uses of the mixture and uses advised against 1.2.1 Uses of the mixture : Flushing and cleaning of proprietary equipments.

1.2.2 Uses advised against : For industrial use only. Not for home use.

1.3 Company Identification 1.3.1 Manufacturer/Supplier : Sao Boso Chemical Company, Ltd.

1.3.2 Contact information

Street address : Fendell Industrial Park

3729 Bensonville Hwy, # A-1 Complex

Any town, Our State, 12345-6789

U.S.A

Telephone number : 1-(877)-000-0000

Fax number : 1-(877)-000-0012

1.3.3 E-mail of contact person : [email protected]

1.4 Emergency telephone number (s) : CHEMTREC: 1-800-424-9300 (USA)

Poison Control Center: 1-800-222-1222 (USA)

National Response Center: 1-800-424-8802 (USA)

1.4.1 Further information obtainable from : Regulatory Affairs

Monday to Friday: 6 am - 6 pm (Pacific Time)

2.1 Classification of the substance or mixture

Product definition : Mixture of solvents.

2.1.1 Emergency Overview : Flammable liquid and vapor. Irritating to eyes, skin, and

respiratory tract. Harmful or fatal if swallowed, if inhaled, and

in contact with skin. May be absorbed through intact skin.

Avoid prolonged contact with skin.

Potential Health Effects : WARNING! FLAMMABLE LIQUID AND VAPOR.

HARMFUL! Keep away from open flame, heat, and static

discharge sources. Aspiration hazard if swallowed. Irritant and

central nervous system depressant. High vapor concentrations

are irritating to the nose, throat, and respiratory tract.

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

2. HAZARDS IDENTIFICATION


Product Code: FCSB No. 3 Prepared Date: 07/02/2012

Version: 1.00 Printing Date: 07/07/2012

Avoid inhalation of vapor and contact with skin and eyes. May

be harmful or if swallowed. Remove victim to fresh air if

overcome with vapor/mist/fumes due to inhalation. If splashed in

eyes, flush with water for 15 minutes. If in contact with skin,

flush with water and wash with mild soap. In medical emergency,

CALL A PHYSICIAN, OR POISON CONTROL CENTER (1-800-222-1222) IMMEDIATELY.

Note: Read the product Safety Data Sheet completely and thoroughly before using this product.

2.2 Classification according to GHS

GHS Classification

Potential Hazards : Highly flammable liquid and vapor. Irritating to eyes, skin, and

respiratory tract. A component in the product may cause central

nervous system effects. Such central nervous system effects can

include drowsiness, headache, and dizziness. Repeated exposure

may cause skin dryness or cracking.

Hazard symbol(s)

F : Flammable.

Xi : Irritant.

Xn : Harmful.

2.2.1 Additional Information

See section 16 for full text of GHS classification declared above.

2.3 GHS Label elements

Labeling according to GHS

Hazard Class Category Hazard Code Hazard Statement

Flam. Liq. 2 H225 Highly flammable liquid and vapor.

Acute tox. (dermal) 4 H312 Harmful in contact with skin.

Acute tox. (inhalation) 4 H332 Harmful if inhaled.

Acute tox. (oral) 4 H302 Harmful if swallowed.

Aspiration hazard 1 H304 May be fatal if swallowed and enters airways.

Skin corro./irrit. 2 H315 Causes skin irritation.

Serious eye dam./Eye irrit. 1 H318 Causes serious eye damage.

Reprod. tox. D 2 H361d Suspected of damaging fertility or the unborn

Child.

STOT SE: RTI 3 H335 May cause respiratory irritation.

STOT SE: NE 3 H336 May cause drowsiness or dizziness.

STOT SE: RE 2 H373 May cause damage to organs through

Prolonged or repeated exposure.




Hazard Pictograms

Signal word: Danger

Hazard statement(s)

H225 : Highly flammable liquid and vapor.

H302 : Harmful if swallowed.

H304 : May be fatal if swallowed and enters airways.

H312 : Harmful in contact with skin.

H315 : Causes skin irritation.

H318 : Cause serious eye damage.

H332 : Harmful if inhaled.

H335 : May cause respiratory irritation.

H336 : May cause drowsiness or dizziness.

H361d : Suspected of damaging fertility or the unborn child.

H373 : May cause damage to organ(s) through prolonged or repeated

exposure.

Precautionary statement(s)

P210 : Keep away from heat/sparks/open flames/hot surfaces – No

smoking.

