amet,tm sample australia nohsc ghs clp sds

7/31/2019 Amet,Tm Sample Australia Nohsc Ghs Clp Sds

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SAMPLE AUSTRALIA SAFETY DATA SHEETPrepared according to ASCC/NOHSC and EU CLP-GHS criteria

Product Name: Fendell Cleaning Solvent Blend No. 3 Page 1 of 21

Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/ 03/2012

1.1 Identification of the substance or mixture1.1.1 Mixture name : Fendell Cleaning Solvent Blend No. 31.1.2 Product/SDS Code : FCSB No. 3

1.1.3 Product description : Mixture of solvents.

1.2 Uses of the mixture and uses advised against1.2.1 Uses of the mixture : Research and Development (R&D) use only.

1.2.2 Uses advised against : Not for personal, household or other uses.

1.3 Company Identification1.3.1 Manufacturer/Supplier : Sao Boso Chemicals Pty Ltd.

1.3.2 Contact informationStreet address : 8000 Anabaena Avenue

Castle Hill, NSW XXXX

Australia

Telephone number : + 61 2 0000 1234

Telefax number : + 61 2 0000 5678

1.3.3 E-mail of contact person : [email protected]

1.4 Emergency telephone number (s) : Chemical Emergency: 1 800 033 111

Life Emergency: 000Poisons Information Centre: 13 11 26 (24 hours/7days)

Chemical Spills- EPA: 13 15 55 or 1 800 018-800

1.4.1 Further information obtainable from : Product Stewardship

Monday to Friday: 6 am - 6 pm (AEST)

The product is classified as DANGEROUS according to the Australian Dangerous Goods Code.

Classified as Hazardous according to ASCC/NOHSC/EU criteria.

Hazards : Highly flammable liquid and vapour.Irritating to eyes and respiratory tract.Harmful by inhalation, in contact with skin and if

swallowed.

POISON SCHEDULE : S5

Road Transport : HAZCHEM CODE = 3[Y]EUN Number : 1210

Proper Shipping Name : Printing Ink Related Material

Dangerous Goods Class : 3Packing Group : II

1. IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING

2. HAZARDS IDENTIFICATION


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Product Code: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

Classification of the substance or mixture

Product definition : Mixture.

2.1.1 Classification according to Regulation (EC) No 1272/2008 [CLP/GHS]Flammable liquids, Category 2, H225

Acute toxicity (dermal), Category 4, H312

Acute toxicity (inhalation), Category 4, H332Acute toxicity (oral), Category 4, H302

Aspiration hazard, Category 1, H304

Skin corrosion/irritation, Category 2, H315Serious eye damage/Eye irritation, Category 1, H318

Reproductive toxicity D, Category 2, H361d

Specific Target Organ Toxicity Single exposure H335Respiratory tract irritation, Category 3,

Specific Target Organ Toxicity Single exposure H336

Narcotic effects, Category 3,Specific Target Organ Toxicity H373

Repeated exposure, Category 2,

2.1.2 Classification of the mixture according to Hazardous Substances Information System (HSIS)

Risk Phrases: (R-) 10, 11, 20/21, 22, 36, 37/38, 38, 41, 48/20, 63, 65, 66, 67

Safety Phrases: (S-) 2, 7, 7/9, 9, 13, 16, 24/25, 25, 26, 36/37, 37/39, 46, 62

Hazard CategoryF : Flammable.

Xi : Irritant.

Xn : Harmful.

2.1.3 Additional Information

This material is a Scheduled S5 Poison and must be stored, handled and used according to the

appropriate regulation.

2.1 Label elementsLabelling according to Regulation (EC) No 1272/2008 [CLP/GHS]

Product identifier: Mixture

Hazard components for labeling: 3-Butanone, Toluene, Xylene

GHS Label ElementsGHS Symbol

(Hazard Pictogram)

GHS Code GHS02 GHS05 GHS07 GHS08

Description Flame Corrosion Exclamation Mark Health Hazard

Signal Word DANGER


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Product Code: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

Hazard statement(s)H225 : Highly flammable liquid and vapour.

H302 : Harmful if swallowed.

H304 : May be fatal if swallowed and enters airways.

H312 : Harmful in contact with skin.H315 : Causes skin irritation.

H318 : Cause serious eye damage.

H332 : Harmful if inhaled.H335 : May cause respiratory irritation.

H336 : May cause drowsiness or dizziness.

H361d : Suspected of damaging the unborn child.H373 : May cause damage to organ(s) through prolonged or repeated

exposure

Precautionary statement(s)P210 : Keep away from heat/sparks/open flames/hot surfaces No

smoking.P233 : Keep container tightly closed.

P261 : Avoid breathing dust/fume/gas/mist/vapours/spray.P264 : Wash hands with soap and plenty of water after handling.

P280 : Wear protective gloves/protective clothing/eye protection/face

protection.P310 : Immediately call a POISON CENTER or doctor/physician.

P403 + P233 : Store in a well-ventilated place. Keep container tightly closed.

P501 : Dispose of contents/container to be in accordance withlocal/regional/national regulations.

