additional attachment- neel...

Enclosure: 1

Name of Product and Its Quantity

Sr. No. Product Name Quantity (MT/Month)

1. C.P.C. Blue 300

2. C.P.C. Alpha Blue 25

3. C.P.C. Green/ Pigment Green 7 50

Total 375

Enclosure: 2

Packing & Final Use of Products

Name of Product CAS No. Type of Packing Final Application of Product

CPC Blue (Copper Phthalo cyanine Blue)

147‐14‐8 HDPE Bag Dye/ Pigment industries

CPC Alpha Blue 147‐14‐8 HDPE Bag

In Chemical Industries and in textile industries for printing and dyeing.

Pigment Green 7 1328‐83‐6

Enclosure: 3

Name of Raw Material with Its Quantity

Raw Material Consumption Detail Product Wise

1. C.P.C. Blue (300 MT/M):

Sr.No. Name of Raw Material MT/MT MT/Month 1. Urea 1.544 463.2 2. Phthalic Anhydride 1.087 326.1 3. Cuprous Chloride 0.185 55.5 4. Ortho nitro Toluene 1.739 10.5 5. Ammonium Molybnate 0.004 1.2 6. Spent Sulphuric Acid 1.925 577.5

2. C.P.C. Alpha Blue (25 MT/M):

Sr.No. Name of Raw Material MT/MT MT/Month 1. Copper Phthalo Cyanine 1.05 26.25 2. Sulphhuric Acid 3.5 87.5 3. Emulsifier 0.005 0.125 4. Caustic lye 0.2 5

3. C.P.C Green/ Pigment Green 7 (50 MT/M):

Sr.No. Name of Raw Material MT/MT MT/Month 1. Aluminum Chloride 1.898 94.9 2. Copper Phthalo Cyanine 0.542 27.1 3. Salt 0.406 20.3 4. Chlorine gas 1.016 50.8 5. Cuprous Chloride 0.061 3.05 6. Xylene 3 3 7. Emulsifier 0.04 2.00 8. Caustic Lye 0.06 3.00

Overall Raw Material Consumption:

Sr. No.

Name of Raw Material MT/Month

1. Urea 463.2 2. Phthalic Anhydride 326.1 3. Cuprous Chloride 58.55 4. Ammonium Molybdate 1.2 5. Sulphuric Acid 665 6. Copper Phthalo Cyanine 53.35 7. Emulsifier 2.125 8. Caustic Lye 8 9. Aluminum Chloride 94.9 10. Salt 20.3 11. Chlorine Gas 50.8 12. ONT 10.5 13. Xylene 3

Overall Solvent Consumption:

Name of Solvent Used in which Product

Quantity In MT/M

Recovered Quantity

Fresh Solvent To Be

Used/Month Ortho Nitro Toluene

CPC Blue 521.7 511.2 10.5

Xylene CPC Green 7 150 147 3

* We will maintain as minimum inventory as possible.

Enclosure: 4

Material Safety Data Sheets of Products & Raw Materials

(Attached)

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Material Safety Data SheetSulfuric acid MSDS

Section 1: Chemical Product and Company Identification

Product Name: Sulfuric acid

Catalog Codes: SLS2539, SLS1741, SLS3166, SLS2371,SLS3793

CAS#: 7664-93-9

RTECS: WS5600000

TSCA: TSCA 8(b) inventory: Sulfuric acid

CI#: Not applicable.

Synonym: Oil of Vitriol; Sulfuric Acid

Chemical Name: Hydrogen sulfate

Chemical Formula: H2-SO4

Contact Information:

Sciencelab.com, Inc.14025 Smith Rd.Houston, Texas 77396

US Sales: 1-800-901-7247International Sales: 1-281-441-4400

Order Online: ScienceLab.com

CHEMTREC (24HR Emergency Telephone), call:1-800-424-9300

International CHEMTREC, call: 1-703-527-3887

For non-emergency assistance, call: 1-281-441-4400

Section 2: Composition and Information on Ingredients

Composition:

Name CAS # % by Weight

Sulfuric acid 7664-93-9 95 - 98

Toxicological Data on Ingredients: Sulfuric acid: ORAL (LD50): Acute: 2140 mg/kg [Rat.]. VAPOR (LC50): Acute: 510 mg/m2 hours [Rat]. 320 mg/m 2 hours [Mouse].

Section 3: Hazards Identification

Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. Liquid or spray mist may produce tissue damage particularly on mucous membranes of eyes, mouth andrespiratory tract. Skin contact may produce burns. Inhalation of the spray mist may produce severe irritation of respiratorytract, characterized by coughing, choking, or shortness of breath. Severe over-exposure can result in death. Inflammation ofthe eye is characterized by redness, watering, and itching. Skin inflammation is characterized by itching, scaling, reddening,or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspected forhuman.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance may be toxic to kidneys, lungs, heart, cardiovascular system, upper respiratory tract,eyes, teeth. Repeated or prolonged exposure to the substance can produce target organs damage. Repeated or prolonged

http://www.sciencelab.com/

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contact with spray mist may produce chronic eye irritation and severe skin irritation. Repeated or prolonged exposure to spraymist may produce respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated exposure to a highlytoxic material may produce general deterioration of health by an accumulation in one or many human organs.

Section 4: First Aid Measures

Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before reuse. Thoroughly cleanshoes before reuse. Get medical attention immediately.

Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek immediate medicalattention.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention immediately.

Serious Inhalation:Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. Ifbreathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. WARNING: It maybe hazardous to the person providing aid to give mouth-to-mouth resuscitation when the inhaled material is toxic, infectious orcorrosive. Seek immediate medical attention.

Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention if symptoms appear.

Serious Ingestion: Not available.

Section 5: Fire and Explosion Data

Flammability of the Product: Non-flammable.

Auto-Ignition Temperature: Not applicable.

Flash Points: Not applicable.

Flammable Limits: Not applicable.

Products of Combustion:Products of combustion are not available since material is non-flammable. However, products of decompostion include fumesof oxides of sulfur. Will react with water or steam to produce toxic and corrosive fumes. Reacts with carbonates to generatecarbon dioxide gas. Reacts with cyanides and sulfides to form poisonous hydrogen cyanide and hydrogen sulfide respectively.

Fire Hazards in Presence of Various Substances: Combustible materials

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of oxidizing materials.

Fire Fighting Media and Instructions: Not applicable.

Special Remarks on Fire Hazards:Metal acetylides (Monocesium and Monorubidium), and carbides ignite with concentrated sulfuric acid. White Phosphorous +boiling Sulfuric acid or its vapor ignites on contact. May ignite other combustible materials. May cause fire when sulfuric acidis mixed with Cyclopentadiene, cyclopentanone oxime, nitroaryl amines, hexalithium disilicide, phorphorous (III) oxide, andoxidizing agents such as chlorates, halogens, permanganates.

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Special Remarks on Explosion Hazards:M i x t u r e s o f s u l f u r i c a c i d a n d a n y o f t h e f o l l o w i n g c a n e x p l o d e : p - n i t r o t o l u e n e , p e n t a s il v e r trihydroxydiaminophosphate, perchlorates, alcohols with strong hydrogen peroxide, ammonium tetraperoxychromate,mercuric nitrite, potassium chlorate, potassium permanganate with potassium chloride, carbides, nitro compounds, nitrates,carbides, phosphorous, iodides, picratres, fulminats, dienes, alcohols (when heated) Nitramide decomposes explosivelyon contact with concentrated sulfuric acid. 1,3,5-Trinitrosohexahydro-1,3,5-triazine + sulfuric acid causes explosivedecompositon.

Section 6: Accidental Release Measures

Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.

Section 7: Handling and Storage

Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, reducingagents, combustible materials, organic materials, metals, acids, alkalis, moisture. May corrode metallic surfaces. Store in ametallic or coated fiberboard drum using a strong polyethylene inner package.

Storage:Hygroscopic. Reacts. violently with water. Keep container tightly closed. Keep container in a cool, well-ventilated area. Do notstore above 23°C (73.4°F).

Section 8: Exposure Controls/Personal Protection

Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:TWA: 1 STEL: 3 (mg/m3) [Australia] Inhalation TWA: 1 (mg/m3) from OSHA (PEL) [United States] Inhalation TWA: 1 STEL: 3(mg/m3) from ACGIH (TLV) [United States] [1999] Inhalation TWA: 1 (mg/m3) from NIOSH [United States] Inhalation TWA: 1(mg/m3) [United Kingdom (UK)]Consult local authorities for acceptable exposure limits.

Section 9: Physical and Chemical Properties

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Physical state and appearance: Liquid. (Thick oily liquid.)

Odor: Odorless, but has a choking odor when hot.

Taste: Marked acid taste. (Strong.)

Molecular Weight: 98.08 g/mole

Color: Colorless.

pH (1% soln/water): Acidic.

Boiling Point:270°C (518°F) - 340 deg. C Decomposes at 340 deg. C

Melting Point: -35°C (-31°F) to 10.36 deg. C (93% to 100% purity)

Critical Temperature: Not available.

Specific Gravity: 1.84 (Water = 1)

Vapor Pressure: Not available.

Vapor Density: 3.4 (Air = 1)

Volatility: Not available.

Odor Threshold: Not available.

Water/Oil Dist. Coeff.: Not available.

Ionicity (in Water): Not available.

Dispersion Properties: See solubility in water.

Solubility:Easily soluble in cold water. Sulfuric is soluble in water with liberation of much heat. Soluble in ethyl alcohol.

Section 10: Stability and Reactivity Data

Stability: The product is stable.

Instability Temperature: Not available.

Conditions of Instability:Conditions to Avoid: Incompatible materials, excess heat, combustible material materials, organic materials, exposure to moistair or water, oxidizers, amines, bases. Always add the acid to water, never the reverse.

Incompatibility with various substances:Reactive with oxidizing agents, reducing agents, combustible materials, organic materials, metals, acids, alkalis, moisture.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(316). Highly corrosive in presence of stainlesssteel(304). Non-corrosive in presence of glass.

Special Remarks on Reactivity:Hygroscopic. Strong oxidizer. Reacts violently with water and alcohol especially when water is added to the product.Incompatible (can react explosively or dangerously) with the following: ACETIC ACID, ACRYLIC ACID, AMMONIUMHYDROXIDE, CRESOL, CUMENE, DICHLOROETHYL ETHER, ETHYLENE CYANOHYDRIN, ETHYLENEIMINE, NITRICACID, 2-NITROPROPANE, PROPYLENE OXIDE, SULFOLANE, VINYLIDENE CHLORIDE, DIETHYLENE GLYCOLMONOMETHYL ETHER, ETHYL ACETATE, ETHYLENE CYANOHYDRIN, ETHYLENE GLYCOL MONOETHYL ETHERACETATE, GLYOXAL, METHYL ETHYL KETONE, dehydrating agents, organic materials, moisture (water), Acetic anhydride,Acetone, cyanohydrin, Acetone+nitric acid, Acetone + potassium dichromate, Acetonitrile, Acrolein, Acrylonitrile, Acrylonitrile+water, Alcohols + hydrogen peroxide, ally compounds such as Allyl alcohol, and Allyl Chloride, 2-Aminoethanol, Ammoniumhydroxide, Ammonium triperchromate, Aniline, Bromate + metals, Bromine pentafluoride, n-Butyraldehyde, Carbides, Cesiumacetylene carbide, Chlorates, Cyclopentanone oxime, chlorinates, Chlorates + metals, Chlorine trifluoride, Chlorosulfonicacid, 2-cyano-4-nitrobenzenediazonium hydrogen sulfate, Cuprous nitride, p-chloronitrobenzene, 1,5-Dinitronaphthlene +

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sulfur, Diisobutylene, p-dimethylaminobenzaldehyde, 1,3-Diazidobenzene, Dimethylbenzylcarbinol + hydrogen peroxide,Epichlorohydrin, Ethyl alcohol + hydrogen peroxide, Ethylene diamine, Ethylene glycol and other glycols, , Ethylenimine,Fulminates, hydrogen peroxide, Hydrochloric acid, Hydrofluoric acid, Iodine heptafluoride, Indane + nitric acid, Iron, Isoprene,Lithium silicide, Mercuric nitride, Mesityl oxide, Mercury nitride, Metals (powdered), Nitromethane, Nitric acid + glycerides,p-Nitrotoluene, Pentasilver trihydroxydiaminophosphate, Perchlorates, Perchloric acid, Permanganates + benzene, 1-Phenyl-2-methylpropyl alcohol + hydrogen peroxide, Phosphorus, Phosphorus isocyanate, Picrates, Potassium tert-butoxide,Potassium chlorate, Potassium Permanganate and other permanganates, halogens, amines, Potassium Permanganate +Potassium chloride, Potassium Permanganate + water, Propiolactone (beta)-, Pyridine, Rubidium aceteylene carbide, Silverpermanganate, Sodium, Sodium carbonate, sodium hydroxide, Steel, styrene monomer, toluene + nitric acid, Vinyl acetate,Thalium (I) azidodithiocarbonate, Zinc chlorate, Zinc Iodide, azides, carbonates, cyanides, sulfides, sulfites, alkali hydrides,carboxylic acid anhydrides, nitriles, olefinic organics, aqueous acids, cyclopentadiene, cyano-alcohols, metal acetylides,Hydrogen gas is generated by the action of the acid on most metals (i.e. lead, copper, tin, zinc, aluminum, etc.). Concentratedsulfuric acid oxidizes, dehydrates, or sulfonates most organic compounds.

Special Remarks on Corrosivity:Non-corrosive to lead and mild steel, but dillute acid attacks most metals. Attacks many metals releasing hydrogen. Minorcorrosive effect on bronze. No corrosion data on brass or zinc.

Polymerization: Will not occur.

Section 11: Toxicological Information

Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 2140 mg/kg [Rat.]. Acute toxicity of the vapor (LC50): 320 mg/m3 2 hours [Mouse].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 1 (Proven for human.) by IARC, + (Proven.) by OSHA. Classified A2 (Suspectedfor human.) by ACGIH. May cause damage to the following organs: kidneys, lungs, heart, cardiovascular system, upperrespiratory tract, eyes, teeth.

Other Toxic Effects on Humans:Extremely hazardous in case of inhalation (lung corrosive). Very hazardous in case of skin contact (corrosive, irritant,permeator), of eye contact (corrosive), of ingestion, .

Special Remarks on Toxicity to Animals: Not available.

Special Remarks on Chronic Effects on Humans:Mutagenicity: Cytogenetic Analysis: Hamster, ovary = 4mmol/L Reproductive effects: May cause adverse reproductive effectsbased on animal data. Developmental abnormalities (musculoskeletal) in rabbits at a dose of 20 mg/m3 for 7 hrs.(RTECS)Teratogenecity: neither embryotoxic, fetoxic, nor teratogenetic in mice or rabbits at inhaled doses producing some maternaltoxicity

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes severe skin irritation and burns. Continued contact can cause tissue necrosis.Eye: Causes severe eye irritation and burns. May cause irreversible eye injury. Ingestion: Harmful if swallowed. May causepermanent damage to the digestive tract. Causes gastrointestial tract burns. May cause perforation of the stomach, GIbleeding, edema of the glottis, necrosis and scarring, and sudden circulatory collapse(similar to acute inhalation). It mayalso cause systemic toxicity with acidosis. Inhalation: May cause severe irritation of the respiratory tract and mucousmembranes with sore throat, coughing, shortness of breath, and delayed lung edema. Causes chemical burns to the repiratorytract. Inhalation may be fatal as a result of spasm, inflammation, edema of the larynx and bronchi, chemical pneumonitis,and pulmonary edema. Cause corrosive action on mucous membranes. May affect cardiovascular system (hypotension,depressed cardiac output, bradycardia). Circulatory collapse with clammy skin, weak and rapid pulse, shallow respiration, andscanty urine may follow. Circulatory shock is often the immediate cause of death. May also affect teeth(changes in teeth andsupporting structures - erosion, discoloration). Chronic Potential Health Effects: Inhalation: Prolonged or repeated inhalationmay affect behavior (muscle contraction or spasticity), urinary system (kidney damage), and cardiovascular system, heart(ischemic heart leisons), and respiratory system/lungs(pulmonary edema, lung damage), teeth (dental discoloration, erosion).Skin: Prolonged or repeated skin contact may cause dermatitis, an allergic skin reaction.

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Section 12: Ecological Information

Ecotoxicity: Ecotoxicity in water (LC50): 49 mg/l 48 hours [bluegill/sunfish].

BOD5 and COD: Not available.

Products of Biodegradation:Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise.

Toxicity of the Products of Biodegradation: The products of degradation are less toxic than the product itself.

Special Remarks on the Products of Biodegradation: Not available.

Section 13: Disposal Considerations

Waste Disposal:Sulfuric acid may be placed in sealed container or absorbed in vermiculite, dry sand, earth, or a similar material. It may alsobe diluted and neutralized. Be sure to consult with local or regional authorities (waste regulators) prior to any disposal. Wastemust be disposed of in accordance with federal, state and local environmental control regulations.

Section 14: Transport Information

DOT Classification: Class 8: Corrosive material

Identification: : Sulfuric acid UNNA: 1830 PG: II

Special Provisions for Transport: Not available.