P233 : Keep container tightly closed.

P261 : Avoid breathing dust/fume/gas/mist/vapors/spray.

P264 : Wash hands with soap and plenty of water after handling.

P280 : Wear protective gloves/protective clothing/eye protection/face

protection.

P310 : Immediately call a POISON CENTER or doctor/physician.

P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

P501 : Dispose of contents/container to be in accordance with

local/regional/national regulations.

2.4 Other hazards

Substance meets the criteria : No.

for PBT (Persistent,

Bioaccumulative, and Toxic)

Substance meets the criteria : No.

for vPvB (very Persistent and

very Bioaccumulative)

Other hazards which do not : Repeated exposure may cause skin dryness or cracking.

result in classification

This product is considered to be hazardous according to the criteria specified in 29 CFR 1900.1200.




3.1 Description of the substance/mixture : Mixture of solvents.

OSHA HAZARDOUS COMPONENTS (29 CFR 1910.1200):

3.1.1 Hazardous components

Component CAS No. EC No. Index No. UN No. Percent GHS Classification Type

Butan-2-one 78-93-3 201-159-0 606-002-00-3 1193 40 - 60 Flam. Liq. 2, H225

Eye Irrit. 2, H319

STOT SE 3, H336

EUH066

[1]

[2]

Butan-1-ol 71-36-3 200-751-6 603-004-00-6 1120 30 - 60 Flam. Liq. 3, H226

Acute Tox. 4*

, H302

STOT SE 3, H335

Skin Irrit. 2, H315

Eye Dam. 1, H318

STOT SE 3, H336

[1]

[2]

Ethyl hydroxide 64-17-5 200-578-6 603-002-00-5 1987 10 - 40 Flam. Liq. 2, H225 [2]

Propan-2-ol 67-63-0 200-661-7 603-117-00-0 1219 10 - 20 Flam. Liq. 2, H225

Eye Irrit. 2, H319

STOT SE 3, H336

[1]

[2]

Methylbenzene 108-88-3 203-625-9 601-021-00-3 1294 1 - 5 Flam. Liq. 2, H225

Repr. 2, H361d***

Asp. Tox. 1, H304

STOT RE 2, H373**

Skin Irrit. 2, H315

STOT SE 3, H336

[1]

[2]

Xylol 1330-20-7 215-535-7 601-022-00-9 1307 1 - 5 Flam. Liq. 3, H226

Acute Tox. 4*, H332

Acute Tox. 4*, H312

Skin Irrit. 2, H315

[1]

[2]

Components in this product are not known or reported to be carcinogenic in humans by any reference source

including OSHA, IARC, NTP, ACGIH, or EPA.

3.2 Additional information

[1] Substance classified with a health or environmental hazard.

[2] Substance with a workplace exposure limit.

[3] Substance meets the criteria for PBT.

[4] Substance meets the criteria for vPvB.

Occupational exposure limits, if available, are listed in Section 8.

See Section 2 for the full text of the H-codes declared above.

3. COMPOSITION/INFORMATION ON INGREDIENTS




4.1 Description of first aid measures

4.1.1 General information : General first aid measures should be followed. In case of

persistent adverse effects, seek immediate medical attention.

Remove contaminated clothing and shoes promptly, and wash

thoroughly before re-use.

4.1.2 Following inhalation : NOTE: Reports have associated repeated and prolonged

occupational overexposure to solvents with permanent brain

and nervous system damage. Intentional misuse by deliberately

concentrating and inhaling the contents may be harmful or fatal.

: Emergency responders should use positive air supplied

respiratory protection when removing the victim from area.

Remove person to fresh air. If not breathing, administer CPR

until help arrives, or the victim starts to breathe on their own.

Give artificial respiration if breathing has stopped. Seek medical

attention immediately.

4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area

thoroughly with water for at least 15 minutes. Use soap if

available. Remove contaminated clothing, including shoes, after

flushing has begun. Wash clothing before re-use. If irritation

persists, seek medical attention.

4.1.4 Following eye contact : Immediately flush affected eye with water for at least 20

minutes. ilt the head to prevent chemical from transferring to

the unaffected eye. Seek medical attention without delay after

flushing.

4.1.5 Following ingestion : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out

with water. Dilute with milk or water. Never give anything to

drink if the victim is unconscious or having convulsions. Seek

medical attention immediately. Contact Poison Control Center at

once.