2.3 Other hazards

Substance meets the criteria : No.for PBT according toRegulation (EC) No 1207/2006, : P: Not available. B: Not available. T: No.

Annex XIII

Substance meets the criteria : Not available.

forvPvB according to

Regulation (EC) No 1207/2006,Annex XIII

Other hazards which do not : Repeated exposure may cause skin dryness or cracking.

result in classification

This product is classified as dangerous according to the Australian Dangerous Goods Code

3.1 Description of the substance/mixture : Mixture of solvents.

3. COMPOSITION/INFORMATION ON INGREDIENTS


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Hazardous ingredients

Chemical/

SubstanceName

CAS No. EC No. Index No. RRN* Weight (%)

Classification

HSIS Regulation (EC)

No. 1272/2008[CLP-GHS]

Type

3-Butanone 78-93-3 201-159-0 606-002-00-3 - 40 60 F; R11

Xi; R36-66-67S: (2-) 9, 16

Flam. Liq. 2,

H225Eye irrit. 2,

H319

STOT SE 3,H336

EUH066

[1]

[2]

n-Butanol 71-36-3 200-751-6 603-004-00-6 - 30 60 R10

Xn; R22

Xi; R37/38,R41, R67

S: (2-)7/9, 13,

26, 37/39, 46

Flam. Liq. 3,

H226

Acute Tox. 4*

H302

STOT SE 3

H335

Skin Irrit. 2H315

Eye Dam. 1

H318STOT SE 3

H336

[1]

[2]

Ethanol 64-17-5 200-578-6 603-002-00-5 - 10 40 F; R11

S: (2)7, 16

Flam. Liq. 2

H225

[2]

Isopropanol 67-63-0 200-661-7 603-117-00-0 - 10 20 F, R11

Xi; R36, R67

S: (2-)

7,16,24/25, 26

Flam. Liq. 2

H225Eye Irrit. 2

H319

STOT SE 3H336

[1]

[2]

Toluene 108-88-3 203-625-9 601-021-00-3 - 1 5 F; R11Repr. Cat. 3

R63

Xn; R48/20,R65

Xi; R38, R67

S; (2-) 36/37,

62

Flam. Liq. 2H225

Repr. 2

H361d***

Asp. Tox. 1

H304

STOT RE 2H373

**

Skin Irrit. 2

H315

STOT SE 3H336

[1]

[2]

Table continued on next page.


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Chemical/Substance

Name

CAS No. EC No. Index No. RRN* Weight (%)

Classification

67/548/EEC Regulation (EC)No. 1272/2008[

CLP]

Type

Xylene 1330-20-7 215-535-7 601-022-00-9 - 1 5 R10

Xi; R38

S; (2) 25

See Section 16

for the fulltext of the R-

phrases

declared

above.

Flam. Liq. 3

H226

Acute Tox. 4*

H332

Acute Tox. 4*

H312Skin Irrit. 2

H315

See Section 2

for the fulltext of the H-

statements

declared

above.

[1]

[2]

*RRN: REACH Registration Number. Product classified according to NOHSC criteria. All hazardous substances are declared.

All other ingredients not hazardous according to ASCC/NOHSC/EU Criteria.

3.2 Additional information

[1] Substance classified with a health or environmental hazard[2] Substance with a workplace exposure limit

[3] Substance meets the criteria for PBT according to Regulation (EC) No 1207/2006, Annex XIII

[4] Substance meets the criteria for vPvB according to Regulation (EC) No 1207/2006, Annex XIII

Occupational exposure limits, if available, are listed in Section 8.

4.1 Description of first aid measures4.1.1 General information : General first aid measures should be followed. In case of

persistent adverse effects, seek immediate medical attention.Remove contaminated clothing and shoes promptly, and wash

thoroughly before re-use.

4.1.2 Following inhalation : NOTE: Reports have associated repeated and prolonged

occupational overexposure to solvents with permanent brainand nervous system damage. Intentional misuse by deliberatelyconcentrating and inhaling the contents may be harmful or fatal.

: Emergency responders should use positive air suppliedrespiratory protection when removing the victim from area.

4. FIRST AID MEASURES


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Product No: FCSB No.3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

Remove person to fresh air. If not breathing, administer CPRuntil help arrives, or the victim starts to breathe on their own.

Give artificial respiration if breathing has stopped. Seek medical

attention immediately.

4.1.3 Following skin contact : If exposure occurs, immediately flush the affected area

thoroughly with water for at least 15 minutes. Use soap if

available. Remove contaminated clothing, including shoes, afterflushing has begun. Wash clothing before re-use. If irritation

persists, seek medical attention.

4.1.4 Following eye contact : Immediately flush affected eye with water for at least 20

minutes. ilt the head to prevent chemical from transferring to

the unaffected eye. Seek medical attention without delay afterflushing.

4.1.5 Following ingestion : DO NOT INDUCE VOMITING if swallowed. Rinse mouth out

with water. Dilute with milk or water. Never give anything todrink if the victim is unconscious or having convulsions. Seek

medical attention immediately. Contact Poison Control Center at

once.