Section 15: Other Regulatory Information

Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sulfuric acid New York release reporting list: Sulfuric acid RhodeIsland RTK hazardous substances: Sulfuric acid Pennsylvania RTK: Sulfuric acid Minnesota: Sulfuric acid MassachusettsRTK: Sulfuric acid New Jersey: Sulfuric acid California Director's List of Hazardous Substances (8 CCR 339): Sulfuric acidTennessee RTK: Sulfuric acid TSCA 8(b) inventory: Sulfuric acid SARA 302/304/311/312 extremely hazardous substances:Sulfuric acid SARA 313 toxic chemical notification and release reporting: Sulfuric acid CERCLA: Hazardous substances.:Sulfuric acid: 1000 lbs. (453.6 kg)

Other Regulations:OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). EINECS: This product is on theEuropean Inventory of Existing Commercial Chemical Substances.

Other Classifications:

WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R35- Causes severe burns. S2- Keep out of the reach of children. S26- In case of contact with eyes, rinse immediately withplenty of water and seek medical advice. S30- Never add water to this product. S45- In case of accident or if you feel unwell,seek medical advice immediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

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Personal Protection:

National Fire Protection Association (U.S.A.):

Health: 3

Flammability: 0

Reactivity: 2

Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.

Section 16: Other Information

References:-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -The Sigma-AldrichLibrary of Chemical Safety Data, Edition II. -Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., VanNostrand Reinold, 1987.

Other Special Considerations: Not available.

Created: 10/09/2005 11:58 PM

Last Updated: 05/21/2013 12:00 PM

The information above is believed to be accurate and represents the best information currently available to us. However, wemake no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assumeno liability resulting from its use. Users should make their own investigations to determine the suitability of the information fortheir particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or forlost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.comhas been advised of the possibility of such damages.

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Material Safety Data SheetSodium hydroxide MSDS


Product Name: Sodium hydroxide


CAS#: 1310-73-2

RTECS: WB4900000

TSCA: TSCA 8(b) inventory: Sodium hydroxide

CI#: Not available.

Synonym: Caustic Soda

Chemical Name: Sodium Hydroxide

Chemical Formula: NaOH









Composition:


Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage orblindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal orrespiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic tomucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce targetorgans damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure canproduce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage.


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Serious Skin Contact:Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention.



Ingestion:Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconsciousperson. If large quantities of this material are swallowed, call a physician immediately. Loosen tight clothing such as a collar,tie, belt or waistband.







Products of Combustion: Not available.

Fire Hazards in Presence of Various Substances: metals

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat.

Fire Fighting Media and Instructions: Not available

Special Remarks on Fire Hazards:sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and stateof division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride,1,2 dichlorethylene, nitroethane, nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorousboiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde +heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas.

Special Remarks on Explosion Hazards:Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonateprepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuumdistillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can

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cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat tocause an explosion.


Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue witha dilute solution of acetic acid.

Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration levelabove TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitablerespiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skinand eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Deliquescent.


Engineering Controls:Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommendedexposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminantsbelow the exposure limit.

Personal Protection:Splash goggles. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent.Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used toavoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handlingthis product.

Exposure Limits:STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from NIOSHConsult local authorities for acceptable exposure limits.


Physical state and appearance: Solid. (Deliquescent solid.)

Odor: Odorless.

Taste: Not available.

Molecular Weight: 40 g/mole

Color: White.

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pH (1% soln/water): 13.5 [Basic.]

Boiling Point: 1388°C (2530.4°F)

Melting Point: 323°C (613.4°F)



Vapor Pressure: Not applicable.

Vapor Density: Not available.






Solubility: Easily soluble in cold water.




Conditions of Instability: Incompatible materials, moisture, moist air

Incompatibility with various substances:Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture.

Corrosivity: Not available.

Special Remarks on Reactivity:Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be usedfor this process. Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime anddiborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids(mineral, non-oxidizing, e.g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromicacid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid,oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran),esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methylchloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acidchlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.ealuminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds(toxic e.g. berylium, lead acetate, nickel carbonyl, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles(e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, chlorohydrin,chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide,chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reactswith formaldehyde hydroxide to yield formic acid, and hydrogen.

Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.




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Toxicity to Animals:LD50: Not available. LC50: Not available.

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucousmembranes, upper respiratory tract, skin, eyes.


Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg

Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogeneticanalysis)

Special Remarks on other Toxic Effects on Humans:


Ecotoxicity: Not available.



Toxicity of the Products of Biodegradation: The product itself and its products of degradation are not toxic.



Waste Disposal:Waste must be disposed of in accordance with federal, state and local environmental control regulations.



Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide NewYork release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide PennsylvaniaRTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxideLouisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg)


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WHMIS (Canada): CLASS E: Corrosive solid.

DSCL (EEC):R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2

Personal Protection: j


Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Synthetic apron. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wearappropriate respirator when ventilation is inadequate. Splash goggles.


References: Not available.


Created: 10/09/2005 06:32 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetSodium chloride MSDS


Product Name: Sodium chloride


CAS#: 7647-14-5

RTECS: VZ4725000

TSCA: TSCA 8(b) inventory: Sodium chloride


Synonym: Salt; Sea Salt

Chemical Name: Sodium chloride

Chemical Formula: NaCl









Composition:


Sodium chloride 7647-14-5 100

Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >42000 mg/m 1 hours [Rat].


Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, ofinhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic forbacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated orprolonged exposure is not known to aggravate medical condition.


Eye Contact:


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Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.

Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.

Serious Skin Contact: Not available.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention if symptoms appear.

Serious Inhalation: Not available.









Fire Hazards in Presence of Various Substances: Not applicable.

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available.


Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes.

Special Remarks on Explosion Hazards:Electrolysis of sodium chloride in presence of nitrogenous compounds to produce chlorine may lead to formation of explosivenitrogen trichloride. Potentially explosive reaction with dichloromaleic anhydride + urea.


Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water onthe contaminated surface and dispose of according to local and regional authority requirements.

Large Spill:Use a shovel to put the material into a convenient waste disposal container. Finish cleaning by spreading water on thecontaminated surface and allow to evacuate through the sanitary system.


Precautions:Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizingagents, acids.

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Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic



Personal Protection:Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits: Not available.


Physical state and appearance: Solid. (Solid crystalline powder.)

Odor: Slight.

Taste: Saline.


Color: White.

pH (1% soln/water): 7 [Neutral.]












Solubility:Easily soluble in cold water, hot water. Soluble in glycerol, and ammonia. Very slightly soluble in alcohol. Insoluble inHydrochloric Acid.



p. 4


Conditions of Instability: Incompatible materials, high temperatures.

Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.

Corrosivity: Not considered to be corrosive for metals and glass.

Special Remarks on Reactivity:Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride israpidly attacked by bromine trifluoride. Violent reaction with lithium.

Special Remarks on Corrosivity: Not available.



Routes of Entry: Inhalation. Ingestion.

Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3000 mg/kg [Rat.]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>42000 mg/m3 1 hours [Rat].

Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose (LDL) [Man] - Route: Oral; Dose: 1000 mg/kg

Special Remarks on Chronic Effects on Humans:Causes adverse reproductive effects in humans (fetotoxicity, abortion, ) by intraplacental route. High intake of sodium chloride,whether from occupational exposure or in the diet, may increase risk of TOXEMIA OF PREGNANCY in susceptible women(Bishop, 1978). Hypertonic sodium chloride solutions have been used to induce abortion in late pregnancy by direct infusioninto the uterus (Brown et al, 1972), but this route of administration is not relevant to occupational exposures. May causeadverse reproductive effects and birth defects in animals, particularly rats and mice (fetotoxicity, abortion, musculoskeletalabnormalities, and maternal effects (effects on ovaries, fallopian tubes) by oral, intraperitoneal, intraplacental, intrauterine,parenteral, and subcutaneous routes. While sodium chloride has been used as a negative control n some reproductivestudies, it has also been used as an example that almost any chemical can cause birth defects in experimental animalsif studied under the right conditions (Nishimura & Miyamoto, 1969). In experimental animals, sodium chloride has causeddelayed effects on newborns, has been fetotoxic, and has caused birth defects and abortions in rats and mice (RTECS, 1997).May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Ingestion: Ingestion of largequantities can irritate the stomach (as in overuse of salt tablets) with nausea and vomiting. May affect behavior (musclespasicity/contraction, somnolence), sense organs, metabolism, and cardiovascular system. Continued exposure mayproduce dehydration, internal organ congestion, and coma. Inhalation: Material is irritating to mucous membranes and upperrespiratory tract.






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DOT Classification: Not a DOT controlled material (United States).

Identification: Not applicable.

Special Provisions for Transport: Not applicable.


Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.


WHMIS (Canada): Not controlled under WHMIS (Canada).

DSCL (EEC):R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0

Personal Protection: E


Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent. Splash goggles.


References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II.


Created: 10/11/2005 12:33 PM

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Material Safety Data SheetSodium chloride MSDS


Product Name: Sodium chloride


CAS#: 7647-14-5

RTECS: VZ4725000

TSCA: TSCA 8(b) inventory: Sodium chloride


Synonym: Salt; Sea Salt

Chemical Name: Sodium chloride

Chemical Formula: NaCl









Composition:


Sodium chloride 7647-14-5 100

Toxicological Data on Ingredients: Sodium chloride: ORAL (LD50): Acute: 3000 mg/kg [Rat.]. 4000 mg/kg [Mouse].DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >42000 mg/m 1 hours [Rat].


Potential Acute Health Effects: Slightly hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, ofinhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic forbacteria and/or yeast. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. Repeated orprolonged exposure is not known to aggravate medical condition.


Eye Contact:


p. 2

Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.

Skin Contact:Wash with soap and water. Cover the irritated skin with an emollient. Get medical attention if irritation develops. Cold watermay be used.

Serious Skin Contact: Not available.

Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention if symptoms appear.













Special Remarks on Fire Hazards: When heated to decomposition it emits toxic fumes.

Special Remarks on Explosion Hazards:Electrolysis of sodium chloride in presence of nitrogenous compounds to produce chlorine may lead to formation of explosivenitrogen trichloride. Potentially explosive reaction with dichloromaleic anhydride + urea.





Precautions:Keep locked up.. Do not ingest. Do not breathe dust. Avoid contact with eyes. Wear suitable protective clothing. If ingested,seek medical advice immediately and show the container or the label. Keep away from incompatibles such as oxidizingagents, acids.

p. 3

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic







Physical state and appearance: Solid. (Solid crystalline powder.)

Odor: Slight.

Taste: Saline.


Color: White.

pH (1% soln/water): 7 [Neutral.]












Solubility:Easily soluble in cold water, hot water. Soluble in glycerol, and ammonia. Very slightly soluble in alcohol. Insoluble inHydrochloric Acid.



p. 4


Conditions of Instability: Incompatible materials, high temperatures.

Incompatibility with various substances: Reactive with oxidizing agents, metals, acids.

Corrosivity: Not considered to be corrosive for metals and glass.

Special Remarks on Reactivity:Hygroscopic. Reacts with most nonnoble metals such as iron or steel, building materials (such as cement) Sodium chloride israpidly attacked by bromine trifluoride. Violent reaction with lithium.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3000 mg/kg [Rat.]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>42000 mg/m3 1 hours [Rat].

Chronic Effects on Humans: MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.

Other Toxic Effects on Humans: Slightly hazardous in case of skin contact (irritant), of ingestion, of inhalation.

Special Remarks on Toxicity to Animals: Lowest Published Lethal Dose (LDL) [Man] - Route: Oral; Dose: 1000 mg/kg

Special Remarks on Chronic Effects on Humans:Causes adverse reproductive effects in humans (fetotoxicity, abortion, ) by intraplacental route. High intake of sodium chloride,whether from occupational exposure or in the diet, may increase risk of TOXEMIA OF PREGNANCY in susceptible women(Bishop, 1978). Hypertonic sodium chloride solutions have been used to induce abortion in late pregnancy by direct infusioninto the uterus (Brown et al, 1972), but this route of administration is not relevant to occupational exposures. May causeadverse reproductive effects and birth defects in animals, particularly rats and mice (fetotoxicity, abortion, musculoskeletalabnormalities, and maternal effects (effects on ovaries, fallopian tubes) by oral, intraperitoneal, intraplacental, intrauterine,parenteral, and subcutaneous routes. While sodium chloride has been used as a negative control n some reproductivestudies, it has also been used as an example that almost any chemical can cause birth defects in experimental animalsif studied under the right conditions (Nishimura & Miyamoto, 1969). In experimental animals, sodium chloride has causeddelayed effects on newborns, has been fetotoxic, and has caused birth defects and abortions in rats and mice (RTECS, 1997).May affect genetic material (mutagenic)

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: May cause skin irritation. Eyes: Causes eye irritation. Ingestion: Ingestion of largequantities can irritate the stomach (as in overuse of salt tablets) with nausea and vomiting. May affect behavior (musclespasicity/contraction, somnolence), sense organs, metabolism, and cardiovascular system. Continued exposure mayproduce dehydration, internal organ congestion, and coma. Inhalation: Material is irritating to mucous membranes and upperrespiratory tract.






p. 5









Federal and State Regulations: TSCA 8(b) inventory: Sodium chloride

Other Regulations: EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.



DSCL (EEC):R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 1

Fire Hazard: 0

Reactivity: 0



Health: 1

Flammability: 0

Reactivity: 0

Specific hazard:



References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II.


Created: 10/11/2005 12:33 PM

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Material Safety Data SheetUrea MSDS


Product Name: Urea

Catalog Codes: SLU1063, SLU1132, SLU1093, SLU1162

CAS#: 57-13-6

RTECS: YR6250000

TSCA: TSCA 8(b) inventory: Urea

CI#: Not available.

Synonym: Carbamide

Chemical Name: carbonyldiamide

Chemical Formula: (NH2)2CO or CH4N2O









Composition:


Urea 57-13-6 100

Toxicological Data on Ingredients: Urea: ORAL (LD50): Acute: 8471 mg/kg [Rat]. 11000 mg/kg [Mouse].


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic toblood, cardiovascular system. Repeated or prolonged exposure to the substance can produce target organs damage.


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. Get medical attention.

Skin Contact:


p. 2

In case of contact, immediately flush skin with plenty of water. Cover the irritated skin with an emollient. Remove contaminatedclothing and shoes. Cold water may be used.Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medicalattention.


Inhalation:If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medicalattention.





Flammability of the Product: May be combustible at high temperature.

Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).

Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of heat.


Fire Fighting Media and Instructions:SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet.

Special Remarks on Fire Hazards: Not available.

Special Remarks on Explosion Hazards: Not available.





Precautions:Keep locked up.. Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporatethe residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitableprotective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice

p. 3

immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such asoxidizing agents.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 23°C (73.4°F).







Physical state and appearance: Solid. (Crystals solid.)

Odor:Almost odorless; May gradually develop slight odor of ammonia, especially in presence of moisture.

Taste: Cooling. Saline


Color: White.

pH (1% soln/water): Not available.

Boiling Point: Not available.

Melting Point: 132.7°C (270.9°F)







Water/Oil Dist. Coeff.: The product is more soluble in water; log(oil/water) = -2.1



Solubility: Easily soluble in cold water, hot water.



p. 4


Conditions of Instability: Excess heat, excess dust generation, incompatible materials.

Incompatibility with various substances: Reactive with oxidizing agents.


Special Remarks on Reactivity:Hygroscopic. Aborbs moisture from air. Reacts violently with Gallum Perchlorate. Reacts with chlorine to form chloramines. Italso reacts with the following: sodium hypochlorite, sodium nitrate, calcium hypochlorite, NaNO2, P2Cl5, nitrosyl perchlorate,strong oxidizing agents (permanganate, nitrate, dichromate, chloride)





Toxicity to Animals: Acute oral toxicity (LD50): 8471 mg/kg [Rat].

Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: blood,cardiovascular system.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.


Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetotoxicity) and genetic material (mutagenicity) based on animal studies. Passesthrough the placental barrier in human and is present in breast milk.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Causes skin irritation. Eyes: Causes eye irritation. Inhalation: Causes irritation of therespiratory tract, nose, and throat, coughing and sneezing. May also affect blood, metabolsim and urinary system. Ingestion:Causes digestive (gastrointestinal) tract irritation with nausea, vomiting, and diarrhea. May affect behavior (altered sleeptime, change in motor activity), cardiovascular system (heart rate), and the brain. May also affect the blood and may causetumorigenic effects. Chronic Potential Health Effects: Prolonged exposure may cause adverse reproductive effects. Laboratoryexperiments on animals have resulted in mutagenic effects. Prolonged exposure or exposure at high concentrations maycause eye damage.









p. 5






Federal and State Regulations:Minnesota: Urea TSCA 8(b) inventory: Urea




DSCL (EEC):R36/38- Irritating to eyes and skin. R40- Possible risks of irreversible effects. S24/25- Avoid contact with skin and eyes.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:





Created: 10/10/2005 08:32 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetPhthalic anhydride MSDS


Product Name: Phthalic anhydride

Catalog Codes: SLP4651, SLP1825

CAS#: 85-44-9

RTECS: TI3150000

TSCA: TSCA 8(b) inventory: Phthalic anhydride

CI#: Not available.