4.1.6 Self protection of the first aider : Appropriate personal protective attire should be worn.

4.1.7 Note to the doctor : Suitable medical intervention should be provided based on

symptoms.

4.2 Most important symptoms and : Irritating to eyes, skin, and respiratory tract upon exposure. High

effects, both acute and delayed vapour concentrations are irritating to eyes, nose, throat, and

lungs; may cause unconsciousness or other signs of central

nervous system depression. Frequent or prolonged skin contact

may irritate the skin and cause skin rash (dermatitis). May cause

4. FIRST AID MEASURES


Product No: FCSB No.3 Prepared Date: 07/02/2012


skin sensitization, an allergic reaction which becomes evident on

re-exposure to this material. Small amounts of this liquid may be

drawn into the lungs by either swallowing or vomiting. This may

cause severe and delayed health effects such as inflammation of

the lungs (pulmonary edema) and infection of the bronchi

(bronchopneumonia). Ingestion may cause irritation of digestive

track and diarrhea.

4.3 Indication of any immediate : Always get immediate medical attention/advice when symptoms

medical attention and special persist.

treatment needed

Fire Fighting Measures : The following applies to Butan-2-one

FLASHPOINT: 26oF

SPECIFC GRAVITY: 0.806 @ 68o

F

EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%.

AUTOIGNITION TEMPERATURE: 961.0oF.

5.1 Extinguishing media

Suitable extinguishing media : Either allow fire to burn out under controlled conditions, or

extinguish with alcohol type or all purpose type foam, or dry

chemical powder. Try to cover liquid spills with appropriate

foam. Use water spray to cool fire exposed surfaces. Avoid

spraying water directly into storage containers due to danger of

boilover. Shut off fuel to fire if possible to do so without hazard.

If a spill has not ignited, use water spray to disperse the vapors.

Unsuitable extinguishing media : Do not use high volume water jet.

5.2 Special hazards arising from : Flammable liquid; may release vapors that form flammable

the mixture mixtures when temperatures are at or above the flash point.

There is a danger of explosion when container is heated or in

fire. Toxic gases will form upon combustion. Vapor may

may accumulate in low or confined areas or travel to a

considerable distance to a source of ignition and flash back.

Avoid runoff into storm sewers and ditches.

Hazardous combustion products : Smoke, fumes, oxides of carbon, irritating or toxic vapors or

gases.

5.3 Advice for fire-fighters

Protective equipment for : Respiratory and eye protection gear is required for fire

fire fighters fighting personnel. Full protective equipment (Bunker Gear)

5. FIRE FIGHTING MEASURES




and a self-contained breathing apparatus (SCBA) should be

used for all indoor fires and any significant outdoor fires. Use

portable fire extinguisher for small outdoor fires. Use of SCBA

may not be required.

5.4 Additional information : Exposure to decomposition products may cause health

hazards. Cool containers exposed to fire with water spray.

Move unexposed containers from fire area if this can be done

without risk.

6.1 Personal precautions, protective equipment and emergency procedures

6.1.1 For non-emergency personnel :

Protective equipment : Wear suitable personal protective equipment (e.g. clothing,

gloves, safety goggles, and mask/respirator). Ensure adequate

ventilation; remove all sources of ignition. Notify the

appropriate authorities immediately.

Emergency procedures : Eliminate ignition source. Shut off leak if safe to do so. Take

all additional action necessary to prevent and remedy the

adverse effects of the spill. Isolate hazard area and deny entry

to unauthorized or unprotected personnel. Contain spilled liquid

with sand or earth. DO NOT use combustible materials such as

saw dust. Absorb spill with an inert material (e.g., sand or earth).

Then place in a chemical waste container.

6.1.2 For emergency responders : Respiratory and eye protection gear is required for emergency

personal protective equipment responders. Full protective equipment (Bunker Gear) and a

self-contained breathing apparatus (SCBA) should be used for

all indoor fires and any significant outdoor fires. Use portable

fire extinguisher for small outdoor fires. Use of SCBA may not

be required.

6.2 Environmental precautions : Avoid dispersal of spilt material and runoff into soil, storm

sewers and ditches which lead to natural waterways, or the

immediate environment. Inform the relevant authorities if the

product has entered into the environment.

6.2 Methods of containment and cleaning up

6.3.1 On water : If spill in water, remove from water surface by skimming

or with suitable absorbent material and place in appropriate

disposal container. If allowed by local environmental

regulatory agencies, you may use a suitable dispersant.