4.1.6 Self protection of the first aider : Appropriate personal protective attire should be worn.

4.1.7 Note to the doctor : Suitable medical intervention should be provided based on

symptoms - treat symptomatically.

In case of poisoning, contact Poisons Information Centre: In Australia call on 13 11 26

In New Zealand call on 03 47 47 000

4.2 Most important symptoms and : Irritating to eyes, skin, and respiratory tract upon exposure. High

effects, both acute and delayed vapour concentrations are irritating to eyes, nose, throat, andlungs; may cause unconsciousness or other signs of central

nervous system depression. Frequent or prolonged skin contact

may irritate the skin and cause skin rash (dermatitis). May cause

skin sensitization, an allergic reaction which becomes evident onre-exposure to this material. Small amounts of this liquid may be

drawn into the lungs by either swallowing or vomiting. This may

cause severe and delayed health effects such as inflammation ofthe lungs (pulmonary edema) and infection of the bronchi

(bronchopneumonia). Ingestion may cause irritation of digestive

track and diarrhea.

4.3 Indication of any immediate : Always get immediate medical attention/advice when symptoms

medical attention and special persist.

treatment needed


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Fire Fighting Measures : The following applies to 3-Butanone

FLASHPOINT: -3.33oCSPECIFC GRAVITY: 0.806 @ 20

oC

EXPLOSIVE LIMITS: LEL: 1.8%, UEL: 11.0%.

AUTOIGNITION TEMPERATURE: 516.11oC.

HAZCHEM CODE : 3[Y] E (Australia)

5.1 Extinguishing media

Suitable extinguishing media : Either allow fire to burn out under controlled conditions, orextinguish with alcohol type or all purpose type foam, or dry

chemical powder. Try to cover liquid spills with appropriatefoam. Use water spray to cool fire exposed surfaces. Avoid

spraying water directly into storage containers due to danger ofboilover. Shut off fuel to fire if possible to do so without hazard.

If a spill has not ignited, use water spray to disperse the vapours.

Unsuitable extinguishing media : Do not use high volume water jet.

5.2 Special hazards arising from : Flammable liquid; may release vapours that form flammable

the mixture mixtures when temperatures are at or above the flash point.

There is a danger of explosion when container is heated or in

fire. Toxic gases will form upon combustion. Vapour maymay accumulate in low or confined areas or travel to aconsiderable distance to a source of ignition and flash back.

Avoid runoff into storm sewers and ditches.

Hazardous combustion products : Smoke, fumes, oxides of carbon, irritating or toxic vapours or

gases.

5.3 Advice for fire-fighters

Protective equipment for : Respiratory and eye protection gear is required for fire

fire fighters fighting personnel. Full protective equipment (Bunker Gear)and a self-contained breathing apparatus (SCBA) should be

used for all indoor fires and any significant outdoor fires. Use

portable fire extinguisher for small outdoor fires. Use of SCBAmay not be required.

5.4 Additional information : Exposure to decomposition products may cause healthhazards. Cool containers exposed to fire with water spray.

Move unexposed containers from fire area if this can be done

without risk.

5. FIRE FIGHTING MEASURES


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6.1 Personal precautions, protective equipment and emergency procedures6.1.1 For non-emergency personnel :

Protective equipment : Wear suitable personal protective equipment (e.g. clothing,

gloves, safety goggles, and mask/respirator). Ensure adequate

ventilation; remove all sources of ignition. Notify theappropriate authorities immediately.

Emergency procedures : Eliminate ignition source. Shut off leak if safe to do so. Takeall additional action necessary to prevent and remedy the

adverse effects of the spill. Isolate hazard area and deny entry

to unauthorized or unprotected personnel. Contain spilled liquidwith sand or earth. DO NOT use combustible materials such as

saw dust. Absorb spill with an inert material (e.g., sand or earth).Then place in a chemical waste container.

6.1.2 For emergency responders : Respiratory and eye protection gear is required for emergency

personal protective equipment responders. Full protective equipment (Bunker Gear) and a

self-contained breathing apparatus (SCBA) should be used forall indoor fires and any significant outdoor fires. Use portable

fire extinguisher for small outdoor fires. Use of SCBA may not

be required.

6.2 Environmental precautions : Avoid dispersal of spilt material and runoff into soil, storm

sewers and ditches which lead to natural waterways, or theimmediate environment. Inform the relevant authorities if theproduct has entered into the environment.

6.2 Methods of containment and cleaning up6.3.1 On water : If spill in water, remove from water surface by skimming

or with suitable absorbent material and place in appropriatedisposal container. If allowed by local environmental

regulatory agencies, you may use a suitable dispersant.

6.3.2 On ground/floor : Contain spill and absorb with an inert material (e.g., dry sand orearth). Then place in an appropriate waste container for disposal

according to local regulations. Large spills should be disposed of

via a licensed waste disposal establishment/contractor.

6.3.3 Other information : Contaminated absorbent material may pose similar hazard as the

spill product.