Synonym: 1,3-Isobenzofurandione

Chemical Name: Phthalic Anydride

Chemical Formula: C8H4O3









Composition:


Phthalic anhydride 85-44-9 100

Toxicological Data on Ingredients: Phthalic anhydride: ORAL (LD50): Acute: 1530 mg/kg [Rat]. 1500 mg/kg [Mouse].DERMAL (LD50): Acute: >10000 mg/kg [Rabbit]. DUST (LC50): Acute: >210 mg/m 1 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. Hazardous in case of skincontact (corrosive, permeator), of eye contact (corrosive). The amount of tissue damage depends on length of contact. Eyecontact can result in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dustwill produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking, unconsciousness or death. Inflammation of the eye is characterized by redness,watering, and itching. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.)by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY:Not available. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure canproduce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation inone or many human organs.


p. 2


Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Cold water may be used. WARM water MUST be used. Get medical attention immediately.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Getmedical attention immediately.








Auto-Ignition Temperature: 570°C (1058°F)

Flash Points: CLOSED CUP: 151.67°C (305°F). OPEN CUP: 165°C (329°F).

Flammable Limits: LOWER: 1.7% UPPER: 10.4%

Products of Combustion: These products are carbon oxides (CO, CO2).

Fire Hazards in Presence of Various Substances:Slightly flammable to flammable in presence of heat. Non-flammable in presence of shocks.






Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.

p. 3

Large Spill:Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Usewater spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignitionsources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. CheckTLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Keep away from heat. Keep away from sources of ignition. Empty containers pose afire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathedust. Never add water to this product. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested,seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away fromincompatibles such as oxidizing agents.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Do not store above 25°C (77°F).





Exposure Limits:TWA: 6.1 (mg/m3) from ACGIH (TLV) [United States] TWA: 6 from ACGIH (TLV) [United States]Consult local authorities foracceptable exposure limits.



Odor: Characteristic acrid, choking



Color: White.


Boiling Point: 295°C (563°F)





p. 4






Dispersion Properties: Not available.

Solubility: Very slightly soluble in cold water, diethyl ether.




Conditions of Instability: Excess heat, dust generation, moisture, incompatible matrerials.

Incompatibility with various substances:Reactive with oxidizing agents. Slightly reactive to reactive with moisture.

Corrosivity: Non-corrosive in presence of glass.

Special Remarks on Reactivity: Also incompatible with Nitric Acid, Sodium Nitrite, and Copper Oxide.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 1500 mg/kg [Mouse]. Acute dermal toxicity (LD50): >10000 mg/kg [Rabbit]. Acute toxicity of the dust (LC50):>210 mg/m 1 hours [Rat]. 3

Chronic Effects on Humans: CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive,permeator), of eye contact (corrosive).


Special Remarks on Chronic Effects on Humans:May affect genetic material. May cause adverse reproductive effects (paternal effects) based on animal data.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Corrosive! If the solid materials is permitted to remain in contact with moist tissues, superficialburns may result. Skin: May cause severe skin irritation witn possible skin burns. If the skin is moist the irritant effects will begreater due to hydrolysis of phthalic acid. Eyes: May cause severe eye irritation with possible eye burns. May cause chemicalconjunctivitis and corneal damage. Inhalation: Causes severe respiratory tract irritation with possible chemical burns to therespiratory tract. May cause asthmatic attacks due to allergic sensitization of respiratory tract. May also affect respiration,and liver. Symptoms may include Rhinorrhea, blaody nasal disharge, hoarseness of voice, cough, bronchospasm Ingestion:Causes severe digestive tract irritation iwth possible burns. May cause severe and permanent damage to the digestivetract. Mah cause perforation of the digestive tract. May affect behavior. Chronic Potential Health Effects: Skin: Prolonged orrepeated skin contact may cause allergic skin reaction. I

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Identification: : Phthalic anhydride UNNA: 2214 PG: III



Federal and State Regulations:Connecticut hazardous material survey.: Phthalic anhydride Illinois toxic substances disclosure to employee act: Phthalicanhydride Illinois chemical safety act: Phthalic anhydride New York release reporting list: Phthalic anhydride Rhode IslandRTK hazardous substances: Phthalic anhydride Pennsylvania RTK: Phthalic anhydride Minnesota: Phthalic anhydrideMichigan critical material: Phthalic anhydride Massachusetts RTK: Phthalic anhydride Massachusetts spill list: Phthalicanhydride New Jersey: Phthalic anhydride New Jersey spill list: Phthalic anhydride Louisiana spill reporting: Phthalicanhydride California Director's List of Hazardous Substances: Phthalic anhydride TSCA 8(b) inventory: Phthalic anhydrideTSCA 8(a) IUR: Phthalic anhydride SARA 313 toxic chemical notification and release reporting: Phthalic anhydride CERCLA:Hazardous substances.: Phthalic anhydride: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive solid.

DSCL (EEC):R22- Harmful if swallowed. R26- Very toxic by inhalation. R38- Irritating to skin. R41- Risk of serious damage to eyes. S1/2-Keep locked up and out of the reach of children. S26- In case of contact with eyes, rinse immediately with plenty of waterand seek medical advice. S28- After contact with skin, wash immediately with plenty of [***] S36/37- Wear suitable protectiveclothing and gloves. S39- Wear eye/face protection. S45- In case of accident or if you feel unwell,

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 1

Reactivity: 1

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Health: 3

Flammability: 1

Reactivity: 0

Specific hazard:





Created: 10/10/2005 11:26 AM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data SheetCuprous chloride MSDS


Product Name: Cuprous chloride

Catalog Codes: SLC3931, SLC1138

CAS#: 7758-89-6

RTECS: GL6990000

TSCA: TSCA 8(b) inventory: Cuprous chloride

CI#: Not available.

Synonym:

Chemical Name: Not available.

Chemical Formula: CuCl









Composition:


Cuprous chloride 7758-89-6 100

Toxicological Data on Ingredients: Cuprous chloride: ORAL (LD50): Acute: 140 mg/kg [Rat].


Potential Acute Health Effects:Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. Slightly hazardous in case ofskin contact (irritant). Corrosive to eyes and skin. The amount of tissue damage depends on length of contact. Eye contact canresult in corneal damage or blindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produceirritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure canproduce lung damage, choking, unconsciousness or death.

Potential Chronic Health Effects:Very hazardous in case of ingestion. Hazardous in case of eye contact (irritant), of inhalation. Slightly hazardous in case ofskin contact (irritant). CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENICEFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to kidneys, lungs, liver,mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Repeatedexposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skindestruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage.Repeated exposure to an highly toxic material may produce general deterioration of health by an accumulation in one or manyhuman organs.


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Eye Contact:Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelidsopen. Cold water may be used. Do not use an eye ointment. Seek medical attention.

Skin Contact:If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protectingyour own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, suchas the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularlycareful to clean folds, crevices, creases and groin. If irritation persists, seek medical attention. Wash contaminated clothingbefore reusing.


Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.


Ingestion:Do not induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication thatthe toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar,tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.















Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray toreduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal. Becareful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities.

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Precautions:Keep locked up Keep container dry. Do not ingest. Do not breathe dust. Avoid contact with eyes Never add water to thisproduct Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If ingested,seek medical advice immediately and show the container or the label.

Storage: Corrosive materials should be stored in a separate safety storage cabinet or room.



Personal Protection:Splash goggles. Lab coat. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Gloves.


Exposure Limits: TWA: 1 CEIL: 2 (mg/m3)Consult local authorities for acceptable exposure limits.


Physical state and appearance: Solid. (Crystalline solid.)

Odor: Not available.



Color: White.


Boiling Point: 1490°C (2714°F)

Melting Point: 430°C (806°F)









Dispersion Properties: See solubility in water, diethyl ether.

Solubility:Soluble in diethyl ether. Very slightly soluble in cold water.

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Conditions of Instability: Not available.

Incompatibility with various substances: Not available.


Special Remarks on Reactivity: Not available.


Polymerization: No.


Routes of Entry: Eye contact. Inhalation. Ingestion.

Toxicity to Animals: Acute oral toxicity (LD50): 140 mg/kg [Rat].

Chronic Effects on Humans: The substance is toxic to kidneys, lungs, liver, mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of ingestion. Hazardous in case of inhalation. Slightly hazardous in case of skin contact (irritant).


Special Remarks on Chronic Effects on Humans: Not available.

Special Remarks on other Toxic Effects on Humans: Not available.





Toxicity of the Products of Biodegradation: The products of degradation are more toxic.



Waste Disposal:


DOT Classification: CLASS 6.1: Poisonous material.

Identification: : Toxic solid, inorganic, n.o.s. (Cuprous Chloride) : UN3288 PG: III

Special Provisions for Transport: Marine Pollutant

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Federal and State Regulations:Pennsylvania RTK: Cuprous chloride Massachusetts RTK: Cuprous chloride TSCA 8(b) inventory: Cuprous chloride SARA313 toxic chemical notification and release reporting: Cuprous chloride CERCLA: Hazardous substances.: Cuprous chloride

Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).



DSCL (EEC):R25- Toxic if swallowed. R36- Irritating to eyes.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0



Health: 3

Flammability: 0

Reactivity: 0

Specific hazard:

Protective Equipment:Gloves. Lab coat. Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriaterespirator when ventilation is inadequate. Splash goggles.




Created: 10/09/2005 05:01 PM

Last Updated: 05/21/2013 12:00 PM


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Material Safety Data Sheet

Aqua Ammonia (19 – 30% NH3)

MSDS Number 2050 (Revised July 1, 2003) 8 Pages 1. CHEMICAL PRODUCT and EMERGENCY TELEPHONE CONTACT

Product Name:............................................ Aqua Ammonia (19 – 30% NH3) Chemical Family: ....................................... Inorganic Nitrogen Compound Synonyms:.................................................. Ammonium Hydroxide; Ammonia Solution,

Aqueous Solution; Ammonia Monohydrate; Ammonia Water; Ammonia Liquor

Formula: ..................................................... NH4OH in H2O Product Use:……………………………… Fertilizers; Pharmaceuticals; Lubricants;

Household Cleaners; SCR NOx Control EMERGENCY TELEPHONE NUMBERS CHEMTREC (U.S.): .................................. 800-424-9300 CANUTEC (Canada): ………………… .. 613-996-6666

2. COMPOSITION/INFORMATION ON INGREDIENTS

Ingredient Name/CAS Number Concentration Exposure Limits (NH3)

Ammonium Hydroxide / 1336-21-6 39-62% 25 ppm TWA Water / 7732-18-5 38-61% 35 ppm STEL 50 ppm PEL Contains between 19 and 30% ammonia as NH3 300 ppm IDLH

3. HAZARDS IDENTIFICATION

Terra Industries Inc. Terra Centre – 600 Fourth Street Sioux City, Iowa 51101

EMERGENCY OVERVIEW Corrosive liquid! May be fatal if swallowed. Vapor is toxic and irritating to eyes, nose, throat and skin. Liquid will burn skin and eyes. Vapor is flammable under limited conditions. Use water to control fire and disperse vapors.

POTENTIAL HEALTH EFFECTS

Primary Routes of Entry: Inhalation, skin contact/absorption and eye contact.

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General Acute Exposure: Aqua ammonia may cause caustic injury. The severity of injury depends upon the concentration and duration of exposure. The extent of injury ranges from mild skin irritation or cough to severe burns or laryngeal edema and life- threatening pulmonary edema. Inhalation: Corrosive! Ammonia vapor is toxic and a severe irritant of the respiratory tract. It may cause a running nose, coughing, chest pain, cessation of respiration and death. It may cause severe breathing difficulties, which may be delayed in onset. ADDITIONAL MEDICAL INFORMATION: Bronchospasm, laryngitis, tracheitis, wheezing, dyspnea, and laryngeal stridor may be noted. Mucosal burns to the tracheobronchial tree, Pulmonary Edema, and associated hypoxemia frequently occur following exposure to concentrated ammonia. Skin Contact: Corrosive! Aqua ammonia is a severe irritant of the skin. Skin exposure to high concentrations may cause pain and deep and severe burns to the skin. ADDITIONAL MEDICAL INFORMATION: Corrosive effects on the skin and other tissues may be delayed, and damage may occur without the sensation or onset of pain. Strict adherence to first aid measures following exposure is essential. Eye Contact: Corrosive! Vapors cause irritation. Effects as a result of direct contact with aqua ammonia may range from irritation and lacrimation to severe injury and blindness. ADDITIONAL MEDICAL INFORMATION: Eye exposure may result in conjunctivitis, lacrimation and/or corneal irritation. Total corneal epithelial loss may occur. Ingestion: Toxic! May cause corrosion to the esophagus and stomach with perforation and peritonitis. Symptoms may include pain in the mouth, chest, and abdomen, with coughing, vomiting and collapse. Ingestion of as little as 3-4 ml of ammonium hydroxide may be fatal.

Note to the Physician: Pneumonitis should be anticipated after severe inhalation or ingestion. If severe exposure is suspected, observe for 48-72 hours for delayed pulmonary edema.

Carcinogenicity: NTP:.................................................. Not Listed

IARC:................................................ Not Listed OSHA:............................................... Not Regulated Medical Conditions Aggravated by Exposure: Chronic respiratory or skin disease.

4. FIRST AID MEASURES

First Aid for Eyes: Immediately flush eyes with copious amounts of tepid water for at least 15 minutes. If irritation, pain, swelling, excessive tearing, or light sensitivity persists,

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the patient should be seen in a health care facility and referral to an ophthalmologist considered. First Aid for Skin: Immediately flush exposed area with copious amounts of tepid water for at least 15 minutes followed by washing area thoroughly with soap and water. The patient should be seen in a health care facility if irritation or pain persists. First Aid for Inhalation: Move patient to fresh air. Monitor for respiratory distress. If cough or difficulty in breathing develops, evaluate for respiratory tract irritation, bronchitis, or pneumonitis. If trained to do so administer supplemental oxygen with assisted ventilation as required. Administer artificial respiration if patient is not breathing. First Aid for Ingestion: Call a physician. If conscious, give the patient 4 to 8 ounces of milk or water to drink immediately. Do not induce vomiting.

5. FIRE FIGHTING MEASURES Flash Point: ................................................. Not Applicable Lower Flammable Limit:............................ 15.5 % Volume in Air (for NH3) Upper Flammable Limit: ............................ 27.0 % Volume in Air (for NH3) Autoignition Temperature .......................... 1204o F (651o C) (for NH3) Extinguishing Media: Stopping the flow of gas rather than extinguishing the fire is usually the best procedure to follow when escaping gas is burning. Small Fire: .........................................Dry chemical or CO2 Large Fire: .........................................Water spray, fog or foam Special Fire Fighting Procedures: Use water to keep fire exposed containers cool. Use water fog or foam to reduce vapor concentrations if necessary. Full protective equipment including a self-contained breathing apparatus should be worn in a fire involving the material.

6. ACCIDENTAL RELEASE MEASURES Spill or Leak Measures: Stop leak if you can do so without risk. Keep unnecessary people away, isolate hazard area and deny entry. Stay upwind, out of low areas, and ventilate closed spaces before entering. Evaluate the affected area to determine whether to evacuate or shelter- in-place by taping windows and doors, shutting off outside air intake (attic fans, etc.), and placing a wet towel or cloth over the face (if needed). Self-contained breathing apparatus (SCBA) and structural firefighter’s protective clothing used in conjunction with water spray will provide limited protection in outdoor releases for short-term exposure. Fully encapsulating, vapor-protective clothing should be worn for spills and leaks with no fire. Use water spray to control vapors.

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CAUTION: Runoff from vapor control or dilution of spilled product may cause pollution.

Determining Spill Size: Generally, a small spill is one that involves a single, small Package (i.e. up to a 55 gallon drum), small cylinder, or a small (non-continuing) leak from a large container. Small Spill: a. Flush area with flooding amounts of water. b. First isolate 100 feet in all directions and then protect persons downwind 0.1 miles

during daylight and 0.1 miles at night (recommended for ammonia vapor).

Large Spill: a. Dike far ahead of liquid spill for later disposal. b. Follow local emergency protocol for handling. c. First isolate 200 feet in all directions, than protect persons downwind 0.3 miles

during daylight and 0.7 miles at night (recommended for ammonia vapor).

7. HANDLING AND STORAGE Handling: Avoid contact with either liquid or vapors. Direct contact with mercury must be avoided. Use proper PPE when working with or around aqua ammonia (See section 8). Storage: Ambient temperature. Store in dry, well-ventilated area away from incompatible materials. Protect against physical damage. Keep out of direct sunlight and away from heat sources.

8. EXPOSURE CONTROLS, PERSONAL PROTECTION Respiratory Protection Requirements: (for NH3) <25 ppm: No protection required. 25 to 35 ppm: Protection required if the daily TWA is exceeded. 35 to 50 ppm: Protection required if exposed for more than 15 minutes. 50 to 250 ppm: Minimum of an air-purifying respirator equipped with

ammonia canister(s) or cartridge(s). 250 to 300 ppm: Minimum of a full- face air-purifying respirator

equipped with ammonia canister(s) or cartridge(s). >300 ppm: A fresh air supply system must be used (i.e. SCBA)

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9. PHYSICAL AND CHEMICAL PROPERTIES

Typical for 30% Aqua Ammonia Physical Form:............................................... Liquid Color:............................................................. Colorless Odor:.............................................................. Strong pungent penetrating odor, ammonia. Boiling Point: ................................................ 27o C pH:................................................................. 12.0 (neat) Specific Gravity: ........................................... 0.8974 (@ 15.5o C) Vapor Density: .............................................. 0.60 (@ 15.5o C) for NH3 Vapor Pressure: ............................................. 475 mm Hg (@ 15.5o C) Molecular Weight:......................................... 35.05 Relative Density: ........................................... 7.48 lb. per gallon (@ 15.5o C)

Skin Protection Requirements: Nitrile rubber, neoprene, or PVC gloves and protective clothing should be used. Eye Protection Requirements: Use chemical (indirectly vented) goggles when there is a potential for eye contact. A full- face shield is recommended in addition to goggles for added protection. Other Protective Equipment: Safety shower and eyewash fountain should be provided in the aqua ammonia handling area. When transporting, provide at least 5 gallons of readily accessible, clean water and personal protective equipment. Engineering Controls: Maintain adequate ventilation to keep ammonia concentrations below applicable standards. NOTE: See Section 2 for regulatory exposure limits.

