bhuonline.inbhuonline.in/pdfs/uet_2016/b.sc (ag).pdf · the intermediate involved in sni reaction...

58

Upload: duongnga

Post on 23-Feb-2018

221 views

Category:

Documents

0 download

Report

Download

Embed Size (px):

TRANSCRIPT

Page 1: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 2: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 3: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 4: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 5: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 6: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 7: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 8: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 9: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 10: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 11: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 12: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 13: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 14: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 15: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 16: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 17: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 18: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 19: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 20: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 21: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 22: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 23: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 24: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 25: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 26: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 27: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 28: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 29: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 30: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 31: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 32: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 33: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 34: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 35: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 36: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 37: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 38: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 39: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 40: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 41: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 42: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 43: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 44: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 45: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 46: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 47: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 48: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 49: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 50: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 51: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 52: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 53: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 54: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 55: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 56: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 57: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Page 58: bhuonline.inbhuonline.in/pdfs/UET_2016/B.Sc (Ag).pdf · The intermediate involved in SNI reaction is (4) carbocation ( 1) carbanion (2) radical t (3) carbene (3) Perkin reaction (4)

Rate laws, Reaction Orders Reaction Order

Protease-catalysed Direct Asymmetric Mannich Reaction in ... · 1. Reaction profiles of the SGP-catalysed Mannich reaction and the blank reaction 2. Optimisation of reaction conditions

K.M.Agrawal College of Arts, Commerce and Science · 2020. 9. 22. · b)Acylation of carbanion c)Aldol condensation d)Mannich reaction Unit 2 1. cyclohexanone react with diazomethane

Photoelectron-Photofragment Coincidence Spectroscopy of tert- Butoxide and the Carbanion Isomer Ben Shen Continetti Group University of California, San

Reaction time website to test reaction time Flash/reaction%20time.htm

Reaction rates for mesoscopic reaction-diffusion … rates for mesoscopic reaction-diffusion kinetics ... function reaction dynamics (GFRD) algorithm [10–12]. ... REACTION RATES

Carbanion generation through tin-lithium exchange of vinyl

L.L.B - Banaras Hindu University : Entrance Exambhuonline.in/pdfs/UET_2016/L.L.B.pdf · · 2016-09-02Deposit only the OMR Answer Sheet at the end of the Test. ... Zinc (3) 10 Dolomite

“FORBIDDEN 1,2 CARBANION SHIFTS” MECHANISM AND APPLICATION … · 2010-11-30 · “FORBIDDEN 1,2-CARBANION SHIFTS” MECHANISM AND APPLICATION OF THE FRITSCH-BUTTENBERG-WIECHELL

Complex reaction environments and competing reaction

Topics about reaction kinetics Rate of reaction Order of reaction Half-life Reaction progress Activation energy Reaction mechanism

Recent Advances in Heteroatom-Stabilized Carbanion Chemistrymacsphere.mcmaster.ca/bitstream/11375/17280/1/Das_Priyabrata_2009... · The field of heteroatom stabilized carbanion chemistry

· Hofmann-Curtius-Lossen rearrangement, Wolff rearrangement, Simmons-Smith reaction, Reimer-Tiemann reaction, Michael reaction, Darzens reaction, Wittig reaction and McMurry reaction;

Ed Language - Banaras Hindu University : Entrance Exambhuonline.in/pdfs/UET_2016/B.Ed Language.pdfDuring the first parent teacher conference of the year, the teacher should do all

Exploring Students Students Students Students’ Perception Perception Perception Perception of and Reaction Reaction Reaction Reaction To

Carbanion - Enolato

CARBANIONS - SIUEtpatric/cban.pdf · Carbanion Structure Carbanions are trivalent with ... below with amide ion give a carbanion with a slow rate ... The aldol products react readily

Rate of reaction Rate of reaction

Key Terms: Combustion reaction Decomposition reaction Double Replacement reaction Hydrocarbon Single replacement Reaction Synthesis Types of Reactions

elimination reaction, addition reaction, oxydation reactions

BPA VOCAL - Banaras Hindu Universitybhuonline.in/pdfs/UET_2016/BPA VOCAL.pdf · BhichRagafrom the following has Vú.a Chalan ? (l) Bahar (2) Malkauns (3) Bhimpalasi (4 ... The Bandishes

Reaction Energy and Reaction Kinetics

Allyl and Pentadienyl Carbanion Complexes of Alkali Metals

CARBANION IN WATER

Reaction Energy and Reaction Kinetics Reaction Rate

2-Lithio-3,3-dimethyl-2-oxazolinyloxirane: Carbanion …3-dimethyl-2-oxazolinyloxirane: Carbanion or Azaenolate? Structure, Conﬁgurational Stability, and Stereodynamics in Solution

Photosynthesis (Light reaction) · 2020. 7. 22. · Photosynthesis (Light reaction) Light reaction/Photochemical reaction/Hill reaction During the light reaction, the primary function

CARBANION - Universitas Pendidikan Indonesia · CARBANION. Kinds of Carbanion 1. Simple ionic 2. Resonance-stabilised carbanions 3. Resonance-stabilised carbanions containing heteroatoms

Classifying Reaction. Objectives Identify, define, and explain: combination reaction, synthesis reaction, decomposition reaction, single replacement reaction,

I. Rates of Reaction Ch. 16 – Reaction Energy and Reaction Kinetics

Co cau goc tu do, carbanion, carben, carbocation

3. Criticisms, Reaction and Counter-Reaction

I CARBANION- AND FREE RADICAL-TYPE REARRANGEMENTS

Isotope Effects the Crotonase Reaction? - University of · PDF file · 2004-06-21is believed to stabilize an enolate form of the carbanion at the ... The crotonase-catalyzed elimination

CHE 275 - State University of New York College of ...people.morrisville.edu/~habera/PDFFiles/Orgo/OrgoI/CHEM_275_Intro.pdf•carbocation •carbon radical •carbanion •carbene •excited