Emergency Information (Transport) :

Dangerous Goods : Initial Emergency Response Guide (SAA/SNZ HB76: 2004)For Liquids : Highly Flammable, Guide No: 14

6. ACCIDENTAL RELEASE MEASURES


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6.4 Reference to other sectionsSee Section 1 for emergency contact information.

See Section 8 for information on appropriate personnel protective equipment.

See Section 13 for additional disposal information.

7.1 Precautions for safe handling7.1.1 Protective measures : Wear appropriate personal protective equipment. Do not get in

eyes, on skin, or on clothing. Do not breathe vapour or mist.

Do not eat, drink, or smoke when using this product. Use onlywith adequate ventilation. Keep away from sources of ignition.

Keep only in original container. Keep tightly closed when not

in use. Do not reuse container. Avoid release to the environ-ment.

7.1.2 Advice on general occupational : Avoid eating, drinking and smoking in areas where this producthygiene is handled, used and stored. Wash hands before eating, drinking

and smoking, and at the end of the working period. Contamina-

ted work clothing and protective equipment should not be

brought into eating, smoking and drinking areas. Wash soiledclothing before re-using.

7.2 Conditions for safe storage, including any incompatibilitiesTechnical measures and : Store at ambient/room temperature. Protect from extreme cold

storage conditions and heat. Store in a segregated and approved area. Store away

from strong oxidizing agents. Loosen closure cautiously withnon-sparking tools before opening. Keep only in original con-tainer. Store and use away from sparks, heat, open flames and

other ignition sources. Ground and bond containers and recei-

ving equipment. Store locked up. Store away from direct sun-light in a dry, cool and well-ventilated area. Containers that

have been opened must be carefully resealed and kept upright

to prevent leakage. Ground and bond containers whentransferring material. Ventilation required along storage floor [

See AS 1940].

Packaging materials : Steel drum, HDPE (High Density Poly Ethylene) -2 plasticbottles and containers.

7.3 Specific end use(s)Recommendations : For industrial use only.Industrial sector specific : Not available.

solutions

No exposure standards are available for this product. The following exposure standards in the table below havebeen assigned by ASCC/NOHSC to the components in the product.

7. HANDLING AND STORAGE

8. EXPOSURE CONTROL/PERSONAL PROTECTION


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8.1 Control parameters8.1.1 Occupational Exposure Limits (OELs) :

Workplace Occupational Exposure Limit(s) OELs [ASCC/NOHSC]

Component Information Occupational Exposure LimitsAir contaminants sampling Long term limit

(8-hour TWA)

Short term limit (STEL)

(15-minutes exposure)

Health Hazard

Chemical Name CAS No ppm mg/m3

ppm mg/m3

Skin

Designation

Carcinogen

category

3-Butanone 78-93-3 150 445 300 890 - -

n-Butanol 71-36-3 50* 152* - - Sk -

Ethanol 64-17-5 1000 1880 - - - -

Isopropanol 67-63-0 400 983 500 1230 - -

Toluene 108-88-3 50 191 150 574 Sk -

Xylene 1330-20-7 80 350 150 655 - -

* = Peak limitationSk = Skin

Recommended monitoring : If this product contains ingredients with exposure limits,

procedures personal, workplace atmosphere or biological monitoring may

be required to determine the effectiveness of the ventilation or

other control measures and/or the necessity to use respiratoryprotective equipment. Reference should be made to European

Standard EN 689 for methods for the assessment of exposure

by inhalation of chemical agents and national guidancedocuments for methods for the determination of hazardous

substances.

Derived effect levels [DNEL] : No information .

Predicted effect concentrations : Not available.

(PNEC Summary)

8.1 Exposure controls8.1.1 Appropriate engineering : Highly flammable liquid. Provide adequate local exhaust

control ventilation to maintain worker below exposure limits. The use

of mechanical ventilation controls is recommended whenever

this product is used in a confined space, is heated above ambienttemperatures, or is agitated. Prevent accumulation of vapours in

hollows or sumps. Eliminate any sources of ignition.

Use explosion-proof ventilation

8.2 Personal protective equipment8.2.1 Eye and face protection : Safety eyewear complying with an approved standard should be

used when a risk assessment indicates this is necessary to avoidexposure to liquid splashes, mist, or dust. Chemical goggles or

spectacles with shields may be used to protect eyes.


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8.2.2 Skin protectionHand protection : Chemical-resistant, impervious gloves complying with an

approved standard should be worn at all times when handling

chemical products if a risk assessment indicates this in necessary

Body protection : Personal protective equipment for the body should be selected

based on the task being performed and the risks involved and

should be approved by a specialist before handling this product.

Other skin protection : Appropriate footwear and any additional skin protection mea-

sures should be selected based on the task being performed andthe risks involved and should be approved by a specialist before

handling this product.

8.3 Respiratory protection : Use approved respiratory protection equipment. Respirator

selection should be based on the form and concentration ofcontaminants in the air, and in accordance with local regulations.

Select and use respirators in accordance with AS/NZS1715/1716. Use Self Contained Breathing Apparatus (SCBA)

with positive pressure air supply complying with AS/NZS

1715/1716, or any other acceptable International Standard whenentering confined spaces with unknown levels of air pollutants.