10. REACTIVITY Stability:.........................................................This is a stable material. Hazardous Polymerization:............................Will not occur. Decomposition: Will liberate ammonia if heated. Hydrogen is released on heating ammonia above 850o F (454o C). The decomposition temperature may be lowered to 575o F (300o C) by contact with certain metals such as nickel. At 12900 F (6900 C) or in the presence of electric spark ammonia decomposes into nitrogen and hydrogen gases, which may form a flammable mixture in the air. Conditions to avoid: Excessive heat. Materials to avoid: Contact with calcium hypochlorite, bleaches, gold, mercury, and silver may form highly explosive products. Contact with iodine, bromine or chlorine may cause violent spattering.

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11. TOXICOLOGICAL INFORMATION Toxicity Acute Oral Toxicity LD50 Rat:..................................................350 mg/kg bw LD50 Cat:………………………………...750 mg/kg bw

Acute Toxicity, Other Routes LDLO Rabbit:……………………………..10 mg/kg bw Skin Irritation / Corrosion Rabbit:……………………………………….Corrosive at 20% but not 10% Eye Irritation / Corrosion Rabbit:……………………………………….Irritating Genetic Toxicity in vitro Gene Mutation E. Coli:..................................Negative Genetic Toxicity in vivo Gene Mutation Drosophila melanogaster: ....No evidence for mutagenicity Ecotoxicity Acute Toxicity to Fish LC50 Cyprinus carpio: .............................1.34 – 1.70 mg un- ionized NH3/L (48 hr

semi-static) Acute Toxicity to Aquatic Invertebrates LC50 Daphnia magna: .............................32 mg NH4OH/L (48 hr static) Chronic Toxicity to Fish LC50 Ictalurus punctatus: ........................37.5 ppm (8 days) Source: TFI Product Testing Program April 2003

12. ECOLOGICAL INFORMATION

a. Ammonia is harmful to aquatic life in very low concentrations and may be

hazardous if it enters water intakes. b. Local health and wildlife authorities, as well as operators of water intakes in the

vicinity, should be notified of water releases. c. Waterfowl toxicity may occur at elevated concentrations. d. Ammonia does not concentrate in the food chain. e. The conversion of ammonia to nitrites/nitrates by bacteria in aquatic systems can

reduce the concentration of dissolved oxygen (referred to as nitrogenous oxygen demand).

Effect on water treatment process: Chlorination will produce chloramines, which are more readily detected by taste and odor. Note: See Ecotoxicity information in section 11.

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14. TRANSPORTATION INFORMATION

U.S. DOT and Canadian TDG Act Shipping Name:............................................. Ammonia solutions, (more than 10% but not

more than 35 % ammonia) Shipping Class/Division:............................... 8 Hazard Class:................................................. Corrosive Liquid Product Identification Number (PIN):........... UN2672 Packing Group ............................................... III OSHA Label Required:................................. Yes RQ (Reportable Quantity):............................ 1000 pounds (as NH4OH) TDG Reporting Quantity:.............................. 5 kg or 5 liters

15. REGULATORY INFORMATION Controlled Products Regulations Classification: D-1B: Toxic (Acute Lethality); E: Corrosive OSHA: This product is considered a hazardous material under criteria of the Federal OSHA Hazard Communication Standard 29 CFR 1910.1200 (Toxic; Corrosive). CAA Chemical Accident Prevention: Ammonia solution with a concentration of 20% or greater is considered a regulated substance, subject to the Chemical Accident Prevention provisions of 40 CFR Part 68. The threshold quantity for this substance is 20,000 lbs. Ammonia solution with a concentration less than 20% is not subject to the provisions of 40 CFR Part 68. CERCLA Hazardous Substances List:

a. RQ (Reportable Quantity): 1000 pounds (as NH4OH) b. Regulation: “Designation, Reportable Quantities, Notification” - 40 CFR Part 302

SARA TITLE III: Ammonia (including ammonia solution) is subject to the reporting requirements of Section 313 “Specific Toxic Chemical Listings” 40 CFR Part 372. Terra is required by 40 CFR Part 372.45 to notify certain customers as to which of its mixture or trade name products contain those chemicals. The purpose of that notification is to ensure that facilities that may be subject to the reporting requirements of Section 313 and that use products of unknown formulation will have knowledge that they are receiving products that contain chemicals subject to those reporting requirements.

13. DISPOSAL CONSIDERATIONS

Reclaim as fertilizer if possible. Otherwise, waste must be disposed of in accordance with federal, state, and local environmental control regulations.

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16. OTHER INFORMATION

May 5, 2003: This MSDS was written to comply with ANSI Standard Z400.1-1993. July 1, 2003: Added toxicity information from the TFI Product Testing Program April 2003.

The information and recommendations herein are taken from data contained in independent, industry-recognized references including but not limited to NIOSH, OSHA, ANSI, NFPA, DOT ERG, the TFI Product Testing Program, Global Engineering Documents, MEDITEXT, HAZARDTEXT, SARATEXT, CHRIS, OHM/TADS, and IRIS. Terra Industries Inc. makes no guarantee, warranty or other representation concerning this substance, since conditions of its use are beyond the control of the company. Terra Industries Inc. disclaims any liability for loss or damage incurred in connection with the use of this substance.

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Material Safety Data SheetHydrochloric acid MSDS


Product Name: Hydrochloric acid

Catalog Codes: SLH1462, SLH3154

CAS#: Mixture.

RTECS: MW4025000

TSCA: TSCA 8(b) inventory: Hydrochloric acid


Synonym: Hydrochloric Acid; Muriatic Acid

Chemical Name: Not applicable.

Chemical Formula: Not applicable.









Composition:


Hydrogen chloride 7647-01-0 20-38

Water 7732-18-5 62-80

Toxicological Data on Ingredients: Hydrogen chloride: GAS (LC50): Acute: 4701 ppm 0.5 hours [Rat].


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion, . Slightlyhazardous in case of inhalation (lung sensitizer). Non-corrosive for lungs. Liquid or spray mist may produce tissue damageparticularly on mucous membranes of eyes, mouth and respiratory tract. Skin contact may produce burns. Inhalation of thespray mist may produce severe irritation of respiratory tract, characterized by coughing, choking, or shortness of breath.Severe over-exposure can result in death. Inflammation of the eye is characterized by redness, watering, and itching. Skininflammation is characterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC EFFECTS: Classified 3 (Not classifiable forhuman.) by IARC [Hydrochloric acid]. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic to kidneys, liver, mucous membranes, upperrespiratory tract, skin, eyes, Circulatory System, teeth. Repeated or prolonged exposure to the substance can produce target


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organs damage. Repeated or prolonged contact with spray mist may produce chronic eye irritation and severe skin irritation.Repeated or prolonged exposure to spray mist may produce respiratory tract irritation leading to frequent attacks of bronchialinfection. Repeated exposure to a highly toxic material may produce general deterioration of health by an accumulation in oneor many human organs.







Ingestion:If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to anunconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention immediately.








Fire Hazards in Presence of Various Substances: of metals

Explosion Hazards in Presence of Various Substances: Non-explosive in presence of open flames and sparks, of shocks.


Special Remarks on Fire Hazards:Non combustible. Calcium carbide reacts with hydrogen chloride gas with incandescence. Uranium phosphide reacts withhydrochloric acid to release spontaneously flammable phosphine. Rubidium acetylene carbides burns with slightly warmhydrochloric acid. Lithium silicide in contact with hydrogen chloride becomes incandescent. When dilute hydrochloric acid isused, gas spontaneously flammable in air is evolved. Magnesium boride treated with concentrated hydrochloric acid producesspontaneously flammble gas. Cesium acetylene carbide burns hydrogen chloride gas. Cesium carbide ignites in contact withhydrochloric acid unless acid is dilute. Reacts with most metals to produce flammable Hydrodgen gas.

Special Remarks on Explosion Hazards:

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Hydrogen chloride in contact with the following can cause an explosion, ignition on contact, or other violent/vigorous reaction:Acetic anhydride AgClO + CCl4 Alcohols + hydrogen cyanide, Aluminum Aluminum-titanium alloys (with HCl vapor), 2-Aminoethanol, Ammonium hydroxide, Calcium carbide Ca3P2 Chlorine + dinitroanilines (evolves gas), Chlorosulfonic acid Cesiumcarbide Cesium acetylene carbide, 1,1-Difluoroethylene Ethylene diamine Ethylene imine, Fluorine, HClO4 Hexalithiumdisilicide H2SO4 Metal acetylides or carbides, Magnesium boride, Mercuric sulfate, Oleum, Potassium permanganate,beta-Propiolactone Propylene oxide Rubidium carbide, Rubidium, acetylene carbide Sodium (with aqueous HCl), Sodiumhydroxide Sodium tetraselenium, Sulfonic acid, Tetraselenium tetranitride, U3P4 , Vinyl acetate. Silver perchlorate with carbontetrachloride in the presence of hydrochloric acid produces trichloromethyl perchlorate which detonates at 40 deg. C.


Small Spill:Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container. Ifnecessary: Neutralize the residue with a dilute solution of sodium carbonate.

Large Spill:Corrosive liquid. Poisonous liquid. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material.Do not get water inside container. Do not touch spilled material. Use water spray curtain to divert vapor drift. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of sodium carbonate. Be careful that the product is not present at a concentrationlevel above TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe gas/fumes/ vapor/spray. Never add water to this product.In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and showthe container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as oxidizing agents, organicmaterials, metals, alkalis, moisture. May corrode metallic surfaces. Store in a metallic or coated fiberboard drum using a strongpolyethylene inner package.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.


Engineering Controls:Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respectivethreshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.

Personal Protection:Face shield. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Boots.

Personal Protection in Case of a Large Spill:Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoidinhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling thisproduct.

Exposure Limits:CEIL: 5 (ppm) from OSHA (PEL) [United States] CEIL: 7 (mg/m3) from OSHA (PEL) [United States] CEIL: 5 from NIOSHCEIL: 7 (mg/m3) from NIOSH TWA: 1 STEL: 5 (ppm) [United Kingdom (UK)] TWA: 2 STEL: 8 (mg/m3) [United Kingdom(UK)]Consult local authorities for acceptable exposure limits.


Physical state and appearance: Liquid.

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Odor: Pungent. Irritating (Strong.)


Molecular Weight: Not applicable.

Color: Colorless to light yellow.

pH (1% soln/water): Acidic.

Boiling Point:108.58 C @ 760 mm Hg (for 20.22% HCl in water) 83 C @ 760 mm Hg (for 31% HCl in water) 50.5 C (for 37% HCl in water)

Melting Point:-62.25°C (-80°F) (20.69% HCl in water) -46.2 C (31.24% HCl in water) -25.4 C (39.17% HCl in water)


Specific Gravity:1.1- 1.19 (Water = 1) 1.10 (20%and 22% HCl solutions) 1.12 (24% HCl solution) 1.15 (29.57% HCl solution) 1.16 (32% HClsolution) 1.19 (37% and 38%HCl solutions)

Vapor Pressure: 16 kPa (@ 20°C) average



Odor Threshold: 0.25 to 10 ppm



Dispersion Properties: See solubility in water, diethyl ether.

Solubility: Soluble in cold water, hot water, diethyl ether.




Conditions of Instability: Incompatible materials, water

Incompatibility with various substances:Highly reactive with metals. Reactive with oxidizing agents, organic materials, alkalis, water.

Corrosivity:Extremely corrosive in presence of aluminum, of copper, of stainless steel(304), of stainless steel(316). Non-corrosive inpresence of glass.

Special Remarks on Reactivity:Reacts with water especially when water is added to the product. Absorption of gaseous hydrogen chloride on mercuricsulfate becomes violent @ 125 deg. C. Sodium reacts very violently with gaseous hydrogen chloride. Calcium phosphideand hydrochloric acid undergo very energetic reaction. It reacts with oxidizers releasing chlorine gas. Incompatible with,alkali metals, carbides, borides, metal oxides, vinyl acetate, acetylides, sulphides, phosphides, cyanides, carbonates. Reactswith most metals to produce flammable Hydrogen gas. Reacts violently (moderate reaction with heat of evolution) withwater especially when water is added to the product. Isolate hydrogen chloride from heat, direct sunlight, alkalies (reactsvigorously), organic materials, and oxidizers (especially nitric acid and chlorates), amines, metals, copper and alloys (e.g.brass), hydroxides, zinc (galvanized materials), lithium silicide (incandescence), sulfuric acid(increase in temperature andpressure) Hydrogen chloride gas is emitted when this product is in contact with sulfuric acid. Adsorption of Hydrochloric Acidonto silicon dioxide results in exothmeric reaction. Hydrogen chloride causes aldehydes and epoxides to violently polymerize.Hydrogen chloride or Hydrochloric Acid in contact with the folloiwng can cause explosion or ignition on contact or

Special Remarks on Corrosivity:

p. 5

Highly corrosive. Incompatible with copper and copper alloys. It attacks nearly all metals (mercury, gold, platinium, tantalum,silver, and certain alloys are exceptions). It is one of the most corrosive of the nonoxidizing acids in contact with copper alloys.No corrosivity data on zinc, steel. Severe Corrosive effect on brass and bronze



Routes of Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation.

Toxicity to Animals:Acute oral toxicity (LD50): 900 mg/kg [Rabbit]. Acute toxicity of the vapor (LC50): 1108 ppm, 1 hours [Mouse]. Acute toxicity ofthe vapor (LC50): 3124 ppm, 1 hours [Rat].

Chronic Effects on Humans:CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Hydrochloric acid]. May cause damage to thefollowing organs: kidneys, liver, mucous membranes, upper respiratory tract, skin, eyes, Circulatory System, teeth.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (corrosive, irritant, permeator), of ingestion, . Hazardous in case of eye contact(corrosive), of inhalation (lung corrosive).

Special Remarks on Toxicity to Animals:Lowest Published Lethal Doses (LDL/LCL) LDL [Man] -Route: Oral; 2857 ug/kg LCL [Human] - Route: Inhalation; Dose: 1300ppm/30M LCL [Rabbit] - Route: Inhalation; Dose: 4413 ppm/30M

Special Remarks on Chronic Effects on Humans:May cause adverse reproductive effects (fetoxicity). May affect genetic material.

Special Remarks on other Toxic Effects on Humans:Acute Potential Health Effects: Skin: Corrosive. Causes severe skin irritation and burns. Eyes: Corrosive. Causes severeeye irritation/conjuntivitis, burns, corneal necrosis. Inhalation: May be fatal if inhaled. Material is extremely destructive totissue of the mucous membranes and upper respiratory tract. Inhalation of hydrochloric acid fumes produces nose, throat,and larryngeal burning, and irritation, pain and inflammation, coughing, sneezing, choking sensation, hoarseness, laryngealspasms, upper respiratory tract edema, chest pains, as well has headache, and palpitations. Inhalation of high concentrationscan result in corrosive burns, necrosis of bronchial epithelium, constriction of the larynx and bronchi, nasospetal perforation,glottal closure, occur, particularly if exposure is prolonged. May affect the liver. Ingestion: May be fatal if swallowed. Causesirritation and burning, ulceration, or perforation of the gastrointestinal tract and resultant peritonitis, gastric hemorrhage andinfection. Can also cause nausea, vomitting (with "coffee ground" emesis), diarrhea, thirst, difficulty swallowing, salivation,chills, fever, uneasiness, shock, strictures and stenosis (esophogeal, gastric, pyloric). May affect behavior (excitement), thecardiovascular system (weak rapid pulse, tachycardia), respiration (shallow respiration), and urinary system (kidneys- renalfailure, nephritis). Acute exposure via inhalation or ingestion can also cause erosion of tooth enamel. Chronic Potential HealthEffects: dyspnea, bronchitis. Chemical pneumonitis and pulmonary edema can also








Waste Disposal:

p. 6

Waste must be disposed of in accordance with federal, state and local environmental control regulations.



Identification: : Hydrochloric acid, solution UNNA: 1789 PG: II



Federal and State Regulations:Connecticut hazardous material survey.: Hydrochloric acid Illinois toxic substances disclosure to employee act: Hydrochloricacid Illinois chemical safety act: Hydrochloric acid New York release reporting list: Hydrochloric acid Rhode Island RTKhazardous substances: Hydrochloric acid Pennsylvania RTK: Hydrochloric acid Minnesota: Hydrochloric acid MassachusettsRTK: Hydrochloric acid Massachusetts spill list: Hydrochloric acid New Jersey: Hydrochloric acid New Jersey spill list:Hydrochloric acid Louisiana RTK reporting list: Hydrochloric acid Louisiana spill reporting: Hydrochloric acid CaliforniaDirector's List of Hazardous Substances: Hydrochloric acid TSCA 8(b) inventory: Hydrochloric acid TSCA 4(a) proposed testrules: Hydrochloric acid SARA 302/304/311/312 extremely hazardous substances: Hydrochloric acid SARA 313 toxic chemicalnotification and release reporting: Hydrochloric acid CERCLA: Hazardous substances.: Hydrochloric acid: 5000 lbs. (2268 kg)



WHMIS (Canada):CLASS D-2A: Material causing other toxic effects (VERY TOXIC). CLASS E: Corrosive liquid.