6. ACCIDENTAL RELEASE MEASURES




6.3.2 On ground/floor : Contain spill and absorb with an inert material (e.g., dry sand or

earth). Then place in an appropriate waste container for disposal

according to local regulations. Large spills should be disposed of

via a licensed waste disposal establishment/contractor.

6.3.3 Other information : Contaminated absorbent material may pose similar hazard as the

spill product.

6.4 Reference to other sections See Section 1 for emergency contact information.

See Section 8 for information on appropriate personnel protective equipment.

See Section 13 for additional disposal information.

7.1 Precautions for safe handling

7.1.1 Protective measures : Wear appropriate personal protective equipment. Do not get in

eyes, on skin, or on clothing. Do not breathe vapor or mist.

Do not eat, drink, or smoke when using this product. Use only

with adequate ventilation. Keep away from sources of ignition.

Keep only in original container. Keep tightly closed when not

in use. Do not reuse container. Avoid release to the environ-

ment.

7.1.2 Advice on general occupational : Avoid eating, drinking and smoking in areas where this product

hygiene is handled, used and stored. Wash hands before eating, drinking

and smoking, and at the end of the working period. Contamina-

ted work clothing and protective equipment should not be

brought into eating, smoking and drinking areas. Wash soiled

clothing before re-using.

7.2 Conditions for safe storage, including any incompatibilities

Technical measures and : Store at ambient/room temperature. Protect from extreme cold

storage conditions and heat. Store in a segregated and approved area. Store away

from strong oxidizing agents. Loosen closure cautiously with

non-sparking tools before opening. Keep only in original con-

tainer. Store and use away from sparks, heat, open flames and

other ignition sources. Ground and bond containers and recei-

ving equipment. Store locked up. Store away from direct sun

-light in a dry, cool and well-ventilated area. Containers that

have been opened must be carefully resealed and kept upright

to prevent leakage. Ground and bond containers when

transferring material. Ventilation required along storage floor.

Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plastic

bottles and containers.

7. HANDLING AND STORAGE




7.3 Specific end use(s)

Recommendations : For industrial use only.

Industrial sector specific : Not available.

solutions

There is no workplace exposure data available on the product itself.

8.1 Control parameters

8.1.1 Occupational Exposure Limits (OELs) :

Occupational Exposure Limit (OELs) Values Exposure Limits Long Term Limit

(8-hour period) - TWA

Short Term Limit

(15-minute(s) period) - STEL

Limit Value Type

Chemical Name ppm [mg/m3] ppm [mg/m

3] Letter Code*

Butan-2-one

Health Factor

200

200

200

3,000

590

590

590

-

-

300

300

-

-

885

885

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Butan-1-ol

Health Factor

100

20

50

1,400

300

61

150

-

-

-

-

-

-

-

-

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Ethyl hydroxide

Health Factor

1000

1000

1000

3,300

1900

1880

1900

-

-

-

-

-

-

-

-

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Propan-2-ol

Health Factor

400

200

400

2,000

980

491

980

-

-

400

500

-

-

983

1,225

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Methylbenzene

Health Factor

200

50

100

500

750

188

375

-

-

-

150

-

-

-

560

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Xylol

Health Factor

100

100

100

900

435

434

435

-

-

150

150

-

-

651

655

-

OSHA (PEL)

ACGIH (TLV)

NIOSH (REL)

NIOSH (IDLH)

Exposure limits provided in the above table contains generic information and guidance on air

contaminants in the workplace. Please consult your local exposure values. Federal and State

requirements may differ.

8. EXPOSURE CONTROL/PERSONAL PROTECTION




Recommended monitoring : If this product contains ingredients with exposure limits,

procedures personal, workplace atmosphere or biological monitoring may

be required to determine the effectiveness of the ventilation or

other control measures and/or the necessity to use respiratory

protective equipment. Reference should be made to European

Standard EN 689 for methods for the assessment of exposure

by inhalation of chemical agents and national guidance

documents for methods for the determination of hazardous

substances.

Derived effect levels [DNEL] : See occupational exposure limits table for guidance.

Predicted effect concentrations : Not available.

(PNEC Summary)

8.1 Exposure controls

8.1.1 Appropriate engineering : Provide adequate local exhaust ventilation to maintain worker

controls below exposure limits. The use of mechanical ventilation

controls is recommended whenever this product is used in a

confined space, is heated above ambient temperatures, or is

agitated. Use explosion-proof ventilation equipment.