8.4 Environmental exposure : Emission from ventilation or work process equipment should becontrols checked to ensure they comply with the requirements of envi-

ronmental protection legislation. Ensure that emission is at the

acceptable level.

9.1 Information on physical and chemical propertiesPhysical state : Liquid.

Colour : Characteristic.

Odour : Solvent odour.Odour threshold : Not determined.

pH : Not available .

Melting/freezing point [oC] : Not available.

Initial boiling point/range [o

C] : Not available.

Flash point [oC] : Not available.

Evaporation rate (n-Butyl Acetate : Not available.

= 1)Flammability (solid, gas) : Not available.

Upper flammability : Not available.

Lower flammability : Not available.Vapour pressure, mm Hg @ 24

oC : Not available.

Vapour density (Air = 1) : Not available .

Relative density : Not available.Solubility in water, Wt % @ 20

oC : Not available.

9. PHYSICAL AND CHEMICAL PROPERTIES


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Partition coefficient: n- : Not available.Octanol/water

Auto-ignition temperature : Not available.

Decomposition temperature : Not applicable.

Viscosity of Liquid, CST @ 25o C : Not available.Explosive properties : Not available.

Oxidizing properties : Not available.

9.2 Other information : Mixture has not been tested.

10.1 Reactivity : Contact with incompatible or reactive materials may cause

hazardous reactions.

10.2 Chemical stability : Stable under normal conditions.

10.3 Possibility of hazardous reactions : Hazardous polymerization will not occur.

10.4 Conditions to avoid : Open flames and sources of ignition.

10.5 Incompatible materials : Strong oxidizing agents.

10.6 Hazardous decomposition products : Burning can produce oxides of carbon.

11.1 Information on toxicological effects

11.1.2 Mixture : There is no toxicological information available for this product.

No adverse effects are expected, if the product is handled inaccordance with this Safety Data Sheet (SDS). Symptoms and

effects may arise if the product mishandled and over exposure

occur.

11.1.2.1 : Relevant effects: Components.

(a) Acute toxicity :Substance name: Test Species Route of Administration Dose/Result Exposure Remark

LD50 Rat Oral > 636 mg/kg - -

Toluene LDLO Human Oral 50 mg/kg - -

LC50 Mouse Inhalation vapour 6405 -7436 ppm 6 hour (s) -

TCLO Human Inhalation vapour 200 ppm - -

LD50 Rabbit Dermal 12124 mg/kg - -

LD50 Mouse Intra-peritoneum (i.p.) 66 mg/kg - -

LD50 Rat Intra venous (i.v.) 1960 mg/kg - -

Identifiers:

EC No: 203-625-9

CAS No: 108-88-3Index No: 601-021-00-3

LC50 Rat Inhalation vapour 28.1 mg/l 4 hour (s) -

10. STABILITY AND REACTIVITY

11. TOXICOLOGICAL INFORMATION


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Substance name: Test Species Route of Administration Dose/Result Exposure Remark

LD50 Rat Oral 4300 mg/kg - -

Xylene LD50 Mouse Oral 3523-8700 mg/kg - -

LC50 Rat Inhalation vapour 6350 ppm 4 hour (s) -

LC50 Rat Inhalation vapour 47635 mg/l 4 hour (s) -LD50 Rabbit Dermal > 4350 mg/kg - -

LD50 Rat Intra-peritoneal (i.p.) 2459 mg/kg - -

LD50 Rat Intra-peritoneal (i.p.) 2608 mg/kg - -

Identifiers:

EC No: 215-535-7

CAS No: 1330-20-7

Index No.: 601-022-00-9

TCLo Human Inhalation vapour 200 ppm - -


3-Butanone LD50 Rat Oral 2600-5400 mg/kg - -

LC50 Rat Inhalation vapour > 5000 ppm 6 hour (s) -Identifiers:

EC No: 201-159-0CAS No: 78-93-3

Index No: 606-002-00-3

LD50 Rabbit Dermal 6400-8000 mg/kg - -


LD50 Rat Oral 8000 mg/kg - -n-Butanol

LD50 Mouse Oral 2680 mg/kg - -

LC50 Rat Inhalation vapour 8000 ppm 4 hour (s) -

ID50 Mouse Inhalation vapour 617 ppm 3 minutes -

LD50 Rabbit Dermal 3400 mg/kg - -LD50 Rat Intra-peritoneal (i.p.) 1122 mg/kg - -

LD50 Moue Intra-petoneal (i.p.) 603 mg/kg - -

Identifiers:

EC No: 200-751-6CAS No: 71-36-3

Index No: 603-004-00-6

LD100 Rat s.c. 5000 mg/kg - -



Ethanol LD50 Mouse Oral 8300 mg/kg - -


LC50 Mouse Inhalation vapour 39 mg/l 4 hour (s) -

LDLO Rabbit Dermal 20000 mg/kg - -LD50 Rat Intra-peritoneal (i.p.) 6710 mg/kg - -

LD50 Mouse Intra-peritoneal (i.p.) 3156 mg/kg - -

Identifiers:

