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  • 8/12/2019 Aerated Anoxic Principles

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    Page 1 Water Technologies

    Aerated Anoxic Principles

    Arkansas Water Environment Associations2012 Waters Worth It Specialty Conference

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    Page 2 Water Technologies

    Getting Started

    Define: Aerated Anoxic

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    Page 3 Water Technologies

    The terms can be very confusing and aconsiderable number of definitions arrived at

    Aerated-anoxic Anoxic-aeration Anaerobic-aeration Anammox bacteria

    what in the world am I talkingabout!

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    Page 4 Water Technologies

    Aerated-Anoxic is not limited to Siemensaeration systems but can be included inany activated sludge aeration processes,such as:

    Multichannel Oxidation Ditch

    Aeration tanks in series

    Multi-pass plug flow systems

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    Page 5 Water Technologies

    Aerobic

    Reactor

    Secondary

    Clarifier

    Internal Recycle

    RAS

    Influent

    WAS

    Effluent

    Conventional plantdesigns use dedicatedanoxic and aerobic biological reactors

    Anoxic

    Reactor

    No air added to the anoxic reactor

    Nitrification achieved in the aerobic reactor

    Nitrates brought back through internal recycle at 4Q

    4Q

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    Page 6 Water Technologies

    Aerated anoxicprocesses operate at constantoxygen deficit in the first part of the process

    Aerobic Reactor Secondary

    Clarifier

    Internal Recycle

    RAS

    Influent

    WAS

    EffluentAerated

    Anoxic

    Reactor

    Aerated

    Anoxic

    Reactor

    O2suppl ied to aerated anoxic reactors is less than O2demand

    No internal recycle required for total nitrogen removal

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    A conventional oxidation ditch with aerobic and anoxic

    zones is not the same as aerated anoxic reactors in series

    Conventional Oxidation Ditch

    O2supply must exceed demand for complete treatment

    It is diffi cult to control aerobic and anoxic zones in a single reactor

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    Complete Mix

    Plug Flow

    Aeration Tanks

    Complete Mix vs. Plug Flow

    Influent

    Influent

    Effluent

    Effluent

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    Aeration Tanks

    Typical Oxidation Ditch

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    Aeration Tanks

    Converting Plug flow to Complete Mix

    Option 1: Add some pipes

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    Orris Albertson

    Control of Sludge Bulking

    Discussed the history of activatedsludge innovations used over 70years ago

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    Early Innovators

    Wellington Donaldson 70 years ago

    decided to compartmentalize plug flow

    tanks

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    Orris Albertson

    Control of Sludge Bulking

    Phoenix 91st Avenue WWTP:Aerated-anoxic system

    Established that anoxic tank could be mixed with

    course bubble air instead of conventional mixers

    Anoxic tank equaled 25% of total volume

    Air did not hurt denitrification.

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    Aerated Anoxic

    Nitrification

    Nitrification Requirements:

    Adequate oxygen

    Alkalinity

    Adequate sludge age

    Adequate ammonia

    Advantages of Nitrification inAerated Anoxic Reactor:

    Air did not hurt denitrification.

    Immediate source of nitrates fordenitrification

    Simultaneous nitrification-denitrification takes place

    A short-cut nitrification/

    denitrification pathway isavailable

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    Ive got a problem with what

    youre saying

    thats not the way I learned it!

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    Where does the nitrification occur?

    Q: Does all the nitrificationoccur in the high DO zone?Y or N

    A: Not in aerated anoxic systems the low DO reactors arethe BEST environment for thenitrifiers

    0 0.5

    2

    Orbal DO profile in mg/l

    The nitrification occurs wherethe majority of O2is delivered.

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    Page 19 Water Technologies

    Carey, OH WWTP Case Study

    Overview

    Challenge: Five rectangular tanksoperating in parallel with nitrificationproblems. Ammonia level was notmeeting requirements

    Solution: Switch operation from parallelto series.

    Results:

    Before (Two in parallel): eff. Ammonia

    1.7 mg/l After (Three in Series): eff. Ammonia

    0.03 mg/l

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    Page 20 Water Technologies

    Reactors in series improve nitr ification

    Carey, OH WWTP case study

    Challenge: 5 tanks in parallelwith nitrification problems

    Ammonia not meeting limits

    Solution: Switch parallel to series

    Parallel Series

    Results:

    Before (parallel):eff. NH3 1.7 mg/l

    After (series):

    eff. NH3 0.03 mg/l

    Explanation:

    Switch to series eliminatedshort circuiting

    Reactors in series created

    aerated anoxic conditions thatpromote simultaneous N-D

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    Page 21 Water Technologies

    Lower Oxygen Delivery Can Lead toSuperior Nitrification

    Increasing Oxygen Delivery inAnoxic Tanks to ImproveDenitrification

    Unusual Titles for Papers

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    INCREASING oxygen delivery in anoxic tanks to

    IMPROVE Denitrif ication

    Sounds backwards, huh?

