ak jeruk kesturi kering

Lampiran 25. Kromatogram GC Minyak Atsiri Kulit Buah Jeruk Kasturi Kering

UNIVERSITAS SUMATERA UTARA FAKULTAS FARMASI

LABORATORIUM PENELITIAN JL. Almamater No. 5 Kampus USU

Medan 20155

Analyzed by : Admin Sample Type : Unknown Level # : 1Sample Name : Minyak kesturi keringSample ID : $F4$ Vial # : 2

Sample Information

Method File : C:\GCMSsolution\Data\Project1\analisa jeruk kasturi.qgmOrg Method File : C:\GCMSsolution\Data\Project1\analisa jeruk kasturi.qgm$EndIf$Modified by : Admin

Peak# R.Time Area Area%Peak Repor

Heightt TIC Name1 1.597 9798974 10.93 3569301 Hexane

2 5.183 210826 0.24 76880 Styrene3 6.596 1838577 2.05 510339 .alpha.-Pinene4 8.056 304356 0.34 89319 .beta.-Phellandrene5 8.172 1009252 1.13 249509 .beta.-Pinene6 8.751 5837317 6.51 999217 .beta.-Myrcene7 10.671 68171524 76.02 2604738 D-Limonene8 13.080 300342 0.33 103936 1,6-Octadien-3-ol, 3,7-dimethyl-9 13.262 60440 0.07 24097 Decanal

10 16.122 21470 0.02 8219 Pentane, 3-bromo-11 16.639 51140 0.06 19759 3-Cyclohexene-1-methanol,

.alpha.,.alpha.4-t12 17.021 14116 0.02 5542 1-Hexene, 3,4-dimethyl-13 17.204 120215 0.13 43018 Dodecanal14 17.448 45033 0.05 18126 Acetic acid, octyl ester $$ n-Octyl acetate

$$15 18.661 23293 0.03 8586 2-Cyclohexen-1-one, 2-methyl-5-(1-methylet

16 22.041 58324 0.07 18005 Cyclohexene, 3-methyl-6-(1-methylethyliden17 22.949 31126 0.03 10505 1-Penten-3-one, 2,4-dimethyl- $$ 2,4-Dimeth18 23.608 397824 0.44 109219 2,6-Octadien-1-ol, 3,7-dimethyl-, acetate, (E)19 26.925 1350886 1.51 323162 1,6-Cyclodecadiene, 1-methyl-5-methylene-820 27.432 30519 0.03 11189 1,5-Heptadiene, 2,5-dimethyl-3-methylene- $89675554 100.00 8802666

Lampiran 26. Spektrum massa dengan waktu retensi 6,600 menit

Lampiran 27. Spektrum massa dengan waktu retensi (Rt) 8,142 menit



Lampiran 32. Pola fragmentasi senyawa α-pinen dengan waktu tambat (Rt) 6,565dan 6,600

menit

C10H16 m/z 136 C9H13]+ m/z 121 C8H11]+ m/z 105

C6H7]+ m/z 77 C3H5]+m/z 39

Lampiran 33. Pola fragmentasi senyawa β-pinen dengan waktu tambat (Rt) 8,142 menit

C10H16 m/z 136 C9H13]+ m/z 121 C8H11]+ m/z 107

C7H9]+ m/z 93 C6H7]+m/z 79 C4H5]+m/z 53

C2H3]+ m/z 27

Lampiran 34. Pola fragmentasi senyawa β-mirsen dengan waktu tambat (Rt) 8,721 dan 8,750 menit

C10H16 m/z 136 C9H13]+ m/z 121 C8H11]+ m/z 107

•-CH3

15

-CH4

28

-C2H4

16

-C3H2

38

15 14 14

-CH2

14

-C2H2

26

-C2H2

26

•-CH3 -CH2 -CH2

•-CH3

15 14

-CH2

14

-CH2

-CH2-C2H2 -C2H2

C7H9]+ m/z 93 C6H7]+m/z 79 C4H5]+m/z 53

C2H3]+ m/z 27

Lampiran 35. Pola fragmentasi senyawa Limonen dengan waktu tambat (Rt) 10,681 menit

C10H16 m/z 136 C9H13]+ m/z 121 C8H11]+ m/z 107

C7H9]+ m/z 93 C6H7]+ m/z 79 C4H5]+ m/z 53

C2H3]+ m/z 27

Lampiran 36. Pola fragmentasi senyawa D_Limonen dengan waktu tambat (Rt) 10,675 menit

14 26 26

•-CH3

15

-CH2

14

-CH2

14

-CH2

14

-C2H2

26

-C2H2

26

•-CH3-CH2 -CH2

C10H16 m/z 136 C9H13]+ m/z 121 C8H11]+ m/z 107

C7H9]+ m/z 93 C6H7]+ m/z 79 C4H5]+ m/z 53

C3H2]+ m/z 38

Lampiran 37. Pola fragmentasi senyawa 2,6-oktadien-1-ol dengan waktu tambat (Rt) 23,598 dan 23,608 menit

C12H20O2 m/z 196 C10H18O]+ m/z 154 C10H16]+ m/z 136

C9H13]+ m/z 121 C8H11]+ m/z 107 C7H9]+ m/z 93

C6H8]+ m/z 80

Lampiran 38. Pola fragmentasi senyawa 1,6-siklodekadien dengan waktu tambat (Rt) 26,920 dan 26,925 menit

15 14 14

-CH2

14

-C2H2

26

-CH3

15

-C2H2O

42

-H2O

18

•-CH3

15-CH2

14

-CH2

14

-CH

13

-C3H8 -CH2 -CH2

C15H24 m/z 204 C12H16]+ m/z 161 C11H14]+ m/z 147

C10H12]+ m/z 133 C9H10]+ m/z 119 C8H8]+ m/z 105

C7H6]+ m/z 91 C3H4]+ m/z 41 C2H2]+ m/z 27

43 14 14

-CH2

14

-CH2

14

-CH2

14

-C4H2

50-CH2

14

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