8.2 Personal protective equipment

8.2.1 Eye and face protection : Safety eyewear complying with an approved standard should be

used when a risk assessment indicates this is necessary to avoid

exposure to liquid splashes, mist, or dust. See OSHA Standard

(29 CFR 1910.133) and applicable State regulations.

8.2.2 Skin protection

Hand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling

chemical products if a risk assessment indicates this in necessary.

Refer to 29 CFR 1910.138 if necessary.

Body protection : Personal protective equipment for the body should be selected

based on the task being performed and the risks involved and

should be approved by a specialist before handling this product.

Consult OSHA 29 CFR 1910.136 for direction.

Other skin protection : Appropriate footwear and any additional skin protection mea-

sures should be selected based on the task being performed and

the risks involved and should be approved by a specialist before

handling this product.

8.3 Respiratory protection : Use approved respiratory protection equipment. Respirator

selection should be based on the form and concentration of

contaminants in the air and in accordance with local regulations.




Guidance on respiratory protection is provided in 29 CFR

1910.134.

8.4 Environmental exposure : Emission from ventilation or work process equipment should be

controls checked to ensure they comply with the requirements of envi-

ronmental protection legislation. Ensure that emission is at the

acceptable level.

9.1 Information on physical and chemical properties

Physical state : Liquid.

Colour : Characteristic.

Odour : Solvent odour.

Odour threshold : Not determined.

pH : Not available .

Melting/freezing point [o

F] : Not available.

Initial boiling point/range [o

F] : Not available.

Flash point [o

F] : Not available.

Evaporation rate (n-Butyl Acetate : Not available.

= 1)

Flammability (solid, gas) : Not available.

Upper flammability : Not available.

Lower flammability : Not available.

Vapour pressure, mm Hg @ 75 o

F : Not available.

Vapour density (Air = 1) : Not available .

Relative density : Not available.

Solubility in water, Wt % @ 68 o

F : Not available.

Partition coefficient: n- : Not available.

Octanol/water

Auto-ignition temperature : Not available.

Decomposition temperature : Not applicable.

Viscosity of Liquid, CST @ 25o

C : Not available.

Explosive properties : Not available.

Oxidizing properties : Not available.

9.2 Other information : Experimental material. Certificate of Analysis is not available.

10.1 Reactivity : Reactivity does not occur.

10.2 Chemical stability : Stable under normal conditions.

10.3 Possibility of hazardous reactions : Hazardous polymerization will not occur.

10.4 Conditions to avoid : Open flames and sources of ignition. Incompatible products.

9. PHYSICAL AND CHEMICAL PROPERTIES

10. STABILITY AND REACTIVITY




10.5 Incompatible materials : Strong oxidizing agents.

10.6 Hazardous decomposition products : Burning can produce oxides of carbon.

11.1 Information on toxicological effects

11.1.2 Mixture : There is no data available on the product itself.

11.1.2.1 : Relevant effects:

Component Carcinogenicity

Information on components CAS Registry Carcinogenicity Databases

Constituents/Ingredients CAS No. OSHA-Z NTP IARC ACGIH EPA

Butan-2-one 78-93-3 - - - - Group D

Butan-1-ol 71-36-3 - - - - -

Ethyl hydroxide 64-17-5 - - - Group A4 -

Propan-2-ol 67-63-0 - - Group 3 Group A4 -

Methylbenzene 108-88-3 - - Group 3 Group A4 Group D

Xylol 1330-20-7 - - Group 3 Group A4 Group D

Classifications :

ACGIH : Group A4: Not classifiable as a human carcinogen.

EPA : Group D: Not classifiable as to Human Carcinogenicity.

IARC : Group 3: Not classifiable as to its carcinogenicity to humans.

(b) Irritation

Inhalation : May cause irritation to the nose, throat, and lungs. High

vapor concentrations may cause unconsciousness or other

signs of central nervous system depression.

Skin contact : Frequent or prolonged contact may irritate the skin and

cause skin rash (dermatitis). May cause skin sensitization,

an allergic reaction which becomes evident on re-exposure

to this material.

Eye contact : Severely irritating. If not removed promptly will injure eye

tissue, which may result in permanent damage.

Ingestion : May cause irritation of the digestive tract and diarrhea.