    Wouldnt denitrification be better with no oxygen

    delivery in anoxic tanks?

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    Page 23 Water Technologies

    Case Study: Hammonton, NJ WWTP

    Increasing O2delivery in aerated anoxic tanks improves denitr ification

    175

    150

    125

    100

    75

    50

    25

    0

    Outer Middle Inner

    O2Demand,

    lbs/hr

    Channel

    By increasing O2delivery in outer channel NO3-N dropped from 2.8 mg/l to 1.6 mg/l!

    O2Supply Before

    O2Supply After

    O2Demand

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    Page 24 Water Technologies

    Hammonton, NJ WWTP

    Nitrogen Balance

    Q: With 0.3 mg/l nitrate, how muchdenitrification is due to recycle?

    Influent N to be nitrified @ 200 lbs/day

    N denitrified @ 197 lbs/day

    N in recycle @ 13 lbs/day

    N denitrified due to simultaneous N-D@ 184 lbs/day

    A: More than 93% is denitrified due to

    simultaneous N-D!

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    Page 25 Water Technologies

    Compared nitrifiers from:

    1. Orbal plants with aerated anoxicreactors

    2. Nitrification plants with conventional

    upfront non-aerated anoxic tanks

    University of Wisconsin F.I.S.H. Study

    Found different types of nitrifiersfor two different types of plant:

    NITROSOMONAS typical ammonia oxidizer for most nitrification

    plants, including those with non-aerated anoxic reactors NITROSPIREA dominant ammonia oxidizer for plants with aerated-

    anoxic reactors

    NITROBACTER dominant nitrite oxidizer

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    Page 26 Water Technologies

    University of Wisconsin F.I.S.H. Study

    NITROSPIREA:

    The dominant ammoniaoxidizer in systems wherethere is simultaneousnitrifcation-denitrification

    A nitrifier that is very good

    at going dormant There are a lot of

    dormant nitrifiers in ourBNR designs

    Staging with aerated anoxic reactors infront is a good way to increase (evendouble) the nitrifier population.

    Nitrifier population does not exclusively

    depend upon the amount of ammoniaentering the plant.

    Under typical conditions:

    10,000 units

    50% active 50% inactive

    With increased dormant population:

    25,000 units

    20% active 80% inactive

    Dormant Nitr ifiers

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    Page 27 Water Technologies

    Nine Springs WWTP: Madison, WI

    Conventional FB plant with upfront anaerobic tank

    Operates at a 10 day SRT side by side test with one side beingaerated anoxic

    Loading MLSS eTN eP CFM/lb of BODConventional: 14 2800 15 0.4 1100Aerated Anoxic: 26 4100 11 0.2 673

    Anaerobic Aerobic (fine bubble)

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    Page 28 Water Technologies

    Denitrification

    Shortcut Pathway

    5-step pathway:

    Ammonia nitrite nitrate

    nitrite nitrogen gas

    3-step Shortcut pathway (in

    aerated anoxic tanks):

    Ammonia nitrite nitrogen gas

    Requires 33% lesscarbon

    Explains lack of nitrite oxidizers inOrris Albertsons Phoenix study

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    Page 29 Water Technologies

    Aerated Anaerobic

    It sounds too odd

    But works in designs with LARGEaerated anoxic tanks and limited

    oxygen

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    Page 30 Water Technologies

    McMinnvil le, Oregon WWTP

    Two 3-channel Orbal Basins

    1stchannel operates asaerated anaerobic channel

    2ndchannel operates as

    aerated anoxic channel 1.52 m.gal. Aeration Volume per

    basin

    Four 50 hp Drives

    0.07 mg/l eff. P required Designed for 8 day sludge age

    0.5 mg/l eff. ammonia required

    Only 18% of total basin volume isaerobic

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    Page 31 Water Technologies

    McMinnvil le, Oregon WWTP

    P-removal Performance

    Typical Municipal Plant

    Operates first channel with discsat 29 rpm less than 10% of thetotal oxygen (aerated anaerobic)

    Second channel operates with70% of the air and a zero DO(aerated anoxic)

    Effluent ammonia at 0.2 mg/l (with 8 day sludge age)

    Sol. P from Orbal/FC is 0.03 mg/l

    Total P from Orbal/FC is 0.1 mg/l

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    Page 32 Water Technologies

    System A SAE @ 3 lbs/hp-hr

    DO levels 0 - 2 - 4

    alpha @ 0.9

    power draw @ 544 hp

    System B

    SAE @ 3 lbs/hp-hr

    DO levels 0 - 2 - 4

    alpha @ 0.9

    power draw @ 444 hp

    Comparison of Two Identical Aeration Systems

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    Page 33 Water Technologies