DSCL (EEC):R34- Causes burns. R37- Irritating to respiratory system. S26- In case of contact with eyes, rinse immediately with plenty ofwater and seek medical advice. S45- In case of accident or if you feel unwell, seek medical advice immediately (show the labelwhere possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 1

Personal Protection:


Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:

Protective Equipment:Gloves. Full suit. Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respiratorwhen ventilation is inadequate. Face shield.


p. 7

References:-Hawley, G.G.. The Condensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987. -SAX, N.I.Dangerous Properties of Indutrial Materials. Toronto, Van Nostrand Reinold, 6e ed. 1984. -The Sigma-Aldrich Library ofChemical Safety Data, Edition II. -Guide de la loi et du règlement sur le transport des marchandises dangeureuses au canada.Centre de conformité internatinal Ltée. 1986.


Created: 10/09/2005 05:45 PM

Last Updated: 05/21/2013 12:00 PM


www.wexfordlabs.com

MATERIAL SAFETY DATA SHEET

IDENTITY: (as used on label and list) MSDS CODE NUMBER:

EMULSIFIER- 404 5694-00

SECTION I: (Manufacturer, Address, Telephone, Date Prepared) Date: 05/22/2012 WEXFORD LABS, INC. HMIS RATINGS 0 = Minimal Hazard 325 Leffingwell Avenue Health 3 1 = Slight Hazard Kirkwood, Missouri 63122 Fire 1 2 = Moderate Hazard (800) 506-1146 Physical Hazard 0 3 = Serious Hazard

4 = Severe Hazard Protective Clothing:

CHEMTREC 24-Hour Emergency Number: (800) 424-9300 CHEMTREC 24-Hour International Number: (703) 527-3887

This number may be used for emergency ONLY. SECTION II: (Hazardous Ingredients Identity Information)

Hazardous Components OSHA PEL

ACGIH TLV

Other Limits Recommended

%

Propylene Glycol Monomethyl Ether CAS # 107-98-2

N/A N/A 360 mg/m3 TWA 540 mg/m3 STEL

10.00

SECTION III: (Physical/Chemical Characteristics) Boiling Point Over Special Gravity (H20 = 1) 1.045-1.060

212º F Melting Point N/A Vapor Pressure (mm Hg.) N/A Evaporation Rate (Butyl Acetate =1) N/A Vapor Density (Air = 1) N/A pH of concentrate: 12.0-13.5 Solubility in Water 100% pH of 1:128 in tap water 10.5-12.0 Appearance and Odor Clear liquid, yellowish cast, characteristic odor SECTION IV: (Fire and Explosion Hazard Data) Flash Point: (Pensky-Martens Closed Cup) 147º F Flammable Limits: N/A Extinguishing Media: Suitable to origin of fire LEL: N/A Special Fire Fighting Procedures: NONE UEL: N/A Unusual Fire and Explosion Hazards: NONE SECTION V: (Reactivity Data) Stability: Stable Incompatibility (materials to avoid ): Acids, Ionics, Nonionics Hazardous Decomposition or Byproducts: NONE Hazardous Polymerization: Will not occur SECTION VI: (Health Hazard Data) Route(s) of Entry: Inhalation? N/A Skin? N/A Ingestion? N/A Health Hazards (acute and chronic ): not established Carcinogenicity: N/A NTP? N/A IARC Monographs? N/A OSHA Regulated? N/A Signs and Symptoms of Exposure: Eye irritation and skin erythema might develop upon direct contact with the product. Medical Conditions Generally Aggravated by Exposure: None established Emergency and First Aid Procedures: In case of eye contact, immediately flush eyes with water. If irritation persists, call a physician. If swallowed: drink milk, egg whites, gelatin solution. If these are not available drink large quantities of water. Call a physician.

KEEP OUT OF REACH OF CHILDREN

page 1 of 2

www.wexfordlabs.com

5694-00 EMULSIFIER-404 MSDS SECTION VII: (Precautions for safe handling and use) Steps to be taken in case material is released or spilled: Pick up material spilled with wet vacuum pick-up, squeegee and pan or, or mop. Flush area with water. Allow to dry. Waste Disposal Method: Through conventional sewage system. Observe local regulations. Precautions to be taken in handling and storing: NONE Other Precautions: NONE SECTION VIII: (Control Measures) Respiratory Protection: NONE Ventilation:

Local Exhaust N/A Mechanical (General) N/A Special NONE Other NONE

Protective Gloves: Recommended Eye Protection: Recommended Other Protective Clothing or Equipment: NONE NEEDED Work/Hygienic Practices: Wash hands after handling chemicals. SECTION IX: TRANSPORTATION DOT (Department of Transportation) Proper Shipping Name: Not regulated by this mode of transportation IMDG (International Maritime Dangerous Goods) Proper Shipping Name: Not regulated by this mode of transportation IATA (International Air Transportation Association) Proper Shipping Name: Not regulated by this mode of transportation

KEEP OUT OF REACH OF CHILDREN

page 2 of 2

p. 1

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E

Material Safety Data SheetCopper phthalocyanine MSDS


Product Name: Copper phthalocyanine

Catalog Codes: SLC1513

CAS#: 147-14-8

RTECS: GL8510000

TSCA: TSCA 8(b) inventory: Copper phthalocyanine

CI#: 74160

Synonym: Phthalocyanine Blue Pigment Blue 15;

Chemical Name: Not available.

Chemical Formula: C32H16CuN8









Composition:


Copper phthalocyanine 147-14-8 100

Toxicological Data on Ingredients: Copper phthalocyanine LD50: Not available. LC50: Not available.


Potential Acute Health Effects: Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation.

Potential Chronic Health Effects:Hazardous in case of skin contact (irritant), of eye contact (irritant), of ingestion, of inhalation. CARCINOGENIC EFFECTS:Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTALTOXICITY: Not available. The substance is toxic to kidneys, liver. Repeated or prolonged exposure to the substance canproduce target organs damage.


Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention.

Skin Contact:After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with runningwater and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with anemollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing.


p. 2


Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.


Ingestion:Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, performmouth-to-mouth resuscitation. Seek immediate medical attention.




Auto-Ignition Temperature: Not available.

Flash Points: Not available.

Flammable Limits: Not available.

Products of Combustion: These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.

Fire Hazards in Presence of Various Substances: Not available.



Special Remarks on Fire Hazards: Material in powder form, capable of creating a dust explosion.






Precautions:Keep away from heat. Keep away from sources of ignition. Empty containers pose a fire risk, evaporate the residue undera fume hood. Ground all equipment containing material. Do not breathe dust. Wear suitable protective clothing In case ofinsufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label whenpossible. Avoid contact with skin and eyes

Storage:Keep container dry. Keep in a cool place. Ground all equipment containing material. Keep container tightly closed. Keep in acool, well-ventilated place. Combustible materials should be stored away from extreme heat and away from strong oxidizingagents.

p. 3







Physical state and appearance: Solid. (Microcrystalline solid powder.)




Color: Blue.

pH (1% soln/water): Not applicable.


Melting Point: Not available.










Solubility: Insoluble in cold water.





Incompatibility with various substances: Not available.


p. 4

Special Remarks on Reactivity: Not available.


Polymerization: No.




Chronic Effects on Humans: The substance is toxic to kidneys, liver.

Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant), of ingestion, of inhalation.











Waste Disposal:






Federal and State Regulations:Pennsylvania RTK: Copper phthalocyanine Massachusetts RTK: Copper phthalocyanine TSCA 8(b) inventory: Copperphthalocyanine SARA 313 toxic chemical notification and release reporting: Copper phthalocyanine CERCLA: Hazardoussubstances.: Copper phthalocyanine



p. 5


DSCL (EEC): R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 2

Fire Hazard: 1

Reactivity: 0



Health: 2

Flammability: 1

Reactivity: 0

Specific hazard:





Created: 10/09/2005 04:59 PM

Last Updated: 05/21/2013 12:00 PM


Chlorine Safety Data Sheet P-4580 This SDS conforms to U.S. Code of Federal Regulations 29 CFR 1910.1200, Hazard Communication.

Date of issue: 01/01/1979 Revision date: 11/30/2016 Supersedes: 10/17/2016

EN (English US) SDS ID: P-4580

1/10

This document is only controlled while on the Praxair, Inc. website and a copy of this controlled version is available for download. Praxair cannot assure the integrity or accuracy of any version of this document after it has been downloaded or removed from our website.

SECTION: 1. Product and company identification

1.1. Product identifier

Product form : Substance

Name : Chlorine

CAS No : 7782-50-5

Formula : Cl2

1.2. Relevant identified uses of the substance or mixture and uses advised against

Use of the substance/mixture : Industrial use. Use as directed.

1.3. Details of the supplier of the safety data sheet

Praxair, Inc. 10 Riverview Drive Danbury, CT 06810-6268 - USA T 1-800-772-9247 (1-800-PRAXAIR) - F 1-716-879-2146 www.praxair.com

1.4. Emergency telephone number

Emergency number : Onsite Emergency: 1-800-645-4633 CHEMTREC, 24hr/day 7days/week — Within USA: 1-800-424-9300, Outside USA: 001-703-527-3887 (collect calls accepted, Contract 17729)

SECTION 2: Hazard identification

2.1. Classification of the substance or mixture

GHS-US classification

Ox. Gas 1 H270 Liquefied gas H280 Acute Tox. 2 (Inhalation: gas) H330 Skin Corr. 1A H314 Eye Dam. 1 H318 STOT SE 3 H335 Aquatic Acute 1 H400

2.2. Label elements

GHS-US labeling

Hazard pictograms (GHS-US) :

GHS03

GHS04

GHS05

GHS06

GHS07

GHS09

Signal word (GHS-US) : DANGER

Hazard statements (GHS-US) : H270 - MAY CAUSE OR INTENSIFY FIRE; OXIDIZER H280 - CONTAINS GAS UNDER PRESSURE; MAY EXPLODE IF HEATED H314 - CAUSES SEVERE SKIN BURNS AND EYE DAMAGE H330 - FATAL IF INHALED H400 - VERY TOXIC TO AQUATIC LIFE CGA-HG22 - CORROSIVE TO THE RESPIRATORY TRACT

Precautionary statements (GHS-US) : P202 - Do not handle until all safety precautions have been read and understood P244 - Keep reduction valves/valves and fittings free from oil and grease P260 - Do not breathe gas P264 - Wash hands thoroughly after handling P271+P403 - Use and store only outdoors or in a well-ventilated place P273 - Avoid release to the environment

www.praxair.com



EN (English US) SDS ID: P-4580 2/10


P280+P284 - Wear protective gloves, protective clothing, eye protection, respiratory protection, and/or face protection P370+P376 - In case of fire: Stop leak if safe to do so P405 - Store locked up P501 - Dispose of contents/container Dispose in a safe manner in accordance with local/national regulations CGA-PG05 - Use a back flow preventive device in the piping CGA-PG20+CGA-PG10 - Use only with equipment of compatible materials of construction and rated for cylinder pressure CGA-PG12 - Do not open valve until connected to equipment prepared for use CGA-PG18 - When returning cylinder, install leak tight valve outlet cap or plug CGA-PG06 - Close valve after each use and when empty CGA-PG02 - Protect from sunlight when ambient temperature exceeds 52°C (125°F)

2.3. Other hazards

Other hazards not contributing to the classification

: None.

2.4. Unknown acute toxicity (GHS US)

No data available

SECTION 3: Composition/Information on ingredients

3.1. Substance

Name Product identifier %

Chlorine (Main constituent)

(CAS No) 7782-50-5 100

3.2. Mixture

Not applicable

SECTION 4: First aid measures

4.1. Description of first aid measures

First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. If not breathing, give artificial respiration. If breathing is difficult, trained personnel should give oxygen. Call a physician. . WARNING: To avoid possible chemical burns, the rescuer should avoid breathing any exhaled air from the victim.

First-aid measures after skin contact : Avoid breathing vapors. In case of contact, immediately flush affected areas with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Call a physician. Wash clothing before reuse. Discard contaminated shoes.

First-aid measures after eye contact : Immediately flush eyes thoroughly with water for at least 15 minutes. Hold the eyelids open and away from the eyeballs to ensure that all surfaces are flushed thoroughly. Contact an ophthalmologist immediately.

First-aid measures after ingestion : Ingestion is not considered a potential route of exposure.

4.2. Most important symptoms and effects, both acute and delayed

Symptoms/injuries after inhalation : Overexposure to concentrations moderately above the TLV of 1 ppm irritates the eyes and respiratory tract. Very brief exposure to a concentration of 1000 ppm may be fatal. Acts as an asphyxiant at high concentrations. Inhalation of high concentrations (e.g, greater than 15 ppm) causes choking, coughing, burning of the throat, and severe irritation of the upper respiratory tract; additionally, pulmonary edema, bronchitis, and pneumonitis may result.

4.3. Indication of any immediate medical attention and special treatment needed

Obtain medical assistance.

SECTION 5: Firefighting measures

5.1. Extinguishing media

Suitable extinguishing media : Use extinguishing media appropriate for surrounding fire.

5.2. Special hazards arising from the substance or mixture

Fire hazard : Oxidizer. May accelerate the burning of other combustible materials.

Reactivity : No reactivity hazard other than the effects described in sub-sections below.





5.3. Advice for firefighters

Firefighting instructions : Evacuate all personnel from the danger area. Use self-contained breathing apparatus (SCBA) and protective clothing. Immediately cool containers with water from maximum distance. Stop flow of gas if safe to do so, while continuing cooling water spray. Remove ignition sources if safe to do so. Remove containers from area of fire if safe to do so. On-site fire brigades must comply with OSHA 29 CFR 1910.156 and applicable standards under 29 CFR 1910 Subpart L—Fire Protection.

Protection during firefighting : DANGER! Toxic, corrosive, high-pressure gas..

Special protective equipment for fire fighters : Standard protective clothing and equipment (Self Contained Breathing Apparatus) for fire fighters.

Specific methods : Use fire control measures appropriate for the surrounding fire. Exposure to fire and heat radiation may cause gas containers to rupture. Cool endangered containers with water spray jet from a protected position. Prevent water used in emergency cases from entering sewers and drainage systems Stop flow of product if safe to do so Use water spray or fog to knock down fire fumes if possible.

Other information : Containers are equipped with a pressure relief device. (Exceptions may exist where authorized by DOT.).

SECTION 6: Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

General measures : DANGER: Oxidizing gas. Corrosive. Evacuate personnel to a safe area. Wear a self-contained breathing apparatus and appropriate personal protective equipment (PPE). (gas tight, chemical-protective) Approach suspected leak area with caution. Remove all sources of ignition. Toxic, corrosive vapor can spread from spill. Contact with flammable materials may cause fire or explosion. Ventilate area or move container to a well-ventilated area. Before entering the area, especially a confined area, check the atmosphere with an appropriate device. Prevent from entering sewers, basements and workpits, or any place where its accumulation can be dangerous.

6.1.1. For non-emergency personnel

No additional information available

6.1.2. For emergency responders


6.2. Environmental precautions

Prevent waste from contaminating the surrounding environment. Prevent soil and water pollution. Dispose of contents/container in accordance with local/regional/national/international regulations. Contact supplier for any special requirements.

6.3. Methods and material for containment and cleaning up


6.4. Reference to other sections

See also sections 8 and 13.





SECTION 7: Handling and storage

7.1. Precautions for safe handling

Precautions for safe handling : Do not breathe gas/vapor. Avoid all contact with skin, eyes, or clothing. Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure Wear leather safety gloves and safety shoes when handling cylinders. Protect cylinders from physical damage; do not drag, roll, slide or drop. While moving cylinder, always keep in place removable valve cover. Never attempt to lift a cylinder by its cap; the cap is intended solely to protect the valve. When moving cylinders, even for short distances, use a cart (trolley, hand truck, etc.) designed to transport cylinders. Never insert an object (e.g, wrench, screwdriver, pry bar) into cap openings; doing so may damage the valve and cause a leak. Use an adjustable strap wrench to remove over-tight or rusted caps. Slowly open the valve. If the valve is hard to open, discontinue use and contact your supplier. Close the container valve after each use; keep closed even when empty. Never apply flame or localized heat directly to any part of the container. High temperatures may damage the container and could cause the pressure relief device to fail prematurely, venting the container contents. For other precautions in using this product, see section 16.