(c) Corrosivity : Severely irritating to eyes. Repeated exposure may cause skin

dryness or cracking.

11. TOXICOLOGICAL INFORMATION




(d) Sensitization : May cause skin sensitization and or respiratory system irritation

due to extended exposure of the preparation above stated occu-

pational exposure limits.

(e) Single dose toxicity : No data available.

(f) Repeated dose toxicity : No data available.

(g) Carcinogenicity : No known significant effects or critical hazards.

(h) Mutagenicity : No information but adverse effects unlikely.

(i) Toxicity for reproduction : No known significant effects or critical hazards.

11.1.2.2 CMR effects : No known significant effects or critical hazards.

(carcinogenic, mutagenic or

toxic for reproduction)

11.2 Potential adverse health effects : Small amounts of this liquid may be drawn into the lungs by

either swallowing or vomiting. This may cause severe and

delayed health effects such as inflammation of the lungs (

pulmonary edema) and infection of the bronchi(broncho-

pneumonia). Ingestion may cause irritation to the digestive

tract or diarrhea.

11.3 Potential chronic health effects : There is no evidence that exposure to Butan-2-one alone

causes progressive or irreversible neurotoxic effects.

However, simultaneous over-exposure to Butan-2-one and

n-Hexane can potentiate the known irreversible neurotoxic

effects of n-Hexane. There is no reported human evidence

that these neurotoxic effects occur when exposure to both

chemicals is maintained below established regulatory limits.

11.4 Other information : The mixture is not likely to be carcinogen in humans.

Note: Ecological testing has not been done on the product. Ecotoxicological information on components of

this product is presented below.

12.1 Toxicity :

Butan-2-one [CAS#: 78-93-3]

Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)

Acute fish toxicity LC50 96 hour (s) Pimephales promelas 3220

Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna > 520

Acute algae toxicity EC3 7 days Scenedesmus quadricauda ≥ 4300

12. ECOLOGICAL INFORMATION




Butan-1-ol [CAS#: 71-36-3]


Acute fish toxicity LC50 96 hour (s) Pimephales promelas < 1630

Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 1983

Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 500

Ethyl hydroxide [CAS#: 64-17-5]


Acute fish toxicity LC50 96 hour (s) Alburnus alburnus 10000 - 11500

Acute Daphnia toxicity LC50 48 hour (s) Daphnia magna 9268 - 14221

Acute algae toxicity EC50 Not specified Chlorella pyrenoidosa 9310

Propan-2-ol [CAS#: 67-63-0]



Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 13299

Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 1000

Methylbenzene [CAS#: 108-88-3]



Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 11.5

Acute algae toxicity EC50 48 hour (s) Scenedesmus subspicatus 125 - 160

Xylol [CAS #: 1330-20-7]


Acute fish toxicity LC50 96 hour (s) Cyprinus carpio > 780

Acute invertebrate toxicity LC50 48 hour (s) Palaemonetes pugio 0.85

Acute algae toxicity Mortality Unknown Scenedesmus quadricauda > 200

12.2 Persistence and degradability : No data available for this product.

(Biochemical Oxygen Demand – BOD values)

Substance name Quantity Degradation rate (%) Incubation time Evaluation (inoculum)

Butan-2-one Unknown 83 5 days Sewage

Butan-1-ol Unknown 66 5 days Sewage sludge

Ethyl hydroxide 10 mg/l 74 5 days Filtered sewage seed

Propan-2-ol 10 mg/l 78*

20 days Filtered sewage seed

Methylbenzene Unknown Completely Short duration Sewage seed

Xylol Isomers 72 20 days Activated sewage

* Theoretical Oxygen Demand (ThOD) value.




12.3 Bioaccumulative potential : No data available for this product.

(BCF – Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate

Substance name Estimated BCF log Kow Remarks

Butan-2-one 3 0.29 Low bioaccumulation

Butan-1-ol 3 0.88 Low bioaccumulation

Ethyl hydroxide 3 -0.31 Low bioaccumulation

Propan-2-ol 3 0.05 Low bioaccumulation

Methylbenzene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation

Xylol 6 – 23.4 3.2 Low bioaccumulation

12.4 Mobility in soil : No data available for this product.

Koc – The soil absorption coefficient

Substance name Koc value Remarks (soil mobility)

Butan-2-one 29 Very high mobility

Butan-1-ol 72 High mobility

Ethyl hydroxide 1 Very high mobility

Propan-2-ol 25 Very high mobility

Methylbenzene variable High to moderate mobility

Xylol 39 – 365 for individual isomers Very high to moderate mobility

12.5 Results of PBT and vPvB assessment PBT : No data available.

vPvB : No data available.