    Case Study @ Lit tle Lower Miami, OH

    Adding more O2at Zero DO saves power DO

    Operating Condi tions: DO levels and alpha/FCF same

    Aerobic Zone 12mg/l DO0.7 FCF

    Aerated Anoxic Zone0 mg/l DO0.9 FCF

    Aerobic Zone 24mg/l DO0.5 FCF

    Add more O2where absorption rateis greatest

    Add less O2 where absorption rateis less

    Add less O2where absorption rateis less

    Actual Optimized

    800

    700

    600

    500

    400

    300

    200

    100

    0

    Aerated Anoxic Opt imizat ion Recommendations

    OxygenDelive

    red,

    lbs/d

    Actual Optimized Actual Optimized

    O2absorbedfrom aerators(AOR)

    UnabsorbedO2fromaerators(FCF)

    Total O2Supplied (lb/hr)

    Actual Optimized DifferenceFor AOR 1050 1000

    For FCF 583 322

    Total 1633 1322 22.5% less

    Power Use 544 HP 444 HP 22.5% less

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    Page 34 Water Technologies

    Anammox Bacteria

    Nitrogen Removal Efficiency at Centralized Domestic

    Wastewater Treatment Plant in Bangkok, Thailand

    VLR @ Nongkhaem: BOD NI 32.8 11.8E 3.8 6.7

    Of the several plants (8) in the study, Anammox type

    bacteria was only present at the Nongkhaem plant

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    Page 35 Water Technologies

    Anammox Bacteria

    2.5 mgd Orbal plant with primaries

    Ratio of BOD:N@ 3.5:1 (105 mg/l BOD 30 mg/l TKN)

    Effluent ammonia @ 0.1 mg/l Effluent nitrate @ 2 mg/l

    AnammoxPathway:

    50% of the ammonia oxidized to NO2-N

    50% of the ammonia uses NO2-N for oxygen supplier

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    Page 36 Water Technologies

    Where do we go from here?

    Blending erobic With naerobic

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    Page 37 Water Technologies

    50,000 gpd Pilot Study in Singapore

    Roof Installation Roof with Canvas

    Gas Holder Installation Digester with Gas Holder

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    Page 38 Water Technologies

    With DAFT and Anaerobic Digestion

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    Page 39 Water Technologies

    BOD Extraction and Digester Recycle

    Plant main gate

    ConstructionTemporaryAccess

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    Page 40 Water Technologies

    Prime Float Normal Loading Conditions

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    Page 41 Water Technologies

    Prime Float High Solids Loading Conditions

    (Simulate Captivator)

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    Page 42 Water Technologies

    Test Plans and Summary for High Solids Loading Condit ions

    High Solids LoadingConditions

    Biosolids TSS Loading/Influent BOD Loading

    DAF performance,Removal Efficiencies, %

    Targeted Actual TSS BOD CODBase Case 2.7 3.5 98 93 96

    Base Case +10 ppm FeCl3 2.7 3.1 99 95 96Base Case + 5 ppm FeCl3 2.7 3.1 97 97 96

    DAF

    System

    DAF Influent

    Biosolids Flow, TSS Source

    Q Inf = 30 gpm,

    BOD = 400 mg/L

    TSS = 375 mg/L

    Q R = 6 gpm, TSS = 6000 mg/L

    DAF Float Sludge, 3.5%

    DAF Effluent, to Aeration Tanks

    BOD = 50 mg/L, TSS = 35 mg/L

    FeCl3,

    0 - 10 ppm

    Primary

    Clarifier

    Contact

    Tank

    Influent Flow

    QDAF = 18 gpm,

    Directly To Aeration Tanks

    Q= 18 gpm

    BOD = 320 mg/L

    TSS = 210 mg/L

    Half of raw influent was treated by combined primary clarifier and contact tank (CT) + DAF:

    DAF effluent BOD = 50 mg/L with total removal of 88%: 20% removed by clari fier and 68% removed by CT + DAF

    DAF effluent TSS = 35 mg/L with to tal removal of 91%: 44% removed by clari fier and 47% removed by CT + DAF

    Estimated reduction in aeration requ ired = 0.5*Q*(320-50)/(Q*320) = 42% based on BOD balance

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    Page 43 Water Technologies

    Sand Island WWTP, Hawaii

    Currently no secondary treatment

    Upgrade cost estimate: $1.2 Billion

    Power Cost: $0.21/kW

    Limited land area for upgrade

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    Page 44 Water Technologies

    Aeration Energy Reduction/Biogas Production

    Conventional Mode BE/DR

    2700 kW Energy used 1300 kW1800 kW Energy recovered 4800 kW

    Total revenue gain of $8M/year

    Total surplus of $6M/year

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    Remembering Wellington Donaldson

    He had great ideas.

    But for the most part they were:

    ignored

    neglectedforgottennot used

    Maybe now we are finally back on the right

    course