7.2. Conditions for safe storage, including any incompatibilities

Storage conditions : Avoid oil, grease and all other combustible materials Store only where temperature will not exceed 125°F (52°C). Post “No Smoking/No Open Flames” signs in storage and use areas. There must be no sources of ignition. Separate packages and protect against potential fire and/or explosion damage following appropriate codes and requirements (e.g, NFPA 30, NFPA 55, NFPA 70, and/or NFPA 221 in the U.S.) or according to requirements determined by the Authority Having Jurisdiction (AHJ). Always secure containers upright to keep them from falling or being knocked over. Install valve protection cap, if provided, firmly in place by hand when the container is not in use. Store full and empty containers separately. Use a first-in, first-out inventory system to prevent storing full containers for long periods. For other precautions in using this product, see section 16 OTHER PRECAUTIONS FOR HANDLING, STORAGE, AND USE: When handling product under pressure, use piping and equipment adequately designed to withstand the pressures to be encountered. Never work on a pressurized system. Use a back flow preventive device in the piping. Gases can cause rapid suffocation because of oxygen deficiency; store and use with adequate ventilation. If a leak occurs, close the container valve and blow down the system in a safe and environmentally correct manner in compliance with all international, federal/national, state/provincial, and local laws; then repair the leak. Never place a container where it may become part of an electrical circuit.

7.3. Specific end use(s)

None.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Chlorine (7782-50-5)

ACGIH ACGIH TLV-TWA (ppm) 0.5 ppm

ACGIH ACGIH TLV-STEL (ppm) 1 ppm

USA OSHA OSHA PEL (Ceiling) (mg/m³) 3 mg/m³

USA OSHA OSHA PEL (Ceiling) (ppm) 1 ppm

USA IDLH US IDLH (ppm) 10 ppm

8.2. Exposure controls

Appropriate engineering controls : Use only in a closed system. A corrosion-resistant, forced-draft fume hood is preferred. LOCAL EXHAUST: A corrosion-resistant system is acceptable.

Eye protection : Wear safety glasses with side shields. Wear goggles and a face shield when transfilling or breaking transfer connections. Provide readily accessible eye wash stations and safety showers. Wear safety glasses with side shields or goggles when transfilling or breaking transfer connections.





Skin and body protection : Wear metatarsal shoes and work gloves for cylinder handling, and protective clothing where needed. Wear appropriate chemical gloves during cylinder changeout or wherever contact with product is possible. Select per OSHA 29 CFR 1910.132, 1910.136, and 1910.138.

Respiratory protection : When workplace conditions warrant respirator use, follow a respiratory protection program that meets OSHA 29 CFR 1910.134, ANSI Z88.2, or MSHA 30 CFR 72.710 (where applicable). Use an air-supplied or air-purifying cartridge if the action level is exceeded. Ensure that the respirator has the appropriate protection factor for the exposure level. If cartridge type respirators are used, the cartridge must be appropriate for the chemical exposure. For emergencies or instances with unknown exposure levels, use a self-contained breathing apparatus (SCBA).

Thermal hazard protection : Wear cold insulating gloves when transfilling or breaking transfer connections.

SECTION 9: Physical and chemical properties

9.1. Information on basic physical and chemical properties

Physical state : Gas

Appearance : Greenish-yellow gas. Amber liquid (under pressure).

Molecular mass : 71 g/mol

Color : Greenish gas.

Odor : Pungent.

Odor threshold : Odor threshold is subjective and inadequate to warn for overexposure. 0.23 mg/m³ (Dixon and Ikels)

pH : Not applicable.

Relative evaporation rate (butyl acetate=1) : No data available

Relative evaporation rate (ether=1) : Not applicable.

Melting point : -101 °C (-149.85°F)

Freezing point : No data available

Boiling point : -34.05 °C (-29.25°F)

Flash point : Not applicable.

Critical temperature : 144 °C

Auto-ignition temperature : Not applicable.

Decomposition temperature : No data available

Flammability (solid, gas) : No data available

Vapor pressure : 6.9 bar (100 psia) (@20°C [68°F])

Critical pressure : 77.11 bar (1118.4 psia)

Relative vapor density at 20 °C : No data available

Relative density : 1.6

Density : 2.7 kg/m³ (at 50 °C)

Relative gas density : 2.5

Solubility : Water: 8620 mg/l

Log Pow : Not applicable.

Log Kow : Not applicable.

Viscosity, kinematic : Not applicable.

Viscosity, dynamic : Not applicable.

Explosive properties : Not applicable.

Oxidizing properties : Oxidizer.

Explosion limits : Non flammable.

9.2. Other information

Gas group : Liquefied gas

Additional information : Gas/vapor heavier than air. May accumulate in confined spaces, particularly at or below ground level





SECTION 10: Stability and reactivity

10.1. Reactivity

No reactivity hazard other than the effects described in sub-sections below.

10.2. Chemical stability

Stable under normal conditions.

10.3. Possibility of hazardous reactions

May occur.

10.4. Conditions to avoid

Air contact. High temperature. Moisture. Incompatible materials.

10.5. Incompatible materials

Chlorine reacts with most materials, especially flammable materials, other reducing agents, and nearly all metals. At temperatures below 250°F (121°C) certain common metals (e.g, iron, copper, steel, lead, nickel) resist reaction with dry chlorine, but others (e.g, aluminum, arsenic, gold, mercury, tin, titanium) react. Moist chlorine is highly corrosive except to glass, stoneware, porcelain, and certain alloys and only at low pressure. Titanium ignites spontaneously on contact with dry chlorine. Carbon steel ignites in chlorine at temperatures near 483°F (251°C).

10.6. Hazardous decomposition products

Toxic fumes. Chlorides.

SECTION 11: Toxicological information

11.1. Information on toxicological effects

Acute toxicity : Inhalation:gas: FATAL IF INHALED.

Chlorine ( \f )7782-50-5

LC50 inhalation rat (ppm) 146.5 ppm/4h

ATE US (gases) 146.500 ppmV/4h

Skin corrosion/irritation : CAUSES SEVERE SKIN BURNS AND EYE DAMAGE.

pH: Not applicable.

Serious eye damage/irritation : CAUSES SERIOUS EYE DAMAGE.

pH: Not applicable.

Respiratory or skin sensitization : Not classified

Germ cell mutagenicity : Not classified

Carcinogenicity : Not classified

Reproductive toxicity : Not classified

Specific target organ toxicity (single exposure) : MAY CAUSE RESPIRATORY IRRITATION.

Specific target organ toxicity (repeated exposure)

: Not classified

Aspiration hazard : Not classified

Symptoms/injuries after inhalation : Overexposure to concentrations moderately above the TLV of 1 ppm irritates the eyes and respiratory tract. Very brief exposure to a concentration of 1000 ppm may be fatal. Acts as an asphyxiant at high concentrations. Inhalation of high concentrations (e.g, greater than 15 ppm) causes choking, coughing, burning of the throat, and severe irritation of the upper respiratory tract; additionally, pulmonary edema, bronchitis, and pneumonitis may result.

SECTION 12: Ecological information

12.1. Toxicity

Ecology - general : VERY TOXIC TO AQUATIC LIFE.


LC50 fish 1 0.44 mg/l (Exposure time: 96 h - Species: Lepomis macrochirus [flow-through])

EC50 Daphnia 1 0.017 mg/l (Exposure time: 48 h - Species: Daphnia magna)






LC50 fish 2 0.014 mg/l (Exposure time: 96 h - Species: Oncorhynchus mykiss [flow-through])

12.2. Persistence and degradability


Persistence and degradability Not applicable for inorganic gases.

12.3. Bioaccumulative potential


BCF fish 1 (no bioaccumulation expected)

Log Pow Not applicable.

Log Kow Not applicable.

Bioaccumulative potential No data available.

12.4. Mobility in soil


Mobility in soil No data available.

Ecology - soil Because of its high volatility, the product is unlikely to cause ground or water pollution.

12.5. Other adverse effects

Other adverse effects : May cause pH changes in aqueous ecological systems.

Effect on ozone layer : None

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Waste disposal recommendations : Do not attempt to dispose of residual or unused quantities. Return container to supplier.

SECTION 14: Transport information

In accordance with DOT

Transport document description : UN1017 Chlorine, 2.3

UN-No.(DOT) : UN1017

Proper Shipping Name (DOT) : Chlorine

Class (DOT) : 2.3 - Class 2.3 - Poisonous gas 49 CFR 173.115

Hazard labels (DOT) : Poison Gas 2.3 - Poison gas

DOT Special Provisions (49 CFR 172.102) : 2 - This material is poisonous by inhalation (see 171.8 of this subchapter) in Hazard Zone B (see 173.116(a) or 173.133(a) of this subchapter), and must be described as an inhalation hazard under the provisions of this subchapter B9 - Bottom outlets are not authorized B14 - Each bulk packaging, except a tank car or a multi-unit-tank car tank, must be insulated with an insulating material so that the overall thermal conductance at 15.5 C (60 F) is no more than 1.5333 kilojoules per hour per square meter per degree Celsius (0.075 Btu per hour per square foot per degree Fahrenheit) temperature differential. Insulating materials must not promote corrosion to steel when wet N86 - UN pressure receptacles made of aluminum alloy are not authorized T50 - When portable tank instruction T50 is referenced in Column (7) of the 172.101 Table, the applicable liquefied compressed gases are authorized to be transported in portable tanks in accordance with the requirements of 173.313 of this subchapter TP19 - The calculated wall thickness must be increased by 3 mm at the time of construction. Wall thickness must be verified ultrasonically at intervals midway between periodic hydraulic tests (every 2.5 years). The portable tank must not be used if the wall thickness is less than that prescribed by the applicable T code in Column (7) of the Table for this material





Marine pollutant : P

Additional information

Emergency Response Guide (ERG) Number : 124;173

Other information : No supplementary information available.

Special transport precautions : Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: - Ensure there is adequate ventilation. - Ensure that containers are firmly secured. - Ensure cylinder valve is closed and not leaking. - Ensure valve outlet cap nut or plug (where provided) is correctly fitted. - Ensure valve protection device (where provided) is correctly fitted.

Transport by sea

UN-No. (IMDG) : 1017

Proper Shipping Name (IMDG) : CHLORINE

Class (IMDG) : 2 - Gases

MFAG-No : 124

Air transport

UN-No. (IATA) : 1017

Proper Shipping Name (IATA) : Chlorine

Class (IATA) : 2

Civil Aeronautics Law : Gases under pressure/Gases toxic under pressure

SECTION 15: Regulatory information

15.1. US Federal regulations


Listed on the United States TSCA (Toxic Substances Control Act) inventory Listed on the United States SARA Section 302 Subject to reporting requirements of United States SARA Section 313

CERCLA RQ 10 lb

SARA Section 302 Threshold Planning Quantity (TPQ)

100 lb

SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Delayed (chronic) health hazard Sudden release of pressure hazard Fire hazard

SARA Section 313 - Emission Reporting 1.0 %

15.2. International regulations

CANADA


Listed on the Canadian DSL (Domestic Substances List)

EU-Regulations






Listed on the EEC inventory EINECS (European Inventory of Existing Commercial Chemical Substances)

15.2.2. National regulations


Listed on the AICS (Australian Inventory of Chemical Substances) Listed on IECSC (Inventory of Existing Chemical Substances Produced or Imported in China) Listed on the Korean ECL (Existing Chemicals List) Listed on NZIoC (New Zealand Inventory of Chemicals) Listed on PICCS (Philippines Inventory of Chemicals and Chemical Substances) Japanese Poisonous and Deleterious Substances Control Law Listed on the Canadian IDL (Ingredient Disclosure List) Listed on INSQ (Mexican National Inventory of Chemical Substances) Listed on CICR (Turkish Inventory and Control of Chemicals)

15.3. US State regulations

Chlorine(7782-50-5)

U.S. - California - Proposition 65 - Carcinogens List No

U.S. - California - Proposition 65 - Developmental Toxicity

No

U.S. - California - Proposition 65 - Reproductive Toxicity - Female

No

U.S. - California - Proposition 65 - Reproductive Toxicity - Male

No

State or local regulations U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) - Environmental Hazard List U.S. - Pennsylvania - RTK (Right to Know) List

SECTION 16: Other information

Other information : When you mix two or more chemicals, you can create additional, unexpected hazards. Obtain and evaluate the safety information for each component before you produce the mixture. Consult an industrial hygienist or other trained person when you evaluate the end product. Before using any plastics, confirm their compatibility with this product Praxair asks users of this product to study this SDS and become aware of the product hazards and safety information. To promote safe use of this product, a user should (1) notify employees, agents, and contractors of the information in this SDS and of any other known product hazards and safety information, (2) furnish this information to each purchaser of the product, and (3) ask each purchaser to notify its employees and customers of the product hazards and safety information The opinions expressed herein are those of qualified experts within Praxair, Inc. We believe that the information contained herein is current as of the date of this Safety Data Sheet. Since the use of this information and the conditions of use are not within the control of Praxair, Inc, it is the user's obligation to determine the conditions of safe use of the product Praxair SDSs are furnished on sale or delivery by Praxair or the independent distributors and suppliers who package and sell our products. To obtain current SDSs for these products, contact your Praxair sales representative, local distributor, or supplier, or download from www.praxair.com. If you have questions regarding Praxair SDSs, would like the document number and date of the latest SDS, or would like the names of the Praxair suppliers in your area, phone or write the Praxair Call Center (Phone: 1-800-PRAXAIR/1-800-772-9247; Address: Praxair Call Center, Praxair, Inc, P.O. Box 44, Tonawanda, NY 14151-0044) PRAXAIR and the Flowing Airstream design are trademarks or registered trademarks of Praxair Technology, Inc. in the United States and/or other countries.





NFPA health hazard : 4 - Very short exposure could cause death or serious residual injury even though prompt medical attention was given.

NFPA fire hazard : 0 - Materials that will not burn.

NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water.

NFPA specific hazard : OX - This denotes an oxidizer, a chemical which can greatly increase the rate of combustion/fire.

HMIS III Rating

Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given

Flammability : 0 Minimal Hazard

Physical : 2 Moderate Hazard

SDS US (GHS HazCom 2012) - Praxair

This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. It should not therefore be construed as guaranteeing any specific property of the product.

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Material Safety Data SheetSodium hydroxide MSDS


Product Name: Sodium hydroxide


CAS#: 1310-73-2

RTECS: WB4900000

TSCA: TSCA 8(b) inventory: Sodium hydroxide

CI#: Not available.

Synonym: Caustic Soda

Chemical Name: Sodium Hydroxide

Chemical Formula: NaOH









Composition:


Sodium hydroxide 1310-73-2 100

Toxicological Data on Ingredients: Sodium hydroxide LD50: Not available. LC50: Not available.


Potential Acute Health Effects:Very hazardous in case of skin contact (corrosive, irritant, permeator), of eye contact (irritant, corrosive), of ingestion,of inhalation. The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage orblindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal orrespiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,unconsciousness or death. Inflammation of the eye is characterized by redness, watering, and itching. Skin inflammation ischaracterized by itching, scaling, reddening, or, occasionally, blistering.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells.TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance may be toxic tomucous membranes, upper respiratory tract, skin, eyes. Repeated or prolonged exposure to the substance can produce targetorgans damage. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure canproduce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation orlung damage.


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Fire Hazards in Presence of Various Substances: metals

Explosion Hazards in Presence of Various Substances:Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product inpresence of static discharge: Not available. Slightly explosive in presence of heat.

Fire Fighting Media and Instructions: Not available

Special Remarks on Fire Hazards:sodium hydroxide + zinc metal dust causes ignition of the latter. Under proper conditions of temperature, pressure and stateof division, it can ignite or react violently with acetaldehyde, ally alcohol, allyl chloride, benzene-1,4-diol, chlorine trifluoride,1,2 dichlorethylene, nitroethane, nitromethane, nitroparaffins, nitropropane, cinnamaldehyde, 2,2-dichloro-3,3-dimethylbutane.Sodium hydroxide in contact with water may generate enough heat to ignite adjacent combustible materials. Phosphorousboiled with NaOH yields mixed phosphines which may ignite spontanously in air. sodium hydroxide and cinnamaldehyde +heat may cause ignition. Reaction with certain metals releases flammable and explosive hydrogen gas.

Special Remarks on Explosion Hazards:Sodium hydroxide reacts to form explosive products with ammonia + silver nitrate. Benzene extract of allyl benzenesulfonateprepared from allyl alcohol, and benzene sulfonyl chloride in presence of aquesous sodium hydroxide, under vacuumdistillation, residue darkened and exploded. Sodium Hydroxde + impure tetrahydrofuran, which can contain peroxides, can

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cause serious explosions. Dry mixtures of sodium hydroxide and sodium tetrahydroborate liberate hydrogen explosively at230-270 deg. C. Sodium Hydroxide reacts with sodium salt of trichlorophenol + methyl alcohol + trichlorobenzene + heat tocause an explosion.


Small Spill:Use appropriate tools to put the spilled solid in a convenient waste disposal container. If necessary: Neutralize the residue witha dilute solution of acetic acid.

Large Spill:Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water sprayto reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance on disposal.Neutralize the residue with a dilute solution of acetic acid. Be careful that the product is not present at a concentration levelabove TLV. Check TLV on the MSDS and with local authorities.


Precautions:Keep container dry. Do not breathe dust. Never add water to this product. In case of insufficient ventilation, wear suitablerespiratory equipment. If you feel unwell, seek medical attention and show the label when possible. Avoid contact with skinand eyes. Keep away from incompatibles such as oxidizing agents, reducing agents, metals, acids, alkalis, moisture.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area. Hygroscopic. Deliquescent.





Exposure Limits:STEL: 2 (mg/m3) from ACGIH (TLV) [United States] TWA: 2 CEIL: 2 (mg/m3) from OSHA (PEL) [United States] CEIL: 2 (mg/m3) from NIOSHConsult local authorities for acceptable exposure limits.


Physical state and appearance: Solid. (Deliquescent solid.)

Odor: Odorless.