12.6 Other adverse effects : No known significant effects or critical hazards.

13.1 Waste treatment methods Product

Methods of disposal : The generation of waste should be avoided or minimized

whenever possible. Empty containers or liners may retain

some product residues. This material and its container must

be disposed of in a safe way. Waste product residue should not

be disposed of via the foul sewer. Consult an expert on the dis-

posal of recovered and surplus material. Incinerate, or recover

by distillation. Ensure disposal is in compliance with current

government requirements and ensure conformity with local

authority regulations.

Packaging waste

Methods of disposal : The generation of waste should be avoided or minimized

whenever possible. Waste packaging should be recycled, or

dispose of according to state and local authority regulations.

Consult your State/Local Land Waste Management Authority.

NOTE: The use of this product should at all times comply with the requirements of environmental

protection and waste disposal legislations/statutes and any local authority requirements.

13. DISPOSAL CONSIDERATIONS




Special precautions : This material and its container must be disposed of according to

local authority regulations. Empty containers or packaging may

contain some product residue. Avoid dispersal of spilt material

and runoff to come in contact with soil, waterways, drains and

sewers.

DOT ADN/ADNR IMDG ICAO-TI/IATA-DGR

14.1 UN No. 1210 1210 1210 1210

14.2 Proper Shipping

Name

Printing Ink Related

Material


Material

Printing Ink

Related Material


Material

14.3 Transport hazard

class

3

3

3

3

14.4 Classification code

F1

F1

F1

F1

14.5 Packing group II II II II

14.6 Hazard label

14.7 Environmental

hazard

No

No

Marine pollutant:

No

No

14.8 Special provision(s) 163

640C

163

640C

163 Not available

Additional Information Hazard identification

number

33

Ltd. Qty

LQ6

Excpt. Qty

E2

Packaging

P001, PP1, MP19

Portable Tanks and

Bulk Cont.

T4; TP1, TP8

-

-

-

-

-

Ltd. Qty

LQ6

Excpt. Qty.

E2

-

-

-

-

Emergency

schedules (EmS)

Fire

F-E

Spillage

S-D

Ltd. Qty

5l

Excpt. Qty

E2

-

-

-

Passenger and Cargo

Aircraft

Quantity limitation:

1.0L

Packing instructions:

Y341

353 5.0L

Cargo Aircraft only

Quantity limitation:

60.0 L

Packaging instruction:

364

-

-

14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.

14. TRANSPORTATION INFORMATION


Product No: FCSB No. 3 Prepared Date: 07/02/2012


This Safety Data Sheet has been prepared in accordance with HazCom 2012 requirements of OSHA’s

revised Hazard Communication Standard at 29 CFR 1910.1200

15.1 Regulatory Information

TSCA Inventory Status : All components are on the U.S. EPA TSCA Inventory.

SARA Title III/CERCLA :

Protective Action Criteria (PACs) :

Chemical PAC-1 PAC-2 PAC-3 LEL

Butan-2-one 200 ppm 2,700 ppm 4,000 ppm 1,400 ppm

Butan-1-ol 20 ppm 50 ppm 8,000 ppm 14,000 ppm

Ethyl hydroxide 1,800 ppm 3,300 ppm 15,000 ppm 33,000 ppm

Propan-2-ol 400 ppm 400 ppm 1,200 ppm 20,000 ppm

Methylbenzene 200 ppm 1,200 ppm 4,500 ppm 11,000 ppm

Xylol 130 ppm 920 ppm 2,500 ppm 9,000 ppm

Methylbenzene (Toluene) is regulated by the Drug Enforcement Administration and appears on List II (

21 CFR Section 1310.02(b) and 1310.04(f)(2).

Methylbenzene is a Toxic Pollutant under Section 307(a)(1) of the Clean Water Act and is subject to effluent

limitations.

State Regulatory Information : Components of this product are covered under specific State

regulations.

California Proposition 65 : This material contains components which are known

to the State of California to cause cancer, birth defects or other

reproductive harm.