EC No: 200-578-6CAS No: 64-17-5Index No:603-002-00-5

LD50 Mouse Sub cutaneous 8700 mg/kg - -


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Isopropanol LD50 Mouse Oral 4475 mg/kg - -


LC50 Mouse Inhalation vapour 53 mg/l 2 hour (s) -LD50 Rat Dermal 12800 mg/kg - -

LD50 Rat Intra-peritoneum (i.p.) 2050 mg/kg - -

LD50 Rat Intra venous (i.v.) 1099 mg/kg - -

Identifiers:

EC No: 200-661-7

CAS No: 67-63-0

Index No: 603-117-00-0

LD50 Mouse Intra-peritoneal (i.p.) 3400 mg/kg - -

Conclusion/Summary : Vapours may cause drowsiness or dizziness.

(b) IrritationInhalation : May cause irritation to the nose, throat, and lungs. High

vapor concentrations may cause unconsciousness or other

signs of central nervous system depression.

Skin contact : Frequent or prolonged contact may irritate the skin and

cause skin rash (dermatitis). May cause skin sensitization,an allergic reaction which becomes evident on re-exposure

to this material.

Eye contact : Severely irritating. If not removed promptly will injure eye

tissue, which may result in permanent damage.

Ingestion : May cause irritation of the digestive tract and diarrhea.

(c) Corrosivity : Severely irritating to eyes. Repeated exposure may cause skindryness or cracking.

(d) Sensitization : May cause skin sensitization and or respiratory system irritation

due to extended exposure of the preparation above stated occu-pational exposure limits.

(e) Single dose toxicity : No data available.

(f) Repeated dose toxicity : No data available.

(g) Carcinogenicity : No known significant effects or critical hazards.

(h) Mutagenicity : No information but adverse effects unlikely.

(i) Toxicity for reproduction : No known significant effects or critical hazards.

11.1.2.2 CMR effects : No known significant effects or critical hazards.(carcinogenic, mutagenic or

toxic for reproduction)


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11.2 Potential adverse health effects : Small amounts of this liquid may be drawn into the lungs byeither swallowing or vomiting. This may cause severe and

delayed health effects such as inflammation of the lungs (

pulmonary edema) and infection of the bronchi(broncho-

pneumonia). Ingestion may cause irritation to the digestivetract or diarrhea.

11.3 Potential chronic health effects : There is no evidence that exposure to 3-Butanone alonecauses progressive or irreversible neurotoxic effects.

However, simultaneous over-exposure to 3-Butanone and

n-Hexane can potentiate the known irreversible neurotoxiceffects of n-Hexane. There is no reported human evidence

that these neurotoxic effects occur when exposure to both

chemicals is maintained below established regulatory limits.

11.4 Other information : The mixture is not likely to be carcinogen in humans.

There is no ecological information available for this product. Ecotoxicological information on components of

this product is presented below.

12.1 Toxicity :

3-Butanone [CAS#: 78-93-3]

Aquatic toxicity Effect dose Exposure time (h) Species Value (mg/l)

Acute fish toxicity LC50 96 hour (s) Pimephales promelas 3220Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna > 520

Acute algae toxicity EC3 7 days Scenedesmus quadricauda 4300

n-Butanol [CAS#: 71-36-3]


Acute fish toxicity LC50 96 hour (s) Pimephales promelas < 1630

Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 1983

Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 500

Ethanol [CAS#: 64-17-5]


Acute fish toxicity LC50 96 hour (s) Alburnus alburnus 10000 - 11500

Acute Daphnia toxicity LC50 48 hour (s) Daphnia magna 9268 - 14221

Acute algae toxicity EC50 Not specified Chlorella pyrenoidosa 9310

Isopropanol [CAS#: 67-63-0]


Acute fish toxicity LC50 96 hour (s) Pimephales promelas 9640

Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 13299

Acute algae toxicity EC50 96 hour (s) Scenedesmus subspicatus > 1000

12. ECOLOGICAL INFORMATION


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Toluene [CAS#: 108-88-3]


Acute fish toxicity LC50 96 hour (s) Pimephales promelas 28

Acute Daphnia toxicity EC50 48 hour (s) Daphnia magna 11.5

Acute algae toxicity EC50 48 hour (s) Scenedesmus subspicatus 125 - 160

Xylene [CAS #: 1330-20-7]


Acute fish toxicity LC50 96 hour (s) Cyprinus carpio > 780

Acute invertebrate toxicity LC50 48 hour (s) Palaemonetes pugio 0.85

Acute algae toxicity Mortality Unknown Scenedesmus quadricauda > 200

12.2 Persistence and degradability : No data available for this product.

(Biochemical Oxygen Demand BOD values)

Substance name Quantity Degradation rate (%) Incubation time Evaluation (inoculum)

3-Butanone Unknown 83 5 days Sewage

n-Butanol Unknown 66 5 days Sewage sludge

Ethanol 10 mg/l 74 5 days Filtered sewage seed

Isopropanol 10 mg/l 78*

20 days Filtered sewage seed

Toluene Unknown Completely Short duration Sewage seed

Xylene Isomers 72 20 days Activated sewage

* Theoretical Oxygen Demand (ThOD) value.