Color: White.

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pH (1% soln/water): 13.5 [Basic.]












Solubility: Easily soluble in cold water.




Conditions of Instability: Incompatible materials, moisture, moist air

Incompatibility with various substances:Highly reactive with metals. Reactive with oxidizing agents, reducing agents, acids, alkalis, moisture.


Special Remarks on Reactivity:Hygroscopic. Much heat is evolved when solid material is dissolved in water. Therefore cold water and caution must be usedfor this process. Sodium hydroxide solution and octanol + diborane during a work-up of a reaction mixture of oxime anddiborane in tetrahyrofuran is very exothermic, a mild explosion being noted on one occassion. Reactive with water, acids(mineral, non-oxidizing, e.g. hydrochloric, hydrofluoric acid, muriatic acid, phosphoric), acids (mineral, oxidizing e.g. chromicacid, hypochlorous acid, nitric acid, sulfuric acid), acids (organic e.g. acetic acid, benzoic acid, formic acid, methanoic acid,oxalic acid), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, foraldehyde), carbamates (e.g. carbanolate, carbofuran),esters (e.g. butyl acetate, ethyl acetate, propyl formate), halogenated organics (dibromoethane, hexachlorobenzene, methylchloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (acetone, acetophenone, MEK, MIBK), acidchlorides, strong bases, strong oxidizing agents, strong reducing agents, flammable liquids, powdered metals and metals (i.ealuminum, tin, zinc, hafnium, raney nickel), metals (alkali and alkaline e.g. cesium, potassium, sodium), metal compounds(toxic e.g. berylium, lead acetate, nickel carbonyl, tetraethyl lead), mitrides (e.g. potassium nitride, sodium nitride), nitriles(e.g. acetonitrile, methyl cyanide), nitro compounds (organic e.g. nitrobenzene, nitromethane), acetic anhydride, chlorohydrin,chlorosulfonic acid, ethylene cyanohydrin, glyoxal, hydrosulfuric acid, oleum, propiolactone, acylonitrile, phorosous pentoxide,chloroethanol, chloroform-methanol, tetrahydroborate, cyanogen azide, 1,2,4,5 tetrachlorobenzene, cinnamaldehyde. Reactswith formaldehyde hydroxide to yield formic acid, and hydrogen.

Special Remarks on Corrosivity: Very caustic to aluminum and other metals in presence of moisture.




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Chronic Effects on Humans:MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. May cause damage to the following organs: mucousmembranes, upper respiratory tract, skin, eyes.


Special Remarks on Toxicity to Animals:Lowest Published Lethal Dose: LDL [Rabbit] - Route: Oral; Dose: 500 mg/kg

Special Remarks on Chronic Effects on Humans: May affect genetic material. Investigation as a mutagen (cytogeneticanalysis)

Special Remarks on other Toxic Effects on Humans:











Identification: : Sodium hydroxide, solid UNNA: 1823 PG: II



Federal and State Regulations:Illinois toxic substances disclosure to employee act: Sodium hydroxide Illinois chemical safety act: Sodium hydroxide NewYork release reporting list: Sodium hydroxide Rhode Island RTK hazardous substances: Sodium hydroxide PennsylvaniaRTK: Sodium hydroxide Minnesota: Sodium hydroxide Massachusetts RTK: Sodium hydroxide New Jersey: Sodium hydroxideLouisiana spill reporting: Sodium hydroxide California Director's List of Hazardous Substances: Sodium hydroxide TSCA 8(b)inventory: Sodium hydroxide CERCLA: Hazardous substances.: Sodium hydroxide: 1000 lbs. (453.6 kg)


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DSCL (EEC):R35- Causes severe burns. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.S37/39- Wear suitable gloves and eye/face protection. S45- In case of accident or if you feel unwell, seek medical adviceimmediately (show the label where possible).

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 2



Health: 3

Flammability: 0

Reactivity: 1

Specific hazard:





Created: 10/09/2005 06:32 PM

Last Updated: 05/21/2013 12:00 PM


Material Safety Data SheetAmmonium Molybdate, 1% W/V in Sulfuric Acid, 1N

- 1 -

Section 1 - Chemical Product and Company Identification

MSDS Name:Ammonium Molybdate, 1% W/V in Sulfuric Acid, 1N

Catalog Numbers:LC11200

Synonyms:

Company Identification:LabChem Inc200 William Pitt WayPittsburgh, PA 15238

Company Phone Number:(412) 826-5230

Emergency Phone Number:(800) 424-9300

CHEMTREC Phone Number:(800) 424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name: Percent7732-18-5 Water balance

7664-93-9 Sulfuric acid <3

Section 3 - Hazards Identification

Emergency OverviewAppearance: Colorless

Caution! Corrosive. Causes eye and skin burns. Causes digestive andrespiratory tract burns.

Target Organs: None.

Potential Health EffectsEye:

Causes severe eye burns. Eye contact can result in blindness; exposure to mist leads to watering,irritation.

Skin:Skin contact may result in severe burns, blistering, pain.

Ingestion:May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns.Vomiting and diarrhea of dark blood may occur; asphyxia from throat swelling. Stomach andesophagus may become perforated.

ISO9001:2000 Certified


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Inhalation:May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breathand delayed lung edema. Causes chemical burns to the respiratory tract. At 5mg/M3 concentrations,nose and throat irritation occurs, with headache, cough, increased respiratory rate, impairment oflung to ventilate.

Chronic:Delayed symptoms include tight chest, fluid in lungs, cyanosis (blue color), hypotension, bronchitisor emphysema. tracheobronchitis, dental erosion/discoloration, pneumonia, gastrointestinaldisturbances may occur. Skin irritation/dermatitis, conjunctivitis and lacrimation of the eye canoccur.

Section 4 - First Aid Measures

Eyes:Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upperand lower lids until chemical is gone. Get medical aid at once.

Skin:Get medical aid at once. Immediately flush skin with plenty of soap and water for at least 15minutes while removing contaminated clothing and shoes.

Ingestion:Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical aidat once. Give one ounce (30ml) of milk of magnesia. Give conscious victim large quantities of waterto dilute acid.

Inhalation:Get medical aid at once. Move victim to fresh air immediately. Give artificial respiration ifnecessary. If breathing is difficult, give oxygen.

Notes to Physician:Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information:As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH(approved or equivalent), and full protective gear. Contact with metals may evolve flammablehydrogen gas. Avoid breathing toxic and corrosive vapors - keep upwind.

Extinguishing Media:Use extinguishing media most appropriate for the surrounding fire.

Autoignition Temperature:No information found.

Flash Point:No information found.

NFPA Rating:CAS# 12054-85-2: Not published.CAS# 7732-18-5: Not published.CAS# 7664-93-9: health - 3; flammability - 0; reactivity - 2.

Explosion Limits:Lower: n/a Upper: n/a


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Section 6 - Accidental Release Measures

General Information:Use proper personal protective equipment as indicated in Section 8.

Spills/Leaks:May be neutralized with slaked lime, limestone, or sodium bicarbonate to a pH 7. Place in labeledplastic containers for disposal, wash area down with water.

Section 7 - Handling and Storage

Handling:Wash thoroughly after handling. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.Use with adequate ventilation.

Storage:Do not store near alkaline substances. Store in labeled non-reactive containers (glass, plastic)protected from heat and incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls:Use adequate general or local exhaust ventilation to keep airborne concentrations below thepermissible exposure limits.

Exposure Limits:Chemical Name: ACGIH NIOSH OSHA

Water None of the componentsare on this list.

None of the componentsare on this list.

None of the componentsare on this list.

Sulfuric acid 1 mg/m3 TWA;3 mg/m3STEL

1 mg/m3 TWA 1 mg/m3 TWA;

Ammoniummolybdate,tetrahydrate

None listed. None listed. None listed.

OSHA Vacated PELs:Sulfuric acid: 1 mg/m3 TWA

Personal Protective EquipmentEyes:

Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye andface protection regulations in 29 CFR 1910.133. Provide an eye-wash fountain in the immediatework area. Do not wear contact lenses when working with chemicals.

Skin:Wear appropriate protective gloves to prevent skin exposure.

Clothing:Wear acid protective clothing and gloves.

Respirators:50mg/M3 -GMAGHiEP/HiEPF/SAF/SCBAF.100mg/M3 - SAF:PD,PP,CF.Escape - GMAGHiEP/SCBA. Firefighting - SCBAF:PD,PP.


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(Respirator Codes: (NIOSH) PUblication No. 78-210)

Section 9 - Physical and Chemical PropertiesPhysical State: Liquid

Color: ColorlessOdor: Odorless

pH: AcidicVapor Pressure: No information found.Vapor Density: No information found.

Evaporation Rate: <etherViscosity: No information found.

Boiling Point: No information found.Freezing/Melting Point: No information found.

Decomposition Temperature: No information found.Solubility in water: Soluble.

Specific Gravity/Density: 1.0 - 1.7Molecular Formula: No information found.

Molecular Weight: No information found.

Section 10 - Stability and Reactivity

Chemical Stability:Stable under normal temperatures and pressures.

Conditions to Avoid:Incompatible materials, excess heat, combustible materials, organic materials, oxidizers, amines,bases.

Incompatibilities with Other Materials:Explosive or violent reactions with acetone cyanohydrin, acetone and nitric acid or potassiumdichromate, acrylonitrile, alcohols, hydrogen peroxide, allyl chloride, bromates and metals, brominepentafluoride, carbides, all chlorates, chlorine trifluoride, cuprous nitride, ethylene cyanohydrin,fulminates, indane and nitric acid, iron, mercuric nitride, nitric acid and glycerides, p-nitrotoluene,pentasilver trihydroxydiaminophosphate, perchlorates, phosphorus isocyanate picrates, sliverpermanganate, sodium, sodium carbonate, toluene and nitric acid. Dangerous temperatures andpressures occur with other substances, especially organic combinations. Explosive hydrogen gas isevolved from contact with steel, other metals.

Hazardous Decomposition Products:Oxides of sulfur, hydrogen gas, oxides of nitrogen, ammonia, toxic and irritating vapors.

Hazardous Polymerization:Has not been reported.

Section 11 - Toxicological Information

RTECS:CAS# 7732-18-5: ZC0110000.CAS# 7664-93-9: WS5600000.CAS# 12054-85-2:QA4900000.

LD50/LC50:CAS# 7732-18-5:


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Oral, rat: LD50 = >90 mL/kg.CAS# 7664-93-9:

Inhalation, mouse: LC50 =320 mg/m3/2HInhalation, rat: LC50 =510 mg/m3/2HOral, rat: LD50 = 2140 mg/kg.

CAS# 12054-85-2:Inhalation, rat: LD50 =>1930 mg/m3/4HOral, rat: LD50 = 3883 mg/kg.

Carcinogenicity:CAS# 7732-18-5: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop

65.CAS# 7664-93-9

ACGIH: A2 - Suspected Human Carcinogen (contained in strong inorganic acid mists)California: Not listed.NIOSH: Not listed.NTP: Not listed.OSHA: Select carcinogenIARC: Group 1 carcinogen

CAS# 12054-85-2: Not listed as a carcinogen by ACGIH, IARC, NIOSH, NTP, OSHA, or CA Prop65.

Epidemiology:Ammonium molybdate is a severe eye, skin, and mucous membrane irritant.

Teratogenicity:

Reproductive:

Mutagenicity:

Neurotoxicity:

Section 12 - Ecological Information

No information found.

Section 13 - Disposal Considerations

Dispose of in accordance with Federal, State, and local regulations.

Section 14 - Transport Information

US DOT

Shipping Name: Sulfuric acid solutionHazard Class: 8

UN Number: UN2796Packing Group: PG II


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Section 15 - Regulatory Information

US FederalTSCA:

CAS# 7732-18-5 is listed on the TSCA Inventory.CAS# 7664-93-9 is listed on the TSCA Inventory.CAS# 12054-85-2: is listed on the TSCA Inventory.

SARA Reportable Quantities (RQ):CAS# 7664-93-9: final RQ = 1000 pounds (454 kg)

CERCLA/SARA Section 313:This material contains Sulfuric acid (CAS# 7664-93-9, 3%),which is subject to the reportingrequirements of Section 313 of SARA Title III and 40 CFR Part 373.

OSHA - Highly Hazardous:None of the components are on this list.

US StateState Right to Know:

Sulfuric acid can be found on the following state Right-to-Know lists: California, New Jersey,Florida, Pennsylvania, Minnesota, Massachusetts.Ammonium molybdate can be found on the following state Right-to-Know lists: New Jersey

California Regulations:

European/International RegulationsCanadian DSL/NDSL:

CAS# 7732-18-5 is listed on Canada's DSL List.CAS# 7664-93-9 is listed on Canada's DSL List. CAS# 12054-85-2: is listed on Canada's DSL List.

Canada Ingredient Disclosure List:CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List.CAS# 7664-93-9 is listed on Canada's Ingredient Disclosure List.CAS# 12054-85-2: is listed on Canada's Ingredient Disclosure List.

Section 16 - Other Information

MSDS Creation Date: October 25, 2007Revision Date: None

Information in this MSDS is from available published sources and is believed to be accurate. No warranty, express or implied,is made and LabChem Inc. assumes no liability resulting from the use of this MSDS. The user must determine suitability of thisinformation for his application.

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Material Safety Data SheetAluminum chloride, anhydrous MSDS


Product Name: Aluminum chloride, anhydrous

Catalog Codes: SLA1015

CAS#: 7446-70-0

RTECS: BD0525000

TSCA: TSCA 8(b) inventory: Aluminum chloride, anhydrous

CI#: Not available.

Synonym:

Chemical Name: Aluminum trichloride

Chemical Formula: AlCl3









Composition:


Aluminum chloride, anhydrous 7446-70-0 100

Toxicological Data on Ingredients: Aluminum chloride, anhydrous: ORAL (LD50): Acute: 3805 mg/kg [Mouse.].


Potential Acute Health Effects:Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive), ofeye contact (irritant). The amount of tissue damage depends on length of contact. Eye contact can result in corneal damage orblindness. Skin contact can produce inflammation and blistering. Inhalation of dust will produce irritation to gastro-intestinal orrespiratory tract, characterized by burning, sneezing and coughing. Severe over-exposure can produce lung damage, choking,unconsciousness or death.

Potential Chronic Health Effects:CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available.DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, mucous membranes. Repeated or prolongedexposure to the substance can produce target organs damage. Repeated exposure of the eyes to a low level of dust canproduce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dustcan produce varying degree of respiratory irritation or lung damage. Repeated exposure to a highly toxic material may producegeneral deterioration of health by an accumulation in one or many human organs.


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Eye Contact:Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of water for at least 15minutes. Get medical attention.

Skin Contact:In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothingand shoes. Cover the irritated skin with an emollient. Wash clothing before reuse. Thoroughly clean shoes before reuse. Getmedical attention immediately.



















Large Spill:Corrosive solid. Poisonous solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Usewater spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Call for assistance ondisposal.

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Precautions:Keep locked up.. Keep container dry. Do not ingest. Do not breathe dust. Never add water to this product. In case ofinsufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show thecontainer or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as metals.

Storage: Keep container tightly closed. Keep container in a cool, well-ventilated area.











Color: White to yellowish.



Melting Point: Sublimes.










Solubility: Not available.

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Incompatibility with various substances: Reactive with metals.


Special Remarks on Reactivity: Reacts violently with water especially when water is added to the product.





Toxicity to Animals:WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oraltoxicity (LD50): 3805 mg/kg [Mouse.]. Acute toxicity of the dust (LC50): 5 8 hours [Human/30 min].

Chronic Effects on Humans: Causes damage to the following organs: lungs, mucous membranes.

Other Toxic Effects on Humans:Very hazardous in case of skin contact (irritant), of ingestion, of inhalation. Hazardous in case of skin contact (corrosive).











Waste Disposal:



Identification: : Aluminum Chloride, Anhydrous UNNA: UN1726 PG: II


p. 5


Federal and State Regulations:Pennsylvania RTK: Aluminum chloride, anhydrous Massachusetts RTK: Aluminum chloride, anhydrous TSCA 8(b) inventory:Aluminum chloride, anhydrous



WHMIS (Canada):CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC). CLASS D-2A: Material causing other toxiceffects (VERY TOXIC). CLASS E: Corrosive solid.

DSCL (EEC): R36/38- Irritating to eyes and skin.

HMIS (U.S.A.):

Health Hazard: 3

Fire Hazard: 0

Reactivity: 0



Health: 3

Flammability: 0

Reactivity: 0

Specific hazard:



References:-Material safety data sheet emitted by: la Commission de la Santé et de la Sécurité du Travail du Québec. -Hawley, G.G.. TheCondensed Chemical Dictionary, 11e ed., New York N.Y., Van Nostrand Reinold, 1987.


Created: 10/09/2005 03:40 PM

Last Updated: 05/21/2013 12:00 PM


Enclosure: 5

Chemical Name and Physical Form of Raw Materials with Its Storage Facility

Sr. No.