Chemical Weapons Convention List

Schedule I Chemicals


Schedule II Chemicals


Schedule III Chemicals

Not listed Not listed Not listed

Chemical CAA RMP CERCLA (RQ) EHS (EPCRA 302) TRI (EPCRA 313)

Butan-2-one Not regulated. Regulated chemical. RQ of

5000 lbs.

Not regulated. Regulated chemical.

Butan-1-ol Not regulated. Regulated chemical. RQ of

5000 lbs.


Ethyl hydroxide Not regulated. Not regulated. Not regulated. Not regulated.

Propan-2-ol Not regulated. Not regulated. Not regulated. Regulated chemical.

Methylbenzene Not regulated. Regulated chemical. RQ of

1000 lbs.


Xylol Not regulated. Regulated chemical. RQ of 100

lbs.


15. REGULATORY INFORMATION



Version: 1.00 Printing Date:07/07/2012

NOTE : This Safety Data Sheet was created as a teaching aid for

freelance safety data sheet writers. The mixture is fictitious.

Product : The product was classified in accordance with GHS

Classification of hazardous substances/mixtures and OSHA’s

requirements.

HMIS Code Hazard Rating NFPA Rating

1 = Health

3 = Flammability

0 = Reactivity

B = Personal Protective Equipment

HMIS/NFPA color scheme: Health = Blue; Red = Fire; Yellow = Reactivity; White = PPE

16.1 Indication of changes

Date of previous issue : No previous validation.

Revisions : To comply with OSHA’s regulations.

Nature of version : Conforms to GHS, ANSI, and OSHA HazCom 2012 Format.

Version : 1.00

Date of issue : 07 July, 2012.

Prepared by : Theodore M. Amet, Regulatory Research Analyst

16.2 Abbreviations and acronyms

ACGIH: American Conference of Governmental Industrial Hygienists;

ADR: Accord européen sur le transport des merchandises dangereuses par Route (European Agreement

concerning the International Carriage of Dangerous Goods by Road);

CAA: Clean Air Act;

CAS#: Chemical Abstract Service Registry Number;

CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act;

CFR: Code of Federal Regulations;

DOT: Department of Transportation;

EINECS: European Inventory of Existing Commercial chemicals Substances;

EHS: Extremely Hazardous Substances;

EPA: Environmental Protection Agency;

EPCRA: Emergency Planning and Community Right-to-Know Act;

GHS: Globally Harmonized System of Classification and Labelling of Chemicals;

IARC: International Agency for Research on Cancer;

IATA: International Air Transport Association;

IATA-DGR: Dangerous Goods Regulations by the “International Air Transport Association” (IATA);

ICAO: International Civil Aviation Organization;

ICAO-TI: Technical Instructions by the “International Civil Aviation Organization” (ICAO);

16. OTHER INFORMATION




IDLH: Immediately Dangerous to Health or Life;

IMDG: International Maritime Code for Dangerous Goods;

LEL: Lower Explosion Limit;

NIOSH: National Institute for Occupational Safety and Health;

NTP: National Toxicology Program;

OSHA: Occupational Safety and Health Administration;

PEL: Permissible Exposure Limit;

REL: Recommended Exposure Limit;

RID: Règlement international concernant le transport des merchandises dangereuses par chemin de fer

(Regulations Concerning the International Transport of Dangerous goods by Rail);

RMP: Risk Management Program;

RQ: Reportable Quantity;

SARA: Superfund Amendment and Reauthorization Act;

STEL: Short Term Exposure Limit;

TLV: Threshold Limit Value;

TRI: Toxic Release Inventory;

TSCA: Toxic Substances Control Act;

TWA: Time Weighted Average.

16.3 Key literature references : CAMEO Chemicals;

and sources of data ESIS (Existing chemical Substances Information System);

OSHA - Chemical Sampling Information (CSI) – OELs;

TOXNET;

Information from technical literature;

Internet research;

Substance Material Safety Data Sheets.

DISCLAIMER

This document was compiled as a service to freelance U.S. Safety Data Sheets writers. Information included

within this material is based on data gathered from many sources. No warranty is expressed regarding the

accuracy of data obtained from various chemical, health, toxicological, and environmental databases.

Responsibility for the accuracy and completeness of information contained herein rests with users who must

satisfy themselves that the data is appropriate for their needs. It is always a good practice to consult a sectional

expert when writing sections of the safety data sheets to clarify and simplify technical matters.

END OF SAMPLE SAFETY DATA SHEET

amet,tm sample us ansi ghs compliant sds

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