12.3 Bioaccumulative potential : No data available for this product.(BCF Bio Concentration Factor). log n-octanol/water partition coefficient (log Kow) estimate

Substance name Estimated BCF log Kow Remarks

3-Butanone 3 0.29 Low bioaccumulation

n-Butanol 3 0.88 Low bioaccumulation

Ethanol 3 -0.31 Low bioaccumulation

Isopropanol 3 0.05 Low bioaccumulation

Toluene 13 (eel) , 90 (Golden ide) 2.73 Low to moderate bioaccumulation

Xylene 6 23.4 3.2 Low bioaccumulation

12.4 Mobility in soil : No data available for this product.

Koc The soil absorption coefficient

Substance name Koc value Remarks (soil mobility)

3-Butanone 29 Very high mobility

n-Butanol 72 High mobility

Ethanol 1 Very high mobility

Isopropanol 25 Very high mobility

Toluene variable High to moderate mobility

Xylene 39 365 for individual isomers Very high to moderate mobility


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12.5 Results of PBT andvPvB assessmentPBT :No data available.

vPvB : No data available.

12.6 Other adverse effects : No known significant effects or critical hazards.

13.1 Waste treatment methodsProduct

Methods of disposal : The generation of waste should be avoided or minimizedwhenever possible. Empty containers or liners may retain

some product residues. This material and its container must

be disposed of in a safe way. Waste product residue should notbe disposed of via the foul sewer. Consult an expert on the dis-

posal of recovered and surplus material. Incinerate, or recoverby distillation. Ensure disposal is in compliance with current

government requirements and ensure conformity with localauthority regulations.

Packaging waste

Methods of disposal : The generation of waste should be avoided or minimizedwhenever possible. Waste packaging should be recycled, or

dispose of according to state and local authority regulations.

Consult your State/Local Land Waste Management Authority.

Waste codes/ waste designation : H3 : flammable liquid (organic solvents) [Australia]

15 01 01 : paper and cardboard packaging [EU].15 01 02 : plastic packaging [EU]

: The listed waste numbers according to the European Waste Code

(EWC) are intended as recommendation for users. The finalclassification has to be worked out together with the local waste

disposal company/authority.

Note: The generator of waste should consult their Environmental

Protection Authority for classification assistance and coding.

Special precautions : This material and its container must be disposed of according tolocal authority regulations. Empty containers or packaging may

contain some product residue. Avoid dispersal of spilt material

and runoff to come in contact with soil, waterways, drains andsewers.

Transportation information is provided on the next page.

13. DISPOSAL CONSIDERATIONS

14. TRANSPORTATION INFORMATION


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ADG/ADR/RID ADN/ADNR IMDG ICAO-TI/IATA-DGR

14.1 UN No. 1210 1210 1210 1210

14.2 Proper ShippingName

Printing InkRelated Material



Printing Ink RelatedMaterial

14.3 Transport hazard

class 3 3 3 3

14.4 Classification

code F1 F1 F1 F1

14.5 Packing group II II II II

14.6 Hazard label

14.7 Environmental

hazard No No

Marine

pollutant: No No

14.8 Specialprovision(s)

163640C

163640C

163 Not available

Additional

Information

Hazard

identificationnumber

33

HC: 3[Y]E

TransportCategory

2

Ltd. QtyLQ6

Excpt. QtyE2

PackagingP001, PP1, MP19

Portable Tanksand Bulk Cont.T4; TP1, TP8

Tunnel codeD/E

-

-

Ltd. QtyLQ6

Excpt. Qty.E2

-

-

-

-

Emergency

schedules(EmS)

FireF-E

SpillageS-D

Ltd. Qty5l

Excpt. QtyE2

-

-

-

Passenger and Cargo

AircraftQuantity limitation:

1.0L

Packing instructions:

Y341

353 5.0L

Cargo Aircraft onlyQuantity limitation:

60.0 L

Packaging instruction:

364

-

-

14.9 Transport in bulk according to Annex II of MARPOL 73/78 and IBC Code: Not applicable.


19/21


Product No: FCSB No. 3 Prepared Date: 07/02/2012Version: 1.00 Printing Date: 07/03/2012

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixturePoison Schedule : S5

This product is a Schedule S5 Poison and must be stored, handled and used according to the appropriateregulation.

Inventory Status :

Australia (AICS) : Y

United States (TSCA) : Y

Europe (EINECS/ELINCS) : Y

Y = all ingredients are on the inventory or exempt.

International regulations

Chemical Weapons Convention ListSchedule I Chemicals

Chemical Weapons Convention ListSchedule II Chemicals

Chemical Weapons Convention ListSchedule III Chemicals

Not listed Not listed Not listed

15.2 Chemical Safety Assessment: No Chemical Safety Assessment has been carried out for this

product.

NOTE : This Safety Data Sheet was created as a training document for

Australian freelance safety data sheet writers. The mixture isunreal.

Product : The product has been classified and marked in accordance with

ASCC/NOHSS/EU criteria.