Raw Material Chemical Name/ Other Name

CAS No. Physical Form

Storage Maximum Storage at a time (MT)

1. Ortho Nitro Toluene 2‐Nitrotoluene 88‐72‐2 Liquid Drum 135

2. Sulphuric Acid Dihydrogen sulfate 7664‐93‐9 Liquid MSRL Tank 167

3. Caustic Lye Sodium hydroxide 1310‐73‐2 Liquid HDPE Drum 3

4. Xylene Dimethylbenzene 7647‐01‐0 Liquid MS Drum 38 5. Urea Carbonyldiamide 57‐13‐6 Solid HDPE Bags 116 6. Phthalic Anhydride 1,3‐Dioxophthalan 85‐44‐9 Powder HDPE Bags 82 7. Cuprous Chloride Copper(I) chloride 7758‐89‐6 Solid HDPE Bags 15 8. Ammonium Molybdate Molybdic acid 13106‐76‐8 Solid HDPE Bags 0.3 9. Copper Phthalo Cyanine Aqualine Blue 147‐14‐8 Solid HDPE Bags 14 10. Emulsifier ‐‐‐ 107‐98‐2 Solid HDPE Bags 0.6 11. Aluminum Chloride Aluminium trichloride 7446‐70‐0 Solid HDPE Bags 24 12. Salt Sodium chloride 7647‐14‐5 Solid HDPE Bags 6 13. Chlorine Gas Dichlorine 7782‐50‐5 Liq.Gas Cylinder 15

Enclosure: 6

Physical and Chemical Properties of the Raw Material

Sr. No

Product

Physical & Chemical Composition

B.P F.P. LEL TLV,

LD50 mg/kg

Sp.Gr.(Water=1) at

V.D. at

(air=1)

Odour Thre

shold,

Solubility in Water

Chemical Formula

State MW oC oC ppm or mg/nm3

ppm, mg/ Nm3

B Raw Materials

1 Phthallic Anhydride

C8H4O3

Solid 148.12 295 140 0 C

NA TWA: 6.1

4020 1.5 6.6 NA 0.62 gm /100 gm of water

2 Urea

NH2CONH2

Solid 60 NA NA NA NA NA 1.34 @ 20 0C

NA NA 119 gm/100 gm of water @ 25 0C

3 Cuprous chloride

CuCl

Solid 99 1490 NA NA TWA: 1 140 4.14 NA NA Very Slightly Soluble in cold water.

4 Ammonium Molyblate

(NH4)6Mo7 -024. 4H2O

Solid 1242.58 NA NA NA TWA: 2 --- 2.498 NA NA 4.3 gm/Liter of water

5 Aluminum Chloride

AlCl3

Solid 133 NA NA NA NA 3805 2.44 NA NA NA

6 CPC Blue Crude

C32H16CuN8

Solid 576 NA NA NA NA NA 1.5 NA NA Insoluble

7 Chlorine

Cl2

Gas 71 -34 NA NA STEL:2.9 293 NA 2.5 Pungent-Suffocating

7.41

8 Caustic lye

NaOH

Liquid 40 1388

NA NA STEL: 2 NA 2.13 NA NA soluble

10 Sulphuric

Acid

H2SO4

Liquid 98 NA Not Pertinent

Not Pertinent

TWA: 1 2140

1.17 – 1.20 gm/cm3

3.4 Odorless Fully Miscible with water

11 Ortho Nitro Toluene

C7H7NO2 Liquid 137.13 225 106 NA TWA:2 891 1.163 NA 0.54 g/Liter of Water

12 Xylene

C6H4(CH3)2 Liquid 106.17 138.5

24 NA TWA:100 2119

0.864 3.7 1 ppm Insoluble

Enclosure: 7

Details of Hazardous Chemicals

The Raw Materials, which are termed as Hazardous Chemicals as per the "Manufacturing, Storage and Import of Hazardous Chemicals Rules, 1989", are as listed in below:

Name of Hazardous Chemical

Reference The Manufacturer, storage & Import of Hazardous chemical Rules 1989

Maximum quantity that

can be stored at a time (MT)

Threshold Quantity in

(MT)

Phthalic Anhydride

Sr. .No. 508 (Part II, Schedule 1 of MSIHCR, 1989 82 No listed

Cuprous Chloride (Copper & its Compound)

Sr. .No. 146 (Part II, Schedule 1 of MSIHCR, 1989 15 No listed

Alluminium Chloride

Sr. No. 22(Part II, Sch. 1 of MSIHCR, 1989) 24 No listed

Chlorine Gas Sr. No. 119(Part II, Sch. 1 of MSIHCR, 1989) 15 25

Sulphuric Acid Sr. No. 591(Part II, Sch. 1 of MSIHCR, 1989) 167 No listed

Xylene Sr. No. 442(Part II, Sch. 1 of MSIHCR, 1989) 38 Not Listed

Ortho Nitro Toluene

Sr. No. 440(Part II, Sch. 1 of MSIHCR, 1989) 135 Not Listed

Enclosure: 8

Manufacturing Process and Mass Balance

1. Copper Phthalo Cyanine Blue:

Charge orthonitro toluene (solvent) in glass lined vessel. Charge required quantity of Phthalic Anhydride, Urea in a Glass Vessel and givethe desire temperature.Heating the content to higher temperature and then, addition of catalyst(ammonium molybdate) and Cuprous Chloride to it.Raise the temperature of the reaction mass at desire temperature and maintainthis temperature for 6/8 hours. Scrub the ammonia and carbon dioxide gas evolved during the process to waterscrubber to get the solution of ammonium carbonate.After reaction is over, draw the sample and check for complete conversion ofPhthalic Anhydride to CPC Blue Crude.Discharge the batch into Horizontal Rotary Vacuum Dryer (HRVD) and removethe solvent under vacuum. After complete removal of solvent add water to theHorizontal Rotary Vacuum Dryer (HRVD) and transfer the material to treatmenttank.Charge crude CPC in another vessel and add Sodium Hydroxide and dilute bywater, raise the temperature of the total mass for the alkali treatment. Filter thematerial through filter press and wash the wet cake by water.Charge the wet cake of crude CPC in another vessel and add dilute sulphuric acidfrom Alpha plant (@ 16 to 18 % Acid), raise the temperature to the total massfor the acid treatment. Filter the material through filter press and wash the wetcake by water.Dry the material using Spin Flash Dryer (SFD) and collect the dried powder inbags.

Chemical Reaction of Copper Phthalo Cyanine Blue

2. C.P.C. Alpha Blue/ Pigment Alpha Blue 15: Copper phthalocyanine blue is charge in a ball millAfter Ball milling of copper phthalocyanine blue adds 98% sulphuric acid andthoroughly mixed in a vessel to obtain a homogenous paste. The temperature of the vessel is cooled to 100°CThe contents are dumped into another vessel containing water. This is done toreduce sulphuric acid concentration.The concentrate liquor obtained from the previous step is neutralized by alkaliwash (NaOH)Washing materials is followed by filter press.The wet cake of finished product is finally sent down for SFD.

Chemical Reaction of C.P.C. Alpha Blue/ Pigment Alpha Blue 15

CPC Crude CPC ALPHA BLUE

Polymorphic form

3. C.P.C. Green/ Pigment Green 7:

Charge CPC crude in Glass line Reactor. Add calculative quantity of CuCl2 Vacuum Salt Anhydrous AlCl3 in reactor. Then Chlorine gas is being purged to the reaction mass.CuCl2 is used for catalytic purpose and to active the chlorination at 14 to 15 position of CPC molecule. After completion of chlorination the above mass is transferred in the Drowning vessel. The product is then filtered and washed.AlCl3 do not take part in reaction and filtrate is taken as ML for sale to actual users. Then take pigmentation reaction.Charge crude wet cake and add Xylene along with the additives. Reflux the mass for 8 hrs. Then, Xylene is recovered by distillation. The pigment Green product obtained is filtered, washed and then taken out and dried, pulverized, mixed and packed.

Chemical Reaction of C.P.C. Alpha Blue/ Pigment Alpha Blue 15

Mass Balance of CPC Blue Crude

Reaction Vessel4559 Kg

Urea: 1544 Kg

Phthalic Anhydride: 1087 Kg

Cuprous Chloride: 185 Kg

ONT: 1739 Kg

Ammonia Molybdate: 4 Kg

Total: 4559 Kg Vacuum Distillation4210 Kg ONT Recovery: 1704 Kg

Recovery loss: 35 Kg

Vessel4396 Kg

Spent Sulfuric Acid: 1925 Kg (Used from CPC Alpha Blue)

Filtration5831 Kg

Wash Water: 1435 L Spent Acid: 1867 Kg Effluent to ETP: 308 L

Spin Flash Dryer3656 Kg

Drying Loss: 2656 Kg

Final Product 1000Kg of CPC Blue

NH3:326 Kg & CO:24 Kg (goes to Water Scrubbber, Water = 400 L)

Ammonium Carbonate Solution: 750 Kg

Mass Balance of CPC Alpha Blue

Reactor6550 Kg

CPC: 1050 Kg Water: 2000 L Sulphuric Acid: 3500 Kg Total: 6550 Kg

Filtration7550 Kg

3845 Kg ‐ Spent Dilute Sulphuric Acid (To be reused in CPC Blue) 1800 L – Effluent to ETP

Reaction Vessel4110 Kg

Water: 2000 L Emulsifier: 5 Kg Caustic Lye: 200 Kg Total: 2205 Kg

Filter Press6610 Kg

Water: 2500 L Effluent to ETP: 4550 L

Flash Dryer2060 kg

Spray Drying Loss: 1060 Kg

Finished Product 1000 Kg of

CPC Alpha Blue

Water for Wash: 1000 L

CPC: 542 AlCl3: 1898 NaCl: 406 CuCl2: 61 Cl2: 1016

Glass Vessel HCl: 481 & Cl2: 82 Scrubbed in water + Alkali Scrubber system

Dumping Vessel

Water: 2500 Vapour loss: 725 Kg

Filter Press-I 10635 Kg Wash Water: 5500 L Aluminum Chlorides Soln: 4700 Kg

Effluent: 3850 L

Pigmentation Reaction

(S.S Vessel) 6685 Kg

Xylene: 3000 Emulsifier: 40

Caustic Lye: 60 Steam: 1500

Xylene Recovered: 2940 kg Recover Loss: 60 Kg

Filter Press-II 5685 Kg

Wash Water: 2000 L Effluent to ETP: 1680 L

Spin Flash Dryer

Drying Loss: 3005 Kg

CPC Green-7: 1000 Kg

Mass Balance of CPC Green 7:

Calculation of CPC Green: 7

Cl2 (gas): 82 Kg HCl (gas): 481 Kg : 563 KG

Water ScrubberAddition of water: 1200 L

Dilute HCL(25‐28%)

1620 Kg Alkali Scrubber System

Cl2 Gas: 143 Kg +

NaOH (100%): 150 Kg Water: 2000 L

Sodium Hypochloride (NaOCl)

(10‐11%)

2293 Kg

Enclosure: 9

Details of Water Consumption and Waste Water Generation

Application Water Consumption

(KL/Day) Waste Water Generation

(KL/Day) Domestic 5.0 3.0 Gardening 2.0 0.0 Industrial Process 44.7 21.1 Washing 20.0 20.0 Boiler 9.0 1.0 Cooling 3.0 0.0 Scrubber 5.0 0.0 Total 88.7 45.1

Domestic water Consumption will be around 5 KLPD and sewage generated will be disposed to soak pit via septic tank @3 KLPD.

Gardening water consumption will be 2.0 KLPD Industrial effluent generation will be 42.1 KLPD.

We have purchased our industry from M/s. Neelkamal Chemicals and they have already become the member of BEAIL, Ankleshwar. So, after purchase of the industry we are also become the member of BEAIL, Ankleshwar by the name of Neel Pigments Pvt.Ltd. (Unit II) having booking of 45.0 KL/Day.

Product wise water consumption and waste water generation for Process only

Sr. No. Product

Batch Size

(in Kg)

Production in

MT/Month

No. of Batches/Month

Water Consumption in KL/Batch

Effluent Generation in KL/Batch

Water Consumpti

on in KL/Day

Effluent generation in KL/Day

1 C.P.C. Blue 1000 300 300 1.435 0.308 17.22 3.69

2 C.P.C. Alpha Blue/ Pigment Alpha Blue 15

1000 25 25 7.5 6.35 7.5 6.35

3 C.P.C.Green/ Pigment Green 7

1000 50 50 10.0 5.53 20 11.06

Total 44.7 21.10

Water Balance Diagram

Water Consumption 88.7

Domestic 5

Sewage 3

Gardening 2

Industrial 81.7

Process 44.7

Boiler 9.0

W/W 21.1

Cooling 3.0

W/W 20.0

Scrubber 5.0

Blow down 1.0

To Soak Pit/ Septic Tank

Washing 20.0

All unit in KL/Day

To ETP 42.1

Blow down Nil

Generate Process Hazardous Waste Spent

Acid: 22.4 M/C Loss

0.2

Spent Acid Calculation

Name of Product

Spent Acid Used/Month

Spent Acid Reuse/Month

Fresh Sulphuric Acid Required/Month

Spent Generate/Month

C.P.C. Blue 577.5 96.125 481.375 560

C.P.C. Alpha Blue/ Pigment Alpha Blue 15

‐‐

‐‐‐

87.5

96.125

(Reuse In CPC Blue)

Total Fresh Sulphuric Acid Required: (481.375+87.5) = 568.87 KL/Month

Total Fresh Sulphuric Acid Required: 22.75 KL/Day

Spent Acid Generated: 560 KL/Month

Spent Acid Generated: 22.4 KL/Day

Enclosure: 10

Details of Effluent Treatment Plant

Sr. No. Name of Unit No. of Unit Size (Feet) 1. Collection Tank 2 12×12×7 (Each)

2. Neutralization Tank 2 12×12×7 (Each)

3. Primary Settling Tank 1 16×16×7

4. Aeration Tank 1 20×16×10

5. Secondary settling Tank 1 16×16×7

6. Sludge Drying Bed 1 4×6×3

7. Holding Tank 1 20×18×7

8. Carbon Cum Sand Filter 1 ‐‐‐‐

9. Final Collection Tank 1 20×20×7

10. Over Head Tank 2 50 KL

Enclosure: 11

Details of Flue Gas Emission And Process Gas emission system with APC System

Details of Flue Gas Emission:

Sr. No.

Stack Attached To No. of Unit Stack

Height (m)

Air Pollution Control Measure

Pollutants

SPM mg/NM3

Sox ppm

NOx

ppm

1 Small Industrial Boiler 1 16 ‐‐‐‐ <150 <100 <50

2 Hot Air Generator 1 16 ‐‐‐‐ <150 <100 <50

3 D.G. Set 1 9 ‐‐‐‐ <150 <100 <50

Details of Process Emission:

Sr. No. Stack attached To APCD System Stack

Height Pollutants

1 Reaction vessel Two Stage Scrubber system 11 m

HCl <= 20 mg/NM3

Cl2 <= 09 mg/NM3

2 Reaction vessel Two Stage Scrubber system 11 m NH3 <= 175

mg/NM3

Fuel Requirement:

Sr.No Name of Fuel Quantity 1 Natural Gas 6000 SCM/Day 2 Diesel 10 Lit. /Hr

Process Gas Emission

Sr. No.

Name Of Product Type of Process Gas Emission

NH3 CO2 HCl Cl2 1. CPC Blue √ √ 2. CPC Alpha Blue 3. CPC Green 7 √ √

Enclosure: 12

Details of Hazardous Waste Generation with its Management

Sr.No. Type of Hazardous Waste Cat. No.

Quantity Management

01 ETP Waste 26.2 150MT/M. We will pack all our generated ETP waste into HDPE bags. Then after we will store it into proposed Solid Waste Storage Area. Then after it will be disposed to BEIL as we will become the member of it after obtaining Environment Clearance.

02 Discarded Containers 33.3 500 Nos./M We will store all our discarded containers into provided solid waste storage area. Then after it will be return back to raw material supplier or use for packing of ETP waste.

03 Spent Oil 5.1 10 Lit/Yr. We will store into carboys and then after it will be reuse as a lubricant in our plant machineries.

04 Spent Acid D-2 Sch-2

560 KL/Month

Will be sold to authorized industries

04 Ammonium Carbonate Sch. 2 Class

C1

225 MT/Month

05 HCl D-2 Sch-1

81 MT/Month

06 Sodium Hypo-chloride ---- 115 MT/Month

07 Aluminum Chloride ---- 235 MT/Month

Process Waste Calculation:

Sr. No.

Name of By Product

Generated From

Quantity/MT Of Product

Quantity/Month Management

1. Ammonium Carbonate

CPC Blue (300 MT/M)

0.750 225

Will be sold to authorized industries

2. HCl CPC Green 7 (75 MT/M)

1.620 81

3. Sodium Hypochloride

CPC Green 7 (75 MT/M)

2.293 114.65

4. Alluminium Chloride

CPC Green 7 (75 MT/M)

4.7 235

5. Spent Acid

CPC Blue (300 MT/M)

1.867 560

CPC Alpha Blue(25 MT/M)

3.845 96.125

Enclosure: 13

Name and Address of Partners

Sr.No. Name of Partner Residential Address of Director

0011 Mr. Vipulbhai Vallabhbhai Gajera 402/8/B, Alkapuri Society, New Colony, GIDC Estate,Ankleshwar-393002

0022 Mr. Ghanshyam Vallabhbhai Gajera 17, Abhishek Avenue, GIDC Estate new Colony, Ankleshwar-393002

Enclosure: 14

Land Supporting Document

Enclosure: 15

Site Plan and Layout Plan

(Attached)

Enclosure: 16

Valuation Certificate

(Attached)

Enclosure: 17

SSI Copy (Attached)