16.1 Indication of changesDate of previous issue : No previous validation.Revisions : To complies with NOHSC criteria.

Nature of version : Conforms to ASCC Guidelines.

Version : 1.00Date of issue : July 03, 2012

Prepared by : Theodore M. Amet, Regulatory Research Analyst.

15. REGULATORY INFORMATION

16. OTHER INFORMATION


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16.2 Abbreviations and acronymsADG: Autralian Dangerous Goods [Int];

ADN: Accord europen relative au transport international des marchandises dangereuses par voie de

navigation intrieure [Int];

ADNR: Accord europen relative au transport international des marchandises dangereuses par marinesur le Rhin [Int];

ADR: Accord europen sur le transport des merchandises dangereuses par route (European Agreement

concerning the International Carriage of Dangerous Goods by Road) [Int];AICS: Australian Inventory of Chemical Substances [Aust];

ASCC: Australian Safety and Compensation Council [Aust];

AS/NZS 1715: Selection, use and maintenance of respiratory devices [Aust/NZ];AS/NZS 1716: Respiratory protective devices [Aust/NZ];

AS 1940: The storage and handling of flammable and combustible liquids [Aust];

Aust/NZ: Australia/New ZealandCAS: Chemical Abstracts Service [Int];

CLP: Regulation on the Classification, Labelling, and Packaging of substances and mixtures [Int]

[CLP Document - REGULATION (EC) No 1272/2008 OF THE EUROPEAN PARLIAMENT AND

OF THE COUNCIL of 16 December, 2008 on classification, labeling, and packaging of substancesand mixtures, amending and repealing Directives 67/548/EEC and 1999/45/EC and amending

Regulation (EC) No 1907/2006];

DGR: Dangerous Goods Regulation [Int];EC: European Commission [Int];

EINECS: European Inventory of Existing Commercial chemicals Substances [Int];

ELINCS: European List of Notified Chemical Substances [Int];EmS: Emergency Schedule [Int];

ESIS: Existing chemical Substances Information System [Int];

EU: European Union [Int];GHS: Globally Harmonized System of Classification and Labelling of Chemicals [Int];Hazchem Code: Fire fighters designation [Aust];

IATA: International Air Transport Association [Int];

IBC Code: International Code for the Construction and equipment of Ships Carrying DangerousChemicals in Bulk [Int];

ICAO: International Civil Aviation Organization [Int];

IMDG: International Maritime Dangerous Goods [Int];TSCA: Toxic Substances Control Act

TI: Technical Instructions for the Safe Transport of Dangerous Goods by Air {Int];

USA: United States of America

16.3 Full text of Risk and Hazard Phrases/Codes in Section 2

Risk (R)-phrase(s)R11 : Highly flammable.

R20/21 : Harmful by inhalation and in contact with skin.

R22 : Harmful if swallowed.R36 : Irritating to eyes.

R37/38 : Irritating to respiratory system and skin.

R38 : Irritating to skin.R41 : Risk of serious damage to eyes.


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R48/20 : Harmful: danger of serious damage to health by prolonged exposurethrough inhalation.

R63 : Possible risk of harm to the unborn child.

R65 : Harmful: may cause lung damage if swallowed.

R66 : Repeated exposure may cause skin dryness or cracking.R67 : Vapours may cause drowsiness and dizziness.

Safety (S)-phrase(s)S2 : Keep out of the reach of children.

S7/9 : Keep container tightly closed and in a well ventilated place.

S13 : Keep away from food, drink and animal feedingstuff.S16 : Keep away from sources of ignition No smoking.

S24/25 : Avoid contact with skin and eyes.

S26 : In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice.

S36/37 : Wear suitable protective clothing and gloves.S37/39 : Wear suitable gloves and eye/face protection.

S46 : If swallowed, seek medical advice immediately and show this containeror label.

S62 : If swallowed, do not induce vomiting: seek medical advice immediately

and show this container or label.

16.3 Key literature references :

and sources of data

ECHA (European Chemicals Agency)

http://echa.europa.eu/ESIS (Existing chemical Substances Information System)http://ecb.jrc.ec.europa.eu/esis/.GESTIS International Limit values Database

http://www.dguv.de/ifa/en/gestis/limit_values/index.jspGuidance on the compilation of safe data sheets

http://guidance.echa.europa.eu/docs/draft_documents/draft_guidance_on_safety_data_sheets_20100324.pdf

TOXNET: Toxicology Data Network.http://toxnet.nlm.nih.gov

Information from technical literature

Internet research.

DISCLAIMER

This guide was compiled as a service to expat freelance Australian Safety Data Sheets writers. Information in

this document is based on data gathered from various Internet sites. No warranty is expressed regarding theaccuracy of data obtained from various chemical, health, toxicological, and environmental databases.

Responsibility for the accuracy and completeness of information contained herein rests with users who must

satisfy themselves that the data is appropriate for their needs. The author specifically disclaims any or all formsof liability and/or responsibility for the use of this guide. It is always a good practice to consult a sectional

expert when writing sections of the safety data sheets to clarify and simplify technical matters.

O SA SA A A S

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